KR20010019373A - The manufacturing method of water-proof with electron emission material - Google Patents

The manufacturing method of water-proof with electron emission material Download PDF

Info

Publication number
KR20010019373A
KR20010019373A KR1019990035730A KR19990035730A KR20010019373A KR 20010019373 A KR20010019373 A KR 20010019373A KR 1019990035730 A KR1019990035730 A KR 1019990035730A KR 19990035730 A KR19990035730 A KR 19990035730A KR 20010019373 A KR20010019373 A KR 20010019373A
Authority
KR
South Korea
Prior art keywords
charge generating
waterproofing agent
added
generating material
water
Prior art date
Application number
KR1019990035730A
Other languages
Korean (ko)
Other versions
KR100303380B1 (en
Inventor
최린
이병수
안상기
Original Assignee
안상기
주식회사 진성토르마린
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 안상기, 주식회사 진성토르마린 filed Critical 안상기
Priority to KR1019990035730A priority Critical patent/KR100303380B1/en
Publication of KR20010019373A publication Critical patent/KR20010019373A/en
Application granted granted Critical
Publication of KR100303380B1 publication Critical patent/KR100303380B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B59/00—Hull protection specially adapted for vessels; Cleaning devices specially adapted for vessels
    • B63B59/04—Preventing hull fouling
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62—Insulation or other protection; Elements or use of specified material therefor
    • E04B1/64—Insulation or other protection; Elements or use of specified material therefor for making damp-proof; Protection against corrosion

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Plant Pathology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE: A method for producing waterproof agent including charge generating materials is provided to have sterilizing ability without using harmful component, other than waterproof property by means of charge generating materials. CONSTITUTION: A preparation of waterproof agent containing charge generating materials comprises mixing water repellent and waterproofing agents into water absorbing resin in common manner. The absorbing resin is added with 5-15 weight part of charge generating material having a particle size of 3-45 micrometer and forms a mixed solution. To 100ml of the mixed solution, methyl cellulose is added in an amount of 50-60mg to control its viscosity to 740-760cp. The charge generating material is selected from uranium ore, magnetite and tourmaline.

Description

전하 발생 물질이 첨가된 방수제의 제조방법{The manufacturing method of water-proof with electron emission material}The manufacturing method of the waterproofing agent to which the charge generating material is added {The manufacturing method of water-proof with electron emission material}

본 발명은 전하 발생 물질이 첨가된 방수제의 제조방법에 관한 것으로, 보다 상세하게는 통상의 방수제가 가지는 물이 침투하는 것을 방지하는 기능 이외에 살균력이 부가되어 방수제를 바른 부위에 미생물 증식을 막아 청결한 상태를 유지 할 수 있도록 한 전하 발생 물질이 첨가된 방수제의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing a waterproofing agent to which a charge generating material is added, and more specifically, a sterilizing force is added in addition to a function of preventing the penetration of water having a conventional waterproofing agent, thereby preventing microbial growth at the site where the waterproofing agent is applied to a clean state. It relates to a method for preparing a waterproofing agent to which a charge generating material is added to maintain the same.

종래로 부터 건축물 내외의 물과 접하는 부분에서 외부로부터 침투되는 물과 내부에서 외부로 빠져나가는 물을 방지하기 위해 방수제를 필요한 부분에 발라 처리하였다.Conventionally, in order to prevent water penetrating from the outside and water flowing out from the inside in the contact with the water inside and outside the building, the waterproofing agent was applied to the necessary portion.

즉 배의 밑바닥이나 주택가구 건물내부의 지하실 또는 화장실 등의 물과 접하는 다양한 분야에서 누수가 생기는 것을 방지하기 위하여 방수제를 이용하여 처리하여 왔다.In other words, in order to prevent the leakage of water in various fields such as the base of the ship, the basement of the residential furniture building, or the toilet, the water has been treated with a waterproofing agent.

