KR20010095125A - Composite sheet and method of preparation thereof - Google Patents

Composite sheet and method of preparation thereof Download PDF

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Publication number
KR20010095125A
KR20010095125A KR1020010016713A KR20010016713A KR20010095125A KR 20010095125 A KR20010095125 A KR 20010095125A KR 1020010016713 A KR1020010016713 A KR 1020010016713A KR 20010016713 A KR20010016713 A KR 20010016713A KR 20010095125 A KR20010095125 A KR 20010095125A
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KR
South Korea
Prior art keywords
composite sheet
continuous fibers
stretchable
web
layer
Prior art date
Application number
KR1020010016713A
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Korean (ko)
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KR100666969B1 (en
Inventor
단게사토루
오하타히로유키
Original Assignee
다카하라 게이이치로
유니챰 가부시키가이샤
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Publication of KR20010095125A publication Critical patent/KR20010095125A/en
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Publication of KR100666969B1 publication Critical patent/KR100666969B1/en

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/022—Mechanical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B32B7/14—Interconnection of layers using interposed adhesives or interposed materials with bonding properties applied in spaced arrangements, e.g. in stripes
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/04—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24033—Structurally defined web or sheet [e.g., overall dimension, etc.] including stitching and discrete fastener[s], coating or bond
    • Y10T428/24041—Discontinuous or differential coating, impregnation, or bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24595—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness and varying density
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24612—Composite web or sheet
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    • Y10T428/2481—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/24826—Spot bonds connect components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3008—Woven fabric has an elastic quality
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T442/3008—Woven fabric has an elastic quality
    • Y10T442/3016—Including a preformed layer other than the elastic woven fabric [e.g., fabric or film or foil or sheet layer, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065—Including strand which is of specific structural definition
    • Y10T442/313—Strand material formed of individual filaments having different chemical compositions
    • Y10T442/3138—Including inorganic filament
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T442/3707—Woven fabric including a nonwoven fabric layer other than paper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T442/3715—Nonwoven fabric layer comprises parallel arrays of strand material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T442/378—Coated, impregnated, or autogenously bonded
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    • Y10T442/602—Nonwoven fabric comprises an elastic strand or fiber material
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    • Y10T442/668—Separate nonwoven fabric layers comprise chemically different strand or fiber material
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    • Y10T442/692—Containing at least two chemically different strand or fiber materials
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    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/697—Containing at least two chemically different strand or fiber materials

Abstract

PURPOSE: To obtain a composite sheet capable of forming a layer comprising extensible filaments having small unevenness of diameter. CONSTITUTION: This composite sheet 10 is formed by intermittently joining an extensible layer 2 comprising extensible filaments 6 in one direction to at least one surface of an elastic stretchable layer 3. The filaments 6 are oriented in nearly one direction thereof and the ratio S1/S2 of tensile strength in the one direction to that in the direction intersecting the one direction at right angles is >=3.0.

Description

복합 시이트 및 이의 제조 방법{COMPOSITE SHEET AND METHOD OF PREPARATION THEREOF}COMPOSITE SHEET AND METHOD OF PREPARATION THEREOF

본 발명은 신축성 웨브와 신장성 연속 섬유로 이루어진 신장성 웨브에 의해서 형성되는 복합 시이트 및 이의 제조 방법에 관한 것이다.The present invention relates to a composite sheet formed by an extensible web composed of an elastic web and an extensible continuous fiber and a method for producing the same.

