KR20020056834A - The adhesive for the film, that is regulating the rays of the sun, and its manufacturing way - Google Patents

The adhesive for the film, that is regulating the rays of the sun, and its manufacturing way Download PDF

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Publication number
KR20020056834A
KR20020056834A KR1020020011192A KR20020011192A KR20020056834A KR 20020056834 A KR20020056834 A KR 20020056834A KR 1020020011192 A KR1020020011192 A KR 1020020011192A KR 20020011192 A KR20020011192 A KR 20020011192A KR 20020056834 A KR20020056834 A KR 20020056834A
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parts
weight
monoma
adhesive
compounding ratio
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KR1020020011192A
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Korean (ko)
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김세영
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(주)삼원
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/10—Presence of inorganic materials
    • C09J2400/14—Glass
    • C09J2400/143—Glass in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

PURPOSE: Provided are an adhesive for film adjusting sunray, which can maintain its own character and is not gelled even if mixed with dyes, which does not degrade its function or is not decolorized by sunray with lapsing of time after working, and which has high heat resistance and moisture resistance, and a method for preparing the same. CONSTITUTION: The adhesive is prepared by the steps of (i) weighing 200-400 parts by weight of ethyl acetate as polymerization solvent, 10-60 parts by weight of methanol, 200-400 parts by weight of 2-ethylhexyl acrylate, 60-180 parts by weight of vinyl acetate, 2-12 parts by weight of acrylic acid, each of 0.5-1.0 parts by weight of benzoyl peroxide and lauroyl peroxide as initiators, and (ii) introducing, warming and polymerizing the materials in reaction bath with reflux condenser to produce the adhesive having glass transition temperature of -60 to -20 deg.C.

Description

태양광선 조절 필름용 점착제 및 그 제조 방법{The adhesive for the film, that is regulating the rays of the sun, and its manufacturing way}Adhesive for solar control film and its manufacturing method {The adhesive for the film, that is regulating the rays of the sun, and its manufacturing way}

본 발명은 아크릴계 용제형 제조 방법을 응용하여 태양광선 조절필름에 적합한 태양광선 조절 필름용 점착제 제조 방법에 관한 것으로,The present invention relates to a pressure-sensitive adhesive production method for a solar control film suitable for a solar control film by applying an acrylic solvent-type manufacturing method,

종래에 있어서 도1에 도시된바와 같이 외국산 태양광선 조절 필름은 필름(p)자체에 색을 넣어 점착제(g)는 단지 필름과의 접착성과 투명성만이 중시되었었다.그러나 다양한 색을 요구하는 소비자의 구미에 맞게 색이 들어있는 필름을 생산하기에는 소비자가 요구하는 필름의 색이 너무 다양하고 그에 비하여 수요량은 상대적으로 적어 다양한 색깔의 필름을 제작하기에는 원가 부담이 높아 색이 있는 폴리에스터 필름을 생산에는 어려움이 있으며, 외국산 색 있는 폴리에스터 필름은 제품의 가격이 높아 소비자에게 부담이 되었다.In the related art, as shown in FIG. 1, the foreign solar light control film put color on the film (p) itself, and the adhesive (g) only emphasized adhesion and transparency with the film. It is difficult to produce colored polyester film because the color of film required by the consumer is too diverse to produce the film that is suitable for the taste and the demand is relatively low, and the cost burden is high to produce various colored films. There is a foreign-colored polyester film is a burden on consumers because of the high price of the product.

이런 이유로 도2에 도시된바와 같이 투명한 폴리에스터 필름(p')을 기재로 하고 그 위에 도포되는 점착제(g')에 다양한 염료를 배합하여 여러 가지 색깔을 내게 하고 투명의 태양광선 조절필름을 구성하여 색상효과를 낼수 있도록 하였는데, 이러한 방법은 아크릴점착제가 다양한 색깔의 염료등과 배합되어 폴리에스터 필름에 코팅될 때 점착제의 겔(t)화로 인한 작업성의 문제와 필름과 결합되어 실제 자동차 유리창이나 건축물의 유리창에 적용했을 경우 자연광선 속의 자외선 등의 영향으로 빛을 받는 부분의 탈색이 진행되어 태양광선 조절 필름으로써의 기능이 저하되는 문제점이 있었으며, 사계절이 있어 날씨의 변화가 있는 국내와 같은 환경에서 사용할 경우에 계절에 따른 습도의 편차등으로 모서리부분의 접지면이 일어나는 현상 즉, 컬(c)현상이 발생하는 등의 문제점이 있었다.For this reason, as shown in FIG. 2, a transparent polyester film (p ') is used as a substrate, and various dyes are mixed with a pressure-sensitive adhesive (g') applied thereon to give various colors and constitute a transparent solar control film. This method is used in combination with the film and the problem of workability due to gelation (t) of adhesive when acrylic adhesive is mixed with dyes of various colors and coated on polyester film. When applied to the glass window of the natural light, due to the effect of ultraviolet light deterioration of the part that receives the light, there was a problem that the function as a solar control film is degraded, there are four seasons in the environment, such as domestic weather change When it is used, the ground plane at the edge part occurs due to seasonal variation of humidity, that is, curl (c) phenomenon. There was a problem such as occurring.