상기와 같이 다양한 용도로 사용되는 방수제의 제조방법은 에폭시수지, 비스페놀A, 폴리에스테르수지, 페놀수지, 우레아수지, 멜라민수지, 폴리에틸렌수지 등의 통상적으로 방수제로 사용되는 수지에 침투성 발수 방수제 혼합한 다음, 방수제의 종류 및 필요한 용도에 따라 에스테르 및 케톤 등의 적당한 유기용제를 선택하여 희석하는 방법으로 방수제를 제조하여 왔다.The manufacturing method of the waterproofing agent used for various purposes as described above is mixed with a permeable water-repellent waterproofing agent to a resin commonly used as a waterproofing agent such as epoxy resin, bisphenol A, polyester resin, phenol resin, urea resin, melamine resin, polyethylene resin In accordance with the type of the waterproofing agent and the required use, a waterproofing agent has been manufactured by selecting and diluting an appropriate organic solvent such as ester and ketone.

상기에서 제조된 방수제를 사용는 경우 아민류, 산무수물, 폴리아미드 및 이미다졸류의 경화제를 첨가하여 사용하여 왔다.In the case of using the above-described waterproofing agent, curing agents of amines, acid anhydrides, polyamides, and imidazoles have been used.

그러나 상기한 제조방법으로 제조된 방수제의 경우 단순히 방수기능만을 가지므로, 상기한 방수제를 배의 밑바닥이나 주택의 지하실 및 화장실 등에 바르게 되면 습기가 찬 부분에 곰팡이 및 각종 미생물이 번식하게 되는 문제점이 발생하였다.However, in the case of the waterproofing agent manufactured by the above-described manufacturing method, it has only a waterproofing function, and when the waterproofing agent is applied to the bottom of a ship or the basement of the house and the bathroom, mold and various microorganisms grow in the moist part. It was.

따라서 상기와 같은 문제점을 해결하기 위해 에폭시수지에 무기항균제를 첨가하여 방수제를 제조하는 방법이 제시되었다.Therefore, in order to solve the above problems, a method of preparing a waterproofing agent by adding an inorganic antibacterial agent to an epoxy resin has been proposed.

그러나 상기한 무기항균제를 첨가한 방수제를 배의 밑바닥에 칠하여 사용하는 경우 무기항균제가 가지는 독성성분이 바닷물속에 용해되어 해양오염을 일으키는 원인으로 작용할 뿐만 아니라, 주택건물에 사용할 경우에도 독성성분이 공기중으로 용출되어 나와 인체에 나쁜 영향을 미친다는 문제점이 발생하였다.However, when the above-mentioned waterproofing agent with inorganic antimicrobial agent is applied to the bottom of a ship, the toxic constituents of the inorganic antimicrobial agent dissolve in seawater and cause marine pollution. Elution has a problem that has a bad effect on the human body.

이에 본 발명은 상기와 같은 종래의 문제점을 해결하기 위한 것으로 방수제의 단순 목적인 방수기능이외에 독성성분을 사용하지 않으면서도 살균능력을 가질 수 있도록 한 전하 발생 물질이 첨가된 방수제의 제조방법을 제공함을 그 목적으로 한다.Accordingly, the present invention is to solve the conventional problems as described above to provide a method of manufacturing a waterproofing agent to which a charge generating material is added so as to have a sterilizing ability without using a toxic ingredient in addition to the waterproofing function that is the simple purpose of the waterproofing agent. The purpose.

상기한 목적을 달성하기 위한 본 발명은 흡수성수지에 침투성 발수 방수제 혼합하는 일반적인 방수제 제조방법에 있어서, 상기 흡수성 수지 100중량부에 대하여 3내지 45㎛로 미분쇄한 전하 발생 물질을 5내지 15중량부 첨가하고 교반하여 혼합용액을 제조한 다음, 제조된 혼합용액 100㎖에 대하여 메틸 셀룰로우스(methyl cellulose)를 50내지 70㎎의 비율로 첨가하여 점도를 740내지 780 cp로 조절하는 것을 특징으로 하는 전하 발생 물질이 첨가된 방수제의 제조방법을 제공함으로써 달성할 수 있다.The present invention for achieving the above object is a general waterproofing agent manufacturing method for mixing the water-repellent waterproofing agent into the absorbent resin, 5 to 15 parts by weight of the finely ground charge generating material 3 to 45㎛ with respect to 100 parts by weight of the absorbent resin After mixing and stirring to prepare a mixed solution, methyl cellulose (methyl cellulose) is added at a rate of 50 to 70 mg to 100 ml of the prepared mixed solution to adjust the viscosity to 740 to 780 cp. It can be achieved by providing a method for producing a waterproofing agent to which a charge generating material is added.

