KR20040017170A - Luminescent compound for the tire side - Google Patents
Luminescent compound for the tire side Download PDFInfo
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- KR20040017170A KR20040017170A KR1020020049311A KR20020049311A KR20040017170A KR 20040017170 A KR20040017170 A KR 20040017170A KR 1020020049311 A KR1020020049311 A KR 1020020049311A KR 20020049311 A KR20020049311 A KR 20020049311A KR 20040017170 A KR20040017170 A KR 20040017170A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C13/00—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof
- B60C13/001—Decorating, marking or the like
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/16—Solid spheres
- C08K7/18—Solid spheres inorganic
- C08K7/20—Glass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/56—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing sulfur
- C09K11/562—Chalcogenides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/64—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing aluminium
- C09K11/641—Chalcogenides
- C09K11/643—Chalcogenides with alkaline earth metals
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- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
본 발명은 타이어의 사이드부용 발광 조성물에 관한 것으로서, 보다 상세하게는 축광물질과 형광물질 및 글래스비드를 포함하는 타이어의 사이드부용 조성물을 제공함으로서 이 조성물을 이용하여 제조된 타이어의 경우 어두운 곳에서 형광물질 및 축광물질에 의한 야광효과와 글래스비드에 의한 재귀반사 효과를 얻을 수 있어 차량위치의 식별력을 극대화시켜 교통 안전사고를 미연에 방지할 수 있을 뿐만 아니라 활동적이고 스포틱한 분위기의 타이어를 원하는 소비자들의 욕구를 충족시킬 수 있는 타이어의 사이드부용 발광 조성물에 관한 것이다.The present invention relates to a light emitting composition for a side portion of a tire, and more particularly, to provide a composition for a side portion of a tire including a phosphorescent material, a fluorescent material, and glass beads to fluoresce in a dark place for a tire manufactured using the composition. The luminous effect of the material and the phosphorescent material and the retroreflective effect of the glass bead can be obtained to maximize the discrimination of the vehicle's location and prevent traffic safety accidents, as well as those who want an active and sporty atmosphere. The present invention relates to a light emitting composition for a side portion of a tire that can satisfy a desire.
근래에 들어 타이어 산업이 급속히 발전하고, 타이어에 적용되는 소재가 다양화됨에 따라 소비자들의 요구 또한 점차 복잡하고 다양화되어가고 있다. 특히, 타이어에 대한 기본 요구성능인 안전성 측면이외에 쾌적한 안락성과, 연비성능, 마모성능 등의 타이어 성능향상을 함께 요구하고 있다.In recent years, with the rapid development of the tire industry and the diversification of materials applied to tires, the demands of consumers are becoming more complex and diversified. In particular, in addition to the safety aspects, which are the basic performance requirements for tires, the tires are also required to improve tire performances such as comfortable comfort, fuel efficiency, and abrasion performance.
이외에도 소비자들은 우수한 성능과 함께 시각적 효과가 높은 타이어를 원하고 있으며, 그에 따라 타이어 개발회사에서는 새로운 패턴을 가지면서 다양한 칼라가 도입된 패션화된 타이어의 개발을 시도하면서 소비자의 성향과 욕구 충족에 심혈을 기울이고 있다.In addition, consumers want tires with excellent performance and high visual effects. Accordingly, tire development companies are trying to develop fashioned tires with various colors and introducing various colors. I'm leaning.
소비자들도 타이어의 사이드부를 포함한 여러 부위에 시각적인 효과와 장식적인 효과를 높이기 위하여 다양한 칼라와 문양이 형성된 스티커를 부착하여 사용하고 있다.Consumers are also using stickers with various colors and patterns to enhance the visual and decorative effects on various parts of the tire's side.
그러나 이와 같이 시각효과를 높이기 위해 타이어에 응용되고 있는 종래의 방법들(스티커 부착 등)은 빛이 있는 곳에서만 식별이 가능하다는 한계를 가지고 있으며, 어두운 곳에서는 식별력이 떨어져 시각적 효과를 얻을 수 없을 뿐만 아니라 활동적이고 스포틱한 분위기의 타이어를 원하는 소비자들의 욕구를 충족시키지 못하고 있다는 단점이 있다.However, the conventional methods (such as sticking stickers) applied to tires to enhance the visual effect have a limitation that they can be identified only in the light, and in the dark, the visual power can not be obtained due to the lack of discrimination. However, there is a disadvantage that it does not meet the needs of consumers who want tires with an active and sporty atmosphere.
