KR20020085376A - Assistance for cosmetic and process method of the assistance - Google Patents

Assistance for cosmetic and process method of the assistance Download PDF

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Publication number
KR20020085376A
KR20020085376A KR1020010024863A KR20010024863A KR20020085376A KR 20020085376 A KR20020085376 A KR 20020085376A KR 1020010024863 A KR1020010024863 A KR 1020010024863A KR 20010024863 A KR20010024863 A KR 20010024863A KR 20020085376 A KR20020085376 A KR 20020085376A
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South Korea
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weight
titanium dioxide
cosmetic composition
color
aryl substituted
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KR1020010024863A
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Korean (ko)
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강희철
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(주) 인터코텍
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Priority to KR1020010024863A priority Critical patent/KR20020085376A/en
Publication of KR20020085376A publication Critical patent/KR20020085376A/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/438—Thermochromatic; Photochromic; Phototropic

Abstract

PURPOSE: A cosmetic composition containing titanium dioxide and iron oxide, or aryl substituted heterocycle as a main component is provided which changes color when exposed to ultraviolet light but recovers original colors when the ultraviolet light is shielded. CONSTITUTION: The cosmetic composition contains 0.001 to 50% by weight of titanium dioxide and iron oxide and additionally 0.001 to 50% by weight of aryl substituted heterocycle of the formula 1. In formula, R1 and R2 are (CH2)nH in which n is an integer containing 0. For example, 0.001 to 50% by weight of titanium dioxide and iron oxide, 0.1 to 10% by weight of a pigment, 2% by weight of solid paraffin, 2% by weight of wax, 10% by weight of linolin and castor oil to make 100% by weight.

Description

화장품 조성물{ASSISTANCE FOR COSMETIC AND PROCESS METHOD OF THE ASSISTANCE}Cosmetic composition {ASSISTANCE FOR COSMETIC AND PROCESS METHOD OF THE ASSISTANCE}

본 발명은 화장품 조성물에 관한 것으로 특히 티타늄디옥사이드 / 아이온옥사이드(Titanium Dioxide and lron Oxide) 또는 아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)을 사용해 자외선(태양광 포함)이 제거되면 원래의 색상 또는 색감, 명암으로 되돌아 오는 화장품 조성물을 제공할 수 있게 한 것이다.The present invention relates to a cosmetic composition, in particular the original color or when the ultraviolet (including sunlight) is removed by using titanium dioxide and lron oxide or aryl substituted heterocycle (Aryl Substituted Heterocyle) It is to be able to provide a cosmetic composition that returns to color, contrast.

종래의 색조 화장품은 하나의 색상만을 나타내었으나 특정한 조건에서 하나 이상의 색으로 변하는 색조화장품에 대한 소비자의 요구가 늘어나고 있는 것이 현실이다.Conventional color cosmetics have only one color, but the reality is that consumer demand for color cosmetics that change to one or more colors under certain conditions is increasing.

본원출원인이 서울거주자로 20∼30세 초반의 여성으로서 학생 및 주부를 대상으로 설문조사한 결과에 의하면 응답자 50명중 50명 전원이 자외선을 받으면 색상이 변하고 자외선이 없어지면 본래의 색으로 돌아오는 색조화장품을 선호하는 것으로 나타났다.According to the results of a survey of students and housewives who are applicants living in Seoul and women in their 20s to 30s, 50 out of 50 respondents changed their color when they received UV rays and returned to their original color when the UV rays disappeared. Found to be preferred.

이에 본원출원인은 자외선을 받으면 색상이 변화하고, 자외선이 없어지면 본래의 색으로 돌아오는 화장품 조성물을 개발하기에 이르렀다.Accordingly, the applicant of the present application has developed a cosmetic composition that changes color when subjected to ultraviolet rays and returns to its original color when the ultraviolet rays disappear.

본 발명이 이루고자 하는 기술적 과제는, 종래의 단일 색상만을 나타내는 색조 화장품이 아닌 사용자의 선호도가 높은, 자외선을 받으면 색상이 변화하고, 자외선이 없어지면 본래의 색으로 돌아오는 화장품 조성물을 제공하기 위한 것이다.The technical problem to be achieved by the present invention is to provide a cosmetic composition that changes in color when subjected to ultraviolet rays, which is highly preferred by the user, rather than a conventional color cosmetic representing only a single color, and returns to the original color when the ultraviolet rays disappear.

