KR20010069587A - Composition of chewing gum - Google Patents
Composition of chewing gum Download PDFInfo
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- KR20010069587A KR20010069587A KR1020010022192A KR20010022192A KR20010069587A KR 20010069587 A KR20010069587 A KR 20010069587A KR 1020010022192 A KR1020010022192 A KR 1020010022192A KR 20010022192 A KR20010022192 A KR 20010022192A KR 20010069587 A KR20010069587 A KR 20010069587A
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
Abstract
Description
본 발명은 껌의 조성물에 관한 것으로서, 더욱 상세히는 껌의 기초원료에 니코틴(nicotine), 니코틴산(nicotinic acid (niacin)), 지방산,구연산, 능금산, 아스코르빈산,토코페놀,유기 게르마늄,멘톨(박하향),감초 추출물, 맥아당 등을 첨가하고 용해하여 혼합하고 냉각 성형한 껌을 씹을 경우에 담배의 맛을 갖게 하는데 그 목적이 있는 껌의 조성물을 제공 하고자 하는 것이다.The present invention relates to a composition of gum, and more particularly, to the basic raw materials of gum, nicotine, nicotinic acid (niacin), fatty acids, citric acid, tungumic acid, ascorbic acid, tocophenol, organic germanium, menthol ( Peppermint flavor), licorice extract, maltose and the like is added to dissolve, mix and cold chewing gum when chewing gum to provide a composition of the gum with the purpose.
통상 껌의 조성물은 껌의 기초원료에 과일향, 불소 등을 첨가하여 입안의 냄새를 제거하고, 음식물을 섭취후에 잇몸의 이물질을 제거하고,입안의 침샘을 자극하여 소화를 촉진 하는데 그 목적이 있는 것으로서 이미 공지 되어 있고 상품화 되어 있는 것과 같다.In general, the composition of gum is to add fruit flavor, fluorine, etc. to the basic raw materials of gum to remove odors in the mouth, remove foreign substances in the gums after ingesting food, and stimulate the salivary glands in the mouth to promote digestion. It is already known and commercialized.
이에 본 발명에서는 껌(chewing gum)의 통상의 기초원료, 통상의 폴리비닐 아스테이트(polyvinyl acetate)에 니코틴(nicotine), 니코틴산(nicotinic acid(niacin)), 비타민류 인 아스코르빈산, 구연산, 토코페놀,방향족계등 및 지방산을 첨가하여 껌의 기초원료의 용해시 용해열에 의한 비타민의 파괴없이 조성하는조성물과 껌을 씹을 경우 니코틴에 의하여 담배의 맛을 느끼면서 니코틴이 산(acid)류등과 입안의 침에 의하여 니코틴산으로 변화 시켜 니코틴의 흡수를 최소화 하고 담배의 맛을 느낄수 있도록 하는것의 조성물을 제공 하고자 기술적 과제를 두고 본 발명을 완성한 것이다.Accordingly, in the present invention, nicotine (nicotine), nicotinic acid (niacin), vitamins ascorbic acid, citric acid, and toco are conventional basic raw materials of chewing gum and ordinary polyvinyl acetate. When phenol, aromatics, etc., and fatty acids are added to melt the basic ingredients of the gum, the composition and composition of the gum are not destroyed by heat of dissolution. The present invention has been completed with the technical problem to provide a composition for changing the nicotine acid by saliva to minimize the absorption of nicotine and to feel the taste of tobacco.
본 발명에서 제공하는 껌의 조성물을 얻기 위하여 주재인 껌의 기초원료에 다음과 같은 성분을 포함하고 조건을 만족하는 첨가제의 성분을 사용한다.In order to obtain the composition of the chewing gum provided by the present invention, the following ingredients are included in the basic raw material of the chewing gum, and the additives satisfying the conditions are used.
