KR20030058525A - A pork sirloin-ham using curing agent containing vegetable tenderizer and process for preparation thereof - Google Patents

A pork sirloin-ham using curing agent containing vegetable tenderizer and process for preparation thereof Download PDF

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KR20030058525A
KR20030058525A KR1020010088982A KR20010088982A KR20030058525A KR 20030058525 A KR20030058525 A KR 20030058525A KR 1020010088982 A KR1020010088982 A KR 1020010088982A KR 20010088982 A KR20010088982 A KR 20010088982A KR 20030058525 A KR20030058525 A KR 20030058525A
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lyophilized
ham
powder
parts
kiwi
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KR100430078B1 (en
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민중석
김일석
이상옥
장애라
이무하
최일신
김강식
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사단법인 한국육류유통수출입협회
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/60Comminuted or emulsified meat products, e.g. sausages; Reformed meat from comminuted meat product
    • A23L13/65Sausages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/40Meat products; Meat meal; Preparation or treatment thereof containing additives
    • A23L13/42Additives other than enzymes or microorganisms in meat products or meat meals
    • A23L13/426Addition of proteins, carbohydrates or fibrous material from vegetable origin other than sugars or sugar alcohols
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/70Tenderised or flavoured meat pieces; Macerating or marinating solutions specially adapted therefor
    • A23L13/72Tenderised or flavoured meat pieces; Macerating or marinating solutions specially adapted therefor using additives, e.g. by injection of solutions
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2200/00Function of food ingredients
    • A23V2200/20Ingredients acting on or related to the structure
    • A23V2200/24Tenderizing

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nutrition Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Molecular Biology (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

PURPOSE: A method of preparing pork sirloin ham by adding an optimum concentration of a natural tendering agent to a curing agent and then injecting them to pork sirloin ham is provided. Therefore, the product has soft and smooth texture without adversely affecting a taste and flavor. CONSTITUTION: To produce pork sirloin ham, 3 to 10 parts by weight of a natural tendering agent is added to 100 parts by weight of a curing agent to adjust the pH of the curing agent to 4.5 to 5.5 and then injected into pork sirloin ham. The pork sirloin ham has improved softness and texture by relaxation or decomposition of a cross link between a thick filament and thin filament of myofibrillar proteins.

Description

식물성 천연연화제 함유 염지제를 이용한 돼지고기 등심햄 및 그 제조방법{A pork sirloin-ham using curing agent containing vegetable tenderizer and process for preparation thereof}A pork sirloin-ham using curing agent containing vegetable tenderizer and process for preparation

본 발명은 배와 키위를 동결건조시켜 분말화한 식물성 천연연화제를 함유한 염지제를 이용하여 부드럽고 유연한 조직감을 가질 수 있는 돼지고기 등심햄의 제조방법에 관한 것이다. 더욱 상세하게는, 본 발명은 동결건조 식물성 천연연화제 분말(배, 키위)을 염지제에 일정 농도로 투입하고 이를 돼지고기 등심에 인젝션(injection)하여 텀블링(tumbling)하고 숙성시킨 후 열처리하여 관능적 품질요인의 하나인 연도와 조직감을 개선시킬 수 있는 돈육가공 식품의 제조방법에 관한 것이다.The present invention relates to a method for preparing pork sirloin ham, which can have a soft and flexible texture by using a salt containing a vegetable natural softener powdered by lyophilizing pears and kiwi. More specifically, the present invention is a lyophilized vegetable softener powder (pear, kiwi) in a certain concentration in the dyeing agent and injected into the pork loin (tuming) by tumbling (aging) and then heat treatment to the sensory quality One of the factors relates to a method of manufacturing pork processed foods that can improve the year and texture.

식육의 연도를 개선시키기 위해서는 향초, 향신료, 포도주, 식초, 배즙, 무즙 등을 전통적인 방법으로 사용해 오고 있으나, 제조공정이나 제품특성상 가공장단위에서 실제 적용은 여러 가지 문제점이 많아 지금까지 이러한 방법은 주로 양념육 제조에 부분적으로 이용되고 있는 실정으로 가공햄류 제품 제조에는 그 활용도가 없었다. 육가공 제품에 가장 널리 쓰이는 돼지고기 부위는 등심과 뒷다리살이다. 그러나 이러한 부위들은 결합조직과 근섬유(muscle fiber) 특성에 의해 햄 제조시 열처리하게 되면 결합조직의 용해도가 떨어져 연도와 조직감이 저하되어 관능적 품질특성이 떨어지는 단점이 있어 소비자의 기호도를 만족시키지 못하는 단점이 있었다.In order to improve the year of meat, vinegar, spices, wine, vinegar, pear juice, radish juice, etc. have been used in the traditional way, but due to the manufacturing process or product characteristics, the actual application in the processing plant unit has many problems. As it is partly used in manufacturing, there has been no utilization in the manufacture of processed ham products. The most widely used pork parts in meat products are sirloin and hind legs. However, these areas are disadvantageous in that the heat treatment during ham production due to the characteristics of connective tissue and muscle fiber results in poor solubility of connective tissue, resulting in poor quality and texture, resulting in poor sensory quality characteristics. there was.