이에 본 발명에서는 에틸헥실 아크릴레이트, 부틸아크릴레이트, 비닐아세테이트, 아크릴산 에스테르, 하이드록시에틸메타아크릴레이트, 아크릴산 메틸, 아크릴에틸, 그리시딜 메타 아크릴레이트 등의 모노마를,Accordingly, in the present invention, monomas such as ethylhexyl acrylate, butyl acrylate, vinyl acetate, acrylic acid ester, hydroxyethyl methacrylate, methyl acrylate, acrylethyl, and glycidyl methacrylate,

메탄올 등의 알콜계 용제, 사이크로핵산이나, 노르말핵산 등의 핵산계 용제,Alcohol solvents such as methanol, nucleic acid solvents such as cyclonucleic acid and normal nucleic acid,

에틸아세테이트, 톨루엔 등의 용제속에서,In solvents such as ethyl acetate and toluene,

벤조퍼옥사이드계, 라우로릴퍼옥사이드계, 아조비스이소부티로니트릴계 유용성 개시제로 열중합하여,Thermally polymerized with a benzoperoxide-based, lauryl peroxide-based and azobisisobutyronitrile-based oil-soluble initiator,

종래 외국산제품이 단순히 색이 들어 있는 폴리에스터 필름에 도포되어 적용되었던 점착제와는 달리, 색상 염료와 배합되어도 점착제 원래의 성질을 유지 겔화를 일으키지 않아 시공시에 문제를 발생시키지 않고, 작업 후 시간의 경과에 따른 태양광선에 의하여 그 기능이 저하되거나 탈색이 되지 않으며 내열과 내습에도 강하여 부착한 필름의 모서리 부분에 컬(curl)현상을 일으키지 않는 점착제를 제공하는 것을 기술적 과제로서 창안하였다.Unlike the pressure-sensitive adhesive, which was previously applied by applying to a polyester film containing color, foreign-made products have maintained the original properties of the pressure-sensitive adhesive even when mixed with color dyes, and do not cause gelation. The technical problem of the present invention was to provide a pressure-sensitive adhesive that does not deteriorate or discolor due to sunlight, and is resistant to heat and moisture, and does not cause curl on the edge of the attached film.

도 1은 기존의 태양광선 조절 필름의 실시예를 보여주는 단면도1 is a cross-sectional view showing an embodiment of a conventional solar control film

도 2는 태양광선 조절 필름용 점착제가 적용된 실시예를 보여주는 단면도Figure 2 is a cross-sectional view showing an embodiment to which the pressure-sensitive adhesive for solar control film is applied

□ 도면의 주요부분에 사용된 부호의 설명 □□ Explanation of symbols used in main part of drawing □

필름 : p투명점착제 : g필름 : p'Film: p Transparent Adhesive: g Film: p '

착색점착제 : g' 겔 : t 컬 : cColorant: g 'gel: t curl: c

본 발명은 열중합 방법으로 태양광선 조절 필름용 점착제를 제조함에 있어서,The present invention provides a pressure-sensitive adhesive for solar light control film by the thermal polymerization method,

적절한 초기 점착력을 유도하기 위하여 폴리마(착색력향상고분자) 전체의 유리전이 온도를 -60℃에서 -20℃로 설계하고 유리전이온도가 낮은 2-에틸핵실아크릴레이트, 부틸아크릴레이트, 에틸아크릴레이트, 라우릴메타아크릴레이트 등을 사용하고,In order to induce the proper initial adhesive force, the glass transition temperature of the entire polyma (coloring enhancement polymer) was designed from -60 ° C to -20 ° C, and 2-ethylnuclear acrylate, butyl acrylate, ethyl acrylate, Using lauryl methacrylate, etc.,

접착력은 유리전이온도가 상대적으로 높은 비닐아세테이트, 메틸아크릴레이트, 메틸메타아크릴레이트, n-부틸메타아크릴레이트 등을 사용하였다.As adhesive strength, vinyl acetate, methyl acrylate, methyl methacrylate, n-butyl methacrylate and the like having a relatively high glass transition temperature were used.

내열성은 나중에 점착제와 염료의 배합 시 배합하는 이소시아네이트계, 멜라민계, 금속킬레이트계, 에폭시계 등의 가교제를 사용하여 조절 가능하지만 점착제 자체내에서 내열성을 보강하기 위하여 그리시딜메타크릴레이트, 아크릴아마이드, n-메티롤아크릴아마이드, 디비닐벤젠, 디아세톤아크릴아마이드, 트리메티롤프로판트리아크릴레이트 등을 사용하기도 하였다.The heat resistance can be controlled by using a crosslinking agent such as isocyanate, melamine, metal chelate, epoxy, etc., which is compounded later when blending the adhesive and the dye, but in order to reinforce the heat resistance in the adhesive itself, glycidyl methacrylate, acrylamide, n-methyrol acrylamide, divinylbenzene, diacetone acrylamide, trimetholpropane triacrylate, and the like were also used.

개시제는 분자량분포도를 줄이는 방법과 분자량분포도를 높이는 방법을 병행하였다. 분자량 분포를 줄이는 방법으로 아조비스이소부티로니트릴계 개시제를 사용하였고, 분자량분포를 높이는 방법으로는 벤조퍼옥사이드계와 라우로릴퍼옥사이드계를 함께 사용하였다.The initiator combined the method of reducing the molecular weight distribution and the method of increasing the molecular weight distribution. An azobisisobutyronitrile-based initiator was used as a method of reducing the molecular weight distribution, and a benzoperoxide type and a lauryl peroxide type were used together to increase the molecular weight distribution.

