KR20030057787A - Multi-layer spunbond - Google Patents

Multi-layer spunbond Download PDF

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Publication number
KR20030057787A
KR20030057787A KR1020010087870A KR20010087870A KR20030057787A KR 20030057787 A KR20030057787 A KR 20030057787A KR 1020010087870 A KR1020010087870 A KR 1020010087870A KR 20010087870 A KR20010087870 A KR 20010087870A KR 20030057787 A KR20030057787 A KR 20030057787A
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South Korea
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nonwoven fabric
layer
spanbonded
per unit
fineness
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KR1020010087870A
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Korean (ko)
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황우창
김동욱
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도레이새한 주식회사
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Priority to KR1020010087870A priority Critical patent/KR20030057787A/en
Publication of KR20030057787A publication Critical patent/KR20030057787A/en

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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/022Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene

Abstract

PURPOSE: Multi-layer spun bond non-woven fabric is characterized by laminating non-woven fabrics different in structure and properties. The multi-layer spun bond non-woven fabric is capable of being light, intercepting sunbeam properly and controlling rearing of weeds. CONSTITUTION: The multi-layer spun bond non-woven fabric is comprised of a surface layer(1) and a back layer(3) manufactured with spun bond non-woven fabrics having 1-3 denier of fineness and a medium layer(2) manufactured with melt blown non-woven fabric having 0.01-0.1 denier of fineness. Weight per unit area is 30-60 gsm.

Description

다층스판본드 부직포{Multi-layer spunbond}Multi-layer spunbond

본 발명은 식물 성장에 필요한 햇빛을 적절하게 차단함으로서 농작물이나 과수원등의 잡초 성장억제에 유용한 다층구조의 스판본드 부직포에 관한 것이다.The present invention relates to a multi-layered spanbonded nonwoven fabric useful for inhibiting weed growth such as crops and orchards by appropriately blocking sunlight required for plant growth.

종래에는 농작물이나 과수원 등에서 잡초방지 또는 제초 방법으로 제초제를 사용하거나 멀칭 비닐을 덮어주는 방법이 흔히 사용되고 있었는데, 제초제를 사용하는 경우는 토양의 오염이나 산성화의 우려가 있고 또 토양에 잔존하여 농작물의 성장에 이로운 미생물까지 고사시키거나 제품으로 출하되는 농작물에 유입되어 인체에 나쁜 영향을 미치는 등의 문제점이 있으며, 멀칭 비닐을 사용하는 경우에는 멀칭 비닐이 토양과 대기를 격리시키므로 토양 및 농작물의 뿌리로 산소공급이 제한 받고 유익한 미생물의 배양이 억제되어 토양의 산성화가 촉진되고 농작물의 성장이 둔화되는 등의 문제점이 있다.Conventionally, a herbicide or a mulch vinyl covering method has been commonly used as a weed prevention or weeding method in crops, orchards, etc. In the case of using a herbicide, there is a risk of soil contamination or acidification. There are problems such as killing beneficial microorganisms or influxing to the crops shipped as products, and adversely affecting the human body.In the case of using mulching vinyl, the mulching vinyl isolates the soil from the air, so oxygen is used as the root of the soil and crops. There is a problem that the supply is limited and the culture of beneficial microorganisms is suppressed to promote acidification of the soil and to slow down the growth of crops.

한편, 최근에는 태양광을 차단하면서 보온성 이는 부직포를 토양의 상부에 덮어 씌우는 방법이 많이 사용되고 있으나, 일반적인 부직포를 사용하는 경우에는 그 두께가 두꺼운 편이어서 토양의 수분함량이 높아지고 그늘이 두꺼워지므로 농작물의 잔뿌리가 부직포에 뿌리를 내리게 되는 등의 폐해가 있다. 따라서 이러한 문제를 해결하기 위해 대한민국 특허공개 제 1998-32호에는 대략 3±0.2 데니어의 극미세 합성사를 사용하고 양면에 엠보싱을 처리한 0.8∼1.5mm두께의 부직포를 토양산성화 방지 및 잡초 성장 억제용 부직포로 사용하는 기술이 개시되어 있는데, 이 경우에는 부직포를 구성하는 섬유의 섬도가 3데니아 수준이기 때문에 단위 중량이 높아야 태양광을 차단할 수 있는 등의 문제점을 지닌다.On the other hand, in recent years, a lot of methods to cover the top of the soil while blocking the heat and heat insulation, but the general non-woven fabric is used because the thicker side of the thicker the moisture content of the soil and thicker shade, so Harsh roots, such as the roots of nonwovens. Therefore, in order to solve this problem, Korean Patent Publication No. 1998-32 uses a very fine synthetic yarn of approximately 3 ± 0.2 denier and 0.8-1.5 mm thick nonwoven fabric embossed on both sides to prevent soil acidification and weed growth. The use of a nonwoven fabric is disclosed. In this case, since the fineness of the fibers constituting the nonwoven fabric is about 3 denier, the unit weight must be high to block sunlight.

