KR20010105648A - A Match Method of Rubber for Continuous Match and System of Rubber Match - Google Patents

A Match Method of Rubber for Continuous Match and System of Rubber Match Download PDF

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KR20010105648A
KR20010105648A KR1020000026320A KR20000026320A KR20010105648A KR 20010105648 A KR20010105648 A KR 20010105648A KR 1020000026320 A KR1020000026320 A KR 1020000026320A KR 20000026320 A KR20000026320 A KR 20000026320A KR 20010105648 A KR20010105648 A KR 20010105648A
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South Korea
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rubber
mixer
mixing
sulfur
match
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KR1020000026320A
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Korean (ko)
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KR100383675B1 (en
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문동석
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신형인
금호산업 주식회사
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/80Falling particle mixers, e.g. with repeated agitation along a vertical axis
    • B01F25/90Falling particle mixers, e.g. with repeated agitation along a vertical axis with moving or vibrating means, e.g. stirrers, for enhancing the mixing
    • B01F25/901Falling particle mixers, e.g. with repeated agitation along a vertical axis with moving or vibrating means, e.g. stirrers, for enhancing the mixing using one central conveyor or several separate conveyors, e.g. belt, screw conveyors or vibrating tables, for discharging flows from receptacles, e.g. in layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F31/00Mixers with shaking, oscillating, or vibrating mechanisms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00Characterised by the use of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers

Abstract

The invention concerns novel 2-(iminomethyl)amino-phenyl derivatives, their preparation, their application as medicines and pharmaceutical compositions containing them.

Description

연속배합을 위한 고무배합방법 및 이를 이용한 고무배합시스템{A Match Method of Rubber for Continuous Match and System of Rubber Match}Rubber Mixing Method for Continuous Mixing and Rubber Mixing System Using The Same {A Match Method of Rubber for Continuous Match and System of Rubber Match}

본 발명은 연속배합을 위한 고무배합방법 및 이를 이용한 고무배합시스템에 관한 것으로서, 타이어용 고무나 테크니컬 고무의 제조를 위한 회분식(回分式, Batch식) 배합 방식에 의존하는 종래의 방식에 탈피하여 연속식(連續式)으로 배합을 가능케 하는 고무배합시스템에 관한 것이다.The present invention relates to a rubber compounding method for a continuous compounding and a rubber compounding system using the same, continuous to escape the conventional method depending on the batch (batch type) blending method for the production of rubber for rubber or technical rubber The present invention relates to a rubber compounding system capable of compounding by a formula.

종래의 기술은 타이어용 고무 또는 테크니컬 고무용 원료 고무를 배합시 소정의 일정량씩만 배합하는 것을 반복하는 회분식 배합방법이 일반적으로 이용되고 있다. 도 1에서, 부호 1a는 원료고무 및 보강제(카본 블랙,Carbon Black)와충전제(Filler)등의 여러 배합재료를 혼합하는 마스터배치(Master Batch) 배합용 믹서를 나타내며. 하부에 도시한 부호 1b는 상기 마스터배치 배합물에 유황과 같은 가루용 약품을 혼합하여 배합하는 용도로 사용되는 유황배합용 믹서(또는 Final Mixing이라 함)를 나타낸다.In the prior art, a batch mixing method is generally used in which a rubber compound for tires or rubber for technical rubbers is mixed in a predetermined amount only. In Fig. 1, reference numeral 1a denotes a master batch blending mixer for mixing various compounding materials such as raw rubber and reinforcing agent (Carbon Black) and filler (Filler). The symbol 1b shown at the bottom represents a sulfur mixing mixer (or final mixing) used for mixing and mixing a powdered chemical such as sulfur in the master batch formulation.

도면의 상부에 도시한 바와 같이, 마스터배치용 믹서(1a)의 하단부에는 통상적으로 압출기(2)와 시팅롤(Sheeting Roll: 3)이 장착되어 믹서에서 배합된 고무를 시팅할 수 있도록 구성되어 있다.As shown in the upper part of the drawing, the lower end of the masterbatch mixer 1a is typically equipped with an extruder 2 and a seating roll 3 so that the rubber compounded in the mixer can be seated. .