상기에서 사용가능한 흡수성수지에는 에틸렌 비닐 아세테이트, 아크릴 수지, 폴리비닐 알코올, 폴리아크릴산 나트륨, 폴리에틸렌 옥사이드, 아크린산아미드, 셀룰로스, 아라비아 고무, 알긴산나트륨 등이 있으며, 또한 비닐 알코올-아크린산염 공중합체, 초산비닐-아크린산 메틸 공중합체, 아크린산-아크린산 에스테르 공중합체등 흡수성이 높은 공중합체 수지도 사용할 수 있다.Absorbent resins usable above include ethylene vinyl acetate, acrylic resins, polyvinyl alcohol, sodium polyacrylate, polyethylene oxide, acrylate amide, cellulose, gum arabic, sodium alginate and the like, and also vinyl alcohol-acrylic acid copolymers. A copolymer resin with high water absorption, such as a vinyl acetate-methyl acrylate copolymer and an acrylic acid-acrylic acid ester copolymer, can also be used.

상기 방수제의 제조공정에서 흡수성 수지에 미분쇄한 전하발생 물질을 첨가하게 되는 데, 전하 발생 물질로는 일반적으로 전기석이라고 불리는 우라늄광, 자철광 및 토루마린 등의 천연광물을 사용할 수 있으며, 이온화경향이 다른 두개의 금속물질을 사용할 수 있다.In the manufacturing process of the waterproofing agent, the finely-charged charge generating material is added to the absorbent resin, and as the charge generating material, natural minerals such as uranium ore, magnetite, and tourmaline, which are generally called tourmaline, can be used. Two other metals may be used.

일반적으로 전기석이란 현재 지구상에 존재하는 광물중에서 자체적으로 에너지를 갖고 있어 자연상태에서 스스로 전하를 띠고 있는 광물을 말하며, 특히 토루마린은 붕소를 함유하는 규산염 광물질로 특이한 결정구조를 가지며, 외부로부터 충격에너지 또는 열에너지를 흡수하여 이를 전류에너지로 변환시켜 약 0.06㎃의 미세한 전류가 영구적으로 흐른다는 특징이 있다.In general, tourmaline is a mineral that has its own energy among the minerals present on the earth and charges itself in the natural state. In particular, tourmaline is a silicate mineral containing boron and has a unique crystal structure, and impact energy from the outside. Alternatively, it absorbs thermal energy and converts it into current energy so that a minute current of about 0.06 mA flows permanently.

상기와 같은 전기석의 일반적인 화학적 조성은 하기한 화학식 1과 같으며, 흑, 청, 적, 녹, 자, 백색등 그 색상 또한 다양하다.The general chemical composition of the tourmaline is the same as the formula (1) below, black, blue, red, green, purple, white and the like also vary in color.

X·Y9B3Si6O27(O·OH·F)4 XY 9 B 3 Si 6 O 27 (OOH F) 4

X는 Ca, Na, K, Mn등의 물질로 1개 또는 그 이상.X is Ca, Na, K, Mn, etc., one or more.

Y는 Mg, Fe, Al, Cr, Mn, Ti, Li등의 물질로 1개 또는 그 이상.Y is one or more of Mg, Fe, Al, Cr, Mn, Ti, Li and the like.

