KR20040065934A - Fiber supported hollow fiber membrane contained wick of cross stripes - Google Patents

Fiber supported hollow fiber membrane contained wick of cross stripes Download PDF

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KR20040065934A
KR20040065934A KR1020030003144A KR20030003144A KR20040065934A KR 20040065934 A KR20040065934 A KR 20040065934A KR 1020030003144 A KR1020030003144 A KR 1020030003144A KR 20030003144 A KR20030003144 A KR 20030003144A KR 20040065934 A KR20040065934 A KR 20040065934A
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South Korea
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wick
fiber
lattice
fiber support
hollow fiber
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KR1020030003144A
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Korean (ko)
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KR100530312B1 (en
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박헌휘
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박헌휘
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08Hollow fibre membranes
    • B01D69/081Hollow fibre membranes characterised by the fibre diameter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/147Microfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0088Physical treatment with compounds, e.g. swelling, coating or impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • B01D69/107Organic support material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • B01D69/108Inorganic support material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/1213Laminated layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/301Polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/32Polyalkenyl halides containing fluorine atoms
    • B01D71/34Polyvinylidene fluoride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/40Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
    • B01D71/42Polymers of nitriles, e.g. polyacrylonitrile
    • B01D71/421Polyacrylonitrile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/66Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68Polysulfones; Polyethersulfones
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/02Details relating to pores or porosity of the membranes
    • B01D2325/0283Pore size
    • B01D2325/02833Pore size more than 10 and up to 100 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/02Details relating to pores or porosity of the membranes
    • B01D2325/0283Pore size
    • B01D2325/02834Pore size more than 0.1 and up to 1 µm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/24Mechanical properties, e.g. strength

Abstract

PURPOSE: Provided is a fiber support hollow fiber separating membrane comprising a latticed wick which is not cut or damaged by being incorporated with foreign matters in the water due to high tensional strength of 65,000 gf. CONSTITUTION: The fiber support hollow fiber separating membrane comprises a triple structure of a latticed wick consisting of polypropylene, polyethylene or nylon, a fiber support covering the outer surface of the latticed wick and prepared by weaving yarn consisting of polyester, polystyrene, polypropylene, nylon, natural cotton and glass fiber on the outer surface of the latticed wick and a high molecular weight resin (5) comprising porous air gaps (7) having a microfiltration fractioning property and prepared by coating a high molecular weight resin such as polysulfone, polyvinylchloride, polyvinylidenefluoride, polyethersulfone and polyacrylonitrile on the outer surface of the fiber support.

Description

격자형 심지를 포함한 섬유지지체 중공사분리막 {Fiber supported hollow fiber membrane contained wick of cross stripes}Fiber supported hollow fiber membrane contained wick of cross stripes}

본 발명은 폐수에 함유된 부유성 입자를 펌프 등의 물리적인 힘에 의해 가압 및 흡입 여과 할 수 있는 격자형 심지를 포함한 섬유지지체 중공사분리막에 대한 기술이다.The present invention relates to a fiber support hollow fiber separator comprising a lattice wick capable of pressurizing and suction filtration of suspended particles contained in waste water by a physical force such as a pump.

보다 자세하게는 폐수 중에 존재하는 입자성 물질을 제거하는 격자형 심지를 포함한 섬유지지체 중공사분리막으로 중공사분리막의 내부에 공간을 일정하게 분할하며 구조적 형태를 일정하게 유지시켜주는 격자를 포함한 섬유지지체와 섬유지지체 외부 표면에 고분자 수지를 코팅 또는 도포하여 제조된 중공사분리막으로 코팅 또는 도포된 고분자 수지의 정밀여과 분획 특성으로 입자성 물질을 차단하고 여과액만을 투과 후 여과 액은 섬유지지체를 통과하는 격자형 심지를 포함한 섬유 지지체 중공사분리막이다. 중공사분리막은 내부의 격자로 인하여 형성되며 일정하게 분할된 유로를 통하여 여과액이 이송되어지는 격자형 심지를 포함한 섬유지지체중공사분리막이다.More specifically, the fiber support hollow fiber membrane including a lattice wick to remove particulate matter present in the wastewater, and the fiber support including a lattice that divides the space uniformly in the hollow fiber membrane and maintains a constant structural form. A hollow fiber membrane prepared by coating or applying a polymer resin on the outer surface of the fiber support to block the particulate matter with the fine filtration fraction characteristics of the polymer resin coated or coated, and then pass through the filtrate only, and the filtrate passes through the fiber support. It is a fiber support hollow fiber separation membrane including a mold wick. Hollow fiber separation membrane is a fiber-supported hollow fiber membrane, including a lattice wick which is formed due to the internal lattice and the filtrate is transported through a regularly divided flow path.