1. 본 발명의 껌의 기초원료에 있어서 일반적으로 사용하는 폴리비닐 아스테이트(polyvinyl acetate)는 비닐 아스테이트(vynil acetate)를 호모폴리머리제이션(homo polymerization) 시켜 천연 저분자화 한것으로서 무색,무취,무독성의 투명한 고체이며, 알카리에 비교적 내성이 있고 체내에 흡수가 않되는 것으로서 그래이드(grade)별로 설명 하면 다음과 같다. 그래이드(grade)는 vp_102로서 솔리드콘텐트 (solidcontent)-99.5-100%, 디그리 오브 폴리머리제이션(degree of polymerization)-210±20, 소프팅포인터(softening point)-40±5 ℃, 에쉬컨텐트(ash content)-0.05%이하, 프리모노마(freemonomer)-0.02%이하, 애쉬드콘텐트(acid content)-0.01%이하, 해비메탈(heavy metal)-0 , 와 같이 인체에 전혀 무해하며, 열가소성이며, 천연저분자 인 껌의 기초제.1-1.그래이드(grade)vp-105로서 폴리비닐 아스테이트(polyvinyl acetate)는 비닐 아스테이트(vynil acetate)를 호모 폴리머리제이션(homo polymerization)시킨 것으로서 무색,무취,무독성의 투명한 고체로서 알카리에 비교적 내성이 있고 체내에 흡수가 않되는 것으로서 솔리드 콘텐트(soidcontent)-99.6-100%,디그리오브 폴리머리제이션(degree of polymerization) -500±40, 소프팅 포인트(softening point)-60±5 ℃, 애쉬 콘텐트(ash content)-0.05%이하, 프리모노마(free monomer)-0.02%이하, 에쉬드 콘텐트(acid content)-0.01%이하, 해비 메탈(heavy metal)- 0 , 와 같이 인체에 전혀 무해하며,열가소성이며, 천연저분자인 껌의 기초제.1. Polyvinyl acetate, which is generally used in the basic raw material of the gum of the present invention, is a natural low molecular weight obtained by homopolymerizing vinyl acetate (vynil acetate), which is colorless, odorless, It is a non-toxic transparent solid, relatively resistant to alkali and not absorbed by the body. Grade is vp_102, solid content-99.5-100%, degree of polymerization-210 ± 20, softening point-40 ± 5 ° C, ash content ash content-0.05% or less, freemonomer-0.02% or less, acid content-0.01% or less, heavy metal-0, harmless to the human body, such as thermoplastic, Natural low molecular weight gum.1-1.Grade vp-105, polyvinyl acetate is homopolymerized vinyl acetate (vynil acetate), colorless, Odorless, non-toxic transparent solid, relatively resistant to alkali and not absorbed by the body.Solidcontent-99.6-100%, degree of polymerization -500 ± 40, softening point softening point) -60 ± 5 ℃, ash content-0.05% or less, It is harmless to the human body such as limonoma (free monomer) -0.02% or less, acid content -0.01% or less, heavy metal-0, a thermoplastic, a natural low molecular weight gum .
본 발명의 구성 성분을 껌의 기초원료인 1과 1-1에 첨가 되는 조성물을 실시예를 들어서 상세히 설명 하면 다음과 같다.When the composition of the present invention is described in detail with reference to the compositions to be added to the base material 1 and 1-1 of the gum as follows.
