KR20020074577A - great volume oxygen and hydrogen mixture gas generation equipment of variable an electrolytic cell - Google Patents
great volume oxygen and hydrogen mixture gas generation equipment of variable an electrolytic cell Download PDFInfo
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- KR20020074577A KR20020074577A KR1020010014421A KR20010014421A KR20020074577A KR 20020074577 A KR20020074577 A KR 20020074577A KR 1020010014421 A KR1020010014421 A KR 1020010014421A KR 20010014421 A KR20010014421 A KR 20010014421A KR 20020074577 A KR20020074577 A KR 20020074577A
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
- C25B1/044—Hydrogen or oxygen by electrolysis of water producing mixed hydrogen and oxygen gas, e.g. Brown's gas [HHO]
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/02—Process control or regulation
- C25B15/021—Process control or regulation of heating or cooling
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
- C25B15/083—Separating products
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
본 발명은 가변형 전해조에 의한 대용량 산소 ·수소 혼성가스 발생장치에 관한 것으로서 특히 다수의 전해조를 병렬로 연결시키고 양측에서 직류전원이 인가되도록 함으로써 단위 시간당 많은 량의 가스를 발생시키도록 한 것이다.The present invention relates to a large-capacity oxygen-hydrogen hybrid gas generator using a variable electrolyzer, and in particular, to connect a large number of electrolyzers in parallel and to generate a large amount of gas per unit time by applying a DC power supply from both sides.
최초에 물을 전기분해 할 때는 전해조내에 격막을 설치하고, 각각의 전해조내에 +, - 전극을 연결하여 산소와 수소가 분리되도록 하였으나 최근 새로운 에너지원을 찾으려는 연구와 함께 산소와 수소가 혼합된 가스를 발생시키는 전해조의 개발이 이루어지고 있다.When water was first electrolyzed, a diaphragm was installed in the electrolytic cell, and oxygen and hydrogen were separated by connecting + and-electrodes in each electrolyzer. However, a gas mixed with oxygen and hydrogen was recently researched to find new energy sources. Development of the electrolytic cell is generated.
그러나 이론상의 물을 전기분해하는 방식에 있어서 그 주된 장치인 전해조의 구조가 잘못되어 있음으로써 대량 발생장치의 제작이 어렵고, 전해조의 밀폐에 문제가 있어 전해액이 누출되며 발열반응에 의한 냉각등의 문제가 있었다.However, in the theoretical method of electrolyzing water, the structure of the electrolytic cell, which is the main device, is incorrect, making it difficult to manufacture a large-capacity generating device, and there is a problem in the sealing of the electrolytic cell, causing electrolyte leakage and cooling by exothermic reactions. there was.
그 예로 +와 -의 전극이 서로 교차되게 배치된 전극뭉치를 전해액이 들어있는 통속에 담근 상태에서 전해를 시킴으로써 발열반응에 의해 전해조의 온도가 상승하게 되는 문제가 있었다. 이로 인해 산소와 수소 가스 외에 수증가가 발생하여 가스와 함께 토출되어 배관라인에 응축수가 생김으로써 간혹 토치를 통해 물이 쏟아져 나오기도 한다.For example, there is a problem in that the temperature of the electrolytic cell is increased by exothermic reaction by performing electrolysis in a state in which an electrode bundle in which + and-electrodes are arranged to cross each other is immersed in a container containing electrolyte. As a result, water increases in addition to oxygen and hydrogen gas and is discharged together with the gas to form condensed water in the pipe line, so that water sometimes flows out through the torch.
또한 각각의 전극에 긴 볼트로 연결한 공냉식 방식은 전해액을 충진할 공간을 마련하고 절연을 위하여 각 전극판 사이를 고무등의 절연재로 밀폐시켜야 함으로 수십개에서 100여개가 넘는 전극판 사이 중에서 1개소라도 누출되면 전체 발생기의 가동이 중단되는 문제점이 있었다.In addition, the air-cooled method connected to each electrode with a long bolt should provide a space to fill the electrolyte and seal each electrode plate with an insulating material such as rubber for insulation. When leaking, there was a problem that the entire generator is stopped.
