KR20030086976A - An absorption pad used in absorbing liquid of food - Google Patents

An absorption pad used in absorbing liquid of food Download PDF

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Publication number
KR20030086976A
KR20030086976A KR1020030074953A KR20030074953A KR20030086976A KR 20030086976 A KR20030086976 A KR 20030086976A KR 1020030074953 A KR1020030074953 A KR 1020030074953A KR 20030074953 A KR20030074953 A KR 20030074953A KR 20030086976 A KR20030086976 A KR 20030086976A
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South Korea
Prior art keywords
absorbent
food
absorbent pad
pad
antimicrobial agent
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KR1020030074953A
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Korean (ko)
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권영원
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주식회사 디엠씨
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Priority to KR1020030074953A priority Critical patent/KR20030086976A/en
Publication of KR20030086976A publication Critical patent/KR20030086976A/en
Priority to US10/802,279 priority patent/US20050008737A1/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/26Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
    • B65D81/264Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/50Containers, packaging elements or packages, specially adapted for particular articles or materials for living organisms, articles or materials sensitive to changes of environment or atmospheric conditions, e.g. land animals, birds, fish, water plants, non-aquatic plants, flower bulbs, cut flowers or foliage

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Food Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Evolutionary Biology (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Toxicology (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Packages (AREA)

Abstract

PURPOSE: An absorbent pad for absorbing the food exudate is provided to prevent the bacteria from growing by containing the antimicrobial and to keep the food safe and sanitary for a long time by composing component harmless to human. CONSTITUTION: The absorbent pad for absorbing and keeping the food exudate comprises a top sheet(10), a bottom sheet(30) and an absorbent material layer located between the top sheet and the bottom sheet. The absorbent material layer comprises a pulp(21), an absorbent resin(23) and the antimicrobial(24). The top sheet(10) is the waterproof film or perforated mesh film of the olefin type resin. The bottom sheet(30) is non-woven fabric.

Description

식품액체 흡수용 흡수패드 {An absorption pad used in absorbing liquid of food}An absorption pad used in absorbing liquid of food}

본 발명은 식품으로부터 배출(유출)되는 액체를 흡수·저장하기 위해서 식품포장시에 식품과 식품용기 사이에 배치, 사용하는 흡수패드(이하 "식품액체 흡수용 흡수패드"라고 한다)에 관한 것이다. 보다 구체적으로 본 발명은 식품으로부터 배출되는 액체를 보다 신속하고 안전하게 흡수, 저장할 수 있으며 항균성도 우수하여 식품을 신선한 상태로 안전하게 오랫동안 보관할 수 있는 식품액체 흡수용 흡수패드에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an absorbent pad (hereinafter referred to as an "absorbent pad for absorbing food liquid") which is disposed and used between food and a food container during food packaging in order to absorb and store liquid discharged from the food. More specifically, the present invention relates to an absorption pad for absorbing food liquids, which can quickly and safely absorb and store liquids discharged from foods, and has excellent antibacterial properties, so that foods can be stored safely in a fresh state for a long time.

일반적으로 육류, 생선류, 채소류 및 과일류 등과 같은 식품은 그 세포가 파괴되면 세포내부 및 외부의 유액이 밖으로 흘러나와 식품의 신선도가 저하 된다. 식품의 신선도가 저하되면 식품의 수분 보유력이 저하되어 식품으로부터 더 많은 액체(삼출물)가 흘러나와 식품의 자가분해, 세균증식 및 변색 등이 더욱 가속화 된다.In general, foods such as meat, fish, vegetables, and fruits are destroyed when the cells are destroyed, the fluid inside and outside the cell flows out to reduce the freshness of the food. When the freshness of the food is reduced, the water retention capacity of the food is reduced, and more liquid (exudate) flows out of the food, further accelerating food self-degradation, bacterial growth and discoloration.

식품의 신선도를 유지하기 위해 흡수패드를 사용하여 식품으로부터 유출된 액체를 흡수함으로서 식품과 유출된 액체를 분리하는 방법이 널리 사용되고 있다.In order to maintain the freshness of food, a method of separating the food and the spilled liquid by absorbing the liquid spilled from the food using the absorption pad is widely used.

상기 흡수패드로 종이나 스폰지 등을 사용하는 경우 겉보기에는 식품과 식품으로부터 유출된 액체가 서로 분리된 듯이 보이지만 실제로는 이들이 서로 접촉된상태이기 때문에 식품의 신선도를 유지할 수 없다.When paper or sponge is used as the absorbent pad, the food and the liquid spilled from the food appear to be separated from each other, but in reality, the freshness of the food cannot be maintained because they are in contact with each other.

최근에는 식품과 식품으로부터 유출된 액체를 서로 분리된 상태로 유지하여 식품의 신선도를 보다 향상시킬 목적으로 유체투과성 상부시이트, 유체불투과성 하부시이트 및 이들 사이에 위치하는 흡수재료층으로 이루어진 흡수패드가 제안되어 널리 사용되고 있다.Recently, an absorbent pad made of a fluid permeable upper sheet, a fluid impermeable lower sheet, and an absorbent material layer disposed therebetween has been developed for the purpose of maintaining food and liquid spilled from the food separately from each other to improve the freshness of the food. It is proposed and widely used.