일본 특허 공개 공보 평성 제6-184897호에 개시된 복합 신축성 재료는, 인장시킴으로써 목을 붙인 재료를 인장한 상태로 인장한 신축성 시이트에 대하여 비직선형으로 배열된 적어도 3점에서 접합되고, 그러한 후에 신축성 시이트를 이완시킴으로써 제조된다. 이 제조 방법에 따르면, 목을 붙인 재료는 그것이 섬유로 이루어지는 것이라면, 신축성 시이트의 이완에 따라 많은 주름이 형성되고, 신축성 시이트의 신축성을 손상하는 일 없이, 이 시이트의 고무형 표면을 천과 같은 촉감이 좋은 것으로 바꿀 수 있다.The composite stretchable material disclosed in Japanese Patent Application Laid-Open No. 6-184897 is joined at at least three points arranged in a non-linear manner with respect to the stretchable sheet stretched in tension with the necked material by stretching, and then the stretchable sheet. It is prepared by relaxing. According to this manufacturing method, if the material with the neck is made of fibers, many wrinkles are formed by the relaxation of the elastic sheet, and the rubber-like surface of the sheet is touched like a cloth without damaging the elasticity of the elastic sheet. You can change this to a good one.

상기 공지 기술에 의하면, 목을 붙인 재료의 일례는 열가소성 합성 섬유가 서로 용착되어 이루어지는 스펀 본드 부직포를 한 방향으로 인장시킨 것이다. 랜덤 분포되어 이 부직포를 형성하고 있는 섬유는 한 방향으로 인장됨으로써, 어떤 것은 그 한 방향을 향하여 소성 변형되면서 신장되고, 또한 어떤 것은 그 한 방향을 향하여 연장되도록 그 방향을 바꿀 뿐이다. 그러한 결과로서 인장된 섬유는 가늘어지는 한편, 방향을 바꾼 것 뿐인 섬유는 굵기가 변하지 않으므로, 얻어지는 복합 신축성 재료는 섬유 직경의 편차가 크고 촉감이 고르지 않거나, 외관이 일정하지 않게 되는 일이 있다.According to the above known technique, one example of a material with a neck is a tension spun bond nonwoven fabric obtained by welding thermoplastic synthetic fibers to one another. The fibers randomly distributed to form this nonwoven fabric are stretched in one direction so that some of them are stretched while plastically deforming in one direction, and only some of them are changed so as to extend in that direction. As a result, the stretched fiber becomes thin, while the fiber having only changed direction does not change its thickness, so that the resulting stretchable composite material may have a large variation in fiber diameter and an uneven feel or an uneven appearance.

본 발명에서는, 상기 공지 기술과 같이, 신축층과 신장성 섬유로 이루어진 신장층으로 형성되고, 신장층에서의 섬유 직경의 편차가 작은 복합 시이트와 이의 제조 방법의 제공을 과제로 하고 있다.In the present invention, as in the known art, it is a problem to provide a composite sheet formed of a stretched layer made of a stretchable layer and stretchable fibers and having a small variation in fiber diameter in the stretched layer and a method for producing the same.

도 1은 복합 시이트의 사시도.1 is a perspective view of a composite sheet.

도 2는 하중/신장도 곡선.2 is a load / elongation curve.

도 3은 복합 시이트의 제조 공정도.3 is a manufacturing process diagram of a composite sheet.

<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for main parts of the drawings>

2 : 신장층2: stretch layer

3 : 신축층3: stretch layer

6 : 연속 섬유6: continuous fiber

10 : 복합 시이트10: composite sheet

31 : 압출기(제1압출기)31 extruder (first extruder)

32 : 컨베이어(제1컨베이어 벨트)32: conveyor (first conveyor belt)

36 : 제2컨베이어(제2컨베이어 벨트)36: 2nd conveyor (2nd conveyor belt)

52 : 신장성 웨브52: stretchable web

53 : 신축성 웨브53: Stretch Web

X : 제2방향X: 2nd direction

Y : 제1방향Y: first direction

상기 과제 해결을 위해서, 본 발명은 신규한 복합 시이트와 이의 제조 방법을 제안한다.MEANS TO SOLVE THE PROBLEM In order to solve the said subject, this invention proposes a novel composite sheet and its manufacturing method.

상기 복합 시이트에 관해서 본 발명이 대상으로 하는 것은, 상하면을 갖는 탄성 신축층의 적어도 한 면에 신장성 연속 섬유로 이루어진 신장층이 서로 직교하는 제1방향과 제2방향 중의 적어도 상기 제1방향에서 간헐적으로 접합됨으로써 형성된 복합 시이트이다.The present invention relates to the composite sheet in that at least one of a first direction and a second direction in which an elongate layer made of stretchable continuous fibers is orthogonal to each other on at least one side of an elastic stretchable layer having an upper and lower surface in at least the first direction. It is a composite sheet formed by intermittently joining.