본 발명은 상기와 같은 문제점들을 해결하기 위하여 안출된 것으로서, 구조 및 특성이 다른 부직포를 다층으로 적층시켜 저중량으로도 태양광을 적절히 차단하여 특히 잡초의 생육을 억제하는 효과가 뛰어나 특성을 지닌 다층 스판본드 부직포를 제공하는데 그 목적이 있는 것이다.The present invention has been made to solve the above problems, multi-layered non-woven fabric having a different structure and characteristics by stacking in a multi-layer to block the sunlight properly even at low weight, especially a multi-layered span with excellent effect of inhibiting the growth of weeds Its purpose is to provide bond nonwovens.

도 1은 본 발명의 다층스판본드 부직포의 단면구조의 일예시도이다.1 is an exemplary view of a cross-sectional structure of a multi-layer span bond nonwoven fabric of the present invention.

〈도면의 주요부에 대한 부호의 설명〉<Description of the code | symbol about the principal part of drawing>

1 : 표면층 2: 중간층 3: 이면층1: Surface layer 2: Intermediate layer 3: Back layer

본 발명은 상기 목적을 달성하는 일 방법으로 표면층(1)과 이면층(3)에 사용된 스판본드층 사이에 중간층(2)으로 극세사 멜트블로운층을 적층시킨 구조, 즉 스판본드층/멜트블로운층/스판본드층의 다층 구조로 된 부직포를 개시하며, 이하에서 본 발명을 구체적으로 설명한다.The present invention has a structure in which a microfiber melt blown layer is laminated as an intermediate layer (2) between a span bond layer used for the surface layer (1) and the back layer (3), that is, a span bond layer / mel in one method of achieving the above object. A nonwoven fabric having a multilayer structure of tumbled / spanbond layers is disclosed, and the present invention will be described in detail below.

종래의 잡초 성장 억제용으로 사용되는 스판본드 부직포는 대부분 2.0∼3.0데니아 수준의 필라멘트로 구성되어 있어 효과적으로 태양광을 차단하기 위해서는 단위 면적당 중량이 60gsm이상인 비교적 무거운 중량의 제품들이 사용되었는바, 본 발명자들은 스판본드 사이에 0.01∼0.1데니아 범위의 극세사 멜트블로운을 적층시킨 구조를 개발하여 저주양으로도 효과적으로 태양광을 차단할 수 있도록 하였다.Since the spunbond nonwoven fabric used for conventional weed growth suppression is mostly composed of filaments of 2.0 to 3.0 denier level, in order to effectively block sunlight, relatively heavy weight products having a weight of 60 gsm or more per unit area have been used. They developed a structure in which microfiber melt blown in the range of 0.01 to 0.1 denier was laminated between span bonds to effectively block sunlight even with a low volume.

일반적으로 스판본드는 일정한 방사홀(Hole)크기로 구성된 구금을 통하여 필라멘트를 형성하고 냉각장치를 통하여 고체화 및 연신시키는 방법에 의해 부직포를 형성하나 멜트블로운의 경우에는 일정구금으로 폴리머가 방사될 때 강한 공기로 불어주는 극세화 시킴으로써 부직포의 조직을 조밀하게 한 것이다.In general, spunbond forms a non-woven fabric by forming a filament through a confinement of a constant spinning hole size and solidifying and stretching it through a cooling device. It is a dense nonwoven fabric by minimizing blowing with strong air.

본 발명에서 표면층(1)과 이면층(3)을 구성하는 스판본드 부직포 원료로는 용융지수(MFR)가 25∼60g/10분 범위에 있는 폴리프로필렌이 특히 유용하나 이에 한정되지는 않고 기타 합성수지들도 필요에 따라 사용될 수 있다. 또한 상기 스판본드층을 구성하는 섬유의 섬도는 대략 1∼3데니아 수준의 것을 사용하고 스판본드 부분의 단위 면적당 대략 10∼60gsm범위로 한 것을 사용하는 것이 바람직하다.In the present invention, as the spunbond nonwoven material constituting the surface layer 1 and the back layer 3, polypropylene having a melt index (MFR) in the range of 25 to 60 g / 10 minutes is particularly useful, but is not limited thereto. These can also be used as needed. In addition, the fineness of the fibers constituting the span bond layer is preferably about 1 to 3 denier, and preferably about 10 to 60 gsm per unit area of the span bond portion.

