KR20010056058A - Management Unit and Method of Foul and Waste Water - Google Patents
Management Unit and Method of Foul and Waste Water Download PDFInfo
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- KR20010056058A KR20010056058A KR1019990057474A KR19990057474A KR20010056058A KR 20010056058 A KR20010056058 A KR 20010056058A KR 1019990057474 A KR1019990057474 A KR 1019990057474A KR 19990057474 A KR19990057474 A KR 19990057474A KR 20010056058 A KR20010056058 A KR 20010056058A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
- C02F3/305—Nitrification and denitrification treatment characterised by the denitrification
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/308—Biological phosphorus removal
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
Abstract
Description
본 발명은 고농도 질소함유폐수의 생물학적 반응에 의한 하폐수처리 장치 및 방법에 관한 것으로, 특히 일반하수 및 오폐수는 물론 처리에 많은 어려움이 있는 난분해성 유기물 및 고농도 질소함유 공장폐수의 경우에도 용이하게 적용함으로써, 안정된 처리수질을 만족시킬 수 있도록 한 것을 특징으로 하는 고농도 질소함유폐수의 생물학적 반응에 의한 하폐수처리 장치 및 방법에 관한 것이다.The present invention relates to an apparatus and method for treating sewage by biological reaction of high concentration nitrogen containing wastewater, in particular, in the case of general sewage and wastewater, as well as difficult to decompose organic matter and high concentration nitrogen containing plant wastewater, which are difficult to treat. In addition, the present invention relates to a wastewater treatment apparatus and method by biological reaction of high concentration nitrogen-containing wastewater, which is characterized in that it can satisfy stable treated water quality.
종래의 대부분의 하폐수 처리장치는 활성슬러지법으로 설계운영되고 있는데 활성슬러지법을 통하여서는 유기물의 제거를 주목적으로 한 처리공정이기 때문에 최근의 호소의 부영양화가 심각해지게 됨에 따라 질소와 인을 제거해야할 시점에 비추어 볼 때 이에 부응할 수 없다. 더욱이 활성슬러지법은 유입 충격부하에 약하고 슬러지 팽화현상이 일어나는 등 처리가 불안정한 면이 있었다.Most of the conventional wastewater treatment systems are designed and operated by activated sludge method, and the activated sludge method is a treatment process that mainly aims at removing organic matter, and thus it is time to remove nitrogen and phosphorus as the eutrophication of the current appeal becomes serious. In light of this, it cannot be met. In addition, the activated sludge method was unstable in processing such as weak influx load and sludge swelling phenomenon.
이러한 활성슬러지법의 운전상 어려움으로 대두되는 팽화의 문제점을 해결함과 동시에 부영양화의 주범인 질소와 인을 효과적으로 제거하기 위한 여러 가지 처리공정들이 연구되어 실용화되고 있다.In addition to solving the problems of swelling caused by the difficulties in operating the activated sludge method, various treatment processes for effectively removing nitrogen and phosphorus, which are the main culprit of eutrophication, have been studied and put into practice.
그 예로서는 A2/O, UCT, MUCT, VIP, 바덴포(Bardenpho)법등이 있다.Examples include A 2 / O, UCT, MUCT, VIP, and the Bardenpho method.
A2/O법은 3개의 혐기조, 3개의 무산소조 및 4개의 포기조로 이루어져 있으며 혐기조에서 인 방출, 무산소조에서 탈질화, 포기조에서 질산화 및 인 섭취 등이 일어나게 된다.The A 2 / O method consists of three anaerobic tanks, three anaerobic tanks and four aeration tanks, which release phosphorus in the anaerobic tank, denitrification in the anaerobic tank, and nitrification and phosphorus intake in the aeration tank.
그러나 반송 슬러지내의 질산성 질소로 인하여 혐기조에서 인 방출 저해작용을 하게 되어 인 제거율이 떨어지며, 유입수의 부하변동에 매우 민감할 뿐만 아니라 동절기시 질산화 미생물의 활성이 크게 저하되는 단점이 있다.However, due to nitrate nitrogen in the return sludge, the phosphorus removal rate is lowered in the anaerobic tank, and the phosphorus removal rate is lowered.
