KR20040041122A - Soil fertilization agent manufacturing by slacking utilizing organic waste matter - Google Patents

Soil fertilization agent manufacturing by slacking utilizing organic waste matter Download PDF

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Publication number
KR20040041122A
KR20040041122A KR1020040027651A KR20040027651A KR20040041122A KR 20040041122 A KR20040041122 A KR 20040041122A KR 1020040027651 A KR1020040027651 A KR 1020040027651A KR 20040027651 A KR20040027651 A KR 20040027651A KR 20040041122 A KR20040041122 A KR 20040041122A
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reactor
slacking
high pressure
organic waste
soil conditioner
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KR1020040027651A
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Korean (ko)
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KR100604217B1 (en
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김재인
김창회
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김재인
김창회
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/02Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F7/00Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/20Sludge processing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

PURPOSE: A method for producing a soil conditioner is provided, by which organic wastes can be treated in a short period of time without generating bad smell, leachate, dust and air pollutant, thereby providing a composite soil conditioner containing slaked lime with high purity. CONSTITUTION: The method for producing a soil conditioner comprises: charging a high pressure and temperature reactor with a mixture of burnt lime and various organic wastes such as animal excrements, sludge from a purifying tank, sewage or wastewater treatment system, food leftovers, animal and plant residues and the like; stirring the mixture; and slacking the resulted mixture in the closed reactor under the condition of high pressure and temperature in a short period of time for stabilization.

Description

유기성 폐기물의 소화방법에 의한 토양개량재 제조방법 및 비료{Soil fertilization agent manufacturing by slacking utilizing organic waste matter}Soil fertilization agent manufacturing by slacking utilizing organic waste matter

고함수 유기성 폐기물의 기존에 처리공법은 퇴비화,염기성 소화,소각,건조,탄화,액비화 방법으로 처리하고 있으며 함수율이 높아 완전한 처리가 어렵다.Conventional treatment methods for high-functional organic wastes are treated by composting, basic extinguishing, incineration, drying, carbonization, and liquid quenching.

소각,건조,탄화처리 방법은 외부의 열원을 이용하여 처리 과정에서 많은 수분함량으로 인해 열효율이 저하되고 불완전한 연소로 대기 오염물질인 분진,수증기,악취와 다이옥신 등 유해물질이 발생하여 민원의 대상이 되고 있으며 처리시설비와 운영비가 많이 소요되는 문제점이 지적되고 있다.Incineration, drying, and carbonization methods use external heat sources to reduce the thermal efficiency due to the large amount of water in the process, and incomplete combustion causes harmful substances such as dust, water vapor, odors, and dioxin. It is pointed out that the processing cost and the operating cost are high.

퇴비화,염기성 소화,액비화,처리방법은 처리기간이 장기간이 소요되며 외부 온도에 따라 처리가 곤란하거나 처리기간중 악취,침출수,유해곤충의 발생,넓은 처리장 면적 등으로 2차 환경오염이 발생하는 문제점이 있다.Composting, basic extinguishing, liquefaction, and treatment methods take a long period of time and are difficult to process depending on the external temperature, or secondary environmental pollution occurs due to odors, leachate, harmful insects, and large plant area during treatment. There is this.

일부 고함수 유기성폐기물을 생석회와 교반하여 처리하는 장치가 있는데 생석회와 반응한 유기성 폐기물을 다른 보조재와 혼합하여 가열 건조시키는 과정을거쳐 토양개량재를 생산하는데 히터나 버너의 열을 직접 혼합조 내부로 공급하여 이 열풍에 의해 건조된 분말이 날려 다량의 분진이 배출되는 문제점이 있다. 또한 상기 버너에서 발생하는 미 연소분과 유해물질이 토양개량재와 혼합되어 품질이 저하되고 순도가 낮아지는 문제점이 지적되고 있다.There is a device that treats some high-function organic wastes by stirring with quicklime. The organic waste reacted with the quicklime is mixed with other auxiliary materials and heated and dried to produce soil modifiers. There is a problem that a large amount of dust is discharged by blowing the powder dried by the hot air supplied. In addition, it is pointed out that the unburned powder and harmful substances generated in the burner are mixed with the soil improving material to degrade the quality and lower the purity.