관능기 모노마는 아크릴산, 메타아크릴산, 하이드록시에틸메타아크릴레이트, 하이드록시에틸아크릴레이트, 하이드록시프로필메타아크릴레이트, 하이드록시프로필아크릴레이트 등을 사용하였다. 염료와의 상용성 및 염료와 배합 후 가사시간을 단축 시켜 작업의 효율 및 작업성을 저해하는 요인이 관능기 중에서 카르복시기가 많은 쪽으로 중합된 고분자에서 발생하므로 점착제를 염료 및 가교제와 배합하여 작업 전에 겔이 발생되어 작업을 진행할 수 없는 경우와 작업이 진행되어도 폴리에스터 필름에 코팅하여 태양광선을 조절하는 필름으로 실제 적용, 즉, 자동차나 건축물에 부착하여 장시간 태양광선에 노출 시 발생하는 염료의 탈색 및 내열, 내습 등을 방지하는 방법으로 카르복시기의 양을 적절하게 조정하여 접착력의 수준을 유지하면서 진행하였다.As the functional group monoma, acrylic acid, methacrylic acid, hydroxyethyl methacrylate, hydroxyethyl acrylate, hydroxypropyl methacrylate, hydroxypropyl acrylate and the like were used. The compatibility with the dye and shortening the pot life after blending with the dye causes the efficiency and workability to be impaired in the polymer polymerized to the higher carboxyl group among the functional groups. It is a film that controls the sun's rays by coating it on polyester film even if the work cannot be progressed due to the occurrence of work. In other words, it is applied to a car or a building, and it is discolored and heat-resistant when exposed to sunlight for a long time. Proceed while maintaining the level of adhesion by appropriately adjusting the amount of carboxyl groups in a way to prevent moisture, moisture and the like.

본 발명에서의 메탄올 등의 알콜계 용제, 사이크로핵산이나, 노르말핵산 등의 핵산계 용제 에틸아세테이트, 톨루엔 등을 중합용제와 배합용제로 사용하였다. 반응유지온도는 용제 중 중합에 참여한 용제의 공비점 온도를 반응유지 온도로 하였다.Alcohol solvents such as methanol in the present invention, nucleic acid solvents such as cyclonucleic acid and normal nucleic acid, ethyl acetate, toluene, and the like were used as a polymerization solvent and a compounding solvent. The reaction holding temperature was the azeotropic boiling point temperature of the solvent participating in the polymerization in the solvent.

염료와 배합 시 동시 또는 시차를 두고 배합하여 점착제의 응집력을 높이고 접착력을 조절하는데 사용되는 가교제는 부틸멜라민계, 금속염계, 이소시아네이트계를 사용하였다.When used in combination with the dye at the same time or at the time of the crosslinking agent used to increase the cohesive strength of the pressure-sensitive adhesive and to control the adhesion was used butyl melamine type, metal salt type, isocyanate type.

중합은 에틸아세테이트 200∼400부, 메탄올 10∼100부, 톨루엔 10∼50 용제와 2-에틸핵실아크릴레이트 200∼400부, 부틸아클릴레이트 30∼100부, 비닐아세테이트 60∼180부 아크릴산 2∼12부, 이타콘산 2∼6부 벤조일퍼옥사이드와 라우로일퍼옥사이드를 각각 0.2∼1.0부씩 계량하여 환류냉각기가 설치된 반응조에서 가온하여 활성온도까지 승온 후 자체 발열이 진행 시 외온을 강제 냉각하여 발열을 제어하고 내부 반응물의 안정화 후 7∼8시간을 반응에 참여한 용제의 공비점으로 온도를 유지 한 후 냉각 방법을 이용하여 반응을 종결시키고 노르말핵산, 사이크로핵산, 톨루엔, 메타놀 등의 용제를 후배합하여 적정고형분과 점도를 맞춘다. 이때 사용되는 아크릴모노마는 2-하이드록시에틸메타크릴레이트, 그리시딜메타크릴레이트, 아크릴아마이드 등으로 기능을 보완할 수 있다. 그리고 중합 분포도를 낮게 하기 위하여 반응개시제를 아조비스이소부티로니트릴을 사용하면 효과 적이고 발열 시작 후 30분 후 또는 4시간 후에 아조비스이소부티로니트릴을 일부 용제에 녹여 투입 하므로써 고분자중합 수율의 향상을 가져올 수 있다.The polymerization was carried out with 200 to 400 parts of ethyl acetate, 10 to 100 parts of methanol, 10 to 50 parts of toluene, 200 to 400 parts of 2-ethylnuclear acrylate, 30 to 100 parts of butyl acrylate, and 60 to 180 parts of vinyl acetate. 12 parts and 2 to 6 parts of itaconic acid benzoyl peroxide and lauroyl peroxide were weighed each 0.2 to 1.0 parts, and then heated in a reaction tank equipped with a reflux cooler, and heated to an active temperature. After stabilizing the internal reactants and maintaining the temperature at the azeotropic point of the solvents involved in the reaction for 7 to 8 hours, the reaction was terminated by using a cooling method, followed by post-mixing of solvents such as normal nucleic acid, cyclonucleic acid, toluene, and methanol. Match the appropriate solids and viscosity. At this time, the acrylic monomer may be supplemented with 2-hydroxyethyl methacrylate, glycidyl methacrylate, acrylamide, and the like. The use of azobisisobutyronitrile as a reaction initiator is effective in order to lower the degree of polymerization distribution, and the improvement of polymer polymerization yield is improved by dissolving azobisisobutyronitrile in some solvent after 30 minutes or 4 hours after the start of exotherm. Can bring