본 발명자들은 이러한 문제점들을 해결하기 위해 식물성 천연연화제, 즉 배와 키위를 세척한 후 껍질을 벗기거나 또는 껍질을 포함한 상태 그대로 각각 세절하여 동결건조시키고 분말화하여 일정 농도별 및 pH별로 처리시켜 근원섬유소편화지수(MFI; Myofibrillar Fragmentation Index)를 측정하고 이를 분석하여 최적농도를 구명하여 등심햄 제조시 적용시켜 상기 문제점을 해결함으로서 본 발명을 완성하였다.In order to solve these problems, the present inventors washed vegetable natural softeners, ie, pears and kiwis, and then peeled or shredded as they were, respectively, lyophilized, powdered, and treated by a certain concentration and pH to remove myofibrils. The present invention was completed by measuring the Myofibrillar Fragmentation Index (MFI) and analyzing the same to find the optimum concentration and applying it in the preparation of sirloin ham.

따라서 본 발명의 목적은 염지제에 동결건조 처리된 식물성 천연연화제분말을 일정량 투입하고 이 용액을 등심에 일정량 인젝션하여 가공처리함으로서 등심햄의 연도와 조직감을 개선시켜 관능적 품질특성을 향상시키는 제조기술과 이를 활용한 축육가공품의 제조방법을 제공하는데 있다.Accordingly, an object of the present invention is to prepare a lyophilized vegetable natural softener powder in a dyeing agent and inject a predetermined amount of the solution into the fillet to improve the sensory quality characteristics by improving the softness and texture of the sirloin ham. The present invention provides a method for manufacturing processed meat products using the same.

본 발명은 돼지고기 등심제조시 사용되는 염지제에 최적 농도의 천연연화제를 첨가하고, 이를 인젝션하여 근원섬유단백질(Myofibrillar proteins)에 있는 굵은 섬유(Thick filament)와 가는 섬유(Thin filament)사이의 교차결합(Cross link) 등을 이완 또는 분해시켜 부드럽고 유연한 조직을 가지게 함으로서 상품가치를 높일 수 있는 간편한 방법을 개발하였고, 이를 물리학적 및 관능학적 품질특성을 분석하여 평가하고 확인함으로서 완성하였다.The present invention adds a natural emollient at an optimal concentration to the dyeing agent used in making pork fillet, and injects it to cross between thick filament and thin filament in Myofibrillar proteins. We developed a simple way to increase product value by relaxing or disassembling the cross link to have a soft and flexible structure, and completed it by analyzing and evaluating physical and sensory quality characteristics.

이하, 본 발명의 구성 및 작용을 설명한다.Hereinafter, the configuration and operation of the present invention.

도 1은 본 발명의 바람직한 제조공정을 도시한 개략도이다.1 is a schematic diagram showing a preferred manufacturing process of the present invention.

본 발명은 돼지고기 등심의 연도와 조직감을 향상시키기 위해 염지제에 식물성 천연연화제 최적 배합비를 설정하는 단계; 상기 결정된 배합비율을 인젝션하여 숙성하고 가열처리, 냉각, 포장하는 단계로 구성된다.The present invention comprises the steps of setting the optimal blending ratio of the vegetable natural softener in the dyeing agent to improve the age and texture of pork fillet; It is composed of the steps of injecting and aging the determined mixture ratio, heat treatment, cooling, packaging.

본 발명에서 사용되는 돈육의 부위는 등심이 가장 바람직하나, 경우에 따라서는 안심, 목살 등의 부위를 사용할 수 있다.Pork loin is most preferably used in the present invention, but in some cases, a part such as tenderloin or neck may be used.

제 1 공정 : 식물성 천연연화제 함유 염지제의 전처리 공정First step: pretreatment of vegetable natural softener-containing dye

식염 11%, 아질산염 0.2%, 인산염 2.35%, 설탕 2.5%, 향신료 4.5%, 물 79.45%로 구성된 염지제에 동결건조시킨 배와 키위의 농도를 각각 3, 5, 10 중량부를 투입하고, 이를 고기 100에 대해 15 중량부를 인젝션하는 것이다. 이 때 바람직한 천연연화제는 껍질을 포함한 배와 키위의 동결건조분말이다. 식물성 천연연화제 함유 염지제의 최적 pH는 동결건조 배 분말은 5.0∼7.0, 동결건조 키위 분말은 4.5∼5.5이다. 또한 염지제 100에 대한 바람직한 투입비율은 동결건조 배 분말 3∼10 중량부, 동결건조 키위 분말 3 중량부이었다.3, 5 and 10 parts by weight of lyophilized pears and kiwis were added to a salt solution consisting of 11% salt, 0.2% nitrite, 2.35% phosphate, 2.5% sugar, 4.5% spices and 79.45% water. It is to inject 15 parts by weight for 100. Preferred natural emollients are lyophilized powders of pears and kiwis containing shells. The optimal pH of the vegetable softener-containing salts is 5.0-7.0 for lyophilized pear powder and 4.5-5.5 for lyophilized kiwi powder. In addition, the preferred input ratio to the dyeing agent 100 was 3 to 10 parts by weight of lyophilized pear powder and 3 parts by weight of lyophilized kiwi powder.