본 발명은 상기의 문제점을 해결하기 위한 겄으로서 고함수의 유기성 폐기물과 생석회를 혼합하여 고온도와 고압력에 견딜수 있는 반응조에 투입하고 교반하여 소화처리 하므로 악취,침출수,분진,대기 오염물딜이 발생하지 않고 유기성 폐기물을 단시간내 처리하여 최종 산물은 오염물질이 혼합되지 않고 순도가 높은 소석회 함유 복합토양개량재를 생산하는 기술을 특징으로 한다.In order to solve the above problems, the present invention mixes organic wastes and quicklime with high water content and puts them into a reaction tank that can withstand high temperature and high pressure, and then digests them by stirring to prevent odor, leachate, dust, and air pollution. By treating organic wastes in a short time, the final product is characterized by a technology that produces a high-purity lime-containing composite soil improver without mixing contaminants.

도 1. 은 본 발명의 공정도1 is a process diagram of the present invention

본 발명은 수분을 다량 함유하여 쉽게 부패되어 침출수와 악취를 내며 하천,지하수,오염과 병원균 전파등 처리가 곤란한 가축분뇨,정화조 오니, 음식물쓰레기,하수슬러지,폐수처리오니류,동식물성잔재물,피혁공장 폐기물(세이빙박)등 각종 유기성 폐기물을 생석회와 혼합하여 고압과 고온에 견딜수 있는 반응조에 투입하고 교반하면 2차 환경오염원이 발생하지 않고 밀폐된 반응조 내에서 고온과 고압력으로 신속히 소화((消和;slacking)처리 안정화하여 복합토양개량재를 제조하는 공법이다.The present invention contains a large amount of water, easily rotted and leachate and bad smell, difficult to treat streams, groundwater, pollution and pathogens, such as livestock manure, septic tank sludge, food waste, sewage sludge, wastewater treatment sludges, animal and plant residues, leather factories When various organic wastes such as waste (saving foil) are mixed with quicklime and put into a reaction tank capable of withstanding high pressure and high temperature and stirred, they are quickly extinguished at high temperature and high pressure in a sealed reactor without generating secondary environmental pollutants ((消 和; Slacking) Stabilization is a method of manufacturing composite soil improvement material by stabilizing.

반응조에 투입하는 유기성 폐기물의 함수율은 80~90%로 조절하며 함수율이 낮은 폐기물은 수분이 많은 축산폐수등 각종 산업폐수나 을을 보충하여 병합처리하며 반응조에 투입하여 교반할때 석회가 수분을 흡착하면서 급속한 발열로 150~200‘C로 유기물이 소화되며 반응조 내부의 압력이 3~4 kg/m2 고압 반응조에서 신속히 소화되며 안정화하여 배출한다.The water content of the organic wastes put into the reactor is controlled to 80 ~ 90%, and the waste water with low moisture content is mixed with various industrial waste waters such as livestock waste water with a lot of water. The organic material is digested to 150 ~ 200'C by rapid heat generation, and the pressure inside the reactor is rapidly extinguished and stabilized in the 3 ~ 4 kg / m2 high pressure reactor.

유기성폐기물의 수분과 생석회가 반응조내에서 교반 혼합하여 수산화 칼슘으로 변화되며 1kg당 15,2kcal의 열을 발생하며 유기물을 소화 수분을 증발시키며 유기성 폐기물에 함유되어 있는 병원성 세균,해충,잡초씨등 유해성 물질을 살멸하며 악취를 중화처리 물리 화학적으로 안정화 되며 반응식은 아래와 같다.Moisture and quicklime of organic waste are mixed with calcium hydroxide by stirring and mixing in the reaction tank, generating 15,2kcal of heat per kg, evaporating organic matter to evaporate moisture, and harmful hazards such as pathogenic bacteria, pests, and weed seeds contained in organic waste. It kills the substance and neutralizes the odor. It is stabilized physically and chemically.