특히 국내 하수의 경우처럼 저농도 유기물이 유입되는 경우 특히 영향이 심하므로 기술보완없이 현장적용을 수행할 경우 안정적인 처리수질 보장이 매우 어렵다.In particular, when low concentrations of organic matter are introduced, as in the case of domestic sewage, it is very difficult to guarantee stable treated water quality when performing on-site application without technical supplementation.
이러한 단점을 해결하기 위하여 개발된 UCT공정은 반송슬러지를 혐기조 다음의 무산소조로 유입시켜 질산성 질소를 제거한 후 혐기조로 보내어 인 방출을 방해하는 것을 억제시킨 것이며,The UCT process developed to solve these shortcomings is to return the return sludge to the anaerobic tank next to the anaerobic tank, remove nitrate nitrogen, and send it to the anaerobic tank to inhibit the phosphorus release.
MUCT 및 VIP공정은 무산소조를 반송슬러지 내의 질산성 질소를 제거하여 혐기조로 반송하는 무산소조와 내부 반송된 질산성 질소를 탈질시키는 무산소조로 분리하여 보다 완벽한 혐기성 조건을 제공하여 인제거율을 높인 것이나 내부 반송펌프의 추가 설치 및 유지관리상의 복잡성 등의 단점이 있는 것이다.The MUCT and VIP process separates the anaerobic tank into an anaerobic tank that removes nitrate nitrogen in the conveying sludge and returns it to the anaerobic tank and an anoxic tank which denitrates the returned nitrogen nitrate nitrogen. There are disadvantages such as additional installation and maintenance complexity.
또한 바텐포(Bardenpho)공정은 기존의 질소, 인 제거 공정중 효율이 90%정도로 가장 우수하나 체류시간을 10∼24시간으로 길게 운전하여야 하는 것이 단점이다. 특히 하수가 저농도인 경우에는 체류시간이 길어 탈질소화를 위한 유기물 부족으로 질소 인등 전체적인 처리 효율이 낮아지는 문제점이 있었다.In addition, the Bardenpho process has the highest efficiency of about 90% among the existing nitrogen and phosphorus removal processes, but has a disadvantage in that a long residence time of 10 to 24 hours is required. In particular, when the sewage concentration is low, the residence time is long, and there is a problem in that the overall treatment efficiency such as nitrogen phosphorus decreases due to the lack of organic material for denitrification.
현재까지 개발된 이상의 모든 고도처리공정을 살펴보면, 모든 공정이 공통적으로 오염원인 유기물, 질소 및 인을 제거하는 미생물군락 즉 반송슬러지를 획일화하여 모두 혐기, 무산소 및 포기조건을 순환하도록 공정을 구성함으로서 연속적인 포기조건에 노출되어야 할 호기성미생물인 질산화미생물의 활성이 충분히 발현되지 못하고 있으며, 따라서 특히 겨울철 온도저하시 질소처리에 상당한 어려움을 겪고 있다.Looking at all of the advanced treatment processes developed to date, all processes have a common microbial community that removes contaminants, nitrogen and phosphorus, that is, return sludge, so that they all circulate anaerobic, anaerobic and aeration conditions. The activity of nitrifying microorganisms, which are aerobic microorganisms that need to be exposed to continuous aeration conditions, is not fully expressed, and thus, it is difficult to treat nitrogen in particular when the temperature decreases in winter.
이러한 점들을 해결하기 위하여 공정 설계시 상대적으로 포기조의 용량을 크게 설계함으로써 초기 시설 투자비가 많이 소요되는 비경제적인 문제가 발생되었다.In order to solve these problems, the design of the aeration tank was relatively large in designing the process, resulting in an uneconomical problem in which the initial facility investment cost was high.
또한, 생분해도가 높은 일반 하수처리를 위주로 개발된 공정이기때문에 난분해성 유기물 농도가 높고, 특히 유입수중의 질소농도가 높은 폐수의 경우 거의 적용이 불가능한 실정이다.In addition, since the process was developed for the general sewage treatment with high biodegradability, it is almost impossible to apply the waste water having high concentration of hardly decomposable organic matter, and especially high nitrogen concentration in the influent.