그리고, 본 발명에서 중간층(3)으로 스판본드층 사이에 적층되는 멜트블로운 부직포의 경우 그 원료로는 용융지수가 800∼1000g/10분 범위에 있는 합성수지(특히 폴리프로필렌)를 사용하는 것이 바람직하며, 또 멜트블로운층을 구성하는 섬유의 섬도는 대략 0.01∼1데니아 수준의 극미세사를 사용하며, 멜트블로운 부분의 단위면적당 중량은 1∼30gsm 범위가 바람직하다.In the present invention, in the case of the meltblown nonwoven fabric laminated between the span bond layers as the intermediate layer 3, it is preferable to use synthetic resin (especially polypropylene) having a melt index in the range of 800 to 1000 g / 10 minutes. In addition, the fineness of the fibers constituting the melt blown layer is about 0.01 to 1 denier microfiber, and the weight per unit area of the melt blown portion is preferably in the range of 1 to 30 gsm.

실로(Silo)에 저장된 합성수지는 원료계량을 하는 도싱(Dosing)으로 이송되어 일정량씩 익스트루더(Extruder)에 공급도며, 스판본드 부분에 공급된 원료는 익스트루더에서 용융 및 혼련이 되어 다수의 오리피스로 구성된 구금을 통하여 방사 되어 필라멘트화 된다. 멜트블로운 경우에는 융용된 합성수지는 구금을 통하여 방사될 때 양측면에서 강한 공기로 불어주어 극세화 시킨다. 그리고, 방사된 필라멘트는 벌집모양의 챔버를 통하여 분사되는 냉각공기에 의해 고화되고 상부에서 불어주는 공기와 컨베이어 벨트 하부에서 흡입하는 공기의 압력에 의해 연신되고 컨베이어 벨트 상에 일정한 중량으로 적층이 된다.The synthetic resin stored in the silo is transferred to a dosing for weighing raw materials and fed to the extruder by a certain amount, and the raw materials supplied to the spunbond portion are melted and kneaded in the extruder. It is filamentized by spinning through a detent consisting of an orifice. In the case of melt blown, the molten synthetic resin is blown into the air with strong air from both sides when it is spun through the mold to make it extremely fine. The radiated filaments are solidified by the cooling air injected through the honeycomb-shaped chamber and are drawn by the pressure of the air blown from the upper part and the air sucked from the lower part of the conveyor belt, and are laminated on the conveyor belt at a constant weight.

본 발명에서는 상기와 같이 제조되는 단일 또는 2 이상의 복합 스판본드 부직포를 표면층(1)과 이면층(3)으로 하고 그 사이에 중간층(2)으로 단일 또는 2 이상의 복합 멜트블로운 부직포를 넣어 적층시킨 구조의 부직포를 제조하는데, 이와같이 다층으로 형성된 웹은 역학적 특성 및 형태안정성을 부여하기 위하여 칼렌더롤(Roll) 등을 사용해 열적으로 적층 결합시킨다. 이때 칼렌더 롤의 구성은 한쪽이 본딩율이 10-19%을 가지는 엠보스롤(Embossroll)이고 다른면은 표면이 매끄러운 롤(Roll)로 구성하는 것이 좋으나, 양쪽면을 엠보스롤로 구성하는 것도 가능하다. 그리고, 상기 표면층, 이면층, 중간층은 단일의 스판본드 부직포나 멜트블로운 부직포로 구성 될 수도 있으나, 이에 한정되는 것은 아니며, 2층 이상의 복합층을 사용해 표면층(1), 이면층(3) 또는 중간층(2)이 구성될 수 있다.In the present invention, a single or two or more composite spanbonded nonwoven fabrics prepared as described above are used as the front layer (1) and the back layer (3), and a single or two or more composite meltblown nonwoven fabrics are laminated between the intermediate layer (2). A nonwoven fabric having a structure is manufactured. The multilayered web is thermally laminated and bonded using a roll roll or the like to impart mechanical properties and shape stability. At this time, the configuration of the calendar roll is preferably emboss roll (Embossroll) having a bonding rate of 10-19% and the other side is composed of rolls with smooth surfaces, but both sides may be composed of emboss rolls. Do. The surface layer, the back layer, and the intermediate layer may be composed of a single spunbond nonwoven fabric or a meltblown nonwoven fabric, but are not limited thereto. The surface layer 1, the back layer 3, or the like may be formed using two or more composite layers. The intermediate layer 2 can be constructed.