상기와 같은 특징을 갖는 전하 발생 물질이 방수제를 제조하는 과정에서 첨가되게 되면 이온화 경향이 서로 다른 두개의 금속류는 전위차에 의해서 전류가 흐르게 되고, 또한 전기석은 자체에 의해 전류가 흐르게 된다.When the charge generating material having the above characteristics is added in the process of manufacturing the waterproofing agent, two metals having different ionization tendencies are caused to flow by electric potential, and the tourmaline is caused to flow by electric current.

이 전류에 의해 물은 수산화 이온(OH-)과 수소이온(H+)으로 전기분해 되며, 이때 수소이온은 전하 발생 물질에서 방출되는 전자을 받아 수소가스 상태로 공기중으로 방출 되며, 또한 수산화이온은 상기와 같은 반응의 연속으로 계속적으로 생성되어 물을 pH 7.5의 약 알칼리성이 되게 한다.Water by this current is hydroxide ion (OH -) is electrolyzed to hydrogen ions (H +), wherein protons accepted jeonjaeul released from the charge generating material is released into the air with the hydrogen gas phase, and hydroxide ions are the It is continuously produced in a series of reactions such as to make the water slightly alkaline at pH 7.5.

상기와 같은 반응에 의해 수중에는 미세한 전류가 흐르게 되고, 발생되는 미세한 전류는 단백질을 분해하게 됨으로써 수중 미생물을 살균할 수 있는 능력을 갖게 되는 것이다.By the above reaction, a minute current flows in the water, and the generated minute current decomposes the protein, thereby having the ability to sterilize the microorganisms in the water.

따라서, 상기에서 설명한 살균력을 갖기 위해 전하 발생 물질은 3내지 45㎛로 미분쇄한 다음, 흡수성 수지 100중량부에 대하여 5내지 15중량부 첨가하여 교반하게 되는 것이다.Therefore, in order to have the bactericidal power described above, the charge generating material is pulverized to 3 to 45 µm, and then 5 to 15 parts by weight is added to 100 parts by weight of the absorbent resin to be stirred.

이때 전하 발생 물질의 입자 크기가 3㎛ 미만일 경우 겉보기 비중이 낮아져 수지와 전하 발생 물질의 혼화가 용이하지 않게 되는 문제점이 발생하며, 45㎛를 초과할 경우 입자가 크므로 쉽게 침전되는 문제점이 있으므로 3내지 45㎛로 미분쇄하는 것이 바람직하다.In this case, when the particle size of the charge generating material is less than 3 μm, the apparent specific gravity is lowered, so that the resin and the charge generating material are not easily mixed, and when the particle size exceeds 45 μm, the particles are large and thus easily precipitated. It is preferable to grind | pulverize to 45 micrometers.

또한 그 첨가량은 5중량부 미만일 경우 전하 발생 물질의 량이 적어 살균효과를 충분히 나타낼 수 없다는 문제점이 발생하게 되고, 15중량부를 초과할 경우 전하 발생 물질의 량이 많아지므로 살균력은 향상되지만 점도 조절이 용이하지 못하다는 문제점이 발생하므로 흡수성 수지 100중량부에 대하여 5내지 15중량부 첨가하는 것이 바람직하다.In addition, if the added amount is less than 5 parts by weight, there is a problem that the amount of the charge generating material is not enough to exhibit a sterilization effect, and if the amount exceeds 15 parts by weight, the amount of the charge generating material is increased, so that the sterilizing power is improved, but the viscosity is not easy to control. It is preferable to add 5 to 15 parts by weight with respect to 100 parts by weight of the water absorbent resin because the problem occurs.

또한 제조된 혼합용액의 침전을 방지하기 위하여 적당한 점도 조절이 필요하게 되는 데, 이때 메틸 셀룰로우스(methyl cellulose)를 혼합용액 100㎖에 대하여 50내지 70㎎의 비율로 첨가하여 점도가 740내지 780 cp가 되도록 첨가한다.In addition, in order to prevent precipitation of the prepared mixed solution, an appropriate viscosity control is required, wherein methyl cellulose (methyl cellulose) is added at a ratio of 50 to 70 mg based on 100 ml of the mixed solution, and the viscosity is 740 to 780. Add cp.

