KR200189487Y1 - Organics from leather wastewater and high concentration organic wastewater. nitrogen. Phosphorus and heavy metal removal device - Google Patents
Organics from leather wastewater and high concentration organic wastewater. nitrogen. Phosphorus and heavy metal removal device Download PDFInfo
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- KR200189487Y1 KR200189487Y1 KR2019990030100U KR19990030100U KR200189487Y1 KR 200189487 Y1 KR200189487 Y1 KR 200189487Y1 KR 2019990030100 U KR2019990030100 U KR 2019990030100U KR 19990030100 U KR19990030100 U KR 19990030100U KR 200189487 Y1 KR200189487 Y1 KR 200189487Y1
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- South Korea
- Prior art keywords
- wastewater
- ozone
- reaction
- ultrasonic
- leather
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- 239000002351 wastewater Substances 0.000 title claims abstract description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title abstract description 8
- 239000010985 leather Substances 0.000 title abstract description 7
- 229910052757 nitrogen Inorganic materials 0.000 title abstract description 4
- 229910001385 heavy metal Inorganic materials 0.000 title abstract description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title description 4
- 229910052698 phosphorus Inorganic materials 0.000 title description 4
- 239000011574 phosphorus Substances 0.000 title description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000001914 filtration Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 239000005416 organic matter Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 2
- 230000002452 interceptive effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 11
- 238000000746 purification Methods 0.000 abstract description 2
- 239000010802 sludge Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 2
- 241000251468 Actinopterygii Species 0.000 abstract 1
- 241000195628 Chlorophyta Species 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000012851 eutrophication Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 230000031018 biological processes and functions Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
- C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
Landscapes
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
(1) 고안이 속한 기술 분야(1) The technical field to which the design belongs
본고안은 폐수속에 초음파와 오존과 자외선을 병용반응시켜 피혁폐수 및 고농도 유기성 폐수를 정화처리하는 장치This paper is a device that purifies leather wastewater and high concentration organic wastewater by combining ultrasonic wave, ozone and ultraviolet ray in wastewater.
(2) 고안의 목적(2) Purpose of devising
고농도 난분해 유기성 폐수나피혁폐수의 정화를 위하여 초음파. 오존. 자외선을 병용하여 폐수속에 반응케 하는데 이때 반응의 효능 즉 분해 산화력을 향상시키기 위하여 다단계 계단식 반응조를 연결해 두어 폐수를 상류토록 하고 또 사각지대가 없게하기 위해 초음파의 반사체를 두고 또 폐수를 고속으로 교반시켜 오존 효능을 높임과 아울러 자외선 빛을 굴절시켜 빛의 모임현상을 일으키게 하여 효능을 향상시킨다.Ultrasonic wave for the purification of high concentration hardly decomposed organic wastewater or leather wastewater. ozone. In order to improve the efficacy of the reaction, that is, decomposition oxidative power, a multi-stage cascade reactor is connected to the waste water so that the waste water is upstream, and the waste water is stirred at a high speed with a reflector of ultrasonic waves in order to avoid blind spots. In addition to improving the ozone effect, the ultraviolet light is refracted to cause light gathering to improve the efficacy.
(3) 고안의 구성(3) constitution
폐수가 유입되면 제일 낮은 반응조에서 오존과 초음파의 조사에 의해 병용 반응을 일으키게 되고 계속 연결된 한단계 위의 반응조로 상류하면서 연속 반응을 일으키게하며 이때 반응의 사각지대를 없애기 위해 초음파 반사체를 두며 마지막 반응조에는 자외선램프와 교반조장치를 두어 오존기포의 원활한 반응을 돕게하고 또 자외선 빛이 굴절되어 빛의 모임현상이 있게하고 잔류 슬러지의 완벽한 제거를 위하여 여과조를 두는 장치의 구성이다.When the wastewater flows in, the lowest reaction tank causes the combined reaction by the irradiation of ozone and ultrasonic waves, and the continuous reaction occurs upstream to the reactor connected up one level continuously. At this time, an ultrasonic reflector is placed to remove the blind spot of the reaction. A lamp and agitator are installed to help the ozone bubbles to react smoothly. Also, the ultraviolet light is refracted to collect the light, and a filter tank is installed to completely remove the residual sludge.