본 발명은 상기와 같은 문제를 해결하는 것으로, 포기조건에서의 암모니아성 질소의 질산화와 내부반송을 통한 무산소조건에서의 탈질화에 의해 질소를 제거하고, 슬러지 순환을 통한 혐기성조건에서의 인방출과 포기조건에서의 과량의 인흡수반응을 이용해 하폐수중의 인을 제거토록 하는데 그 목적이 있다.The present invention solves the above problems, by removing the nitrogen by the nitrification of ammonia nitrogen in aeration conditions and the denitrification in anoxic conditions through internal transport, and the phosphorus discharge in anaerobic conditions through the sludge circulation and The purpose is to remove phosphorus from sewage water by using excessive phosphorus absorption under aeration conditions.
즉, 생물 반응조의 구성을 무산소, 혐기 및 호기조 순으로 배열하고, 유입수중의 유기물을 탈질에 최대한 활용하고 유입수 특성상 불균형적인 C/N 비 조절을 위하여 무산소조에 유입수 특성 및 목표수질에 적합한 양의 외부 유기원을 투입하여 호기조로부터 반송된 질산화물을 완전 탈질시키며, 이로인하여 혐기조에서는 완벽한 혐기조건이 제공됨으로써 탈인 미생물에 의한 인방출이 최대화되며 후속하는 호기조건하에서 인을 과잉 흡수하게 함으로써 질소와 인을 동시에 효율적으로 처리할 수 있도록 하는 것이 특징이다.In other words, the composition of the bioreactor is arranged in the order of anaerobic, anaerobic and aerobic tanks, and in order to make the best use of organic matter in denitrification for denitrification, and to control the imbalanced C / N ratio due to the characteristics of the influent, the amount of outside suitable for influent characteristics and target water quality. The nitrogen source returned from the aerobic tank is completely denitrified by inputting an organic source, thereby providing perfect anaerobic conditions in the anaerobic tank to maximize phosphorus release by dephosphorized microorganisms and to simultaneously absorb nitrogen and phosphorus under the subsequent aerobic conditions. It is characterized by efficient processing.
도 1은 본 발명에 따른 하폐수 처리장치 구성도.1 is a block diagram of a wastewater treatment apparatus according to the present invention.
이하에서 도면을 참조로 본 발명을 보다 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail with reference to the accompanying drawings.
도 1은 본 발명에 따른 하폐수 처리장치 구성도로써, 유입수 특성 및 목표수질에 적합한 양의 외부 유기원을 투입하여 질소제거율을 극대화는 무산소조와;1 is a schematic diagram of a wastewater treatment apparatus according to the present invention, an anoxic tank for maximizing nitrogen removal rate by inputting an external organic source in an amount suitable for influent characteristics and target water quality;
상기 무산소조에서 고율의 탈질반응에 의해 후속하여 보다 완벽한 혐기조건이 제공됨으로써 탈인미생물에 의한 인방출이 최대화되는 혐기조와;An anaerobic tank in which the anaerobic tank provides a more complete anaerobic condition by a high rate of denitrification reaction, thereby maximizing phosphorus release by dephosphorus microorganisms;
후속하는 호기조건하에서는 인을 과잉 흡수하게 함으로써 수중의 인농도를 급격히 저감시키고 호기조 슬러지반송에 의해 완전호기성미생물인 질산화미생물의 활성을 향상시켜 고율 질산화가 수행되며, 고율 질산화된 처리수를 내부반송시켜 무산소조에서 고율 탈질시킴으로써 수중의 질소농도를 효율적으로 저감시키키도록 구성한 것을 특징으로 한 생물학적 질소, 인 동시제거 기술이다.Under the following aerobic conditions, by over-absorbing phosphorus, the concentration of phosphorus in the water is drastically reduced, and the rate of nitrification is enhanced by the aerobic sludge transport to improve the activity of nitrifying microorganisms, which are completely aerobic microorganisms. Biological nitrogen and phosphorus simultaneous removal technology characterized in that it is configured to efficiently reduce the nitrogen concentration in the water by high rate denitrification in an oxygen-free tank.
