KR20030093615A - Hydrophilic gel sheet - Google Patents

Hydrophilic gel sheet Download PDF

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Publication number
KR20030093615A
KR20030093615A KR1020020031222A KR20020031222A KR20030093615A KR 20030093615 A KR20030093615 A KR 20030093615A KR 1020020031222 A KR1020020031222 A KR 1020020031222A KR 20020031222 A KR20020031222 A KR 20020031222A KR 20030093615 A KR20030093615 A KR 20030093615A
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South Korea
Prior art keywords
gel layer
skin
hydrophilic
gel
hydrophilic gel
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KR1020020031222A
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Korean (ko)
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김봉조
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한웅코텍 주식회사
김봉조
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Priority to KR1020020031222A priority Critical patent/KR20030093615A/en
Publication of KR20030093615A publication Critical patent/KR20030093615A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/728Hydrophilic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2535/00Medical equipment, e.g. bandage, prostheses, catheter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00Personal care

Abstract

PURPOSE: A hydrophilic gel sheet is provided which has higher adhesion to the skin and is thus used as adhesion sheets for cosmetics, medical devices, cooling devices, cataplasma and transdermal absorption preparations. CONSTITUTION: In a hydrophilic gel sheet, a hydrophilic gel layer(a skin side gel layer) having a high adhesion force is laminated on one side of a porous core material(11), a hydrophilic or lipophilic gel layer(a non-skin side gel layer) having a low adhesion force is laminated on another side thereof, wherein each gel layer(12, 13) is covered with separating material(14).

Description

친수성 겔 시트{Hydrophilic Gel Sheet}Hydrophilic Gel Sheet {Hydrophilic Gel Sheet}

본 발명은 화장품, 의료용구, 냉각용구, 파프제 및 경피흡수제제 등의 의약품과 위생용품 등 피부 첩부용 시트로 사용되는 친수성 겔 시트에 관한 것이다.The present invention relates to a hydrophilic gel sheet used as a sheet for skin patching such as medicines and hygiene products such as cosmetics, medical equipment, cooling equipment, pape and percutaneous absorption preparations.

현재 시판되고 있는 피부 첩부용 시트로는 보수성 부직포 등에 물을 함유시켜 밀봉 포장한 형태(종래예 1)와, 친수성 겔 기재(22)에 필요에 따라 각종 유효성분을 함유시켜 부직포(21) 등에 도포한 형태(종래예 2)와, 비점착성 친수성 겔 시트에 필요에 따라 글리세린 등의 점착성 액체를 표면에 도포한 형태(종래예 3) 등이 있다. (종래예 2는 도 2에 도시하였음. 도면부호 23은 박리재임.)The currently available sheet for skin application includes water-sealed nonwoven fabrics and the like in water-sealed packaging (conventional example 1), and the hydrophilic gel base material 22 contains various active ingredients as necessary and applied to the nonwoven fabrics 21 and the like. One form (conventional example 2) and the form which apply | coated the adhesive liquid, such as glycerin, to the surface as needed to a non-adhesive hydrophilic gel sheet (conventional example 3) etc. are mentioned. (Prior example 2 is shown in Fig. 2. Reference numeral 23 is a peeling material.)

그러나, 종래예 1은 효과에 있어서 비교적 양호하나 피부에 잘 고정되지 않고 사용시 피부와의 일체감이 없어 사용감이 나쁘고, 종래예 2는 효과도 좋고 피부에 잘 고정되나 사용시 피부와의 일체감이 떨어진다. 그리고, 종래예 3은 종래에 2에 비해 사용시 피부와의 일체감은 어느 정도 개선되었으나 글리세린 등의 점착성 액체에 의해 피부와의 밀착성이 유지되기 어렵고, 시간이 경과함에 따라 그 액체가 피부에 흡수되는 등의 이유로 밀착성이 유지되지 않는다.However, the conventional example 1 is relatively good in effect, but is not well fixed to the skin and there is no sense of unity with the skin when used, the use is bad, while the conventional example 2 is also good effect and well fixed to the skin, but when used, the unity with the skin is poor. In addition, in the conventional example 3, the sense of unity with the skin is improved to some extent when compared with the conventional 2, but adhesiveness with the skin is difficult to be maintained by the adhesive liquid such as glycerin, and the liquid is absorbed into the skin with time. The adhesion is not maintained for the reason.