상기에서 메틸 셀룰로우스의 첨가량이 50㎎미만으로 첨가할 경우 방수제의 점도가 떨어져 상기에서 첨가한 이온화물질의 침전을 빠르게 진행시키게 되며, 70㎎을 초과할 경우 점도가 높아져 침전물을 생기지 않지만 방수제의 상부로 이온화물질이 부상하는 문제점이 발생하므로 혼합용액 100㎖에 대하여 50내지 70㎎ 첨가하여 혼합용액의 점도를 740내지 780 cp로 하는 것이 바람직하다.When the amount of methyl cellulose added is less than 50 mg, the viscosity of the waterproofing agent is lowered, and the precipitation of the added ionization material is accelerated. If the amount exceeds 70 mg, the viscosity increases, so that no precipitate is formed. Since the problem of floating the ionization material in the upper portion, it is preferable to add 50 to 70 mg to 100 ml of the mixed solution to make the viscosity of the mixed solution 740 to 780 cp.

이하 본 발명을 하기한 실시예 및 실험예를 참조하여 상세하게 설명하나, 본 발명은 하기한 실시예에 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to the following Examples and Experimental Examples, but the present invention is not limited to the following Examples.

<실시예 1＞<Example 1>

흡수성수지에 침투성 발수 방수제 혼합하는 일반적인 방수제 제조방법에 있어서, 상기 흡수성 수지로 에틸렌 비닐 아세테이트 수지 100중량부에 대하여 10㎛로 미분쇄한 전기석 10중량부를 첨가하고 교반하여 혼합용액을 제조한 다음, 혼합용액 100㎖에 대하여 메틸 셀룰로우스를 70㎎의 비율로 첨가하여 점도를 760 cp로 조절하여 전하 방출 물질이 첨가된 방수제를 제조하였다.In the general waterproofing agent manufacturing method of mixing the water-permeable waterproofing agent into the water-absorbent resin, 10 parts by weight of tourmaline finely ground at 10 μm with respect to 100 parts by weight of ethylene vinyl acetate resin is added to the absorbent resin and stirred to prepare a mixed solution, and then mixed To 100 ml of solution, methyl cellulose was added at a rate of 70 mg to adjust the viscosity to 760 cp to prepare a waterproofing agent to which a charge releasing material was added.

<실시예 2＞<Example 2>

흡수성수지에 침투성 발수 방수제 혼합하는 일반적인 방수제 제조방법에 있어서, 상기 흡수성수지로 아크릴 수지 100중량부에 대하여 10㎛로 미분쇄한 전기석 10중량부를 첨가하고 교반하여 혼합용액을 제조한 다음, 혼합용액 100㎖에 대하여 메틸 셀룰로우스를 50㎎의 비율로 첨가하여 점도를 760 cp로 조절하여 전하 방출 물질이 첨가된 방수제를 제조하였다.In the general waterproofing agent manufacturing method for mixing the water-permeable waterproofing agent into the water-absorbent resin, 10 parts by weight of tourmaline finely pulverized into 10㎛ with respect to 100 parts by weight of acrylic resin was added to the absorbent resin and stirred to prepare a mixed solution, and then mixed solution 100 Methyl cellulose was added at a rate of 50 mg per ml to adjust the viscosity to 760 cp to prepare a waterproofing agent to which a charge releasing material was added.