그리고 조합된 전극 사이로 바람을 불어주어 냉각을 하지만 각 전극 전체가 긴 볼트로 조여져 있으므로 실제로는 하나의 전해조 뭉치가 됨으로써 장시간 가동이 어렵과 대량의 가스발생장치가 될 수 없다는 문제점이 있었다.In addition, the air is cooled by blowing air between the combined electrodes, but since each of the electrodes is fastened by a long bolt, it is difficult to operate a long time due to a bundle of electrolyzers and a large amount of gas generators.
본 발명은 이와 같은 문제점을 해소하기 위해 안출한 것으로서 일정한 크기를 갖는 얇고 넓은 형태를 갖는 다수의 전해조를 소정 간격으로 병렬로 연결시키고 조합된 그 양 끝단에 직류전원이 인가되도록 함으로써 전해조의 온도 상승을 억제 하고, 같은 전기 에너지로서 가스발생량은 단면적에 비례함으로 시간당 가스발생율을 증가시켜 효율적으로 사용할 수 있도록 하고 아울러 그 안전율을 높인 개별 공냉식 산소 ·수소 혼성가스 발생장치를 제공하는데 그 목적이 있다.The present invention has been made in order to solve such a problem as the temperature rise of the electrolytic cell by increasing the temperature of the electrolytic cell by connecting a plurality of electrolytic cells having a thin and wide form having a constant size in parallel at a predetermined interval and the DC power is applied to the combined ends thereof. The purpose of the present invention is to provide an individual air-cooled oxygen-hydrogen hybrid gas generator that suppresses and increases the gas generation rate per hour as the amount of gas generated as the electric energy is proportional to the cross-sectional area, thereby increasing the safety rate.
이와 같은 목적을 달성하기 위한 본 발명은 전해조에 음극과 양극판을 구비하고, 전해액을 전기분해시켜 수소와 산소가스를 얻는 장치에 있어서, 받침판과; 요홈을 갖는 각각의 절연받침과; 전해액을 보관할 수 있는 공간내부로 전극판을 이용하여 전기분해가 가능하도록 구비된 전해조와; 전해조의 하단 양측에 상기 절연받침이 끼워져 받침판 위에 소정의 개수가 병렬로 놓여지도록 하고, 전해조 사이로 전기분해를 통해 발생된 가스를 외부로 배출시키는 가스배출부와; 전기분해시 필요한 전해액을 공급하는 전해액 유입구와; 전기분해시 발생되는 열을 냉각시키기 위해 병렬로 연결된 전해조의 정면에 구비된 블로워로 구성된 것을 특징으로 하는 가변형 전해조에 의한 대용량 산소 ·수소 혼성가스 발생장치를 제공함에 달성된다.The present invention for achieving the above object is provided with an anode and a cathode plate in the electrolytic cell, the device for obtaining hydrogen and oxygen gas by electrolysis of the electrolyte solution, the support plate; Each insulating support having grooves; An electrolytic cell provided to allow electrolysis using an electrode plate into a space capable of storing an electrolyte solution; A gas discharge part for inserting the insulation support on both sides of the lower end of the electrolytic cell so that a predetermined number is placed in parallel on the support plate, and discharging the gas generated through electrolysis between the electrolytic cells to the outside; An electrolyte inlet for supplying an electrolyte required for electrolysis; It is achieved to provide a large-capacity oxygen-hydrogen hybrid gas generator by a variable type electrolytic cell, characterized in that the blower provided in front of the electrolytic cell connected in parallel to cool the heat generated during electrolysis.
도 1은 본 발명에 따른 혼성가스 발생장치의 요부 사시도.1 is a perspective view of main parts of a hybrid gas generator according to the present invention;
도 2는 본 발명에 따른 혼성가스 발생장치의 분해 사시도.Figure 2 is an exploded perspective view of the hybrid gas generator according to the present invention.
도 3은 본 발명에 따른 혼성가스 발생장치의 종단면도.Figure 3 is a longitudinal sectional view of the hybrid gas generator according to the present invention.
<도면의 주요 부분에 대한 부호의 간단한 설명><Brief description of symbols for main parts of the drawings>
2:받침판 3:절연받침2: support plate 3: insulation support
4:전해조 7:블로워4: Electrolyzer 7: Blower
8:요홈 9:방폭소음기8: recess 9: explosion-proof silencer
10:요홈부 11:체결공10: groove 11: fastener
12:커플러 13:함체부12: Coupler 13: Enclosure
14:+ 입력단자 16:+ 전극판14: + input terminal 16: + electrode plate
17: 커버 18:절연부재17: cover 18: insulating member
19:체결부재19: Fastening member
이하 본 발명의 실시예를 첨부 도면을 참조하여 설명하면 다음과 같다.Hereinafter, an embodiment of the present invention will be described with reference to the accompanying drawings.