이에 본 발명은 어두운 곳에서도 형광물질 및 축광물질에 의한 야광효과와 글래스비드에 의한 재귀반사 효과를 통해 차량위치의 식별력을 극대화시켜 교통 안전사고를 미연에 방지할 수 있을 뿐만 아니라 활동적이고 스포틱한 분위기의 타이어를 원하는 소비자들의 욕구를 충족시킬 수 있는 타이어의 사이드부용 발광 조성물을 제공하는데 그 목적이 있다.Therefore, the present invention maximizes the identification power of the vehicle location through the luminous effect by the fluorescent material and the photoluminescent material and the retroreflective effect by the glass bead in the dark to prevent traffic safety accidents in advance, as well as active and sporty atmosphere It is an object of the present invention to provide a light emitting composition for the side portion of a tire that can satisfy the desires of consumers who want a tire.
또한 본 발명은 상기 발광 조성물을 타이어 제조시 사이드부에 적용하여 제조된 발광 타이어를 제공하는데 다른 목적이 있다.In another aspect, the present invention is to provide a light emitting tire manufactured by applying the light emitting composition to the side portion when manufacturing the tire.
상기한 목적을 달성하기 위하여 본 발명은The present invention to achieve the above object
고무수지와 클레이, 촉진제, 가황제, 오일을 포함하는 타이어용 사이드부 조성물에 있어서,In the side part composition for tires containing a rubber resin, clay, accelerator, vulcanizing agent, oil,
상기 고무수지 100중량부에 대하여 축광안료 10 내지 30중량부와 형광안료 10 내지 20중량부 및 글래스비드(glass bead) 5 내지 20중량부 더 포함하는 것을 특징으로 하는 타이어의 사이드부용 발광 조성물을 제공한다.It provides a light emitting composition for the side portion of the tire, characterized in that it further comprises 10 to 30 parts by weight of the phosphorescent pigment, 10 to 20 parts by weight of the fluorescent pigment and 5 to 20 parts by weight of glass beads (glass bead) based on 100 parts by weight of the rubber resin. do.
또한 본 발명은 상기 발광 조성물을 타이어 제조시 사이드부에 적용하여 제조된 것임을 특징으로 하는 발광 타이어를 제공한다.In another aspect, the present invention provides a light emitting tire, characterized in that the light emitting composition is produced by applying to the side portion when manufacturing the tire.
이와 같이 축광안료와 형광안료 및 글래스비드를 포함하는 타이어용 사이드부 발광 조성물을 이용하여 제조된 타이어의 경우 타이어의 사이드부가 어두운 곳에서도 형광 및 축광효과를 나타냄과 동시에 재귀반사효과를 나타내게 되며, 따라서 차량위치의 식별력 증대에 따른 교통 안전사고를 미연에 방지할 수 있을 뿐만 아니라 스폭틱한 분위기의 타이어를 원하는 소비자들의 욕구를 충족시킬 수 있게 된다.As described above, in the case of a tire manufactured using a side light emitting composition for a tire including a phosphorescent pigment, a fluorescent pigment, and glass beads, the tire has a fluorescence and a photoluminescent effect in a dark place, and a retroreflective effect. In addition to preventing traffic safety accidents caused by the increased identification of vehicle positions, it is possible to meet the desires of consumers who want tires with a spastic atmosphere.
이하 본 발명을 보다 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail.
본 발명은 통상의 타이어용 사이드부 조성물에 축광안료와 형광안료 및 글래스비드가 더 포함되도록 한 것에 그 특징이 있는 것이다.The present invention is characterized in that the phosphorescent pigments, fluorescent pigments and glass beads are further included in the side composition for a tire.