이상 살펴본 바와 같이 현재로서는 효과에 있어서도 우수하고, 피부에 잘 고정되며 피부와 일체감이 있는 피부첩부용 시트는 아직 없는 실정이다.As described above, at present, there is no sheet for skin affixation, which is excellent in effect and is well fixed to the skin and has a sense of unity with the skin.

본 발명은 효과도 우수하고, 피부에 잘 고정되고, 사용시 피부와 일체감이 있어 사용감이 좋은 화장품, 의료용구, 냉각용구, 파프제 및 경피흡수제제 등의 의약품과 위생용품 등으로 사용되는 친수성 겔 시트를 제공하는 것이다.The present invention has excellent effects, is well fixed to the skin, and has a sense of unity with the skin when used, and has a good feeling of use, and is a hydrophilic gel sheet used in medicines and hygiene products such as cosmetics, medical equipment, cooling equipment, pap and transdermal absorbents, To provide.

도 1은 본 발명의 친수성 겔 시트의 단면도이다.1 is a cross-sectional view of a hydrophilic gel sheet of the present invention.

도 2는 종래의 친수성 겔 시트의 단면도이다.2 is a cross-sectional view of a conventional hydrophilic gel sheet.

* 도면의 주요 부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

11: 다공성 심재12: 피부측 겔층11: porous core 12: skin side gel layer

12: 비피부측 겔층14, 23: 박리재12: non-skin side gel layer 14, 23: release material

21: 부직포22: 겔층21: nonwoven fabric 22: gel layer

본 발명의 발명자는 상기 목적을 달성하기 위하여 효과도 좋고 피부에 잘 고정되나 사용시 피부와의 일체감만 떨어지는 종래예 2의 구성을 검토한 결과, 피부와의 일체감이 떨어지는 것은 부직포(21) 때문이라고 판단하고 종래예 2에서 사용되는 형태 즉, 신축성을 떨어뜨리는 부직포를 사용하지 않기로 하였다. 그러나, 부직포가 없으면(즉, 겔층만으로 시트를 형성하면) 피부 반대측의 표면도 강한 점착력을 갖게 되고, 신축성은 좋으나 형태가 잘 유지되지 않아 첩부 조작시 다루기가 어려워진다.In order to achieve the above object, the inventor of the present invention examines the structure of the prior art example 2, which is effective and is well fixed to the skin, but inferior to the skin when used. As a result, the non-woven fabric 21 is judged to be inferior to the skin. And the form used in the conventional example 2, that is, the non-woven fabric to reduce the elasticity is not to be used. However, if there is no nonwoven fabric (i.e., the sheet is formed only by the gel layer), the surface on the opposite side of the skin also has a strong adhesive force, and the elasticity is good but the shape is not maintained well, making it difficult to handle during the sticking operation.

따라서, 시트가 최소한의 형태를 유지하도록 하기 위하여 다공성 심재를 겔 내부의 층간에 두고, 첩부 조작시 장애가 되지 않을 정도로 점착력이 낮은 겔층으로 피부측 겔층을 덮기로 하였다. 즉, 두 개의 겔층의 조성을 다르게 하여 피부측 겔층은 점착력을 높게 하고, 비피부측 겔층은 점착력을 낮게 하는 것이다.Therefore, in order to keep the sheet in a minimal form, the porous core was placed between the layers inside the gel, and the gel layer on the skin side was covered with a gel layer having a low adhesive strength so as not to be an obstacle during the sticking operation. In other words, the composition of the two gel layers are different, so that the skin side gel layer has high adhesive strength, and the non-skin side gel layer has low adhesive strength.