제 2 공정 : 등심햄의 가공공정2nd process: processing of sirloin ham

상기 제 1공정에서 천연연화제 함유 염지제가 주입된 돼지고기 등심을 텀블러(Tumbler)에 넣어 30분간 텀블링하고 5℃냉장고에서 48시간 숙성시킨 다음 열처리한다. 열처리조건은 건조(60℃·습도 20%·1시간), 훈연(60℃·습도 25%·1시간), 1차 가열(60℃·습도 99%·1시간)행한 후, 2차 가열은 등심햄의 중심온도가 72℃에 도달할 때 까지 75℃(습도 90%)에서 실시한다. 열처리 된 후 5℃냉장고에서 등심햄의 중심온도가 10℃이하가 될 때 까지 냉각시키고 Nylon/PE필름에 진공포장하여 상품화한다.In the first step, the pork fillet in which the natural softener-containing dye is injected is tumbled for 30 minutes, aged for 48 hours in a 5 ° C. refrigerator, and then heat-treated. The heat treatment conditions were drying (60 ° C, humidity 20%, 1 hour), smoking (60 ° C, humidity 25%, 1 hour), primary heating (60 ° C, humidity 99%, 1 hour), and secondary heating was performed. It is carried out at 75 ° C (90% humidity) until the core temperature of sirloin ham reaches 72 ° C. After heat treatment, cool the fillet ham in the refrigerator at 5 ℃ until the center temperature is below 10 ℃ and vacuum-pack it in Nylon / PE film.

본 발명 제품의 바람직한 제조방법은 도 1에 도시하였다.A preferred method of making the product of the invention is shown in FIG.

이하, 본 발명의 구체적인 방법을 실시예를 들어 상세히 설명하고자 하지만, 본 발명의 권리범위는 이들 실시예에만 한정되는 것은 아니다.Hereinafter, the specific method of the present invention will be described in detail with reference to Examples, but the scope of the present invention is not limited only to these Examples.

실시예 1 : 처리형태별 식물성 천연연화제의 연도증진 효과분석Example 1: Analysis of the effect of increasing the plant natural softener according to the treatment type

배와 키위를 깨끗하게 세척한 후 껍질을 벗긴것과 껍질을 함유한 것을 각각 준비하였다. 이를 미트믹서에 넣어 세절하고, -50℃에서 4시간 급속동결하고, 다시 -80℃ 동결건조기에서 72시간 완전 건조시킨 후 염지제에 투입시 용해와 분산이 용이하도록 완전 분말화하였다. 이를 증류수 100에 대해 10 중량부를 주입시켜 5℃에서 48시간 숙성시킨 후 MFI(Myofibrillar Framentation Index)를 측정하여 그 효과를 분석하였다.After washing the pears and kiwi clean, and peeled and containing the shells were prepared respectively. This was chopped into a meat mixer, rapidly frozen at -50 ° C for 4 hours, completely dried at -80 ° C in a freeze dryer for 72 hours, and then completely powdered to facilitate dissolution and dispersion when added to a dyeing agent. 10 parts by weight of 100 parts of distilled water was incubated for 48 hours at 5 ° C., and MFI (Myofibrillar Framentation Index) was measured to analyze the effect.

실험결과 표 1에서 나타낸 바와 같이 껍질이 있는 처리구가 P<0.001 수준에서 유의적으로 연도증진효과가 있었다. 따라서 가공장에서 굳이 껍질을 제거하는 공정을 거치지 않고 세척하여 그대로 동결건조시키고 이들 분말을 사용하는 것이 간편성과 실효성면에서 효과적이라는 사실을 구명하였다.Experimental results As shown in Table 1, the shelled treatments were significantly effective at increasing P <0.001. Therefore, it was found that it is effective in terms of simplicity and effectiveness to wash and freeze-dry as it is, and to use these powders without going through the process of removing the shell from the processing plant.

하기 표 1을 포함한 모든 자료의 통계처리는 SAS 통계프로그램을 이용하여 분산분석을 수행하였고, 평균간 유의성 검정은 던칸(Duncane)의 멀티플 레인지 테스트(Multiple range test)로 처리간의 결과차이를 분석하였다(P<0.05, P<0.01, P<0.001).Statistical analysis of all data including the following Table 1 was performed by analysis of variance using SAS statistical program, and the mean-to-mean significance test was analyzed by Duncan's multiple range test to analyze the result difference between treatments ( P <0.05, P <0.01, P <0.001).

천연연화제 처리 형태별 연도증진 효과분석결과(N=10)Result of Year Enhancement Effect by Type of Natural Softener (N = 10) 무처리구No treatment 처리구 1Treatment Zone 1 처리구 2Treatment 2 처리구 3Treatment Zone 3 처리구 4Treatment Zone 4 연화제 처리Softener treatment 무처리No treatment 동결건조 배 분말Lyophilized Pear Powder 동결건조 키위 분말Lyophilized Kiwi Powder 껍질제거Peel 껍질포함With shell 껍질제거Peel 껍질포함With shell 연화효과(MFI)1) Softening Effect (MFI) 1) 153.27±6.45c 153.27 ± 6.45 c 242.7±15.11b 242.7 ± 15.11 b 288.23±6.47a 288.23 ± 6.47 a 277.63±5.56a 277.63 ± 5.56 a 282.60±7.23a 282.60 ± 7.23 a 1)MFI(Myofibrillar Framentation Index) : 근원섬유소편화지수a, bP < 0.001 수준에서 유의적인 차이를 보임 1) Myofibrillar Framentation Index (MFI): Significant differences were found at myofibrillar fragmentation index a, b P <0.001.

실시예 2 : pH별 식물성 천연연화제의 연도증진 효과분석Example 2 Analysis of Soft Enhancement Effect of Vegetable Natural Softener by pH

실시예 1에서 간편성과 실효성면에서 연도증진효과가 입증된 껍질함유 배와키위의 동결건조분말의 연화제가 pH에 의한 영향 정도를 검증하기 위해 인위적으로 pH를 조정하여 그 효과를 분석하였다.In Example 1, the softening agent of the lyophilized powder of the bark and pear kiwi containing the skin proved to be effective in simplicity and effectiveness was analyzed by artificially adjusting the pH to verify the effect of pH.