본 발명에 따른 혼성가스 발생장치(1)는 도 1 내지 도 3에 도시된 바와 같이 가스발생장치(1)가 설치되는 바닥에 놓여지는 받침판(2)과, 받침판(2) 윗면에 놓여진 다수의 절연받침(3)과, 절연받침(3) 위로 내부에 전해액을 저장하여 전기분해가 가능하도록 구비된 전해조(4)(4a)와, 전해조(4)(4a)의 내부에서 발생된 산소와 수소의 혼성가스를 외부로 배출시키면서 전기분해에 필요한 전해액을 공급하도록 전해조(4)(4a) 사이의 상하단부에 구비된 가스배출구(5)와 전해액 유입구(6)로 구성되고, 상기 전해조(4)(4a) 사이로 외부의 공기를 강제 송풍시키도록 구비된 블로워 (7)로 구성된다.As shown in FIGS. 1 to 3, the mixed gas generator 1 according to the present invention includes a support plate 2 placed on the bottom on which the gas generator 1 is installed, and a plurality of support plates placed on the support plate 2. Electrolyzers (4) (4a) and electrolyzers (4) (4a) provided to store electrolytic solution on the insulator (3), the insulator (3), and electrolyzers (4) (4a). And a gas discharge port 5 and an electrolyte inlet 6 provided at upper and lower ends between the electrolytic cells 4 and 4a so as to supply an electrolytic solution for electrolysis while discharging the mixed gas to the outside. It consists of the blower 7 provided so that external air may be forcedly blown between 4a.
여기에서 상기 받침판(2)은 그 위로 설치되는 전해조(4)의 갯수에 따라 길이를 조절하여 사용할 수 있도록 구비되어 있다.Here, the support plate (2) is provided to be used to adjust the length according to the number of electrolytic cells (4) installed thereon.
상기 절연받침(3)은 전해조(4)로 인가되는 전류가 외부로 누전되는 것을 방지하도록 하는 것으로서 전해조(4)의 하단으로 돌출된 가장자리에 삽입되도록 하는 요홈(8)이 형성되어 있다.The insulating support 3 is formed to prevent the electric current applied to the electrolytic cell 4 from leaking out to the groove 8 to be inserted into the edge protruding to the lower end of the electrolytic cell 4 is formed.
상기 전해조(4)는 도 2에 도시된 바와 같이, 일측면에 내부 역화 등에 의한 역압력을 조절하는 방폭소음기(9)가 구비되어 있고, 방폭소음기(9)와 대향되는 방향에 소정 공간을 갖는 요홈부(10) 가장자리로 다수의 체결공(11)이 형성된 커플러(12)를 갖는 함체부 (13)가 구비되어 있다.As shown in FIG. 2, the electrolytic cell 4 is provided with an explosion-proof silencer 9 for controlling a reverse pressure due to internal backfire or the like on one side, and has a predetermined space in a direction opposite to the explosion-proof silencer 9. A housing 13 having a coupler 12 having a plurality of fastening holes 11 formed at the edge of the recess 10 is provided.
또한 함체부(13)의 외측면에는 미도시한 파워 서플리에 접속된 + 입력단자 (14)가 구비되어 있고, + 입력단자(14)의 자유단부가 위치하는 함체부(13)의 내측면에 절연부시(15)가 끼워진 + 전극판(16)이 구비되어 있다.In addition, the outer surface of the enclosure 13 is provided with + input terminal 14 connected to a power supply not shown, and on the inner surface of the enclosure 13 where the free end of the + input terminal 14 is located. The + electrode plate 16 into which the insulation bush 15 is fitted is provided.
여기에서 상기 전극판(16)은 면적을 최대한 넓게 하기 위해 요홈부(10)의 면적과 거의 동일하거나 작게 하도록 하는 것이 바람직하고, 전기 분해과정에서 발생되는 부식을 방지하면서 전류밀도를 높이기 위해 표면에 니켈도금을 하는 것이 더욱 바람직하다.Here, the electrode plate 16 is preferably made to be substantially the same or smaller than the area of the recess 10 in order to maximize the area, and to increase the current density while preventing corrosion caused in the electrolysis process. It is more preferable to carry out nickel plating.