구체적인 종래 식품액체 흡수용 흡수패드로서 대한민국 공개특허 제 1992-2324호에서는 반투막과 수분흡수성 다공시이트 사이에 분말상 또는 과립상 식용당이 위치하는 흡수패드를 제안하고 있으며, 대한민국 공개특허 제 1990-3038호에서는 유체투과성 상부시이트와 유체불투과성 하부시이트 사이에 펄프 및/또는 카르복시메틸셀룰로오스와 같은 흡수재료가 배열되어 있는 흡수패드를 제안하고 있으며, 대한민국 공개특허 제 1999-87146호에서는 하나 이상의 셀을 형성하도록 결합한 상부시이트와 하부시이트를 구비하고, 상기 셀 내에는 흡수제가 위치하고, 상기 시트들 중 적어도 하나는 미세천공부들을 포함하는 액체 불침투성 재료로 형성되어 있는 흡수패드를 제안하고 있다.As a specific conventional absorbent pad for absorbing food liquids, Korean Patent Laid-Open Publication No. 1992-2324 proposes an absorbent pad in which a powdered or granular edible sugar is located between a semipermeable membrane and a water absorbent porous sheet. The present invention proposes an absorbent pad in which absorbent materials such as pulp and / or carboxymethylcellulose are arranged between the fluid permeable upper sheet and the fluid impermeable lower sheet, and Korean Patent Laid-Open No. 1999-87146 proposes to form one or more cells. It is proposed an absorbent pad having a combined upper sheet and a lower sheet, wherein an absorbent is placed in the cell and at least one of the sheets is formed of a liquid impermeable material comprising microperforations.

상기 종래의 흡수패드들은 항균성이 결여되어 식품을 오래 보관시 살모넬라살모넬라식하여 식중독을 유발하는등 위생적이지 못한 문제가 발생하였다. 또한 종래의 흡수패드들은 인체에 유해한 물질들을 외부로 배출하여 식품액체용 흡수패드로는 부적합한 문제등이 있었다.The conventional absorbent pads lack antimicrobial properties and cause unhealthy problems such as Salmonella salmonella expression when food is stored for a long time, causing food poisoning. In addition, the conventional absorbent pads are discharged to the outside harmful to the human body there was a problem, such as inappropriate pads for food liquids.

본 발명의 목적은 이와 같은 문제점을 해소하기 위해서, 키토산등의 항균제가 흡수패드의 중간층인 흡수재료층에 함유되어있으며, 인체에 유해한 물질을 외부로 배출하지 않아 보관중인 식품을 안전하게 위생적으로 오랫동안 보관 할수 있는 흡수패드를 제공하기 위한 것이다.In order to solve this problem, the present invention contains an antimicrobial agent such as chitosan in the absorbent material layer, which is an intermediate layer of the absorbent pad, and does not discharge harmful substances to the outside to safely and hygienicly store the food in storage. To provide an absorbent pad that can be.

본 발명에서는 흡수재료층(20) 내에 키토산등의 항균제를 함유시켜 살모넬라균등의 세균 증식을 효과적으로 방지 할수 있는 식품액체 흡수용 흡수패드를 제공하고자 한다. 또한, 본 발명에서는 흡수성수지(23)를 인체에 무해한 성분으로 구성하여, 위생성과 안전성이 뛰어난 식품액체 흡수용 흡수패드를 제공하고자 한다.The present invention is to provide an absorbent pad for absorbing food liquid which can effectively prevent the growth of bacteria such as Salmonella by containing an antibacterial agent such as chitosan in the absorbent material layer (20). In addition, the present invention is to provide an absorbent pad for absorbing food liquid excellent in hygiene and safety by configuring the absorbent resin 23 to harmless components.

도 1은 본 발명 흡수패드의 단면 모식도Figure 1 is a schematic cross-sectional view of the absorbent pad of the present invention

도 2는 흡수재료층(20)이 펄프, 흡수성 수지 및 항균제로 이루어진 본 발명 흡수패드의 단면 모식도2 is a schematic cross-sectional view of the absorbent pad of the present invention in which the absorbent material layer 20 is made of pulp, an absorbent resin, and an antibacterial agent.

도 3은 본 발명 흡수패드를 제조하는 공정 개략도Figure 3 is a process schematic diagram of manufacturing the absorbent pad of the present invention

※ 도면 중 주요부분에 대한 부호설명※ Explanation of code of main part of drawing

10 : 상부시이트 20 : 흡수재료층10: upper sheet 20: absorber layer

30 : 하부시이트 21 : 펄프30: lower sheet 21: pulp

12,32 : 티슈 23 : 흡수성수지12,32: tissue 23: absorbent resin

24 : 항균제 A : 하부시이트 공급로울러24: Antibacterial A: Lower sheet supply roller

B : 메쉬벨트 C : 드럼포머B: Mesh Belt C: Drumformer

D : 펄프공급기 E : 항균제 또는 흡수성수지 공급기D: Pulp Feeder E: Antibacterial or Absorbent Resin Feeder

F : 건조기 G : 핫멜트접착제 공급기F: Dryer G: Hot Melt Adhesive Feeder

H : 상부시이트 공급로울러 I : 닙로울러H: Upper sheet feed roller I: Nip roller

J : 흡수패드 권취로울러J: absorption pad winding roller

이와 같은 과제들을 달성하기 위한 본 발명의 식품액체 흡수용 흡수패드는, 상부시이트(10), 하부시이트(30) 및 이들 사이에 위치하는 흡수재료층(20)으로 구성되어 식품에서 유출되는 액체를 흡수, 저장하는 흡수패드에 있어서, 상기 흡수재료층(20)이 펄프(21), 흡수성수지(23) 및 항균제(24)로 이루어지며, 상기 상부시이트(10)가 올레핀계 수지인 방수필름 또는 천공된 메쉬 필름이고, 상기 하부시이트(30)가 부직포인 것을 특징으로 한다.Absorption pad for food liquid absorption of the present invention for achieving the above problems is composed of the upper sheet 10, the lower sheet 30 and the absorbent material layer 20 disposed therebetween to the liquid flowing out of the food In the absorbent pad for absorbing and storing, the absorbent material layer 20 is made of a pulp 21, an absorbent resin 23, and an antibacterial agent 24, and the upper sheet 10 is an olefin resin waterproof film or Perforated mesh film, characterized in that the lower sheet 30 is a nonwoven fabric.