일반적으로 중공사분리막은 고분자 수지의 단독으로 제조되어 중공사분리막 내부의 단일 유로를 갖고 있어 가압 또는 흡입 등의 방법으로 액체의 여과과정이 장기간 지속되거나 중공사분리막의 표면이 오염되면 투과 압력의 상승으로 구형의 중공사분리막의 형태는 타원형으로 수축하여 결과적으로 중공사분리막 내부 유로가 좁아지게되어 여과액의 원할한 이송이 어렵게 되고, 또한 중공사분리막의 구조적 결함을 주게되어 그 수명이 짧아 지게된다.In general, hollow fiber membranes are made of polymer resin alone and have a single flow path inside the hollow fiber membranes. Therefore, if the filtration process of the liquid continues for a long time or the surface of the hollow fiber membranes is contaminated by pressure or suction, the permeation pressure is increased. As a result, the spherical hollow fiber membrane is shrunk to an elliptical shape, consequently narrowing the internal flow path of the hollow fiber membrane, making it difficult to smoothly transport the filtrate, and shortening the life of the hollow fiber membrane. .

또한, 종래의 중공사분리막은 침적법 및 연신법 등에 의하여 생산되어지며 그 내부 EH는 구조적으로 어떠한 심지 또는 섬유지지체를 갖고있지 않아 일반적으로 알려져 있기로 그 인장강도가 200 gf 이하로 수중의 협잡물 등의 혼입에 의한 분리막의 절단 및 파손 등 분리막의 성능 저하와 손상 등의 문제를 안고있다.In addition, the conventional hollow fiber membranes are produced by the immersion method and the stretching method, and the internal EH does not have any wick or fiber support in structure, so it is generally known that its tensile strength is 200 gf or less, There are problems such as degradation and damage of the membrane, such as cutting and breakage of the membrane due to mixing.

그러므로 본 발명은 상기의 문제점을 해결 방안으로 격자형 심지(1) 외부에 섬유지지체(2)를 직조한(도 2)후 그 섬유지지체(2) 외부 표면에 고분자 수지(5)를 코팅 및 도포하여 정밀여과 분획 특성을 갖는 중공사분리막(도 3)을 제공함으로서 가압 및 흡입에 의한 여과액의 장시간 투과시 중공사분리막(도 3)의 구조적 형태가 변형되지 않음은 물론, 본 발명의 중공사분리막(도 3) 내부로 원할한 여과액의 수송을 할 수 있는 내부유로(6)를 제공하며, 격자형 심지(1)를 포함한 섬유지지체 중공사분리막(도 3)은 격자형 심지(1)와 섬유지지체(2) 및 고분자수지(5)의 3중 구조로 구성됨을 특징으로 하는 중공사분리막(도 3)으로 그 인장강도가 65,000 gf로 수중의 협잡물 등의 혼입에 의한 분리막의 절단 및 파손 등 분리막의 성능 저하와 손상 등의 문제를 해결할 수 있다.Therefore, the present invention is to solve the above problems by woven fiber support (2) on the outside of the lattice wick (Fig. 2) and then coating and applying the polymer resin (5) on the outer surface of the fiber support (2) By providing a hollow fiber separation membrane (FIG. 3) having a fine filtration fraction characteristics, the structural form of the hollow fiber separation membrane (FIG. 3) during the long time permeation of the filtrate by pressure and suction, as well as the hollow fiber of the present invention An internal flow path 6 capable of transporting a smooth filtrate into the separation membrane (FIG. 3) is provided, and the fiber support hollow fiber separation membrane (FIG. 3) including the lattice wick 1 is a lattice wick 1 And the fiber support (2) and the polymer resin (5) in the structure of the hollow fiber membrane (Fig. 3) characterized in that the tensile strength of 65,000 gf of the membrane separation and breakage due to the mixing of impurities such as underwater Problems such as deterioration and damage of the separator can be solved.