동결건조된 껍질함유 배 분말의 pH는 4.7이고, 키위 분말의 pH는 3.1이어서 염지제에 첨가시 염지제의 pH를 낮출수 있고, 또한 염지액에 사용되는 첨가제의 종류와 배합비율에 의해 pH가 달라질 수 있다. 따라서 이로 인한 연도증진효과의 차이가 발생할 가능성이 있기 때문에 다양한 pH별로 MFI를 조사하였다. 증류수에 동결건조 배 분말 10%를 넣은 처리구의 pH는 5.8이었고, 동결건조 키위 분말을 10% 넣은 처리구는 4.5로 나타났다. 여기에 1N HCl과 1N NaOH를 이용하여 pH를 3, 4, 5, 6, 7로 맞춘 후, MFI의 경향을 분석한 결과가 표 2와 표 3에 나타나 있다.The pH of the lyophilized bark-containing pear powder is 4.7 and the pH of the kiwi powder is 3.1, which can lower the pH of the salting agent when added to the salting agent. Can vary. Therefore, the MFI was investigated for various pHs because there is a possibility of a difference in the year-promoting effect. The pH of the treatment group in which 10% of lyophilized pear powder was added to distilled water was 5.8, and the treatment in which 10% of lyophilized kiwi powder was added was 4.5. After adjusting the pH to 3, 4, 5, 6, and 7 using 1N HCl and 1N NaOH, the results of analyzing the trend of MFI are shown in Tables 2 and 3.

표 2에서 나타난 바와 같이 MFI측정결과 pH 3.0에서 7.0까지 연도증진에는 유의적인 차이가 나타나지 않았다. 따라서 염지액 제조시 사용되는 첨가제에 의해 pH가 변화되더라도 동결건조 배 분말의 연도증진효과에는 아무런 변화가 없음을 확인하였다. 그러나 실제 본 발명에 이용된 염지제는 식염 11%, 아질산염 0.2%, 인산염 2.35%, 설탕 2.5%, 향신료 4.5%, 물 79.45%로 구성되며 이때 염지액의 pH는 6.6이었고, 이러한 조성의 염지액 100에 대해 동결건조 배 분말을 3, 5, 10 중량부 투입시 pH는 각각 6.15, 6.00, 5.80로 나타나, 동결건조 배 분말 함유 염지제의 최적 pH는 MFI 분석결과와 종합해 볼 때 5.0∼7.0이었다.As shown in Table 2, MFI measurement showed no significant difference in the year increase from pH 3.0 to 7.0. Therefore, even if the pH was changed by the additive used in the preparation of the salt solution, it was confirmed that there was no change in the flue-improving effect of the lyophilized pear powder. However, in fact, the salting agent used in the present invention is composed of 11% salt, nitrite 0.2%, phosphate 2.35%, sugar 2.5%, spices 4.5%, water 79.45%, wherein the pH of the salt solution was 6.6, the salt solution of this composition When 3, 5, and 10 parts by weight of lyophilized pear powder was added to 100, the pH was 6.15, 6.00, and 5.80, respectively. The optimal pH of the lyophilized pear powder-containing salting agent was 5.0 to 7.0 based on the MFI analysis results. It was.

각 pH별 동결건조 배 분말의 연도증진 효과(N=6)Year Enhancement Effect of Lyophilized Pear Powder at Each pH (N = 6) 무조정구No adjustment 처리구1Treatment tool 1 처리구2Treatment 2 처리구3Processing Unit 3 처리구4Treatment tool 4 처리구5Processing 5 pHpH 5.85.8 3.03.0 4.04.0 5.05.0 6.06.0 7.07.0 MFIMFI 297.13±15.40297.13 ± 15.40 298.23±23.79298.23 ± 23.79 296.57±21.27296.57 ± 21.27 312.83±9.45312.83 ± 9.45 300.80±13.91300.80 ± 13.91 300.90±6.42300.90 ± 6.42

표 3에서 나타난 바와 같이 동결건조 키위 분말을 이용한 실험에서는 pH 무조정구와 pH 5.0로 조정한 시료가 유의적으로 높은 MFI를 나타내고 있다. 앞서 설명한 바와 같이 염지제는 식염 11%, 아질산염 0.2%, 인산염 2.35%, 설탕 2.5%, 향신료 4.5%, 물 79.45%로 구성되며 이때 염지액의 pH는 6.6이다. 여기에 동결건조 키위 분말을 염지액 100에 대해 3, 5, 10 중량부 투입시 pH는 각각 5.4, 5.0, 4.5이었다. 표 3의 MFI측정 결과 pH 4.5∼5.0에서 유의적으로 높은 결과가 나타난 점을 고려할 때 동결건조 키위 분말 활용시 염지제의 최적 pH는 4.5∼5.0사이임을 확인하였다.As shown in Table 3, in the experiment using lyophilized kiwi powder, the pH control group and the sample adjusted to pH 5.0 showed significantly high MFI. As described above, the salt is composed of 11% salt, nitrite 0.2%, phosphate 2.35%, sugar 2.5%, spices 4.5%, water 79.45%, the pH of the salt solution is 6.6. When the lyophilized kiwi powder was added to 3, 5, and 10 parts by weight of the salt solution 100, the pHs were 5.4, 5.0, and 4.5, respectively. Considering that the MFI measurement results of Table 3 showed a significantly higher result at pH 4.5-5.0, it was confirmed that the optimum pH of the salt inhibitor was between 4.5-5.0 when utilizing lyophilized kiwi powder.

