KR20040033520A - Manufacture method of a fullgrain leather processing water repellent - Google Patents
Manufacture method of a fullgrain leather processing water repellent Download PDFInfo
- Publication number
- KR20040033520A KR20040033520A KR1020020062635A KR20020062635A KR20040033520A KR 20040033520 A KR20040033520 A KR 20040033520A KR 1020020062635 A KR1020020062635 A KR 1020020062635A KR 20020062635 A KR20020062635 A KR 20020062635A KR 20040033520 A KR20040033520 A KR 20040033520A
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- KR
- South Korea
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- water
- leather
- repellent
- dye
- water repellent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
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- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
Abstract
Description
본 발명은 발수가공 에프지 가죽지의 제조방법에 관한 것으로 염색은 패드다잉, 스크린 인쇄 또는 브러쉬, 도포 방법으로 가죽의 표면층 염색을 하되 그 염색잉크가 가죽의 표면층에 침투 고정되게 하여 염색층이 견고하면서도 유연성과 통기성이 양호하여 특히 구두(등산화, 군화, 전투화 등) 제조에 검정색 또는 얼룩무늬 단면염색된 에프지 가죽지를 제공하는데 목적이 있다.The present invention relates to a method of manufacturing water-repellent fuji leather paper, the dyeing is dyed the surface layer of the leather by padding, screen printing or brush, application method, but the dyeing ink penetrates and fixed to the surface layer of the leather Good flexibility and breathability, the purpose is to provide a black or speckled cross section dyed fuji leather paper, especially in the manufacture of shoes (shoes, boots, combat boots, etc.).
일반적으로, 가죽은 발수가공 처리를 하게 되면 수명이 연장되고, 신발일 때 장시간 착화시 발의 안전은 물론 땀이 배이지 않고 착화감이 우수하다.In general, when the leather is subjected to a water-repellent treatment, the life is extended, and when the shoes are worn for a long time, the safety of the feet as well as the sweat is excellent and the wear feeling is excellent.
한편, 구두에 사용되는 가죽지는 물과 접촉시(비를 맞거나 수중에 잠겼을 때) 착색된 염료가 씻겨 나와 발을 오염시키거나, 탈색 또는 통기성이 없는 관계로 침적방법으로 전체가 염색된 가죽지 보다는 표면만을 염색한 단면 염색 가죽지의 선호도가 높은 실정이다.On the other hand, leather paper used for shoes is leather paper that has been dyed by the deposition method due to staining of colored dyes when it comes in contact with water (when rained or immersed in water) and contaminates the feet or is not discolored or breathable. Rather, it is a high preference of single-sided dyed leather paper dyed only the surface.
이와 같은 종래 단면 염색 가죽지의 제조과정을 보면 인달카(Indalka)를 주재로 한 염색잉크를 가죽표면에 스크린인쇄 하는 경우가 있었다.In the manufacturing process of the conventional single-sided dyed leather paper, there were cases in which a dyed ink based on Indalka was screen printed on the leather surface.
인달카가 함유되어 있는 종래의 염색잉크는 인달카에 함유되어 있는 고무성분에 의해 잉크가 가죽표층에 침투되지 못하고 도착되어 두터운 잉크층으로 존재하기 때문에 가죽의 유연성과 통기성이 떨어져 구두를 지어 착용시 비위생적이고, 염색잉크와 가죽표면과의 결합상태가 견고하지 못하여 착용시 외부마찰에 의해 염색 인쇄층이 마손되어 퇴색하거나 이탈되어 염색인쇄층이 훼손되는 등의 문제점이 있었다.The conventional dyed ink containing indalka does not penetrate the leather surface due to the rubber component contained in the indcar, and it exists as a thick ink layer. Therefore, the softness and breathability of the leather are poor. In addition, there is a problem that the dyeing layer and the leather surface are not firmly bonded and the dyeing layer is damaged by fading or leaving due to external friction when worn.