이하, 첨부된 도면등을 통하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

먼저, 본 발명의 식품액체 흡수용 흡수패드(이하 "흡수패드"라 약칭한다)는 도 1과 같이 상부시이트(10), 하부시이트(30) 및 이들 사이에 위치하는 흡수재료층(20)으로 구성된다.First, the absorbent pad for absorbing food liquid of the present invention (hereinafter, abbreviated as "absorbent pad") is an upper sheet 10, a lower sheet 30, and an absorbent material layer 20 disposed therebetween as shown in FIG. It is composed.

상기 상부시이트(10)는 사용시 식품 바로 아래에 위치하여 식품과 직접 접촉하게 되고, 상기 하부시이트(30)는 식품용기 바닥과 접촉하게 된다. 상기 상부시이트(10)는 올레핀계 수지인 방수 필름 또는 천공된 메쉬필름이다.The upper sheet 10 is positioned directly under the food when in use, so that the upper sheet 10 is in direct contact with the food, and the lower sheet 30 is in contact with the bottom of the food container. The upper sheet 10 is a waterproof film or a perforated mesh film of olefin resin.

보다 구체적으로, 상부시이트(10)는 저밀도 폴리에틸렌수지인 LG화학(주)의 LB 5000(상품명)로 구성된다.More specifically, the upper sheet 10 is composed of LB 5000 (trade name) of LG Chemical Co., Ltd., which is a low density polyethylene resin.

상기 상부시이트(10)는 앞에서 설명한 방수 필름 또는 천공된 메쉬필름 1개층으로 형성될수도 있고, 흡수성수지가 식품쪽으로 빠져나가는 현상을 예방하기 위하여 방수 필름 또는 천공된 메쉬필름과 티슈가 적층된 2층구조로도 형성될 수 있다.The upper sheet 10 may be formed of one layer of the waterproof film or the perforated mesh film described above, and in order to prevent the absorbent resin from escaping toward the food, the two-layer structure in which the waterproof film or the perforated mesh film and the tissue are laminated. Can also be formed.

상기 하부시이트(30)는 부직포이다. 하부시이트(30)는 부직포 1개층으로 형성될 수도 있고, 흡수성 수지가 외부로 빠져나오는 것을 방지하기 위하여 부직포와 티슈가 적층된 2층구조로도 형성될수 있다.The lower sheet 30 is a nonwoven fabric. The lower sheet 30 may be formed of one layer of nonwoven fabric, or may be formed of a two-layered structure in which a nonwoven fabric and tissues are laminated to prevent the absorbent resin from coming out.

상기 부직포는 단섬유를 혼면(Blending), 타면(Opening), 소면(Carding), 접합(Bonding), 절단(Sliting) 및 권취(Winding)하는 통상의 공정으로 제조될 수 있다.The nonwoven fabric may be manufactured by a conventional process of blending short fibers, opening, carding, bonding, slitting and winding.

또한, 상기 부직포를 구성하는 섬유는 폴리에틸렌 섬유, 폴리프로필렌 섬유, 폴리에스테르 섬유, 폴리아미드 섬유, 레이온 섬유, 폴리우레탄 섬유, 면섬유, 마 섬유 또는 이들의 복합섬유 등이다.Further, the fibers constituting the nonwoven fabric are polyethylene fibers, polypropylene fibers, polyester fibers, polyamide fibers, rayon fibers, polyurethane fibers, cotton fibers, hemp fibers or composite fibers thereof.

복합섬유로는 사이드 바이 사이드(Side-by-Side) 형태의 분할형 복합섬유, 시쓰-코어(Sheath and Core) 형태의 심초형 복합섬유, 해도형(Island in the sea)의 복합섬유 등이 사용될 수 있다.As the composite fiber, side-by-side type split fiber, sheath-core type sheath type fiber and islandland in the sea fiber can be used. Can be.

상기 흡수성수지(23)로는 인체에 무해한 스톡하우젠(Stockhausen)회사의 훼이버 팩(FAVOR PAC) 100 (상품명)을 사용한다.As the absorbent resin 23, FAVOR PAC 100 (trade name) of the Stockhausen company is used.

상기 흡수성 수지(23)는 가교화된 소디움 아크릴레이트 공중합체로서, 20℃인 수용성 소디움 클로라이드 용액(고형분 : 0.2중량%)에서 24시간동안 처리시에 추출되는 수가용성분(Extractives)이 0.15중량% 이하 함유되어 사용중 인체에 유해한 물질을 배출하지 않는 장점이 있다.The water absorbent resin 23 is a crosslinked sodium acrylate copolymer, and 0.15% by weight of water-soluble extracts extracted during treatment for 24 hours in a water-soluble sodium chloride solution (solid content: 0.2% by weight) at 20 ° C. It is contained below has the advantage of not emitting substances harmful to the human body during use.

한편, 본 발명의 흡수패드중 흡수재료층(20)에 항균제가 함유되어 있다. 흡수재료층(20)내 항균제의 함량은 0.1~5중량%인것 바람직하다.On the other hand, the absorbent material layer 20 of the absorbent pad of the present invention contains an antimicrobial agent. The content of the antimicrobial agent in the absorbent material layer 20 is preferably 0.1 to 5% by weight.

항균제의 함량이 0.1 중량% 미만이면 항균성이 부족하고, 5중량%를 초과하면 제조원가가 상승하고 식용에 바람직하지 않다.If the content of the antimicrobial agent is less than 0.1% by weight, the antimicrobial activity is insufficient, and if the content of the antimicrobial agent is more than 5% by weight, the manufacturing cost is increased and it is not suitable for edible use.