각 pH별 동결건조 키위 분말의 연도증진 효과(N=6)Yearly Enhancement Effect of Freeze-Dried Kiwi Powder for Each pH (N = 6) 무조정구No adjustment 처리구1Treatment tool 1 처리구2Treatment 2 처리구3Processing Unit 3 처리구4Treatment tool 4 처리구5Processing 5 pHpH 4.54.5 3.03.0 4.04.0 5.05.0 6.06.0 7.07.0 MFIMFI 323.50±0.78a 323.50 ± 0.78 a 301.00±6.44b 301.00 ± 6.44 b 298.60±9.69b 298.60 ± 9.69 b 320.03±7.33a 320.03 ± 7.33 a 304.90±12.85b 304.90 ± 12.85 b 297.93±2.11b 297.93 ± 2.11 b a, bP < 0.01 수준에서 유의적인 차이를 보임 a, b P <0.01, significant difference

실시예 3 : 식물성 천연연화제의 최적 투입량 결정Example 3 Determination of Optimal Dose of Vegetable Natural Softener

최적 투입량을 결정하기 위해 식염 11%, 아질산염 0.2%, 인산염 2.35%, 설탕 2.5%, 향신료 4.5%, 물 79.45%로 구성된 염지제에 껍질이 함유된 배와 키위 동결건조분말을 염지제 100에 대해 각각 3, 5, 10 중량부 투입하고, 이를 고기 100에 대해 15 중량부 인젝션하여 텀블링하고 숙성시킨 후 가열처리하기전 시료를 이용하여 MFI를 측정한 결과가 표 4와 5에 나타나 있다.To determine the optimal dose, lyophilized pear and kiwi freeze-dried powders were prepared for salt 100 with salt salt consisting of 11% salt, 0.2% nitrite, 2.35% phosphate, 2.5% sugar, 4.5% spices and 79.45% water. 3, 5, and 10 parts by weight, respectively, 15 parts by weight of the injection of 100 to 100 parts by weight after tumbling and aging, the MFI was measured using a sample before heat treatment is shown in Tables 4 and 5.

표 4와 5에서 보면, 배와 키위를 첨가한 처리구의 MFI가 첨가하지 않은 대조구에 비해 유의적으로 높은 수준을 보이고 있어 염지제 100에 대해 각각 3∼10중량부 첨가 사용시 효과가 있음을 입증하였다.In Tables 4 and 5, the MFI of the pear and kiwi added treatments was significantly higher than that of the non-added control, demonstrating the effectiveness of adding 3 to 10 parts by weight of the dyeing agent 100, respectively. .

연화제로 동결건조 배 분말을 첨가한 가열전 등심의 MFI(N=3)MFI of fillet before heating with lyophilized pear powder as softener (N = 3) 대조구Control 처리구 1Treatment Zone 1 처리구 2Treatment 2 처리구 3Treatment Zone 3 연화제 농도Softener concentration 00 33 55 1010 MFI* MFI * 149.85±6.52c 149.85 ± 6.52 c 210.05±49.20b 210.05 ± 49.20 b 279.00±19.15a 279.00 ± 19.15 a 226.55±21.62ab 226.55 ± 21.62 ab *P < 0.01 * P <0.01

연화제로 동결건조 키위 분말을 첨가한 가열전 등심의 MFI(N=3)MFI (N = 3) of sirloin before heating with lyophilized kiwi powder as softener 대조구Control 처리구 1Treatment Zone 1 처리구 2Treatment 2 처리구 3Treatment Zone 3 연화제 농도Softener concentration 00 33 55 1010 MFI* MFI * 149.85±6.52b 149.85 ± 6.52 b 289.15±31.59a 289.15 ± 31.59 a 309.05±11.94a 309.05 ± 11.94 a 294.45±11.57a 294.45 ± 11.57 a *P < 0.001 * P <0.001

실시예 4 : 천연 연화제 함유 염지제 처리한 등심햄의 기계적 측정에 의한 전단력 및 조직학적 특성Example 4 Shear Force and Histological Properties by Mechanical Measurement of Fillet Ham Treated with Natural Softener-Containing Salt

가열처리한 후 연도의 개선효과를 확인하기 위하여 Warner-Bratzler 전단력(Shear force)과 조직학적 특성을 조사하였다. 조직학적인 특성은 시료를 2×2×2cm로 잘라 Instron(Universal testing machine, Model 1140, England)를 이용하여 Texture profile analysis curve를 구하여 평가하였다. 이 때 기기의 조건은 Deformation degree 67%, Crosshead speed 100mm/min 이었다.Warner-Bratzler shear force and histological characteristics were investigated to confirm the improvement of the flue after heat treatment. Histological characteristics were evaluated by cutting the sample into 2 × 2 × 2cm and obtaining a texture profile analysis curve using an Instron (Universal testing machine, Model 1140, England). At this time, the condition of the instrument was Deformation degree 67%, Crosshead speed 100mm / min.