<실시예 3＞<Example 3>

흡수성수지에 침투성 발수 방수제 혼합하는 일반적인 방수제 제조방법에 있어서, 상기 흡수성수지로 에틸렌 비닐 아세테이트 수지 100중량부에 대하여 10㎛로 미분쇄한 동분(Cu)과 아연분(Zn)을 각각 5중량부씩 첨가하고 교반하여 혼합용액을 제조한 다음, 혼합용액 100㎖에 대하여 메틸 셀룰로우스를 70㎎의 비율로 첨가하여 점도를 760 cp로 조절하여 전하 방출 물질이 첨가된 방수제를 제조하였다.In a general waterproofing agent manufacturing method of mixing a water-permeable waterproofing agent with an absorbent resin, 5 parts by weight of copper powder (Cu) and zinc powder (Zn) finely ground to 10 µm are added to 100 parts by weight of ethylene vinyl acetate resin. After stirring and preparing a mixed solution, methyl cellulose was added at a rate of 70 mg to 100 ml of the mixed solution to adjust the viscosity to 760 cp to prepare a waterproofing agent to which a charge releasing material was added.

<비교예＞<Comparative Example>

전하 발생 물질을 첨가하지 않고 상기 실시예 1과 동일한 조건으로 통상의 방수제 제조방법에 의해 방수제를 제조하였다.The waterproofing agent was manufactured by the conventional waterproofing agent manufacturing method under the same conditions as in Example 1 without adding the charge generating material.

<실험예 1＞Experimental Example 1

수중미생물의 살균효과를 측정하기 위하여 상기 실시예 1내지 3 및 비교예에서 제조한 방수제를 이용하여 4개의 비이커 내부에 각각 도포하여 충분히 건조한 다음, 각각의 비이커에 일정량의 물을 붓고 각각 민물조개 5개씩을 넣어 시간 경과에 따른 민물조개의 생존 갯수를 측정하여 표 1에 나타내었다.In order to measure the sterilization effect of aquatic microorganisms, each of the beakers was applied to each of the four beakers using the waterproofing agents prepared in Examples 1 to 3 and Comparative Examples, and then sufficiently dried. The number of surviving freshwater clams over time was measured and the results are shown in Table 1.

구분division 24시간24 hours 48시간48 hours 72시간72 hours 실시예 1Example 1 33 00 00 실시예 2Example 2 44 22 00 실시예 3Example 3 22 00 00 비교예Comparative example 55 33 22

상기 표 1에서 보는 바와 같이 전하 발생 물질을 첨가하여 방수제를 제조한 실시예 1내지 3의 경우 24시간 경과 후 실시예 1은 3개, 실시예 2는 4개, 실시예 3은 2개의 민물조개만 생존해 있는 것을 확인할 수 있었으나, 전하 발생 물질을 첨가하지 않은 비교예의 경우 5개 모두 살아 있는 것을 확인 할 수 있었다.As shown in Table 1, in Examples 1 to 3, where the waterproofing agent was added by adding a charge generating material, after Example 1 and 3, Example 1 was 4, Example 2 was 4, and Example 3 was 2 freshwater clams. Only alive was confirmed, but in the case of the comparative example without the addition of a charge generating material it was confirmed that all five are alive.

또한 72시간 경과 후에는 실시예 1내지 3의 경우 민물조개가 모두 죽은 것을 확인할 수 있으나, 비교예의 경우 2개가 살아 있는 것을 확인 할 수 있었다.In addition, after 72 hours, all of the freshwater clams were dead in Examples 1 to 3, but in the comparative example, two were alive.

따라서, 본 발명에 의해 제조된 방수제의 경우 통상의 제조방법에 의해 제조된 방수제에 비해 살균력이 뛰어난 것을 확인 할 수 있다.Therefore, it can be confirmed that the waterproofing agent produced according to the present invention has superior sterilizing power as compared to the waterproofing agent manufactured by a conventional manufacturing method.

상기에서 살펴본 바와 같이 살균력이 뛰어나므로 습기가 차고 미생물이 번식하는 분야에서 사용하게 되면 살균 효과를 얻을 수 있다는 장점이 있다As described above, since the sterilizing power is excellent, the sterilizing effect can be obtained when used in a field in which moisture and microorganisms propagate.