항균제로는 키토산, 유기계 항균제 또는 무기계 항균제를 사용한다. 유기계 항균제로는 유기구리화합물, 유기아연화합물, 유기질소계화합물, 유기실리콘4급암모늄 등이 있고, 좀더 구체적으로는 이소티아조린계화합물이나 피리티온계 금속화합물 등이 있다. 무기계 항균제로는 제오라이트, 실리카알루미나 등의 무기담체에 은, 구리, 아연 등과 같이 항균성이 뛰어난 금속이온을 치환시킨 것을 사용한다. 더욱 바람직하기로는 키토산 또는 키토산-은 혼합액을 사용한다.As an antimicrobial agent, chitosan, an organic antimicrobial agent, or an inorganic antimicrobial agent is used. Organic antimicrobial agents include organic copper compounds, organic zinc compounds, organic nitrogen compounds, organosilicon quaternary ammonium, and more specifically, isothiazoline compounds and pyrithione metal compounds. As the inorganic antimicrobial agent, an inorganic carrier such as zeolite or silica alumina is substituted with a metal ion excellent in antimicrobial properties such as silver, copper, and zinc. More preferably, chitosan or chitosan-silver mixed liquid is used.

한편, 흡수패드의 항균성을 보다 개선하기위해서 부직포인 하부시이트(30) 내에도 상기의 항균제가 0.1~3.0중량% 함유 될수 있다.On the other hand, in order to further improve the antimicrobial properties of the absorbent pad, the antimicrobial agent may be contained in the non-woven lower sheet 30, 0.1 to 3.0% by weight.

한편, 상기 흡수재료층(20)내 펄프(21)들은 도 2와 같이 식품으로부터 유출되는 액체가 흡수패드 내로 흡수, 저장되는 방향(Z 방향)으로 배열되어 있는 것이 보다 바람직히다.On the other hand, the pulp 21 in the absorbent material layer 20 is more preferably arranged in the direction (Z direction) in which the liquid flowing out of the food is absorbed and stored in the absorbent pad, as shown in FIG.

상기와 같은 펄프 배열에 의해 식품으로부터 유출되는 액체들은 흡수재료층 (20) 내로 신속하게 흡수, 저장된다. 구체적으로 Z 방향으로 배열된 펄프는 액체흡수시 도관역활을 하여 보다 신속하게 상기 액체가 흡수재료층(20) 내로 흡수되어 안전하게 저장되도록 한다.Liquids flowing out of the food by the above pulp arrangement are rapidly absorbed and stored into the absorbent material layer 20. Specifically, the pulp arranged in the Z direction acts as a conduit when absorbing liquid, so that the liquid is absorbed into the absorbent material layer 20 more quickly and safely stored.

도 2은 흡수재료층(20)이 펄프(21), 흡수성수지(23) 및 항균제(24)로 구성되는 흡수패드의 단면도 이다. 도 2에 도시된 바와 같이 흡수성수지(23)는 Z 방향으로 배열된 펄프(21)들 사이에 랜덤하게 분산 배열되어 있다.2 is a cross-sectional view of an absorbent pad in which the absorbent material layer 20 is composed of a pulp 21, an absorbent resin 23, and an antimicrobial agent 24. As shown in FIG. 2, the absorbent resin 23 is randomly distributed between pulps 21 arranged in the Z direction.

앞에서 설명한 바와 같이 상기 흡수성수지(23)는 스톡하우젠회사의 FAVOR PAC 100(상품명) 이고, 펄프(21)로는 웨어하우져(Weyerhaeuser)회사의 제품인 PL-416 또는 NF-40I(상품명)등을 사용하는 것이 좋다.As described above, the absorbent resin 23 is FAVOR PAC 100 (trade name) of the Stockhausen company, and PL-416 or NF-40I (trade name), which is a product of the Weyerhaeuser company, is used as the pulp 21. It is good.

다음으로는, 본 발명의 흡수패드를 제조하는 방법 일례를 도 3을 통해 설명한다. 도 3은 본 발명의 흡수패드를 제조하는 일례의 공정개략도 이다.Next, an example of a method of manufacturing the absorbent pad of the present invention will be described with reference to FIG. 3. 3 is a process schematic diagram of an example of manufacturing an absorbent pad of the present invention.

먼저, 본 발명은 도 3과 같이 하부시이트 공급로울러(A)에 의해 연속적으로 공급되는 하부시이트(30) 위에 펄프공급기(D)와 항균제 또는 흡수성수지 공급기(E)가 설치된 드럼포머(C)를 이용하여 펄프(분쇄된 펄프)와 향균제 및 흡수성수지를 균일하게 분산, 배치한 다음, 계속해서 건조기(F) 내에서 건조 한다.First, the present invention provides a drum former (C) having a pulp feeder (D) and an antimicrobial or absorbent resin feeder (E) installed on the lower sheet 30 continuously supplied by the lower sheet supply roller (A) as shown in FIG. The pulp (crushed pulp), the antimicrobial agent and the absorbent resin are uniformly dispersed and placed, followed by drying in the dryer (F).

계속해서, 건조된 하부시이트(30) 상에 상부시이트 공급로울러(H)에 의해 연속적으로 공급되는 상부시이트(10)를 라미네이팅한 후 닙 로울러(I)로 가열, 압착하여 본 발명의 흡수패드를 제조한다. 이때, 본 발명은 펄프가 Z 방향으로 배열되도록 상기 드럼포머(C)의 하단부(메쉬벨트 부분)를 100-600mmHg 로 감압하는 것을 특징으로 한다.Subsequently, after laminating the upper sheet 10 continuously supplied by the upper sheet supply roller H on the dried lower sheet 30, the absorbent pad of the present invention is heated and compressed by a nip roller I. Manufacture. At this time, the present invention is characterized in that the lower end portion (mesh belt portion) of the drum former (C) to reduce the pressure to 100-600mmHg so that the pulp is arranged in the Z direction.

본 발명에 있어서 흡수패드의 각종 물성은 아래 방법으로 측정,평가 하였다.Various physical properties of the absorbent pad in the present invention were measured and evaluated by the following method.