표 6과 7은 껍질이 함유된 동결건조 배와 키위 분말을 각각 첨가한 염지액을 등심 100에 대해 15중량부 인젝션하여 제조된 등심햄의 전단력 및 조직학적 특성을 나타낸 것으로서 전단력에 있어서 대조구와 처리구사이의 차이가 매우 높은 유의성을 갖는 것으로 나타나, 이러한 결과는 동결건조 배와 키위분말을 염지제에 혼합하고 인젝션하여 등심햄 제조시 첨가하게 되면 연도에 있어서 그 효과가 매우 높게 나타나는 것을 의미한다. 이를 조직학적인 특성과 비교시 검성(전단력×응집성)과 저작성(검성×탄력성)에서도 유의적인 차이가 나타나 등심햄 섭취시 입안에서 느끼는 조직감이 대조구에 비해 상당히 부드럽고 연한 것으로 평가되었다. 따라서, 전단력 및 조직학적 특성면에서 바람직한 동결건조 배 및 키위 분말은 염지제 100에 대해 각각 3∼10 중량부이었다.Tables 6 and 7 show shear and histological characteristics of sirloin ham prepared by injecting 15 parts by weight of salt-free solution containing lyophilized pear and kiwi powder, each containing 15% by weight of sirloin. The difference between the two is shown to have a very high significance, this result means that when the lyophilized pear and kiwi powder is mixed and injected into the dyeing agent and added during the preparation of sirloin ham, the effect is very high in the year. Compared with the histological characteristics, there were significant differences in gumability (shearing strength × cohesiveness) and chewability (guminess × elasticity). Therefore, the preferred lyophilized pear and kiwi powder in terms of shear force and histological properties were 3 to 10 parts by weight, respectively, relative to the dyeing agent 100.

동결건조 배 분말 함유 염지제 처리 제조된 등심햄의 전단력 및 조직학적 특성(N=3)Shear force and histological characteristics of sirloin ham prepared with lyophilized pear powder-containing dye (N = 3) 대조구Control 처리구 1Treatment Zone 1 처리구 2Treatment 2 처리구 3Treatment Zone 3 연화제 농도Softener concentration 00 33 55 1010 전단력(kg/cm2)*** Shear force (kg / cm 2 ) *** 8.36±0.25a 8.36 ± 0.25 a 2.85±0.39c 2.85 ± 0.39 c 3.94±0.38b 3.94 ± 0.38 b 4.49±0.47b 4.49 ± 0.47 b 부착성** Adhesion ** 0.03±0.00c 0.03 ± 0.00 c 0.07±0.01ab 0.07 ± 0.01 ab 0.04±0.02bc 0.04 ± 0.02 bc 0.09±0.02a 0.09 ± 0.02 a 응집성Cohesive 0.56±0.130.56 ± 0.13 0.55±0.140.55 ± 0.14 0.48±0.120.48 ± 0.12 0.48±0.030.48 ± 0.03 탄력성Elasticity 0.74±0.080.74 ± 0.08 0.75±0.170.75 ± 0.17 0.64±0.130.64 ± 0.13 0.70±0.010.70 ± 0.01 검성** Swordsman ** 4.65±1.09a 4.65 ± 1.09 a 1.57±0.39b 1.57 ± 0.39 b 1.89±0.48b 1.89 ± 0.48 b 2.14±0.13b 2.14 ± 0.13 b 저작성* Authorship * 3.48±1.20a 3.48 ± 1.20 a 1.21±0.58b 1.21 ± 0.58 b 1.23±0.50b 1.23 ± 0.50 b 1.50±0.11b 1.50 ± 0.11 b *P < 0.05 ;**P < 0.01 ;***P < 0.001a, b, c같은 줄의 같은 문자는 유의적인 차이가 없음 * P <0.05; ** P <0.01; *** P <0.001 The same character on the same line as a, b, c has no significant difference

동결건조 키위 분말 함유 염지제 처리 제조된 등심햄의 전단력 및 조직학적 특성(N=3)Shear force and histologic characteristics of sirloin ham prepared with lyophilized kiwi powder containing salt (N = 3) 대조구Control 처리구 1Treatment Zone 1 처리구 2Treatment 2 처리구 3Treatment Zone 3 연화제 농도Softener concentration 00 33 55 1010 전단력(kg/cm2)*** Shear force (kg / cm 2 ) *** 8.36±0.25a 8.36 ± 0.25 a 3.05±0.39c 3.05 ± 0.39 c 3.50±0.37bc 3.50 ± 0.37 bc 3.69±0.48b 3.69 ± 0.48 b 부착성* Adhesion * 0.03±0.00b 0.03 ± 0.00 b 0.17±0.08a 0.17 ± 0.08 a 0.04±0.02b 0.04 ± 0.02 b 0.09±0.02b 0.09 ± 0.02 b 응집성Cohesive 0.56±0.130.56 ± 0.13 0.48±0.120.48 ± 0.12 0.49±0.120.49 ± 0.12 0.46±0.050.46 ± 0.05 탄력성Elasticity 0.74±0.080.74 ± 0.08 0.66±0.080.66 ± 0.08 0.71±0.120.71 ± 0.12 0.69±0.100.69 ± 0.10 검성*** Gladness *** 4.65±1.09a 4.65 ± 1.09 a 1.48±0.36b 1.48 ± 0.36 b 1.70±0.41b 1.70 ± 0.41 b 1.69±0.18b 1.69 ± 0.18 b 저작성** Authorship ** 3.48±1.20a 3.48 ± 1.20 a 1.00±0.35b 1.00 ± 0.35 b 1.24±0.53b 1.24 ± 0.53 b 1.17±0.29b 1.17 ± 0.29 b *P < 0.05 ;**P < 0.01 ;***P < 0.001a, b, c같은 줄의 같은 문자는 유의적인 차이가 없음 * P <0.05; ** P <0.01; *** P <0.001 The same character on the same line as a, b, c has no significant difference