따라서, 계량 콘베어(9a)에 의해 계량, 절단된 원료고무(10)는 마스터배치 믹서(1a)에서 여러 배합재료와 혼합되어 상기 압출기(2)와 시팅롤(Sheeting Roll: 3)를 거쳐 시팅된다. 이렇게 제조된 시팅 고무(5)는 운송벨트(4), 이형용액(離型溶液)이 들어있는 디핑용액탱크(6) 그리고 냉각, 건조용 배치오프장치(Batch Off Machine: 7)를 경유하여 적재다이(8)에 적재된다.Therefore, the raw material rubber 10 weighed and cut by the weighing conveyor 9a is mixed with various compounding materials in the masterbatch mixer 1a and seated through the extruder 2 and the sheeting roll 3. . The seating rubber (5) thus prepared is loaded via a transport belt (4), a dipping solution tank (6) containing a release solution, and a batch off machine (7) for cooling and drying. Loaded on the die 8.

그리고, 하부의 유황배합용 믹서(1b)의 하단부에는 통상적으로 덤프 밀(Dump Mill: 12)과 후방의 유황배합용 개방밀(Open Mill: 13)이 설치되어 있으며, 개방밀 이후의 적재까지의 과정은 앞서의 마스터배치용 믹서(1a)의 시팅롤(3)이후의 과정과 같다In addition, a lower end of the sulfur mixing mixer 1b is typically provided with a dump mill 12 and an open mill 13 for rear sulfur mixing. The procedure is the same as that after the seating roll 3 of the masterbatch mixer 1a.

유황배합용 믹서(1b) 상단부의 배합재료 투입구의 전방에는 상술한 마스터배치용 믹서(1a)에서 여러 회수의 배합과정을 마친 고무가 배치되어 있으며, 계량 콘베어(9b)를 거쳐 정해진 량만큼 절단, 계량되어 믹서(1b)의 내부로 투입되어 배합된다. 여기에서 배합이 완료되어 적재된 고무는 이후에 압연 및 압출 공정을 거친다.In front of the mixing material inlet of the upper end of the sulfur mixing mixer 1b, a rubber is disposed in the above-mentioned master batch mixer 1a, which has been subjected to several times of mixing, and is cut by a predetermined amount via a weighing conveyor 9b. It is weighed and fed into the mixer 1b and blended. Here, the compounded rubber is loaded and then subjected to a rolling and extrusion process.

그런데, 이러한 종래의 방법에 있어서, 마스터배치 배합물은 그 배합성이 까다롭고 난이한 관계로 통상 수 차례의 배합 단계를 거쳐야만 비로소 유황배합용 믹서로 운반되어 유황배합을 할 수 있다. 즉, 도면에서 화살표 위부분의 배합과정을 수 차례 거쳐야 유황배합과정으로 진행될 수 있으므로, 과정이 번거로운 문제점이 있었다.However, in such a conventional method, the masterbatch compound is difficult and difficult to mix, and thus, the masterbatch compound is usually transferred to the sulfur blending mixer to be sulfur blended only after several mixing steps. That is, since the sulfur compounding process can only proceed through the compounding process of the upper portion of the arrow several times, there was a troublesome process.

도 2a 및 도 2b는 종래의 고무 연속배합장치를 도시한 도면이다.2a and 2b is a view showing a conventional rubber continuous mixing device.

도 2a는 탄뎀믹서(Tandem Mixer)를 도시한 것으로, 이는 상술한 2개의 믹서를 상하로 일체화시킨 것으로, 즉, 마스터배치용 믹서와 유황배치용 믹서를 상하에 일체형으로 제조한 것이다. 유황배합믹서(21)이후에 설치된 나머지 장치는 상술한 종래기술에서와 같다.Figure 2a shows a tandem mixer (Tandem Mixer), which is a combination of the above-described two mixers up and down, that is, a master batch mixer and a sulfur batch mixer is manufactured in one body up and down. The remaining apparatus installed after the sulfur mixture mixer 21 is the same as in the above-mentioned prior art.

