KR20020087714A - Organic Light Emitting Diodes(OLEDs) with Guard Ring - Google Patents

Organic Light Emitting Diodes(OLEDs) with Guard Ring Download PDF

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KR20020087714A
KR20020087714A KR1020010026672A KR20010026672A KR20020087714A KR 20020087714 A KR20020087714 A KR 20020087714A KR 1020010026672 A KR1020010026672 A KR 1020010026672A KR 20010026672 A KR20010026672 A KR 20010026672A KR 20020087714 A KR20020087714 A KR 20020087714A
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light emitting
guard ring
layer
transport layer
organic light
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KR1020010026672A
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Korean (ko)
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노병규
강명구
오환술
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강명구
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/85Arrangements for extracting light from the devices
    • H10K50/856Arrangements for extracting light from the devices comprising reflective means
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Electroluminescent Light Sources (AREA)

Abstract

PURPOSE: A thin film organic electroluminescence display device is provided to achieve improved luminance and optical characteristics of organic electroluminescence display device. CONSTITUTION: An organic electroluminescence display device comprises a transparent electrode(3), a hole injection layer(4), a hole transport layer(6), a luminescence layer(5), an electron transport layer, an electron injection layer, a metal electrode and a guard ring(1). The guard ring is made of Al having a reflectivity of 60 to 85% or Ag having a reflectivity of 95% deposited into the thickness of 1200 angstrom, at the four side surfaces of a glass substrate(2), through a vacuum evaporation method.

Description

가드링을 도입한 박막 유기전계발광소자{Organic Light Emitting Diodes(OLEDs) with Guard Ring}Thin Film Organic Light Emitting Diodes with Guard Rings {Organic Light Emitting Diodes (OLEDs) with Guard Ring}

본 발명은 데이터 표시와 화상처리 및 기타분야에 사용되는 유기전계발광소자의 가드링을 사용하여 제조된 유기전계발광소자 또는 표시소자에 관한 것이다.The present invention relates to an organic light emitting display device or display device manufactured using a guard ring of an organic light emitting display device used in data display and image processing and other fields.

유기전계발광소자는 유리 기판위의 양극전극과 음극전극사이에 (1)단분자 정공수송층/단분자 발광층, (2)단분자 정공주입층/단분자 정공수송층/단분자 발광층, (3)단분자 정공수송층/단분자 발광층/단분자 전자수송층, (4)단분자 정공주입층/단분자 정공수송층/단분자 발광층/단분자 전자수송층/단분자 전자주입층, (5)고분자 정공수송층/고분자 발광층, (6)고분자 정공주입층/고분자 정공수송층/고분자 발광층/고분자 전자수송층을 포함하는 형태로 나눌 수 있다.The organic electroluminescent device is composed of (1) monolayer hole transport layer / monolayer light emitting layer, (2) monolayer hole injection layer / monolayer hole transport layer / monolayer light emitting layer between anode and cathode electrode on glass substrate, (3) Molecular hole transport layer / Molecular light emitting layer / Molecular electron transport layer, (4) Molecular hole injection layer / Single molecule hole transport layer / Single molecule light emitting layer / Single molecule electron transport layer / Single molecule electron injection layer, (5) Polymer hole transport layer / Polymer Light emitting layer, (6) It can be divided into the form containing a polymer hole injection layer / polymer hole transport layer / polymer light emitting layer / polymer electron transport layer.

이러한 종래의 유기전계발광소자는 기판을 유리로 사용하기 때문에 필연적으로 유기박막에 비해 두꺼운 유리기판의 측면으로 발광된 빛의 측면손실이 발생하여 유기전계발광소자의 중요한 특성인 휘도가 낮아지는 경향이 있어 개선되어야 할 점이 많이 있다.Since the conventional organic light emitting diode uses glass as a substrate, the side loss of light emitted toward the side of the thick glass substrate is inevitably generated compared to the organic thin film, and thus the luminance, which is an important characteristic of the organic light emitting diode, tends to be lowered. There are many things that need to be improved.