·항균력 시험Antibacterial test

흡수패드 상에 식품(닭고기)을 3일 동안 포장된 상태로 올려놓은 다음, 상기 흡수패드를 분리하여 37℃ 항온배양기에서 24시간 배양한 후 흡수패드 내 일반 세균농도를 측정 하였다.After placing the food (chicken) on the absorbent pad in a packaged state for 3 days, the absorbent pad was separated and incubated in a 37 ° C. incubator for 24 hours, and then the general bacterial concentration in the absorbent pad was measured.

·식품(닭고기)로 부터 배출되는 액체에 대한 투과시간 측정Permeation time measurement for liquids discharged from food (chicken)

가로 7cm, 세로 20cm의 흡수패드에 식품(닭고기)로 부터 배출되는 액체 8g을 투입하여, 표면에 상기 액체가 모두 흡입되는 시간을 측정한다. 이때 수치가 낮을수록 식품액체에 대한 표면흡입력 및 투과율이 우수한 것으로 간주한다.8 g of the liquid discharged from the food (chicken) is put into an absorption pad of 7 cm in width and 20 cm in length, and the time when all the liquid is sucked on the surface is measured. The lower the value, the better the surface absorption and transmittance of the food liquid.

·식품(닭고기)로 부터 배출되는 액체에 대한 표면건조성 측정Measurement of surface dryness of liquids emitted from food (chicken)

가로 7cm, 세로 20cm의 흡수패드에 식품(닭고기)로 부터 배출되는 액체 8g을 모두 흡입시킨 다음, 상기 흡수패드를 상온에서 10분 방치한 후에 여과지 5장을 0.3psi로 가압하여 여과지에 묻어 나오는 양을 기록하여, 이때 수치가 낮을수록 표면 건조성이 우수한 것으로 간주 한다.After absorbing all 8g of liquid discharged from food (chicken) into an absorbent pad of 7cm in width and 20cm in length, and then leaving the absorbent pad at room temperature for 10 minutes, the amount of 5 sheets of filter paper to pressurize to 0.3psi Record it, and the lower the value, the better the surface dryness.

이하, 실시예 및 비교실시예를 통하여 본 발명을 더욱 구체적으로 살펴 본다. 그러나 본 발명은 하기 실시예에만 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples. However, the present invention is not limited only to the following examples.

실시예 1Example 1

항균제(키토산) 1중량%를 함유하는 부직포인 하부시이트(30)를 그의 공급로울러(A)에 의해 연속적으로 공급하면서 드럼포머(C) 상에 설치된 펄프공급기(D)와 흡수성수지 및 항균제(상표명:Chito Fix Siver) 공급기(E)로 흡수재료층(20) 100중량부 대비 펄프 35중량부, 흡수성수지 62중량부 및 항균제(상표명:ChitoFix Silver) 3중량부를 하부시이트(30) 상에 분산, 배치하여 흡수재료층(20)을 형성한 후 건조기(F) 내에서 건조한다. 이때, 상기 드럼포머(C)의 하단부를 300mmHg 로 감압하여 펄프들이 Z 방향으로 배열되도록 하였고, 흡수성수지로는 스톡하우젠 회사의 FAVOR PAC-100(상품명)을 사용 하였다. 계속해서, 건조된 흡수재료층(30) 상에 저밀도 폴리에틸렌수지(LDPE)인 LG화학 회사의 LB-5000(제품명)으로 구성된 방수필름인 상부시이트(10)를 라미네이팅한 후 닙 로울러(I)로 가열, 압착하여 흡수패드를 제조 하였다. 제조된 흡수패드의 각종 물성을 평가한 결과는 표 1과 같다.A pulp feeder (D), an absorbent resin and an antibacterial agent installed on the drum former (C) while continuously supplying the lower sheet (30), which is a nonwoven fabric containing 1% by weight of an antibacterial agent (chitosan), by its feed roller (A). : 35 parts by weight of pulp, 62 parts by weight of absorbent resin, and 3 parts by weight of an antimicrobial agent (trade name: ChitoFix Silver) were dispersed on the lower sheet 30 using a Chito Fix Siver feeder E, 100 parts by weight of the absorbent material layer 20. It arrange | positions, and forms the absorber material layer 20, and it dries in drier F. At this time, the lower end of the drum former (C) to reduce the pressure to 300mmHg so that the pulp is arranged in the Z direction, as the absorbent resin was used FAVOR PAC-100 (trade name) of the Stockhausen company. Subsequently, after laminating the upper sheet 10, which is a waterproof film composed of LG Chem's LB-5000 (product name), which is a low density polyethylene resin (LDPE) on the dried absorbent material layer 30, the nip roller (I) Heated and compressed to prepare an absorbent pad. The results of evaluating various physical properties of the manufactured absorbent pads are shown in Table 1.