이러한 복합 시이트에서, 본 발명이 특징으로 하는 것은, 상기 연속 섬유가 거의 상기 제1방향으로 배향하고, 상기 복합 시이트의 상기 제1방향에서의 인장 강도(S1)와 상기 제2방향에서의 인장 강도(S2)의 비 S1/S2가 3.0 이상인 것에 있다.In this composite sheet, the present invention is characterized in that the continuous fibers are oriented almost in the first direction, and the tensile strength (S 1 ) in the first direction of the composite sheet and the tensile in the second direction. strength is less than that ratio S 1 / S 2 is 3.0 (S 2).

또한, 상기 제조 방법에 관해서, 본 발명이 대상으로 하는 것은, 상하면을 갖는 탄성 신축성 웨브의 적어도 한 면에 신장성 연속 섬유로 이루어진 신장성 웨브를 서로 직교하는 제1방향과 제2방향 중의 적어도 상기 제1방향에서 간헐적으로 접합됨으로써 복합 시이트를 제조하는 방법이다.Moreover, regarding the said manufacturing method, what this invention makes object is at least the said 1st direction and 2nd direction which orthogonally cross an elongate web which consists of an elongate continuous fiber on at least one surface of the elastically stretchable web which has a top and bottom. It is a method of manufacturing a composite sheet by intermittently joining in a 1st direction.

이러한 제조 방법에서, 본 발명이 특징으로 하는 것은, 상기 연속 섬유가 실질적으로 비결합의 상태로 중첩됨으로써 상기 신장성 웨브를 형성하고 있는 것으로서, 상기 연속 섬유를 거의 상기 한 방향으로 배향시킨 후, 상기 신장성 웨브를 상기 신축성 웨브에 접합시키는 것에 있다.In this manufacturing method, the present invention is characterized in that the continuous fibers are overlapped in a substantially unbonded state to form the stretchable web, and the stretching fibers are oriented in almost one direction, and then the stretching is performed. Joining the web to the elastic web.

이 제조 방법의 바람직한 구체예에서, 용융 압출기로부터 상기 연속 섬유를 압출시켜 한 방향으로 주행하는 컨베이어 위에 포집하여 상기 신장성 웨브를 형성한 후, 상기 연속 섬유를 거의 상기 한 방향으로 배향시키도록 처리하여 상기 신축성 웨브와 중첩되고, 그러한 후에 이들 양 웨브를 상기 한 방향에서 간헐적으로 접합시킴으로써 상기 복합 시이트를 얻는다.In a preferred embodiment of this manufacturing method, the continuous fibers are extruded from a melt extruder and collected on a conveyor running in one direction to form the extensible web and then treated to orient the continuous fibers in substantially one direction. The composite sheet is obtained by overlapping the stretchable web and then joining both webs intermittently in the one direction.

또한, 바람직한 구체예의 다른 하나에서, 상기 연속 섬유를 상기 한 방향으로 배향시키는 공정이 속도 V1로 주행하는 상기 컨베이어 및, 상기 컨베이어에 이어서 속도 V2로 주행하는 제2컨베이어를 포함하고, 이들 컨베이어의 주행 속도비(V2/V1)는 1.05∼10이다.In another of the preferred embodiments, the step of orienting the continuous fibers in the one direction includes the conveyor running at speed V 1 and a second conveyor following the conveyor at speed V 2 , these conveyors The running speed ratio of V 2 / V 1 is 1.05 to 10.

첨부의 도면을 참조하여, 본 발명에 의한 복합 시이트와 이의 제조 방법을 상세하게 설명하면 이하와 같다.EMBODIMENT OF THE INVENTION With reference to an accompanying drawing, the composite sheet and its manufacturing method by this invention are demonstrated in detail as follows.