본 발명에서는 이상과 같은 종래의 문제점을 해결하기 위하여, 고무성분이 없는 알긴산소다 풀을 주재로한 염색잉크를 사용한 결과 가죽표층에 염색잉크가 잘 침투, 고정되어 염색층이 견고하고 색상이 선명하며 유연성 및 통기성이 우수하여 구두(군화, 등산화, 전투화 등)에 사용하기 적합한 단면염색 발수가공 얼룩무늬 에프지 가죽지를 제조하게 된 것이다.In the present invention, in order to solve the conventional problems as described above, as a result of using a dyeing ink based on soda alginate paste without rubber components, the dyeing ink penetrates well into the leather surface layer, and the dyeing layer is firm and the color is clear. Its excellent flexibility and breathability make it suitable for use in shoes (military shoes, hiking boots, combat shoes, etc.).
본 발명을 상세히 설명하면 다음과 같다.The present invention is described in detail as follows.
가죽지의 표면에 패드다잉, 스크린 인쇄 또는 브러쉬 도포 방법으로 염색잉크를 염색하여 단면염색 가죽지를 제조함에 있어서, 상기 염색잉크는 알긴산소다 풀(Sodium Alginate Thickener)에 산성 염료를 색상의 농도에 따라 혼합한 액에 개미산(Formic Acid)과 가소제(Balance)를 혼합하여 염색잉크를 조성하되, 이에 염료를 분산시켜 색상이 균등하게 하는 분산제 솔벤트(Solvent)와 염료를 가죽표층에 침투시키는 침투제 오레인산(Oleic Acid) 및 염료가 표층에 침투된 것을 고착시키기 위한 고착제로 암모니아수(Agueous Ammonia)를 혼합하여 염색잉크(Dyeing paste)를 조성하여 이를 염색한다.In the manufacture of single-side dyeing leather paper by dyeing the dyeing ink by padding, screen printing or brush coating on the surface of the leather paper, the dyeing ink is mixed with an acid dye in sodium alginate thickener according to the color concentration. Forming ink by mixing formic acid and plasticizer in liquid, dispersant Solvent and disperse dye to evenly disperse dye, and penetrant Oleic acid penetrating dye into leather surface ) And dyeing dye by mixing ammonia water (Agueous Ammonia) as a fixing agent for fixing that the dye penetrates the surface layer and dyes it.
염색후에는 자연건조시켜 약 94도의 스팀으로 약 60분간 숙 처리한 후 수세, 건조한 다음 그 표면에 발수가공처로 불소수지(Fluoro Carbon Resin)와 메틸렌 크로라이드(Methylen Chloride)로 조제된 특수 발수제를 도포하여 단면염색 가죽지를 완성한다.After dyeing, it is dried naturally and treated for about 60 minutes with steam at 94 degrees, washed with water, dried, and then applied with a special water repellent prepared by Fluoro Carbon Resin and Methylene Chloride on the surface. To finish single-sided dyed leather paper.
본 발명 실시에 있어서, 유광처리를 할 때에는 바인더(Binder), 암모니아, 실리콘을 혼합하여 조제된 유광제로 1차 코팅하고, 2차 일반 가죽용 광택제를 코팅한다.In the practice of the present invention, when performing a gloss treatment, a binder, ammonia, and silicon are mixed firstly with a gloss prepared by mixing, and a secondary general leather varnish is coated.
이하, 본 발명 실시예는 다음과 같다.Hereinafter, the present invention is as follows.