(실시 예 1)(Example 1)
1. 폴리비닐 아스데이트(polyvinyl acetate) --- 91.80-66중량 %1.polyvinyl acetate --- 91.80-66% by weight
2. 니코틴(nicotine) --- 0.1-3중량%2. Nicotine --- 0.1-3% by weight
3. 니코틴산(nicotinic acid(niacin))---1-3중량%3. Nicotinic acid (niacin) --- 1-3 wt%
4. 지방산--- 1-3중량%4. Fatty acid --- 1-3 wt%
5. 구연산--- 1-3중량%5. Citric acid --- 1-3% by weight
6. 능금산---1-3중량%6. Nitrate Acid --- 1-3% by weight
7. 아스코르빈산---0.5-1중량%7. Ascorbic acid --- 0.5-1 wt%
8. 토코페놀--- 1-5중량%8. Tocophenol --- 1-5% by weight
9. 유기게르마늄--- 0.51중량%9. Organic Germanium --- 0.51 wt%
10. 맥아당 추출물---1-5중량%10. Maltose Extract --- 1-5% by weight
11. 감초추출물 ---1-5중량%11.Licorice Extract --- 1-5% by weight
12. 멘톨 --- 0.1-2중량%12.menthol --- 0.1-2% by weight
(실시예 2)(Example 2)
1. 폴리비닐 아스테이트(polyvinyl acetate)---99-90중량%1.polyvinyl acetate --- 99-90 wt%
2. 니코틴(nicotine)---1-10중량%2. Nicotine --- 1-10% by weight
(실시예 3)(Example 3)
1. 폴리비닐 아스테이트(polyvinyl acetate)---95-85중량%1.polyvinyl acetate --- 95-85 wt%
2. 니코틴산(nicotinic acid(niacin)---5-15중량%2. Nicotinic acid (niacin) --- 5-15% by weight
(실시예 4)(Example 4)
1. 폴리비닐 아스테이트(polyvinyl acetate)---91.90-62.00중량%1.polyvinyl acetate --- 91.90-62.00% by weight
2. 니코틴(nicotine)---1-10중량%2. Nicotine --- 1-10% by weight
3. 지방산---1-3중량%3. Fatty acid --- 1-3% by weight
4. 구연산---1-3중량%4. Citric Acid --- 1-3% by weight
5. 능금산---1-3중량%5. Neunggumsan--1-3% by weight
6. 아스코르빈산---0.5-1중량%6. Ascorbic acid --- 0.5-1 wt%
7. 토코페놀---1-5중량%7. Tocophenol--1-5% by weight
8. 유기게르마늄---0.5-1중량%8. Organic Germanium --- 0.5-1% by weight
9. 멘톨---0.1-2중량%9. Menthol --- 0.1-2% by weight
10. 감초 추출물---1-5중량%10. Licorice Extract --- 1-5% by weight
11. 맥아당 ---1-5중량%11.Malts --- 1-5% by weight
실시예1-4의 조성물들의 배합비에 있어서 상세히 설명하면 다음과 같다.The compounding ratio of the compositions of Examples 1-4 will be described in detail as follows.
실시예1의 껌의 기초원료인(1). 폴리비닐 아스테이트(polyvinyl acetate) 상술한 1과1-1 내용과 같이 금속의 용기에 섭씨 30-40℃의 온도로 용해후(2). 니코틴(nicotine)은 가지과( 科)식물인 담배(nicotiana tabacum)에 함유되어있는 알카로이드로 분자식은 C1OH14N2이며, 피리딘 같은 냄새가 나는 유상(油狀)의 담황색 액체로 , 끓는점 247℃(일부분해), 비중이 1.0097이다.(1) which is the basic raw material of the gum of Example 1. Polyvinyl acetate After dissolving in a metal container at a temperature of 30-40 ℃ as described in 1 and 1-1 (2). Nicotine is an alkaloid contained in tobacco (nicotiana tabacum), a molecular formula of C1OH14N2. It is an oily pale yellow liquid with a smell of pyridine.It has a boiling point of 247 ° C (partially), Specific gravity is 1.0097.
실온에서는 상당한 휘발성을 지니며 빛이나 공기와 접촉하면 쉽게 산화되어 갈색으로 변한다. 수용액은 알카리성을 보이며 60℃ 이하 및 210℃ 이상에서는 물에 무제한으로 용해된다.At room temperature it is quite volatile and readily oxidizes to brown when in contact with light or air. The aqueous solution shows alkalinity and dissolves in water at 60 ° C. or lower and 210 ° C. or higher.
조성물의 배합비율되로 조성순서는 다음과 같다.The compositional order of the composition ratio is as follows.
