KR20030077240A - Instrument contained high tension hollow-fiber membrane module to separate solid-liquid and the method of operation the same - Google Patents

Instrument contained high tension hollow-fiber membrane module to separate solid-liquid and the method of operation the same Download PDF

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KR20030077240A
KR20030077240A KR1020020016217A KR20020016217A KR20030077240A KR 20030077240 A KR20030077240 A KR 20030077240A KR 1020020016217 A KR1020020016217 A KR 1020020016217A KR 20020016217 A KR20020016217 A KR 20020016217A KR 20030077240 A KR20030077240 A KR 20030077240A
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South Korea
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solid
hollow fiber
fiber membrane
liquid separator
liquid
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KR1020020016217A
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Korean (ko)
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박헌휘
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박헌휘
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Publication of KR20030077240A publication Critical patent/KR20030077240A/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis

Abstract

PURPOSE: Provided are a solid-liquid separator having a hollow fiber membrane therein, which performs a role of a sedimentation tank, the separator being advantageous in ensuring treated water quality and reducing installment area of a water treatment system, and further provided is a method for operating the same separator. CONSTITUTION: The separator comprises a membrane support(8), a hollow fiber membrane(9) installed in the support(8), an air distributor(10) installed near the bottom of the support(8) and an intake pipe(12) installed at an upper portion of the support(8). The method comprises continuously inputting raw water in aeration tank to the solid-liquid separator having the hollow fiber membrane(9) therein, while discharging the water from the membrane(9) by a pump, performing suction filtration by the hollow fiber membrane(9) for 5-30 minutes, stopping the filtration for 1-10 minutes, and repeating the suction filtration and stopping, wherein the hollow fiber membrane filtrates raw water with suspended solids concentration less than 1 mg/L at flux rate of 10-50 L/m¬2/hr.

Description

고 인장강도 중공사형분리막 모듈이 내장된 고액분리장치 및 그 운전 방법{Instrument contained high tension hollow-fiber membrane module to separate solid-liquid and the method of operation the same}{Instrument contained high tension hollow-fiber membrane module to separate solid-liquid and the method of operation the same}

본 발명은 활성슬러지법의 포기조 원수(1)를 슬러지 및 부유입자의 농도가 1 mg/ℓ이하의 처리수로 여과(16)하기 위한 0.1-0.5㎛ 크기의 공극과 심한 포기에서도 끊어지지 않는 12,000-18,000 kgf/㎠의 높은 인장강도를 가진 중공사형분리막 모듈(9)이 내장된 고액분리 장치이다.In the present invention, 12,000-μm-sized pores for filtration (16) of the aeration tank raw water (1) of the activated sludge method with treated water having a concentration of sludge and suspended particles of 1 mg / l or less and 12,000 which are not broken even in severe aeration It is a solid-liquid separation device with a hollow fiber membrane module (9) having a high tensile strength of -18,000 kgf / ㎠.

보다 자세하게는 부유입자 등 고형물질이 많이 있는 포기조 원수(1)를 고액분리용기(7)로 이송하여 중공사형분리막 모듈(9)을 통하여 부유입자 농도가 최대 1 mg/ℓ 이하인 처리수(16)를 10-50 L/㎡/hr의 성능으로 여과 처리하는 고액분리장치이다.More specifically, the treated water 16 having the suspended particle concentration of up to 1 mg / l through the hollow fiber membrane module 9 is transferred to the solid-liquid separation container 7 by transferring the aeration tank raw water 1 containing a lot of solid materials such as suspended particles. It is a solid-liquid separator for filtration at a performance of 10-50 L / ㎡ / hr.