본 발명의 기술적 과제는, 티타늄디옥사이드/아이온옥사이드(Titanium Dioxide and lron Oxide) 또는 아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)을 사용한 화장품 조성물에 의하여 달성되어진다.The technical problem of the present invention is achieved by a cosmetic composition using titanium dioxide and lron oxide or aryl substituted heterocycle.

본 발명의 화장품 조성물에 대하여 상세히 설명하면 다음과 같다.Hereinafter, the cosmetic composition of the present invention will be described in detail.

본 발명의 화장품 조성물은 자외선을 받으면 종래의 색상이 아닌 다른 색상으로 변화하고, 자외선이 없어지면 본래의 색으로 돌아오는 화장품 조성물을 위해 주성분으로 티타늄디옥사이드/아이온옥사이드(Titanium Dioxide and lron Oxide) 또는 아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)을 각각 0.001∼50 중량% 범위내에서 사용한다./Cosmetic composition of the present invention is changed to a color other than the conventional color when receiving ultraviolet rays, titanium dioxide / ion oxide (Titanium Dioxide and lron Oxide) or arylsubs as the main component for the cosmetic composition to return to the original color when the ultraviolet ray disappears Aryl Substituted Heterocyle is used in the range of 0.001 to 50% by weight, respectively.

티타늄디옥사이드/아이온옥사이드(Titanium Dioxide and lron Oxide)Titanium Dioxide and lron Oxide

TiO2/Fe2O3 TiO 2 / Fe 2 O 3

아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)Aryl Substituted Heterocyle

(상기식에서 R1,R2는 (CH2)nH(n은 0을 포함한 정수)이다)(Wherein R 1 and R 2 are (CH 2 ) n H (n is an integer including 0))

이하 본 발명을 화장품 조성물의 실시예를 들어 구체적으로 설명한다.Hereinafter, the present invention will be described in detail by way of examples of cosmetic compositions.

실시예 1) 립글로스Example 1 Lip Gloss

NONO 성 분 명Name 중 량(%)weight(%) 1One 티타늄디옥사이드 / 아이온옥사이드Titanium Dioxide / Ion Oxide 0.001∼500.001-50 22 색소Pigment 0.1∼100.1 to 10 33 고형 파라핀Solid paraffin 22 44 밀납Beeswax 22 55 리놀린Linoline 1010 66 피마자유Castor Oil 총합이 100Total 100

성분 1∼6을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다.The components 1-6 are melt | dissolved by heating to 80 degreeC, and it makes it uniform, and cools to room temperature.

실시예 2) 립글로스Example 2 Lip Gloss

NONO 성 분 명Name 중 량(%)weight(%) 1One 아릴섭스티튜티드 헤테로사이클Arylsubstituted heterocycle 0.001∼500.001-50 22 색소Pigment 0.1∼100.1 to 10 33 고형 파라핀Solid paraffin 22 44 밀납Beeswax 22 55 리놀린Linoline 1010 66 피마자유Castor Oil 총합이 100Total 100

성분 1∼6을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다.The components 1-6 are melt | dissolved by heating to 80 degreeC, and it makes it uniform, and cools to room temperature.

실시예 3) 립글로스Example 3 Lip Gloss

NONO 성 분 명Name 중 량(%)weight(%) 1One 티타늄디옥사이드 / 아이온옥사이드Titanium Dioxide / Ion Oxide 0.001∼500.001-50 22 아릴섭스티튜티드 헤테로사이클Arylsubstituted heterocycle 0.001∼500.001-50 33 색소Pigment 0.1∼100.1 to 10 44 고형 파라핀Solid paraffin 22 55 밀납Beeswax 22 66 리놀린Linoline 1010 77 피마자유Castor Oil 총합이 100Total 100

성분 1∼7을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다.The components 1 to 7 are dissolved by heating to 80 ° C, and then uniformly cooled to room temperature.

