KR20010068967A - Sanitary chopping board - Google Patents

Sanitary chopping board Download PDF

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Publication number
KR20010068967A
KR20010068967A KR1020000001139A KR20000001139A KR20010068967A KR 20010068967 A KR20010068967 A KR 20010068967A KR 1020000001139 A KR1020000001139 A KR 1020000001139A KR 20000001139 A KR20000001139 A KR 20000001139A KR 20010068967 A KR20010068967 A KR 20010068967A
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South Korea
Prior art keywords
polyol
diol
isocyanate
polyurethane
sanitary
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KR1020000001139A
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Korean (ko)
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KR100347745B1 (en
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김연수
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손병권
김형락
(주)한국기술소재
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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J47/00Kitchen containers, stands or the like, not provided for in other groups of this subclass; Cutting-boards, e.g. for bread
    • A47J47/005Cutting boards
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J36/00Parts, details or accessories of cooking-vessels
    • A47J36/02Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
    • A47J36/04Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay the materials being non-metallic

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

PURPOSE: A sanitary kitchen board for cooking is provided to be light and durable by using polyurethane. CONSTITUTION: A sanitary kitchen board is made of polyurethane in which isocyanate is reacted with a mixture mixed with polyol and diol at a ratio of 1: 0.2 to 0.4. The average molecular weight of the polyol and the diol is 1000 to 3000 units. The polyol is (PTMG)(HO-(-CH2CH2CH2CH2-O)NH) and the diol is 1,4-HOCH2CH2CH2CH2OH. The isocyanate is 4,4-MDI,OCN-Ph-CH2-Ph-NCO. Thus, the sanitary kitchen board is light and durable.

Description

요리용 위생 도마{SANITARY CHOPPING BOARD}Sanitary cutting board for cooking {SANITARY CHOPPING BOARD}

본 발명은 요리용 위생 도마에 관한 것으로, 경량이면서도 위생적이고 내구성이 강한 도마에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sanitary cutting board for cooking, and more particularly, to a cutting board which is lightweight, hygienic and durable.

현재 국내에서 사용되고 있는 가정용 및 업소용 도마는 대개 중국산 나무 또는 폴리에틸렌 재질의 플라스틱 및 유리 재질로 제조되고 있다. 그러나, 이들은 도마의 재질이 무겁다는 단점 이외에도 딱딱하여 조리용 음식물을 도마 위에서 식칼로 절단하거나 다지거나 기타 형태의 가공시 타격음이 너무 크며, 나무나 폴리에틸렌 재질의 경우 식칼의 칼자국(scratch)이나 홈 등으로 인해 음식물 또는 국물이 그 안에 인입되어 곰팡이 등의 유해 세균의 배양소 역할을 할 수가 있다. 인입된 음식 찌끼나 세균은 행주나 물 등으로는 완전히 제거하기가 용이치 않으며 악취를 발생하여 음식물의 맛이나 풍미를 해치게 된다.Domestic and commercial cutting boards currently used in Korea are usually made of plastic and glass materials made of Chinese wood or polyethylene. However, in addition to the disadvantages of heavy cutting boards, they are hard, and the cutting sound is too loud when cutting or chopping cooking food with a knife on a cutting board or processing other forms.In the case of wood or polyethylene materials, such as knife cuts or grooves, etc. Due to the food or broth is introduced into it can act as a culture of harmful bacteria such as mold. The incoming food residues and bacteria are not easy to remove completely with dish cloths or water, and cause bad smells to damage the taste or flavor of the food.

따라서 본 발명의 목적은 무게가 가벼우면서도 내구성이 강하고 위생적인 도마를 제공하는 것이다.It is therefore an object of the present invention to provide a cutting board which is light in weight and durable and hygienic.

상기 목적을 달성하기 위하여 본 발명에서는 폴리올과 디올의 혼합물과 이소시아네이트를 반응시켜 수득한 폴리우레탄를 성형시켜 제조한 위생 도마를 제공한다.In order to achieve the above object, the present invention provides a sanitary cutting board prepared by molding a polyurethane obtained by reacting a mixture of polyol and diol with isocyanate.

이하 본 발명에 대하여 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명에 사용되는 폴리올은 평균분자량 1,000 내지 3,000 범위의 것으로, 대표적인 예로는 폴리테트라메틸렌글리콜(PTMG)(HO-[-CH2CH2CH2CH2-O]nH) 등이 있으며, 디올의 대표적인 예로는 1,4-디부탄디올(HOCH2CH2CH2CH2OH) 등이 있다. 본 발명에 따르면, 상기 폴리올 성분과 상기 디올 성분은 보통 1: 0.2 내지 1: 0.4의 중량비로 혼합되며, 혼합은 60 내지 70 ℃ 범위의 온도에서 수행될 수 있다.The polyol used in the present invention has an average molecular weight in the range of 1,000 to 3,000, and typical examples thereof include polytetramethylene glycol (PTMG) (HO-[-CH 2 CH 2 CH 2 CH 2 -O] n H) and the like. Representative examples thereof include 1,4-dibutanediol (HOCH 2 CH 2 CH 2 CH 2 OH). According to the invention, the polyol component and the diol component are usually mixed in a weight ratio of 1: 0.2 to 1: 0.4, and mixing may be performed at a temperature in the range of 60 to 70 ° C.

