KR20040009150A - Manufacturing Method of Lightweight Foam Concrete for Backfilling of Cavities in Tunnel/Underground Structure using Stone Dust in Cake State - Google Patents

Manufacturing Method of Lightweight Foam Concrete for Backfilling of Cavities in Tunnel/Underground Structure using Stone Dust in Cake State Download PDF

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KR20040009150A
KR20040009150A KR1020020042992A KR20020042992A KR20040009150A KR 20040009150 A KR20040009150 A KR 20040009150A KR 1020020042992 A KR1020020042992 A KR 1020020042992A KR 20020042992 A KR20020042992 A KR 20020042992A KR 20040009150 A KR20040009150 A KR 20040009150A
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weight
cake
tunnel
cement
weight ratio
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KR1020020042992A
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Korean (ko)
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KR100483492B1 (en
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마상준
배규진
서경원
안상철
임경하
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한국건설기술연구원
주식회사 리폼시스템
삼표산업 주식회사
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Priority to KR10-2002-0042992A priority Critical patent/KR100483492B1/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
    • C04B38/106Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam by adding preformed foams
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/12Waste materials; Refuse from quarries, mining or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mining & Mineral Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PURPOSE: A method for making a light-weight aerated concrete from a stone dust in cake state is provided to reduce the cost needed for treating the waste stone dust, prevent environment pollutions and obtain improved physical properties and quality. CONSTITUTION: The method for making a light-weight aerated concrete for filing a cavity of tunnel/underground structures comprises the steps of: mixing stone dust in cake state which is a waste material generated in a stony mountain during an aggregate/stone construction process in a light aerated concrete for filler, in the ratio of 2-4 wt% based on the total weight, and foaming the mixture through a foaming device. Particularly, the stone dust in cake state is mixed with cement in the weight ratio of 5:5 to 3:7, and then foamed.

Description

케익상 석분토를 활용한 터널/지하시설물의 공동부채움용 경량기포 콘크리트 제조방법 {Manufacturing Method of Lightweight Foam Concrete for Backfilling of Cavities in Tunnel/Underground Structure using Stone Dust in Cake State}Manufacturing Method of Lightweight Foam Concrete for Backfilling of Cavities in Tunnel / Underground Structure using Stone Dust in Cake State}

본 발명은 폐기되는 케익상석분토(Stone dust in cake state)를 활용한 터널/지하시설물의 공도부채움용 경량기포 콘크리트 제조방법에 관한 것으로,The present invention relates to a method for manufacturing lightweight foamed concrete for pavement of tunnels / underground facilities using discarded cake dust in cake state,

특히 터널/지하시설물의 공동부채움재는 석산에서 발생되는 케익상석분토와, 통상에서와 같이 시멘트를 혼합하여 혼합한후 소량의 기포제를 혼합하여 건상의 공동부채움재를 조성하며 물로 반죽한 후, 기포를 혼합하여 채움재 모르타르로 사용하게 되는 공동부 채음용 경량기포콘크리트에 관한 것이다.In particular, the cavity filling material of the tunnel / underground facilities is a cake topstone clay produced in Seoksan and cement as usual, and then a small amount of foaming agent is mixed to form a dry cavity filling material, kneaded with water, and then bubbled. It relates to a light-weight foam concrete for filling the cavity to be used as a filler mortar by mixing.

이러한, 본 발명은 석산(石山)에서 석조물(石造物)과 토목건축용의 골재/모래를 생산하는 과정에서 발생되어 폐기 처리되던 케익상석분토를 재활용자재로 유효하게 이용함으로써, 종전의 석산 폐기물인 케익상석분토의 처리비용의 부담 및 환경파괴의 원인들을 해결할 뿐만 아니라, 채움재로서 물리적 성질도 우수하여 안전시공과 견고성을 보장할 수 있는 공동부채움용 경량기포콘크리트에 그 특징이 있다.The present invention effectively utilizes the cake topstone soil generated in the process of producing the stone and sand for the construction of aggregates and sand in the stone mountain as a recycled material, the cake of the former stone acid waste It not only solves the burden of treatment cost and environmental destruction of the topsoil, but also has the characteristics of lightweight foam concrete for co-filling which can guarantee safety construction and robustness as it has excellent physical properties as a filler.

일반적으로, 터널을 포함하는 지하구조물에는 콘크리트라이닝과 지반사이에 시공과정 또는 유지관리 과정에서 공동부가 존재 또는 발생되며 이 배면공동으로 인해 터널 구조물에 국부적인 응력집중이 발생, 터널 라이닝에 크랙, 누수, 변형 등 터널변상을 야기시킨다. 또한, 폐갱도/천연동굴과 같은 지하의 인위적/자연적으로 발생된 지하공동에 의해 지표침하 등 지상구조물에 심각한 피해를 일으키는데 이러한 변상에 대한 대책공법으로서 터널 및 지하구조물에 존재하는 공동부를 뒤채움하므로써, 구조물에 미치는 지반하중을 구조물 전체에 균등하게 분포시키며 구조물과 지반과의 일체화 및 터널의 아칭효과를 극대화하여 터널의 변상을 최소화 또는 변상을 미연에 방지할수 있다.In general, in underground structures including tunnels, cavities are present or generated between the concrete lining and the ground during construction or maintenance, and the rear cavity causes localized stress concentrations in the tunnel structure. Or tunnel deformation. In addition, underground artificial cavities, such as closed tunnels and natural caves, cause severe damage to ground structures such as ground subsidence.As a countermeasure against such damages, it is necessary to fill the cavities in tunnels and underground structures. In addition, the ground load on the structure is distributed evenly over the structure, and the structure and ground can be integrated and the arching effect of the tunnel can be maximized to minimize or prevent tunnel damage.

