KR20010095350A - Method for manufacturing a brick and bottom materials with fly ash - Google Patents

Method for manufacturing a brick and bottom materials with fly ash Download PDF

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Publication number
KR20010095350A
KR20010095350A KR1020010004261A KR20010004261A KR20010095350A KR 20010095350 A KR20010095350 A KR 20010095350A KR 1020010004261 A KR1020010004261 A KR 1020010004261A KR 20010004261 A KR20010004261 A KR 20010004261A KR 20010095350 A KR20010095350 A KR 20010095350A
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South Korea
Prior art keywords
brick
coal ash
manufacturing
bricks
flooring
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KR1020010004261A
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Korean (ko)
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KR100415329B1 (en
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김인태
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이용석
주식회사 대평세라믹스산업
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

PURPOSE: A method of manufacturing a brick using coal ash, which is generated in thermoelectric power plant, is provided to recycle waste coal ash as a raw material for brick. CONSTITUTION: The manufacture method of a brick comprises the steps of (i) mixing coal ash 15-30wt.%, kaoline powder 50-70wt.%, 5-10wt.% of clay with a particle size of less than 0.004mm, feldspar 15-30wt.%; (ii) after molding the mixture, calcining the molded mixture in a rotary kiln at 1160deg.C.

Description

석탄재를 이용한 벽돌 및 바닥재의 제조방법{METHOD FOR MANUFACTURING A BRICK AND BOTTOM MATERIALS WITH FLY ASH}METHODS FOR MANUFACTURING A BRICK AND BOTTOM MATERIALS WITH FLY ASH}

본 발명은 석탄재를 이용한 벽돌 및 바닥재의 제조방법에 관한 것으로, 보다 상세하게는 화력발전소에서 발전을 하기 위해 석탄을 전소하고 남은 산업폐기물인 석탄재를 재료로 사용하여 벽돌과 보름달 무늬와 흑반점이 나타날 수 있도록 한 석탄재를 이용한 벽돌 및 바닥재의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing bricks and flooring materials using coal ash, and more specifically, using coal ash, which is the industrial waste remaining after burning coal to generate power in a thermal power plant, bricks and full moon patterns and black spots may appear. It relates to a method for producing bricks and flooring using coal ash.

일반적인 건축자재중 벽돌 및 바닥재를 생산하는 방법은 산화철을 많이 함유하고 있는 점토와 모래를 진공토련기로 잘 이겨 압출시킨 다음(이를 '소지'라 한다), 철사나 칼로 일정한 크기로 잘라 성형하고 건조 및 소성공정을 거쳐 길이 210㎜, 너비 100㎜, 두께 61㎜의 크기로 만들어진다.The method of producing bricks and flooring materials among general building materials is obtained by extruding clay and sand containing iron oxide well by vacuum pulverizer (referred to as 'holder'), cutting it to a certain size with wire or knife, and drying and Through the firing process, it is made into 210mm in length, 100mm in width and 61mm in thickness.

건조는 실내와 일광에서 자연 건조시키거나 폐열을 이용한 건조실에서 건조되고, 소성은 오름가마, 고리가마, 및 터널가마 등에서 900 - 1,200℃의 온도로 산화염 소성이 된다.Drying is naturally dried in the room and daylight, or dried in a drying room using waste heat, and calcination is carried out at the temperature of 900-1,200 ° C in ascending kilns, ring kilns, and tunnel kilns.

이때 소성시의 가열의 정도에 따라 서로다른 물리적 성질을 갖는 요업제품이 수득되어질 수 있으며, 적점토를 주성분으로 하여 고온소성시키는 경우 경도가 뛰어나고, 붉은색상을 갖는 벽돌이 얻어진다.In this case, ceramic products having different physical properties may be obtained according to the degree of heating at the time of firing, and red brick is obtained when the high temperature baking is performed with red clay as a main component.

또한 표면을 더 아름답게 하고 흡수성을 줄이기 위하여 유약을 바르기도 한다.It can also be glazed to make the surface more beautiful and less absorbent.