이 두 가지 대응책, 즉, 비피부 첩부측 겔층의 점착력을 첩부 조작시 장애가 되지 않을 정도로 하는 것과 형태가 유지되도록 다공성 심재를 겔 내부의 층간에 설치하는 것, 다시 말하면, 다공성 심재의 한쪽 면에는 점착력이 높은 친수성 겔층을 적층하고, 다른 한쪽 면에는 점착력이 낮은 친수성 또는 친유성 겔층을 적층하는 것에 의하여 피부에 잘 고정이 되며 사용시 피부와 일체감이 있어 사용감이 좋은 화장품, 의료용구, 냉각용구, 파프제 및 경피흡수제제 등의 의약품과 위생용품 등으로 사용되는 친수성 겔 시트가 얻어질 수 있는 것이다.Two countermeasures, namely, the adhesive force of the non-skin-adhesive side gel layer are such that they do not interfere with the patching operation, and the porous core is interposed between layers within the gel so that the shape is maintained, that is, the adhesive force is applied to one side of the porous core. The high hydrophilic gel layer is laminated, and on the other side, the hydrophilic or lipophilic gel layer with low adhesion is fixed to the skin, and it is well fixed to the skin. And hydrophilic gel sheets for use in medicines and hygiene products such as transdermal absorbents and the like.

각각의 겔층은 사용시까지 겔층의 수분이 증발하는 것과 오염되는 것을 방지하기 위하여 박리재로 덮는다.Each gel layer is covered with a release material to prevent evaporation and contamination of the moisture in the gel layer until use.

도 1을 사용하여 보다 상세히 설명하면, 본 발명의 친수성 겔 시트는 다공성 심재(11)를 중심으로 한면에 피부측 겔층 (또는 비피부측 겔층)(12)이 적층되고, 다른 한면에 비피부측 겔층 (또는 피부측 겔층)(13)이 적층되며, 각각의 겔층(12, 13)은 박리재(14)로 덮는 구조를 취하는 것으로, 피부측 친수성 겔층에 사용 목적에 따라 (약물이나 화장 성분)을 함유시켜 피부에 첩부하는 것이다.Referring to FIG. 1, the hydrophilic gel sheet of the present invention has a skin-side gel layer (or non-skin-side gel layer) 12 laminated on one surface of the porous core 11 and the non-skin side on the other side. The gel layer (or skin side gel layer) 13 is laminated, and each gel layer 12 and 13 has a structure that is covered with a release material 14, depending on the purpose of use for the skin side hydrophilic gel layer (drug or cosmetic component) It contains and attaches to skin.

다공성 시트의 양면에 적층되는 겔층의 점착력은 피부측 겔층은 볼택치 13 이상, 비피부측 겔층은 볼택치 10 이하로 하는 것이 바람직하다. (볼택치의 측정방법은 후술하는 실시예에 기재되어 있음.)As for the adhesive force of the gel layer laminated | stacked on both surfaces of a porous sheet, it is preferable that the skin side gel layer is 13 or more ball-tachches, and the non-skin-side gel layer is 10 or less ball-tachches. (Measurement method for ball touch is described in the examples described later.)

다공성 심재는 면, 레이온, 펄프, 셀룰로즈 등의 친수성 소재나 PE, PP, PET 등의 비친수성 소재로 올이 성긴 직포나 부직포, 또는 그물 형태의 직물로 신축성만 좋다면 재질과 직조 형태에 특별히 제한이 없다.Porous core material is a hydrophilic material such as cotton, rayon, pulp, cellulose, or non-hydrophilic material such as PE, PP, PET. It is a woven fabric, nonwoven fabric, or net-shaped fabric. There is no

친수성 겔 성분도 일반적으로 허용되는 것이라면 제한이 없다. 예를 들면, 폴리아크릴산 및 폴리아크릴산염, 셀룰로즈 유도체, PVA, PVP, 메틸비닐에스테르무수말레인산 공중합체 등의 합성, 반합성 친수성 고분자 화합물과, 젤라틴, 알긴산염, 다당체 등의 천연 증점제(겔 형성제)와, 알루미늄 화합물 등의 다가 금속염 등의 경화제와, 카올린, 산화티탄 등의 충진제 등으로 이루어진다.Hydrophilic gel components are also not limited as long as they are generally acceptable. For example, synthetic, semisynthetic hydrophilic polymer compounds such as polyacrylic acid and polyacrylate, cellulose derivatives, PVA, PVP, methylvinyl ester maleic anhydride copolymers, and natural thickeners (gel forming agents) such as gelatin, alginate, and polysaccharides. And a curing agent such as a polyvalent metal salt such as an aluminum compound, and a filler such as kaolin and titanium oxide.