터널 배면 공동부의 발생원인을 터널 공법별로 분류하면 다음과 같다.The causes of tunnel back cavity are classified by tunnel construction method as follows.

1980년대 이전 ASSM공법으로 시공된 터널은 지반과 라이닝 사이에 공동은 목재나 발파부석을 이용하여 충진시키는데 이때 충진재 공간을 모르타르를 이용하여 충진시켜야 하는데 대부분의 터널에서는 충분히 충진시키지 않음으로써, 목재로 충진시킨 경우는 시간이 경과함에 따라 목재가 썩거나 발파부석으로 충진한 경우는 부분적인 유동침하를 유발시킬 수 있다. 이때 목재나 발파부석으로 충진한 경우 지반과 터널 라이닝사이에 중·대규모의 공동이 발생, 터널 라이닝과 강지보에 직접 하중을 전달하는 ASSM공법 터널인 경우, 터널구조물 안정성에 심각한 문제를 야기 시킬 수 있다.Tunnels constructed by the ASSM method before the 1980s are filled with wood or blast pavement between the ground and the lining, and the filler space should be filled with mortar, but most tunnels do not fill enough, In some cases, the wood may rot over time or be filled with blastite, causing partial flow subsidence. In case of filling with wood or blast stone, medium-to-large cavities occur between ground and tunnel lining, and in case of ASSM tunnel that directly transfers load to tunnel lining and steel beam, it can cause serious problems in tunnel structure stability. have.

그리고, 1980년대 중반부터 NATM공법으로 시공된 터널은 지반과 콘크리트 라이닝사이가 밀착되어 공동규모가 작지만 터널 천단부에는 라이닝 타설시 재료분리및 블리딩현상 등으로 크고 작은 공동이 존재한다. 그외 지하수와 함께 토사가 유출될 경우과 경과년수로 인한 자연적인 현상으로 배면공동이 발생·확대 및 지하수 유입에 의한 숏크리트 입자 유출로 숏크리트 두께 경감등 터널 배면 공동이 발생된다.In the mid 1980s, the tunnel constructed by the NATM method has a small joint size due to the close contact between the ground and the concrete lining, but there are large and small cavities at the top of the tunnel due to material separation and bleeding during lining. In addition, when the soil is discharged along with the groundwater and the natural phenomenon due to the elapsed years, the rear cavity is generated and enlarged, and the shotcrete particle leakage caused by the inflow of groundwater causes the tunnel rear cavity to be reduced.

이렇게, 터널에 공동부가 발생되어 심각한 터널 변상을 일으킬 경우에는 일반적으로 주행/통행을 차단하고 터널 보수공사로서 공동부를 채워주는 채움 시공하게 되는데, 이때 시멘트모르타르로 구조물 공동부의 채움 작업을 실시할 수 있겠으나, 상기 시멘트 모르타르의 경우는 재료분리 및 블리딩현상에 의해 재료의 품질저하와 공동부를 완전하게 채우지 못하는 문제점이 있다.In this case, when the cavity is generated in the tunnel and causes severe tunnel remodeling, it is generally required to block driving / passage and fill the cavity as a tunnel repair work. In this case, the cement mortar may be filled with the cavity. However, in the case of the cement mortar, there is a problem in that the quality of the material and the cavity is not completely filled due to material separation and bleeding.

이러한, 채움재의 종류로는 모르타르이나 시멘트밀크에 공기를 넣어 유동성을 양호하게 한 에어모르타르/에어밀크로 주로 산악터널에 이용되는 것과, 양수량이 많은 고분자계약액의 일종인 발포우레탄으로 긴급복구용에 이용되는 것, 겔타입 조절이 가능하여 순결성이 요구되는 경우에 이용되는 물유리계와, 고분자계 시멘트의 일종으로 가소성주입제로 수중에 한정되는 폴리머 시멘트계로 분류 할 수 있다.This type of filling material is mainly used in mountain tunnels as air mortar / air milk, which has good air flow through mortar or cement milk, and foam urethane, which is a kind of high-molecular quantity polymer solution, for emergency recovery. It can be classified into a water glass system used when the purity of the gel type can be adjusted, and a polymer cement system limited in water as a plastic injection agent, which is a kind of polymer cement.

이러한, 공동부채움재로 사용되고 있는 모르타르는 주입작업시에 분리원활, 침전예방, 비수축성, 강도10㎏/㎠의 유지가 보장되어야 공동부채움재로 바람직한 것인바, 이에대한 하나의 예를 들면, 잔골재900㎏, 시멘트150㎏, 기포제3,45㎏, 물시멘트비130%, 공기량35-45%,(유하 기간)20-3초, 강도10㎏/㎠의 에어모르타르채움재가 사용되고 있다.The mortar, which is used as the cavity filling material, is preferred as the cavity filling material to ensure separation, sedimentation prevention, non-shrinkage, and maintenance of strength of 10 kg / cm 2 during the injection operation. 900 kg of cement, 150 kg of foam, 3,45 kg of foam, 130% of water cement, 35-45% of air volume, 20-3 seconds (falling period), and air mortar filling material of 10 kg / cm 2 strength are used.