그리고, 상기 호기조 후단부에는, 미생물 월류로 인한 미생물의 유실을 최소화하고 처리수질의 안정화를 꾀하기 위해 호기조 후단 처리수 월류부분 기준으로 수리학적 체류시간 0.5∼2.0시간 범위내에서 미생물 유실 방지판을 설치하고, 미생물 유실 방지판의 높이와 경사 조절을 통해 목적하는 미생물 농도를 유지하도록 한다. 상기한 미생물 유실 방지판의 높이는 포기조 수위를 기준으로 5%∼ 최대 50% 범위로 운영토록하며, 경사판의 각도는 수면직각으로부터 0。∼ 45。 범위로 적용한다.And, in order to minimize the loss of microorganisms due to the microbial overflow and stabilization of the treated water quality at the rear end of the aerobic tank, a microbial loss prevention plate is installed within the hydraulic retention time of 0.5 to 2.0 hours based on the aerobic backside treated water overflow portion And, through the height and inclination of the microbial loss prevention plate to maintain the desired concentration of microorganisms. The height of the microbial loss prevention plate is to operate in the range of 5% to 50% based on the aeration tank level, the angle of the inclined plate is applied in the range of 0 ° to 45 ° from the water perpendicular angle.
탈질을 위한 내부반송관은 호기조와 무산소조 사이에 설치하며,An internal return pipe for denitrification is installed between the aerobic and anoxic tanks.
슬러지 반송은 침전지 반송슬러지로부터 인제거와 탈질을 위한 무산소조 선단으로의 무산소조 슬러지반송과, 질산화미생물의 지속적인 호기조건 제공을 통한 질산화율 향상을 고려한 침전지 반송슬러지로부터 호기조 선단으로의 호기조 슬러지반송을 설치하여 이루어진다.Sludge conveyance is accomplished by installing anoxic tank sludge return from the settling tank sludge to the anoxic tank end for phosphorus removal and denitrification, and aerobic tank sludge transport from the clarifier basin sludge to the aerobic tank end in consideration of the improvement of nitrification rate by providing continuous aerobic conditions of nitrifying microorganisms. .
상기와 같이 구성하는 본 발명은 기존의 처리시설에 적용하기가 용이하도록 장치를 구성하였는바, 특히 처리에 어려움이 많은 질소를 보다 용이하고 효율적으로 처리함을 목적으로, 생물 반응조의 구성을 무산소, 혐기 및 호기조 순으로 배열하였다.The present invention configured as described above is configured to be easy to apply to the existing treatment facility bar, in particular, for the purpose of more easily and efficiently processing nitrogen, which is difficult to process, the composition of the biological reaction tank anaerobic, It was arranged in order of anaerobic and aerobic tanks.
즉, 호기조건에서의 암모니아성 질소의 질산화와, 무산소 조건에서는 내부반송을 통한 질산화물의 탈질을 통해 수중의 질소를 안정적으로 제거하고;That is, the nitrogen in the water is stably removed through nitrification of ammonia nitrogen under aerobic conditions and denitrification of nitric oxide through internal transport under anoxic conditions;
슬러지반송을 통한 무산소조에 후속하는 혐기성 조건에서는 인을 방출하고 호기조건에서는 과량 인 흡수반응을 이용하여 하폐수의 인을 제거토록 한 것이다.Phosphorus was released under anaerobic conditions following sludge transfer and excess phosphorus absorption under aerobic conditions was used to remove phosphorus from wastewater.
이때 유입수중의 유기물을 탈질에 최대한 활용하고 유입수 특성상 불균형적인 C/N비 조절을 위하여 무산소조에 유입수 특성 및 목표수질에 적합한 량의 외부 유기원을 주입하여 질소제거율을 극대화 하는 것을 특징으로 한다.At this time, to maximize the removal rate of nitrogen by injecting the organic material in the influent in an amount suitable for the characteristics of the influent and the target water quality in order to maximize the denitrification and to control the imbalanced C / N ratio due to the characteristics of the influent.
상기와 같은 구성으로 이루어지는 본 발명의 하폐수 처리공정을 살펴보면 다음과 같다.Looking at the wastewater treatment process of the present invention made of a configuration as described above are as follows.