상기 폴리올과 디올의 혼합물에 이소시아네이트 성분을 가하고 반응시켜 본 발명에 따른 폴리우레탄을 수득하게 되는데, 상기 이소시아네이트 성분으로는 대표적으로 4,4'-디이소시아네이토페닐메탄(MDI, OCN-Ph-CH2-Ph-NCO) 등을 사용할 수 있으며, 반응몰비는 통상의 우레탄 제조시에서와 유사할 수 있고, 반응 온도는 40 내지 50 ℃ 범위이다.Isocyanate component is added to the mixture of the polyol and diol and reacted to obtain a polyurethane according to the present invention. As the isocyanate component, typically 4,4'-diisocyanatophenylmethane (MDI, OCN-Ph-CH) 2 -Ph-NCO) and the like, and the reaction molar ratio may be similar to that in preparing a conventional urethane, and the reaction temperature is in the range of 40 to 50 ° C.

상기 폴리올과 디올의 혼합물에 이소시아네이트 성분을 가하게 되면 발열 반응이 일어나면서 원료가 중합되어 90 내지 95 ℃ 범위의 온도에서 고체의 중합체로되는데, 반응 메카니즘은 하기 반응식 1과 같다.When an isocyanate component is added to the mixture of the polyol and the diol, an exothermic reaction occurs and the raw material is polymerized to obtain a solid polymer at a temperature in the range of 90 to 95 ° C. The reaction mechanism is shown in Scheme 1 below.

상기와 같이 수득된 중합물을 대략 60 ℃의 온도에서 약 2 내지 4 주 동안 고분자의 안정화를 위해 숙성시킨 후, 이를 분쇄, 압출, 성형(예를 들면 압출성형 또는 사출성형)하여 본 발명에 따른 도마를 원하는 형태로 제조할 수 있다.The polymer obtained as described above is aged for stabilization of the polymer for about 2 to 4 weeks at a temperature of about 60 ° C., and then pulverized, extruded, and molded (for example, extrusion or injection molding) to obtain a cutting board according to the present invention. Can be prepared in the desired form.

본 발명에 따른 도마는 완전 연질의 고탄성, 고신축성을 가지며, 뛰어난 내열성을 갖고, 비활성(끓는 물에도 사용 가능)이며, 인체에 무해하다.The cutting board according to the present invention is completely soft, high elasticity, high elasticity, excellent heat resistance, inert (can also be used in boiling water) and harmless to the human body.

이하, 본 발명을 실시예에 의해 설명하며, 이 실시예가 본 발명을 한정하는 것은 아니다.Hereinafter, an Example demonstrates this invention, and this Example does not limit this invention.

실시예 : 폴리우레탄의 합성Example Synthesis of Polyurethane

생성 중합체의 중량을 기준으로, 평균분자량 약 1,000의 폴리테트라메틸렌글리콜 50 중량%와 1,4-디부탄디올 15 중량%를 60 내지 70 ℃ 범위의 온도에서 혼합한 다음, 상기 폴리올과 디올의 혼합물에 4,4'-디이소시아네이토페닐메탄 35 중량%를 가하고, 40 내지 50 ℃ 범위에서 반응을 개시시켜 90 내지 95 ℃ 범위의 온도에서 고체 상태의 폴리우레탄 중합체를 수득하였다Based on the weight of the resulting polymer, 50% by weight of polytetramethylene glycol with an average molecular weight of about 1,000 and 15% by weight of 1,4-dibutanediol were mixed at a temperature in the range of 60 to 70 ° C. and then added to the mixture of polyols and diols. 35% by weight of 4,4'-diisocyanatophenylmethane was added and the reaction was initiated in the range of 40 to 50 ° C. to obtain a polyurethane polymer in the solid state at a temperature in the range of 90 to 95 ° C.

시험예 1Test Example 1

상기 실시예에서 수득된 폴리우레탄 중합체의 위생성을 시험하기 위해, 폴리우레탄 수지 샘플에 대해 납, 카드뮴 및 기타 중금속의 함량, 증발잔류물 및 이소시아네이트 함량을 해당항목 시험법에 따라 분석하였으며, 그 결과를 규격 기준과 비교하여 하기 표 1에 나타내었다.In order to test the hygiene of the polyurethane polymer obtained in the above examples, the contents of lead, cadmium and other heavy metals, evaporation residues and isocyanate contents of the polyurethane resin samples were analyzed according to the corresponding test methods. It is shown in Table 1 below in comparison with the standard.