그리고, 근래의 개발된 채움재로서, 화력발전소의 폐기물인 석탄재인 플라이애쉬 4%, 조골재 10%, 중간골재 62%, 모래 24%와 아스팔트량을 5.0% ∼ 6.5%까지 배합한 플라이애쉬를 이용한 도로포장용 아스콘의 채움재로의 이용 및 이의 제조방법의 채움재(공개번호 특1998-028032호)와, 채움재로 시멘트, 모래, 플라이애시를 물과 혼합한 것에 기포액을 혼합하여 채움성이 양호한 유동성과 채움 후 하중부담이 없는 경량성 및 견고성이 있는 압축강도를 구비한 기포 혼합 모르타르를 조성하는 기포모르타르를 이용한 공동부의 채움공법의 채움재(공개특허 공개번호10-2000-0031838호)와, 제철·제강 더스트와 소각재를 중량기준으로 6:4-8:2의 비율로 혼합/고형화 시키고 건조/소성단계로 입도를 조정하고 130??∼170?? 가열하여 크기별로 분리된 충진제를 140??∼160??로 가열된 아스팔트와 혼합하는 폐기물은 유효하게 이용하는 전기로, 제강 더스트와 소각재를 이용한 역청포장용 채움재 및 이를 이용한 아스콘 제조방법의 채움재(공개특허공보공개번호 10-2000-003636호)등이 개시되고 있고,In recent years, as a filling material, roads using fly ash including 4% of fly ash, 10% of aggregate, 10% of intermediate aggregate, 62% of sand, and 24% of asphalt and 5.0% to 6.5% of asphalt, which are wastes of thermal power plants. Use of packaging ascon as a filler and its manufacturing method (Public Publication No. 1998-028032), and a mixture of cement, sand, and fly ash with water as a filler to mix air bubbles with good fluidity and filling Filler of the cavity filling method using bubble mortar to form a bubble-mixing mortar with light weight and robust compressive strength without load burden (Public Patent Publication No. 10-2000-0031838), and steel and steel dust And incineration are mixed / solidified at a ratio of 6: 4-8: 2 by weight, and the particle size is adjusted in the drying / firing step. Waste which mixes the fillers separated by size by heating with asphalt heated from 140 ?? to 160 ?? is an electric furnace which is effectively used, a filler for bitumen packing using steelmaking dust and an incinerator, and a filler of an ascon manufacturing method using the same. Publication No. 10-2000-003636), etc. are disclosed,

또한, 각종 토목공사나 건축공사, 수중지하공사 등 다습한 곳의 공사등에 좋도록, 슬래그분말 71 중량부와 포틀랜드시멘트 25 중량부에 혼화제로 무수석고 2.85중량부, 명반(Alum Stone) 0.9 중량부, 카본블랙(Carbon Black)0.09중량부, 메칠셀루로이스(Methil Cellouse) 0.1 중량부, 실리카슘 0.06 중량부로 함유되는 슬래그를 이용한 저비용 복합시멘트 조성물(공개특허공보공개번호10-1997-0059135호)와, 또 경량기포 콘크리트로서, 플라이 애쉬(Fly Ash)를 혼입한 경량 기포콘크리트 조성물 및 그 제조방법에 관한 것으로, 시멘트와 플라이 애쉬를 중량비로 2 내지 8 대 1의 비율로 혼합하고, 여기에 물을 가하여 시멘트 페이스트를 제조한다.다음 기포제와 물을 혼합한 희석액을 기포발생장치에 투입하여 기포를 발생시키고, 상기 기포 용액을 상기 시멘트 페이스트에 혼합하고 교반하여 되는(플라이 애쉬를 혼입한 경량 기포콘크리트 조성물 및 그 제조방법(공개특허공보(공개번호10-2000-0007185호)와, 시멘트 70~90 중량%, 모래 10~20 중량%, 플라이애시 1~10 중량% 비율로 배합된 혼합몰탈을 현장에서 물과 혼합 교반한 후, 상기 혼합 몰탈과, 물에 기포제 2~4 중량%를 혼합한 후 발포기를 통과하열 발생된 기포군을 90~97 중량% ; 3~10 중량%의비율로 혼합하여서 된 기포 혼합 몰탈을 동공부내에 7m 이내로 주입하여 12~17 시간 양생 후 그 위에 재차 기포 혼합 몰탈을 적층 시공하는 기포 혼합몰탈을 이용한 동공부의 채움공법(공개특허공보 공개번호10-2000-0031838호)도 개시되고 있다.In addition, in order to be suitable for various works such as various civil works, construction works, underwater underground works, etc., 71 parts by weight of slag powder and 25 parts by weight of Portland cement are admixtures 2.85 parts by weight of gypsum, 0.9 parts by weight of alum stone, Low-cost composite cement composition using a slag containing carbon black (0.09 parts by weight, 0.1 parts by weight of methyl cellulose, 0.06 parts by weight of silica) (Public Publication No. 10-1997-0059135), The present invention relates to a lightweight foamed concrete composition containing fly ash as a light-weight foamed concrete and a method for manufacturing the same, wherein cement and fly ash are mixed in a weight ratio of 2 to 8 to 1, and water is added thereto. A cement paste is prepared. Next, a diluent mixture of foaming agent and water is introduced into a bubble generator to generate bubbles, and the bubble solution is mixed with the cement paste. On the contrary (lightweight foamed concrete composition containing fly ash and its manufacturing method (Patent No. 10-2000-0007185), 70 to 90% by weight of cement, 10 to 20% by weight of sand, 1 to fly ash After mixing and mixing the mixed mortar blended with water at 10% by weight in the field, and mixing the mixed mortar with 2 to 4% by weight of the foaming agent to water, 90 to 97% by weight of the bubble group generated by passing through the foamer. Filling method of the pupil part using bubble mixing mortar which bubbles-mixed mortar mixed by 3-10 wt% ratio is injected within 7m into the pupil part and cured for 12-17 hours, and then laminating the bubble-mixing mortar on it again. Korean Laid-Open Patent Publication No. 10-2000-0031838) is also disclosed.