한편, 상기와 같은 구성으로 된 부직포의 최종제품의 단위면적당 중량은 대략 30∼60gsm 범위가 적당한데, 30gsm 미만이면 태양광의 투과율이 높아 효과적으로 잡초성장을 억제하기기 어려우며, 60gsm을 초과하면 저중량화의 효과가 미흡하다.On the other hand, the weight per unit area of the final product of the nonwoven fabric having the above configuration is suitable in the range of about 30 ~ 60gsm, if less than 30gsm it is difficult to effectively inhibit weed growth due to the high transmittance of sunlight, and if it exceeds 60gsm The effect is insufficient.

이하에서 실시예 및 비교실시예를 들어 본 발명을 좀 더 구체적으로 설명하며, 이때 제조된 부직포의 각종 특성치는 하기의 방법들을 사용하여 측정하였다.Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, wherein various characteristics of the manufactured nonwoven fabric were measured using the following methods.

〈인장강도〉<The tensile strength>

인장강신도기(Instron) 측정설비를 이용하여 ASTM D1682-64법에 의해 시료폭 5cm, 시료장 7.5cm의 시료편을 인장속도 300mm/min의 조건으로 분석하였다.Using a tensile strength tester (Instron) measuring equipment by using the ASTM D1682-64 method, a sample piece of 5cm in width and 7.5cm in sample length was analyzed under the condition of 300mm / min tensile speed.

〈인장신도〉〈Mt. Shinto〉

ASTM D1682-64의 방법으로 측정한 최대 인장강력시의 신도를 구하였다.The elongation at maximum tensile strength measured by the method of ASTM D1682-64 was determined.

〈두께〉<thickness>

다이알게이지(Dial gauge)를 이용하여 측정하였다.Measurement was made using a dial gauge.

〈섬도〉〈Full Island〉

현미경을 이용하여 필라멘트의 직경을 측정하였다.The diameter of the filament was measured using a microscope.

〈광투과도〉〈Light Transmittance〉

광투과도를 측정할 수 있는 설비를 이용하여 부직포를 투과하는 빛을 CCD 카메라로 측정하여 원광대비 투과한 빛의 감소 %로 나타낸다.Using the equipment that can measure the light transmittance, the light transmitted through the nonwoven fabric is measured by CCD camera, and it is expressed as% of the light transmitted through the original light.

[실시예 1]Example 1

표면층과 이면층을 구성하는 스판본드 부직포는 주원료로 용융지수(MFR) 60g/10분인 폴리프로필렌을 사용하고, 중강층을 구성하는 멜트블로운 부직포눈 주원료로 용융지수 900g/10분인 폴리프로필렌을 사용하여 하기 표 1에 나타낸바와 같은 특성을 지닌 적층 부직포를 제작하였으며, 그 물성을 평가하여 표 1에 나타내었다.The spunbond nonwoven fabric constituting the surface layer and the back layer uses polypropylene having a melt index (MFR) of 60 g / 10 minutes as the main raw material, and the polypropylene having a melt index of 900 g / 10 minutes as the main raw material of the meltblown nonwoven fabric constituting the middle steel layer. To prepare a laminated nonwoven fabric having the characteristics as shown in Table 1 below, the physical properties are shown in Table 1 to evaluate.

[실시예 2]Example 2

실시예 1에서 표 1에 나타낸 바와 같이 변혀아여, 단위 1㎡당 중량을 60g으로 하여 복합 적층 부직포를 제작하였으며, 그 물성을 평가하여 표 1에 나타내었다.As shown in Table 1 in Example 1, a composite laminated nonwoven fabric was produced with a weight of 60 g per 1 m 2, and the physical properties thereof were shown in Table 1 below.

[비교실시예 1]Comparative Example 1

실시예 1에서 표 1에 나타낸 바와 같이 변형하여 단위 1㎡당 중량을 20g으로 하여 복합 적층 부직포를 제작하였으며, 그 물성을 평가하여 표 1에 나타내었다.As shown in Table 1 in Example 1, a composite laminated nonwoven fabric was prepared with a weight of 20 g per unit of 2 m 2, and the physical properties thereof are shown in Table 1 below.