유입수중의 난분해성 고분자 유기물이 무산소조, 혐기조를 거치면서 분해용이한 저분자 유기물로 분해되는 제 1 단계와;A first step in which the hardly decomposable high molecular weight organic material in the influent is decomposed into low molecular weight organic materials that are easily decomposed while passing through an anaerobic tank and an anaerobic tank;
유입수중의 총 질소의 80% 이상을 차지하는 암모니아성 질소를 질산성 질소로 질산화시키는 호기조와 내부반송을 통해 무산소조에서 유입수중의 유기물 외 부족분 유기원을 외부로부터 투입함으로써 고율 탈질시켜 수중의 총질소농도를 저감시키는 제 2단계와;Total anitrogen concentration in water by denitrification by introducing denitrified organic sources other than organic matter in the inflow water from outside through an aerobic tank and internal return that nitrifies ammonia nitrogen, which accounts for more than 80% of the total nitrogen in the influent water Reducing the second step;
슬러지 반송을 통한 탈인미생물에 의헤 무산소조에 연이은 혐기조건하에서 인방출시키고 후속하는 호기조건하에서 인과잉 흡수하게 하여 수중의 인농도를 급격히 저감시키는 제 3단계로 이루어지도록 공정 구성하였다.The process was configured to be discharged under anaerobic conditions by dephosphorization microorganisms through sludge return, and to carry out over-absorption under anaerobic conditions and to drastically reduce phosphorus concentration in water.
그리고, 상기 제 2 단계는 무산소조에서의 탈질반응을 위해 침전조로부터 무산소조로의 슬러지반송과 질산화율을 증진시키기 위해 침전조로부터 호기조 선단으로의 질산화미생물 반송 공정을 더 포함하여 이루어진다.The second step further includes a nitrification and microbial return process from the settling tank to the aerobic tank tip in order to improve sludge transfer and nitrification rate from the settling tank to the anoxic tank for denitrification in the anoxic tank.
그리고, 상기한 공정을 보다 효율적으로 운영하기 위하여 호기조건 후단에 미생물 유실 방지벽을 설치하여 월류되는 미생물을 최소화하고 미생물 농도를 조절 용이하게 함으로써 목표수질을 보다 안정적으로 처리할수 있도록 포기조 후단처리공정을 보완하여 이루어진다.In order to operate the above process more efficiently, a microbial loss prevention wall is installed at the end of the aerobic condition to minimize overflowing microorganisms and to easily control the concentration of microorganisms so that the target water quality can be treated more stably. Complementary
상기와 같은 공정에 의해 이루어지는 본 발명은 미생물학적인 생리특성을 고려하여 기존 고도처리공정에서 전통적으로 문제시 되었던 질산화미생물 활성문제를 해결하였는바, 침전지로부터의 반송슬러지를 호기조 선단으로 설치하여 호기조건에서만 내부순환하는 미생물 군락을 형성하여 질산화미생물의 적응력을 증진시키고 미생물 활성을 향상시킴으로써 안정된 질소제거가 가능하게 하였다.즉 계절적인 영향에 관계없이 상시 안정된 처리가 가능하게 하였으며 따라서, 겨울철에 특히 활성저하로 처리상의 어려움을 겪는 질소제거 문제를 근본적으로 해결하고 동시에 안정된 미생물 군락형성 및 적응을 통한 보다 안정된 처리를 가능하게 하였다.The present invention made by the above process has solved the problem of nitrification microorganism activity which has been traditionally problematic in the existing high-treatment process in consideration of the microbiological physiological characteristics, by installing the return sludge from the sedimentation basin to the aerobic tank end only By forming a microbial community that circulates internally, it is possible to stabilize nitrogen removal by enhancing the adaptability of nitrifying microorganisms and improving microbial activity, i.e. allowing stable treatment at all times regardless of seasonal effects, and thus, particularly in winter It fundamentally solved the problem of nitrogen removal, which suffers from treatment difficulties, and at the same time enabled more stable treatment through stable microbial colonization and adaptation.