그리고, 기포의 분포가 균일하여 단열, 방음 경량성이 우수하고 압축강도가 균일한 양질의 기포모르타르를 각종 건축물의 바닥 슬라브에 단열, 방음재로 타설하거나, 연약지반성토용으로 사용할 수 있는 기포 모르타르 조성물 및 그 제조방법에 관한 것으로. 물에 농도 2~4의 기포제를 섞어 기포가 충분히 발생되게 하고 제조한 다음,시멘트 75~80중량, 모래 8~10중량, 플라이애쉬 15~17중량및 세멕스판(Cemexpan)1~3중량를 물과 함께 혼합 교반하여 모르타르를 제조한 후에, 혼합모르타르 90~95중량에 대하여 기포가 발생된 상기 기포액 5~15중량를 혼합하여 제조함을 특징으로 하는 기포용 모르타르조성물(공개특허공보 공개번호10-2001-0028978호)와, 또 각종 건축물의 바닥 슬라브에 단열, 방음재로 타설하거나, 연약지반성토용으로 사용할 수 있는 기포 모르타르 조성물 및 그 제조방법으로서,물에농도 2~4의 기포제를 섞어 기포가 충분히 발생되게 하고 제조한 다음,시멘트 75~80중량, 모래 8~10중량, 플라이애쉬 15~17중량및 세멕스판(Cemexpan)1~3중량를 물과 함께 혼합 교반하여 모르타르를 제조한 후에, 혼합모르타르 90~95중량에 대하여 기포가 발생된 상기 기포액 5~15중량를 혼합하여 제조함을 특징으로 하는 기포용 모르타르조성물(공개특허공보공개번호10-2001-0028978호)도 개시된바 있다In addition, a high-quality foam mortar with uniform foam distribution, excellent insulation and soundproofing lightness, and uniform compressive strength can be used as a thermal insulation and soundproofing material for floor slabs of various buildings, or can be used for soft ground soils. And to a method for producing the same. Mix the foaming agent of concentration 2 ~ 4 with water to make enough bubbles, and then prepare 75 ~ 80 weight of cement, 8 ~ 10 weight of sand, 15 ~ 17 weight of fly ash and 1-3 weight of Cemexpan. After mixing and stirring together to prepare a mortar, a mortar composition for foaming, characterized in that the mixture is prepared by mixing 5 to 15 weight of the bubble liquid generated bubbles with respect to 90 to 95 weight of the mixed mortar. -0028978) and a foam mortar composition and a method for manufacturing the same, which can be used as a thermal insulation and soundproofing material for floor slabs of various buildings, or for soft soils, and a method of manufacturing the same. After the mortar was prepared by mixing the mixture with 75 to 80 weights of cement, 8 to 10 weights of sand, 15 to 17 weights of fly ash, and 1 to 3 weights of Cemexpan with water, to prepare a mortar, mixed mortar 90 To ~ 95 weight There is also disclosed a foam mortar composition (Published Patent Publication No. 10-2001-0028978) characterized in that the mixture is prepared by mixing 5 to 15 weight of the bubble solution generated bubbles.

이러한, 종전의 공동부 채움재들은 수화물 생성기능과, 조성물의 일체화를 가능케하는 포졸란반응의 촉진기능/응집작용배가의 역할이나, 시멘트입자와의 분산성능과 고분율의 석분토등의 수함율을 저감시키고 흐름성의 양호기능이나, 워커빌리티(작업성)기능, 동결융해에 대한 저항성을 향상시키는 기능, 조성물의 기공층의 증가로 비중을 낮추는 기능들이 없이 공동부채움재를 조성함으로써, 바람직한 하중이나 강도를 기대할 수 없는 것이다.These former cavity fillers have a function of hydrate generation and a function of promoting / coagulating the pozzolanic reaction, which enables the integration of the composition, but also reduces the dispersing performance with cement particles and the water content such as high fraction of clay powder. Desirable load or strength can be expected by forming a cavity filling material without having good flowability, workability, improving resistance to freezing and thawing, and lowering the specific gravity by increasing the pore layer of the composition. It is not there.