도 1에 사시도로 표시된 복합 시이트(10)는 스티렌계 엘라스토머의 연속 섬유(40)로 이루어진 탄성 신축층(3)의 상면에, 신장성 폴리프로필렌 연속 섬유(6)로 이루어진 신장층(2)이 접합부(4A)에서 용착됨으로써 형성되어 있다. 복합 시이트(10)는 X 방향과, 이것에 직교하는 Y 방향을 가지고, 신축층(3)이 X, Y 방향 중의 적어도 Y 방향으로 탄성적으로 신축한다. 신장층(2)의 연속 섬유(6)는 거의 Y 방향을 향하여 연장되도록 배향되어 있다. 신축층(3)의 인장 강도가 X 방향과 Y 방향에서 차이가 없는 경우, 연속 섬유(6)의 배향의 정도는 Y 방향에서의 인장 강도(S1)와 X 방향에서의 인장 강도(S2)의 비 S1/S2로 나타내는 것이 가능하고, 본 발명의 바람직한 복합 시이트(10)에서는 S1/S2가 적어도 3.0이 되도록 연속 섬유(6)가 배향되어 있다. 또한, 연속 섬유(6)는 접합부(4A)를 제거하면 용착이나 접착에 의해서 서로 접합되는 일 없이 중첩되어 있을 뿐이거나, 또는 복합 시이트(10)가 Y 방향으로 약간 인장되면 서로 떨어지도록 매우 약하게 접합되어 있어 실질적으로는 중첩되고 있을 뿐인 상태와 같다.The composite sheet 10 shown in perspective view in FIG. 1 has an elongated layer 2 made of stretchable polypropylene continuous fibers 6 on the upper surface of the elastic stretchable layer 3 made of continuous fibers 40 of a styrenic elastomer. It is formed by welding at the bonding part 4A. The composite sheet 10 has the X direction and the Y direction orthogonal to this, and the expansion and contraction layer 3 elastically expands and contracts in at least the Y direction among X and Y directions. The continuous fibers 6 of the elongate layer 2 are oriented to extend almost in the Y direction. When the tensile strength of the stretchable layer 3 is not different in the X direction and the Y direction, the degree of orientation of the continuous fibers 6 is determined by the tensile strength (S 1 ) in the Y direction and the tensile strength (S 2 in the X direction). It is possible to represent the ratio S 1 / S 2 , and in the preferred composite sheet 10 of the present invention, the continuous fibers 6 are oriented so that S 1 / S 2 is at least 3.0. Further, the continuous fibers 6 are superimposed so as not to be bonded to each other by welding or adhesion when the bonding portion 4A is removed, or very weakly bonded so that the composite sheets 10 are separated from each other when the sheet 10 is slightly tensioned in the Y direction. It is like a state that is actually overlapping.

이러한 복합 시이트(10)는 이것을 양 층(2, 3)의 파단 신장도 이하이면서 신축층(3)의 탄성 한계 내에서 Y 방향으로 신장하면, 신축층(3)이 탄성적으로 신장하는 한편, 신장층(2)이 비탄성적으로 신장되어 연속 섬유(6)가 가늘고 길어지도록 소성 변형된다. 신장하는 힘을 풀면, 복합 시이트(10)는 신축층(3)의 수축력에 의해서 원래의 치수 부근까지 수축하고, 이 때에, 길게 신장된 연속 섬유(6)에는 많은 주름이 형성되어 신장층(2)은 신장 전의 상태보다도 부피가 크고 촉감이 유연해진다.When the composite sheet 10 is stretched in the Y direction within the elastic limit of the stretchable layer 3 while being less than the elongation at break of both layers 2 and 3, the stretchable layer 3 elastically stretches, The elongate layer 2 is inelastically stretched and plastically deformed so that the continuous fibers 6 are thinner and longer. When the stretching force is released, the composite sheet 10 is contracted to the vicinity of the original dimension by the contracting force of the stretchable layer 3, and at this time, many wrinkles are formed in the elongated continuous fiber 6, and the stretched layer 2 ) Is bulkier than the state before stretching and soft to the touch.