또한 입력단자(14)가 구비된 함체부(13)의 상하부에는 전기분해시 발생되는 압력에 의해 함체부(13)가 변형되는 것을 방지하는 복수개의 보강부(13a)(13b)가 구비되어 있고, 윗면에는 전해열의 온도를 측정하는 온도감지센서(13c)가 설치되어 있다. 그리고 밑면에는 전해액의 교환 및 전해조의 청소를 용이하도록 하기 위한 드레인 밸브(13d)가 구비되있다.In addition, the upper and lower portions of the housing portion 13 provided with the input terminal 14 is provided with a plurality of reinforcing portions (13a) (13b) for preventing the housing portion 13 from being deformed by the pressure generated during electrolysis. The upper surface is provided with a temperature sensor 13c for measuring the temperature of the electrolytic heat. The bottom surface is provided with a drain valve 13d for facilitating exchange of electrolyte and cleaning of the electrolytic cell.
상기 커플러(12)에 닿을 수 있는 커버(17)가 절연부재(18)를 사이에 두고 다수의 체결부재(19)에 의해 기밀이 유지되도록 고정되어 있다.The cover 17 which can reach the coupler 12 is fixed to maintain airtightness by the plurality of fastening members 19 with the insulating member 18 therebetween.
상기 커버(17)은 함체부(13)의 가장자리에 구비된 커플러(12)에 그 끝단부가 맞닿도록 구비하는 것이 바람직하고, 외측면에 상기 가스배출구(5)와 전해액 유입구(6)가 연결되도록 구비되어 있다. 그리고 커버(17)와 절연부재(18) 내측면 사이에 소정의 간격을 갖는 - 전극판(16a)이 구비되어 있다.The cover 17 is preferably provided so that the end portion thereof is in contact with the coupler 12 provided at the edge of the housing portion 13, so that the gas outlet 5 and the electrolyte inlet 6 is connected to the outer surface. It is provided. An electrode plate 16a having a predetermined distance between the cover 17 and the inner surface of the insulating member 18 is provided.
상기 함체부(13)의 하단에 구비된 드레인 밸브(13d)는 이웃한 다른 드레인 밸브에 파이프(30)로 연결되어 있어 여러곳으로 부터 배출된 전해액을 한 곳으로 모을 수 있도록 구비되어 있다.The drain valve 13d provided at the lower end of the housing part 13 is connected to another neighboring drain valve by a pipe 30 so that the electrolyte discharged from various places can be collected in one place.
본 발명에서 사용된 블로워(7)의 방열팬 크기는 전극판과 동일한 크기로 하는 것이 더욱 바람직하다. 또한 본발명에서 사용된 전해액은 수산화 칼슘용액 또는 수산화 칼슘용액에 순수한 물을 희석시켜 사용하는 것이 바람직하다.The heat dissipation fan of the blower 7 used in the present invention is more preferably the same size as the electrode plate. In addition, the electrolyte solution used in the present invention is preferably used by diluting pure water with calcium hydroxide solution or calcium hydroxide solution.
이와 같이 구성된 본 고안의 작용은 다음과 같다.The operation of the present invention configured as described above is as follows.
먼저 미도시한 파워 서플리를 통해 직류인 전류가 인가됨과 동시에 전해조 (4)의 + 입력단자(14)와 연결된 + 전극판(16)과 - 전극판(16a)에 의해 전해액에서 전기분해가 일어나면서 산소와 수소가스가 발생한다.First, a direct current is applied through a power supply (not shown), and at the same time, electrolysis occurs in the electrolyte by the + electrode plate 16 and-electrode plate 16a connected to the + input terminal 14 of the electrolytic cell 4. Oxygen and hydrogen gas are generated.
발생된 산소와 수소가스는 혼합된 상태로 전해조(4)(4a)사이에 구비된 가스배출구(5)를 통해 배출되며 배출된 혼합가스는 공지의 수분제거장치를 통과시켜 수분이 제거된 상태에서 토오치로 연소시켜 사용하면 된다.The generated oxygen and hydrogen gas are discharged through the gas outlet 5 provided between the electrolyzers 4 and 4a in a mixed state, and the discharged mixed gas passes through a known moisture removal device to remove moisture. It can be used by burning with torch.