본 발명의 터널/지하시설문 공동부 뒤채음용 경량기포콘크리트의 소재로 활용되는 케익상석분토 및 부순모래는 석산에서 암괴를 자갈 및 골재로 생산하는 파분쇄과정에서 발생되는데, 파분쇄된 골재의 선별과정에서 굵은골재(4,7mm이상)가 선별되고 마지막 선별과정에서 물로 세척할 때 부순모래(잔골재;0,074mm-4,7mm)를 선별하여 모르타르용 골재로 사용되고 세척물에 침전되는 0,074mm이하의 석분 즉, 케익상석분토가 발생된다.Cake tops and soils and crushed sands used as the material for the back-filled lightweight foam concrete for tunnels / underground facility doors of the present invention are generated in the crushing process of producing rock as gravel and aggregates in the quarries. The coarse aggregate (4,7mm or more) is selected in the process, and when washing with water in the final screening process, the crushed sand (fine aggregate; 0,074mm-4,7mm) is selected and used as aggregate for mortar, and below 0,074mm. Stone dust, that is, cake topstone soil, is generated.

또한, 암괴를 절단하거나 표면을 연마할때는 물을 사용하게되어 석분이 물과 같이 배출되어 쌓이면서 자연적으로 탈수되어 케익상석분토가 발생된다.In addition, when cutting the rock or polish the surface water is used, and the stone powder is discharged and accumulated like water and naturally dehydrated to generate cake topstone soil.

이렇게, 석산에서 발생되는 케익상석분토는 사용가치가 없어 현재까지는 폐기물(쓰레기)로 분류하여 매립처리되고 있다. 폐기되는 케익상석분토는 쓰레기매립장으로 운송되어 처리되고 있어 매립지 확보 및 매립처리에 의한 비용등이 부과되는 경제적인 문제점이 있고, 더욱 이러한 케익상석분토의 처리비용을 줄이기 위하여 세척물에 침전되는 석분토를 그대로 하천에 방류하여 하천오염을 일으키는 문제점도 있는 것이다.As such, the cake topsoil produced in quarries has no value in use, and has been classified as waste (garbage) until now and landfilled. The discarded cake topsoil is transported to a landfill and is disposed of, so there is an economic problem that the landfill site and landfill costs are imposed. There is also a problem that causes river pollution by leaving the river as it is.

본 발명은 석산에서 발생되어 폐기물로 매립처리되던 케익상석분토(폐기물)를 케익상석분토(폐기물)(중량20-35%)를 주제로 하고 여기에 시멘트, 물을 혼합 교반한 후, 기포제를 발포기를 이용하여 발포시킨 기포를 혼합 반죽한 경량기포콘크리트를 조성하여 토목(터널)/시설물(지하)의 공동부에 타설하므로서, 특히 경제적인 효과가 높고 물리적인 물성도 일반적인 시멘트콘크리트의 물성과 유사하며 종전에 폐기물로 처리되던 케익상석분토의 처리문제도 해결되는 동시에 환경문제등도 해결되는 케익상석분토를 활용하여 공동부 채움용 경량기포콘크리트를 제공함에 있다.The present invention is based on the cake tops (waste) (waste) (waste) (20-35%) of cake topsoil (waste), which was generated and disposed of as waste in quarries, was mixed with agitated cement and water, and then foamed with a foaming agent. By constructing lightweight foamed concrete mixed with foamed foam using the machine, and placing it in the cavity of civil engineering (tunnel) / facilities (underground), it is particularly economical and its physical properties are similar to those of general cement concrete. It is to provide lightweight foamed concrete for filling the cavity by using cake topsoil which solves the problem of cake topsoil previously treated as waste and solves environmental problems.

본 발명을 구현하기 위하여는 폐기물로 처리되던 케익상석분토(중량비20-35%)를 주제로 하고 여기에 시멘트(중량비35-50%), 물(중량비25~30%)를 혼합교반한 후, 기포제(물과 기포제를 중량비30~40:1로 희석)를 발포기를 이용하여 발포시킨 기포(중량비2~10%)를 혼합 반죽하여 물리/화학적 안전성, 하중 및 강도의 우수성으로 시공성도 양호한 케익상 석분토를 활용한 터널/시설물의 공동부채움용 경량기포 콘크리트에 특징이 있다.In order to implement the present invention, the cake tops were treated as waste (20-35% by weight) and mixed with cement (35-50% by weight) and water (25-30% by weight). A cake phase with excellent workability due to the excellent physical / chemical safety, load and strength by mixing and kneading the foaming agent (diluted water and foaming agent in a weight ratio of 30 to 40: 1) using a foaming machine (weight ratio 2 to 10%). It is characterized by lightweight foamed concrete for co-filling of tunnels / facilities using stone powder.

본 발명의 다른 목적은 폐기물로 매립처리되던 환경친화적 물질인 케익상 석분토를 활용한 경량기포 콘크리트 성토바닥재로 활용함으로써 종전에 폐기처리비용을 생략하는 경제적인 이익과 재활용산업에 기여함에 그 특징이 있다. 또한, 환경친화적 물질인 케익상석분토수의 방류에 따른 수질오염도 예방하는 환경친화적인 터널/시설물의 공동부 뒤채음용 경량기포콘크리트의 개발 및 사용에 있다.Another object of the present invention is characterized by contributing to the economic benefits and recycling industry by eliminating the waste disposal costs by using as a lightweight foam concrete fillet flooring using the cake-like stone powder, which is an environmentally friendly material that was disposed of as waste. . In addition, the present invention is to develop and use lightweight foam concrete for backing the cavity of an environmentally friendly tunnel / facility that also prevents water pollution caused by the discharge of environmentally friendly cake topsoil.

