KR20010017624A - Rubber composition (washing ball) for activating water molecular and production method thereof - Google Patents

Rubber composition (washing ball) for activating water molecular and production method thereof Download PDF

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Publication number
KR20010017624A
KR20010017624A KR1019990033225A KR19990033225A KR20010017624A KR 20010017624 A KR20010017624 A KR 20010017624A KR 1019990033225 A KR1019990033225 A KR 1019990033225A KR 19990033225 A KR19990033225 A KR 19990033225A KR 20010017624 A KR20010017624 A KR 20010017624A
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weight
rubber
parts
vulcanization accelerator
production method
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KR1019990033225A
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Korean (ko)
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KR100351382B1 (en
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전창호
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홍석범
주식회사 테크노홀딩스
최낙명
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/26—Crosslinking, e.g. vulcanising, of macromolecules of latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers

Abstract

PURPOSE: A rubber composition (washing ball) for activating water molecular and production method thereof are provided to clean clothing fibers by adding alkali ceramic/non-ionic surfactant into natural rubber and compression-foaming it. CONSTITUTION: The rubber composition comprises 100 parts by weight of natural rubber (or synthetic rubber), 20 parts by weight of calcium hydroxide, 50 parts by weight of a surfactant (liquid LAS or NP-8), 73 parts by weight of sodium lauryl sulfate, 90 parts by weight of sodium carbonate, 3 parts by weight of sulfur, 5 parts by weight of zinc oxide, 2 parts by weight of stearic acid, 1 parts by weight of TT (a rubber vulcanization accelerator), 0.5 parts by weight of TS (a rubber vulcanization accelerator), 2 parts by weight of DM (a rubber vulcanization accelerator), and prepared by mixing the above composition for 1 to 3 hrs, compression-foaming at a temperature range of 150 to 170 deg.C for 12-17 min.

Description

물의 계면활성화를 위한 고무의 조성물 및 그의 제조방법Rubber composition for water activation and its preparation method

본 발명은 물의 계면 활성화를 위한 고무의 조성물 및 그의 제조 방법에 관한 것으로서 천연고무(또는 합성고무)에 알카리성 세라믹과 계면활성제 등을 첨가 하여 세탁시 별도의 세제를 첨가하지 않고서도 물을 계면의 상태로 변화 시켜주고, 하이드록실 이온의 생성으로 물을 계면 활성화 시켜 섬유를 세정 하고자 하는데 그 목적이 있다.The present invention relates to a rubber composition for the surface activation of water and a method of manufacturing the same, adding alkaline ceramics and surfactants to natural rubber (or synthetic rubber) and washing the water without adding a detergent. The purpose is to clean the fibers by interfacially activating water with the formation of hydroxyl ions.

본 발명을 실시 예를 들어서 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to Examples.

종래의 세탁 방법은 세탁기의 세탁조에 물과 함께 합성세제를 넣고서 빨래를 하고 있는데 세탁기에서 배수되는 물에 의하여 수질오염을 발생 시켜 생태계를 파괴하고 있으며, 적조 현상 토질오염, 악취발생 등 환경오염 발생 문제점을 해결코자 본 발명품을 개발하게 되었다.The conventional washing method is to wash laundry by putting synthetic detergent together with water in the washing tank of the washing machine, which causes water pollution by water draining from the washing machine, destroying the ecosystem, and causes environmental pollution such as red tide, soil pollution, and odor generation. In order to solve the problem, the present invention was developed.

본 발명은 천연고무(또는 합성고무)에 알카리성 세라믹 분말 과 액상 및 분말 계면활성제 등을 첨가하여 압축성형 발포하여 다공화한 것으로서 물을 계면활성화 하기 위한 목적을 갖고 있다.The present invention has the purpose of surface-activating water as a porous porous by adding an alkaline ceramic powder and a liquid and powdered surfactant to the natural rubber (or synthetic rubber) by compression molding and foaming.

본 발명에서 특징으로 하는 기술적인 과제는 고무의 가황 촉진제 첨가시 사용하는 혼합기 에서 고무의 성질을 잃지 않는 범위에서 알카리성 세라믹분말과 액상 및 분말의 계면활성제와 첨가제의 첨가 한도를 찾아내는 실험을 수십차례에 걸쳐서 실행함으로서 그 한개를 찾아내었고 압축 성형시에 압축 온도와 고무의 가교화 시간에 따라서 성형의 형태가 불규칙하고 부풀어올라 성형의 모양을 규칙적으로 생산하기 위한 성형의 조건은 첨가제의 량을 고무의 중량비에 대하여 188 - 233 중량% 첨가 할 수 있고 성형물의 형상은 원형으로서 50-80mm 의 크기로 가열온도는 섭씨 150-170℃,압축시간은 12-17분 의 성형 조건하에 이루어진 고무의 조성물 및 그의 제조 방법에 그 특징이 있는 것으로 실시예 를 들어서 상세히 설명하면 다음과 같다.Technical problem characterized in the present invention is dozens of experiments to find the addition limit of the surfactant and additives of alkaline ceramic powder, liquid and powder in the range that does not lose the properties of the rubber in the mixer used to add the vulcanization accelerator of rubber In order to produce the shape of the molding regularly, the shape of the molding is irregular and swells according to the compression temperature and the crosslinking time of the rubber during compression molding. It can be added 188-233% by weight relative to the weight ratio, the shape of the molding is circular, 50-80mm in size, the heating temperature is 150-170 ℃, compression time 12-17 minutes of the composition of the rubber and its composition If the manufacturing method is described in detail with reference to the embodiment as follows.