일반적으로 활성슬러지의 포기조 원수는 침전조로 이동되어 중력에 의하여 고액분리가 이루어지며 상징수 부분은 배출되고 침전된 슬러지는 일부 폐기되고 일부는 포기조로 반송된다. 그러나 포기조의 이상현상, 즉 슬러지 벌킹 등의 침전성이 불량한 경우는 침전조로 이동한 포기조 원수가 잘 분리되지 못하고 상징수에 일부 슬러지가 포함되어 배출수의 수질이 폐수 배출기준에 부적합하게 된다.In general, the raw water of the aeration tank of activated sludge is transferred to the settling tank and solid-liquid separation is carried out by gravity, and the portion of the supernatant is discharged, and some of the precipitated sludge is discarded and some is returned to the aeration tank. However, if the abnormality of the aeration tank, ie, sludge bulking, is poor, raw water from the abandonment tank moved to the sedimentation tank cannot be separated well, and some sludge is included in the symbolic water, and the quality of the discharged water is not suitable for the wastewater discharge standard.

또 포기조의 활성슬러지의 침강성이 나뿐 경우는 침전조에서 고액분리가 잘 되지 못하므로 상징수의 수질이 배출 기준에 미치지 못하며 동시에 반송되는 활성슬러지의 양을 조절하는 데도 어려움이 많다. 이는 포기조의 활성슬러지 농도를 변화 시켜 안정된 폐수처리가 되지 못함은 물론이고 활성슬러지의 농도가 낮으므로 포기조 처리 능력도 크게 저하된다.In addition, the sedimentation of the activated sludge in the aeration tank is not good, so the solid-liquid separation in the sedimentation tank is not good, and the water quality of the supernatant water does not meet the emission standard, and at the same time, it is difficult to control the amount of activated sludge returned. This changes the concentration of activated sludge in the aeration tank to prevent stable wastewater treatment, and the concentration of the activated sludge is low, which greatly reduces the capacity of the aeration tank.

상징수에 미세한 입자나 활성슬러지가 있는 경우 2차 처리를 위하여 모래 여과재, 활성탄 필터 등의 번거로운 처리를 추가하기도 한다. 활성슬러지공정에서 고액분리를 위한 침전조는 슬러지의 침강성에 따라서 대용량의 침전조를 설치하여야 하므로 부지비용이 많이 소요되는 큰 단점이 있다.In the case of fine particles or activated sludge in the supernatant water, cumbersome treatment such as sand filter media or activated carbon filter may be added for secondary treatment. In the activated sludge process, the sedimentation tank for solid-liquid separation has a big disadvantage in that a lot of site costs are required because a large capacity sedimentation tank must be installed according to the sedimentation properties of the sludge.

본 발명 장치는 활성슬러지와 모든 입자가 제외된 처리수만 분리하여 배출시키고 활성슬러지는 포기조에 전량 반송하므로 포기조의 슬러지농도가 종래의 포기조보다 1.5 - 2배 많아지므로 포기조의 성능이 향상되고 균일하게 유지되는 장점이 있다.The apparatus of the present invention separates and discharges only the treated water from which the activated sludge and all particles are excluded, and the total amount of the activated sludge is returned to the aeration tank, so that the sludge concentration of the aeration tank is 1.5-2 times higher than that of the conventional aeration tank. It has the advantage of being.

그러므로 본 발명은 상기의 문제점을 해결하기 위해 침전조를 대신하여 포기조의 원수(1)를 고액분리용기(7)내로 이송하여 0.1-0.5㎛ 크기의 공극이 있고 높은 인장 강도를 가진 중공사형분리막 모듈(9)을 이용하여 정밀 여과 특성으로 부유물질이 제거된 처리수를 10-50L/㎡/hr의 성능으로 여과 배출(16)하여 침전조의 기능을 대신함으로 처리수의 수질을 항상 일정하게 보증하고 넓은 침전조의 부지를 없애므로 공간적 문제를 해결하고 포기조의 운전 이상에서 발생하는 슬러지 벌킹 문제해결과 고액분리장치에서 분리막으로 분리된 활성슬러지를 전량 포기조로 반송(6)하여 포기조 내에 미생물의 농도를 높게 유지할 수 있어 처리효율을 크게 높일 수 있다.Therefore, the present invention transfers the raw water (1) of the aeration tank in the solid-liquid separation vessel (7) in place of the settling tank to solve the above problems, the hollow fiber membrane module having a pore size of 0.1-0.5㎛ and high tensile strength ( 9) Filter water is discharged with the performance of 10-50L / ㎡ / hr to remove the suspended solids due to the precision filtration characteristics, thereby replacing the function of the sedimentation tank. It eliminates the site of the settling tank to solve the space problem and solve the sludge bulking problem caused by the operation of the aeration tank and to return the active sludge separated by the membrane from the solid-liquid separator to the aeration tank (6) to maintain high concentration of microorganisms in the aeration tank. It can greatly increase the processing efficiency.