상부의 마스터배치용 믹서(20)에서 원료 고무 및 보강제등의 배합재료를 배합하여 마스터배치 고무배합물을 만들며, 이는 즉시 하부의 유황배합용 믹서(21)로 토출되어 유황 등의 약품등과 배합되는 과정을 거친다.In the upper masterbatch mixer 20, the blending material such as raw rubber and reinforcing agent is blended to make a masterbatch rubber compound, which is immediately discharged to the lower sulfur blender 21 to be combined with chemicals such as sulfur. Go through the process.

그런데, 이러한 연속배치에서는 유황배합용 믹서에 투입되는 고무의 적정 온도를 맞추기 어려운 단점이 있다. 즉, 마스터배치용 믹서를 거쳐 유황배합용 믹서로 투입되는 고무의 온도는 약 150-160℃인데, 이러한 온도는 유황배합용 믹서로부터 100-105℃ 온도의 고무를 얻기에는 부적절한 온도여서 상용화되기 어려운 단점이 있다.However, in such a continuous arrangement, there is a disadvantage that it is difficult to match the appropriate temperature of the rubber that is added to the sulfur mixing mixer. That is, the temperature of the rubber introduced into the sulfur mixing mixer through the master batch mixer is about 150-160 ℃, which is not suitable for commercialization of the rubber of 100-105 ℃ temperature from the sulfur mixing mixer is difficult to commercialize There are disadvantages.

도 2b는 종래의 압출기 형식의 연속배합장치에 관한 것이다. 도면에 도시한바와 같이, 일반적인 고무 압출용 압출기에 비해 길이가 더 긴 구성을 가지고 있다. 이러한 압출기 형식의 연속배합장치(22)는 마스터배치용 구간(22a), 유황배합용 구간(22b)으로 구분되어 있으며, 상부에 형성된 다수의 투입구로 배합재료들을 투입할 수 있도록 되어 있다.Figure 2b relates to a continuous mixer of the conventional extruder type. As shown in the figure, it has a longer configuration than the general rubber extruder. The continuous mixing device 22 of the extruder type is divided into a master batch section 22a and a sulfur blend section 22b, and is capable of injecting the blending materials into a plurality of inlets formed on the top.

마스터배치용 구간(22a)에서는 원료고무 투입구(23), 보강제 및 충전제 투입구(24) 및 각종 공정재료 투입구(25)로 각각의 배합재료들이 투입되면서 마스터배치용 고무가 배합이 되며, 이 배합물은 유황배합용 구간(22b)으로 진행되어 약품 투입구(26)으로부터 투입된 약품과 혼합되어 배합이 완료된다.In the master batch section 22a, the master batch rubber is blended with the respective compounding materials introduced into the raw material rubber inlet 23, the reinforcing agent and the filler inlet 24, and the various process material inlets 25. Proceeds to the sulfur mixing section 22b is mixed with the chemicals injected from the chemical inlet 26 is completed.

그런데, 이러한 장치는 높은 탄성도의 원료 고무 배합에 필요한 충분한 동력을 배합물에 가해주지 못하므로 고무 제조용으로는 적합하지 않은 단점이 있다.By the way, such a device does not apply sufficient power required for high elasticity raw rubber compounding to the compounding, there is a disadvantage that is not suitable for rubber production.

본 발명은 고무배합 작업과정을 간단하게 함과 동시에 배합효율과 생산성의 극대화를 얻음과 동시에 고무제조 비용을 줄이는 것을 목적으로 한다.The present invention aims to simplify the rubber compounding process and at the same time to maximize the compounding efficiency and productivity while reducing the rubber manufacturing cost.

도 1은 종래의 회분식 방법에 따른 마스터배치배합용 믹서 및 유황배합용 믹서와 주변 장치를 도시한 도면,1 is a view showing a master batch mixing mixer and a sulfur mixing mixer and a peripheral device according to a conventional batch method;

도 2는 종래의 연속배합장치 및 주변 장치를 도시한 도면,2 is a view showing a conventional continuous mixing device and a peripheral device,

도 3은 본 발명에 따른 연속배합을 위한 고무배합시스템의 구성도이다.3 is a block diagram of a rubber compounding system for continuous blending according to the present invention.