상기 방법으로 중합한 태양광선 조절 필름용 점착제는 사용 시에 고형분 60%부틸메라민계 가교제를 점착제 중량비100에 대하여 0.1∼10정도로 다양하게 배합하여 다양한 점착력의 제품을 만들 수 있다. 그리고 또한 고형분 5%금속염계 가교제를 점착제 중량비100에 대하여 0.1∼10정도로 다양하게 배합하여 다양한 점착력의 제품을 만들 수 있다. 그리고 또한 고형분 50%이소시아네이트계 가교제를 점착제 중량비100에 대하여 0.1∼10정도로 다양하게 배합하여 다양한 점착력의 제품을 만들 수 있다. 이때 부틸멜라민계 가교제는 코팅과정에서 100℃이상의 열을 받으면 가교가 이루어지고 금속염계 가교제는 잔류용제를 완전히 제거시키므로 가교가 진행되며 이소시아네이트계 가교제는 상온 또는 40∼60℃에서 일정 시간 숙성을 시켜 가교가 진행 완료되어야 제품으로 사용할 수 있다.The pressure-sensitive adhesive for solar control film polymerized by the above method can be used in various formulations of a solid content 60% butylmeramine-based crosslinking agent in the range of 0.1 to 10 with respect to the pressure-sensitive adhesive weight ratio 100 to make a product of various adhesive strength. In addition, the solid content 5% metal salt-based crosslinking agent may be variously blended in an amount of about 0.1 to about 10 with respect to the pressure-sensitive adhesive weight ratio 100 to make products having various adhesive strengths. In addition, a solid content of 50% isocyanate-based crosslinking agent may be variously blended in an amount of about 0.1 to about 10 with respect to the pressure-sensitive adhesive weight ratio 100 to make products having various adhesive strengths. At this time, the butyl melamine-based crosslinking agent crosslinks when it receives heat of 100 ° C. or more during the coating process, and the metal salt-based crosslinking agent completely removes the residual solvent. You must complete this before you can use the product.

이하 본 발명의 실시예를 들어 설명한다.Hereinafter, an embodiment of the present invention will be described.

실시예 1.Example 1.

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 285중량부285 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 모노마 20중량부20 parts by weight of butyl acrylate monomar

비닐아세테이트 모노마 95중량부95% by weight of vinyl acetate monoma

아크릴산모노마 8중량부8 parts by weight of acrylic acid

이타콘산 4중량부Itaconic acid 4 parts by weight

2-하이드록시에틸메타크릴레이트 2중량부2 parts by weight of 2-hydroxyethyl methacrylate

-용제의 조성-Composition of solvent

에틸아세테이트 370중량부370 parts by weight of ethyl acetate

메틸알코올 10중량부10 parts by weight of methyl alcohol

노르말핵산 156중량부Normal nucleic acid 156 parts by weight

톨루엔 382중량부Toluene 382 parts by weight

상기 모노마와 용제중 일부를 벤조일퍼옥사이드와 라우로일퍼옥사이드를 각각 1.0중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 가온하여 활성온도까지 승온 후 자체 발열이 진행 시 외온을 강제 냉각하여 발열을 제어하고 내부 반응물의 안정화 후 7∼8시간을 반응에 참여한 용제의 공비점으로 온도를 유지한 후 냉각 방법을 이용하여 반응을 종결시키고 상기 용제 중 중합에 참여하지 않은 용제를 후 배합하여 적정고형분과 점도를 맞춘다.Some of the monoma and the solvent were measured with 1.0 parts by weight of benzoyl peroxide and lauroyl peroxide, respectively, and heated in a reaction vessel equipped with a reflux cooler to raise the temperature to the active temperature. After stabilizing the internal reactants, the temperature was maintained at the azeotropic point of the solvents participating in the reaction for 7 to 8 hours, and then the reaction was terminated by using a cooling method. Fit.

실시예 2Example 2

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 240중량부240 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 모노마 120중량부Butyl acrylate monoma 120 parts by weight

비닐아세테이트 모노마 40중량부Vinyl acetate monoma 40 parts by weight

아크릴산모노마 12중량부12 parts by weight of acrylic acid

2-하이드록시에틸메타크릴레이트 2중량부2 parts by weight of 2-hydroxyethyl methacrylate

-용제의 조성-Composition of solvent

에틸아세테이트 400중량부400 parts by weight of ethyl acetate

메틸알코올 10중량부10 parts by weight of methyl alcohol

톨루엔 382중량부Toluene 382 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

실시예 3Example 3

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 220중량부220 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 모노마 90중량부Butyl acrylate monoma 90 parts by weight

비닐아세테이트 모노마 90중량부90% by weight of vinyl acetate monoma

아크릴산모노마 6중량부6 parts by weight of acrylic acid

말레인산 모노마 2중량부2 parts by weight of maleic acid monoma

그리시딜메타크릴레이트 모노마 2중량부Glycidyl methacrylate monoma 2 parts by weight

2-하이드록시에틸메타크릴레이트모노마 4중량부4 parts by weight of 2-hydroxyethyl methacrylate mono

-용제의 조성-Composition of solvent

에틸아세테이트 520중량부520 parts by weight of ethyl acetate

노르말핵산 30중량부Normal nucleic acid 30 parts by weight

톨루엔 300중량부Toluene 300 parts by weight

메타놀 60중량부Methanol 60 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

실시예 4.Example 4.

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 280중량부280 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 모노마 20중량부20 parts by weight of butyl acrylate monomar

메틸아크릴레이트 모노마 100중량부100 parts by weight of methyl acrylate monoma

이타콘산모노마 8중량부Itaconic Acid Monoma 8 parts by weight

글리시딜메타크릴레이트모노마 2중량부2 parts by weight of glycidyl methacrylate monomer

-용제의 조성-Composition of solvent

에틸아세테이트 380중량부380 parts by weight of ethyl acetate

메틸알코올 20중량부20 parts by weight of methyl alcohol

톨루엔 382중량부Toluene 382 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

실시예 5Example 5

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 230중량부230 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 모노마 110중량부Butyl acrylate monoma 110 parts by weight

비닐아세테이트 모노마 60중량부Vinyl acetate monoma 60 parts by weight

아크릴산모노마 6중량부6 parts by weight of acrylic acid

N-메티롤아크릴아마이드 모노마 0.5중량부0.5 parts by weight of N-metholacrylamide monoma

그리시딜메타크릴레이트 모노마 2중량부Glycidyl methacrylate monoma 2 parts by weight

2-하이드록시에틸메타크릴레이트모노마 4중량부4 parts by weight of 2-hydroxyethyl methacrylate mono

-용제의 조성-Composition of solvent

에틸아세테이트 520중량부520 parts by weight of ethyl acetate

노르말핵산 30중량부Normal nucleic acid 30 parts by weight

톨루엔 300중량부Toluene 300 parts by weight

메타놀 60중량부Methanol 60 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

실시예 6Example 6

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 70중량부70 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 모노마 90중량부Butyl acrylate monoma 90 parts by weight