도 2는 최초에 150%까지 신장된 복합 시이트(10)를 재차 신장시켰을 때의 하중/신장도 곡선으로서, 복합 시이트(10)의 구성은 다음과 같다. 또한, 복합 시이트(10)를 최초에 신장시킬 때의 비율을 초기 신장율(EI)로 정의한다.FIG. 2 is a load / extension curve when the composite sheet 10 first stretched to 150% is elongated again. The structure of the composite sheet 10 is as follows. In addition, it defines the rate at the time of stretching the composite sheet 10 in the first to the initial elongation (E I).

신장층: 신장성 연속 섬유: 폴리프로필렌/프로필렌, 에틸렌, 부텐 Stretch layer : stretchable continuous fiber: polypropylene / propylene, ethylene, butene

삼원공중합체=60/40(중량비)Terpolymer = 60/40 (weight ratio)

섬유 직경: 15.2 ㎛Fiber diameter: 15.2 ㎛

평량: 15 g/㎡Basis weight: 15 g / ㎡

신축층: 신축성 연속 섬유:스티렌계 엘라스토머Stretch layer : Stretch continuous fiber: Styrene-based elastomer

섬유 직경: 16.4 ㎛Fiber diameter: 16.4 ㎛

평량 : 60 g/㎡Basis weight: 60 g / ㎡

복합 시이트: 강도비(S1/S2): 4.9 Composite sheet : strength ratio (S 1 / S 2 ): 4.9

도 2에서, 곡선은 느리게 상승한 후에 거의 동일한 하중으로 신장도 100%의 변곡점(P)까지 도달하고, 거기에서 급격히 상승한다. 복합 시이트(10)에서는, 우선 신장층(2)의 연속 섬유(6)의 주름이 신장되고, 그와 동시에 신축층(3)이 탄성적으로 변곡점(P)까지 신장된다. 변곡점(P) 이후에서는 연속 섬유(6)가 소성 변형되어 가늘고 길어지도록 신장되고, 신축층(3)이 계속해서 탄성적으로 신장된다. 이와 같이 복합 시이트(10)에서는, 최초에 150%까지 신장하면, 2번째의 신장에서는 신장도 100%까지의 범위에서 낮은 응력으로 신축되는 신축층(3)의 특성이 나타나고, 신장층(2)은 그 특성에 거의 영향을 주는 일이 없다. 복합 시이트(10)를 2번째로 신장시켰을 때에 관찰되는 변곡점(P)까지의 낮은 하중을 나타내는 신장율을 제2차 신장율(ES)이라 정의한다. 제2차 신장율(ES)과 초기 신장률(EI)의 비(ES/EI)가 스트레치 효율(SE)이고, 도 2의 경우의 스트레치 효율(SE)은 100(%)/150(%)×100=67(%)이다. 본 발명에 의한 복합 시이트(10)에서는, 연속 섬유(6)가 거의 Y 방향으로 배향되어 있으므로, 이것을 Y 방향으로 신장시킬 때에는 많은 연속 섬유(6)도 Y 방향으로 신장되어 길어지기 때문에, 스트레치 효율(SE)이 60∼90% 정도의 높은 값이 된다. 이 복합 시이트(10)와 비교하여, 연속 섬유(6)가 랜덤 분포되어 있는 경우의 복합 시이트에서는 스트레치 효율(SE)이 60% 이하이다.In Fig. 2, the curve rises slowly and then reaches an inflection point P of 100% elongation at almost the same load and rises sharply there. In the composite sheet 10, first, the wrinkles of the continuous fibers 6 of the stretched layer 2 are stretched, and at the same time, the stretched layer 3 elastically stretches to the inflection point P. After the inflection point P, the continuous fibers 6 are plastically deformed and elongated to become thin and long, and the stretchable layer 3 continues to elastically stretch. As described above, in the composite sheet 10, when the first stretched to 150%, the second stretched layer exhibits the properties of the stretchable layer 3 stretched with low stress in the range of 100% elongation, and the stretched layer 2 Hardly affects its properties. The elongation rate which shows the low load to the inflection point P observed when the composite sheet 10 is extended 2nd time is defined as the 2nd elongation rate E S. The ratio (E S / E I ) of the second elongation (E S ) and the initial elongation (E I ) is the stretch efficiency (S E ), and the stretch efficiency (S E ) in the case of FIG. 2 is 100 (%) / 150 (%) x 100 = 67 (%). In the composite sheet 10 according to the present invention, since the continuous fibers 6 are oriented substantially in the Y direction, many continuous fibers 6 also extend in the Y direction when they are stretched in the Y direction, so that the stretch efficiency is increased. (S E ) becomes a high value of about 60 to 90%. Compared with this composite sheet 10, in the composite sheet in which the continuous fibers 6 are randomly distributed, the stretch efficiency S E is 60% or less.