따라서, 본 발명의 목적은 휘도가 개선될 수 있는 박막의 유기전계발광소자를 제공하는 것이다.Accordingly, it is an object of the present invention to provide a thin film organic electroluminescent device whose luminance can be improved.

제1도는 가드링(guard ring)이 없는 일반적인 박막 유기전계발광소자의 구조를 개략적으로 나타내는 도면이다.FIG. 1 is a diagram schematically illustrating a structure of a general thin film organic light emitting diode having no guard ring.

제2도는 본 발명의 가드링을 도입한 박막 유기전계발광소자의 구조를 개략적으로 나타내는 도면이다.2 is a view schematically showing the structure of a thin film organic light emitting diode incorporating a guard ring of the present invention.

제3도는 가드링이 없는 경우 유기전계발광소자에서 빛의 측면 손실을 개략적으로 나타내는 도면이다.3 is a view schematically showing the side loss of the light in the organic light emitting device when there is no guard ring.

제4도는 가드링이 있는 경우 유기전계발광소자에서 빛의 측면 반사에 의해 발광에 기여하는 것을 개략적으로 나타내는 도면이다.4 is a diagram schematically illustrating the contribution of light emission by side reflection of light in an organic light emitting diode in the presence of a guard ring.

<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>

1: 가드링(guard ring)2: 유리 기판1: guard ring 2: glass substrate

3: ITO 투명전극4: 정공수송층3: ITO transparent electrode 4: hole transport layer

5: 발광층6: 전자수송층5: light emitting layer 6: electron transport layer

7: 음극전극7: cathode electrode

데이터 표시, 화상처리 및 기타분야에서 최근에 유기 전계발광소자에 관심이 집중되고 있다. 유기전계발광소자는 전계발광재료를 양극과 음극사이에 넣고, 전압을 인가하면 그 재료의 파장과 강도특성을 갖는 빛을 방출한다. 이러한 동작법은 전압을 인가하면 양극으로부터 정공이, 음극으로부터는 전자가 발광층의 발광재료에 주입되어 그 안에서 이동한 다음 재결합하면서 발광하는 것으로 사료된다. 방출된 빛은 전계발광재료의 고유한 형광스펙트럼과 거의 동일한 스펙트럼을 갖는다.Recently, attention has been focused on organic electroluminescent devices in data display, image processing and other fields. The organic electroluminescent device puts an electroluminescent material between an anode and a cathode, and emits light having a wavelength and an intensity characteristic of the material when a voltage is applied. In this method, holes are injected from the anode and electrons are injected into the light emitting material of the light emitting layer when the voltage is applied. The emitted light has a spectrum almost identical to the inherent fluorescence spectrum of the electroluminescent material.

제작된 유기전계발광소자는 기판으로 사용되는 유리의 두께 때문에 공기와 유리의 임계각이 19이상으로 발광된 빛이 측면으로 퍼져나가 휘도의 저하를 유발하는 문제점이 있다(피. 이. 버로우(P. E. Burrows)등, IEEE Tansactions on Electron Devices, Vol.44, No.8(1997)). 따라서 이러한 측면을 통해 손실이되는 빛을 가두어서 유리의 전면으로 방출되도록 유도하여 유기전계발광소자의 휘도를 크게 개선시킬 수 있도록 유리 기판의 사방 측면에 가드링(guard ring)을 도입하는 것이 바람직하다.The fabricated organic electroluminescent device, since the thickness of the glass used as a substrate, there is a problem that out becomes the critical angle of the air and the glass emits light in more than 19 light spreads laterally causing decrease in luminance (p. A. Burrows (PE Burrows et al., IEEE Tansactions on Electron Devices, Vol. 44, No. 8 (1997). Therefore, it is desirable to introduce a guard ring on all sides of the glass substrate so that the lossy light is trapped through the side to be emitted to the front surface of the glass to greatly improve the brightness of the organic light emitting display device. .

이하 본 발명에 대하여 상세히 설명한다.Hereinafter, the present invention will be described in detail.