메틸메타크릴레이트 모노마 40중량부Methyl methacrylate monoma 40 parts by weight

아크릴산모노마 8중량부8 parts by weight of acrylic acid

말레인산 모노마 1중량부1 part by weight of maleic acid monoma

2-하이드록시에틸메타크릴레이트모노마 12중량부12 parts by weight of 2-hydroxyethyl methacrylate mono

-용제의 조성-Composition of solvent

에틸아세테이트 520중량부520 parts by weight of ethyl acetate

노르말핵산 30중량부Normal nucleic acid 30 parts by weight

톨루엔 300중량부Toluene 300 parts by weight

메타놀 60중량부Methanol 60 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

실시예 7Example 7

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 210중량부210 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 모노마 100중량부100 parts by weight of butyl acrylate monomar

비닐아세테이트 모노마 50중량부50 parts by weight of vinyl acetate monoma

메틸아세테이트 모노마 40중량부Methyl acetate monoma 40 parts by weight

아크릴산모노마 6중량부6 parts by weight of acrylic acid

말레인산 모노마 2중량부2 parts by weight of maleic acid monoma

그리시딜메타크릴레이트 모노마 2중량부Glycidyl methacrylate monoma 2 parts by weight

2-하이드록시에틸메타크릴레이트모노마 4중량부4 parts by weight of 2-hydroxyethyl methacrylate mono

-용제의 조성-Composition of solvent

에틸아세테이트 520중량부520 parts by weight of ethyl acetate

노르말핵산 30중량부Normal nucleic acid 30 parts by weight

톨루엔 300중량부Toluene 300 parts by weight

메타놀 60중량부Methanol 60 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

실시예 8Example 8

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 285중량부285 parts by weight of 2-ethylnuclear acrylate monoma

비닐아세테이트 모노마 90중량부90% by weight of vinyl acetate monoma

메틸메타크릴레이트 25중량부25 parts by weight of methyl methacrylate

아크릴산모노마 4중량부4 parts by weight of acrylic acid

2-하이드록시에틸메타크릴레이트모노마 8중량부8 parts by weight of 2-hydroxyethyl methacrylate mono

-용제의 조성-Composition of solvent

에틸아세테이트 520중량부520 parts by weight of ethyl acetate

노르말핵산 30중량부Normal nucleic acid 30 parts by weight

톨루엔 300중량부Toluene 300 parts by weight

메타놀 60중량부Methanol 60 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

실시예 9.Example 9.

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 280중량부280 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 30중량부Butyl acrylate 30 parts by weight

비닐아세테이트 모노마 90중량부90% by weight of vinyl acetate monoma

크릴산모노마 3중량부3 parts by weight of monochloric acid

트리메티롤프로판트리아크릴레이트모노마 2중량부2 parts by weight of trimetholpropane triacrylate monomer

-하이드록시에틸메타크릴레이트모노마 6중량부6 parts by weight of hydroxyethyl methacrylate monomer

용제의 조성-Composition of solvent

틸아세테이트 300중량부300 parts by weight of tilacetate

르말핵산 172중량부172 parts by weight of remal nucleic acid

루엔 132중량부132 parts by weight

타놀 60중량부Tanol 60 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

시예 10.Example 10.

모노마의 조성-Composition of monoma

틸아크릴레이트 360중량부Butyl acrylate 360 parts by weight

틸 아크릴레이트 모노마 40중량부Tetra acrylate monoma 40 parts by weight

크릴산모노마 6중량부6 parts by weight of monochloric acid

타아크릴산모노마 1중량부1 part by weight of monoacrylic acid

-하이드록시에틸메타크릴레이트모노마 6중량부6 parts by weight of hydroxyethyl methacrylate monomer

용제의 조성-Composition of solvent

틸아세테이트 300중량부300 parts by weight of tilacetate

루엔 332중량부332 parts by weight

타놀 60중량부Tanol 60 parts by weight

모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다Some of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

시예 11.Example 11.

모노마의 조성-Composition of monoma

-에틸핵실아크릴레이트 모노마 240중량부240 parts by weight of ethyl nuclear acrylate monoma

틸아크릴레이트 120중량부120 parts by weight of butyl acrylate

비닐아세테이트 모노마 40중량부Vinyl acetate monoma 40 parts by weight

아크릴산모노마 3중량부3 parts by weight of acrylic acid

아크릴아마이드 3중량부3 parts by weight of acrylamide

2-하이드록시에틸메타크릴레이트모노마 6중량부6 parts by weight of 2-hydroxyethyl methacrylate mono

-용제의 조성-Composition of solvent

에틸아세테이트 300중량부300 parts by weight of ethyl acetate

톨루엔 332중량부Toluene 332 parts by weight

메타놀 60중량부Methanol 60 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께 계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were measured together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

실시예 12.Example 12.