그러나, 기존의 마감재로서의 벽돌은 주로 적색 한 가지 만을 가지는 것이 대부분이며, 부분적으로 소성시에 소성을 위한 온도를 얻기 위하여 사용되는 연료를 과량 공급하여 연료의 불완전연소를 유도하므로써 연료의 불완전연소에 의한 열분해탄소의 형성 및 이의 벽돌의 표면에서의 반응, 특히 환원반응을 강제하므로써 검은색 반점이 표출되록 하는 소위 '환원소성'을 시켜 미려한 벽돌을 수득하는 경우도 있었으며, 일박적으로는 소지에 산화망간 등을 첨가하여 심한 환원염에서 소성하여 탄소침적에 의한 검은색의 벽돌을 만들기도 하고 탄소, 흑연 등이 주재료에 투입되어 상기의 검은색이 나타나게 된다.However, most of the conventional finish bricks have only one red color, and incomplete combustion of fuel is caused by incomplete combustion of fuel by partially supplying excessive fuel used to obtain the temperature for firing at the time of firing. The formation of pyrolytic carbon and reactions on the surface of the bricks, in particular reduction reactions, resulted in the so-called 'reduction firing', which causes black spots to appear, sometimes yielding beautiful bricks. It may be fired in a severe reducing salt by addition of black and the like to make black bricks by carbon deposition, and carbon and graphite may be added to the main material to produce the black color.

그러나 상기와 같은 여러방법은 일단 검은색을 생성하게 위해 주재료에 부가적인 화학작용의 발생이나 부재료가 사용되어야 하며 특히, 상기 탄소와 흑연은 고가의 재료이어서 벽돌의 제조비 상승의 원인이 된다.However, various methods such as those described above require additional chemical reactions or materials to be used to produce black color. In particular, the carbon and graphite are expensive materials, which leads to an increase in the manufacturing cost of bricks.

본 발명은 상술한 바와 같은 종래 기술이 갖는 제반 문제점을 감안하여 이를 해결하고자 창출한 것으로, 화력발전소에서 발전에 사용되고 난 후의 산업폐기물인석탄재를 벽돌 제조공정에 재료로 사용하여 상기 벽돌의 표면에 검은색의 임의의 무늬가 나타날 수 있도록 한 석탄재를 이용한 벽돌 및 바닥재의 제조방법을 제공함에 그 목적이 있다.The present invention has been made in view of the above-described problems of the prior art, and is intended to solve this problem. The industrial waste charcoal material after being used for power generation in a coal-fired power plant is used as a material in a brick manufacturing process, and the surface of the brick is black. It is an object of the present invention to provide a method of manufacturing bricks and floorings using coal ash to enable arbitrary patterns of color to appear.

본 발명의 상술한 목적은 석탄재 분말을 15% - 30%에 카올린 분말 50% - 70%, 점토 5% - 10%, 장석 15% - 30%의 비로 혼합교반후 벽돌 및 바닥재로 성형후 온도가 1,160℃로 설정된 터널가마에서 소성되도록 하여서 달성된다.The above-mentioned object of the present invention is a coal ash powder in a ratio of 15%-30% kaolin powder 50%-70%, clay 5%-10%, feldspar 15%-30% after mixing and stirring the brick and flooring material after molding A tunnel set at 1,160 ° C. is achieved by firing in a kiln.

도 1은 본 발명에 따른 보름달 무늬와 흑반점이 나타난 실시예를 도시한 벽돌 및 바닥재의 사진.1 is a photograph of a brick and flooring showing an embodiment showing the full moon pattern and black spots according to the present invention.

이하에서는, 본 발명에 따른 바람직한 일 실시예를 하기의 본 발명인 벽돌 및 바닥재의 조성물표와 첨부도면에 의거하여 보다 상세하게 설명한다.Hereinafter, a preferred embodiment according to the present invention will be described in more detail on the basis of the composition table and the accompanying drawings of the present invention brick and flooring.