도 1은 중공사형분리막 모듈이 내장된 고액분리장치의 개념도 이며,1 is a conceptual diagram of a solid-liquid separation device with a hollow fiber membrane module,

도 2는 고액분리장치내의 고 인장 강도의 중공사형분리막 모듈의 상세도 이다.Figure 2 is a detailed view of the high tensile strength hollow fiber membrane module in a solid-liquid separator.

- 도면의 부호 설명-Explanation of symbols in the drawings

(1) 포기조 원수(1) abandonment

(2) 유입펌프(2) inflow pump

(3) 유입라인(3) inflow line

(4) 유입구(4) inlet

(5) 유출구(5) outlet

(6) 반송 유출라인(6) Return spill line

(7) 고액분리용기(7) Solid-liquid Separation Container

(8) 중공사형분리막 모듈 지지대(8) Hollow fiber membrane module support

(9) 중공사형분리막 모듈(9) Hollow fiber membrane module

(10) 산기관(10) diffuser

(11) 배수구(11) drain

(12) 흡입라인(12) suction line

(13) 흡입라인 개폐밸브(13) Suction line shut off valve

(14) 흡입압력계(14) suction pressure gauge

(15) 흡입펌프(15) suction pump

(16) 여과처리수(16) filtered water

(17) 세정액 주입라인 개폐밸브(17) Cleaning fluid injection line on / off valve

(18) 세정액 주입 압력계(18) cleaning liquid injection pressure gauge

(19) 세정액 주입라인(19) Cleaning solution injection line

(20) 세정액 주입펌프(20) Cleaning liquid injection pump

(21) 세정액 저장탱크(21) Cleaning solution storage tank

(22) 공기주입라인(22) Air injection line

(23) 송풍기23 blower

(24) 컨트롤 박스(24) control box

(25) 컨트롤 센서 라인25 control sensor lines

본 발명은 0.1-0.5㎛ 크기의 공극과 12,000-18,000 kgf/㎠의 높은 인장강도를 가진 중공사형 분리막 모듈(9)이 내장된 고액분리 장치(7)로서 포기조 원수(1)를 펌프(2)를 이용하여 이송라인(3)을 통해 고액분리장치(7)의 유입구(4)로 유입(3)시키고, 포기조 원수(1)가 고액분리장치(7) 유출구(5) 수위까지 채워지고 포기조 원수(1)는 유출구(5) 밖으로 반송라인(6)을 통하여 포기조로 반송된다. 포기조 원수(1)가 고액분리장치(7)로 유입(3)과 유출(6)이 연속적으로 일어나는 동시에 고액분리장치(7) 내에 장착된 중공사형 분리막 모듈(9)을 이용하여 포기조 원수의 슬러지와 부유물질을 분리한 처리수를 포기조 원수의 수질에 따라서 10-50L/㎡/hr 의 성능으로 생산하는데, 고액분리 효과를 높이기 위하여 컨트롤 박스(24)의 조작으로 10-35cmHg의 흡입압력(14)이 되도록 흡입펌프(15)의 가동시간을 5분에서 30분으로 정지시간을 1분에서 10분으로 지정하여 반복 작동하게 한다. 중공사형분리막 모듈 지지대(8) 하부에 장착된 산기관(10)은 송풍기(23)에 의해 주입된 공기를 1-3mm의 공기방울을 발생시켜 고액분리장치(7)내의 포기조 원수(1)가 충분히 혼합 될 수 있도록 하며, 슬러지 및 부유입자가 중공사형 분리막 모듈(9) 외부 표면에 부착되어 투과 처리 성능의 감소(16) 및 흡입압력(14)의 상승을 억제시키게 한다. 흡입압력(14)이 35cmHg 이상으로 증가하면 컨트롤 박스(24)의 센서라인(25)에 의해 흡입펌프(15)의 가동이 멈추고 흡입라인(12) 개폐밸브(13)가 잠기게 된다. 동시에 세정액 주입라인(19)의 개폐밸브(17)가 열리고 세정액 주입펌프(20)가 가동하여 세정액 저장탱크(리)의 세정액을 0.1-0.5kgf/㎠의 압력(18)으로 10분에서 1시간 동안 세정액을 중공사형분리막 모듈(9) 내부로 주입하여 폐쇄된 공극을 열리게 하고 분리막(9)의 표면의 gel 층을 탈리시킨다. 세정액 주입이 끝나면 세정액 주입펌프(20)의 가동이 멈추고 세정액 주입라인(19) 개폐밸브(17)가 잠긴다. 동시에 흡입라인(12) 개폐밸브(13)가 열리고 흡입펌프(15)가 가동되며, 중공사형 분리막 모듈(9)은 초기 흡입압력(14)과 투과처리성능으로 여과처리(16)한다. 장시간 사용으로 상기의 자동 세정으로 투과성능이 회복되지 못하는 경우는 30분에서1시간정도로 1내지 2회 정도 고액분리장치(7)의 가동을 멈추고, 배수구(11)를 통하여 고액분리장치(7)내의 포기조 원수(1)를 포기조로 반송 한 후, 고액분리 장치(7) 내로 여과처리수(16)에 NaOCl 0.1-0.5%+NaOH 1- 5%를 혼합한 용액을 유출수(5) 수위까지 채운 후 송풍기(23)에 의하여 공기를 주입하면서(22, 10), 세정액 주입라인 펌프(20)에 의하여 0.1-0.5kgf/㎠의 압력(18)으로 세정액을 분리막 모듈(9) 내부로 주입한다. 