본 발명은 석산에서 발생되어 폐기물로 매립처리되는 케익상석분토(폐기물)를 효율적이고 경제적으로 활용할 수 있도록, 환경친화적 물질인 케익상석분토(폐기물)(중량비20-35%)에다, 시멘트(중량비35-50%), 물(중량비25~30%)를 혼합교반한 후, 기포제(물과 기포제를 중량비30~40:1로 희석)를 발포기를 이용하여 발포시킨 기포(중량비2~10%)를 혼합 반죽하여 물리/화학적 안전성, 하중 및 강도의 우수성으로 시공성도 양호한 케익상석분토를 활용한 터널/시설물의 공동부 뒤채음용 경량기포콘크리트를 제공하는데 있다.In order to efficiently and economically utilize cake topsoil (waste) generated from quarries and landfilled as waste, cake topsoil (waste) (weight ratio 20-35%), which is an environmentally friendly substance, is added to cement (weight ratio 35). -50%) and mixed with water (25-30% by weight), and then foamed by foaming the foaming agent (water and foaming agent diluted to 30-40: 1 by weight) using a foaming machine (2-10% by weight) It is to provide lightweight foamed concrete for back filling of tunnels / facilities using cake topsoil with excellent construction properties by mixing and kneading with excellent physical / chemical safety, load and strength.

상기와 같은 본 발명은 석산에서 골재 및 석조물을 생산하는 과정에서 발생되어 폐기되던 케익상석분토를 활용하여 여기에다 시멘트, 물을 혼합교반하여, 여기에 여기에 발포기에 의해서 발포된 기포를 혼합하여 터널/지하시설물의 공동부 뒤채움용 경량기포콘크리트를 주입시공 한다.As described above, the present invention utilizes a mixture of cement and water, which is generated and discarded during the production of aggregates and masonry in quarries, by mixing and stirring cement and water therein, and mixing bubbles foamed by a foaming machine in the tunnel / Inject and construct lightweight foamed concrete for filling the cavity of underground facilities.

이러한, 환경친화적인 본 발명의 케익상석분토를 활용한 터널/시설물 공동부 뒤채움용 경량기포콘크리트의 구체적인 조성비는 다음과 같다.The specific composition ratio of the lightweight foam concrete for filling the tunnel / facility cavity using the environmentally friendly cake topsoil of the present invention is as follows.

케익상석분토,,,,,,,,,,,,,,,, 20-35%(중량비),Cake topsoil ,,,,,,,,,,,,,,, 20-35% (weight ratio),

시멘트,,,,,,,,,,,,,,,,,,,,,, 35-50%(중량비),Cement ,,,,,,,,,,,,,,,,,,,, 35-50% (weight ratio),

물,,,,,,,,,,,,,,,,,,,,,,,,,, 25-30%(중량비),Water ,,,,,,,,,,,,,,,,,,,,,,,,, 25-30% (weight ratio),

희석기포액,,,,,,,,,,,,,,,,,, 2-10% (중량비),Dilution bubble liquid ,,,,,,,,,,,,,,,,, 2-10% (weight ratio),

상기와 같이 환경친화적 물질인 케익상석분토(폐기물)을 활용함에 그 특성이 높고, 통상의 시멘트 외에 첨가되는 발포기에 의해서 발포된 기포를 반죽하여 공동부에 주입충진 작업시에 채움용 경량기포콘크리트의 분리가 원활하고, 고형물의 침전이 없었고, 경화시에 수축성이 전혀 없으며, 코아(조건??10㎠-20㎠)의 하중27,220-14,895Kgf와, 강도 346,6-189,6Kgf/㎠가 보장되고, 또한 블리딩현상이 전혀 없었고, 특히 최적혼합비별로 실험실/현장실험(조건3-7일간양생)에 의한 결과로서 하중300-900Kgf에 이르고, 강도 12-70Kgf/㎠을 유지함을 확인하였다.As the above, the use of the environmentally friendly cake topsoil (waste) is high in its properties, and kneading the foam foamed by a foaming machine added in addition to the ordinary cement to fill the cavity during filling and filling of lightweight foam concrete Smooth separation, no settling of solids, no shrinkage at the time of curing, guaranteed 27,220-14,895Kgf of core (condition ?? 10㎠-20㎠) and strength of 346,6-189,6Kgf / ㎠ In addition, there was no bleeding at all, and it was confirmed that the load was 300-900 Kgf and the strength was maintained at 12-70 Kgf / cm 2, especially as a result of laboratory / field experiments (condition 3-7 days curing) for each optimum mixing ratio.

이러한, 본 발명은 첨가제로서 자연친화형 케익상석분토를 첨가하고, 또 기포제를 첨가하여 경량의 채움재를 조성함으로써, 흐름성이 양호하여 주입 및 충진이 용이하여 작업성을 높이고, 고형물의 침전예방, 수축성의 방지, 블리딩현상의 방지, 하중부담의 격감 등의 기능에 의해 충진재의 강도를 향상시켜 견고성을 유지하게 되는 것이다.In the present invention, by adding a natural friendly cake topsoil as an additive, and adding a foaming agent to form a lightweight filling material, the flowability is good, injection and filling is easy to improve workability, preventing the precipitation of solids, It is possible to maintain the rigidity by improving the strength of the filler by the function of preventing shrinkage, preventing bleeding, and reducing the load.