본 발명인 벽돌의 조성물Composition of the inventors brick

주재료Main material 중량비(%)Weight ratio (%) 비 고Remarks 카올린kaoline 50% - 70%50%-70% 함수율 30% - 38%Water content 30%-38% 점 토Clay 5% - 10%5%-10% 장 석Feldspar 15% - 30%15%-30% 석탄재Coal ash 15% - 30%15%-30%

도 1은 본 발명에 따른 보름달 무늬와 흑반점이 나타난 실시예를 도시한 벽돌 및 바닥재의 사진으로서, 석탄재 분말을 15% - 30%로 하고 내열 내화재인 카올린 분말 50% - 70%, 입자의 지름이 0.004㎜ 이하인 점토 5% - 10%, 알루미노 규산염 광물인 장석 15% - 30%의 비로 혼합건식분쇄 하면 함수율이 30% - 38%인 카올린의 수분이 상기 석탄재에 의해 조해되고 이후 임이의 벽돌형상과 바닥재로 가압성형된 피소성물이 레일 위의 대차에 실어 내화벽돌로 짜여져 내부온도가 300℃ - 400℃인 예열대에서 서서히 고온부로 이동되며 터널의 거의 중앙에 있는 고온소성대에서는 양쪽 옆벽에 설치된 1,160℃의 온도를 내는 여러 개의 버너에 의해서 소성된다.1 is a picture of a brick and flooring showing an embodiment showing the full moon pattern and black spots according to the present invention, the coal ash powder 15%-30% and the kaolin powder 50%-70% heat-resistant refractory material, the diameter of the particles When mixed dry grinding in the ratio of 5% -10% clay and 15% -30% aluminosilicate mineral feldspar less than 0.004㎜, moisture of kaolin with water content of 30% -38% is dissolved by the coal ash, and then it becomes The fired material, which is press-molded with the floor and the flooring, is loaded on the trolley on the rail and woven into a refractory brick, and gradually moves to the high temperature part in the preheating zone where the internal temperature is 300 ° C-400 ° C. It is fired by several burners producing a temperature of 1,160 ° C.

상기 노 내부의 온도 1,160℃은 상기 석탄재가 화력발전용으로 1차 소성되어 있어 일반적인 소성온도 1,200℃가 낮춰진 것이며, 상기 터널을 통과한 다음 상기 피소성물은 냉각대에서 제품에 균열이 생기지 않도록 송풍기로 조절된다.In the furnace, the temperature of 1,160 ° C is that the coal ash is firstly fired for thermal power generation, and thus the general firing temperature is lowered to 1,200 ° C. Is adjusted.

이상에서 상세히 설명한 바와 같이, 본 발명은 상기한 종래의 방법에 의해 제조되는 벽돌에 비해 산업폐기물인 석탄재를 재료로 사용하여 함수율이 30% - 38%인 카올린의 수분을 흡수하여 성형능력이 향상되며 화력발전용으로 1차 소성이 되어 있어 흡열량이 적으며 전체적으로는 벽돌 및 바닥재의 소성온도를 낮추게 되며 기존의 재료에 의해 제조된 벽돌 및 바닥재 보다 뛰어난 보름달 무늬와 흑반점이 형성된 제품을 생산할 수 있게 된다.As described in detail above, the present invention uses the coal ash which is industrial waste as a material compared to the brick manufactured by the conventional method as a material to absorb the moisture of kaolin having a water content of 30%-38% to improve the molding capacity The primary firing is for thermal power generation, so the endothermic amount is low. Overall, the firing temperature of bricks and flooring materials is lowered, and the products with full moon patterns and black spots can be produced than the bricks and flooring materials manufactured by conventional materials.

또한 이와 같은 본 발명을 적용하면 상기 벽돌 및 바닥재의 표면색상이 수입벽돌과 동일한 미려한 색상을 나타낼 수 있는 효과를 제공한다.In addition, applying the present invention provides the effect that the surface color of the brick and flooring material can exhibit the same beautiful color as the imported brick.