CaO + H2O = Ca(OH)2 + 15,2kcal/kgCaO + H2O = Ca (OH) 2 + 15,2 kcal / kg

반응조에 부착된 온도계와 압력 게이지가 내부의 소화상태를 자동 측정하여 반응 안정화처리 기간중 내부의 온도 150~200“압력3~4kg/m2 범위로 자동 제어되며 과부하시에 배기구를 통하여배출되는수증기와염화암모니움 메탄개스를 배기구를 통하여응축기로빼내어 응축 액화 수집하므로 대기오염물질이 배출되지 않고 수집된 액체는 액체비료나 악취제거재로 사용한다, 본 발명을 제1 공정도에 의거 공정별로 좀더 상세히 설명하면 아래와 같다.Thermometer and pressure gauge attached to the reactor automatically measure the internal digestion status and automatically control the internal temperature within the range of 150 ~ 200 “pressure 3 ~ 4kg / m2 during the reaction stabilization process. Since ammonium chloride methane gas is extracted through a condenser to collect condensed liquid and thus air contaminants are not discharged, the collected liquid is used as a liquid fertilizer or odor removing material. Is as follows.

제 1 공정 ; 원료의 입고First process; Receipt of raw materials

유기성 폐기물을 탱크로리나 암롤차 카고차로 수거운반하여 폐기물창고나 탱크에 입고한다. 생석회는 벌크차량이나 톤빽으로 운반하여 생석회 보관탱크 또는 Silo 에 입고한다. 처리하고자 하는 유기성 폐기물의 함수율이 80% 이하 인 경우는 수분보충을 위한 폐수탱크나 보충수 탱크를 별도로 설치 보관한다.Organic wastes are collected in tank lorry or amrol car cargo car and put into the warehouse or tank. Quicklime is transported in bulk vehicles or tonnes of wheat and stored in quicklime storage tanks or silos. If the water content of organic waste to be treated is less than 80%, separate waste water tank or supplementary water tank for water replenishment.

제 2 공정 ; 혼합 반응조 투입Second process; Mixed reactor input

안정화 처리할 유기성 폐기물의 함수율은 80~90%로 혼합조절하여 반응조에 스크류컨베어 나 피이프 라인으로 투입하며 중량비 20~30%의 생석회를 자동계량하여 투입한다.The moisture content of the organic waste to be stabilized is 80 ~ 90%, and the mixture is controlled by the screw conveyor or pipe line.

제 3 공정 ; 교반 소화 안정화처리Third process; Stirring Digestion Stabilization

반응조에 원료투입이 완료된 후에 실린더에 의해 작동되는 해치로 투입구를 밀봉하고 반응조의 구동모터가 자동으로 작동되어 반응조 내부에 장착된 나선형의 양방향 교반날개를 회전시켜 원료가 고르게 교반 혼합되면서 급속한 발열로 150~200“C의 고온이 발생하고 수증기와 가스가 반응조 내부에 충만하게 되어 내부압력이 3~4kg/m2 로 반응조 외부에 부착된 온도계와 압력계에 반응 상태가 나타내면 반응조의 개폐 발브가 자동으로 열려 안전하게 가스와 수증기가 배출되어 운전이 자동화 된다.After the raw material is added to the reactor, the inlet is sealed with a hatch operated by the cylinder, and the driving motor of the reactor is automatically operated to rotate the spiral two-way stirring blades mounted inside the reactor, and the raw materials are evenly mixed and mixed. When the high temperature of ~ 200 “C is generated and water and gas are filled inside the reactor, the internal pressure is 3 ~ 4kg / m2 and the reaction state is indicated on the thermometer and pressure gauge attached to the outside of the reactor. Operation is automated by the release of gas and water vapor.

제 4 공정 ; 액화처리Fourth process; Liquefaction

반응조의 배기구개폐발브를 통하여 외부에 배출되는 가스와 수증기는 응축기로 액화처리 하여 액상비료나 악취 제거재로 출하 한다.Gas and water vapor discharged to the outside through the exhaust opening and closing valve of the reactor are liquefied by a condenser and shipped as liquid fertilizer or odor removing material.

제 5 공정 ;소화처리 물질의 배출 및 건조5th process; discharge and drying of digested material

반응조에 투입하여 20~30분간 소화처리한 물질은 반응조 하단에 설치한 반응조 배출구 도어가 열려 반응조 하부로 자체 온도 50~60“c 상태로 배출하게 되며 이를 건조 및 분쇄기에 투입하여 브로어로 건조하여 일정한 규격으로 분쇄가 된다.Substances digested for 20 to 30 minutes in the reactor are discharged at the bottom of the reactor with the temperature of 50 ~ 60 “c in the bottom of the reactor. It is ground to the standard.