상기한 목적을 이루기 위해 본 발명의 고무배합시스템은 상기 마스터배치 배합용 믹서와 유황배합용 믹서를 하나의 일련 작업 라인에 배열하여 고무의 배합을 연속적으로 수행할 수 있도록 구성되며, 상기 두 믹서 사이에는 배합된 고무의 냉각을 위한 운송콘베어 및 개방밀을 배치하는 것을 특징으로 한다.In order to achieve the above object, the rubber compounding system of the present invention is configured to continuously perform the rubber compounding by arranging the masterbatch blending mixer and the sulfur blending mixer in one serial work line, and between the two mixers. It is characterized by arranging a transport conveyor and an open mill for cooling the blended rubber.

본발명의 연속배합을 위한 고무배합방법 및 이를 이용한 고무배합시스템은 계량콘베어를 거쳐 계량,절단된 원료고무를 마스터배치용 믹서에 의해 배합하여 시팅하는 단계와; 상기 마스터배치용 믹서의 하부에 배치된 다수의 개방밀을 거쳐 상기 시트고무를 가공하는 단계와; 비교적 길이가 긴 운송콘베어를 거쳐 상기 가공된 시트고무를 운송하는 단계와; 상기 시트고무를 계량 콘베어에 의해 계량한 후, 유황배합용 믹서로 유황배합하는 단계와; 덤프 밀과 개방밀을 거쳐 가공하는 단계와; 상기 시트 고무의 서로간의 점착을 방지하도록 이형용액(離型溶液)이 들어있는 디핑용액탱크를 통과시키는 단계와; 운송 벨트, 냉각, 건조용 배치오프장치를 경유하여 적재하는 단계를 포함하는 것을 특징으로 한다.Rubber compounding method and a rubber compounding system using the same for the continuous blending of the present invention comprises the steps of mixing and weighing raw material rubber weighed and cut through a weighing conveyor by a master batch mixer; Processing the sheet rubber through a plurality of open mills arranged under the masterbatch mixer; Transporting the processed sheet rubber through a relatively long transport conveyor; Weighing the sheet rubber with a metering conveyor and then sulfur blending with a sulfur blending mixer; Processing through a dump mill and an open mill; Passing a dipping solution tank containing a release solution to prevent adhesion of the sheet rubber to each other; And loading via a transport belt, a cooling and drying batch-off device.

이하, 도면을 참고하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the drawings.

도 3에 도시한 바와 같이, 마스터배치용 믹서(1a) 및 유황배합용 믹서(1b)가 하나의 일련 작업라인에 놓여 있다.As shown in Fig. 3, the masterbatch mixer 1a and the sulfur blending mixer 1b are placed in one serial work line.

그리고 마스터배치용 믹서(1a)의 하부쪽에는 4개의 개방밀(30a~30d)이 일정 간격을 두고 일렬로 배치되어 있다.In the lower side of the masterbatch mixer 1a, four open mills 30a to 30d are arranged in a row at regular intervals.

계량콘베어(9a)를 거쳐 계량,절단된 원료고무(10)은 마스터배치용 믹서(1a)에 의해 배합되어 토출되며, 토출된 배합 시트고무는 상기 개방밀(30a~30d)에 의해 가공한다.The raw material rubber 10 measured and cut through the measuring conveyor 9a is mixed and discharged by the master batch mixer 1a, and the discharged mixing sheet rubber is processed by the open mills 30a to 30d.

그리고, 각각의 개방밀 사이에는 가공된 배합물을 운반하기 위한 운송콘베어(32)가 설치되어 있으며, 마지막 순번의 개방밀(30d)과 유황배합용 믹서(1b)와의 사이에는 비교적 길이가 긴 운송콘베어(33)가 위치하고 있다. 상기 운송콘베어(33)는 길이가 충분히 길기 때문에 운송중 시트고무(5)가 충분히 냉각되어, 유황배합용 믹서(1b)에서 배합을 시작할 때에 요구되는 적정 온도로 상기 시트고무의 온도를 맞출 수가 있다.A transport conveyor 32 for transporting the processed compound is installed between each open mill, and a transport conveyor having a relatively long length between the last open mill 30d and the sulfur mixing mixer 1b. (33) is located. Since the conveying conveyor 33 is sufficiently long, the sheet rubber 5 is sufficiently cooled during transportation, so that the temperature of the sheet rubber can be adjusted to an appropriate temperature required when starting mixing in the sulfur mixing mixer 1b. .

