KR20040041879A - Method of manufacturing a semiconductor device - Google Patents
Method of manufacturing a semiconductor device Download PDFInfo
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- KR20040041879A KR20040041879A KR1020020069978A KR20020069978A KR20040041879A KR 20040041879 A KR20040041879 A KR 20040041879A KR 1020020069978 A KR1020020069978 A KR 1020020069978A KR 20020069978 A KR20020069978 A KR 20020069978A KR 20040041879 A KR20040041879 A KR 20040041879A
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- Prior art keywords
- trench
- metal
- layer
- plating layer
- metal plating
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000010410 layer Substances 0.000 claims abstract description 68
- 229910052751 metal Inorganic materials 0.000 claims abstract description 61
- 239000002184 metal Substances 0.000 claims abstract description 61
- 238000007747 plating Methods 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 38
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052802 copper Inorganic materials 0.000 claims abstract description 22
- 239000010949 copper Substances 0.000 claims abstract description 22
- 239000011229 interlayer Substances 0.000 claims abstract description 11
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 6
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 6
- 239000010937 tungsten Substances 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000000059 patterning Methods 0.000 claims abstract description 4
- 230000004888 barrier function Effects 0.000 claims description 8
- 238000000151 deposition Methods 0.000 claims description 7
- 238000005530 etching Methods 0.000 claims description 5
- 238000009713 electroplating Methods 0.000 claims description 4
- 238000004544 sputter deposition Methods 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 238000007772 electroless plating Methods 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910019001 CoSi Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 description 1
- RVSGESPTHDDNTH-UHFFFAOYSA-N alumane;tantalum Chemical compound [AlH3].[Ta] RVSGESPTHDDNTH-UHFFFAOYSA-N 0.000 description 1
- MANYRMJQFFSZKJ-UHFFFAOYSA-N bis($l^{2}-silanylidene)tantalum Chemical compound [Si]=[Ta]=[Si] MANYRMJQFFSZKJ-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- HWEYZGSCHQNNEH-UHFFFAOYSA-N silicon tantalum Chemical compound [Si].[Ta] HWEYZGSCHQNNEH-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- -1 tungsten nitride Chemical class 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76877—Filling of holes, grooves or trenches, e.g. vias, with conductive material
- H01L21/76879—Filling of holes, grooves or trenches, e.g. vias, with conductive material by selective deposition of conductive material in the vias, e.g. selective C.V.D. on semiconductor material, plating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/32115—Planarisation
- H01L21/3212—Planarisation by chemical mechanical polishing [CMP]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/7684—Smoothing; Planarisation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76871—Layers specifically deposited to enhance or enable the nucleation of further layers, i.e. seed layers
- H01L21/76873—Layers specifically deposited to enhance or enable the nucleation of further layers, i.e. seed layers for electroplating
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
Abstract
Description
본 발명은 반도체 소자의 제조 방법에 관한 것으로, 특히 구리를 이용한 금속막 상부의 계면특성을 향상할 수 있는 반도체 소자의 제조 방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a semiconductor device, and more particularly, to a method for manufacturing a semiconductor device capable of improving the interfacial properties of an upper portion of a metal film using copper.
최근의 반도체 소자의 제조 공정에서 저항이 낮은 구리를 금속물질로 많이 사용하게 되었다. 구리를 이용한 금속막을 형성할 경우, 금속막 상부에 다른 금속의 자연 산화막에 비해 조직이 조밀하지 못한 구조의 자연 산화막(CuO)이 형성된다.In the recent semiconductor device manufacturing process, low resistance copper has been used as a metal material. When the metal film using copper is formed, a natural oxide film (CuO) having a structure in which the structure is not dense as compared with the natural oxide film of another metal is formed on the metal film.
조밀하지 못한 자연 산화막으로 인해, 자연 산화막 상에 절연막을 증착하면 자연 산화막과 절연막간의 접착이 잘되지 않게 되는 문제점이 발생한다. 이를 해결하기 위해 350 내지 400℃의 고온에서 NH3을 이용한 플라즈마 처리를 통해 산화막을 환원하여 제거하게 된다. 플라즈마 처리를 통한 자연 산화막 제거시에 구리 표면의 평탄화가 깨지는 결함(힐록(Hillock)이 발생)이 발생하여 후속 공정에서의 패턴 왜곡을 가져오는 문제점이 발생한다.Due to the dense natural oxide film, when the insulating film is deposited on the natural oxide film, a problem arises in that adhesion between the natural oxide film and the insulating film becomes poor. In order to solve this problem, the oxide film is reduced and removed by plasma treatment using NH 3 at a high temperature of 350 to 400 ° C. When the natural oxide film is removed through the plasma treatment, defects in which the planarization of the copper surface is broken (Hillock is generated) occur, which causes pattern distortion in subsequent processes.