천연고무(또는 합성고무)--- 100중량 %에 첨가제로서 아래와 같다.Natural Rubber (or Synthetic Rubber)

1). 비이온 계면활성제(액상의 LAS,또는 NP-8) --- 50중량%One). Nonionic Surfactant (Liquid LAS, or NP-8) --- 50% by weight

2). SLS(soudium lauryl sulfate) --- 73중량 %2). SLS (soudium lauryl sulfate) --- 73 weight%

3). 소다회(Na2CO3) --- 90 중량 %3). Soda ash (Na 2 CO 3 ) --- 90% by weight

4). 수산화 칼슘(Ca (OH)2) --- 20 중량 %4). Calcium Hydroxide (Ca (OH) 2 )-20 wt%

위의 성분은 물을 계면활성화 하기 위한 첨가제로서 천연고무(또는 합성고무) 중량비에 총 233중량%로서 첨가하고 고무 가황 촉진제로서 이미 공지되어 사용 되고 있는 천연고무(또는 합성고무)의 중량비에 배합비는 아래와 같다.The above components are added to the natural rubber (or synthetic rubber) weight ratio as an additive for surface-activating water as a total of 233% by weight, and the compounding ratio to the weight ratio of natural rubber (or synthetic rubber) already known and used as a rubber vulcanization accelerator. It looks like this:

1). S(유황) --- 3중량%One). S (sulfur) --- 3 wt%

2). ZnO(산화아연) --- 5 중량 %2). ZnO (zinc oxide) --- 5 wt%

3). 스테아린산(경화 지방산) --- 2중량%3). Stearic acid (cured fatty acid) --- 2 wt%

4). TT(가황촉진제) --- 1 중량 %4). TT (vulcanization accelerator) --- 1% by weight

5). TS(가황촉진제) --- 0.5 중량 %5). TS (vulcanization accelerator) --- 0.5 wt%

6). DM(가황촉진제) --- 2 중량 %6). DM (vulcanization accelerator)-2 weight%

총 13.5 중량 % 첨가하여 리다기(고무 배합기)에서 약 2-3시간 배합한후 24시간 상온에서 숙성하여 고무 성형 프레스에서 압축성형 하였다.A total of 13.5% by weight was added, and the mixture was blended for about 2-3 hours in a rubber machine (rubber blender), and then aged at room temperature for 24 hours, followed by compression molding in a rubber molding press.

위와 같이 조성된 볼을 세탁시 세탁조에 투입하여 빨래를 할경우 물을 계면활성화 하고 물의 PH를 알카리화 하여 하이드록실 이온을 생성 섬유의 오물을 분해 유화,분산,젖음성,침투등의 작용을 보인다.When washing the balls prepared as described above into the washing tank to wash the water, the surface of the water is activated and the pH of the water is alkalinized to generate hydroxyl ions, which decomposes, and disperses, disperses, wetts and penetrates the fiber.

본 발명이 이루고자 하는 기술적 과제는 천연고무(또는 합성고무)에 알카리족 세라믹과 비이온 계면활성제를 첨가하여 압축 성형시의 조건을 찾아내어 규격화된 성형품을 생산하기 위한 조건을 찾아내는 기술적 문제를 해결하여 아래와 같은 효과를 얻고자 함이다.The technical problem to be achieved by the present invention is to solve the technical problem of finding the conditions for producing standardized molded products by finding the conditions for compression molding by adding alkali ceramics and nonionic surfactants to natural rubber (or synthetic rubber) To achieve the following effect.

본 발명의 특징에 있어서 천연고무(또는 합성고무) 에 첨가된 수산화 칼슘의 작용은 대기중에서는 수분을 용출 시키고 물 중에서는 대기중에 용출시킨 계면활성제를 세탁시 일정한 용량만을 용출 시켜 행굼,탈수시에는 계면활성제의 용출이 거의 없고 배수되는 물에는 거품의 발생이 없어 생활오수로 인한 수질오염을 근본적으로 방지하는 것이다.In the characteristic of the present invention, the action of calcium hydroxide added to natural rubber (or synthetic rubber) is to elute the moisture in the air and the surfactant eluted in the air in water. There is little elution of surfactant and there is no bubble in the drained water, which basically prevents water pollution caused by domestic sewage.