제 6 공정 ; 첨가재 첨가 및 입상화 포장출하6th process; Additives added and granulated packing

건조 분쇄기에서 나온 토양개량재는 유기물등 첨가재와 혼합 선별후 포장하거나 펠렛으로 제조한후 포장하고 출하한다.Soil-improving material from the dry grinder is mixed and sorted with additives such as organic matter, then packed or manufactured into pellets, and then packed and shipped.

상기 공정에 의한 본 발명의 복합토양개량재에는 석회와 유기물과 비료삼요소 미량원소를 함유한 복합토양개량재가 생산되며 산성토양을 중성토양으로 개량하며 농작물의 영양흡수를 돕고 중금속 흡수를 억제하고 탄수화물의 이동을 촉진하여 뿌리 및 잎줄기를 튼튼하게 하여 병충해에 내성이 강해져 농약사용량이 줄어 맛좋은 농산물의 생산에 기여하고,토양미생물의 활동을 촉진하여 토양의 물리성을 개선하고 유기물의 분해 촉진으로 연작지 토양개량에 큰 효과가 있다.The composite soil improver of the present invention by the above process is produced a complex soil improver containing a trace element of lime and organic matter and fertilizer tri-element, improve acid soil to neutral soil, help to absorb nutrients of crops, inhibit heavy metal absorption and carbohydrates Promotes migration to strengthen roots and leaf stems, making them more resistant to pests, reducing the use of pesticides, contributing to the production of delicious agricultural products, promoting the activity of soil microorganisms, improving the physical properties of soils, and promoting degradation of organic matter. It has a big effect on improvement.

또한 양분의 유효도를 증진시켜 농작물의 뿌리 발육과 생육을 촉진하여 환경농업에 적합한 복합토양개량재가 되며 처리가 곤란한 고함수 유기성 폐기물을 안정화 처리 양질의 복합토양 개량재로 재활용하는 유효한 발명으로서 생산된 복합토양개량재 의 성분은 아래와 같다.In addition, it promotes the effectiveness of nutrients to promote the root development and growth of crops, making it a complex soil improver suitable for environmental farming.It is produced as an effective invention for recycling high-functional organic waste, which is difficult to treat, to stabilized high-quality complex soil improver. The components of the composite soil modifier are as follows.

복합토양개량재 분석 성적서Composite Soil Improvement Report

Claims (1)

가축분뇨,축산폐수,음식물쓰레기,하수슬러지,정화조오니류,침출수,동식물성잔재물,피혁공장 폐기물(세이빙박등) 각종 유기성 폐기물등 을 생석회와 혼합하여 고압 고온에 견딜수 있는 반응조에 투입 교반하고 2차 환경오염원이 발생시키지 않고 밀폐된 반응조 내에서 고온과 고압력으로 신속히 소화처리 안정화하여 복합토양개량 재나 복토재를 제조하는 방법.Livestock manure, livestock waste water, food waste, sewage sludge, septic tank sludge, leachate, animal and vegetable residues, leather factory waste (saving foil, etc.) mixed with organic lime and mixed with quicklime into a reactor that can withstand high pressure and high temperature. A method for producing complex soil reforming material or cover soil material by rapidly extinguishing and stabilizing at high temperature and high pressure in a sealed reactor without generating environmental pollution sources.
KR1020040027651A 2004-04-21 2004-04-21 A method for manufacturing soil fertilization agent by slacking organic waste matter KR100604217B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100740006B1 (en) * 2006-03-13 2007-07-16 조옥현 Disinfectnat for soil using sludge of purification plant
KR100788243B1 (en) * 2007-03-09 2007-12-27 (주)청림바이오 Manufacturing methods of organic fertilizer
KR102041825B1 (en) * 2018-12-31 2019-11-27 김덕환 Method of Manufacturing Organic and Inorganic Fertilizer Using Animal Carcass

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100731762B1 (en) 2007-02-16 2007-06-22 이을승 An organic fertilizer obtaining product from treatement of food waste and organic waste

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100740006B1 (en) * 2006-03-13 2007-07-16 조옥현 Disinfectnat for soil using sludge of purification plant
KR100788243B1 (en) * 2007-03-09 2007-12-27 (주)청림바이오 Manufacturing methods of organic fertilizer
KR102041825B1 (en) * 2018-12-31 2019-11-27 김덕환 Method of Manufacturing Organic and Inorganic Fertilizer Using Animal Carcass

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