상기의 목적을 달성하기 위하여 본 발명에서 사용되는 가드링의 재료로는 반사율일 60∼85%인 알루미늄(Al)이나 95%의 반사율을 갖는 은(Ag)을 진공증착방법으로 유리기판의 사방 측면에 1200Å 두께로 증착하여 제작한다. 이렇게 제작된 가드링에 의해 반사된 빛은 휘도를 증가시켜 밝은 주위광 조건하에서 정보를 볼 수 있는 개선된 화질을 갖는 유기전계발광소자를 제공할 수 있게 된다.In order to achieve the above object, the material of the guard ring used in the present invention includes aluminum (Al) having a reflectance of 60% to 85% or silver (Ag) having a reflectance of 95%, on all sides of the glass substrate by a vacuum deposition method. It is produced by depositing at 1200Å thickness. The light reflected by the guard ring thus manufactured increases the luminance, thereby providing an organic light emitting display device having an improved image quality for viewing information under bright ambient light conditions.

본 발명의 대표적인 실시 예에서 가드링으로 사용될 수 있는 바람직한 물질로는 특히, 은(Ag), 알루미늄(Al) 또는 유리 기판의 측면에 가드링으로 사용될 수 있는 반사율이 좋은 어떤 다른 물질을 포함한다. 여기에 인용된 두께 범위로 제한되는 것은 아니지만 가드링의 두께는 발광 재료가 방출하는 빛을 충분히 반사시킬 수 있는 정도의 두께 모두를 포함한다.Preferred materials that can be used as guard rings in exemplary embodiments of the present invention include, in particular, silver (Ag), aluminum (Al) or any other material with good reflectivity that can be used as guard rings on the side of the glass substrate. Although not limited to the thickness range recited herein, the thickness of the guard ring includes any thickness sufficient to sufficiently reflect the light emitted by the luminescent material.

본 발명의 유기전계발광소자는 전체적으로 어떤 층들이 스핀코팅된 폴리머성 물질로 이루어진 유기전계발광소자나 진공증착된 분자 유기물질로 제작된 유기전계발광소자에도 사용할 수 있는 장점이 있다.The organic electroluminescent device of the present invention has an advantage that it can be used in an organic electroluminescent device made of a polymeric material spin-coated as a whole, or an organic electroluminescent device made of a vacuum organic molecular organic material.

또한 장치가 SOLED이든 단일 OLED이든 TOLED이든 IOLED이든 또는 다른 디자인 변형이 사용된 유기전계발광소자에도 적용할 수 있는 장점이 있다.It also has the advantage that the device can be applied to organic light emitting devices using SOLED, single OLED, TOLED, IOLED or other design variations.

따라서 "가드링"은 그러한 추가 공정이 없는 유사한 장치보다 최소한 10%, 일반적으로는 약 30∼50% 또는 그 이상 더 높은 휘도를 갖도록 개선시키는 것으로 믿어진다.Thus, it is believed that the "guard ring" improves to have a brightness that is at least 10%, generally about 30-50% or more higher than similar devices without such additional processes.

가드링을 도입한 스핀코팅에 의한 고분자 유기전계발광소자나 진공증착에 의한 단분자 유기전계발광소자를 제조하는 본 발명 방법에 의하면, 유기전계발광소자의 발광특성이 개선될 뿐만 아니라 측면 손실의 빛을 발광에 기여하도록 하여 유기전계발광소자뿐만 아니라 광다이오드, 산업용 LED, 태양전지등에 널리 활용될 수 있다.According to the method of manufacturing a polymer organic light emitting device by spin coating with a guard ring or a single molecule organic light emitting device by vacuum deposition, the light emission characteristics of the organic light emitting device are not only improved, but light of side loss is also improved. By contributing to the light emission, it can be widely used in not only organic light emitting devices but also photodiodes, industrial LEDs, solar cells, and the like.