-모노마의 조성--Composition of monoma-

2-에틸핵실아크릴레이트 모노마 150중량부150 parts by weight of 2-ethylnuclear acrylate monoma

부틸아크릴레이트 230중량부Butyl acrylate 230 parts by weight

비닐아세테이트 모노마 20중량부20 parts by weight of vinyl acetate monoma

아크릴산모노마 10중량부10 parts by weight of acrylic acid

2-하이드록시에틸메타크릴레이트모노마 6중량부6 parts by weight of 2-hydroxyethyl methacrylate mono

-용제의 조성-Composition of solvent

에틸아세테이트 300중량부300 parts by weight of ethyl acetate

노르말핵산 172중량부Normal nucleic acid 172 parts by weight

톨루엔 132중량부Toluene 132 parts by weight

메타놀 60중량부Methanol 60 parts by weight

상기 모노마와 용제중 일부를 아조비스이소부티로니트릴 0.6중량부과 함께계량하여 환류냉각기가 설치된 반응조에서 실시예1과 같은 방법으로 중합한다A portion of the monoma and the solvent were weighed together with 0.6 parts by weight of azobisisobutyronitrile and polymerized in the same manner as in Example 1 in a reactor equipped with a reflux condenser.

상기 실시예 중합품에 의한 물성시험Physical property test by the polymerized product of Example

1) 기본 물성1) Basic Properties

·배 합 비(단위 ; Part)Compounding ratio (unit)

배합비-ⅠCompounding ratio -Ⅰ 배합비-ⅡCompounding ratio -Ⅱ 배합비-ⅢCompounding ratio -Ⅲ 실시예 1Example 1 100100 실시예 2Example 2 100100 실시예 3Example 3 100100 CAT-45CAT-45 0.50.5 0.50.5 0.50.5

주) CAT-45 : (주)삼원 무황변형 이소시아네이트계 경화제Note) CAT-45: Samwon Co., Ltd. sulfur-free modified isocyanate type

·시료제작Sample production

대상기재 : 25μ폴리에스터 필름Target material: 25μ polyester film

도 포 량 : 25g/m2건조된 상태Coating volume: 25g / m 2 dried

건 조 : 90℃ 오븐에서 5분간 건조시킴.Drying: Dry in an oven at 90 ° C for 5 minutes.

숙 성 : 60℃ 오븐에서 24시간 숙성시킴.Aging: Aged at 60 ℃ oven for 24 hours.

결 과result

접착력(g/25mm)Adhesive force (g / 25mm) 유지력(sec)Holding force (sec) 유 리Glass 80℃80 ℃ 120℃120 ℃ 배합비-ⅠCompounding ratio -Ⅰ 820820 변화 없음.No change. 변화 없음.No change. 배합비-ⅡCompounding ratio -Ⅱ 800800 변화 없음.No change. 변화 없음.No change. 배합비-ⅢCompounding ratio -Ⅲ 800800 변화 없음.No change. 변화 없음.No change. * 접착력 시험 : JIS Z. 에서 180° 박리 시 접착력(피착체 : 유리판)* 유지력 시험 : JIS Z. 0237 에서 정한 방법에 따라 첨부된 면적이25mm×25mm이고 80℃, 120℃에서 1Kg의 하중을 견디는시간을 측정 후 변화된 거리를 나타낸 것임.* Adhesion test: Adhesion at 180 ° peeling in JIS Z. (adhesive: glass plate) * Retention force: Attached area is 25mm × 25mm according to the method specified in JIS Z. 0237 It shows the changed distance after measuring the endurance time.

2) 중합품에 의한 염료 배합시험.2) Dye mix test by polymerized product.

: 염료의 배합 시험은 배합염료에 의한 점착제의 겔화 및 색깔의 선명도, 염료의 탈색도 등을 확인할 수 있는 시험으로 각 염료색깔별 상용성을 알아본다.: Dye compound test is a test that can confirm gelation of adhesive by colorant dye, clarity of color, and discoloration of dye.

2-1) 실시예 1의 배 합 비 (단위 : Part)2-1) Formulation Ratio of Example 1 (Unit: Part)

배합비-1Compounding ratio-1 배합비-2Compounding ratio-2 배합비-3Compounding ratio-3 배합비-4Compounding ratio-4 배합비-5Compounding ratio -5 배합비-6Compounding ratio-6 실시예 1Example 1 100100 100100 100100 100100 100100 100100 염료 레드Dye red 10.510.5 염료 오렌지Dye orange 10.510.5 염료 그린Dye green 10.510.5 염료 블랙Dye black 10.510.5 염료 옐로우Dye yellow 10.510.5 염료 블루Dye blue 10.510.5 경 화 제Hardener 1.01.0 1.01.0 1.01.0 1.01.0 1.01.0 1.01.0

주) 각 염료는 호도가에 및 시바가이기 제품임.Note) Each dye is a product of Hodogoe and Shivagai.

2-2) 실시예 1의 겔레이션 정도2-2) Gelation degree of Example 1

배합비-1Compounding ratio-1 배합비-2Compounding ratio-2 배합비-3Compounding ratio-3 배합비-4Compounding ratio-4 배합비-5Compounding ratio -5 배합비-6Compounding ratio-6 비 고Remarks 초기배합점도Initial Blend Viscosity 560560 565565 550550 550550 550550 560560 cps/30℃cps / 30 ℃ 1일 후 점도Viscosity after 1 day 580580 590590 550550 550550 550550 570570 cps/30℃cps / 30 ℃ 판 정Judgment ○○ ○○ ◎◎ ◎◎ ◎◎ ○○ △ : 보통○ : 양호◎ : 아주양호△: normal ○: good ◎: very good

2-3) 실시예 2의 배 합 비 (단위 : Part)2-3) Formulation Ratio of Example 2 (Unit: Part)

배합비-1Compounding ratio-1 배합비-2Compounding ratio-2 배합비-3Compounding ratio-3 배합비-4Compounding ratio-4 배합비-5Compounding ratio -5 배합비-6Compounding ratio-6 실시예 2Example 2 100100 100100 100100 100100 100100 100100 염료 레드Dye red 10.510.5 염료 오렌지Dye orange 10.510.5 염료 그린Dye green 10.510.5 염료 블랙Dye black 10.510.5 염료 옐로우Dye yellow 10.510.5 염료 블루Dye blue 10.510.5 경 화 제Hardener 1.01.0 1.01.0 1.01.0 1.01.0 1.01.0 1.01.0

주) 각 염료는 호도가에 및 시바가이기 제품임.Note) Each dye is a product of Hodogoe and Shivagai.

2-4) 실시예 2의 겔레이션 정도2-4) degree of gelation of Example 2

배합비-1Compounding ratio-1 배합비-2Compounding ratio-2 배합비-3Compounding ratio-3 배합비-4Compounding ratio-4 배합비-5Compounding ratio -5 배합비-6Compounding ratio-6 비 고Remarks 초기배합점도Initial Blend Viscosity 380380 385385 360360 360360 360360 380380 cps/30℃cps / 30 ℃ 1일 후 점도Viscosity after 1 day 400400 410410 360360 360360 360360 405405 cps/30℃cps / 30 ℃ 판 정Judgment ○○ ○○ ◎◎ ◎◎ ◎◎ ○○ △ : 보통○ : 양호◎ : 아주양호△: normal ○: good ◎: very good

2-5) 실시예 3의 배 합 비 (단위 : Part)2-5) Combination Ratio of Example 3 (Unit: Part)

배합비-1Compounding ratio-1 배합비-2Compounding ratio-2 배합비-3Compounding ratio-3 배합비-4Compounding ratio-4 배합비-5Compounding ratio -5 배합비-6Compounding ratio-6 실시예 3Example 3 100100 100100 100100 100100 100100 100100 염료 레드Dye red 10.510.5 염료 오렌지Dye orange 10.510.5 염료 그린Dye green 10.510.5 염료 블랙Dye black 10.510.5 염료 옐로우Dye yellow 10.510.5 염료 블루Dye blue 10.510.5 경 화 제Hardener 1.01.0 1.01.0 1.01.0 1.01.0 1.01.0 1.01.0

주) 각 염료는 호도가에 및 시바가이기 제품임.Note) Each dye is a product of Hodogoe and Shivagai.

2-6) 실시예 3의 겔레이션 정도2-6) degree of gelation of Example 3

배합비-1Compounding ratio-1 배합비-2Compounding ratio-2 배합비-3Compounding ratio-3 배합비-4Compounding ratio-4 배합비-5Compounding ratio -5 배합비-6Compounding ratio-6 비 고Remarks 초기배합점도Initial Blend Viscosity 420420 415415 420420 420420 420420 420420 cps/30℃cps / 30 ℃ 1일 후 점도Viscosity after 1 day 425425 420420 420420 420420 420420 415415 cps/30℃cps / 30 ℃ 판 정Judgment ◎◎ ◎◎ ◎◎ ◎◎ ◎◎ ◎◎ △ : 보통○ : 양호◎ : 아주양호△: normal ○: good ◎: very good

3) 중합품에 의한 내열, 내습성 시험3) Heat and moisture resistance test by polymerized product

: 유리판에 시료를 부착 60℃×95%RH×72시간 조건에서 시험, 점착제와 배합된 염료의 탈색 및 점착제가 수분과 온도의 영향에 의하여 유리판에서 쉽게 박리가 되거나 모서리 부분이 CURL 현상이 나타나는지에 따라 적용 가능성을 시험 하고자 한다. 이 시험은 최종제품으로 적용 되 어 무더운 여름 장마철의 습도와 온도조건을 감안하여 실험한다.: Attach sample to glass plate Test under 60 ℃ × 95% RH × 72 hours condition, discoloration of dye blended with adhesive and adhesive peel off easily from glass plate due to the influence of moisture and temperature. We will test the applicability accordingly. This test is applied as a final product, taking into account the humidity and temperature conditions of the hot summer rainy season.

① 시 험 비(단위 : Part)① Test fee (Unit: Part)

시험비-1Examination fee-1 시험비-2Examination fee-2 시험비-3Exam fee-3 실시예 1Example 1 100100 실시예 2Example 2 100100 실시예 3Example 3 100100 염료 블랙Dye black 7.57.5 7.57.5 7.57.5 염료 블루Dye blue 33 33 33 경 화 제Hardener 1.01.0 1.01.0 1.01.0

주) 각 염료는 호도가에 및 시바가이기 제품임.Note) Each dye is a product of Hodogoe and Shivagai.

② 결 과② Result

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비고Remarks 박 리 력Peeling force 800800 760760 750750 SUS/g/25mmSUS / g / 25mm CURL 현상CURL phenomenon 이상 없음clear 이상 없음clear 이상 없음clear 염료 탈색성Dye depigmentation ○○ △△ ◎◎ ◎ : 아주양호○ : 양호△ : 보통◎: Very good ○: Good △: Normal

상기와 같이 염료와 배합하여도 작업에 무리가 없고 또한 자동차 유리창 및 건물의 유리창에 부착하여 태양광선을 장기간 받아도 염료의 탈색이 진행되지 않는 본 발명 태양광선 조절용 필름용 점착제를 통하여 색깔이 있는 폴리에스터 필름을 사용치 않고도 다양한 색깔의 태양광선 조절용 필름의 효과를 낼 수 있게되었다. 이로써 고가로 수입되는 색필름을 사용하지 않고 투명한 무색의 폴리에스터 필름을 그대로 사용하여 저렴한 가격으로 소비자에게 색깔있는 태양광선 조절용 필름의 효과를 낼수 있도록 제공할 수 있어, 생산자와 소비자 양쪽에 경제적으로 큰 이득을 줄 수 있는 그 효과가 다대한 발명이라 하겠다.Even if blended with the dye as described above, it is easy to work, and also attached to the glass window of the car window and the building, the colored polyester through the pressure-sensitive adhesive for the solar light control film of the present invention does not progress the dye even after receiving sunlight for a long time It is possible to produce the effects of various colors of the sun control film without using the film. This makes it possible to provide consumers with the effect of colored solar control film at low price by using transparent colorless polyester film as it is without using expensive imported color film. The effect that can benefit is a great invention.

Claims (3)

중합용제로서 에틸아세테이트 200∼400부와, 모노마로 메탄올 10∼60부 와 2-에틸핵실아크릴레이트 200∼400부, 비닐아세테이트 60∼180부 아크릴산 2∼12부, 개시제로 벤조일퍼옥사이드와 라우로일퍼옥사이드를 각각 0.5∼1.0부씩 계량하여 환류냉각기가 설치된 반응조에서 가온하여 중합하여 유리전이온도 -60℃∼-20℃로 제조하는 것을 특징으로하는 태양광선 조절 필름용 아크릴 점착제 및 그 제조방법200 to 400 parts of ethyl acetate as a polymerization solvent, 10 to 60 parts of monomaro methanol, 200 to 400 parts of 2-ethylnuclear acrylate, 60 to 180 parts of vinyl acetate, 2 to 12 parts of acrylic acid, benzoyl peroxide and lauro as an initiator The acrylic pressure-sensitive adhesive for solar control film and its manufacturing method, characterized in that each of the peroxide is measured by 0.5 to 1.0 parts by heating in a reaction tank equipped with a reflux cooler and polymerized to produce a glass transition temperature of -60 ℃ to -20 ℃. 중합용제에 노르말핵산, 사이크로핵산계를 선택사용하고 모노마로 부틸아크릴레이트를 20∼80중량부 사용하고 그리시딜메타크릴레이트, 2-하이드록시메타크릴레이트를 사용하여 반응개시제 아조비스이소부티로니트릴을 선행에 0.1∼1.0중량부 계량하여 환류냉각기가 설치된 반응조에서 가온하여 중합하고 발열 30분 후 아조비스이소부티로니트릴을 0.1∼1.0중량부 투입하여 제조하는 것을 특징으로 하는 태양광선 조절 필름용 아크릴 점착제 및 그 제조방법Azobisisobutyro is selected from the group consisting of normal nucleic acid and cyclonucleic acid, 20 to 80 parts by weight of monomaro butyl acrylate, and glycidyl methacrylate and 2-hydroxy methacrylate. 0.1 to 1.0 parts by weight of nitrile was previously measured and heated in a reactor equipped with a reflux condenser, followed by polymerization, and 30 minutes after exotherm, azobisisobutyronitrile was prepared by adding 0.1 to 1.0 parts by weight of a solar control film. Acrylic adhesive and its manufacturing method 청구항 2에 있어서,The method according to claim 2, 모노마로 2-하이드록시메타크릴레이트를 사용하고 반응개시제로 아조비스이소부티로니트릴을 선행에 0.1∼1.0중량부 계량하여 환류냉각기가 설치된 반응조에서 가온하여 중합하고 발열 4 시간 후 아조비스이소부티로니트릴을 0.1∼1.0중량부 투입하여 제조하는 것을 특징으로하는 태양광선 조절 필름용 아크릴 점착제 및 그 제조방법0.1-1.0 parts by weight of azobisisobutyronitrile was previously measured using monomaro 2-hydroxymethacrylate, and the reaction initiator was warmed and polymerized in a reactor equipped with a reflux condenser, followed by azobisisobutyro for 4 hours. 0.1-1.0 parts by weight of nitrile is prepared by producing an acrylic pressure-sensitive adhesive for solar control film and its manufacturing method
KR1020020011192A 2002-03-02 2002-03-02 The adhesive for the film, that is regulating the rays of the sun, and its manufacturing way KR20020056834A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100500042B1 (en) * 2002-03-06 2005-07-07 (주) 코스모텍 The method for manufacturing and adhesive composition
WO2013118932A1 (en) * 2012-02-10 2013-08-15 (주)앤디포스 Highly transparent solar film having superior anti-oxidation effect
KR101350213B1 (en) * 2013-07-23 2014-01-15 (주)에이에프씨 The method for manufacturing infrared blocking coating agent and film using the same
CN115466584A (en) * 2022-09-09 2022-12-13 苏州市贝特利高分子材料股份有限公司 High surface tension waterproof adhesive with durable bonding strength

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Publication number Priority date Publication date Assignee Title
JPH069932A (en) * 1992-06-25 1994-01-18 Tosoh Corp Adhesive composition
KR20010016674A (en) * 1999-08-02 2001-03-05 한형수 Pressure sensitive adhesive
KR100314949B1 (en) * 1998-03-26 2001-11-23 호소이 쇼지로 Attachment film for electronic display device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH069932A (en) * 1992-06-25 1994-01-18 Tosoh Corp Adhesive composition
KR100314949B1 (en) * 1998-03-26 2001-11-23 호소이 쇼지로 Attachment film for electronic display device
KR20010016674A (en) * 1999-08-02 2001-03-05 한형수 Pressure sensitive adhesive

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100500042B1 (en) * 2002-03-06 2005-07-07 (주) 코스모텍 The method for manufacturing and adhesive composition
WO2013118932A1 (en) * 2012-02-10 2013-08-15 (주)앤디포스 Highly transparent solar film having superior anti-oxidation effect
KR101350213B1 (en) * 2013-07-23 2014-01-15 (주)에이에프씨 The method for manufacturing infrared blocking coating agent and film using the same
CN115466584A (en) * 2022-09-09 2022-12-13 苏州市贝特利高分子材料股份有限公司 High surface tension waterproof adhesive with durable bonding strength
CN115466584B (en) * 2022-09-09 2024-03-26 苏州市贝特利高分子材料股份有限公司 High-surface tension waterproof adhesive with durable bonding strength

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