실시예 4) 립스틱Example 4 Lipstick

NONO 성 분 명Name 중 량(%)weight(%) 1One 티타늄디옥사이드 / 아이온옥사이드Titanium Dioxide / Ion Oxide 0.001∼500.001-50 22 아릴섭스티튜티드 헤테로사이클Arylsubstituted heterocycle 44 33 색소Pigment 0.1∼100.1 to 10 44 고형 파라핀Solid paraffin 22 55 밀납Beeswax 22 66 리놀린Linoline 1010 77 피마자유Castor Oil 총합이 100Total 100

성분 1∼7을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다.The components 1 to 7 are dissolved by heating to 80 ° C, and then uniformly cooled to room temperature.

실시예 5) 립스틱Example 5 Lipstick

NONO 성 분 명Name 중 량(%)weight(%) 1One 아릴섭스티튜티드 헤테로사이클Arylsubstituted heterocycle 0.001∼500.001-50 22 이산화티탄Titanium dioxide 44 33 색소Pigment 0.1∼100.1 to 10 44 고형 파라핀Solid paraffin 22 55 밀납Beeswax 22 66 리놀린Linoline 1010 77 피마자유Castor Oil 총합이 100Total 100

성분 1∼7을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다The components 1 to 7 are dissolved by heating to 80 ° C, and then uniformly cooled to room temperature.

실시예 6) 립스틱Example 6 Lipstick

NONO 성 분 명Name 중 량(%)weight(%) 1One 티타늄옥사이드 / 아이온옥사이드Titanium Oxide / Ion Oxide 0.001∼500.001-50 22 아릴섭스터튜티드 헤테로사이클Arylsubstituted heterocycle 0.001∼500.001-50 33 이산화티탄Titanium dioxide 44 44 색소Pigment 0.1∼100.1 to 10 55 고형 파라핀Solid paraffin 22 66 밀납Beeswax 22 77 리놀린Linoline 1010 88 피마자유Castor Oil 총합이 100Total 100

성분 1∼8을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다.After dissolving components 1-8 to 80 degreeC by heating, it is made uniform and cooled to room temperature.

실시예 7) 아이섀도우Example 7 Eye Shadow

NONO 성 분 명Name 중 량(%)weight(%) 1One 티타늄디옥사이드 / 아이온옥사이드Titanium Dioxide / Ion Oxide 0.001∼500.001-50 22 이산화티탄Titanium dioxide 44 33 색소Pigment 0.1∼100.1 to 10 44 마이카Mica 1010 55 유동 파라핀Floating paraffin 77 66 탈크Talc 총합이 100Total 100

성분 1∼6을 균일하게 혼합한다.The components 1-6 are mixed uniformly.

실시예 8) 아이섀도우Example 8) Eye Shadow

NONO 성 분 명Name 중 량(%)weight(%) 1One 아릴섭티튜티드 헤테로사이클Aryl interference heterocycle 0.001∼500.001-50 22 이산화티탄Titanium dioxide 44 33 색소Pigment 0.1∼100.1 to 10 44 마이카Mica 1010 55 유동 파라핀Floating paraffin 77 66 탈크Talc 총합이 100Total 100

성분 1∼6을 균일하게 혼합한다.The components 1-6 are mixed uniformly.

실시예 9) 아이섀도우Example 9) Eye Shadow

NONO 성 분 명Name 중 량(%)weight(%) 1One 티타늄디옥사이드 / 아이온옥사이드Titanium Dioxide / Ion Oxide 0.001-500.001-50 22 아릴섭스티튜티드 헤테로사이클Arylsubstituted heterocycle 0.001-500.001-50 33 이산화티탄Titanium dioxide 44 44 색소Pigment 0.1∼100.1 to 10 55 마이카Mica 1010 66 유동 파라핀Floating paraffin 77 77 탈크Talc 총합이 100Total 100

성분 1∼6을 균일하게 혼합한다.The components 1-6 are mixed uniformly.