시험 항목Test Items 측정치Measure 기준standard lead 불검출Not detected 10 mg/kg 이하10 mg / kg or less 카드뮴cadmium 불검출Not detected 10 mg/kg 이하10 mg / kg or less 기타 중금속Other heavy metals Pb로서 1.0 mg/l 이하1.0 mg / l or less as Pb Pb로서 1.0 mg/l 이하1.0 mg / l or less as Pb 과망간산 칼륨 소비량Potassium Permanganate Consumption 3.13 mg/l3.13 mg / l 10 mg/l 이하10 mg / l or less 증발 잔류물Evaporation residue 27.5 mg/l27.5 mg / l 30 mg/l 이하30 mg / l or less 이소시아네이트 함량Isocyanate Content 0.035 mg/l0.035 mg / l 0.1 mg/l 이하0.1 mg / l or less

시험예 2Test Example 2

상기 실시예에서 수득된 폴리우레탄 중합체에 대해 여러가지 물성을 측정하였으며, 그 결과를 하기 표 2에 나타내었다.Various physical properties were measured for the polyurethane polymer obtained in the above example, and the results are shown in Table 2 below.

시험 항목Test Items 시험 방법Test Methods 측정치Measure 비중importance JIS K 7311JIS K 7311 112112 쇼어(Shore) A 경도Shore A Hardness JIS K 7311JIS K 7311 9090 100% 모듈러스(Kgf/cm2)100% Modulus (Kgf / cm 2 ) JIS K 7311JIS K 7311 9090 인장 강도(Kgf/cm2)Tensile Strength (Kgf / cm 2 ) JIS K 7311JIS K 7311 470470 파단 신율(%)Elongation at Break (%) JIS K 7311JIS K 7311 480480 인열 강도(Kgf/cm)Tear strength (Kgf / cm) JIS K 7311JIS K 7311 125125 복원력(%)dynamic stability(%) JIS K 7311JIS K 7311 5555 압축 세트(70 ℃, 22시간)(%)Compression set (70 degrees Celsius, 22 hours) (%) JIS K 6301JIS K 6301 4040 비캣(Vicat) 연화점(℃)Vicat Softening Point (℃) JIS K 7206JIS K 7206 114114 테이버 마모율(mg)Taber wear rate (mg) JIS K 7311JIS K 7311 3030 유리전이온도(℃)Glass transition temperature (℃) 미분주사열량계(DSC)Differential Scanning Calorimeter (DSC) 5555

본 발명에 따른 도마는 폴리우레탄을 주성분으로 하여, 경량이면서도 내구성이 강하고 매우 위생적이다.The cutting board according to the present invention is mainly composed of polyurethane, which is lightweight, durable and very hygienic.

Claims (2)

평균분자량 1,000 내지 3,000 범위의 폴리올과 디올의 1:0.2 내지 1:0.4 범위 중량비의 혼합물과 이소시아네이트를 반응시켜 수득한 폴리우레탄으로부터 성형된 위생 도마.A sanitary chopping board formed from polyurethane obtained by reacting isocyanate with a mixture of a polyol having an average molecular weight in the range of 1,000 to 3,000 and a weight ratio in the range of 1: 0.2 to 1: 0.4. 제 1 항에 있어서,The method of claim 1, 폴리올이 폴리테트라메틸렌글리콜(PTMG)(HO-[-CH2CH2CH2CH2-O]nH)이고, 디올이 1,4-디부탄디올(HOCH2CH2CH2CH2OH)이며, 이소시아네이트가 4,4'-디이소시아네이토페닐메탄(MDI, OCN-Ph-CH2-Ph-NCO)인 것을 특징으로 하는 위생 도마.The polyol is polytetramethylene glycol (PTMG) (HO-[-CH 2 CH 2 CH 2 CH 2 -O] n H) and the diol is 1,4-dibutanediol (HOCH 2 CH 2 CH 2 CH 2 OH) And an isocyanate is 4,4'-diisocyanatophenylmethane (MDI, OCN-Ph-CH 2 -Ph-NCO).
KR1020000001139A 2000-01-11 2000-01-11 Sanitary chopping board KR100347745B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005084505A1 (en) * 2004-03-08 2005-09-15 Kiso Korea Co., Ltd A sanitary chopping board and a making method of the chopping board
KR100541869B1 (en) * 2002-10-04 2006-01-16 목동엽 A resin composition of polyurethane for accessories used in shoes and clothing, and for substituting for PVC
KR100912265B1 (en) * 2007-04-10 2009-08-17 동양케미칼주식회사 Anti-virus Board Made with Thermoplastic Polyurethane and Its Producing Method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100902086B1 (en) * 2008-11-06 2009-06-09 주식회사 리빙아이콘 Method for fabricating anti-virus chopping board for enabling boiling use and anti-virus chopping board

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100541869B1 (en) * 2002-10-04 2006-01-16 목동엽 A resin composition of polyurethane for accessories used in shoes and clothing, and for substituting for PVC
WO2005084505A1 (en) * 2004-03-08 2005-09-15 Kiso Korea Co., Ltd A sanitary chopping board and a making method of the chopping board
KR100912265B1 (en) * 2007-04-10 2009-08-17 동양케미칼주식회사 Anti-virus Board Made with Thermoplastic Polyurethane and Its Producing Method

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