통상적으로 사용되는 타이어용 사이드부 조성물은 주로 고무수지와 클레이, 촉진제, 가황제 및 오일로 구성된다. 이때, 고무수지는 천연고무와 합성고무(에틸렌 프로필렌 디엔 모노머(EPDM)과 부틸고무)로 이루어지며, 대부분의 고무수지는 천연고무 35 내지 45중량%와 합성고무 55 내지 65중량%로 이루어진다.Commonly used side composition for tires mainly consists of rubber resin and clay, accelerator, vulcanizing agent and oil. At this time, the rubber resin is made of natural rubber and synthetic rubber (ethylene propylene diene monomer (EPDM) and butyl rubber), most of the rubber resin is made of 35 to 45% by weight of natural rubber and 55 to 65% by weight of synthetic rubber.
상기와 같은 통상의 타이어용 사이드부 조성물에 축광안료와 형광안료 및 글래스비드를 더 첨가하게 되는데, 축광안료는 고무수지 100중량부에 대하여 10 내지 30중량부, 형광안료는 10 내지 20중량부, 글래스비드는 5 내지 20중량부 첨가하게 된다.To the conventional side-side composition for tires, a phosphorescent pigment, a fluorescent pigment and glass beads are further added. The phosphorescent pigment is 10 to 30 parts by weight based on 100 parts by weight of a rubber resin, and a fluorescent pigment is 10 to 20 parts by weight, Glass beads will be added 5 to 20 parts by weight.
이때, 상기 축광안료는 고무수지 100중량부에 대하여 10중량부 미만일 경우 충분한 축광효과를 얻을 수 없으며, 30중량부를 초과할 경우 과도한 축광안료의 함유로 인하여 타이어의 사이드부 물성변화를 초래할 수 있으므로 상기 범위내에서 축광안료를 사용하는 것이 좋다.In this case, the photoluminescent pigment may not obtain sufficient photoluminescent effect when less than 10 parts by weight based on 100 parts by weight of the rubber resin, and when it exceeds 30 parts by weight, it may cause a change in physical properties of the side part of the tire due to the inclusion of excessive photoluminescent pigment. It is better to use photoluminescent pigments within the range.
또한 상기 축광안료는 80 내지 130메쉬의 입경을 갖는 것을 사용하는데, 상기 축광안료의 입경이 80메쉬 미만일 경우 다른 재료와의 분산성이 하락하고, 130메쉬를 초과할 경우 입자가 너무작아 축광효과가 하락되는 단점이 있으므로 상기 범위내의 입경을 갖는 축광안료를 사용하는 것이 바람직하다.In addition, the phosphorescent pigment is used to have a particle size of 80 to 130 mesh, when the particle diameter of the phosphorescent pigment is less than 80 mesh dispersibility with other materials, and when exceeding 130 mesh, the particle is too small, so the photoluminescent effect is It is preferable to use a photoluminescent pigment having a particle size within the above range because there is a disadvantage that it falls.
본 발명에서 사용된 축광안료는 주성분인 클레이(SiO2, Al2O3)와 SrO3, Zr, Fe 등의 무기물로 구성되는 통상의 ZnS계 또는 AlSr계로서, 그 표면을 염료, Cu 또는 Eu 등으로 처리한 것을 사하였다. 상기 축광안료의 여기피크 파장은 200 내지 450nm이고, 방출피크 파장은 470 내지 510nm이며, 색상은 노란색, 녹색, 연녹색, 청색, 분홍색, 붉은 색상을 나타내는 것에서 선택하여 사용할 수 있다.The photoluminescent pigment used in the present invention is a conventional ZnS-based or AlSr-based composition composed of main components clay (SiO 2 , Al 2 O 3 ) and inorganic materials such as SrO 3 , Zr, Fe, and the surface thereof is dye, Cu or Eu. And the like was used. The excitation peak wavelength of the photoluminescent pigment is 200 to 450 nm, the emission peak wavelength is 470 to 510 nm, the color may be selected from yellow, green, light green, blue, pink, red color.