산(acid)류인 (3).니코틴산(niacin)으로 비타민 B6 , B12 1-3중량% (4). 지방산류의 라우린산, 미리스딘산,파르미티산,스테아린산,올레인산,베네닌산 중의 하나를 선택하여 1-3중량%, (5) 구연산 1-3중량% (6).능금산1-3중량% (7).아스코르빈산 0.5-1중량%,(8). 토코페놀 1-5중량%,(9).유기게르마늄 0.5-1중량%, 천연의 감미료로서 (10). 맥아당추출물 1-5중량%,(11). 감초추출물 1-5중량%, 향료로서 (12). 멘톨 0.1-2중량%를 껌의기초원료인 (1).폴리비닐 아스테이트(polyvinyl acetate)를 91.80-66.00중량% 금속의 전기히팅 교반기에서 섭씨 10℃에서 서서히 온도를 높혀 가면서 강제적으로 교반을 행하면서 비타민의 파괴없이 분산을 시키고 최종적으로 (2)니코틴(nicotine) 0.1-3중량% 첨가하여 신속히 분산 혼합하고 진공압출기로 압출성형하여 급속냉각 고형화한 껌의 조성물에 그 특징이 있다.Acids (3). 1-3% by weight of vitamin B6, B12 with niacin (4). Choose from lauric acid, myridine acid, partic acid, stearic acid, oleic acid, or behenic acid in fatty acids, 1-3 wt%, (5) 1-3 wt% citric acid, (6). % (7). 0.5-1% by weight of ascorbic acid, (8). 1-5% by weight of tocophenol, (9). As organic germanium 0.5-1% by weight, as a natural sweetener (10). Maltose extract 1-5% by weight, (11). Licorice extract 1-5% by weight, as a perfume (12). Menthol 0.1-2% by weight of the gum (1), the basic raw material of the gum (polyvinyl acetate) 91.80-66.00% by weight in a metal electric heating stirrer at a temperature of 10 ° C. While dispersing without breakdown of vitamins, and finally (2) 0.1-3% by weight of nicotine (dispersion) is quickly dispersed and mixed and extruded by a vacuum extruder has a feature of the composition of the rapid cooling solidified gum.
실시예1에 있어서In Example 1
니코틴(nicotine)을 마직막 공정에 둔 것은 산(acid)및 지방산에 의하여 니코틴(nicotine)이 니코틴산(nicotinic acid)으로 변환 반응이 일어나므로 급속 교반에 의하여 니코틴을 보존코져 진공압출 성형하여 급속냉각 고체화 한 것에 그특징이 있는 껌의 조성물 .In the last process, nicotine is converted into nicotinic acid by acid and fatty acid, so nicotine is preserved by rapid stirring to rapidly cool and solidify. Composition of gum which is characterized by thing.
실시예2에 있어서,In Example 2,
(1).폴리비닐 아스테이트(polyvinyl acetate) 99.0-90중량%,를 전기히팅 금속 교반기에서 섭씨 10-35℃부터 온도를 올리면서 급속교반중에 (2)니코틴(nicotine)을 1-10중량% 첨가하여 진공압출 성형하여 급속냉각 고형화 할것에 그특징이 있는 껌의 조성물.(1) 99.0-90% by weight of polyvinyl acetate, (10) 1-10% by weight of nicotine during rapid stirring while raising the temperature from 10-35 ° C in an electric heating metal stirrer. A composition of chewing gum having the characteristics of being added by vacuum extrusion molding to rapid cooling and solidifying.
실시예3에 있어서,In Example 3,
(1).폴리비닐 아스테이트(polyvinyl acetate) 95-85중량%를 전기히팅 금속교반기에서 섭씨 10-35℃부터 온도를 올리면서 급속교반중에 (2)니코 틴산(nicotinic acid)을 5-15중량% 첨가하여 진공압출 성형하여 급속냉각 고형화 한것에 그 특징이 있는 껌의 조성물.(1) 95-85% by weight of polyvinyl acetate in an electric heating metal stirrer during rapid stirring while raising the temperature from 10-35 ° C. (2) 5-15% by weight of nicotinic acid. A composition of chewing gum characterized by rapid cooling and solidification by addition of vacuum extrusion molding.