특히 고농도 질소함유 폐수의 경우 일반적으로 활성 슬러지 보다 플럭이 가벼워 미생물 유실이 많이 발생하고, 따라서 일정량의 미생물 유지가 어려움으로써 실증시설 운영시 안정처리에 어려움이 야기되는바, 호기조 후단에 미생물 유실 방지벽을 설치함으로써 월류되는 미생물을 최소화하고 유입수질 및 목표수질에 적합한 미생물량을 조절하게 함으로써 목표하는 바에 따라 목표 수질을 용이하게 조절할 수 있게 하였으며 특히 고농도 미생물 운영으로 인해 최소의 반응조 설계만으로도 충분히 안정된 고율처리가 가능하게 됨으로써, 초기시설 투자비를 절감하는 효과도 창출하였다. 실규모 플랜트 운영에 있어 이 운영기술이 실질적으로 경제적인면과 효율적인 면에서 상당히 간단하면서도 효과적인 기술임이 입증되었다.In particular, in the case of high nitrogen concentration wastewater, the flocs are generally lighter than activated sludge, resulting in a large amount of microorganisms. Therefore, it is difficult to maintain a certain amount of microorganisms, which makes it difficult to stabilize the operation of the demonstration facility. By minimizing the amount of microorganisms overflowed and controlling the amount of microorganisms suitable for inflow and target water quality, the target water quality can be easily adjusted according to the target.In particular, the high concentration of microorganisms allows stable and high rate treatment with minimal reactor design. By making it possible, it also created the effect of reducing the initial capital investment. In real-world plant operations, this operating technology has proved to be quite simple and effective in practical economic and efficient terms.
따라서, 본 발명은 일반하수 및 오폐수는 물론 처리에 많은 어려움이 있는 난분해성 유기물 및 고농도 질소함유 공장폐수의 경우에도 용이하게 적용함으로써, 안정된 처리수질을 만족시킬 수 있는 장점이 있다.Therefore, the present invention has an advantage that it is easy to apply even in the case of non-degradable organic matter and high concentration nitrogen-containing plant wastewater having a lot of difficulties in treatment as well as general sewage and wastewater, it is possible to satisfy the stable treated water quality.
상술한 바와같이 본 발명은 일반하수 및 오폐수는 물론 처리에 많은 어려움이 있는 난분해성 유기물 및 고농도 질소함유 공장폐수의 경우에도 용이하게 적용함으로써, 안정된 처리수질을만족시킬는 있는 장점을 제공하게 된다.As described above, the present invention can be easily applied to non-degradable organic matter and high concentration nitrogen-containing plant wastewater, which have many difficulties in treatment as well as general sewage and wastewater, thereby providing an advantage of satisfying stable treated water quality.
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KR100443109B1 (en) * | 2002-09-30 | 2004-08-04 | 한상배 | A Mixing Methods of Reactor using stream of Sludge Recycle and Mixed Liquor Recycle with Pre-Denitrification |
KR20170109322A (en) * | 2016-03-21 | 2017-09-29 | 현대건설주식회사 | Phosphorus adsorption advanced wastewater treatment system |
CN108911428A (en) * | 2018-08-27 | 2018-11-30 | 谢宁汉 | A kind of biochemical sewage disposal system of small water of high concentration |
CN110127958A (en) * | 2019-06-19 | 2019-08-16 | 重庆环保投资有限公司 | The sewage-treatment plant and processing method of multiple spot reflux |
CN114873845A (en) * | 2022-04-25 | 2022-08-09 | 广东新洁源环保工程有限公司 | Integrated vertical tank culture water treatment process |
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KR0143529B1 (en) * | 1994-06-22 | 1998-07-15 | 김광호 | Servo controlling apparatus for disk player |
KR0165630B1 (en) * | 1996-04-23 | 1999-01-15 | 이일쇄 | Highly efficient elimination equipment of nitrogen and phosphor for sewage water |
KR20000019567A (en) * | 1998-09-09 | 2000-04-15 | 김윤규, 정주영, 심옥진, 정몽헌 | Tertiary process using biological method. |
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KR100443109B1 (en) * | 2002-09-30 | 2004-08-04 | 한상배 | A Mixing Methods of Reactor using stream of Sludge Recycle and Mixed Liquor Recycle with Pre-Denitrification |
KR20170109322A (en) * | 2016-03-21 | 2017-09-29 | 현대건설주식회사 | Phosphorus adsorption advanced wastewater treatment system |
CN108911428A (en) * | 2018-08-27 | 2018-11-30 | 谢宁汉 | A kind of biochemical sewage disposal system of small water of high concentration |
CN110127958A (en) * | 2019-06-19 | 2019-08-16 | 重庆环保投资有限公司 | The sewage-treatment plant and processing method of multiple spot reflux |
CN114873845A (en) * | 2022-04-25 | 2022-08-09 | 广东新洁源环保工程有限公司 | Integrated vertical tank culture water treatment process |
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