도1은 사각 격자 심지의 구성도이며,1 is a block diagram of a rectangular lattice wick,

도2는 격자형 심지 외부에 직조된 섬유지지체의 구성도이며,2 is a block diagram of a fiber support woven outside the lattice wick,

도3은 격자형 심지를 포함한 섬유지지체 중공사분리막의 개념도이며,3 is a conceptual diagram of a fiber support hollow fiber separation membrane including a lattice wick,

도4는 다각의 격자형 심지 단면도 이며,Figure 4 is a cross-sectional view of the grid wick of the polygon,

도5는 날개로 구성된 다각의 격자형 심지 단면도 이다.Fig. 5 is a cross-sectional view of a polygonal lattice wick composed of wings.

- 도면의 주요 부호의 설명-Description of the main symbols in the drawings

1. 격자형 심지 2. 성유지지체1. Lattice type wick 2. Oil support

3. 섬유지지체 두께 4. 공경3. Fiber support thickness 4. Pore

5. 고분자수지 6. 내부유로5. Polymer resin 6. Internal flow path

7. 다공성 공극 8. 중공사분리막 외경7. Porous Pore 8. Hollow Fiber Membrane Outer Diameter

9. 격자 10. 격자 모서리9. Grid 10. Grid edges

11. 날개11.wing

본 발명은 상기의 문제점을 해결하는 방안으로 격자형 심지(1)로 중공사분리막(도 3) 내부유로(6)를 일정하게 분할하고, 중공사분리막(도 3)이 여과액을 여과처리할 때 수축되어 중공사분리막(도 3)의 형태가 변형되는 것을 방지하며, 격자형 심지(1)는 외부에 섬유지지체(2)로 감싸져 있고(도 2) 그 섬유지지체(2) 외부 표면에 고분자수지(5)를 코팅 또는 도포하여 수중에서 경화되어 정밀여과 분획 특성을 갖는 격자형 심지(1)를 포함한 섬유지지체 중공사분리막(도 3)이다.According to the present invention, the hollow fiber membrane (FIG. 3) divides the internal flow path 6 into a grid-like wick 1 in a constant manner, and the hollow fiber membrane (FIG. 3) filters the filtrate. When contracted to prevent deformation of the hollow fiber membrane (Fig. 3), the lattice wick (1) is wrapped with a fiber support (2) on the outside (Fig. 2) and the fiber support (2) on the outer surface It is a fiber support hollow fiber membrane (FIG. 3) including a lattice wick (1) coated or coated with a polymer resin (5) and cured in water to have microfiltration fractionation characteristics.

격자형 심지(1)는 삼각격자에서 팔각격자(도 4)로 할 수 있으며, 그 격자 끝의 면은 날개(11)를 포함 할 수 있다. 하나의 격자(9)는 그 길이를 1∼10mm, 격자모서리(10)의 길이는 0.5∼5mm, 날개(11)의 길이는 1∼3mm로 구성될 수 있다. 또한 격자형 심지(1)는 폴리프로필렌, 폴리에틸렌 및 나일론 등으로 이루어질 수 있다.The lattice wick 1 may be an octagonal lattice (FIG. 4) in a triangular lattice, and the surface of the lattice end may include a wing 11. One grating 9 may have a length of 1 to 10 mm, a length of the grating edge 10 to 0.5 to 5 mm, and a length of the blade 11 to 1 to 3 mm. In addition, the lattice wick 1 may be made of polypropylene, polyethylene, nylon and the like.

격자형 심지의 외부표면에 감싸고 있는 섬유지지체(2)는 폴리에스테르, 폴리스틸렌, 폴리프로필렌, 나일론, 천연면 및 유리섬유로 구성되어진 실을 격자형 심지(1) 외부표면에 직조하게 되어(도 2) 일정한 공경(4)을 보유하게되며 0.1∼2mm의 두께(3)로 구성될 수 있다.The fiber support 2 wrapped on the outer surface of the lattice wick is woven on the outer surface of the lattice wick 1 of yarns composed of polyester, polystyrene, polypropylene, nylon, natural cotton and glass fiber (FIG. 2). It has a constant pore diameter (4) and may consist of a thickness (3) of 0.1 to 2 mm.