실시예 5 : 천연 연화제 함유 염지제 처리한 등심햄의 관능적 품질특성Example 5 Sensory Quality Characteristics of Sirloin Ham Treated with Natural Softener-Containing Salting Agent

천연 연화제 함유 염지제를 처리하여 제조된 등심햄의 척도묘사분석(Descriptive Analysis with Scaling)결과가 표 8에 나타나 있다. 관능검사는 1∼9점 사이의 점수를 주관적으로 주도록 하였으며, 이 때 풍미와 냄새는 1∼3;약함, 4∼6;보통, 7∼9;강함, 불쾌취는 1∼3;약함, 4∼6;보통, 7∼9;강함, 연도는 1∼3;질김, 4∼6;보통, 7∼9;연함으로 점수를 주게 하였으며, 관능검사요원은 잘 훈련된 서울대학교 근육식품학연구실 20대∼30대 초반 남녀 각 7인씩 총 14명을 대상으로 실시하였다.Descriptive Analysis with Scaling results of sirloin ham prepared by treating a natural softener-containing dye are shown in Table 8. The sensory test was designed to give a subjective score between 1 and 9, with flavor and odor being 1 to 3; weak, 4 to 6, usually 7 to 9; strong, and unpleasant to 1 to 3; weak, 4 ~ 6; usually, 7-9; strong, year 1 ~ 3; toughness, 4 ~ 6, normal, 7 ~ 9; gave a score to the age, sensory test personnel 20 well-trained muscle food laboratory in Seoul National University Seventeen men and women in their early 30s were selected.

표 8에서 나타난 바와 같이, 모든 처리구에서 냄새, 풍미, 불쾌취에서는 유의적인 차이가 나타나지 않았으나 본 발명의 주가 되는 연도에서는 대조구에 비해 모든 처리구에서 높게 나타났다. 따라서, 관능적인 평가 측면에서 염지제 100에 대해 가장 바람직한 동결건조 배 분말은 3∼10 중량부이고, 키위 분말의 경우에는 배 분말 10 중량부 투입과 동일한 5.56점을 얻은 3 중량부이었다.As shown in Table 8, there was no significant difference in odor, flavor, and odor in all treatments, but in the year of the present invention, it was higher in all treatments than control. Therefore, in terms of sensory evaluation, the most preferable lyophilized pear powder for the dyeing agent 100 was 3 to 10 parts by weight, and in the case of kiwi powder, 3 parts by weight, which obtained 5.56 points equal to 10 parts by weight of pear powder.

동결건조 배 및 키위 분말 함유 염지제 처리하여 제조된 등심햄의 척도묘사분석결과Scale Descriptive Analysis of Fillet Ham Prepared by Lyophilized Pear and Kiwi Powder Containing Dyeing Agent 냄새smell 풍미zest 불쾌취Displeasure 연도* Year * 대조구Control 3.63±2.393.63 ± 2.39 5.00±2.395.00 ± 2.39 1.88±1.131.88 ± 1.13 4.25±2.25b 4.25 ± 2.25 b 처리구1Treatment tool 1 배 3%Pear 3% 4.56±1.674.56 ± 1.67 4.22±1.994.22 ± 1.99 2.33±2.182.33 ± 2.18 6.67±1.22a 6.67 ± 1.22 a 처리구2Treatment 2 배 5%5% 3.00±1.223.00 ± 1.22 3.11±1.273.11 ± 1.27 2.22±1.092.22 ± 1.09 5.22±0.83ab 5.22 ± 0.83 ab 처리구3Processing Unit 3 배 10%10% times 3.56±1.423.56 ± 1.42 3.67±1.733.67 ± 1.73 2.78±2.332.78 ± 2.33 5.56±1.33ab 5.56 ± 1.33 ab 처리구4Treatment tool 4 키위 3%Kiwi 3% 3.56±1.133.56 ± 1.13 3.44±1.673.44 ± 1.67 3.00±2.693.00 ± 2.69 5.56±1.59ab 5.56 ± 1.59 ab 처리구5Processing 5 키위 5%Kiwi 5% 2.78±1.092.78 ± 1.09 3.00±1.003.00 ± 1.00 2.44±1.242.44 ± 1.24 4.67±2.65b 4.67 ± 2.65 b 처리구6Treatment Tool 6 키위 10%Kiwi 10% 3.63±1.513.63 ± 1.51 3.38±1.193.38 ± 1.19 2.88±1.962.88 ± 1.96 5.38±2.26ab 5.38 ± 2.26 ab *P < 0.05a, b같은 칸의 같은 문자는 유의적인 차이가 없음 * There is no significant difference in the same letter in the same column as P <0.05 a, b

이상 실시예 1의 결과에서 껍질을 제거하지 않은 상태의 배와 키위를 이용하여 동결건조시킨 분말이 실효성 및 경제성 측면에서 효과적이었다.In the results of Example 1 above, the lyophilized powder using the pear and kiwi without peeling was effective in terms of effectiveness and economics.

실시예 2의 결과를 고려할 때, 동결건조 배 분말 함유 염지제의 최적 pH는 5.0∼7.0, 동결건조 키위 분말 함유 염지제의 최적 pH는 4.5∼5.0으로 나타났다. 그러나 실시예 4에서 분석된 결과를 고려할 때, 염지제 100에 대해 동결건조 키위 분말 3 중량부 첨가시(pH 5.4) 연도개선 효과가 우수한 것으로 보아 키위 분말 함유 염지제의 최적 pH는 4.5∼5.5인 것으로 확인되었다.Considering the results of Example 2, the optimum pH of the lyophilized pear powder-containing salting agent was 5.0 to 7.0, and the optimum pH of the lyophilized kiwi powder-containing salting agent was 4.5 to 5.0. However, considering the results analyzed in Example 4, the addition of 3 parts by weight of lyophilized kiwi powder to the dyeing agent 100 (pH 5.4) shows that the effect of improving the year, the optimum pH of the kiwi powder-containing dyeing agent is 4.5 to 5.5 It was confirmed.