또, 형광안료는 고무수지 100중량부에 대하여 10중량부 미만일 경우 충분한 형광효과를 얻을 수 없으며, 20중량부를 초과할 경우 과도한 형광안료의 함유로 인하여 타이어의 사이드부 물성변화를 초래할 수 있으므로 상기 범위내에서 형광안료를 사용하는 것이 좋다.In addition, the fluorescent pigment can not obtain a sufficient fluorescence effect when less than 10 parts by weight relative to 100 parts by weight of rubber resin, and if it exceeds 20 parts by weight it may cause a change in the physical properties of the side part of the tire due to the inclusion of excessive fluorescent pigments It is recommended to use fluorescent pigments in the interior.
상기 형광안료는 270 내지 380메쉬의 입자크기를 갖는 것을 사용하는데, 형광안료로 270메쉬 미만의 것을 사용할 경우 다른 물질과의 분산성이 하락하는 단점이 있으며, 형광안료로 380메쉬를 초과한 것을 사용할 경우 입자가 너무 작아 형광효과가 저하되는 단점이 있다. 따라서 상기 범위 내의 입자크기를 갖는 형광안료를 사용하는 것이 바람직하다.The fluorescent pigments are those having a particle size of 270 to 380 mesh, the use of less than 270 mesh as a fluorescent pigment has a disadvantage in that the dispersibility with other materials is deteriorated, and those that exceed 380 mesh as a fluorescent pigment If the particles are too small there is a disadvantage that the fluorescent effect is lowered. Therefore, it is preferable to use a fluorescent pigment having a particle size within the above range.
본 발명에서 사용된 형광안료는 일반적으로 시판중인 아민과 알데히드를 축합 반응시켜 제조한 열 경화성 수지에 염료를 투입하여 형성된 안료를 분말화시킨 것을 사용하였으며, 안료의 색상은 노란색, 녹색, 분홍색, 청색을 나타내는 것에서 선택하여 사용할 수 있다.Fluorescent pigments used in the present invention were generally powdered pigments formed by adding dyes to a thermosetting resin prepared by condensation reaction of commercially available amines and aldehydes, and the colors of the pigments were yellow, green, pink, and blue. It can be used by selecting from.
또, 글래스비드는 고무수지 100중량부에 대하여 5중량부 미만일 경우 충분한 재귀반사 효과를 얻을 수 없으며, 20중량부를 초과할 경우 과도한 글래스비드의 함유로 인하여 타이어의 사이드부 물성변화를 초래할 수 있으므로 상기 범위내에서 글래스비드를 사용하는 것이 좋다. 상기 글래스비드는 통상적으로 사용되는 것으로서 조성물내에서의 균질한 혼합을 위하여 200메쉬 이상, 더욱 바람직하게는 200 내지 250메쉬의 입경을 갖는 것을 사용하는 것이 좋다.In addition, if the glass bead is less than 5 parts by weight relative to 100 parts by weight of the rubber resin can not obtain a sufficient retroreflective effect, if it exceeds 20 parts by weight it may cause a change in the physical properties of the side of the tire due to the excessive glass bead content It is recommended to use glass beads within the range. The glass beads are commonly used, and it is preferable to use those having a particle size of 200 mesh or more, more preferably 200 to 250 mesh for homogeneous mixing in the composition.
상기한 바와 같이 본 발명은 통상의 타이어용 사이드부 조성물에 축광안료와 형광안료 및 글래스비드를 더 투입하여 얻어지는 발광 조성물을 제공하는데, 이 발광 조성물을 타이어 제조시 사이드부에 적용하여 제조된 타이어의 경우 사이드부가 어두운 곳에서도 형광 및 축광효과와 함께 재귀반사 효과를 나타내게 되므로 차량위치의 식별력이 증대되고, 그에 따른 교통 안전사고를 미연에 방지할 수 있을 뿐만 아니라 활동적이고 스포틱한 분위기의 타이어를 원하는 소비자들의 욕구를 충족시킬 수 있게 된다.As described above, the present invention provides a light emitting composition obtained by further adding photoluminescent pigments, fluorescent pigments, and glass beads to a conventional side portion composition for a tire. In this case, the side part shows the fluorescence and the photoluminescent effect together with the retroreflective effect, so that the identification of the vehicle location is increased, and thus the traffic safety accident can be prevented in advance, and consumers who want an active and sporty atmosphere tire It will be able to meet their needs.