세정 후 세정액은 포기조로 배수구(11)를 통하여 반송시키고, 고액분리장치(7)를 초기와 같이 정상 가동시킨다.The present invention is a solid-liquid separation device (7) with a hollow fiber membrane module (9) having a pore size of 0.1-0.5㎛ size and a high tensile strength of 12,000-18,000 kgf / ㎠ and pumps the aeration tank raw water (1) (2) Inlet (3) to the inlet (4) of the solid-liquid separator (7) through the transfer line (3) by using, and the aeration tank raw water (1) is filled up to the water level of the solid-liquid separator (7) outlet (5) (1) is conveyed to the aeration tank through the conveyance line 6 out of the outlet 5. Sludge of the aeration tank raw water using the hollow fiber membrane module 9 mounted in the solid-liquid separator 7 at the same time the inlet (3) and the outflow (6) occur continuously to the solid-liquid separator (7). And the treated water separated from the suspended solids are produced at the performance of 10-50L / m2 / hr depending on the quality of the raw water of the aeration tank.In order to enhance the solid-liquid separation effect, the suction box (10-35cmHg) has a suction pressure (14). The operation time of the suction pump 15 is set to 5 to 30 minutes so that the stop time is set to 1 to 10 minutes to be repeated. The diffuser 10 mounted below the hollow fiber membrane module support 8 generates air bubbles of 1-3 mm from the air injected by the blower 23, so that the aeration tank raw water 1 in the solid-liquid separator 7 is discharged. Sludge and suspended particles are attached to the outer surface of the hollow fiber membrane module 9 to suppress the decrease in permeation performance (16) and the increase in suction pressure (14). When the suction pressure 14 increases to 35 cmHg or more, the operation of the suction pump 15 is stopped by the sensor line 25 of the control box 24 and the suction line 12 opening / closing valve 13 is locked. At the same time, the opening / closing valve 17 of the cleaning liquid injection line 19 is opened and the cleaning liquid injection pump 20 is operated to open the cleaning liquid in the cleaning liquid storage tank (L) at a pressure 18 of 0.1-0.5 kgf / cm 2 for 10 minutes to 1 hour. The cleaning solution is injected into the hollow fiber membrane module 9 to open the closed pores and detach the gel layer on the surface of the membrane 9. After the injection of the cleaning liquid, the operation of the cleaning liquid injection pump 20 is stopped and the cleaning liquid injection line 19 is closed. At the same time, the suction line 12 opening / closing valve 13 is opened and the suction pump 15 is operated, and the hollow fiber membrane module 9 is filtered 16 at the initial suction pressure 14 and the permeation performance. If the permeation performance is not restored by the above automatic cleaning due to long time use, stop the operation of the solid-liquid separator (7) once or twice in about 30 minutes to 1 hour, and the solid-liquid separator (7) through the drain hole (11). After returning the raw aeration tank 1 to the aeration tank, a solution obtained by mixing NaOCl 0.1-0.5% + NaOH 1-5% with the filtered water 16 into the solid-liquid separator 7 was filled to the effluent water 5 level. After the air is injected by the blower 23 (22, 10), the cleaning liquid is injected into the membrane module 9 at a pressure 18 of 0.1-0.5 kgf / cm 2 by the cleaning liquid injection line pump 20. After washing, the washing liquid is returned to the aeration tank through the drain port 11, and the solid-liquid separator 7 is operated normally as in the initial stage.