도 3은 복합 시이트(10)를 제조할 때의 공정도이다. 도면의 왼쪽에는 연속 섬유(6)를 토출하는 제1 압출기(31), 제1컨베이어 벨트(32), 흡입 박스(33)가 있다. 토출된 연속 섬유(6)는 제1 압출기의 노즐 옆쪽으로부터 토출되는 열풍(도시하지 않음)이나 흡입 작용으로 제1컨베이어 벨트(32) 위에 포집되어 신장성 웨브(52)를 형성한다. 연속 섬유(6)는 서로 용착되는 일이 없도록, 또한, 가령 용착되더라도 매우 용이하게 분리될 수 있도록, 제1 압출기(31)의 토출 조건, 열풍이나 흡입의 작용 조건, 연속 섬유(6)의 냉각 조건 및 제1컨베이어 벨트(32)의 속도 V1를 선택한다.3 is a process chart when manufacturing the composite sheet 10. On the left side of the drawing is a first extruder 31, a first conveyor belt 32, and a suction box 33 for discharging the continuous fibers 6. The discharged continuous fiber 6 is collected on the first conveyor belt 32 by hot air (not shown) discharged from the nozzle side of the first extruder or by suction to form the stretchable web 52. The continuous fibers 6 are not discharged to each other and, for example, they can be separated very easily even if they are welded, so that the discharge conditions of the first extruder 31, the operating conditions of hot air or suction, the cooling of the continuous fibers 6 The condition and the speed V 1 of the first conveyor belt 32 are selected.

신장성 웨브(52)는 제2컨베이어 벨트(36)로 진행된다. 제2컨베이어 벨트(36)는 속도 V2로 주행하고, 신장성 웨브(52)를 누르는 롤(37, 38)은 둘레 속도 V2로 회전하고 있다. 속도 V2와 V1의 비 V2/V1은 1.05∼10으로서, 신장성 웨브(52)는 제1컨베이어 벨트(32)로부터 제2컨베이어 벨트(36)로 이행되는 과정에서 진행 방향으로 인장되고, 연속 섬유(6)가 진행 방향을 향해 연장되도록 배향된다. 연속 섬유(6)가 서로 약하게 용착되어 있을 때에는 제2컨베이어 벨트(36)에서 제각기 분해된다.The stretchable web 52 proceeds to the second conveyor belt 36. The second conveyor belt 36 travels at the speed V 2 , and the rolls 37 and 38 that press the stretchable web 52 are rotating at the circumferential speed V 2 . The ratio V 2 / V 1 between the speeds V 2 and V 1 is 1.05 to 10, and the extensible web 52 is tensioned in the advancing direction during the transition from the first conveyor belt 32 to the second conveyor belt 36. And the continuous fibers 6 are oriented so as to extend in the advancing direction. When the continuous fibers 6 are weakly welded to each other, they are respectively disassembled in the second conveyor belt 36.