그리고 가스가 발생되면서 줄어든 물은 유입구를 통해 전해액 유입구(6)를 통해 적당량이 유입됨으로써 항상 일정한 량을 유지할 수 있게 된다.In addition, the water reduced as the gas is generated can always maintain a constant amount by introducing an appropriate amount through the electrolyte inlet 6 through the inlet.
한편 전해액이 전기분해되면서 발생되는 전해열은 전해액을 둘러싸고 있는 전해조(4)에 전달되고, 전해조(4)로 전달된 열은 일측에 설치된 블로워(7)로 부터 토출되는 외기에 의해 냉각이 된다.Meanwhile, the electrolytic heat generated as the electrolytic solution is electrolyzed is transferred to the electrolyzer 4 surrounding the electrolytic solution, and the heat transferred to the electrolyzer 4 is cooled by the outside air discharged from the blower 7 installed at one side.
본 발명에서 사용된 전해조는 필요한 가스량에 따라 직렬이나 병렬로 사용하여 충족시킬 수 있고, 또한 그 형태를 사각형 뿐만 아니라 내부에 공간을 갖도록 하는 원형이나 타원형 및 다각형으로 변경시켜 사용할 수 있다.The electrolyzer used in the present invention can be used in series or in parallel according to the amount of gas required, and can also be used by changing the shape into a circle, an ellipse, and a polygon having a space therein as well as a rectangle.
또한 파워 서플리에서 공급되는 전원을 통상의 가변저항기를 경유하도록 할 경우에는 가스의 발생량을 조절할 수 있다.In addition, when the power supplied from the power supply is made to pass through a conventional variable resistor, the amount of gas generated can be adjusted.
그리고 전해조의 일측에 상하한 압력자동 제어기를 부착할 경우에는 전해조내부의 압력을 일정하게 유지되도록 하여 더욱 안전하게 사용할 수 있다.And when the upper and lower pressure automatic controller is attached to one side of the electrolytic cell, the pressure inside the electrolytic cell is kept constant so that it can be used more safely.
또한 전해액 농도측정 센서를 이용할 경우에는 전해질의 농도가 최상이 되도록 유지시켜 불필요한 전력소모를 줄여 보다 효율적으로 사용할 수 도 있고, 다수의 필터를 갖는 자동급수장치를 설치할 경우에는 증류수와 초순수 등을 용이하게 공급할 수 있다.In addition, when using an electrolyte concentration measurement sensor, the concentration of the electrolyte is maintained to be the best to reduce unnecessary power consumption, and when using an automatic water supply device having a large number of filters, distilled water and ultrapure water can be easily used. Can supply
이상에서 살펴 본 바와 같이 본 발명은 여러개의 전해조를 병렬로 연결시킨 상태에서 파워 서플리로 부터 직류 전원이 인가되도록 하여 전해액을 전기분해시켜 산소와 수소 가스를 발생되도록 하는 과정에서 외부에 설치된 블로워를 통해 전해조에서 발생되는 열을 용이하게 냉각시킬 수 있도록 함으로써 많은 가스를 발생시킬 수 있을 뿐만 아니라 24시간 연속가동이 가능하고, 3년 이상 전해조의 부품교체 없이 사용할 수 있도록 안전도와 안전율을 높인 것이다.As described above, the present invention provides a blower installed externally in the process of generating oxygen and hydrogen gas by electrolytically dissolving the electrolyte by applying a DC power supply from a power supply in a state in which a plurality of electrolyzers are connected in parallel. By making it easy to cool the heat generated in the electrolytic cell, not only can generate a lot of gas, but also 24 hours of continuous operation, and increased safety and safety rate to be used without replacing the parts of the electrolytic cell for more than three years.
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CN105776445A (en) * | 2016-05-23 | 2016-07-20 | 王兆健 | Electrolysis system without cell shell |
CN116623200A (en) * | 2023-05-30 | 2023-08-22 | 荥经佳仕达化工有限公司 | Sodium chlorate electrolytic tank with multilayer sealing structure |
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KR100275504B1 (en) * | 1998-10-23 | 2001-04-02 | 김상남 | Brown gas mass generator including row type electrolyzer |
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CN105776445A (en) * | 2016-05-23 | 2016-07-20 | 王兆健 | Electrolysis system without cell shell |
CN116623200A (en) * | 2023-05-30 | 2023-08-22 | 荥经佳仕达化工有限公司 | Sodium chlorate electrolytic tank with multilayer sealing structure |
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