계속해서, 운송콘베어(33)를 거친 시트고무(5)는 유황배합용 믹서(1b)로 투입되기 위해 계량 콘베어(9b)에 의해 계량되며, 유황배합용 믹서(1b)에 의해 유황배합된다. 이어서, 배합된 시팅 고무(5)는 덤프 밀과 개방밀(13)과 디핑용액탱크(6)를 거친 후, 운송되어 냉각 및 건조용 배치오프장치를 경유하여 적재된다.Subsequently, the sheet rubber 5 which has passed through the transportation conveyor 33 is weighed by the metering conveyor 9b to be fed into the sulfur mixing mixer 1b, and sulfur-blended by the sulfur mixing mixer 1b. Subsequently, the blended seating rubber 5 passes through the dump mill, the open mill 13 and the dipping solution tank 6, and is then transported and loaded via the batch-off device for cooling and drying.

본 발명의 또다른 실시예에서는 상기 비교적 길이가 긴 운송 콘베어(33)를 대신하여 배치오프 머신이 배치될 수도 있다.In another embodiment of the present invention, a batch off machine may be arranged in place of the relatively long transport conveyor 33.

상술한 바와 같이, 본 발명인 연속배합을 위한 고무배합시스템에서는 상기 마스터배치용 믹서에서의 배합단계를 하나의 일련 작업라인에서 마칠 수 있으므로, 작업과정이 간단해짐과 동시에 토출 배합물의 양호한 분산도 및 점도를 얻을 수 있다. 따라서, 생산성이 극대화되며, 또한 마스터배치배합용의 이형용액이 필요치 않으므로 원가절감을 달성할 수 있다.As described above, in the rubber compounding system for the continuous blending of the present invention, the blending step in the master batch mixer can be completed in one serial work line, thereby simplifying the work process and at the same time, good dispersibility and viscosity of the ejection compound. Can be obtained. Therefore, productivity is maximized and cost reduction can be achieved since no release solution for master batch formulation is required.

Claims (1)

타이어용 고무나 테크니컬 고무의 제조를 위한 고무배합방법에 있어서,In the rubber compounding method for the production of rubber for rubber or technical rubber, 계량콘베어를 거쳐 계량,절단된 원료고무를 마스터배치용 믹서에 의해 배합하여 시팅하는 단계와;Mixing and metering the raw rubber weighed and cut through the weighing conveyor by a master batch mixer; 상기 마스터배치용 믹서의 하부에 배치된 다수의 개방밀을 거쳐 상기 시트고무를 가공하는 단계와;Processing the sheet rubber through a plurality of open mills arranged under the masterbatch mixer; 비교적 길이가 긴 운송콘베어를 거쳐 상기 가공된 시트고무를 운송하는 단계와;Transporting the processed sheet rubber through a relatively long transport conveyor; 상기 시트고무를 계량 콘베어에 의해 계량한 후, 유황배합용 믹서에 의해 유황배합하는 단계와;Weighing the sheet rubber with a metering conveyor and then sulfur blending with a sulfur blending mixer; 덤프 밀과 개방밀을 거쳐 가공하는 단계와;Processing through a dump mill and an open mill; 상기 시트 고무의 서로간의 점착을 방지하도록 이형용액(離型溶液)이 들어있는 디핑용액탱크를 통과시키는 단계와;Passing a dipping solution tank containing a release solution to prevent adhesion of the sheet rubber to each other; 운송 벨트와 냉각 건조용 배치오프장치를 경유하여 적재하는 단계를 포함하는 연속배합을 위한 고무배합방법 및 이를 이용한 고무배합시스템.A rubber compounding method for continuous compounding comprising the step of loading via a transport belt and a cooling drying batch-off device, and a rubber compounding system using the same.
KR10-2000-0026320A 2000-05-17 2000-05-17 A Match Method of Rubber for Continuous Match and System of Rubber Match KR100383675B1 (en)

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