실시예 10) 파운데이션Example 10) Foundation

NONO 성 분 명Name 중 량(%)weight(%) 1One 티타늄옥사이드 / 아이온옥사이드Titanium Oxide / Ion Oxide 0.001∼500.001-50 22 이산화티탄Titanium dioxide 44 33 색소Pigment 0.1∼100.1 to 10 44 고형 파라핀Solid paraffin 22 55 밀납Beeswax 22 66 리놀린Linoline 1010 77 탈크Talc 1010 88 피마자유Castor Oil 총합이 100Total 100

성분 1∼8을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다.After dissolving components 1-8 to 80 degreeC by heating, it is made uniform and cooled to room temperature.

실시예 11) 파운데이션Example 11 Foundation

NONO 성 분 명Name 중 량(%)weight(%) 1One 아릴섭티튜티드 헤테로사이클Aryl interference heterocycle 0.001∼500.001-50 22 이산화티탄Titanium dioxide 44 33 색소Pigment 0.1∼100.1 to 10 44 고형 파라핀Solid paraffin 22 55 밀납Beeswax 22 66 리놀린Linoline 1010 77 탈크Talc 1010 88 피마자유Castor Oil 총합이 100Total 100

성분 1∼8을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다.After dissolving components 1-8 to 80 degreeC by heating, it is made uniform and cooled to room temperature.

실시예 12) 파운데이션Example 12) Foundation

NONO 성 분 명Name 중 량(%)weight(%) 1One 티타늄디옥사이드 / 아이온옥사이드Titanium Dioxide / Ion Oxide 0.001∼500.001-50 22 아릴섭스티투티드 헤테로사이클Arylsubstituted heterocycle 0.001∼500.001-50 33 이산화티탄Titanium dioxide 44 44 색소Pigment 0.1∼100.1 to 10 55 고형 파라핀Solid paraffin 22 66 밀납Beeswax 22 77 리놀린Linoline 1010 88 탈크Talc 1010 99 피마자유Castor Oil 총합이 100Total 100

성분 1∼9을 80℃까지 가열 용해한 후 균일하게 하여 실온까지 냉각한다.The components 1-9 are melt | dissolved by heating to 80 degreeC, and it makes it uniform, and cools to room temperature.

하기의 비교예는 본 발명과의 비교를 위하여 티타늄디옥사이드/아이온옥사이드(Titanium Dioxide and lron Oxide) 또는 아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)을 사용한 화장품 조성물과 사용하지 않는 화장품 조성물을 각각 제조한 후 자외선을 조사하여 색상의 변화여부를 육안으로 비교한 것이다.The following comparative examples are the cosmetic composition using titanium dioxide and lron oxide or aryl substituted heterocycle (Aryl Substituted Heterocyle) and the cosmetic composition not used for comparison with the present invention, respectively After manufacturing, the color is irradiated and compared with the naked eye.

비교예 1)Comparative Example 1)

AA BB CC DD 립글로스Lip gloss ◎◎ ◎◎ ◎◎ ×× 립스틱lipstick ◎◎ ◎◎ ◎◎ ×× 아이섀도우Eyeshadow ◎◎ ◎◎ ◎◎ ×× 파운데이션foundation ◎◎ ◎◎ ◎◎ ××

◎ : 색상이 변함◎: color changes

× : 색상이 변하지 않음×: color does not change

A : 티타늄디옥사이드 / 아이온옥사이드(Titanium Dioxide and lron Oxide)를 사용한 화장품 조성물A: Cosmetic composition using titanium dioxide and lron oxide

B : 아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)를 사용한 화장품 조성물B: Cosmetic Composition Using Aryl Substituted Heterocyle

C : 티타늄디옥사이드 / 아이온옥사이드 (Titanium Dioxide and lron Oxide)와 아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)를 사용한 화장품 조성물C: Cosmetic composition using Titanium Dioxide and lron Oxide and Aryl Substituted Heterocyle

D : 티타늄디옥사이드 / 아이온옥사이드(Titanium Dioxide and lron Oxide)나 아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)를 사용하지 않은 화장품 조성물D: Cosmetic composition without using titanium dioxide and lron oxide or aryl substituted heterocycle

본 발명은 티타늄디옥사이드 / 아이온옥사이드(Titanium Dioxide and lron Oxide)또는 아릴섭스티튜티드 헤데로사이클(Aryl Substituted Heterocyle)을 사용해 자외선(태양광 포함)을 받아 색상 또는 색감, 명암이 변화하고 자외선(태양광 포함)이 제거되면 원래의 색상 또는 색감, 명암으로 되돌아 오는 사용자의 선호도가 높은 화장품 조성물을 제공할 수 있게 한 것이다.The present invention uses a titanium dioxide and lron oxide or an aryl substituted heterocycle (Aryl Substituted Heterocyle) to receive ultraviolet light (including sunlight) to change the color, color, contrast, and ultraviolet (Sun) When the light is removed), it is possible to provide a cosmetic composition having a high preference of the user to return to the original color, color, and contrast.