발명의 구성에 있어서 천연고무(또는 합성고무)에 수산화 칼슘 (Ca(OH)2),소다회(Na2CO3), 비이온 계면활성제(액상의 LAS또는 NP-8), SLS(soudium lauryl sulfate) 고무 중량비에 233중량 %첨가하고 고무 가황 촉진제 유황,산화아연, 스테아린산,TT, TS, DM을 13.5 중량 % 첨가하여 압축성형 하여 조성된 원형의 볼로 섬유의 오물을 분해하기 위한 조성물의특징을 갖는 구성.In the composition of the invention, natural rubber (or synthetic rubber) is added to calcium hydroxide (Ca (OH) 2 ), soda ash (Na 2 CO 3 ), nonionic surfactant (liquid LAS or NP-8), SLS (soudium lauryl sulfate ) 233% by weight to the rubber weight ratio and the rubber vulcanization accelerator sulfur, zinc oxide, stearic acid, TT, TS, DM by adding 13.5% by weight of the composition of the composition for decomposing the dirt of the fiber into a circular ball formed by compression molding Configuration.

위의 조성물로 구성된 고무는 고무 성형 프레스로 압축 성형시 가교화 시키는 온도에 의하여 고무 자체가 발포되어 다공성으로 비표면적이 형성되어 물과 접촉시 계면활성제의 용출이 용이하여 섬유의 세정력을 일정한 수치로 획일화 시킬수 있다. 위와 같은 조성물에 천연고무(또는 합성고무)와 첨가제를 가교화 시켜 조성된 것에 그 특징이 있는 조성물 및 제조방법.Rubber composed of the above composition is foamed by the temperature of the cross-linking during compression molding with a rubber molding press to form a specific surface area of the porous, easy to dissolve the surfactant when contacted with water, so that the cleaning power of the fiber to a constant value It can be made uniform. A composition and a manufacturing method characterized by crosslinking the natural rubber (or synthetic rubber) and additives in the composition as described above.

Claims (2)

천연고무(또는 합성고무)100중량%에 수산화 칼슘(Ca(OH)2)---20중량%, 계면 활성제(액상의 LAS또는 NP-8)--- 50중량%, SLS(soudium lauryl sulfate) --- 73 중량%, 소다회(Na2CO3)--- 90중량% 와 고무가황 촉진제 S(유황) --- 3중량%, ZnO(산화아연)--- 5중량%, 스테아린산(경화 지방산)---- 2중량%, TT(가황촉진제)--- 1중량%, TS(가황촉진제)---0.5중량%, DM(가황촉진제)--- 2중량% 가 혼합된 것에 그 특징이 있는 물의 계면활성화를 위한 고무의 조성물.100% by weight of natural rubber (or synthetic rubber) calcium hydroxide (Ca (OH) 2 ) --20% by weight, surfactant (liquid LAS or NP-8)--50% by weight, SLS (soudium lauryl sulfate ) --- 73% by weight, Soda ash (Na 2 CO 3 ) --- 90% by weight and rubber vulcanization accelerator S (sulfur) --- 3% by weight, ZnO (zinc oxide) --- 5% by weight, stearic acid ( Hardened fatty acid) ---- 2% by weight, TT (vulcanization accelerator) --- 1% by weight, TS (vulcanization accelerator) --- 0.5% by weight, DM (vulcanization accelerator) --- 2% by weight A composition of rubber for the surface activation of water characterized by that. 1항에 있어서 위의 조성물을 고무배합기로 1-3시간 배합하여 고무롤라에서 규격화 시켜 고무성형 프레스로 섭씨 150-170℃의 가열온도와 가교시간 12-17분으로 압축 성형하여 완성된 것에 그 특징이 있는 물의 계면활성화를 위한 고무의 제조방법.According to claim 1, the above composition is mixed with a rubber mixer for 1 to 3 hours and standardized in a rubber roll. The rubber molding press is compression molded at a heating temperature of 150 to 170 ° C. and a crosslinking time of 12 to 17 minutes. Rubber production method for the surface activation of water.
KR1019990033225A 1999-08-05 1999-08-05 Rubber composition for water surface activation and its manufacturing method KR100351382B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030088829A (en) * 2002-05-15 2003-11-20 김영환 No Detergent Rubber Required

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2245279B (en) * 1990-06-20 1993-04-07 Unilever Plc Shampoo composition
CA2133446A1 (en) * 1992-04-13 1993-10-28 Janet L. Marshall Thixotropic liquid automatic dishwashing composition with enzyme
CA2133445C (en) * 1992-04-13 1998-12-15 Steven M. Gabriel Process for preparing thixotropic liquid detergent compositions
JPH07126687A (en) * 1993-11-05 1995-05-16 Toho Chem Ind Co Ltd Detergent composition
JP3764239B2 (en) * 1996-12-10 2006-04-05 日東電工株式会社 Mold cleaning composition for molding semiconductor device and mold cleaning method using the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030088829A (en) * 2002-05-15 2003-11-20 김영환 No Detergent Rubber Required

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