신장성 웨브(52)는 제2컨베이어 벨트(36)로부터 제3 컨베이어 벨트(41)로 진행된다. 제2 압출기(42)로부터는 엘라스토머의 연속 섬유(40)가 토출되고, 흡입 박스(43)의 흡입 작용을 받아 신장성 웨브(52)의 위에 퇴적되고, 신축성 웨브(53)를 형성한다. 양 웨브(52, 53)는 상하 한 쌍의 열 엠보스 롤(44, 44)을 통과할 때에 접합부(4A)를 형성하여 일체화되어 복합 시이트(10)가 된다.The stretchable web 52 runs from the second conveyor belt 36 to the third conveyor belt 41. The continuous fibers 40 of the elastomer are discharged from the second extruder 42, are subjected to the suction action of the suction box 43, and are deposited on the stretchable web 52 to form the stretchable web 53. When both webs 52 and 53 pass through a pair of upper and lower thermal emboss rolls 44 and 44, they form the joining part 4A, are integrated, and it becomes the composite sheet 10. As shown in FIG.

이러한 복합 시이트(10)의 제조 공정에서는, 제1컨베이어 벨트(32)의 속도 V1와 제2컨베이어 벨트(36)의 속도 V2의 관계를 V2/V1=1.05∼10으로 함으로써 연속 섬유(6)를 배향시키면, 그 배향은 복합 시이트(10)에 60∼90%의 높은 스트레치 효율(SE)을 초래하기에 충분한 정도가 된다. 이 배향이 충분할 때의 복합 시이트(10)에서는, 기계 방향과 그것에 직교하는 방향의 인장 강도(S1)와 인장 강도(S2)의 비(S1/S2)는 3.0 이상이 된다.In the manufacturing process of the composite sheet 10, the continuous fibers by the relationship between the speed V 2 of the first conveyor belt 32, the speed V 1 and the second conveyor belt 36 of the V 2 / V 1 = 1.05~10 When (6) is oriented, the orientation is sufficient to cause a high stretch efficiency (S E ) of 60 to 90% in the composite sheet 10. In the composite sheet 10 when this orientation is sufficient, the ratio S 1 / S 2 of the tensile strength S 1 and the tensile strength S 2 in the machine direction and the direction orthogonal thereto is 3.0 or more.

본 발명에 의한 복합 시이트(10)는 도시예의 것을, 신축층(3)의 상하면에 신장층(2)을 갖는 것으로 대체할 수 있다. 또한, 그것에 맞추어 도 3의 공정에 제3 압출기 및, 복수의 컨베이어 벨트를 추가할 수 있다.The composite sheet 10 according to the present invention can be replaced with one having an extension layer 2 on the upper and lower surfaces of the stretchable layer 3 in the illustrated example. In addition, a 3rd extruder and several conveyor belt can be added to the process of FIG. 3 accordingly.

본 발명에 따른 복합 시이트는 신장성의 연속 섬유가 거의 한 방향으로 배향되어 있기 때문에, 그 한 방향으로 신장되면 다수의 연속 섬유가 어느 것이나 동일하게 신장되므로, 신장 후의 섬유 직경의 편차가 작고 피부가 닿았을 때의 감촉이 고르고 외관에 일정하게 된다.In the composite sheet according to the present invention, since the stretchable continuous fibers are oriented in almost one direction, any number of continuous fibers are stretched in the same manner when stretched in one direction, so that the variation in fiber diameter after stretching is small and the skin touches. The texture is even and uniform in appearance.

본 발명에 의한 제조 방법은 신장성 웨브의 연속 섬유를 거의 한 방향으로 배향시키는 공정을 갖기 때문에 상기 복합 시이트의 제조가 용이하게 된다.The manufacturing method according to the present invention has a step of orienting continuous fibers of the extensible web in almost one direction, thereby facilitating the production of the composite sheet.