{실시예}{Example}
알긴산소다 풀(Sodium Alginate Thickener) 500 중량%Sodium Alginate Thickener 500% by weight
솔벤트(Solvent) 50 중량%Solvent 50% by weight
오레인산(Oleic Acid) 50 중량%50% by weight of oleic acid
개미산(Formic Acid:의산) 50 중량%50% by weight of formic acid
암모니아수(Agueous Ammonia) 60 중량%Agueous Ammonia 60% by weight
검정색 산성염료(Dye) 12 중량%12% by weight of black acid dye (Dye)
빙소산(Acetic Acid) 7 중량%7% by weight of acetic acid
상기와 같이 조성된 염색잉크를 가죽지 표면에 스크린 인쇄 방법으로 염색하여 자연 건조시킨 후 94도의 스팀으로 60분간 숙 처리하였다. 상기 숙 처리된 염색 가죽지를 수세, 건조한 다음 불소수지와 메칠렌 크로라이드로 조제된 발수가공처리 발수제로 발수처리하여 검정색 단면염색 또는 얼룩무늬 에프지(FG;Full Grain)가죽지를 만들었다.The dyeing ink prepared as described above was dyed by screen printing on the surface of the leather paper and dried naturally, and then aged for 60 minutes with steam at 94 degrees. The aged dyed leather paper was washed with water, dried, and then water-repelled with a water-repellent water-repellent agent prepared with fluorine resin and methylene chromide to produce black single-sided dye or stained FG (Full Grain) leather.
상기와 같이 제조된 단면염색 발수가공 에프지 가죽지는 용도에 따라 바인더, 암모니아, 실리콘으로 혼합조제된 유광제를 1차 코팅하고, 일반 광택제를 2차 코팅하여 사용하게 된다.The cross-sectional dyed water-repellent f-fur leather paper prepared as described above is coated with a binder, ammonia, and silicone, mixed with a first gloss agent, and a second general coating agent is used.
본 발명 방법에 의하여 제조되는 단면염색 발수가공 에프지 가죽지는 고무성분이 없는 알긴산소다 풀과 분산제 솔벤트, 침투제 오레인산 및 고착제 암모니아로 조성된 염색잉크를 사용하므로서 가죽표층에 염색잉크가 잘 침투 고정되어 염색층이 견고하고 색상이 선명하며 유연성 및 통기성이 우수하여 구두(군화, 등산화, 전투화 등)에 사용하기 적합한 효과가 있고, 구두를 지어 착용시에는 통풍성에 의해 땀이 차거나 악취가 축적되지 않아 위생적으로 착용할 수 있는 효과가 있다.The cross-sectional dyed water-repellent processed FRP leather produced by the method of the present invention is well penetrated and fixed to the leather surface by using a dye-free ink composed of a rubber-free sodium alginate paste, a dispersant solvent, a penetrant ore acid, and ammonia fixing agent. The dyeing layer is solid, the color is clear, and the flexibility and breathability are excellent for use in shoes (military shoes, hiking boots, combat shoes, etc.), and when wearing shoes, it is hygienic because of sweating or odor accumulation due to ventilation. Can be worn as an effect.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100975111B1 (en) * | 2010-04-28 | 2010-08-11 | 김경규 | Acidic printing method for fur |
KR101235621B1 (en) * | 2011-05-03 | 2013-02-21 | 한국신발피혁연구소 | Method for producing eco-leather packing and eco-leather packing produced thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR910012452A (en) * | 1989-12-07 | 1991-08-07 | 김재두 | Printing method of leather |
JPH06306775A (en) * | 1991-02-23 | 1994-11-01 | Cassella Ag | Method for dyeing leather with water- insoluble sulfur dye |
KR20040011650A (en) * | 2002-07-27 | 2004-02-11 | 김재두 | manufacture method of a section dyeing leather |
-
2002
- 2002-10-15 KR KR1020020062635A patent/KR20040033520A/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR910012452A (en) * | 1989-12-07 | 1991-08-07 | 김재두 | Printing method of leather |
JPH06306775A (en) * | 1991-02-23 | 1994-11-01 | Cassella Ag | Method for dyeing leather with water- insoluble sulfur dye |
KR20040011650A (en) * | 2002-07-27 | 2004-02-11 | 김재두 | manufacture method of a section dyeing leather |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100975111B1 (en) * | 2010-04-28 | 2010-08-11 | 김경규 | Acidic printing method for fur |
KR101235621B1 (en) * | 2011-05-03 | 2013-02-21 | 한국신발피혁연구소 | Method for producing eco-leather packing and eco-leather packing produced thereof |
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