박리재로는 이형 필름, 합성수지가 코팅된 이형지를 사용한다.As the release material, a release film and a release paper coated with a synthetic resin are used.

본 발명의 구성은 후술하는 실시예로부터 더욱 명확해 질 것이나 권리가 실시예에 한정되는 것은 아니다.The configuration of the present invention will become clearer from the embodiments described below, but the rights are not limited to the embodiments.

<실시예><Example>

다공성 심재로 큐프라로 직조한 면적중량 20g/m3, 두께 0.3mm의 친수성 다공성 심재를 사용하고, 그 일면에는 피부측 겔층을, 타측에는 비피부측 겔층을 각각 900g/m2, 500g/m2 씩 코팅하고, 양면에는 이형지를 라미네이트하였다.A hydrophilic porous core material of 20g / m3 area weight and 0.3mm thickness woven from cupra is used as the porous core material, and the skin side gel layer is coated on one side, and the non-skin side gel layer is coated on the other side by 900g / m2 and 500g / m2, respectively. Release paper was laminated on both surfaces.

피부측 겔층과 비피부측 겔층의 성분은 다음 [표 1]에 기재한 바와 같으며, 관능 테스트와 볼택(ball tack)치 측정을 실시하였다.The components of the skin-side gel layer and the non-skin-side gel layer were as shown in the following [Table 1], and the sensory test and the ball tack value were measured.

구 분division 피부측 겔층(100g 당)Skin side gel layer (per 100 g) 비피부측 겔층(100g 당)Non-skin side gel layer (per 100 g) 폴리아크릴산Polyacrylic acid 2.02.0 2.02.0 폴리아크릴산 나트륨Sodium polyacrylate 10.010.0 4.04.0 메타규산알루민산 마그네슘Magnesium metasilicate 0.40.4 0.60.6 글리세린glycerin 2020 20.020.0 water 67.667.6 73.473.4

1. 관능 테스트1. Sensory test

5명의 모니터에게 3cm×6cm의 시편을 만들어 좌측 뺨에는 피부측의 겔층을, 우측 뺨에는 3cm×6cm의 비피부측 겔층을 각각 붙이는 실험을 하였다. 그러나, 비피부측 겔층은 당초부터 점착성이 없도록 제조된 것으로 뺨에는 물론 그를 다루는 손가락에도 붙지 않았다. 한편, 피부측 겔층은 5명 모두에게 잘 붙었으며 시간을 측정한 결과, 10시간이 경과할 때까지 박리되지 않았다.Five monitors were prepared with 3 cm x 6 cm specimens and skin gels were attached to the left cheek and 3 cm x 6 cm non-skin gel layers were attached to the right cheek. However, the non-skin-side gel layer was prepared from the beginning so as not to be sticky, and did not adhere to the cheeks or the fingers for handling it. On the other hand, the skin-side gel layer adhered well to all five patients, and as a result of measuring the time, it did not peel off until 10 hours had elapsed.

2. 볼택(ball tack)치의 측정2. Measurement of ball tack value

볼택 장치는 JIS Z 0237 1980에 기재된 전구(轉球)장치를 사용하고, 경사각은 20°로 하였다. JIS Z 4805에 규정된 재질을 사용하였으며, JIS B 1501의 1/16에 의하여 측정한 수치의 32배수를 볼 넘버(ball number)로 하였다.The ball contact apparatus used the electric bulb apparatus of JISZ02371980, and set the inclination-angle to 20 degrees. The material prescribed | regulated to JIS Z 4805 was used, and 32 times the numerical value measured by 1/16 of JIS B 1501 was made into the ball number.

전구장치의 경사판 위에 볼택치를 측정하고자 하는 면을 위로 오게 하여 시편을 붙이고, 볼을 굴렸을 때 완전히 정지(5초 이상 움직이지 않음)한 최대치의 볼 넘버를 시험편의 볼택치로 하였다.The test piece was placed on the inclined plate of the electric bulb with the surface to be measured facing up, and the maximum ball number that completely stopped (not moving for more than 5 seconds) when the ball was rolled was used as the ball tact of the test piece.