상기와 같은 하중경감과 높은강도의 유지효과를 갖는 본 발명의 물리적인 특성은 다음의 도표 및 실시예와 같다.The physical characteristics of the present invention having the above-described load reduction and high strength retention effect are shown in the following table and examples.

(단위:kg/m3)(Unit: kg / m 3 )

시멘트cement 석분토Stone powder water 기포율(%)Bubble rate (%) 압축강도(kgf/cm2)Compressive strength (kgf / cm 2 ) 7일7 days 28일28 days 1One 510510 220220 270270 44.9044.90 3535 4646 22 460460 200200 240240 50.6050.60 2828 3434 33 440440 290290 270270 43.3043.30 3232 3939 44 400400 260260 240240 49.3049.30 2222 2727 55 350350 230230 210210 55.5055.50 1717 2121 66 310310 200200 190190 60.4060.40 1515 1818

실시예1Example 1

케익상석분토21.5%(중량비).시멘트50%(중량비).물26.5%(중량비).희석기포제2%(중량비)의 조성비로 혼합한 비중 1.0의 경량기포콘크리트의 재령 7일 및 28일 압축강도는 각각 35Kgf/㎠와 46Kgf/㎠이다.21.5% of cake topsoil (weight ratio), 50% of cement (weight), 26.5% of water (weight), 2% of diluted foam (weight ratio) Are 35 Kgf / cm 2 and 46 Kgf / cm 2, respectively.

실시예2Example 2

케익상석분토21.75%(중량비).시멘트50%(중량비).물26%(중량비).희석기포제2.25%(중량비)의 조성비로 혼합한 비중 0.9의 경량기포콘크리트의 재령 7일 및 28일 압축강도는 각각 28Kgf/㎠와 34Kgf/㎠이다.7-day and 28-day compressive strength of lightweight foam concrete with a specific gravity of 0.95% (weight ratio), cement 50% (weight ratio), water 26% (weight ratio), diluent foam agent 2.25% (weight ratio) Are 28 Kgf / cm 2 and 34 Kgf / cm 2, respectively.

실시예3Example 3

케익상석분토28.5%(중량비).시멘트43%(중량비).물26.5%(중량비).희석기포제2%(중량비)의 조성비로 혼합한 비중 1.0의 경량기포콘크리트의 재령 7일 및 28일 압축강도는 각각 32Kgf/㎠와 39Kgf/㎠이다.78.5 and 28-day compressive strength of lightweight foam concrete with specific gravity 1.0 mixed with 28.5% (weight ratio) cake, 43% (weight ratio) water, 26.5% (weight ratio) water, 26.5% (weight ratio) dilution foam, and 2% (weight ratio) Are 32 Kgf / cm 2 and 39 Kgf / cm 2, respectively.

실시예4Example 4

케익상석분토28.5%(중량비).시멘트43.5%(중량비).물26%(중량비).희석기포제2.25%(중량비)의 조성비로 혼합한 비중 0.9의 경량기포콘크리트의 재령 7일 및 28일 압축강도는 각각 22Kgf/㎠와 27Kgf/㎠이다.78.5 and 28-day compressive strength of lightweight foamed concrete with a specific gravity of 0.95 (weight ratio), cement 43.5% (weight ratio), water 26% (weight ratio), diluent foam agent 2.25% (weight ratio) Are 22 Kgf / cm 2 and 27 Kgf / cm 2, respectively.

실시예5Example 5

케익상석분토28%(중량비).시멘트43%(중량비).물25.5%(중량비).희석기포제2.5%(중량비)의 조성비로 혼합한 비중 0.8의 경량기포콘크리트의 재령 7일 및 28일 압축강도는 각각 17Kgf/㎠와 21Kgf/㎠이다.7% and 28-day compressive strength of lightweight foamed concrete with a specific gravity of 0.8% of cake topsoil (weight ratio), cement 43% (weight ratio), water 25.5% (weight ratio), dilution foam agent 2.5% (weight ratio) Are 17 Kgf / cm 2 and 21 Kgf / cm 2, respectively.

실시예6Example 6

케익상석분토28%(중량비).시멘트43.25%(중량비).물26%(중량비).희석기포제2.75%(중량비)의 조성비로 혼합한 비중 0.7의 경량기포콘크리트의 재령 7일 및 28일 압축강도는 각각 15Kgf/㎠와 18Kgf/㎠이다.7% and 28-day compressive strength of lightweight foamed concrete with a specific gravity of 0.7% (weight ratio), cement 43.25% (weight ratio), water 26% (weight ratio), diluent foam 2.75% (weight ratio) Are 15 Kgf / cm 2 and 18 Kgf / cm 2, respectively.