따라서, 본 발명은 상기의 문제점을 해결하기 위하여 구리 금속막 상부에 스퍼터링 방법으로 얇은 금속층을 형성함으로서 절연막과의 접착 특성과 구리 표면의 결함발생을 방지할 수 있는 반도체 소자의 제조 방법을 제공하는데 그 목적이 있다.Accordingly, the present invention provides a method of manufacturing a semiconductor device that can prevent the occurrence of defects on the copper surface and the adhesive properties of the insulating film by forming a thin metal layer on the copper metal film by the sputtering method to solve the above problems. There is a purpose.
도 1a 내지 도 1d는 본 발명에 따른 반도체 소자의 제조 방법을 설명하기 위한 단면도들 이다.1A to 1D are cross-sectional views illustrating a method of manufacturing a semiconductor device in accordance with the present invention.
<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>
10 : 반도체 기판12 : 층간 절연막10 semiconductor substrate 12 interlayer insulating film
14 : 트렌치16 : 금속 장벽층14 trench 16: metal barrier layer
18 : 금속 도금층20 : 금속막18 metal plating layer 20 metal film
22 : 다이일렉트릭막22: electric film
본 발명에 따른 반도체 기판 상에 층간 절연막을 증착한 다음 패터닝 공정을실시하여 트렌치를 형성하는 단계와, 상기 트렌치 바닥으로 부터 상기 트렌치의 전체 깊이 보다는 낮게 매립되도록 금속도금층으로 매립하는 단계와, 상기 금속 도금층 상부에 금속막을 형성하여 상기 트렌치를 매립하는 단계 및 전체 구조 상부에 다이일렉트릭 막을 형성하는 단계를 포함하는 것을 특징으로 하는 반도체 소자의 제조 방법을 제공한다.Depositing an interlayer insulating film on a semiconductor substrate according to the present invention and then performing a patterning process to form a trench, and filling the metal plating layer so that the trench is buried below the entire depth of the trench from the bottom of the trench; A method of manufacturing a semiconductor device comprising forming a metal film on an upper portion of a plating layer to fill the trench, and forming a direct film on the entire structure.
이하, 첨부된 도면을 참조하여 본 발명의 실시예를 더욱 상세히 설명하기로 한다. 그러나 본 발명은 이하에서 개시되는 실시예에 한정되는 것이 아니라 서로 다른 다양한 형태로 구현될 것이며, 단지 본 실시예들은 본 발명의 개시가 완전하도록 하며, 통상의 지식을 가진 자에게 발명의 범주를 완전하게 알려주기 위해 제공되는 것이다. 도면상에서 동일 부호는 동일한 요소를 지칭한다.Hereinafter, with reference to the accompanying drawings will be described an embodiment of the present invention in more detail. However, the present invention is not limited to the embodiments disclosed below, but will be implemented in various forms, and only the embodiments are intended to complete the disclosure of the present invention, and to those skilled in the art to fully understand the scope of the invention. It is provided to inform you. Like numbers refer to like elements in the figures.
도 1a 내지 도 1d는 본 발명에 따른 반도체 소자의 제조 방법을 설명하기 위한 단면도들 이다.1A to 1D are cross-sectional views illustrating a method of manufacturing a semiconductor device in accordance with the present invention.