(4) 고안의 효과(4) effect of design
난분해성 유기 폐수나피혁폐수속에는 질소. 인. 중금속인크롬 등이 함유되어 있어 강이나 바다에 유입되면 부영양화 현상이 일어나 녹조나 적조현상이 일어나 물고기 등이 살멸 당하게 되는데 이러한 현상을 예방할수 있다.Nitrogen in refractory organic wastewater or leather wastewater. sign. Heavy metals such as chromium are contained, so when it enters rivers or the sea, eutrophication occurs and green algae or red tide occur, causing fish to be killed.
Description
- 초음파 및 오존과 자외선의 복합작용에 의하여 난분해성 유무기물 폐수처리시 초음파와 오존을 병용하고 자외선 존재하에서 오존을 첨가하는 방법을 적용하여 BOD, COD, 슬러지, 질소, 인, 중금속 등의 처리효율을 검토하였는데 복합산화법의 정화이론을 보면 생물학적공법과의 처리 개념이 전혀 상이한데 생물학적 공법은 유기물을 미생물이 (섭취)하는 것이고 복합처리법은 유기물을 고속으로 분해산화하여 물과 이산화탄소로 분해하는 것이다.-Treatment of BOD, COD, Sludge, Nitrogen, Phosphorus, Heavy Metal, etc According to the purification theory of the complex oxidation method, the concept of treatment with the biological process is completely different. The biological process is the ingestion of organic matter by microorganisms, and the complex treatment method is that the organic matter is rapidly decomposed and oxidized into water and carbon dioxide.
유기물은 고분자 유기물과 저분자 유기물로 분류되며 또 저분자 유기물 중에는 극성이 강한 저분자 유기물(난분해성 물질)로 이루어져 있어 오존 단독으로는 유기물을 물과 이산화탄소로 분해하는 것은 곤란하고 실질적인 오존처리 조건하에서는 처리후에 카르복실산처럼 극성이 큰 저분자 유기물(난분해성 물질)이 잔류하게 되는데 이와같은 물질을 완전히 분해하기 위해 수중에 초음파를 조사하면 수를 헤아릴 수 없는 미세한 기포가 발생하게 되고 기포가 많을수록 오존과 접촉 면적이 늘어나 유기물이 빨리 분해되며 오존과 자외선에 의해 고속으 산화되고 초음파의 작은 기포가 오존의 큰 기포를 파쇄해 주므로서 오존 효능은 향상되고 비례하여 미파괴오존(폐오존)도 감소된다. 이리하여 초음파와 오존과 자외선을 병용하는 공법이 취급되었고 이복합반응에 의하여 극성이 큰 저분자 유기물이 물과 이산화탄소로 완전분해되며 이때 발생한 부유물질을 특수여과 기능을 통하여 완벽하게 제거하여 오염전의 맑은 물처럼 된다.Organic matters are classified into high molecular weight organic matters and low molecular weight organic matters. Among the low molecular weight organic matters, they are composed of highly polarized low molecular weight organic matters (hard-decomposable materials). So, ozone alone is difficult to decompose organic matters into water and carbon dioxide. Low molecular organic materials (hardly decomposable substances), such as acids, remain, and when ultrasonic waves are irradiated in water to completely decompose such substances, an uncountable fine bubble is generated. As the organic matter is rapidly decomposed, it is rapidly oxidized by ozone and ultraviolet rays, and the small bubbles of ultrasonic waves break up the large bubbles of ozone, thereby improving ozone efficiency and proportionally reducing undestructed ozone (waste ozone). In this way, a combination of ultrasonic waves, ozone and ultraviolet light was handled, and a low-molecular organic substance with high polarity was completely decomposed into water and carbon dioxide by a heterogeneous reaction, and the suspended solids were completely removed through a special filtration function. Become like
o 기능성 및 경제성 비교o Functional and economic comparison
o 종래의 기술과 본고안과의 처리수질비교(피혁폐수 : 가죽모피폐수)o Comparison of treated water quality between conventional technology and this paper (leather wastewater: leather fur wastewater)
- 무기물과의 반응-Reaction with minerals;
- 각종 유기물과의 반응- Reaction with various organic substances
- 질소와의 반응-Reaction with nitrogen
- 인과의 반응-Reaction with phosphorus;