실시예 4에 있어서 ,In Example 4,
(1)폴리비닐 아스테이트(polyvinyl acetate) 91.90-62.00중량%를 섭씨 10-35℃의 온도로 서서히 올리면서 급속교반중에 (3)지방산 1-3중량%, (4)구연산 1-3중량%, (5)능금산 1-3중량%, (6)아스코르빈산 0.5-1중량%, (7)토코페놀 1-5중량%,(8)유기게르마늄 0.5-1중량%, (9)맨톨 0.1-2중량%, (10)감초추출물 1-5중량%, (11)맥아당 1-5중량%을 첨가하여 분산 시키고 (2)니코틴(nicotine) 1-10중량%를 첨가하여급속히 교반하여 진공압출기에서 압출성형 급속냉각하여 고형화 한것에 그 특징이 있는 껌의 조성물 .(1) 91.90-62.00% by weight of polyvinyl acetate is gradually raised to a temperature of 10-35 ° C. during rapid stirring, (3) 1-3% by weight of fatty acids, (4) 1-3% by weight of citric acid (5) 1-3% by weight of nitric acid, (6) 0.5-1% by weight of ascorbic acid, (7) 1-5% by weight of tocophenol, (8) 0.5-1% by weight of organic germanium, (9) Menthol 0.1 -2% by weight, (10) Licorice extract 1-5% by weight, (11) malt sugar 1-5% by weight to disperse, (2) 1-10% by weight of nicotine is rapidly stirred and vacuum extruder The composition of chewing gum characterized by solidification by extrusion molding and rapid cooling.
본 발명의 껌의 조성물을 실시예 1-4에서 첨가성분에 따라서 그 기능의 약간의 차이는 있어나 그 근본적인 목적은 담배의 대용으로서 껌의 조성물로서 담배가 인체에 미치는 해로움을 고찰하여 보면 담배는 피울때에 발생되는 연기중의 유해성분이 4,000-7,000종류에 달하고 연기가 주위에 간접 흡연의 피해뿐 아니라 자신에게도 치명적인 것으로서 대표적인 것으로서 타르,니코틴,일산화탄소,등 특히 니코틴은 담배 1개피에 대략 1mg이 함유되어 있어 사람의 경우 40mg이 치사량이다.The composition of the gum of the present invention has a slight difference in its function depending on the additive ingredients in Examples 1-4, but its basic purpose is to consider the harmful effects of tobacco on the human body as a composition of gum as a substitute for tobacco. There are 4,000-7,000 kinds of harmful constituents in smoke, and the smoke is not only harmful to secondhand smoke, but also fatal to oneself.Tar, nicotine, carbon monoxide, etc. Especially nicotine contains about 1mg per cigarette For humans, 40mg is the lethal dose.
적은양의 니코틴은 신경계에 작용하고 교감 및 부교감신경을 흥분시켜 쾌감을 얻게하고, 많은량의 니코틴은 신경을 마비시켜 환각상태에 이르게 한다. 또한 각성효과가 있어 글을 쓰거나 작업을 할 때 일시적으로 창의력을 향상시키기도 하며, 흥분되었을 때 일시적으로 진정시키는 효과가 있다. 니코틴은 말초혈관을 수축하며 맥박을 빠르게 하고 혈압을 높이며, 콜레스테롤을 증가시켜 동맥경화증을 악화 시킨다 따라서 담배를 피우는 사람에게서 심장병,버거씨병,그리고 니코틴은 소화기계에도 작용하여 궤양을 일어키고 내분비계 및 호흡기에도 나쁜 영향을 끼친다.Small amounts of nicotine act on the nervous system and excite the sympathetic and parasympathetic nerves to get pleasure, while large amounts of nicotine paralyze the nerves leading to hallucinations. It also has an awakening effect, which temporarily improves creativity when writing or working, and temporarily calms when excited. Nicotine constricts peripheral blood vessels, speeds up pulses, increases blood pressure, and increases cholesterol, which makes arteriosclerosis worse. Therefore, in people who smoke, heart disease, burger disease, and nicotine also act on the digestive system, causing ulcers, It also has a bad effect on the respiratory system.