도 1a를 참조하면, 트랜지스터나 커패시터와 같은 반도체 소자(도시되지 않음)를 포함하여 여러 요소가 형성된 반도체 기판(10) 상에 층간 절연막(12)을 증착한 다음 패터닝 공정을 실시하여 트렌치(14)를 형성한다. 전체 구조 상부에 그 단차를 따라 금속 장벽층(16)과 시드층(미도시)을 증착한다. 금속 장벽층(16)은 탄탈륨(Ta), 탄탈륨질화막(TaN), 탄탈륨알루미늄질화막(TaAlN), 탄탈륨실리콘질화막(TaSiN), 탄탈륨실리사이드(TaSi2), 티타늄(Ti), 티타늄질화막(TiN), 티타늄실리콘질화막(TiSiN), 텅스텐질화막(WN), 코발트(Co) 및 코발트실리사이드(CoSi2) 중 적어도 어느 하나를 이용하여 형성한다. 금속 장벽층(16) 상의 전면에 도금을 위한 시드층을 구리를 이용하여 형성한다. 시드층은 구리뿐만 아니라 플래티늄(Platinum), 팔라듐(Palladium), 루비(Rubidium), 스토론튬(Strontium), 로듐(Rhodium) 및 코발트(Cobalt)등의 전이 금속을 이용하여 형성한다. 시드층의 형성 방법은 스퍼터링 등의 물리적 화학 기상증착(Physical Vapor Deposition; PVD)법 또는 화학적 기상증착(Chemical Vapor Deposition; CVD)법을 사용한다.Referring to FIG. 1A, an interlayer insulating film 12 is deposited on a semiconductor substrate 10 having various elements including a semiconductor device (not shown) such as a transistor or a capacitor, and then a patterning process is performed to form a trench 14. To form. A metal barrier layer 16 and seed layer (not shown) are deposited along the steps above the entire structure. The metal barrier layer 16 includes tantalum (Ta), tantalum nitride (TaN), tantalum aluminum nitride (TaAlN), tantalum silicon nitride (TaSiN), tantalum silicide (TaSi 2 ), titanium (Ti), titanium nitride (TiN), It is formed using at least one of a titanium silicon nitride film (TiSiN), a tungsten nitride film (WN), cobalt (Co) and cobalt silicide (CoSi 2 ). A seed layer for plating is formed on the entire surface of the metal barrier layer 16 using copper. The seed layer is formed using not only copper but also transition metals such as platinum, palladium, rubidium, strontium, rhodium, and cobalt. The seed layer is formed by a physical vapor deposition (PVD) method or a chemical vapor deposition (CVD) method such as sputtering.
도 1b를 참조하면, 도금공정을 실시하여 트렌치(14) 내부의 일부만을 금속 도금층(18)으로 매립한다. 도금 공정은 전해 도금법 및 무전해 도금법을 사용한다. 구리에 대한 전해 도금은 구리 이온이 포함된 전해용액내로 시드층이 형성된 기판을 넣은 후 이를 음극으로 하여 전압을 인가하면 구리 금속 도금층(18)이 형성된다. 한편 무전해 도금법은 팔라듐처리를 수행한 후 구리 이온을 포함한 도금액에 집어넣으면 구리 금속 도금층(18)이 형성된다. 구리를 이용한 도금공정시, 트랜지(14) 하부에서부터 상부까지 완전히 매립하였을 경우를 100%로 하였을 때, 트랜지(14) 하부로 부터 85 내지 95%만을 구리로 매립하여 금속 도금층(18)을 형성한다.Referring to FIG. 1B, only a part of the inside of the trench 14 is filled with the metal plating layer 18 by performing a plating process. The plating process uses an electrolytic plating method and an electroless plating method. In electrolytic plating of copper, a copper metal plating layer 18 is formed by applying a voltage by placing a substrate having a seed layer into an electrolytic solution containing copper ions and then using this as a cathode. On the other hand, in the electroless plating method, after the palladium treatment, the copper metal plating layer 18 is formed by placing it in a plating solution containing copper ions. In the plating process using copper, when the total filling from the lower part of the trench 14 to the upper part is 100%, only 85 to 95% of the lower part of the transistor 14 is embedded with copper to form the metal plating layer 18. Form.
상술한 바와 같이 트렌치(14) 내부의 85 내지 95%를 금속으로 매립하여 금속 도금층(18)을 형성하기 위해서는 도금 공정의 시간 즉, 전해 용액 또는 도금액 내에 침전되어 있는 기판의 시간을 조절하여 트렌치(14) 내부에 매립되는 구리의 높이를 제어하는 방법과, 시드층을 증착한 다음 식각공정을 실시하여 금속 장벽층(16) 상부의 시드층과 트렌치(14) 상부영역의 시드층을 제거하여 형성하는 방법과, 전체 구조 상부에 금속 도금층(18)을 형성한 다음 식각공정을 실시하여 트렌치(14) 상부영역에 형성된 금속 도금층(18)의 일부를 제거하는 방법을 사용한다.As described above, in order to form the metal plating layer 18 by filling 85 to 95% of the inside of the trench 14 with metal, the time of the plating process, that is, the time of the substrate deposited in the electrolytic solution or the plating liquid is controlled to adjust the trench ( 14) forming a seed layer by depositing a seed layer and then performing an etching process to remove the seed layer on the metal barrier layer 16 and the seed layer on the upper region of the trench 14 by depositing a seed layer. And the metal plating layer 18 is formed on the entire structure and then etched to remove a portion of the metal plating layer 18 formed in the upper region of the trench 14.