Claims (1)

석탄재 분말 15% - 30%에 카올린 분말 50% - 70%, 점토 5% - 10%, 장석 15% - 30%의 비로 혼합건식분쇄후 벽돌 및 바닥재로 성형후 온도가 1,160℃로 설정된 터널가마에서 소성되도록 하는 것을 특징으로 하는 석탄재를 이용한 벽돌 및 바닥재의 제조방법.In the tunnel kiln with the temperature set to 1,160 ℃ after mixing dry grinding and molding to brick and floor materials in the ratio of coal ash powder 15%-30%, kaolin powder 50%-70%, clay 5%-10%, feldspar 15%-30% Brick and flooring manufacturing method using the coal ash, characterized in that to be fired.
KR10-2001-0004261A 2001-01-30 2001-01-30 Method for manufacturing a brick and bottom materials with fly ash KR100415329B1 (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030083497A (en) * 2002-04-23 2003-10-30 주식회사 대평세라믹스산업 Composition and manufacturing method of low temperature sintering bricks for construction
KR20040003201A (en) * 2002-07-02 2004-01-13 봉황세라믹스(주) Light clay brick using anthracite coal and manufacturing method of the same
KR20040008734A (en) * 2002-07-19 2004-01-31 한갑수 The manufacturing method of light weight material useing coal ash
KR100536880B1 (en) * 2002-08-31 2005-12-19 우성세라믹스공업 주식회사 Low temperature sintering ceramic clay bricks and pavers and method of producing them using solid industrial waste
KR100678365B1 (en) * 2003-05-19 2007-02-05 우성세라믹스공업 주식회사 Low temperature sintering porous and hollow light weight clay brick and method of producing it using solid industrial waste
KR100691644B1 (en) * 2004-08-26 2007-03-09 요업기술원 Clay brick containing coal waste and preparation method thereof
KR100795129B1 (en) * 2007-04-23 2008-01-28 (주)쎄라그린 Method for Preparing Block Having Porosity
KR101897042B1 (en) * 2017-04-28 2018-09-12 한국생산기술연구원 Method for manufacturing emotional clay bricks and emotional clay bricks manufactured by the same

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JPS57166361A (en) * 1981-04-03 1982-10-13 Tohoku Electric Power Co Manufacture of clay product mixed with coal ash
KR860001754B1 (en) * 1984-12-28 1986-10-21 김일련 Method for producing brick
KR930011260B1 (en) * 1990-11-20 1993-11-29 박병욱 Method of firebrick use with fly ash
US5362319A (en) * 1992-10-23 1994-11-08 Johnson William B Process for treating fly ash and bottom ash and the resulting product
JPH06191919A (en) * 1992-12-16 1994-07-12 Gashin Kyo Production of brick-like block from coal cinder and ash
US5584895A (en) * 1994-04-18 1996-12-17 Ngk Insulators, Ltd. Process for preparing solidified material containing coal ash
KR19990011079A (en) * 1997-07-15 1999-02-18 이익중 Block manufacturing method using mainly coal ash

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030083497A (en) * 2002-04-23 2003-10-30 주식회사 대평세라믹스산업 Composition and manufacturing method of low temperature sintering bricks for construction
KR20040003201A (en) * 2002-07-02 2004-01-13 봉황세라믹스(주) Light clay brick using anthracite coal and manufacturing method of the same
KR20040008734A (en) * 2002-07-19 2004-01-31 한갑수 The manufacturing method of light weight material useing coal ash
KR100536880B1 (en) * 2002-08-31 2005-12-19 우성세라믹스공업 주식회사 Low temperature sintering ceramic clay bricks and pavers and method of producing them using solid industrial waste
KR100678365B1 (en) * 2003-05-19 2007-02-05 우성세라믹스공업 주식회사 Low temperature sintering porous and hollow light weight clay brick and method of producing it using solid industrial waste
KR100691644B1 (en) * 2004-08-26 2007-03-09 요업기술원 Clay brick containing coal waste and preparation method thereof
KR100795129B1 (en) * 2007-04-23 2008-01-28 (주)쎄라그린 Method for Preparing Block Having Porosity
KR101897042B1 (en) * 2017-04-28 2018-09-12 한국생산기술연구원 Method for manufacturing emotional clay bricks and emotional clay bricks manufactured by the same

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