격자형 심지(1)를 포함한 섬유지지체(2) 외부 표면에 Polysulfone, Polyvinylchloride, Polyvinyldenefluoride, Polyethersulfone, Polyacrylonitrite 등의 고분자로 제조한 고분자 수지(5)를 제작 기구에 의하여 코팅 또는 도포하여 제작된 격자형 심지를 포함한 섬유지지체 중공사분리막(도 3)은 0.05∼1.0 ㎛ 의 정밀여과의 분획특성을 가진 다공성 공극(7)을 갖고 있다. 격자형 심지를 포함한 섬유지지체 중공사 분리막(도 3)은 1∼20mm의 외경(8)을 가진다.A lattice wick made by coating or applying a polymer resin (5) made of a polymer such as polysulfone, polyvinylchloride, polyvinyldenefluoride, polyethersulfone, and polyacrylonitrite on the outer surface of the fiber support including the lattice wick (1). The fiber support hollow fiber separation membrane (FIG. 3) including the porous support membrane 7 has a fractional characteristic of microfiltration of 0.05 to 1.0 µm. The fiber support hollow fiber separator (FIG. 3) including the lattice wick has an outer diameter 8 of 1 to 20 mm.

상기의 구성에 의하여 제조된 격자형 심지를 포함한 섬유지지체 중공사분리막(도 3)은 격자형 심지(1)와 섬유지지체(2) 및 고분자수지(5)의 3중 구조로 구성됨을 특징으로 하는 중공사분리막(도 3)으로, 분석에 따르면 그 인장강도가 65,000 gf이다.The fiber support hollow fiber separator (FIG. 3) including the lattice wick manufactured by the above configuration is characterized in that it consists of a triple structure of the lattice wick (1), the fiber support (2), and the polymer resin (5). Hollow fiber separator (Fig. 3), the analysis shows that the tensile strength is 65,000 gf.

이상의 구성 및 작용에 의하면 본 발명은 폴리프로필렌, 폴리에틸렌 및 나일론 등으로 이루어진 격자형 심지(1)와 폴리에스테르, 폴리스틸렌, 폴리프로필렌, 나일론, 천연면 및 유리섬유로 구성되어진 실을 격자형 심지(1) 의부표면에 직조(도 2)하게 되어 일정한 공경(4)을 보유하는 섬유지지체(2) 그리고 섬유지지체(2) 외부 표면에 Polysulfone, Polyvinylchloride, Polyvinyldenefluoride, Polyethersulfone, Polyacrylonitrite 등의 고분자로 제조한 고분자 수지(5)를 제작 기구에 의하여 코팅 또는 도포하여 제작된 격자형 심지를 포함한 섬유지지체 중공사분리막(도 3)은 격자형 심지(1)와 섬유지지체(2) 및 정밀여과 분획 특성을 갖는 고분자수지(5)의 3중 구조로 구성됨을 특징으로 하는 격자형 심지를 포함한 섬유지지체 중공사형분리막(도 3)으로 가압 및 흡입에 의한 여과액의 장시간 투과시 중공사분리막(도 3)의 구조적형태가 변형되지 않음은 물론, 본 발명의 중공사분리막(도 3) 내부로 원할한 여과액의 수송을 할 수 있는 내부유로(6)를 제공하며, 분석에 따르면 그 인장강도가 65,000 gf인 격자형 심지를 포함한 섬유지지체 중공사분리막(도 3)이다.According to the above configuration and operation, the present invention is a lattice wick (1) made of polypropylene, polyethylene, nylon, and the like, and a yarn composed of polyester, polystyrene, polypropylene, nylon, natural cotton and glass fiber (1). 2) Polymer resin made of a polymer such as polysulfone, polyvinylchloride, polyvinyldenefluoride, polyethersulfone, polyacrylonitrite, etc. on the outer surface of the fiber support (2) and the fiber support (2) having a constant pore diameter (4) (5) the fiber support hollow fiber separation membrane (FIG. 3) including a lattice wick produced by coating or coating by a fabrication apparatus is a lattice wick (1) and a fiber support (2) and a polymer resin having microfiltration fractionation characteristics. Long time of filtrate by pressurization and suction with fiber support hollow fiber membrane (FIG. 3) including lattice wick, characterized by consisting of triple structure of (5) In addition, the structural form of the hollow fiber separation membrane (FIG. 3) is not deformed during liver permeation, and provides an internal flow path 6 capable of transporting a filtrate into the hollow fiber separation membrane (FIG. 3) of the present invention. According to the analysis, the fiber support hollow fiber membranes (Fig. 3) including a lattice wick whose tensile strength is 65,000 gf.