구체적으로, 시드층의 식각은 트렌치(14)의 측벽에 형성된 시드층을 100%로 하였을 경우 측벽 상부로부터 5 내지 15%의 시드층을 식각한다. 이로인해 도금공정을 실시하게 되면 시드층이 증착된 부분만 금속 도금층(18)이 형성된다.Specifically, when the seed layer is etched, when the seed layer formed on the sidewall of the trench 14 is 100%, 5 to 15% of the seed layer is etched from the top of the sidewall. As a result, when the plating process is performed, only the portion where the seed layer is deposited is formed with the metal plating layer 18.
한편 금속 도금층(18)의 제거 방법은, 상기 시드층을 식각하지 않고 도금 공정을 실시하여 전체 구조 상부에 금속 도금층(18)을 형성한다. 식각공정을 통해 금속 장벽층(16) 상부의 금속 도금층(18)을 제거하고, 과도식각을 실시하여 트렌치 상부영역의 금속 도금층(18)의 일부를 제거한다. 이때 트렌치 상부의 5 내지 15%의 금속 도금층(18)을 식각함으로서 트렌치 내부의 85 내지 95%를 금속 도금층(18)을 잔류시킨다.In the method of removing the metal plating layer 18, the metal plating layer 18 is formed on the entire structure by performing a plating process without etching the seed layer. The metal plating layer 18 on the metal barrier layer 16 is removed through an etching process, and a portion of the metal plating layer 18 in the upper region of the trench is removed by performing excessive etching. At this time, 5 to 15% of the metal plating layer 18 in the upper portion of the trench is etched to leave 85 to 95% of the metal plating layer 18 in the trench.
도 1c 및 1d를 참조하면, 전도성물질을 이용하여 트렌치(14) 내부를 완전히 매립함으로서 금속 도금층(18) 상부에 금속막(20)을 증착한다. 평탄화 공정을 실시하여 층간 절연막(12) 상부에 형성된 금속장벽층(16)과 금속막(20)을 제거하여 층간 절연막(12)을 노출시킨다. 전체 구조 상부에 다이일렉트릭(Dielectric)막(22)을 증착한다.1C and 1D, a metal film 20 is deposited on the metal plating layer 18 by completely filling the inside of the trench 14 using a conductive material. The planarization process is performed to remove the metal barrier layer 16 and the metal film 20 formed on the interlayer insulating film 12 to expose the interlayer insulating film 12. A dielectric film 22 is deposited over the entire structure.
금속막(20)은 알루미늄(Al), 탄탈륨(Ta) 및 텅스텐(W) 중 적어도 어느 하나를 상온 스퍼터링 등의 CVD방법 또는 PVD방법을 이용하여 형성한다. 이로써 트렌치 상부의 표면에 노출되는 분율은 금속막에 비해 매우 작게 된다. 구리로 구성된 금속 도금층 상에 알루미늄, 탄탈륨 및 텅스텐 중 적어도 어느 하나를 이용한 금속막을 형성하여 치밀한 자연 산화막을 형성할 수 있다. 또한, 구리에 의해 형성된 CuO를 제거하기 위한 트리트먼트(Treatment) 공정을 실시하지 않음으로써 공정의 단순화와 트리트먼트 공정에 의한 문제점들을 방지할 수 있다.The metal film 20 is formed of at least one of aluminum (Al), tantalum (Ta), and tungsten (W) using a CVD method such as normal temperature sputtering or a PVD method. As a result, the fraction exposed to the surface of the trench is very small compared to the metal film. A metal film using at least one of aluminum, tantalum and tungsten may be formed on the metal plating layer made of copper to form a dense natural oxide film. In addition, by not performing a treatment process for removing CuO formed by copper, it is possible to simplify the process and to prevent problems due to the treatment process.
상술한 바와 같이, 본 발명은 구리로 구성된 금속 도금층 상에 알루미늄, 탄탈륨 및 텅스텐 중 적어도 어느 하나를 이용한 금속막을 형성하여 치밀한 자연 산화막을 형성할 수 있다.As described above, the present invention can form a dense natural oxide film by forming a metal film using at least one of aluminum, tantalum and tungsten on the metal plating layer made of copper.
또한, 치밀한 자연 산화막으로 인해 구리로 구성된 금속 도금층과 다이익렉트릭막의 계면특성을 향상할 수 있다.In addition, due to the dense natural oxide film, it is possible to improve the interfacial properties of the metal plating layer made of copper and the multi- profit electric film.
또한, 구리에 의해 형성된 CuO를 제거하기 위한 트리트먼트 공정을 실시하지 않음으로써 공정의 단순화와 트리트먼트 공정에 의한 문제점들을 방지할 수 있다.In addition, by not performing a treatment process for removing CuO formed by copper, it is possible to simplify the process and prevent problems caused by the treatment process.
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