실시예 3의 결과에서 동결건조 배와 키위 분말을 첨가한 처리구의 MFI가 첨가하지 않은 대조구에 비해 유의적으로 높은 수준을 보이고 있어 염지제 100에 대해 각각 3∼10중량부 첨가 사용시 효과가 있음이 입증되었고, 또한 실시예 4에서 나타난 가열처리된 등심햄에서의 전단력과 조직학적 특성의 결과를 고려할 때도 배 및 키위 분말 첨가수준은 염지제 100에 대해 3∼10 중량부였다. 그러나 실시예 5의 관능적인 평가에서는 동결건조 배분말의 경우 3∼10 중량부, 동결건조 키위 분말의 경우 3 중량부인 것으로 나타났다. 이상의 실시예 3∼4의 결과를 종합하여 볼 때, 염지제 100에 대한 동결건조 배 분말의 최적 투입량은 3∼10 중량부, 동결건조 키위 분말의 최적 투입량은 3 중량부인 것으로 분석되었다.In the results of Example 3, the MFI of the lyophilized pear and kiwi powder added group was significantly higher than the control group without the addition of 3-10 parts by weight of the dyeing agent 100, respectively. The pear and kiwi powder addition levels were 3 to 10 parts by weight relative to the dyeing agent 100, as demonstrated, and also considering the results of the shear force and histological properties in the heat treated sirloin shown in Example 4. However, in the sensual evaluation of Example 5, 3 to 10 parts by weight for lyophilized embryo powder and 3 parts by weight for lyophilized kiwi powder. Based on the results of the above Examples 3 to 4, it was analyzed that the optimal amount of lyophilized pear powder to the dyeing agent 100 was 3 to 10 parts by weight, and the optimal amount of lyophilized kiwi powder was 3 parts by weight.

이상, 상기 실시예를 통하여 분석한 바와 같이, 염지제에 식물성 천연연화제(배와 키위)를 일정농도 첨가하여 만들어진 천연연화염지제를 돼지고기등심에 일정량 주입하여 제조된 본 발명에 의한 등심햄은 관능검사 결과, 냄새, 풍미, 불쾌취(Off-flavor)에서는 전혀 영향을 미치지 않으면서 전단력에 있어서 그 효과가 매우 높게 나타나고 또한 등심햄 섭취시 입안에서 느끼는 조직감이 일반 등심햄에 비해 상당히 부드럽고 연한 것으로 평가되어 그 효과가 뛰어난 것이 입증되었고 비교적 간단하게 적용시킬 수 있기 때문에 식품가공분야의 산업상 매우 유용한 발명이다.As described above, as described above, the sirloin ham according to the present invention prepared by injecting a predetermined amount of a natural softening salt agent made by adding a certain amount of a vegetable natural softener (pear and kiwi) to a pork fillet in a pork fillet is As a result of sensory evaluation, the effect was very high in shear force without any influence on smell, flavor, and off-flavor. It has been evaluated and proved to be excellent, and it is a very useful invention in the food processing industry because it can be applied relatively simply.

Claims (4)

세척된 배 또는 키위를 껍질째 잘게 갈아 동결건조한 분말형 식물성 천연연화제를 염지제에 첨가한 후 등심에 인젝션하여 가공함을 특징으로 하는 돼지고기 등심햄의 제조방법Method for producing pork fillet ham, characterized in that the pear or kiwi is finely chopped and the lyophilized powdered vegetable softener is added to the dyeing agent and then injected into the sirloin for processing. 제1항에 있어서, 상기 식물성 천연연화제가 동결건조한 배 분말로서 염지제 100에 대해 3∼10 중량부를 투입하여 염지제의 pH가 5.0∼7.0되게 한 후 인젝션함을 특징으로 하는 돼지고기 등심햄의 제조방법.The method of claim 1, wherein the vegetable softener is lyophilized pear powder 3 to 10 parts by weight based on 100 of the dye, so that the pH of the salt is 5.0 to 7.0 and then injected into the pork sirloin ham. Manufacturing method. 제1항에 있어서, 상기 식물성 천연연화제가 동결건조한 키위 분말로서 염지제 100에 대해 3 중량부를 투입하여 염지제의 pH가 4.5∼5.5되게 한 후 인젝션함을 특징으로 하는 돼지고기 등심햄의 제조방법.The method of claim 1, wherein the vegetable natural softener is lyophilized kiwi powder, and 3 parts by weight of the dyeing agent is added to the salting agent 100 so that the pH of the salting agent is 4.5 to 5.5 and then injected. . 제1항 내지 제3항의 어느 하나의 항에 있어서, 돼지고기 등심 100에 대해 식물성 천연연화제로서 동결건조한 배분말 또는 키위분말 함유 염지제를 15 중량부가 되게 인젝션함을 특징으로 하는 등심햄의 제조방법.The method for preparing sirloin ham according to any one of claims 1 to 3, wherein the pork fillet 100 is injected with 15 parts by weight of a lyophilized coarse powder or a kiwi powder-containing salt as a vegetable softener. .
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