Claims (8)

격자형 심지(1)와 섬유지지체(2) 및 정밀여과 분획 특성을 갖는 고분자수지(5)의 3중 구조로 구성됨을 특징으로 하는 격자형 심지를 포함한 섬유지지체 중공사형분리막(도 3).Fiber support hollow fiber membranes comprising a lattice wick (3) characterized in that it consists of a triple structure of the lattice wick (1) and the fiber support (2) and the polymer resin (5) having microfiltration fractionation characteristics. 제 1항에 있어서, 중공사분리막(도 3)의 인장강도가 65,000 gf인 격자형 심지를 포함한 섬유지지체 중공사형분리막(도 3).The fiber support hollow fiber separator according to claim 1, wherein the fiber support hollow fiber separator (FIG. 3) includes a lattice wick having a tensile strength of 65,000 gf. 제 1항에 있어 격자형 심지(1)는 폴리프로필렌, 폴리에틸렌 및 나일론 등으로 구성되며, 그 구조는 삼각격자에서 팔각격자(도 4)로 할 수 있는 격자형 심지(1).The lattice wick (1) according to claim 1, wherein the lattice wick (1) is composed of polypropylene, polyethylene, nylon, and the like, and its structure is a lattice wick (1) which can be made of a triangular lattice to an octagonal lattice (Fig. 4). 제 3항에 있어, 격자형 심지(1) 중 하나의 격자(9)는 그 길이를 1∼10mm, 격자 모서리(10)의 길이는 0.5∼5mm, 날개(11)의 길이는 1∼3mm로 구성될 수 있는 격자형 심지(1).4. The grating 9 of one of the grating wicks 1 has a length of 1 to 10 mm, a length of the grating edge 10 of 0.5 to 5 mm, and a length of the blade 11 of 1 to 3 mm. Lattice wick (1) that can be constructed. 제 1항에 있어, 섬유지지체(2)는 폴리에스테르, 폴리스틸렌, 폴리프로필렌, 나일론, 천연면 및 유리섬유로 구성되어진 실을 격자형 심지(1) 외부표면에 직조하게(도 2) 되어 일정한 공경(4)을 보유하는 섬유지지체(2).2. The fiber support (2) according to claim 1, wherein the fiber support (2) is made of polyester, polystyrene, polypropylene, nylon, natural cotton, and glass fiber to weave (FIG. 2) the outer surface of the lattice wick (1) to a constant pore diameter. A fiber support (2) having (4). 제 5항에 있어, 0.1∼2mm의 두께(3)로 구성될 수 있는 섬유지지체(2).6. The fiber support (2) according to claim 5, which can be composed of a thickness (3) of 0.1 to 2 mm. 제 1항에 있어, 격자형 심지(1)를 포함한 섬유지지체(2) 외부 표면에 Polysulfone, Polyvinylchloride, Polyvinyldenefluoride, Polyethersulfone, Polyacrylonitrite 등의 고분자로 제조한 고분자 수지(5)를 제작 기구에 의하여 코팅 또는 도포하여 제작된 격자형 심지를 포함한 섬유지지체 중공사분리막(도 3).The method according to claim 1, wherein a polymer resin (5) made of a polymer such as Polysulfone, Polyvinylchloride, Polyvinyldenefluoride, Polyethersulfone, Polyacrylonitrite, etc. is coated or coated on the outer surface of the fiber support (2) including the lattice wick (1). Fiber support hollow fiber separation membrane including a lattice wick produced by (Fig. 3). 제 7항에 있어, 1∼20mm의 외경(8)과 0.05∼1.0 ㎛의 다공성 공극(7)으로 정밀여과의 분획 특성을 갖는 격자형 심지를 포함한 섬유지지체 중공사분리막(도 3).The fiber support hollow fiber separator according to claim 7, comprising a lattice wick having a fractional characteristic of microfiltration with an outer diameter (8) of 1 to 20 mm and a porous pore (7) of 0.05 to 1.0 μm (FIG. 3).
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