Claims (6)

상하면을 갖는 탄성 신축층의 적어도 한 면에 신장성 연속 섬유로 이루어진 신장층이 서로 직교하는 제1방향과 제2방향 중의 적어도 상기 제1방향에서 간헐적으로 접합됨으로써 형성된 복합 시이트에 있어서,In a composite sheet formed by intermittently joining an elongate layer made of stretchable continuous fibers on at least one surface of an elastic stretchable layer having an upper and lower surface intermittently in at least the first direction of a first direction and a second direction perpendicular to each other, 상기 연속 섬유가 거의 상기 제1방향으로 배향되고, 상기 복합 시이트의 상기 제1방향에서의 인장 강도(S1)와 상기 제2방향에서의 인장 강도(S2)의 비(S1/S2)가 3.0 이상인 것을 특징으로 하는 복합 시이트.Wherein the continuous fibers are oriented in substantially the first direction, the ratio (S 1 / S 2 of the tensile strength (S 2) in tensile strength (S 1) and the second direction of the in the first direction of the composite sheet ) Is 3.0 or more. 제1항에 있어서, 상기 제1방향에서의 스트레치 효율이 60∼90%인 것인 복합 시이트.The composite sheet according to claim 1, wherein the stretch efficiency in the first direction is 60 to 90%. 상하면을 갖는 탄성 신축성 웨브의 적어도 한 면에 신장성 연속 섬유로 이루어진 신장성 웨브를 서로 직교하는 제1방향과 제2방향 중의 적어도 상기 제1방향에서 간헐적으로 접합됨으로써 복합 시이트를 제조하는 방법에 있어서,In a method for producing a composite sheet by intermittently joining an extensible web made of stretchable continuous fibers to at least one side of an elastic stretchable web having an upper and lower surface in at least the first direction orthogonal to each other in a first direction and a second direction. , 상기 연속 섬유는 실질적으로 비결합 상태로 중첩됨으로써 상기 신장성 웨브를 형성하고 있는 것으로서, 상기 연속 섬유를 거의 상기 한 방향으로 배향시킨 후, 상기 신장성 웨브를 상기 신축성 웨브에 접합시키는 것을 특징으로 하는 제조 방법.The continuous fibers overlap the substantially non-bonded state to form the extensible web, and after the orienting the continuous fibers in almost one direction, the extensible web is bonded to the stretchable web. Manufacturing method. 제3항에 있어서, 용융 압출기로부터 상기 연속 섬유를 압출시켜 한 방향으로 주행하는 컨베이어 위에 포집하여 상기 신장성 웨브를 형성한 후, 상기 연속 섬유를 거의 상기 한 방향으로 배향시키도록 처리하여 상기 신축성 웨브와 중첩되고, 그러한 후에 이들 양 웨브를 상기 한 방향에서 간헐적으로 접합시킴으로써 상기 복합 시이트를 얻는 것인 방법.4. The stretchable web of claim 3 wherein the continuous fibers are extruded from a melt extruder and collected on a conveyor running in one direction to form the extensible web and then treated to orient the continuous fibers in substantially one direction. And a composite sheet obtained after that by intermittently joining both webs in the one direction. 제3항 또는 제4항에 있어서, 상기 연속 섬유를 상기 한 방향으로 배향시키는 공정이 속도 V1로 주행하는 상기 컨베이어 및, 상기 컨베이어에 이어서, 속도 V2로 주행하는 제2컨베이어를 포함하고, 이들 컨베이어의 주행 속도비(V2/V1)가 1.05∼10인 것인 방법.The process according to claim 3 or 4, wherein the step of orienting the continuous fibers in the one direction includes the conveyor running at speed V 1 and a second conveyor following the conveyor at speed V 2 , The traveling speed ratio (V 2 / V 1 ) of these conveyors is 1.05-10. 제3항 내지 제5항 중 어느 하나의 항에 있어서, 상기 복합 시이트의 상기 한 방향에서의 인장 강도(S1)와 상기 한 방향에 직교하는 방향에서의 인장 강도(S2)의 비(S1/S2)가 3.0 이상이 되도록 상기 연속 섬유를 상기 한 방향으로 배향시키는 것인 방법.The ratio S of the tensile strength S 1 in the one direction of the composite sheet to the tensile strength S 2 in the direction orthogonal to the one direction of the composite sheet. Or 1 / S 2 ) to orient the continuous fiber in the one direction such that at least 3.0.
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