이상과 같이 본 발명은 석산에서 골재 및 석조물을 생산하는 과정에서 발생되어 폐기처리 되고 있는 케익상석분토를 재활용하여 경량기포 성토바닥콘크리트를 생산함으로써, 재료비의 절감 및 폐기물의 매립처리로 인한 비용부담을 생략하여 얻어지는 경제적인 이익과 폐기석분의 방류에 의한 하천오염을 방지하여 환경친화에도 유익하며, 또 케익상석분토을 재활용하는 재활용산업에도 기여할 수 있는 유익한 발명이다.As described above, the present invention recycles the cake topsoil that is generated and processed in the production of aggregates and masonry in quarries to produce lightweight foamed clay bottom concrete, thereby reducing the material cost and cost burden due to landfill treatment of waste. Economical benefits obtained by omitting and preventing river pollution caused by the discharge of waste stone powder is beneficial to the environment and beneficial to the recycling industry for recycling cake topsoil.

이상에서 와같이 본 발명은 석산에서 석조물/골재들의 생산시에 발생되어 폐기되던 케익상석분토를 주재로 활용하여 공동부 경량기포 모르타르 채움재를 제조함으로써, 케익상석분토를 매립처리하던 경제적인 부담도 해소되고 하천의 오염도 예방되어 친환경적이며, 하중,강도등의 물리적인 특성과 품질도 종래의 것에 비하여 우수한 것으로 판명되었다.As described above, the present invention utilizes the cake topstone soil generated and discarded in the production of masonry / aggregate in quarries as a predominant material to manufacture the light-weight foam mortar filling material in the cavity, thereby eliminating the economic burden of landfilling the cake topstone soil. In addition, the pollution of the river is prevented and it is eco-friendly, and the physical properties and quality of load, strength, etc. are also proved to be superior to the conventional ones.

Claims (3)

석산에서 골재/석조물가공에서 발생되어 폐기되던 케익상석분토를 채움용 경량기포콘크리트의 전체비에 2내지 4의 중량비로 혼합하고 발포기를 통해서 발포되는 기포로 조성함을 특징으로 하는 케익상석분토를 활용한 터널/시설물의 공동부 채움용 경량기포 콘크리트의 제조방법.The cake topstone clay, which is generated from the aggregate / stone processing in Seoksan, is discarded and mixed with the total ratio of lightweight foam concrete for filling in a weight ratio of 2 to 4, and formed into bubbles that are foamed through a foaming machine. Method for manufacturing lightweight foamed concrete for filling a cavity of a tunnel / facility. 제 1 항에 있어서, 케익상석분토와 시멘트를 5;5내지 3;7(중량비)으로 혼합하고 발포기를 통해서 발포되는 기포로 조성되는 케익상석분토를 활용한 터널/시설물의 공동부 채움용 경량기포콘크리트의 제조방법.The light-weight bubble for filling the cavity of a tunnel / facility using a cake topstone, wherein the cake topsoil and cement are mixed at a ratio of 5; 5 to 3; 7 (weight ratio) and foamed through a foaming machine. Method of making concrete. 제 1 항에 있어서, 케익상석분토(중량비)20-35%와 시멘트(중량비)35-50%, 물(중량비)25-30%에 발포기를 통해서 발포한 기포로 조성한 케익상석분토를 활용한 터널/시설물의 공동부 채움용 경량기포콘크리트의 제조방법.The tunnel according to claim 1, wherein the cake tops are composed of bubbles foamed through a foaming machine in 20 to 35% of cake topsoil (weight ratio), 35-50% of cement (weight ratios), and 25-30% of water (weight ratios). / Method for manufacturing lightweight foamed concrete for filling cavity of facility.
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* Cited by examiner, † Cited by third party
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KR100500022B1 (en) * 2002-10-18 2005-07-14 주식회사 리폼시스템 Method of Preparing Expansible Backfill Lightweight Porous Concrete
CN111606689A (en) * 2020-06-05 2020-09-01 河北恒钏建筑材料有限公司 Light microcrystal foaming thermal insulation material made from waste stone powder and manufacturing method thereof
KR102272944B1 (en) * 2021-01-19 2021-07-05 손성래 Lightweight Aerated Concrete Block Composition using Waste Glasswool and Manufacturing Method of thereof
CN116003062A (en) * 2022-12-29 2023-04-25 中国石油大学(华东) Foam concrete for backfilling gas transmission pipeline in tunnel and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
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JPH08259348A (en) * 1995-03-20 1996-10-08 Asahi Chem Ind Co Ltd Production of light-weight foamed concrete
JP2001302367A (en) * 2000-04-26 2001-10-31 Clion Co Ltd Method for manufacturing lightweight foamed concrete
KR20020019680A (en) * 2000-09-06 2002-03-13 김두홍 Light weight foamed concrete using granite sludge

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Publication number Priority date Publication date Assignee Title
KR100500022B1 (en) * 2002-10-18 2005-07-14 주식회사 리폼시스템 Method of Preparing Expansible Backfill Lightweight Porous Concrete
CN111606689A (en) * 2020-06-05 2020-09-01 河北恒钏建筑材料有限公司 Light microcrystal foaming thermal insulation material made from waste stone powder and manufacturing method thereof
KR102272944B1 (en) * 2021-01-19 2021-07-05 손성래 Lightweight Aerated Concrete Block Composition using Waste Glasswool and Manufacturing Method of thereof
CN116003062A (en) * 2022-12-29 2023-04-25 中国石油大学(华东) Foam concrete for backfilling gas transmission pipeline in tunnel and preparation method thereof

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