니코틴이 담배연기로 흡입되어 뇌에 약리작용을 일어키는데 소요되는 시간은 불과 4-5초이며, 흡입된 니코틴이 몸밖으로 완전히 배출되는데는 약 3일이 걸린다. 또한 담배는 중독성이 있어 일정량의 니코틴이 부족하면 계속하여 담배를 피우게되는데 이러한 문제점을 해소코자 본 발명의 껌의 조성물은 연기가 나지 않으로므로 간접 흡연의 피해가 없고 연기가 발생하여 직접적인 폐의 흡입이 없으므로 니코틴이 입안의 타액과 위의 위산등 및 조성물들로 인하여 니코틴산으로 변환하여 인체에 해가 최소화 하고자 하며, 본 발명의 조성물의 실험결과 니코틴이 85%이상 니코틴산(nicotinic acid)로 변환 하였고 흡연자의 니코틴의 만족도도 충분하여 그효과가 뛰어 났다.The time it takes for nicotine to be inhaled by tobacco smoke and cause pharmacological effects on the brain is only 4-5 seconds, and it takes about 3 days for the inhaled nicotine to be completely discharged out of the body. In addition, cigarettes are addictive, so if a certain amount of nicotine is insufficient to continue to smoke. To solve this problem, the composition of the gum of the present invention does not smoke because there is no damage of secondhand smoke and smoke occurs directly inhalation of the lungs Since there is no nicotine is converted to nicotinic acid due to saliva in the mouth and gastric acid and compositions in the mouth to minimize harm to the human body, the experimental results of the composition of the present invention nicotine is converted to nicotinic acid (nicotinic acid) more than 85% and smokers The satisfaction of nicotine was also good enough that the effect was excellent.
Claims (4)
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US4775537A (en) * | 1987-04-30 | 1988-10-04 | Warner-Lambert Company | Sequentially flavored chewing gum composition |
US4822621A (en) * | 1987-07-30 | 1989-04-18 | Warner-Lambert Company | Method and product for increased aspartame stability in chewing gum |
US4931293A (en) * | 1986-12-23 | 1990-06-05 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US5057328A (en) * | 1988-11-14 | 1991-10-15 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US5487902A (en) * | 1989-07-24 | 1996-01-30 | Fertin Laboratories Ltd. (Dansk Tyggegummi Fabrik A/S) | Chewing gum composition with accelerated, controlled release of active agents |
US5512306A (en) * | 1992-06-19 | 1996-04-30 | Pharmica Ab | Smoking substitute |
US5569477A (en) * | 1995-04-28 | 1996-10-29 | Mccready Consumer Products, Inc. | Chewing gum containing vitamins or other active materials |
US5866179A (en) * | 1996-05-03 | 1999-02-02 | Avant-Garde Technologies & Products S.A. | Medicated chewing gum and a process for preparation thereof |
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2001
- 2001-04-18 KR KR1020010022192A patent/KR20010069587A/en not_active Application Discontinuation
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Publication number | Priority date | Publication date | Assignee | Title |
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US4931293A (en) * | 1986-12-23 | 1990-06-05 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US4775537A (en) * | 1987-04-30 | 1988-10-04 | Warner-Lambert Company | Sequentially flavored chewing gum composition |
US4822621A (en) * | 1987-07-30 | 1989-04-18 | Warner-Lambert Company | Method and product for increased aspartame stability in chewing gum |
US5057328A (en) * | 1988-11-14 | 1991-10-15 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US5487902A (en) * | 1989-07-24 | 1996-01-30 | Fertin Laboratories Ltd. (Dansk Tyggegummi Fabrik A/S) | Chewing gum composition with accelerated, controlled release of active agents |
US5512306A (en) * | 1992-06-19 | 1996-04-30 | Pharmica Ab | Smoking substitute |
US5569477A (en) * | 1995-04-28 | 1996-10-29 | Mccready Consumer Products, Inc. | Chewing gum containing vitamins or other active materials |
US5866179A (en) * | 1996-05-03 | 1999-02-02 | Avant-Garde Technologies & Products S.A. | Medicated chewing gum and a process for preparation thereof |
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