실시예 2Example 2

부직포인 하부시이트(30)를 그의 공급로울러(A)에 의해 연속적으로 공급하면서 드럼포머(C) 상에 설치된 펄프공급기(D)와 흡수성수지 및 항균제 (상표명:ChitoFix Silver) 공급기(E)로 흡수재료층 100중량부 대비 펄프 35중량부,흡수성수지 61중량부 및 항균제(상표명:ChitoFix Silver) 4중량부를 하부시이트(30) 상에 분산, 배치하여 흡수재료층(20)을 형성한 후 건조기(F) 내에서 건조한다. 이때, 상기 드럼포머(C)의 하단부를 300mmHg 로 감압하여 펄프들이 Z 방향으로 배열되도록 하였고, 흡수성수지로는 스톡하우젠회사의 FAVOR PAC-100(상품명)을 사용하였다. 계속해서, 건조된 흡수재료층(20) 상에 저밀도 폴리에틸렌수지(LDPE)인 LG화학 회사의 LB-5000(제품명)으로 구성된 메쉬 필름인 상부시이트(10)를 라미네이팅한 후 닙 로울러(I)로 가열, 압착하여 흡수패드를 제조 하였다. 상기 상부시이트(10)로는 항균제(상표명:ChitoFix Silver)가 1중량% 함유된것을 사용하였다. 제조된 흡수패드의 각종 물성을 평가한 결과는 표 1과 같다.Absorbed by the pulp feeder (D) and the absorbent resin and antibacterial (trade name: ChitoFix Silver) feeder (E) installed on the drum former (C) while continuously supplying the non-woven lower sheet (30) by its feed roller (A). 35 parts by weight of pulp, 61 parts by weight of absorbent resin, and 4 parts by weight of antibacterial agent (trade name: ChitoFix Silver) are dispersed and disposed on the lower sheet 30 to form an absorbent material layer 20, and then a dryer ( F) It is dried in. At this time, the lower end of the drum former (C) was decompressed to 300mmHg so that the pulp were arranged in the Z direction, and FAVOR PAC-100 (trade name) of Stockhausen Company was used as the absorbent resin. Subsequently, after laminating the upper sheet 10, which is a mesh film composed of LG Chem's LB-5000 (product name), which is a low density polyethylene resin (LDPE), on the dried absorbent material layer 20, a nip roller (I) was used. Heated and compressed to prepare an absorbent pad. As the upper sheet 10, an antimicrobial agent (trade name: ChitoFix Silver) containing 1% by weight was used. The results of evaluating various physical properties of the manufactured absorbent pads are shown in Table 1.

실시예 3Example 3

먼저, 저밀도 폴리에틸렌수지(LDPE)인 LG화학 회사의 LB-5000(제품명)으로 구성된 메쉬필름 상에 티슈를 라미네이팅시켜 상부시이트(10)를 제조한다. 한편, 항균제(상표명:ChitoFix Silver)를 1.5 중량% 함유하는 부직포 상에 티슈를 라미네이팅시켜 하부시이트(30)를 제조한다. 다음으로는, 상기 하부시이트(30)를 그의 공급로울러(A)에 의해 티슈가 상부에 부직포가 하부에 위치하는 상태로 연속적으로 공급하면서 드럼포머(C) 상에 설치된 펄프공급기(D)와 흡수성수지 및 항균제 공급기(E)로 흡수재료층(20) 100중량부 대비 펄프 35중량부, 흡수성수지 62중량부 및 항균제(상표명:ChitoFix Silver) 3중량부 하부시이트(30) 상에 분산, 배치하여 흡수재료층(20)을 형성한 후 건조기(F) 내에서 건조한다. 이때, 상기 드럼포머(C)의하단부를 300mmHg 로 감압하여 펄프들이 Z 방향으로 배열되도록 하였고, 흡수성수지로는 스톡하우젠 회사의 FAVOR PAC-100(상품명)을 사용 하였다. 계속해서, 건조된 흡수재료층(20) 상에 상기 상부시이트(10)를 라미네이팅한 후 닙 로울러(I)로 가열, 압착하여 흡수패드를 제조 하였다. 상기 라미네이팅시 상부시이트(10)을 구성하는 천공된 메쉬필름이 상부에 위치하고 티슈가 하부에 위치하도록 상부시이트(10)를 공급하였다. 제조된 흡수패드의 각종 물성을 평가한 결과는 표 1과 같다.First, the upper sheet 10 is manufactured by laminating a tissue on a mesh film composed of LB-5000 (product name) of LG Chemical Co., Ltd., a low density polyethylene resin (LDPE). Meanwhile, the lower sheet 30 is manufactured by laminating a tissue on a nonwoven fabric containing 1.5 wt% of an antimicrobial agent (trade name: ChitoFix Silver). Next, the lower sheet 30 is absorbed with the pulp feeder D installed on the drum former C while continuously supplying the tissue with the nonwoven fabric at the upper portion thereof by means of the feed roller A thereof. The resin and antimicrobial agent (E) are dispersed and disposed on 35 parts by weight of pulp, 62 parts by weight of absorbent resin, and 3 parts by weight of antibacterial agent (trade name: ChitoFix Silver) based on 100 parts by weight of absorbent material layer (20). After the absorber material layer 20 is formed, it is dried in a dryer (F). At this time, the lower end of the drum former (C) was reduced to 300mmHg so that the pulp were arranged in the Z direction, and FAVOR PAC-100 (trade name) of Stockhausen Company was used as the absorbent resin. Subsequently, the upper sheet 10 was laminated on the dried absorbent material layer 20, and then heated and compressed with a nip roller I to prepare an absorbent pad. In the lamination, the upper sheet 10 was supplied such that the perforated mesh film constituting the upper sheet 10 was positioned at the top and the tissue was positioned at the bottom. The results of evaluating various physical properties of the manufactured absorbent pads are shown in Table 1.