이상의 구성 및 작용에 의하면 본 발명은 포기조의 원수를 0.1-0.5㎛ 크기의 공극을 지닌 중공사형분리막 모듈(9)이 내장된 고액분리장치(7)내로 유입되고 중공사형분리막 모듈(9)은 부유물질 농도가 1 mg/l 이하로 유지하는 처리수를 10-50L/㎡/hr의 처리성능으로 흡입 여과하여 배출(16)하고 고액분리장치(7) 밖으로 유출(6)되는 포기조 원수(1)는 다시 포기조로 반송(6)되어 포기조의 미생물 농도를 높게 유지시킴으로 처리효율을 1.5 내지 2배 증가시키고 침전조 기능을 대신함으로 침전조 설치 부지를 절감시키는 큰 효과가 있다.According to the above configuration and operation, the present invention introduces the raw water of the aeration tank into the solid-liquid separator 7 having the hollow fiber membrane module 9 having a pore size of 0.1-0.5 μm and the hollow fiber membrane module 9 is suspended. Abandoned tank raw water (1), which is discharged by suction filtration (16) and discharged (6) out of the solid-liquid separator (7) with a treatment performance of 10-50 L / m2 / hr to maintain a substance concentration of 1 mg / l or less. 6 is returned to the aeration tank again to maintain a high concentration of microorganisms in the aeration tank to increase the treatment efficiency 1.5 to 2 times and has a great effect of reducing the settling tank installation site by replacing the settling tank function.