특히, 본 발명은 기존 사이드부 조성물에 축광안료와, 형광 안료 및 글래스비드를 혼합하되 물성의 하락 없이 타이어의 제조가 가능하며, 빛이 없는 곳에서 5시간 이상 육안으로 발광을 감지할 수 있게 되어 야간의 식별력이 증대된 타이어의 제조가 가능하게 된다.In particular, the present invention is to mix the phosphorescent pigment, fluorescent pigments and glass beads in the existing side composition, but it is possible to manufacture the tire without deterioration of physical properties, it is possible to detect the light emission with the naked eye for more than 5 hours in the absence of light. It is possible to manufacture tires with improved nighttime discrimination.
이하 본 발명을 하기한 실시예를 통하여 보다 상세하게 설명하기로 하나, 이는 본 발명의 이해를 돕기 위하여 제시된 것일 뿐, 본 발명이 이에 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to the following examples, which are only presented to aid the understanding of the present invention, but the present invention is not limited thereto.
<실시예 1 내지 7 및 비교예 1><Examples 1 to 7 and Comparative Example 1>
하기 표 1의 조성을 갖는 타이어용 사이드부 조성물을 통상의 타이어 제조순서에 따라 압출과 성형을 실시한 후 160℃에서 가황하여 가황고무 조성물을 제조한 다음 이에 대한 물성을 인장 시험기를 통해 시험하였으며, 발광 및 형광성은 크리스탈 박스(Crystal box)에 조성물을 채운 후 20시간이상 광을 차단한 다음 일반 햇볕에 20분간 노출시킨 후 시간 경과에 따른 휘도를 TOPCON BM-5렌즈로 측정하고 이때의 휘도를 ABC로 구분하여 그 결과를 하기 표 1에 나타내었다.The tire side part composition having the composition shown in Table 1 was subjected to extrusion and molding according to a conventional tire manufacturing procedure, and then vulcanized at 160 ° C. to prepare a vulcanized rubber composition, and then tested for physical properties thereof through a tensile tester. Fluorescent, after filling the composition in the crystal box (block) for more than 20 hours, and then exposed to sunlight for 20 minutes, the luminance over time is measured with a TOPCON BM-5 lens and the luminance is classified as ABC The results are shown in Table 1 below.
상기 표 1에서 보는 바와 같이 본 발명의 바람직한 범위 내에서 실시한 실시예 1 내지 5의 경우 형광성, 발광성 및 물성이 우수함을 확인할 수 있다.As shown in Table 1, in Examples 1 to 5 carried out within the preferred range of the present invention, it can be confirmed that the fluorescent, luminescent and physical properties are excellent.
상기에서 설명한 바와 같이 본 발명은 축광물질과 형광물질 및 글래스비드를 포함하는 타이어의 사이드부용 조성물을 제공함으로서 상기 조성물을 타이어 제조시 사이드부에 적용하여 제조된 타이어의 경우 어두운 곳에서 형광 및 축광안료에 의한 야광효과와 글래스비드에 의한 재귀반사효과로 차량위치의 식별력을 극대화시켜 교통 안전사고를 미연에 방지할 수 있을 뿐만 아니라 활동적이고 스포틱한 분위의 타이어를 원하는 소비자들의 욕구를 충족시킬 수 있는 유용한 효과가 있다.As described above, the present invention provides a composition for a side portion of a tire including a photoluminescent material, a fluorescent material, and glass beads, so that the tire is manufactured by applying the composition to the side portion when the tire is manufactured. The luminous effect caused by luminous and retroreflective effect by glass bead maximizes the discrimination ability of the vehicle location and prevents traffic safety accidents in advance, and is also useful for satisfying the needs of consumers who want active and sporty tires. It works.