비교실시예 1Comparative Example 1

먼저, 항균제가 처리되지 않은 부직포(11) 상에 티슈(12)를 라미네이팅시켜 유체투과성 상부시이트(10)를 제조한다. 한편, 방수필름(31) 상에 티슈(32)를 라미네이팅시켜 유체불투과성 하부시이트를 제조한다. 다음으로는, 상기 유체불투과성 하부시이트(30)를 그의 공급로울러(A)에 의해 티슈(32)가 상부에 방수필름(31)이 하부에 위치하는 상태로 연속적으로 공급하면서 드럼포머(C) 상에 설치된 펄프공급기(D)와 열활성섬유 공급기(E)로 유체불투과성 하부시이트(30) 100중량부 대비 펄프 30중량부와 열활성섬유 50중량부를 유체불투과성 하부시이트(30) 상에 분산, 배치하여 흡수재료층(20)을 형성한 후 건조기(F) 내에서 건조한다. 이때, 상기 드럼포머(C)의 하단부를 감압하지 않아 펄프들이 랜덤하게 배열되도록 하였고, 열활성섬유로는 폴리에틸렌수지와 폴리에스테르수지가 심초형으로 복합된 복합섬유를 사용 하였다. 계속해서, 건조된 유체불투과성 하부시이트(30) 상에 상기 유체투과성상부시이트(10)를 라미네이팅한 후 닙 로울러(I)로 가열, 압착하여 흡수패드를 제조 하였다. 상기 라미네이팅시 유체투과성 상부시이트(10)을 구성하는 부직포(11)가 상부에 위치하고 티슈(12)가 하부에 위치하도록 유체투과성 상부시이트(10)를 공급하였다. 제조된 흡수패드의 각종 물성을 평가한 결과는 표 1과 같다.First, the tissue 12 is laminated on the nonwoven fabric 11 that is not treated with the antimicrobial agent to prepare a fluid permeable upper sheet 10. Meanwhile, the tissue 32 is laminated on the waterproof film 31 to prepare a fluid impermeable lower sheet. Next, the drum former (C) while continuously supplying the fluid-impermeable lower sheet (30) to the tissue (32) while the tissue (32) is positioned at the upper portion with the waterproof film (31) at the lower portion thereof. 30 parts by weight of pulp and 50 parts by weight of thermally active fibers on the fluid-impermeable lower sheet 30 with respect to 100 parts by weight of the fluid impermeable lower sheet 30 with the pulp feeder (D) and the thermally active fiber feeder (E) installed on the substrate. It disperse | distributes and arrange | positions, the absorber material layer 20 is formed, and it dries in drier F. At this time, the lower end of the drum former (C) was not decompressed so that the pulp was randomly arranged, and as the thermally active fiber, a composite fiber in which a polyethylene resin and a polyester resin were composited into a sheath type was used. Subsequently, the fluid permeable sheet 10 was laminated on the dried fluid impermeable lower sheet 30, and then heated and compressed with a nip roller I to prepare an absorbent pad. In the lamination, the fluid permeable upper sheet 10 was supplied such that the nonwoven fabric 11 constituting the fluid permeable upper sheet 10 was positioned above and the tissue 12 was positioned below. The results of evaluating various physical properties of the manufactured absorbent pads are shown in Table 1.

비교실시예 2Comparative Example 2

먼저, 항균처리 되지 않고, 천공된 폴리프로필렌 메쉬필름(11) 상에 티슈(12)를 라미네이팅시켜 유체투과성 상부시이트(10)를 제조한다. 한편, 방수필름(31) 상에 티슈(32)를 라미네이팅시켜 유체불투과성 하부시이트를 제조한다. 다음으로는, 상기 유체불투과성 하부시이트(30)를 그의 공급로울러(A)에 의해 티슈(32)가 상부에 방수필름(31)이 하부에 위치하는 상태로 연속적으로 공급하면서 드럼포머(C) 상에 설치된 펄프공급기(D)와 흡수성수지 공급기(E)로 유체불투과성 하부시이트(30) 100중량부 대비 펄프 30중량부와 흡수성수지 50중량부를 유체불투과성 하부시이트(30) 상에 분산, 배치하여 흡수재료층(20)을 형성한 후 건조기(F) 내에서 건조한다. 이때, 상기 드럼포머(C)의 하단부를 감압하지 않아 펄프들이 랜덤하게 배열되도록 하였고, 흡수성수지로는 아크릴레이트 소듐 솔트를 사용 하였다. 계속해서, 건조된 유체불투과성 하부시이트(30) 상에 상기 유체투과성 상부시이트(10)를 라미네이팅한 후 닙 로울러(I)로 가열, 압착하여 흡수패드를 제조 하였다. 상기 라미네이팅시 유체투과성 상부시이트(10)을 구성하는 천공된 폴리프로필렌 메쉬필름(11)이 상부에 위치하고 티슈(12)가 하부에 위치하도록 유체투과성 상부시이트(10)를 공급하였다. 제조된 흡수패드의 각종 물성을 평가한 결과는 표 1과 같다.First, a non-microbial treatment, by laminating the tissue 12 on the perforated polypropylene mesh film 11 to produce a fluid permeable upper sheet (10). Meanwhile, the tissue 32 is laminated on the waterproof film 31 to prepare a fluid impermeable lower sheet. Next, the drum former (C) while continuously supplying the fluid-impermeable lower sheet (30) to the tissue (32) while the tissue (32) is positioned at the upper portion with the waterproof film (31) at the lower portion thereof. Disperse 30 parts by weight of pulp and 50 parts by weight of the absorbent resin on the fluid impermeable lower sheet 30 with respect to 100 parts by weight of the impermeable lower sheet 30 with the pulp feeder D and the absorbent resin feeder E installed thereon. It arrange | positions, and forms the absorber material layer 20, and it dries in drier F. At this time, the lower end of the drum former (C) was not decompressed so that the pulp was randomly arranged, and an absorbent resin was used as acrylate sodium salt. Subsequently, the fluid permeable upper sheet 10 was laminated on the dried fluid impermeable lower sheet 30, and then heated and compressed with a nip roller I to prepare an absorbent pad. In the laminating, the perforated polypropylene mesh film 11 constituting the fluid permeable top sheet 10 was supplied with the fluid permeable top sheet 10 such that the perforated polypropylene mesh film 11 was positioned at the top and the tissue 12 was located at the bottom. The results of evaluating various physical properties of the manufactured absorbent pads are shown in Table 1.