(1)유입구 (2)반응조용기 (3)오존산기관 (4)초음파진동판 (5)초음파반사체 (6)여과조 (7)여과처리수 (8)감속회전모타 (9)자외선램프 (10)교반날개 (11)방류조 (12)배출구(1) inlets (2) reactors (3) ozone acid engines (4) ultrasound vibrating plates (5) ultrasonic reflectors (6) filtration tanks (7) filtration water (8) deceleration rotary motors (9) ultraviolet lamps (10) stirring Wings (11) Discharge Tanks (12) Outlets
이를 실현하기 위하여 유입되는 폐수가 반응조에 유입되기 전에 부유물질을 최대한 제거 한후의 폐수를 반응조용기(2)에 유입되게 하고 폐수는 상류가 되도록 하는데 이때 연속 반응이 되도록 다단게 계단식의 반응조를 연결해 두는데 각 반응조 밑바닥에는 오존산기관(3)과 초음파진동판(4)을 설치하고 초음파 조사시의 사각지대를 없애기 위해 초음파반사체(5)를 두어 초음파가 서로 간섭하면서 효능을 높이고 또 폐수속에 교반장치 즉 교반날개(10)를 장치하여 폐수의 기포를 많이 형성시키며 오존과의 접촉면적을 많이하게 하여 원활한 반응을 일으키게 하고 다음으로 여과공정(6)을 두어 부유물질을 제거한다음 방류조에는 오존을 조사하고 여기에 폐수를 회전시켜 자외선 빛을 굴절시키므로 처리효능을 극대화시키는 장치로 구성된 다.In order to realize this, before the incoming waste water is introduced into the reactor, the waste water after removing the suspended solids as much as possible is allowed to flow into the reactor vessel (2) and the waste water is upstream. At the bottom of each reactor, an ozone acid pipe (3) and an ultrasonic vibrating plate (4) are installed, and an ultrasonic reflector (5) is placed to remove blind spots during ultrasonic irradiation, so that the ultrasonic waves interfere with each other to increase the efficacy, Equipped with agitating blades (10) to form a lot of bubbles in the waste water, to increase the contact area with ozone to cause a smooth reaction, and then to remove the suspended solids by the filtration step (6) and to irradiate the discharge tank with ozone It consists of a device that maximizes treatment efficiency by rotating the wastewater to refract ultraviolet light. All.
1.난분해성 유무기성 폐수중 피혁폐수나 침출수 및 축산폐수 같은 것은 악취 및 색도가 진하여 강이나 바다에 유입되면 엄청난 오염원이 되는데 또 여기에 질소. 인 등도 함유되어 있어 생물이 살 수 없는 지경에 이르는데 이를 안정적으로 제거할수 있는 효과가 있다.1. Among the non-degradable organic-inorganic wastewaters, such as leather wastewater, leachate water and livestock wastewater, the odor and color are so strong that it becomes a huge source of pollution when it enters the river or the sea. It also contains phosphorus, which leads to an area where organisms cannot live, and it can effectively remove it.
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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KR2019990030100U KR200189487Y1 (en) | 1999-12-28 | 1999-12-28 | Organics from leather wastewater and high concentration organic wastewater. nitrogen. Phosphorus and heavy metal removal device |
Applications Claiming Priority (1)
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KR2019990030100U KR200189487Y1 (en) | 1999-12-28 | 1999-12-28 | Organics from leather wastewater and high concentration organic wastewater. nitrogen. Phosphorus and heavy metal removal device |
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KR200189487Y1 true KR200189487Y1 (en) | 2000-07-15 |
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KR2019990030100U KR200189487Y1 (en) | 1999-12-28 | 1999-12-28 | Organics from leather wastewater and high concentration organic wastewater. nitrogen. Phosphorus and heavy metal removal device |
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KR (1) | KR200189487Y1 (en) |
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1999
- 1999-12-28 KR KR2019990030100U patent/KR200189487Y1/en not_active IP Right Cessation
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