Claims (7)

청구항 1. 양극 투명전극, 정공주입층, 정공수송층, 발광층, 전자수송층 및 전자주입층, 금속전극을 포함하는 유기전계발광소자.An organic electroluminescent device comprising an anode transparent electrode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer and an electron injection layer, a metal electrode. 청구항 2. 양극 투명전극, 정공주입층, 정공수송층, 발광층, 전자수송층 및 전자주입층, 금속전극을 포함하는 유기전계발광소자에 있어서 가드링을 포함하는 것을 특징으로 하는 유기전계발광소자.2. An organic electroluminescent device comprising a guard ring in an organic electroluminescent device comprising an anode transparent electrode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer and an electron injection layer, a metal electrode. 청구항 3. 제 2항에 있어서,3. The method of claim 2, 상기 가드링의 재료가 은(Ag), 알루미늄(Al)등 반사율이 높은 물질을 사용하는 것을 특징으로 하는 유기전계발광소자.The material of the guard ring is an organic light emitting device, characterized in that the use of a material having a high reflectance such as silver (Ag), aluminum (Al). 청구항 4. 제 2항에 있어서,4. The method of claim 2, 유리기판의 사면 측면에 가드링을 도입하는 것을 특징으로 하는 유기전계발광소자.An organic light emitting display device, characterized in that the guard ring is introduced to the side surface of the glass substrate. 청구항 5. 제 2항에 있어서,5. The process of claim 2, 가드링 제작시 은(Ag), 알루미늄(Al)을 진공증착법이나 스퍼터링방법으로 성막하는 공정.Process of forming silver (Ag) and aluminum (Al) by vacuum evaporation or sputtering during the formation of guard rings. 청구항 6. 제 5항에 있어서,6. The method of claim 5, wherein 가드링 제작시 은(Ag), 알루미늄(Al)의 두께가 1200Å이라는 것과 인용된 두께 범위이외의 발광 재료가 방출하는 빛을 충분히 반사시킬 수 있는 정도의 가드링의 두께 모두를 포함하는 것을 특징으로 하는 유기전계발광소자.It is characterized by including both the thickness of silver (Ag) and aluminum (Al) when manufacturing the guard ring, and the thickness of the guard ring to the extent that can sufficiently reflect the light emitted by the light emitting material outside the cited thickness range. An organic electroluminescent device. 청구항 7. 유기전계발광소자 뿐만 아니라 가드링이 사용되는 광다이오드, 산업용 LED, 태양전지 등의 광소자.7. An optical device such as a photodiode, an industrial LED, and a solar cell, in which a guard ring is used as well as an organic light emitting device.
KR1020010026672A 2001-05-16 2001-05-16 Organic Light Emitting Diodes(OLEDs) with Guard Ring KR20020087714A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012138181A3 (en) * 2011-04-06 2013-01-10 네오뷰코오롱 주식회사 Screen for displaying information for an optical device

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Publication number Priority date Publication date Assignee Title
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JPH10255974A (en) * 1997-03-06 1998-09-25 Nippon Steel Chem Co Ltd Bidirectional field drive type organic electroluminescent element
JP2000277253A (en) * 1999-03-26 2000-10-06 Canon Inc Luminous element, light emitting device, display device, aligner, and image forming device
JP2001023771A (en) * 1999-07-12 2001-01-26 Sony Corp Planar display element
JP2001093661A (en) * 1999-09-22 2001-04-06 Semiconductor Energy Lab Co Ltd El display device and electronic device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR900013812A (en) * 1989-02-27 1990-09-06 최근선 Full length light emitting device
JPH10255974A (en) * 1997-03-06 1998-09-25 Nippon Steel Chem Co Ltd Bidirectional field drive type organic electroluminescent element
JP2000277253A (en) * 1999-03-26 2000-10-06 Canon Inc Luminous element, light emitting device, display device, aligner, and image forming device
JP2001023771A (en) * 1999-07-12 2001-01-26 Sony Corp Planar display element
JP2001093661A (en) * 1999-09-22 2001-04-06 Semiconductor Energy Lab Co Ltd El display device and electronic device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012138181A3 (en) * 2011-04-06 2013-01-10 네오뷰코오롱 주식회사 Screen for displaying information for an optical device
US9425423B2 (en) 2011-04-06 2016-08-23 Neoviewkolon Co., Ltd. Screen for displaying information for an optical device

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