흡수패드 물성 측정 결과Absorption pad physical property measurement result 구 분division 실시예1Example 1 실시예2Example 2 실시예3Example 3 비교실시예1Comparative Example 1 비교실시예2Comparative Example 2 항균성 : 일반세균농도(CFU/㎖)Antibacterial: General bacterial concentration (CFU / mL) 4040 2020 3030 13,00013,000 15,00015,000 식품(닭고기)로부터 배출되는 액체에 대한 투과시간(초)Permeation time (seconds) for liquid discharged from food (chicken) 7575 7070 6060 208208 190190 식품(닭고기)로부터 배출되는 액체에 대한 표면건조성(g)Surface dryness (g) for liquids released from food (chicken) 1.61.6 1.51.5 2.02.0 3.53.5 4.44.4

본 발명은 항균성이 특히 우수하여 식품을 보다 위생적으로 오랫동안 보관 할수 있다. 또한 본 발명은 흡수패드내 흡수성수지로 부터 인체에 유해한 성분이 추출되지 않아 식품용 패드로 특히 안전하다. 또한 본 발명은 식품으로부터 유출되는 액체를 보다 신속하게 흡수, 저장 할수 있다.The present invention is particularly excellent in antimicrobial and can keep food more hygienic for a long time. In addition, the present invention is particularly safe as a food pad because no harmful components are extracted from the absorbent resin in the absorbent pad. In addition, the present invention can more quickly absorb, store the liquid flowing out of the food.

Claims (9)

상부시이트(10), 하부시이트(30) 및 이들 사이에 위치하는 흡수재료층(20)으로 구성되어 식품에서 유출되는 액체를 흡수, 저장하는 흡수패드에 있어서, 상기 흡수재료층(20)이 펄프(21), 흡수성수지(23) 및 항균제(24)로 이루어지며, 상기 상부시이트(10)가 올레핀계 수지인 방수필름 또는 천공된 메쉬 필름이고, 상기 하부시이트(30)가 부직포인 것을 특징으로 하는 식품액체 흡수용 흡수 패드.An absorbent pad comprising an upper sheet 10, a lower sheet 30, and an absorbent material layer 20 disposed therebetween, wherein the absorbent material layer 20 is a pulp. (21), the absorbent resin 23 and the antimicrobial agent 24, the upper sheet 10 is an olefin resin waterproof film or a perforated mesh film, the lower sheet 30 is characterized in that the nonwoven fabric Absorption pad for food liquid absorption. 1항에 있어서, 흡수패드(20)내 항균제(24)의 함량이 0.1~5중량% 인것을 특징으로 하는 식품액체 흡수용 흡수패드.The absorption pad of claim 1, wherein the content of the antimicrobial agent 24 in the absorbent pad 20 is 0.1 to 5% by weight. 1항에 있어서, 하부시이트(30)내에 항균제가 0.1~3.0중량% 함유되어 있는 것을 특징으로 하는 식품액체 흡수용 흡수패드.The absorbent pad for absorbing food liquid according to claim 1, wherein the lower sheet contains 0.1 to 3.0% by weight of an antimicrobial agent. 1항 또는 3항에 있어서, 항균제가 키토산, 유기계 항균제 또는 무기계 항균제인것을 특징으로 하는 식품액체 흡수용 흡수패드.The absorbent pad of claim 1 or 3, wherein the antimicrobial agent is chitosan, an organic antimicrobial agent, or an inorganic antimicrobial agent. 1항에 있어서, 흡수성수지(23)가 수가용 성분(Extractives)을 0.15중량% 이하 함유하는 가교화된 소디움 아크릴레이트 공중합체인 것을 특징으로 하는 식품액체 흡수용 흡수패드.The absorbent pad according to claim 1, wherein the absorbent resin (23) is a crosslinked sodium acrylate copolymer containing 0.15% by weight or less of water-soluble components. 1항에 있어서, 펄프(21)가 흡수패드내로 식품액체가 흡수, 저장되는 방향(Z방향)으로 배열되어 있는 것을 특징으로 하는 식품액체 흡수용 흡수패드.The absorbent pad for absorbing food liquid according to claim 1, wherein the pulp is arranged in a direction (Z direction) in which the food liquid is absorbed and stored in the absorbent pad. 1항에 있어서, 상부시이트(10)가 (i)방수필름 또는 천공된 메쉬필름과 (ii)티슈가 적층된 2층 구조인 것을 특징으로 하는 식품액체 흡수용 흡수패드.The absorbent pad according to claim 1, wherein the upper sheet (10) has a two-layer structure in which (i) a waterproof film or a perforated mesh film and (ii) a tissue is laminated. 1항에 있어서, 하부시이트(30)가 (i)부직포와 (ii)티슈가 적층된 2층 구조인 것을 특징으로 하는 식품액체 흡수용 흡수패드.The absorbent pad according to claim 1, wherein the lower sheet (30) has a two-layer structure in which (i) nonwoven fabric and (ii) tissue are laminated. 1항에 있어서, 올레핀계 수지가 저밀도 폴리에틸렌 수지인것을 특징으로 하는 식품액체 흡수용 흡수패드.The absorbing pad for absorbing food liquid according to claim 1, wherein the olefin resin is a low density polyethylene resin.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100870138B1 (en) * 2007-05-15 2008-11-24 한국식품연구원 Natural antibacterial agent for freshness preservation of blanched vegetables and Packing container comprising thereof
KR101105086B1 (en) * 2009-06-24 2012-01-16 건국대학교 산학협력단 Elastomeric bearing instrumented with load and thermo measuring sensor
KR20190119501A (en) 2018-04-12 2019-10-22 숙명여자대학교산학협력단 Antimicrobial hydrogel for preserving freshness of food
KR20210085147A (en) * 2019-12-30 2021-07-08 주식회사 대한바이오팜 Eco-superabsorbing polymer and its manufacturing method using jellyfish powder

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100870138B1 (en) * 2007-05-15 2008-11-24 한국식품연구원 Natural antibacterial agent for freshness preservation of blanched vegetables and Packing container comprising thereof
KR101105086B1 (en) * 2009-06-24 2012-01-16 건국대학교 산학협력단 Elastomeric bearing instrumented with load and thermo measuring sensor
KR20190119501A (en) 2018-04-12 2019-10-22 숙명여자대학교산학협력단 Antimicrobial hydrogel for preserving freshness of food
KR20210085147A (en) * 2019-12-30 2021-07-08 주식회사 대한바이오팜 Eco-superabsorbing polymer and its manufacturing method using jellyfish powder

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