Claims (6)

포기조 원수를 펌프를 이용하여 고액분리장치로 연속적으로 유입과 유출을 실시하고, 고액분리장치 내에 장착된 중공사형 분리막 모듈은 5분에서 30분 흡입여과와 1분에서 10분 정지하고, 내장된 중공사형분리막은 흡입펌프에 의해 포기조 원수 중의 부유입자의 농도가 1 mg/l 이하인 처리수를 10-50L/㎡/hr의 투과처지성능으로 여과 처리하는 것으로 구성됨을 특징으로 하는 고액분리장치.The inlet and outlet water of the aeration tank is continuously inflowed and outflowed into the solid-liquid separator using the pump, and the hollow fiber membrane module mounted in the solid-liquid separator is stopped for 5 to 30 minutes by suction suction and 1 to 10 minutes. Sand-type separation membrane is a solid-liquid separation device, characterized in that by the suction pump to filter the treated water having a concentration of suspended particles in the aeration tank raw water of 1 mg / l or less with a permeation performance of 10-50L / ㎡ / hr. 청구항 1항에 있어서, 중공사형분리막의 기공의 크기는 0.1-0.5㎛로 구성됨을 특징으로 하는 고액분리장치.The solid-liquid separation device of claim 1, wherein the pore size of the hollow fiber separation membrane is 0.1-0.5 µm. 청구항 1항에 있어서, 중공사형 분리막의 인장강도는 12,000-18,000kgf/㎠를 갖는 것을 특징으로 하는 고액분리장치.The solid-liquid separator of claim 1, wherein the hollow fiber separator has a tensile strength of 12,000-18,000 kgf / cm 2. 청구항 1항에 있어서, 중공사형 분리막의 처리성능은 10-35cmHg의 흡입압력에서 10-50L/㎡/hr를 갖는 것을 특징으로 하는 고액분리장치.The solid-liquid separator according to claim 1, wherein the hollow fiber membrane has a processing performance of 10-50 L / m 2 / hr at a suction pressure of 10-35 cmHg. 청구항 1항에 있어서, 중공사형분리막 지지대 하부에 장착된 산기관은 송풍기에 의해 주입된 공기를 1-3mm의 공기방울을 발생시켜 중공사형 분리막의 외부표면에 부유물질의 부착을 억제하는 것을 특징으로 하는 고액분리장치According to claim 1, The diffuser mounted below the hollow fiber membrane supporter is characterized in that the air injected by the blower generates 1-3mm of air bubbles to suppress the adhesion of suspended matter to the outer surface of the hollow fiber membrane Solid-liquid separator 청구항 1에 있어서, 흡입압력이 35 cmHg 이상으로 증가하면 0.1-0.5kgf/㎠의 압력으로 30분에서 1시간 동안 세정액을 중공사형분리막 내부로 주입하여 분리막을 세척하고, 세정액의 주입이 끝나면 흡입펌프가 가동되어 여과 처리가 시작되는 것이 자동으로 운전되는 것을 특징으로 하는 고액분리장치.The method according to claim 1, when the suction pressure is increased to more than 35 cmHg injection of the cleaning solution into the hollow fiber membrane for 30 minutes to 1 hour at a pressure of 0.1-0.5kgf / ㎠ to wash the separation membrane, the suction pump is finished The solid-liquid separation device, characterized in that the operation is automatically started to operate the filtration process.
KR1020020016217A 2002-03-25 2002-03-25 Instrument contained high tension hollow-fiber membrane module to separate solid-liquid and the method of operation the same KR20030077240A (en)

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CN101934200A (en) * 2009-12-24 2011-01-05 北京碧水源科技股份有限公司 Method for cleaning hollow fiber membrane
KR101503887B1 (en) * 2014-07-25 2015-03-20 박경숙 High degree and energy reduction type process system of wasted water using membrane tank

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JPH0924251A (en) * 1995-07-11 1997-01-28 Mitsubishi Rayon Co Ltd Filter and operating method thereof
JPH0938472A (en) * 1995-07-28 1997-02-10 Mitsubishi Rayon Co Ltd Waste liquid treatment and waste liquid treating system
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101934200A (en) * 2009-12-24 2011-01-05 北京碧水源科技股份有限公司 Method for cleaning hollow fiber membrane
KR101503887B1 (en) * 2014-07-25 2015-03-20 박경숙 High degree and energy reduction type process system of wasted water using membrane tank

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