이상에서는 본 발명을 실시예에 의거 설명하였으나 첨부된 특허청구 범위 내에서 당해분야에서 통상의 지식을 가진 자에 의해 다양한 변형예 및 수정예가 가능한 것으로 이해되어야 함은 물론이다.The present invention has been described above based on the embodiments, but it should be understood that various modifications and changes can be made by those skilled in the art within the scope of the appended claims.

Claims (3)

티타늄디옥사이드와 아이온옥사이드가 각각 0.001∼50중량% 부가된 화장품 조성물.Cosmetic composition to which titanium dioxide and ion oxide are added 0.001 to 50% by weight, respectively. 청구항 1에 있어서, 다음의 식으로 구성된 아릴섭스터튜티드 헤테로사이클를 0.001∼50중량% 더 첨가된 것을 특징으로 하는 화장품 조성물.The cosmetic composition according to claim 1, further comprising 0.001 to 50% by weight of an arylsubstituted heterocycle having the following formula. (상기식에서 R1,R2는 (CH2)nH(n은 0을 포함한 정수)이다)(Wherein R 1 and R 2 are (CH 2 ) n H (n is an integer including 0)) (상기식에서 R1,R2는 (CH2)nH(n은 0을 포함한 정수)이다)(Wherein R 1 and R 2 are (CH 2 ) n H (n is an integer including 0)) 상기의 식(1)으로 구성된 아릴섭스터튜티드 헤테로사이클을 0.001∼50중량% 부가하여서 된 화장품 조성물.Cosmetic composition by adding 0.001-50 weight% of aryl substantiated heterocycles comprised of said Formula (1).
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR830002513A (en) * 1979-06-08 1983-05-30 한스 스렌데르, 쥐르겐 어른스트 Pancreatin preparation method
EP0186364A2 (en) * 1984-12-11 1986-07-02 Unitika Ltd. Photochromic compounds
EP0245020A2 (en) * 1986-05-01 1987-11-11 Pilkington Plc Photochromic articles
EP0277639A2 (en) * 1987-02-02 1988-08-10 Toray Industries, Inc. Photochromic compound
JPS6429381A (en) * 1987-07-24 1989-01-31 Toray Industries Spirooxazine dimer compound
KR910009047A (en) * 1989-10-31 1991-05-31 김광호 Synchronous Signal Separation Circuit
WO1995020184A1 (en) * 1994-01-24 1995-07-27 Catalysts & Chemicals Industries Co., Ltd. Photochromic composite oxide and cosmetics containing the photochromic composite oxide
JPH1045523A (en) * 1996-08-06 1998-02-17 Kanebo Ltd Cosmetic

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR830002513A (en) * 1979-06-08 1983-05-30 한스 스렌데르, 쥐르겐 어른스트 Pancreatin preparation method
EP0186364A2 (en) * 1984-12-11 1986-07-02 Unitika Ltd. Photochromic compounds
EP0245020A2 (en) * 1986-05-01 1987-11-11 Pilkington Plc Photochromic articles
EP0277639A2 (en) * 1987-02-02 1988-08-10 Toray Industries, Inc. Photochromic compound
JPS6429381A (en) * 1987-07-24 1989-01-31 Toray Industries Spirooxazine dimer compound
KR910009047A (en) * 1989-10-31 1991-05-31 김광호 Synchronous Signal Separation Circuit
WO1995020184A1 (en) * 1994-01-24 1995-07-27 Catalysts & Chemicals Industries Co., Ltd. Photochromic composite oxide and cosmetics containing the photochromic composite oxide
JPH1045523A (en) * 1996-08-06 1998-02-17 Kanebo Ltd Cosmetic

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