Claims (7)
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| KR10-2002-0049311A KR100529854B1 (en) | 2002-08-20 | 2002-08-20 | Luminescent compound for the tire side |
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| KR10-2002-0049311A KR100529854B1 (en) | 2002-08-20 | 2002-08-20 | Luminescent compound for the tire side |
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| KR20040017170A true KR20040017170A (en) | 2004-02-26 |
| KR100529854B1 KR100529854B1 (en) | 2005-11-22 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100529853B1 (en) * | 2002-08-20 | 2005-11-22 | 금호타이어 주식회사 | Luminescent compound for the tire side |
| KR100529855B1 (en) * | 2002-08-20 | 2005-11-22 | 금호타이어 주식회사 | Luminescent compound for coating of the tire side |
| KR100771685B1 (en) * | 2006-06-20 | 2007-10-31 | 금호타이어 주식회사 | Tire sidewall rubber composition |
| KR100792008B1 (en) * | 2006-10-26 | 2008-01-04 | 금호타이어 주식회사 | Supplying device of fluorescence substance |
| CN102964639A (en) * | 2011-08-31 | 2013-03-13 | 赛轮股份有限公司 | Tire fluorescent sidewall rubber and preparation method |
| CN111164143A (en) * | 2017-09-28 | 2020-05-15 | 米其林集团总公司 | Tire comprising rubber composition |
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| JP2597259Y2 (en) * | 1993-12-22 | 1999-07-05 | 横浜ゴム株式会社 | Pneumatic tire |
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| JPH10907A (en) * | 1996-06-18 | 1998-01-06 | Matsushita Electric Ind Co Ltd | Tire, wheel, vehicle and manufacture thereof |
| KR19990011831A (en) * | 1997-07-25 | 1999-02-18 | 남일 | Rubber composition for tire tread with luminous effect |
| DE60022260T2 (en) * | 1999-05-28 | 2006-06-08 | Société de Technologie Michelin | Colored rubber composition for tires |
| JP2002019402A (en) * | 2000-07-07 | 2002-01-23 | Teikoku Printing Inks Mfg Co Ltd | Wheel cap |
| KR100756332B1 (en) * | 2001-12-21 | 2007-09-06 | (주)브레인유니온시스템 | Complex highmolecular resin composition and printed matter surface treating method therewith |
| KR20030092742A (en) * | 2002-05-31 | 2003-12-06 | 금호타이어 주식회사 | The tire side rubber composition having the effect of photoluminescent and the tire produced using the same |
| KR20030092743A (en) * | 2002-05-31 | 2003-12-06 | 금호타이어 주식회사 | The photoluminescent tire applied with the photoluminescent paint |
| KR100451861B1 (en) * | 2002-06-27 | 2004-10-08 | 금호타이어 주식회사 | The Photoluminescent Tire |
| KR100529855B1 (en) * | 2002-08-20 | 2005-11-22 | 금호타이어 주식회사 | Luminescent compound for coating of the tire side |
| KR100529853B1 (en) * | 2002-08-20 | 2005-11-22 | 금호타이어 주식회사 | Luminescent compound for the tire side |
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2002
- 2002-08-20 KR KR10-2002-0049311A patent/KR100529854B1/en not_active IP Right Cessation
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100529853B1 (en) * | 2002-08-20 | 2005-11-22 | 금호타이어 주식회사 | Luminescent compound for the tire side |
| KR100529855B1 (en) * | 2002-08-20 | 2005-11-22 | 금호타이어 주식회사 | Luminescent compound for coating of the tire side |
| KR100771685B1 (en) * | 2006-06-20 | 2007-10-31 | 금호타이어 주식회사 | Tire sidewall rubber composition |
| KR100792008B1 (en) * | 2006-10-26 | 2008-01-04 | 금호타이어 주식회사 | Supplying device of fluorescence substance |
| CN102964639A (en) * | 2011-08-31 | 2013-03-13 | 赛轮股份有限公司 | Tire fluorescent sidewall rubber and preparation method |
| CN111164143A (en) * | 2017-09-28 | 2020-05-15 | 米其林集团总公司 | Tire comprising rubber composition |
| EP3688088A4 (en) * | 2017-09-28 | 2021-05-19 | Compagnie Générale des Etablissements Michelin | A tire comprising a rubber composition |
| US11724542B2 (en) | 2017-09-28 | 2023-08-15 | Compagnie Generale Des Etablissements Michelin | Tire comprising a rubber composition |
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|---|---|
| KR100529854B1 (en) | 2005-11-22 |
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