그 결과, 피부측 겔층의 점착력은 볼택치 23으로, 비피부측 겔층의 점착력은 볼택치 5로 각각 측정되었다.As a result, the adhesive force of the skin side gel layer was measured by ball-tact 23, and the adhesive force of the non-skin side gel layer was measured by ball-tach 5, respectively.

본 발명에 의하면 피부에 잘 고정이 될 뿐만 아니라 신축성이 좋아 피부와의 일체감이 있는 친수성 겔 시트가 제공된다. 또한, 친수성 겔층이 두 개 존재함으로써 더 많은 물을 함유한다.According to the present invention, a hydrophilic gel sheet having a sense of unity with the skin as well as being well fixed to the skin and having good elasticity is provided. In addition, the presence of two hydrophilic gel layers contains more water.

Claims (3)

다공성 심재의 한쪽 면에는 점착력이 높은 친수성 겔층(피부측 겔층)을 적층하고, 다른 한쪽 면에는 점착력이 낮은 친수성 또는 친유성 겔층(비피부측 겔층)을 적층하고, 각각의 겔층을 박리재로 덮은 것을 특징으로 하는 친수성 겔 시트.A hydrophilic gel layer (skin side gel layer) having high adhesion is laminated on one side of the porous core material, and a hydrophilic or lipophilic gel layer (non-skin side gel layer) having low adhesive strength is laminated on the other side, and each gel layer is covered with a release material. Hydrophilic gel sheet, characterized in that. 제1항에 있어서, 점착력이 높은 친수성 겔층은 점착력이 볼택치 13 이상이고, 점착력이 낮은 친수성 또는 친유성 겔층은 점착력이 볼택치 10 이하인 것을 특징으로 하는 친수성 겔 시트.The hydrophilic gel sheet according to claim 1, wherein the hydrophilic gel layer having high adhesion has a balltack of 13 or more, and the hydrophilic or lipophilic gel layer having low adhesion has a adhesion of 10 or less. 제1항에 있어서, 다공성 심재가 올이 성긴 직포나 부직포, 또는 그물 형태의 직물인 것을 특징으로 하는 친수성 겔 시트.The hydrophilic gel sheet according to claim 1, wherein the porous core material is a loose woven fabric, a nonwoven fabric, or a net-shaped fabric.
KR1020020031222A 2002-06-04 2002-06-04 Hydrophilic gel sheet KR20030093615A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2543350A4 (en) * 2010-04-14 2014-04-23 Bongjo Kim Adhesive hydrous gel sheet
WO2017073826A1 (en) * 2015-10-30 2017-05-04 이태완 Super absorbent zero gel dressing for treating wound
KR101977889B1 (en) * 2017-11-15 2019-05-13 (주)이미인 Hydrogel mask pack and manufacturing method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6344519A (en) * 1986-08-12 1988-02-25 Taisho Pharmaceut Co Ltd Patch
JPS63130529A (en) * 1986-11-18 1988-06-02 Nitto Electric Ind Co Ltd Complex plaster preparation
JPS63297320A (en) * 1987-05-28 1988-12-05 Nitto Electric Ind Co Ltd Complex patch preparation
JP2000297009A (en) * 1999-04-14 2000-10-24 Sekisui Plastics Co Ltd Adhesive gel sheet for organism, cosmetic and quasi-drag using the sheet

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6344519A (en) * 1986-08-12 1988-02-25 Taisho Pharmaceut Co Ltd Patch
JPS63130529A (en) * 1986-11-18 1988-06-02 Nitto Electric Ind Co Ltd Complex plaster preparation
JPS63297320A (en) * 1987-05-28 1988-12-05 Nitto Electric Ind Co Ltd Complex patch preparation
JP2000297009A (en) * 1999-04-14 2000-10-24 Sekisui Plastics Co Ltd Adhesive gel sheet for organism, cosmetic and quasi-drag using the sheet

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2543350A4 (en) * 2010-04-14 2014-04-23 Bongjo Kim Adhesive hydrous gel sheet
WO2017073826A1 (en) * 2015-10-30 2017-05-04 이태완 Super absorbent zero gel dressing for treating wound
KR101977889B1 (en) * 2017-11-15 2019-05-13 (주)이미인 Hydrogel mask pack and manufacturing method thereof

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