상기에서 설명한 바와 같이 본 발명은 방수제에 전하 발생 물질을 첨가함으로써 통상의 방수제가 가지는 방수 효과 이외에 독성물질을 사용하지 않으면서도 살균력이 부가됨으로써, 배의 밑바닥이나 주택의 지하실 및 화장실 등 습기가 차고 곰팡이나 각종 미생물 번식이 발생하는 분야에서 사용할 경우 미생물 증식을 막아 깨끗한 환경을 유지할 수 있는 효과를 얻을 수 있다.As described above, in the present invention, by adding a charge generating material to the waterproofing agent, in addition to the waterproofing effect of the conventional waterproofing agent, sterilizing power is added without using a toxic substance, so that the bottom of the ship or the basement of the house and the toilet, the damp and the mold If used in the field where various microbial propagation occurs, it is possible to prevent microbial growth and maintain a clean environment.

또한 본 발명에 의해 제조된 방수제 자체에 전하를 발생하는 물질이 첨가됨으로 방수제로부터 음이온이 발생하여 음이온이 나타내는 공기청정의 효과를 부수적으로 얻을 수 있는 유용한 발명이다.In addition, a charge generating material is added to the waterproofing agent produced by the present invention is a useful invention that can additionally obtain the effect of the air cleaning exhibited by the negative ions generated by the negative ions from the waterproofing agent.

Claims (4)

계면활성제를 첨가하여 만든 흡수성 수지 에멀젼에 침투성 발수 방수제 및 경화제를 혼합하는 방수제의 제조방법에 있어서, 상기 흡수성 수지 100중량부에 대하여 3내지 45㎛로 미분쇄한 전하 발생 물질을 5내지 15중량부 첨가하고 교반하여 혼합용액을 제조한 다음, 제조된 혼합용액 100㎖에 대하여 메틸 셀룰로우스(methyl cellulose)를 50내지 70㎎의 비율로 첨가하여 점도를 740내지 780 cp로 조절하는 것을 특징으로 하는 전하 발생 물질이 첨가된 방수제의 제조방법.In the manufacturing method of the waterproofing agent which mixes a permeable water-repellent waterproofing agent and a hardening | curing agent in the water-absorbent resin emulsion made with the addition of surfactant, 5-15 weight part of finely-pulverized charge generating substances which are 3 to 45 micrometers with respect to 100 weight part of said absorbent resins. After mixing and stirring to prepare a mixed solution, methyl cellulose (methyl cellulose) is added at a rate of 50 to 70 mg to 100 ml of the prepared mixed solution to adjust the viscosity to 740 to 780 cp. Method for producing a waterproofing agent to which a charge generating material is added. 상기 제 1항에 있어서, 흡수성 수지는 에틸렌 비닐 아세테이트, 아크릴 수지, 폴리비닐 알코올, 폴리아크릴산 나트륨, 폴리에틸렌 옥사이드, 아크린산아미드, 셀룰로스, 아라비아 고무, 알긴산나트륨 등이 있으며, 또한 비닐 알코올-아크린산염 공중합체, 초산비닐-아크린산 메틸 공중합체, 아크린산-아크린산 에스테르 공중합체등의 흡수성이 높은 공중합체 수지를 포함하는 것을 특징으로 하는 전하 발생 물질이 첨가된 방수제의 제조방법.The method of claim 1, wherein the water absorbent resin includes ethylene vinyl acetate, acrylic resin, polyvinyl alcohol, sodium polyacrylate, polyethylene oxide, acrylate amide, cellulose, gum arabic, sodium alginate, and the like. A method for producing a waterproofing agent to which a charge generating substance is added, comprising a copolymer resin having high water absorption, such as an acidic acid copolymer, a vinyl acetate-methyl acrylate copolymer, and an acrylic acid-acrylic acid ester copolymer. 제 1항 또는 제 2항에 있어서, 전하 발생 물질로 우라늄광, 자철광 및 토루마린 등의 전기석을 사용함을 특징으로 하는 전하 발생 물질이 첨가된 방수제의 제조방법.The method of manufacturing a waterproofing agent with a charge generating material according to claim 1 or 2, wherein a tourmaline such as uranium ore, magnetite, or tourmaline is used as the charge generating material. 제 1항 또는 제 2항에 있어서, 전하 발생 물질로 이온화경향이 다른 두개의 금속물질을 사용함을 특징으로 하는 전하 발생 물질이 첨가된 방수제의 제조방법.The method of manufacturing a waterproofing agent to which a charge generating material is added is characterized in that two metal materials having different ionization tendencies are used as the charge generating material.
KR1019990035730A 1999-08-26 1999-08-26 The manufacturing method of water-proof with electron emission material KR100303380B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019990035730A KR100303380B1 (en) 1999-08-26 1999-08-26 The manufacturing method of water-proof with electron emission material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019990035730A KR100303380B1 (en) 1999-08-26 1999-08-26 The manufacturing method of water-proof with electron emission material