[비교실시예 2]Comparative Example 2

실시예 2에서 표 1에 나타낸 바와 같이 멜트블로운 적층시키지 않고 스판본드로만 구성하여 단위 1㎡당 중량을 60g으로 복합 적층 부직포를 제작하였으며, 그 물성을 평가하여 표 1에 나타내었다.As shown in Table 1 in Example 2, a composite laminate nonwoven fabric was produced with only 60 g of weight per 1 m 2 of the composition by spunbonding without melt blown lamination, and the physical properties thereof are shown in Table 1 below.

[표 1]TABLE 1

상기 실시예 및 비교실시예에서 확인되듯이 본 발명에 따른 다층 스판본드 부직포는 표면층과 스판본드 부직포를 사용하고 중간층에 멜트블로운 부직포를 사용하여 적층시킴에 의해 저중량으로 태양광을 적절히 차단할 수 있어 특히 잡초 성장 억제용으로 유용한 농업용 부직포이다.As can be seen from the above examples and comparative examples, the multi-layered spunbond nonwoven fabric according to the present invention can properly block sunlight at low weight by laminating the surface layer and the spunbond nonwoven fabric using a meltblown nonwoven fabric in the intermediate layer. In particular, it is an agricultural nonwoven fabric useful for inhibiting weed growth.

Claims (4)

표면층과 이면층은 섬도 1∼3데니아 수준의 스판본드 부직포로 구성되고 중간층은 섬도 0.1∼0.1데니아 수준의 멜트블로운 부직포로 구성되며, 단위 면적당 중량이 30∼60gsm범위에 있는 다층 스판본드 부직포.Multi-layered spunbond nonwoven fabric with the surface layer and the back layer composed of spanbonded nonwoven fabric with 1 ~ 3 denier degree of fineness, and the middle layer composed of meltblown nonwoven fabric with 0.1 ~ 0.1 degree of fineness with 30 ~ 60gsm per unit area. 제 1항에 있어서, 스판본드 부직포는 단위면적당 중량이 10∼60gsm범위에 있는 다층 스판본드 부직포.The multi-layer spanbonded nonwoven fabric of claim 1, wherein the spanbonded nonwoven fabric has a weight per unit area in the range of 10 to 60 gsm. 제 1항에 있어서, 멜트블로운 부직포는 단위면적당 중량이 1∼30gsm범위에 있는 다층 스판본드 부직포.The multi-layer spunbond nonwoven fabric of claim 1, wherein the meltblown nonwoven fabric has a weight per unit area in the range of 1-30 gsm. 제 1항에 있어서, 스판본드 부직포는 주원료로 용융지수 25∼60g/10분 범위에 있는 폴리프로필렌을 사용하고, 멜트블로운 부직포는 주원료료 용융지수 800∼1000g/10분 범위에 있는 폴리프로필렌을 사용한 다층 스판본드 부직포.The nonwoven fabric of claim 1 wherein the spanbonded nonwoven fabric uses polypropylene having a melt index of 25 to 60 g / 10 minutes as the main raw material, and the meltblown nonwoven fabric comprises polypropylene having a main material melt index of 800 to 1000 g / 10 minutes. Used multi-layer spanbonded nonwovens.
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KR100477954B1 (en) * 2002-07-25 2005-03-22 도레이새한 주식회사 Laminated spanbond non-woven fabric having high rewet efficiency and manufacturing method thereof
KR100742962B1 (en) * 2005-11-16 2007-07-25 도레이새한 주식회사 Polypropylene spunbond nonwoven fabric having multi-layer for mulching and manufacturing method thereof
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KR100477954B1 (en) * 2002-07-25 2005-03-22 도레이새한 주식회사 Laminated spanbond non-woven fabric having high rewet efficiency and manufacturing method thereof
KR100742962B1 (en) * 2005-11-16 2007-07-25 도레이새한 주식회사 Polypropylene spunbond nonwoven fabric having multi-layer for mulching and manufacturing method thereof
KR101221277B1 (en) * 2010-12-01 2013-01-11 도레이첨단소재 주식회사 Mutilayer spunbond nonwoven fabric including meltblown polylactic acid and preparing method thereof
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KR20230039368A (en) * 2021-09-14 2023-03-21 주식회사 휴비스 Non-woven Fabric With Excellent Moisture Adhesion And Shape Retention
WO2023195746A1 (en) * 2022-04-04 2023-10-12 도레이첨단소재 주식회사 Non-woven fabric laminate and article

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