Publications (2)

Publication Number Publication Date
KR20010019373A true KR20010019373A (en) 2001-03-15
KR100303380B1 KR100303380B1 (en) 2001-09-13

Family

ID=19608853

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019990035730A KR100303380B1 (en) 1999-08-26 1999-08-26 The manufacturing method of water-proof with electron emission material

Country Status (1)

Country Link
KR (1) KR100303380B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010099224A (en) * 2001-09-13 2001-11-09 최린 Synthesis of minerals to produce water-resistant charge-release waterproofing agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010099224A (en) * 2001-09-13 2001-11-09 최린 Synthesis of minerals to produce water-resistant charge-release waterproofing agent

Also Published As

Publication number Publication date
KR100303380B1 (en) 2001-09-13

Similar Documents

Publication Publication Date Title
CN101333022B (en) Ecological modifying agent for mineral substance water quality
KR100848605B1 (en) Chemical reagent for the purpose of simultaneous treatment of n, p and microalgae for prevention eutrophication of water bodies
US20140042075A1 (en) Scale inhibitor
CN103458694A (en) Methods and compositions for remediating microbial induced corrosion and environmental damage and for improving wastewater treatment processes
CN105623406A (en) Water-based conductive electromagnetic shielding building coating based on graphene and production method thereof
CN111268960B (en) Cement-based paint for inducing sessile organisms on surface of ocean engineering and preparation method thereof
CN111253125A (en) Green concrete for inducing adhesion of marine periphyton and preparation method thereof
CN111253124A (en) Construction method of ecological high-durability concrete structure in marine environment
CN101148347A (en) Bacterium-restraining haydite and preparation method thereof
CN110984405B (en) Ecological anti-corrosion method for serving marine reinforced concrete engineering
KR100303380B1 (en) The manufacturing method of water-proof with electron emission material
CN111499290B (en) Periphyton-inducing mortar for surface of underwater ocean engineering and preparation method thereof
WO2019009648A2 (en) Algae-suppressing composition
WO1999030564A1 (en) Algal growth or microbial proliferation inhibitors and use thereof
Adebanjo et al. Antimicrobial Concrete for Development: A Critical Review
KR100896989B1 (en) Water stratum wave blocking composition and plywood floor coated or impregnated composition thereof
CN106966480B (en) Method for improving capability of green synthesis of nano zero-valent iron in degradation of crystal violet dye wastewater and application of method
CN106957098B (en) Method for improving capacity of green synthesis of nano zero-valent iron for degrading alkaline brown G dye waste water and application of method
JPH0565433A (en) Material for preventing adhesion of aquatic life
CN109705686A (en) The multi-functional green inner wall paint of nano silver system
CN101643262A (en) Composite type magnetic trap flocculant and method for removing algaltufa by using flocculant
JP2005272320A (en) Algaecidal additive, method for producing the same and plastic plate and coating containing the same
KR20010099224A (en) Synthesis of minerals to produce water-resistant charge-release waterproofing agent
CN105746513B (en) It is a kind of for compound of dissipation bottom harmful organism and preparation method thereof
KR20030036424A (en) the loess production for improvement of a red tide and a Geological of the sea

Legal Events

Date Code Title Description
A201 Request for examination
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee