KR20000052801A - Cleansing products - Google Patents

Abstract

PURPOSE: Cleansing products provide effective cleansing using low, and hence less irritating, levels of surfactant while providing superior conditioning benefits. CONSTITUTION: A disposable, single use personal care cleansing and conditioning product comprises: (A) a water insoluble substrate, (B) a lathering surfactant, and (C) a conditioning component, wherein the conditioning component comprises, (i) a water soluble conditioning agent, and (ii) an oil soluble conditioning agent, wherein said cleansing product deposits greater than 2.5 μg/cm¬2 of the conditioning component to the surface of the skin or hair, and wherein the product is substantially dry.

Description

Cleaning products {CLEANSING PRODUCTS}

Personal cleansing products have typically been sold in various forms such as bar soaps, creams, lotions and gels. These cleaning formulations have been developed to meet various criteria that are acceptable to the consumer. These criteria include cleaning efficiency, skin feel, mildness, and amount of foam for the skin, hair and eye mucous membranes. An ideal personal cleanser should gently cleanse the skin or hair, have little or no irritation, and should not produce excessively dry skin or hair after frequent use.

However, these conventional types of personal cleansing products have inherent problems of delivering conditioning effects and balancing cleansing effects. One solution to this problem is to use separate cleaning and conditioning products. However, this is not always convenient or practical, and many consumers prefer to use a single product that can condition the skin or hair with cleansing. In typical cleaning compositions, it is difficult to formulate the conditioning components because many conditioning agents are immiscible with the surfactants, resulting in an undesirable non-homogeneous mixture. In order to obtain a homogeneous mixture with the conditioning component and to prevent the conditioning component from being lost prior to attachment, additional ingredients which suspend the conditioning components in the surfactant mixture are often added, for example emulsifiers, thickeners and gelling agents. Although this produces an aesthetically good homogeneous mixture, it is common for poor adhesion of the conditioning component because the conditioning agent is emulsified during cleaning and is not released effectively. In addition, many conditioning agents have the disadvantage of inhibiting foaming. Foam suppression is a problem because many consumers look for cleaning products that provide a rich, creamy, rich foam.

Thus, it is well known that conventional cleaning products intended to blend surfactants and conditioning components suffer from the inherent disadvantages resulting from the immiscibility of surfactants and conditioning agents. There is a clear need to develop cleaning systems that provide sufficient conditioning with effective cleaning in a single product.

It is also highly desirable to obtain cleaning and conditioning effects from disposable single articles. Disposable products are convenient because they do not require the hassle of carrying bottles, bars, jars, tubes and other forms of cleaning and conditioning products. Disposable products are also more hygienic than these tools because sponges, washcloths, or other cleaning tools that are intended to be reused many times exhibit germ growth, unpleasant odor, and other undesirable properties associated with repeated use. to be.

The present invention has surprisingly found that it is possible to develop products that provide effective detergency and conditioning for convenient, inexpensive and hygienic disposable personal cleansing products. The present invention provides the convenience of not having to use both separate cleaning and conditioning products. The present invention is very convenient to use because it is in the form of a substantially dry product to be used by wetting.

The present invention relates to a dry disposable personal cleansing product, useful for cleaning and conditioning the skin or hair. This product is used by consumers by soaking dry products with water. This product consists of a water insoluble substrate, a surfactant and a conditioning agent. Without wishing to be bound by theory, the substrate improves foaming with a small amount of surfactant, increases cleaning and peelability, and optimizes delivery and adhesion of conditioning components. Thus, the present invention provides an excellent cleansing effect while providing effective detergency using a small, therefore hypoallergenic amount of surfactant. These products are also useful for delivering various active ingredients to the skin or hair during the cleaning process.

It is therefore an object of the present invention to provide a substantially dry skin or hair cleansing and conditioning product for use with water.

Another object of the present invention is to provide a product comprising a water insoluble substrate, a surfactant and a conditioning agent component.

Another object of the present invention is to provide a disposable product intended for single use.

Another object of the present invention is to provide a product that is gentle on skin or hair.

Another object of the present invention is to provide a product useful for delivering various active ingredients to the skin or hair during the cleaning and conditioning process.

Another object of the present invention is to provide a method for cleaning and conditioning the skin or hair.

Another object of the present invention is to provide a method for producing the product of the present invention.

These and other objects of the present invention will become apparent from the following disclosure.

Summary of the Invention

The present invention

(A) a water insoluble substrate,

(B) foaming surfactants, and

(C) a conditioning component comprising (i) a water soluble conditioning agent and (ii) an oil soluble conditioning agent

Wherein the cleaning product adheres more than about 2.5 μg / cm ² of the conditioning component to the surface of the skin or hair, a substantially dry disposable single-use personal protective cleaning and conditioning product.

In another embodiment, the present invention

(A) a water insoluble substrate, and

A cleaning and conditioning composition comprising (B) a conditioning component comprising (i) a foaming surfactant and (ii) (a) a water soluble conditioning agent and (b) an oil soluble conditioning agent.

Wherein the foaming surfactant, the water-soluble conditioning agent and the oil-soluble conditioning agent are added separately or simultaneously to or incorporated in the water-insoluble substrate, wherein the weight ratio of foaming surfactant to conditioning component is about A substantially dry disposable single-use personal protective cleansing and conditioning product, wherein the cleansing product is less than 40: 7 and the cleaning product adheres more than about 2.5 μg / cm ² of conditioning component to the surface of the skin or hair.

In another embodiment, the present invention

(A) foaming surfactants and

(B) a conditioning component comprising (i) a water soluble conditioning agent and (ii) an oil soluble conditioning agent

Adding to the water insoluble substrate separately or simultaneously or incorporating into the substrate,

A substantially dry disposable single use wherein the foaming surfactant to conditioning component has a weight ratio of less than about 40: 7 and the cleaning product adheres more than about 2.5 μg / cm ² of conditioning component to the surface of the skin or hair. A method of making a personal protective cleaning and conditioning product is provided.

In another embodiment, the present invention relates to a method of cleaning and conditioning the skin or hair with the aforementioned personal cleansing product.

In another embodiment, the present invention relates to a method of attaching a conditioning agent to skin or hair.

All percentages and ratios used herein are by weight unless otherwise noted, and all measurements are made at 25 ° C. unless stated otherwise. The present invention may comprise, consist of, or consist essentially of the optional ingredients as well as the optional ingredients described herein.

The present invention relates to a substantially dry disposable personal cleansing product useful for cleaning and conditioning the skin or hair. This dry product is used by consumers soaked in water. The product includes a water insoluble substrate, a foaming surfactant, and a conditioning component further comprising an oil soluble conditioning agent and a water soluble conditioning agent.

The use of a water insoluble substrate improves foaming with a small amount of surfactant, increases cleaning and peelability and optimizes delivery and attachment of conditioning components. Thus, the present invention provides an excellent cleansing effect while providing effective detergency using a small, therefore hypoallergenic amount of surfactant.

The invention also encompasses products comprising various active ingredients for delivery to the skin or hair.

The invention also includes methods of cleaning and wetting skin and hair using the products of the invention and methods of making these products.

The personal cleansing products of the present invention are very effective at cleaning skin or hair while providing effective adhesion of conditioning agents. The product of the present invention may also contain other active ingredients to be attached to the skin or hair.

Without wishing to be bound by theory, it is believed that the substrate contributes greatly to the formation of bubbles and to the attachment of conditioning agents and other active ingredients. This increase in foaming is thought to be a result of the surface action of the substrate. Thus, milder and significantly reduced amounts of surfactant can be used. The reduction in the amount of surfactant required is believed to be related to the reduction in skin or hair drying by the surfactant. In addition, the reduced amount of surfactant greatly reduces the action of the surfactant to inhibit adhesion of the conditioning agent (eg, through emulsification or direct removal by the surfactant).

Without wishing to be bound by theory, the substrate also enhances adhesion of the conditioning agent and active ingredient. Since the present invention is in a dry form, the present invention does not require an emulsifier to inhibit adhesion of the conditioning agent and the active ingredient. In addition, since skin conditioning agents and active ingredients are dried on or incorporated into the substrate, the wet product is delivered directly to the skin or hair by surface contact with the skin.

Finally, the substrate also improves cleaning power. The substrate may have a different texture on each side, for example, rough and smooth. The substrate acts as an effective foaming and peeling tool. When physically contacted with skin or hair, the substrate significantly helps to clean and remove contaminants, cosmetics, dead skin and other debris.

The term "bubbling surfactant" refers to a surfactant which, when mixed with water and mechanically stirred, produces a foam. It is preferred that these surfactants are mild, and that mild means that these surfactants provide a sufficient cleansing or cleaning effect but do not excessively dry the skin or hair, but still meet the foaming criteria described above.

The term "disposable" or "single use" is generally used herein to mean a product that is disposed of after one use.

As used herein, the term "water-activated" means that the present invention is provided to the consumer in a dry form to be used after being wetted with water. These products have been found to foam or “activate” when contacted with water and further stirred.

As used herein, the term "substantially dry" means that the product has little water and generally feels dry when touched. The product of the present invention comprises less than about 10% by weight of water, preferably less than about 5% by weight of water and more preferably less than about 1% by weight of water, as measured in a dry environment, such as low humidity. Those skilled in the art will appreciate that the moisture content of the product as in the present invention may vary depending on the relative humidity of the environment.

As used herein in connection with the foaming surfactants and products of the present invention, the term "mild" refers to an alkyl glyceryl ether sulfonate (AGS) surfactant-based synthetic bar (synbar) Means a mild degree to the skin, comparable to)). The method of measuring the mildness or inverted irritation of surfactant-containing products is based on skin wall destruction testing. In this test, the milder the surfactant, the less the skin wall is destroyed. Skin wall destruction is measured by the relative amount of radio-labeled (tritium labeled) water (3H-H ₂ O) passed through the skin envelope into the physiological buffer from the test solution contained in the diffusion chamber. do. This test is described in TJ Franz [J. Invest. Dermatol., 1975, 64, pp. 190-195 and US Pat. No. 4,673,525, issued to Small et al. On June 16, 1987, both of which are incorporated herein by reference in their entirety. Mild test methods of other surfactants well known to those skilled in the art may be used.

The personal care product of the present invention comprises the following essential ingredients. Compositions incorporated into or applied to a substrate consist essentially of one or more surfactants and one or more conditioning agents. Additional active ingredients may also be included in the composition. Another preferred method is to apply each component separately to the substrate.

Water Insoluble Substrate

The product of the present invention comprises a water insoluble substrate. The term "water insoluble" means that the substrate does not readily decompose when dissolved or immersed in water. Water-insoluble substrates are tools or vehicles for delivering the foaming surfactants and conditioning components of the invention to the skin or hair to be cleaned and conditioned. Without wishing to be bound by theory, the substrate provides a foaming effect upon mechanical agitation and aids in the attachment of the conditioning component.

Various materials can be used as the substrate. The following properties are preferred, but are not limited to: (i) sufficient wet strength for use, (ii) sufficient wear resistance, (iii) sufficient loft and porosity, (iv) sufficient thickness and (v) Suitable size.

Examples of suitable insoluble substrates that meet the criteria include nonwoven substrates, woven substrates, hydroentangled substrates, air entangled substrates, natural sponges, synthetic sponges, polymeric netted meshes, and the like. It is not limited only to. Preferred embodiments use nonwoven substrates because they are economical and readily available in a variety of materials. The term nonwoven means that the layer includes fibers that are not woven into the fabric but are formed from a sheet, mat or pad layer. The fibers may be random (ie, randomly aligned) or carded (ie, combed to be oriented primarily in one direction). The nonwoven substrate can also be made of a combination of layers of random fibers and carded fibers.

Nonwoven substrates may be comprised of a variety of natural and synthetic materials. The term natural means that the substance is derived from a plant, animal, insect, or plant, animal and insect by-product. The term synthetic means that the material is obtained mainly from various artificial materials or further modified natural materials. Common substrate starting materials are usually fibrous webs comprising conventional synthetic or natural textile-length fibers or mixtures thereof.

Examples of natural materials useful in the present invention include, but are not limited to, silk fibers, keratin fibers and cellulose fibers. Examples of keratinous fibers include, but are not limited to, those selected from the group consisting of hair fibers, camel hair fibers and the like. Examples of cellulose fibers include, but are not limited to, those selected from the group consisting of wood pulp fibers, cotton fibers, hemp fibers, jute fibers, flax fibers, and mixtures thereof.

Examples of synthetic materials useful in the present invention include the group consisting of acetate fibers, acrylics, cellulose ester fibers, modacryl, polyamide fibers, polyester fibers, polyolefin fibers, polyvinyl alcohol fibers, rayon fibers, polyurethane foams, and mixtures thereof. It includes, but is not limited to one selected from. Some examples of such synthetic fibers include acrylics, creslan and acrylonitrile-based fibers, acrylics such as oleone; Cellulose ester fibers such as cellulose acetate, anel and aselle; Polyamide fibers such as nylon (eg nylon 6, nylon 66, nylon 610, etc.); Polyesters such as potrel, cordel and polyethylene terephthalate fibers, and dycron; Polyolefin fibers such as polypropylene and polyethylene; Polyvinyl acetate fibers; Polyurethane foams and mixtures thereof. These and other suitable fibers and nonwovens made therefrom are described in Riedel, "Nonwoven Bonding Methods and Materials," Nonwoven World (1987); And The Encyclopedia Americana, vol. 11, pp. 147-153 and vol. 26, pp. 566-581 (1984), and US Pat. Nos. 4,891,227 and 4,891,228, issued to Thaman et al. On January 2, 1990, all of which are incorporated herein by reference in their entirety. .

Nonwoven substrates made from natural materials usually consist of webs or sheets formed from suspensions of fibers on fine wire screens (The Hamper, The Encyclopedia of Chemistry, 3rd edition, 1973, pp. 793-). 795 (1973); and The Encyclopedia Americana, vol. 21, pp. 376-383 (1984) and GA Smook, Handbook of Pulp and Paper Technologies, Technical Association for the Pulp and Paper Industy (1986). ), All of which are incorporated herein by reference in their entirety).

Substrates made from natural materials useful in the present invention can be purchased from a wide variety of sources. Examples of suitable commercially available paper layers useful herein are Airtex ^{R, an} embossed air laid cellulose layer with a base weight of about 71 gsy available from James River, Green Bay, Wyoming, USA. ); And Airtex, an embossed Airlaid Cellulose layer with a base weight of approximately 71 gsy available from James River, Green Bay, Wyoming, USA, available from Walkiesoft USA of Mount Halle, North Carolina. Walkiesoft ^R , an embossed airlaid cellulose layer having a basis weight of about 75 gsy.

Methods of making nonwoven substrates are known in the art. Generally, these nonwoven substrates first cut long strands of fibers or filaments into predetermined lengths, pass water or an air stream, and then pass the air or water loaded with fibers through the screen so that It can be prepared by air laying, water laying, meltblowing, coforming, spun bonding or carding processes to be attached. The resulting layer is then processed in at least one of several types of bonding processes that, regardless of the method of manufacture or composition, hold the individual fibers together and form them into a web that can be held by itself. In the present invention, the nonwoven layer can be prepared by hydroentanglement, thermally bonding or thermobonding, and a combination of the above methods. Moreover, the substrate of the present invention may comprise a single layer or multiple layers. In addition, multilayer substrates may include films and other nonfibrous materials.

Nonwoven substrates made from synthetic materials useful in the present invention can be purchased from a wide range of commercial sources. Examples of suitable nonwoven layers useful herein contain about 50% rayon and about 50% polyester with a basis weight of about 43 gsy (grams per square yard), commercially available from Veratec, Inc., Walpole, Massachusetts. Perforated and hydroentangled material, HEF 40-047, perforated containing about 50% rayon and about 50% polyester with a basis weight of about 56 gsy (grams per square yard) commercially available from Veratech, Walpole, Mass. Hydroentangled material HEF 140-102; Novonet, a warm bonded grid pattern material containing about 100% polypropylene with a basis weight of about 50 gsy, available from Veratech, Walpole, Mass.^R149-616; Novonet 149-801, a heat-bonded grid patterned material containing about 69% rayon, about 25% polypropylene, and about 6% cotton, with a base weight of about 75 gsy available from Veratech, Walpole, Mass. ; Novonet 149-191, a heated bonded grid patterned material containing about 69% rayon, about 25% polypropylene, and about 6% cotton, with a base weight of about 100 gsy available from Veratech, Walpole, Mass. ; HEF Nubtex, a nubbed and perforated hydroentangled material containing about 100% polyester with a basis weight of about 70 gsy, available from Veratech, Walpole, Mass.^R149-801; Keyback, a dry-molded and perforated hydroentangled material containing about 75% rayon and about 25% acrylic fiber with a base weight of about 43 gsy available from Chicopee, New Brunswick, NJ^R) 951V; Keyback, a dry molded perforated hydroentangled material containing about 75% rayon, about 25% acrylic fiber with a base weight of about 39 gsy available from Chicopi, New Brunswick, NJ 1236; Duralace, a perforated, hydroentangled material containing about 100% rayon with a base weight of about 40 gsy to about 115 gsy commercially available from Chicopi, New Brunswick, NJ^R) 1236; Duralace, a perforated, hydroentangled material containing about 100% polyester with a base weight of about 40 gsy commercially available from Chicopi, New Brunswick, NJ 5904; Sonntaro 8868, a hydroentangled material containing about 50% cellulose and about 50% polyester, with a basis weight of about 60 gsy, commercially available from Dupont Chemical Corp. Do not.

Alternatively, the water insoluble substrate may be the polymeric mesh sponge described in EP 702550 A1 published March 27, 1996, which is incorporated herein by reference in its entirety. The polymeric sponges comprise a plurality of extruded tubular net piles made of strong and flexible polymers such as polyamides of polycarboxylic acids and addition polymers of olefin monomers. Although the polymeric sponge is designed for use with a liquid detergent, this type of sponge can be used as the water-insoluble substrate of the present invention.

The substrate can be made into a wide variety of shapes and shapes, including flat pads, thick pads, thin sheets, co-shaped instruments, irregular instruments, and surface area sizes of about 1 to several hundred square inches. The exact size depends on the intended use and product characteristics. About 1 to about 144 in ² , preferably about 10 to about 120 in ² , more preferably about 30 to about 80 in ² , and a surface area of about 1 mil to about 500 mils, preferably about 5 mils to about 250 Particularly convenient are square, round, rectangular or oval pads having a thickness of wheat, more preferably about 10 mils to about 100 mils.

The water insoluble substrate of the present invention may comprise two or more layers, each having a different texture and wearability. Different textures may be made from combinations of different materials or from different manufacturing processes or combinations thereof. The dually textured substrate can provide the advantage of having a more abrasive surface for peeling and a softer absorbing surface for light cleaning. In addition, individual layers of the substrate may be made to have different colors to allow the user to better distinguish the surface.

Foaming Surfactants

The product of the present invention foams from about 0.5% to about 12.5%, preferably from about 0.75% to about 11%, more preferably from about 1% to about 10% by weight based on the water-insoluble substrate Surfactants.

The term foaming surfactant refers to a surfactant that creates bubbles or bubbles when mixed with water and mechanically rubbed. Preferably, the surfactant and surfactant combination should be mild, meaning that it should satisfy the foaming criteria described above without providing excessive drying of the skin or hair while providing sufficient cleaning and cleaning effects.

A wide variety of foaming surfactants are useful herein and include those selected from the group consisting of anionic foaming surfactants, nonionic foaming surfactants, amphoteric foaming surfactants, and mixtures thereof. Cationic surfactants may also be used as optional components so long as they do not adversely affect the overall foaming properties of the required foaming surfactant.

Anionic Foaming Surfactants

Examples of anionic foaming surfactants useful in the compositions of the present invention are described in McCutcheon, Detgents and Emulsifiers, North American Edition (1986), published by allured Publishing Corporation; And Functional Materials, North American Edition (1992) and US Patent No. 3,929,678 to Laughlin et al. On December 30, 1975, but is not limited to such.

A wide variety of anionic foaming surfactants are useful herein. Examples of anionic foaming surfactants are selected from, but are not limited to, sarcosinates, sulfates, isethionates, taurates, phosphates, and mixtures thereof. Among the isethionates, alcoholic isethionates are preferred, and among sulfates, alkyl and alkyl ether sulfates are preferred. Alcoyl isethionates are typically RCO-OCH ₂ CH ₂ SO ₃ M, where R is alkyl or alkenyl having from about 10 to about 30 carbon atoms, and M is ammonium, sodium, potassium, and triethanolamine Water-soluble cation). Examples of such isethionates include, but are not limited to, alkoyl isethionates selected from the group consisting of ammonium cocoyl isethionate, sodium cocoyl isethionate, sodium lauroyl isethionate, and mixtures thereof. .

Alkyl and alkyl ether sulfates are typically ROSO ₃ M and RO (C ₂ H ₄ O) _x SO ₃ M, where R is alkyl or alkenyl having from about 10 to about 30 carbon atoms, and x is about 1 To about 10, M is a water-soluble cation such as ammonium, sodium, potassium, and triethanolamine). Another suitable anionic surfactant is a saturated aliphatic compound of the general formula R ₁ -SO ₃ -M wherein R ₁ is a straight or branched chain having from about 8 to about 24, preferably about 10 to about 16 carbon atoms. Is a water-soluble salt which is the product of an organic sulfuric acid reaction, selected from the group consisting of hydrocarbon radicals, M is a cation). Still other anionic synthetic surfactants include classes referred to as succinamate, olefin sulfonates having about 12 to about 24 carbon atoms, and b-alkyloxy alkanes sulfonates. Examples of such materials are sodium lauryl sulfate and ammonium lauryl sulfate.

Other anionic materials include sarcosinates, examples of which include, but are not limited to, sodium lauroyl sarcosinate, sodium cocoyl sarcosinate, and ammonium lauroyl sarcosinate.

Other anionic materials useful herein are typically soaps of fatty acids having about 8 to about 24, preferably about 10 to about 20 carbon atoms (ie, alkali metal salts such as, for example, sodium or potassium salts). to be. Fatty acids used in soap production can be obtained from natural sources such as glycerides derived from plants or animals such as palm oil, coconut oil, soybean oil, castor oil, resins, laards and the like. Fatty acids may also be artificially synthesized. Soaps are described in more detail in the aforementioned US Pat. No. 4,557,853.

Other anionic materials include phosphates such as monoalkyl, dialkyl and trialkylphosphate salts.

Other anionic materials are of the general formula RCON (CH ₃ ) CH ₂ CH ₂ CO ₂ M, wherein R is alkyl or alkenyl having from about 10 to about 20 carbon atoms, and M is ammonium, sodium, potassium and trialkanol Alkanoyl sarcosinates corresponding to amines (such as water soluble cations such as triethanolamine), with sodium lauroyl sarcosinate being the preferred example.

Another useful substance is taurate based taurine, also known as 2-aminoethanesulfonic acid. Examples of taurates include N-alkyltaurines such as those prepared by reacting dodecylamine with sodium isethionate in accordance with the teachings of US Pat. No. 2,658,072, which is incorporated herein by reference in its entirety.

Preferred examples of anionic foaming surfactants useful herein are sodium lauryl sulfate, ammonium lauryl sulfate, ammonium laureth sulfate, sodium laureth sulfate, sodium trideset sulfate, ammonium cetyl sulfate, sodium cetyl sulfate, ammonium cocoyl Isethionate, sodium lauroyl isethionate, sodium lauroyl sarcosinate, and mixtures thereof.

Particularly preferred for use herein are ammonium lauryl sulfate and ammonium laurate sulfate.

Nonionic Foaming Surfactant

Examples of nonionic foaming surfactants for use in the compositions of the present invention are described in McConcheon, Detgents and Emulsifiers, North American Edition (1986), published by allured Publishing Corporation; And Functional Materials, North American Edition (1992), but is not limited to such.

Nonionic foaming surfactants useful herein include those selected from the group consisting of alkyl glucosides, alkyl polyglucosides, polyhydroxy fatty acid amides, alkoxylated fatty acid esters, sucrose esters, amine oxides and mixtures thereof.

Useful herein are alkyl glucosides and alkyl polyglucosides, which are, for example, condensation of long chain alcohols such as C _8-30 alcohols with sugars or starches such as glycosides or polyglycosides, or polymers of sugars or starches It can be broadly defined as a product. These compounds are of the general formula (S) _n- OR wherein S is a sugar moiety such as glucose, fructose, mannose, and galactose, n is an integer from about 1 to about 1000, and R is a C _8-30 alkyl group ). Examples of the long chain alcohol from which the alkyl group can be derived include decyl alcohol, cetyl alcohol, stearyl alcohol, lauryl alcohol, myristyl alcohol, oleyl alcohol and the like. Preferred examples of such surfactants are those in which S is a glucose moiety, R is a C _8-20 alkyl group and n is an integer from about 1 to about 9. Commercially available examples of such surfactants are decyl polyglucoside (commercially available as APG 325 CS from Henkel) and lauryl polyglucoside (commercially available as APG 600CS and 625 CS from Henkel). Sucrose ester surfactants such as sucrose cocoate and sucrose laurate are also useful.

Other useful nonionic foaming surfactants are polyhydroxy fatty acid amide surfactants, more particular examples of which include glucosamides corresponding to the formula:

Where

R ¹ is H, C _1-4 alkyl, 2-hydroxyethyl, 2-hydroxypropyl, preferably C _1-4 alkyl, more preferably methyl or ethyl, most preferably methyl; R ² is C _5-31 alkyl or alkenyl, preferably C _7-19 alkyl or alkenyl, more preferably C _9-17 alkyl or alkenyl, most preferably C _11-15 alkyl or alkenyl ; Z is a polyhydroxyhydrocarbyl or an alcoholylated derivative thereof (preferably ethoxylated or propoxylated) with a linear hydrocarbyl chain to which at least three hydroxyl groups are directly bonded. Preferably, Z is a sugar residue selected from the group consisting of glucose, fructose, maltose, lactose, galactose, mannose, xylose and mixtures thereof. Particularly preferred surfactants corresponding to the above structure are coconut alkyl N-methyl glucoside amides (ie when the R ² CO-residue is derived from coconut oil fatty acids). Methods for preparing compositions containing polyhydroxy fatty acid amides are described, for example, in British Patent Application No. 809,060, published February 18, 1959 by Thomas Hedley & Co., Ltd. number; US Patent No. 2,965,576, issued to ER Wilson on December 20, 1960; US Patent No. 2,703,798 to AM Schwartz, March 8, 1955; US Patent No. 1,985,424 to Figgot, issued December 25, 1934, all of which are incorporated herein by reference in their entirety.

Other examples of nonionic surfactants include amine oxides. The amine oxides are of the general formula R ₁ R ₂ R ₃ NO wherein R ₁ is an alkyl, alkenyl or monohydroxy alkyl radical having from about 8 to about 18 carbon atoms, 0 to about 10 ethylene oxide residues and 0 to about One glyceryl moiety, and R ₂ and R ₃ have about 1 to about 3 carbon atoms and 0 to about 1 hydroxy group, such as, for example, methyl, ethyl, propyl, hydroxyethyl or hydroxypropyl radicals Corresponds to). The arrow in the above formula is a conventional indication of semipolar bonding. Examples of suitable amine oxides for use in the present invention include dimethyldodecylamine oxide, oleyldi (2-hydroxyethyl) amine oxide, dimethyloctylamine oxide, dimethyldecylamine oxide, dimethyltedecylamine oxide, 3,6,9 -Trioxaheptadecyldimethylamine oxide, di (2-hydroxyethyl) tetradecyl oxide, 2-dodecoxyethyldimethylamine oxide, 3-dodecoxy-2-hydroxypropyldi (3-hydroxypropyl) Amine oxides, dimethylhexadecylamine oxides.

Examples of preferred nonionic surfactants used herein _consist of C _8-14 glucose amide, C _8-14 alkyl polyglucoside, sucrose cocoate, sucrose laurate, lauramin oxide, cocoamine oxide and mixtures thereof And those selected from the group, but not limited thereto.

Amphoteric Foaming Surfactant

The term "amphoteric foaming surfactant" as used herein also includes zwitterionic surfactants well known to those skilled in the art of amphoteric surfactants.

A wide variety of amphoteric foaming surfactants can be used in the compositions of the present invention. Particularly useful are those broadly described as derivatives of aliphatic secondary and tertiary amines, preferably of which nitrogen is in a cationic state, aliphatic radicals are straight or branched chains, and one of the radicals is an ionizable water soluble group, for example For example carboxy, sulfonate, sulfate, phosphate or phosphonate.

Examples of amphoteric surfactants useful in the compositions of the present invention include those described in McCurcheon, Detergents and Emulsifiers, North American edition (1986), published by allured Publishing Corporation; And Functional Materials, North American Edition (1992), but are not limited to these, all of which are incorporated herein by reference in their entirety.

Examples of amphoteric or zwitterionic ionic surfactants are selected from, and are limited to, betaine, sultine, hydroxideultine, alkyliminoacetates, iminodialkanoates, aminoalkanoates, and mixtures thereof It doesn't work.

Examples of betaines include coco dimethyl carboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alpha-carboxyethyl betaine, cetyl dimethyl carboxymethyl betaine, cetyl dimethyl betaine (Lonza Corp.) Commercially available as Lonzaine 16SP), lauryl bis- (2-hydroxyethyl) carboxymethyl betaine, oleyl dimethyl gamma-carboxypropyl betaine, lauryl bis- (2-hydroxypropyl) alpha-carboxyethyl Betaine, coco dimethyl sulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bis- (2-hydroxyethyl) sulfopropyl betaine, amidobetaine and amidosulfobetaine, where RCONH (CH ₂ ) ₃ radicals are bound to the nitrogen atom of betaine, oleyl betaine (available as amphoteric Veltex OLB-50 from Henkel), and cocamidopropyl betaine (Veltex BK-35 and BA from Henkel) As -35 It includes higher alkyl betaines, such as a plate).

Examples of sultaines and hydroxidesultines include substances such as cocamidopropyl hydroxidesultine (available as Mirataine CBS from Rhone-Poulenc).

As used herein, amphoteric surfactants preferably have the following structure:

Wherein R ¹ is unsubstituted, saturated or unsaturated, straight or branched alkyl having from about 9 to about 22 carbon atoms. R ¹ preferably has about 11 to about 18, more preferably about 12 to about 18, and most preferably about 14 to about 18 carbon atoms; m is an integer of 1 to about 3, preferably about 2 to about 3, more preferably 3; n is 0 or 1, preferably 1; R ² and R ³ are independently selected from the group consisting of unsubstituted or hydroxy monosubstituted C ₁ -C ₃ alkyl, preferably R ² and R ³ are CH ₃ ; X is selected from the group consisting of CO ₂ , SO ₃ and SO ₄ ; R ⁴ is selected from the group consisting of alkyl having 1 to about 5 carbon atoms, straight or branched, unsubstituted or hydroxy monosubstituted, saturated or unsaturated. When X is CO ₂ , R ⁴ preferably has one or three, more preferably one carbon atom. When X is SO ₃ or SO ₄ , R ⁴ preferably has about 2 to about 4, more preferably 3 carbon atoms.

Examples of amphoteric surfactants of the invention include the following compounds:

Cetyl dimethyl betaine (also this substance is cetyl betaine under CTFA name)

Cocamidopropyl Betaine

Wherein R has from about 9 to about 13 carbon atoms.

Cocamidopropyl Hydroxy Sultine

Wherein R has from about 9 to about 13 carbon atoms.

Examples of other useful amphoteric surfactants include alkyliminoacetates, and iminodialkanoates and aminoalkanos of the general formulas RN [(CH ₂ ) _m CO ₂ M] ₂ and RNH (CH ₂ ) _m CO ₂ M Ate, where m is 1 to 4, R is C ₈ -C ₂₂ alkyl or alkenyl, and M is H, alkali metal, alkaline earth metal ammonium or alkanol ammonium. Also included are imidazolinium and ammonium derivatives. Specific examples of suitable amphoteric surfactants are sodium 3-dodecyl-aminopropionate, sodium 3-dodecylaminopropane sulfonate, produced according to the teachings of U.S. Patent No. 2,438,091, under the trade name "Miranol". N-higher alkyl aspartic acids such as those commercially available and described in US Pat. No. 2,528,378, all of which are incorporated herein by reference in their entirety. Other examples of useful amphoterics include amphoteric phosphates such as coamidopropyl PG-dimonium chloride phosphate (commercially available as Monaquat PTC from Mona Corp.). Ampoacetates such as disodium lauroampodiaacetate, sodium lauroampoacetate and mixtures thereof are also useful.

Preferred foaming surfactants as used herein are as follows, wherein the anionic foaming surfactant is ammonium lauroyl sarcosinate, sodium tridecet sulfate, sodium lauroyl sarcosinate, ammonium laureth sulfate, Sodium laurate sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, ammonium cocoyl isethionate, sodium cocoyl isethionate, sodium lauroyl isethionate, sodium cetyl sulfate and mixtures thereof ; Wherein the nonionic foaming surfactant consists of lauramin oxide, cocoamine oxide, decyl polyglucose, lauryl polyglucose, sucrose cocoate, C ₁₂ -C ₁₄ glucosamide, sucrose laurate and mixtures thereof Selected from the group; Wherein the amphoteric foaming surfactant is selected from the group consisting of disodium lauroampodiacetate, sodium lauroampoacetate, cetyl dimethyl betaine, cocoamidopropyl betaine, cocoamidopropyl hydroxy sultaine and mixtures thereof do.

Conditioning Ingredients

The product of the present invention comprises conditioning ingredients useful for providing conditioning benefits to the skin or hair during use of the product. The conditioning component constitutes from about 3% to about 99%, preferably from about 4% to about 50%, more preferably from about 5% to about 25% by weight of the water-insoluble substrate.

The conditioning component of the present invention includes a water-soluble conditioning agent and an oil-soluble conditioning agent. The oil soluble conditioning agent is selected from one or more oil soluble conditioning agents having a weighted arithmetic mean solubility parameter of 10.5 or less. The water soluble conditioning agent is selected from one or more water soluble conditioning agents whose weighted arithmetic mean solubility parameter of the water soluble conditioning agent is greater than 10.5. Based on the mathematical definition of these solubility parameters, for oil-soluble conditioning agents comprising two or more compounds, when one compound has an individual solubility parameter greater than 10.5, for example, the weighted arithmetic mean solubility parameter requirement, i.e. 10.5 or less It is understood that the value can be achieved. Conversely, in the case of a water-soluble conditioning agent comprising two or more compounds, when one compound has an individual solubility parameter of 10.5 or less, an appropriate weighted arithmetic mean solubility parameter, i.e., a value greater than 10.5, can be achieved.

Solubility parameters are well known to formulation chemists of ordinary skill in the art and are commonly used as a guide to determine the compatibility and solubility of materials in the formulation process.

The solubility parameter δ of a compound is defined as the square root of the aggregation energy density of that compound. Typically, the solubility parameter of a compound is calculated using Equation 1 below from the values in the other group contribution table to the heat of vaporization and molar volume of the compound element.

In the above formula, Σ _i E _i is the sum of heat of vaporization contributed by the addition group, and Σ _i m _i is the sum of the molar volumes contributed by the addition group.

Standardization tables of heat of vaporization and molar volume contributed by other groups for a wide range of atoms and groups of atoms are described in Barton, A.F. Handbook of Solubility Parameters, CRC Press, Chapter 6, Table 3, pp. 64-66 (1985), which is hereby incorporated by reference in its entirety. The solubility parameter Equation 1 is described in Fedors, R.F., "A Method for Estimating Both the Solubility Parameters and Molar Volumes of Liquids", Polymer Engineering and Science, vol. 14, no. 2, pp. 147-154 (February 1974), which is incorporated herein by reference in its entirety.

The solubility parameters follow the mixing law where the solubility parameter of the mixture is the weighted arithmetic mean (weighted average) of the solubility parameters of each component of the mixture. Handbook of Chemistry and Physics, 57th edition, CRC Press, p. C-726 (1976-1977).

Formulation chemists typically report and use solubility parameters in units of (cal / cm 3) ^1/2 . In the Handbook of Solubility Parameters, the values in the Addition Group Contributions table to the heat of vaporization are reported in kJ / mol. However, the heat of fever values are easily converted to cal / mol using the following well-known relationship:

Gordon, A.J. et al., The Chemist's Companion, John Willey & Sons, pp. 456-463, (1972).

Solubility parameters are also tabulated for a wide range of chemicals. A table of solubility parameters can be found in the Handbook of Solubility Parameters, supra. See also Sollubility Effects In Product, Package, Penetration, And Preservation, C.D., which is hereby incorporated by reference in its entirety. Vaughan, Cosmetics and Toiletries, vol. 103, October 1988, pp. 47-69.

Conditioned show ningje useful as conditioning show usefulness ningje are mineral oil, petrolatum, C ₇ -C ₄₀ branched chain hydrocarbons, C ₁ -C ₃₀ carboxylic acid of the C ₁ -C ₃₀ alcohol esters, C ₂ -C ₃₀ dicarboxylic acid C ₁ -C ₃₀ alcohol esters, C ₁ -C ₃₀ carboxylic acids of monoglycerides, C ₁ -C ₃₀ carboxylic acid of the diglycerides, triglycerides of C ₁ -C ₃₀ carboxylic acid triglyceride, C ₁ -C ₃₀ carboxylic acid of ethylene glycol monoesters, C ₁ -C ₃₀ carboxylic acid esters of ethylene glycol, C ₁ -C ₃₀ carboxylic acids, propylene glycol monoesters, C ₁ -C ₃₀ carboxylic acid of propylene glycol ester, a sugar C ₁ -C ₃₀ carboxylic acid monoesters and polyesters, dialkyl Siloxane, polydiarylsiloxane, polyalkarylsiloxane, cyclomethicone having 3 to 9 silicon atoms, vegetable oil, vegetable hardened oil, polypropylene glycol C ₄ -C ₂₀ alkyl ether, di C ₈ -C ₃₀ alkyl ether And their Including but not limited to those selected from the group consisting of mixtures.

Mineral oil is also known as waseline liquid and is a mixture of liquid hydrocarbons obtained from petroleum. The Merck Index, Tenth Edition, Entry 7048, p. 1033 (1983); And International Cosmetic Ingredient Dictionary, Fifth Edition, vol. 1, p. 415-417 (1993).

Waselin, also known as petroleum jelly, is a colloidal system of non-linear solid hydrocarbons, and high-boiling liquid hydrocarbons, most of which are anchored to micelles. The Merck Index, Tenth Edition, Entry 7047, p. 1033 (1983); Schindler, Drug, Cosmet. Ind., 89, 36-37, 76, 78-80, 82 (1961); And International Cosmetic Ingredient Dictionary, Fifth Edition, vol. 1, p. 537 (1993).

Useful herein are straight and branched chain hydrocarbons having from about 7 to about 40 carbon atoms. Examples of such hydrocarbon materials include dodecane, isododecane, squalane, cholesterol, hydrogenated polyisobutylene, docoic acid (i.e. C ₂₂ hydrocarbons), hexadecane, isohexadecane (pressurs of South Plainfield, NJ) Hydrocarbons sold as Permethyl ^R in Presperse), but is not limited thereto. Also useful are C ₇ -C ₄₀ isoparaffins, which are C ₇ -C ₄₀ branched chain hydrocarbons.

It is also useful ones straight-chain, branched-chain material and of C ₁ -C ₃₀ carboxylic acids, as well as aromatic derivatives, C ₁ -C ₃₀ alcohol esters of C ₂ -C ₃₀ dicarboxylic acids and C ₁ -C ₃₀ alcohol esters. In addition, C ₁ -C ₃₀ carboxylic acids of monoglycerides, C ₁ -C ₃₀ carboxylic acid of the diglycerides, triglycerides of C ₁ -C ₃₀ carboxylic acid triglyceride, C ₁ -C ₃₀ carboxylic acid of ethylene glycol monoesters, C ₁ -C an ester such as _{30-carboxylic} acid ester of ethylene glycol, C ₁ -C ₃₀ carboxylic acids, propylene glycol monoesters and C ₁ -C ₃₀ carboxylic acids, propylene glycol diesters useful. Straight chain, branched and aryl carboxylic acids are included here. Also useful are propoxylated and ethoxylated derivatives of these materials. Examples include diisopropyl sebacate, diisopropyl adipate, isopropyl myristate, isopropyl palmitate, myristyl propionate, ethylene glycol distearate, 2-ethylhexyl palmitate, isodecyl neopentanoate, Di-2-ethylhexyl malate, cetyl palmitate, myristyl myristate, stearyl stearate, cetyl stearate, behenyl behenate, dioctyl malate, dioctyl sebacate, diisopropyl adipate, cetyl octa Noate, diisopropyl dilinoleate, capryl / capric triglycerides, PEG-6 capryl / capric triglycerides, PEG-8 capryl / capric triglycerides, and mixtures thereof Do not.

Also useful are C ₁ -C ₃₀ monoesters and polyesters of various sugars and related materials. These esters are derived from sugar or polyol residues and one or more carboxylic acid residues. Depending on the constituent acids and sugars, these esters may be in liquid or solid form at room temperature. Examples of liquid esters include glucose tetraoleate, glucose tetraester of soybean oil fatty acid (unsaturated), mannose tetraester of mixed soybean oil fatty acid, galactose tetraester of oleic acid, arabinose tetraester of linoleic acid, xylose tetralinoleate, Galactose pentaoleate, sorbitol tetraoleate, sorbitol hexaester of unsaturated soybean oil fatty acid, xylitol pentaoleate, sucrose tetraoleate, sucrose pentaoleate, sucrose hexaoleate, sucrose heptaoleate, Sucrose octaoleate and mixtures thereof. Examples of solid esters include sorbitol hexaesters having a 1: 2 molar ratio of palmitoleate and arachidate, and octaesters of raffinose having a 1: 3 molar ratio of linoleate and behenate. Heptaester of maltose whose carboxylic acid residue is 3: 4 molar ratio of sunflower seed oil fatty acid and lignocerate, octaester of sucrose, which esterifies carboxylic acid residue is 2: 6 molar ratio of oleate and behenate, and esterified Octaesters of sucrose with carboxylic acid residues in a 1: 3: 4 molar ratio of laurate, linoleate and behenate. Preferred solid materials are sucrose polys with an esterification degree of 7 to 8, fatty acid residues of C ₁₈ mono- and / or di-unsaturates and behenic acid, and a molar ratio of unsaturated to behenic acid 1: 7 to 3: 5. Ester. Particularly preferred solid sugar polyesters are sucrose octaesters having about 7 Behen fatty acid residues and about 1 oleic acid residues in the molecule. Other substances are cottonseed or soybean oil fatty acid esters of sucrose. Such ester materials are described in US Pat. No. 2,831,854, US Pat. No. 4,005,196, issued Jan. 25, 1977, and Jan. Pat. US Pat. No. 4,005,195, 1994, issued January 25, 1977. U.S. Patent No. 5,306,516 to Letton et al. On April 26, 1994; U.S. Patent No. 5,306,515 to Leton et al. On April 26, 1994, to Leton et al. On April 26, 1994 U.S. Patent No. 5,305,514, U.S. Patent No. 4,797,300, issued Jan. 10, 1989, to Janizzek et al., U.S. Patent No. 3,963,699, issued June 15, 1976, to Rizzi et al., May 1985. It is further described in U.S. Patent No. 4,518,772 to Volpenhein, dated 21, and U.S. Patent No. 4,517,360, issued to Wolfenstein dated May 21, 1985, all of which are incorporated herein in their entirety. Cited for reference All.

Non-volatile silicones such as polydialkylsiloxanes, polydiarylsiloxanes, and polyalkarylsiloxanes are useful oils. These silicones are described in US Pat. No. 5,069,897, issued to Orr on December 3, 1991, which is incorporated herein by reference in its entirety. The polyalkylsiloxanes correspond to the general formula R ₃ SiO [R ₂ SiO] _x SiR ₃ , wherein R is an alkyl group (preferably R is methyl or ethyl, more preferably methyl) and x is from 0 to Is an integer of about 500 and selected to obtain the desired molecular weight. Commercially available polyalkylsiloxanes include polydimethylsiloxanes, also known as dimethicones, examples of which are the Vicasil ^R series and Dow Corning available from General Electric Company. Corporation, such as, but not limited to, the Dow Corning ^R 200 series commercially available. Specific examples of polydimethylsiloxanes useful herein include Dow Corning 225 fluid having a viscosity of 10 centistokes and a boiling point of at least 200 ° C., and Dow Corning 200 fluids having a boiling point of at least 200 ° C. and having a viscosity of 50, 350 and 12,500 centistokes, respectively. It includes. Also useful are materials such as trimethylsiloxysilicate, a polymeric material corresponding to the general formula [(CH ₂ ) ₃ SiO _1/2 ] _x [SiO ₂ ] _y , where x is an integer from about 1 to about 500 And y is an integer from about 1 to about 500. Trimethylsiloxysilicate is commercially available as a Dow Corning 593 fluid in admixture with dimethicone. Dimethicone, which is dimethyl silicone with hydroxy termini, is also useful herein. These materials can be represented by the general formulas R ₃ SiO [R ₂ SiO] _x SiR ₂ OH and HOR ₂ SiO [R ₂ SiO] _x SiR ₂ OH, where R is an alkyl group (preferably R is methyl or ethyl, More preferably methyl), x is an integer from 0 to about 500 and chosen to obtain the desired molecular weight. Dimethiconols are typically sold as a mixture with dimethicone or cyclomethicone (eg Dow Corning 1401, 1402 and 1403 fluids). Polyalkylaryl siloxanes are also useful herein, with polymethylphenyl siloxanes having a viscosity of about 15 to about 65 centistokes at 25 ° C. These materials can be purchased, for example, as SF 1075 methylphenyl fluid (commercially available from General Electric Company) and 556 Cosmetic Grade phenyl trimethicone fluid (commercially available from Dow Corning Corporation).

Also useful herein are vegetable oils and vegetable cured oils. Examples of vegetable and vegetable oils include safflower oil, castor oil, coconut oil, cottonseed oil, herring oil, palm seed oil, palm oil, peanut oil, soybean oil, rapeseed oil, flaxseed oil, rice bran oil, pine oil, sesame oil, sunflower Seed oil, safflower hardened oil, castor hardened oil, coconut hardened oil, cotton thread hardened oil, herring foil hardened oil, palm seed hardened oil, palm hardened oil, peanut hardened oil, soy hardened oil, flaxseed hardened oil, rapeseed hardened oil, rice bran hardened oil, sesame oil hardened oil, sunflower seed hardened oil and Mixtures thereof.

Also useful are C ₄ -C ₂₀ alkyl ethers of polypropylene glycol, C ₁ -C ₂₀ carboxylic acid esters of polypropylene glycol and di-C ₈ -C ₃₀ alkyl ethers. Examples of these materials include, but are not limited to, PPG-14 butyl ether, PPG-15 stearyl ether, dioctyl ether, dodecyl octyl ether, and mixtures thereof.

Examples of conditioning agents useful as water-soluble conditioning agents include polyhydric alcohols, polypropylene glycols, polyethylene glycols, ureas, pyrrolidone carboxylic acids, ethoxylated and / or propoxylated C ₃ -C ₆ diols and triols, alpha- Hydroxy C ₂ -C ₆ carboxylic acids, ethoxylated and / or propoxylated sugars, polyacrylic acid copolymers, sugars having up to about 12 carbon atoms, sugar alcohols having up to about 12 carbon atoms, and these It includes one selected from the group consisting of a mixture of Specific examples of useful water-soluble conditioning agents include urea; Guanidine; Glycolic acid and glycolate salts (eg ammonium and quaternary alkyl ammonium); Lactic acid and lactate salts (eg, ammonium and quaternary alkyl ammonium); Sucrose, fructose, glucose, erthrose, erythritol, sorbitol, mannitol, glycerol, hexanetriol, propylene glycol, butylene glycol, hexylene glycol and the like; Polyethylene glycols such as PEG-2, PEG-3, PEG-30, PEG-50, PPG-9, PPG-12, PPG-15, PPG-17, PPG-20, PPG-26, PPG-30, PPG- Polypropylene glycol such as 34; Alkoxylated glucose; Hyaluronic acid; And materials such as mixtures thereof. Also available in a variety of forms: aloe vera (e.g., aloe vera gel), chitin, Sanwet, RTM IM-1000, IM-1500, and IM-2500 (Cellanise SuperAbsolvent Materials, Fort Smooth, VA) Sodium polyacrylate, grafted with starch, such as (available from Celanese Superabsorbent Materials); Lactamide monoethanolamine; Acetamide monoethanolamine; And materials such as mixtures thereof are also useful. Also useful are propoxylated glycerol, described as propoxylated glycerol in US Pat. No. 4,976,953, issued December 11, 1990 to Or et al., Which is incorporated herein by reference in its entirety.

Weight ratio and weight percent

In the present invention, the weight ratio of foaming surfactant to conditioning component is less than about 40: 7, preferably less than about 5: 1, more preferably less than about 2.5: 1, most preferably about 1: Less than 1

In one embodiment of the present invention, the cleaning and conditioning component is defined to include a foaming surfactant and a conditioning component further comprising an oil soluble conditioning agent and a water soluble conditioning agent, wherein the foaming surfactant is cleaned And from about 1% to about 75% by weight, preferably from about 10% to about 65%, more preferably from about 15% to about 45% by weight of the conditioning component, wherein the conditioning component From about 15% to about 99%, preferably from about 20% to about 75%, more preferably from about 25% to about 55% by weight of the cleaning and conditioning components.

Additive ingredients

The product of the present invention may include a wide range of optional ingredients. Some of these components are described in detail herein. Particularly useful are several active ingredients that are useful for providing various benefits to the skin or hair during the cleaning and conditioning process. In such compositions, the product is useful for delivering the active ingredient to the skin or hair.

Active ingredient

The compositions of the present invention may comprise one or more active ingredients or pharmaceutically acceptable salts thereof in a safe and effective amount.

As used herein, a “safe and effective amount” is high enough to modify the treatment conditions or benefit the desired skin, but low enough to avoid serious side effects, within the scope of medical judgment, which would reasonably benefit the risk. Means the amount of active ingredient. The safe and effective amount of the active ingredient may vary depending on the particular active ingredient, the ability of the active ingredient to penetrate the skin, the age of the user, health and skin conditions, and other requirements.

Active ingredients useful herein can be classified by therapeutic benefit or inferred mode of action. However, it is to be understood that the active ingredients useful herein can, for example, provide one or more therapeutic advantages or act as one or more pathways of action. Thus, classification herein is made for convenience purposes and is not intended to limit the active ingredient to the particular use or uses described. Also useful herein are pharmaceutically acceptable salts of these active ingredients. The following active ingredients are useful in the compositions of the present invention.

Anti-acne active ingredients: Representative examples of anti-acne active ingredients include salicylic acid (o-hydroxybenzoic acid), salicylic acid derivatives such as 5-octanoyl salicylic acid and keratin solubilizers such as resorcinol; Retinoids such as retinoic acid and derivatives thereof (eg cis and trans); Sulfur containing D and L amino acids and derivatives and salts thereof, in particular N-acetyl derivatives thereof, preferably N-acetyl-L-cysteine; Lipoic acid; Benzoyl peroxide, octopyrox, tetracycline, 2,4,4'-trichloro-2'-hydroxy diphenyl ether, 3,4,4'-trichlorovanylide, azelaic acid and derivatives thereof, phenoxy Antibiotic and antibacterial agents such as ethanol, phenoxypropanol, phenoxyisopropanol, ethyl acetate, clindamycin and meclocycline; Sebostats such as flavonoids; Bile salts such as scynmnol sulfate and its derivatives, deoxycholate and cholate.

Anti-Wrinkle and Anti-Wrinkle Active Ingredients Examples of anti-wrinkle and anti-skin shrink active ingredients include retinoic acid and derivatives thereof (eg cis and trans); Retinol; Retinyl esters; Niacinamide, silicic acid and derivatives thereof; Sulfur-containing D and L amino acids and derivatives and salts thereof, in particular N-acetyl derivatives, preferred examples thereof are N-acetyl-L-cysteine; Thiols such as ethane thiol; Oxyacids, phytic acid, lipoic acid; Lysophosphatidic acid and skin release agents (eg, phenol, etc.).

Nonsteroidal Anti-inflammatory Active Ingredients (NSAIDS): Examples of NSAIDS include the following categories: propionic acid derivatives; Acetic acid derivatives; Phenoic acid derivatives; Biphenylcarboxylic acid derivatives; And oxycam. All of these NSAIDS are fully described in US Pat. No. 4,985,459, issued January 15, 1991 to Sunshine et al., Which is incorporated herein by reference in its entirety. Useful examples of NSAIDS include acetyl salicylic acid, ibuprofen, naproxen, venoxaprofen, flubiprofen, phenofene, fenbufen, ketoprofen, indoprofen, pirprofen, carpropene, oxaprozin, Pranopropene, miroprofen, thioxapropene, supropene, aminopropene, thiapropene acid, flupropene and bucloic acid. Also useful are steroidal anti-inflammatory drugs, including hydrocortisone and the like.

Local Anesthetics Examples of local anesthetic drugs include benzocaine, lidocaine, bupivacaine, chloroprocaine, dibucaine, ethidocaine, mepivacaine, tetracaine, diclonin, hexylcaine, procaine, cocaine, ketamine, Pramoxin, phenol and pharmaceutically acceptable salts thereof.

Artificial tanning agents and tanning promoters: Examples of artificial tanning agents and tanning promoters include tyrosine esters such as dihydroxyacetone, tyrosine, ethyl tyrosinate and phospho-DOPA.

Antibacterial and Antifungal Active Ingredients: Examples of antibacterial and antifungal active ingredients include β-lactam drugs, quinolone drugs, ciprofloxacin, norfloxacin, tetracycline, erythromycin, amikacin, 2,4,4'-trichloro- 2'-hydroxy diphenyl ether, 3,4,4'-trichlorovanilide, phenoxyethanol, phenoxy propanol, phenoxyisopropanol, doxycycline, capreomycin, chlorhexidine, chlortetracycline, oxytetracycline, clindamycin , Ethambutol, hexamidine isethionate, metronidazole, pentamidine, gentamicin, kanamycin, linenemycin, methacycline, metheneamine, minocycline, neomycin, netylmycin, paromomycin, streptomycin, tobramycin, myconazole , Tetracycline hydrochloride, erythromycin, zinc erythromycin, erythromycin estholate, erythromycin Stearate, Amikacin Sulfate, Doxycycline Hydrochloride, Capreomycin Sulfate, Chlorhexidine Gluconate, Chlorhexidine Hydrochloride, Chlortetracycline Hydrochloride, Oxytetracycline Hydrochloride, Clindamycin Hydrochloride, Etambutol Hydrochloride, Metronidazole Hydrochloride, Penta Mydine Hydrochloride, Gentamicin Sulfate, Kanamycin Sulfate, Linenemycin Hydrochloride, Methacycline Hydrochloride, Metheneamine Hypurate, Metheneamine Mandelate, Minocycline Hydrochloride, Neomycin Sulfate, Netylmycin Sulfate, Paromomycin Sulfate, Streptoto Mycin Sulfate, Tobramycin Sulfate, Myconazole Hydrochloride, Amanpadin HA Draw chloride, Amman padin sulfate, loam rocks, blood, para-chloro-meta-xylenol, needle comprises a statin, toll-naphthyl lactate, zinc pyrithione and clotrimazole.

Preferred examples of active agents useful herein are salicylic acid, benzoyl peroxide, 3-hydroxy benzoic acid, glycolic acid, lactic acid, 4-hydroxy benzoic acid, acetyl salicylic acid, 2-hydroxybutanoic acid, 2-hydroxypentanoic acid, 2 Hydroxyhexanoic acid, cis-retinoic acid, trans-retinoic acid, retinol, phytic acid, N-acetyl-L-cysteine, lipoic acid, azelaic acid, arachidonic acid, benzoylperoxide, tetracycline, ibuprofen, naproxen, hydrocortisone , Acetominophene, resorcinol, phenoxyethanol, phenoxypropanol, phenoxyisopropanol, 2,4,4'-trichloro-2'-hydroxy diphenyl ether, 3,4,4'-trichloro Carbanilide, octopyrox, lidocaine hydrochloride, clotrimazole, myconazole, neocycin sulfate, and mixtures thereof.

Sunscreen Active Materials: Useful herein are also sunscreen active materials. Various sunscreen agents are disclosed in U. S. Patent No. 5,087, 445 to Haffey et al. On Feb. 11, 1992; US Patent No. 5,073,372, issued to Turner et al. On December 17, 1991; US Patent No. 5,073,371 to Turner et al. On December 17, 1991; And Segarin et al., Cosmetics Science and Technology, Chapter VIII, pp 189 et al., All of which are incorporated herein by reference in their entirety. Examples of sunscreen agents useful in the compositions of the present invention include 2-ethylhexyl p-methoxycinnamate, 2-ethylhexyl N, N-dimethyl-p-aminobenzoate, p-aminobenzoic acid, 2-phenylbenzimidazole- 5-sulfonic acid, octocrylene, oxybenzone, homomentyl salicylate, octyl salicylate, 4,4'-methoxy-t-butyldibenzoylmethane, 4-isopropyl dibenzoylmethane, 3-benzylidene Camphor, 3- (4-methylbenzylidene) camphor, titanium dioxide, zinc oxide, silica, iron oxide and mixtures thereof, but is not limited thereto. Other useful sunscreen agents are described in US Pat. No. 4,937,370, issued to Sabatelli et al. On June 26, 1990; And US Pat. No. 4,999,186, issued to Sabatelli et al. On March 12, 1991, all of which are incorporated herein by reference in their entirety. Particularly preferred examples of the sunscreen agent are 4-N, N- (2-ethylhexyl) methylaminobenzoic acid ester of 2,4-dihydroxybenzophenone and 4-N, N- with 4-hydroxydibenzoylmethane. (2-ethylhexyl) methylaminobenzoic acid ester, 4-N, N- (2-ethylhexyl) methylaminobenzoic acid ester of 2-hydroxy-4- (2-hydroxyethoxy) benzophenone, 4- (2 4-N, N- (2-ethylhexyl) methylaminobenzoic acid ester of -hydroxyethoxy) dibenzoylmethane and mixtures thereof. The exact amount of sunscreen that can be used depends on the sunscreen chosen and the desired Sun Protection Factor (SPF) to achieve. SPF is a commonly used measure to indicate photoprotection of sunscreens against erythema. The Federal Register, Vol. 43, No. 166, pp. 38206-38269, August 25, 1978.

Examples of preferred active agents useful herein are salicylic acid, benzoyl peroxide, niacinamide, cis-retinoic acid, trans-retinoic acid, retinol, retinyl palmitate, phytic acid, N-acetyl-L-cysteine, azelaic acid, lipoic acid , Resorcinol, lactic acid, glycolic acid, ibuprofen, naproxen, hydrocortisone, phenoxyethanol, phenoxypropanol, phenoxyisopropanol, 2,4,4'-trichloro-2'-hydroxy diphenyl ether, 3 , 4,4'-trichlorocarbanilide, 2-ethylhexyl p-methoxycinnamic acid, oxybenzone, 2-phenylbenzimidazole-5-sulfonic acid, dihydroxyacetone and mixtures thereof It includes, but is not limited to.

Cationic surfactant

The products of the present invention may optionally also include one or more cationic surfactants, so long as they are selected so as not to interfere with the overall foaming properties of the required foaming surfactant.

Examples of cationic surfactants useful herein can be found in McCherchen, Detgents and Emulsifiers, North American edition (1986), published by allured Publishing Corporation; And Functional Materials, North American edition (1992), but is not limited to such.

Examples of cationic surfactants useful herein include, but are not limited to, cationic alkyl ammonium salts such as those having the following general formula:

_{R 1 R 2 R 3 R 4} N + X -

Wherein R ₁ is selected from alkyl groups having about 12 to about 18 carbon atoms, or aromatic, aryl or alkaryl groups having about 12 to about 18 carbon atoms; R ₂ , R ₃ and R ₄ are independently selected from hydrogen, alkyl groups having from about 1 to about 18 carbon atoms, or aromatic, aryl or alkaryl groups having from about 12 to about 18 carbon atoms; X is an anion selected from chloride, bromide, iodide, acetate, phosphate, nitrate, sulfate, methyl sulfate, ethyl sulfate, tosylate, lactate, citrate, glycolate and mixtures thereof. In addition, the alkyl groups may also include ether bonds, or hydroxy or amino group substituents (eg, alkyl groups may include polyethylene glycol and polypropylene glycol moieties).

More preferably, R ₁ is an alkyl group having from about 12 to about 18 carbon atoms; R ₂ is selected from H or an alkyl group having from about 1 to about 18 carbon atoms; R ₃ and R ₄ are independently selected from H or an alkyl group having from about 1 to about 3 carbon atoms; X is as described in the previous paragraph.

Most preferably, R ₁ is an alkyl group having from about 12 to about 18 carbon atoms; R ₂ , R ₃ and R ₄ are selected from H or an alkyl group having from about 1 to about 3 carbon atoms; X is as described above.

On the other hand, other useful cationic surfactants include amino-amides, in which case R ₁ in the structure is otherwise R ₅ CO— (CH ₂ ) _n −, where R ₅ is from about 12 to about 22 carbon atoms And an alkyl group with n being an integer from about 2 to about 6, more preferably from about 2 to about 4, most preferably from about 2 to about 3. Examples of such cationic emulsifiers include stearamidopropyl PG-dimonium chloride phosphate, stearamidopropyl ethyldimonium ethosulfate, stearamidopropyl dimethyl (myristyl acetate) ammonium chloride, stearamidopropyl dimethyl cetearyl ammonium Tosylate, stearamidopropyl dimethyl ammonium chloride, stearamidopropyl dimethyl ammonium lactate and mixtures thereof.

Examples of quaternary ammonium salt cationic surfactants are cetyl ammonium chloride, cetyl ammonium bromide, lauryl ammonium chloride, lauryl ammonium bromide, stearyl ammonium chloride, stearyl ammonium bromide, cetyl dimethyl ammonium chloride, cetyl dimethyl ammonium bromide, lauryl Dimethyl ammonium chloride, lauryl dimethyl ammonium bromide, stearyl dimethyl ammonium chloride, stearyl dimethyl ammonium bromide, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, stearyl trimethyl ammonium chloride, Stearyl Trimethyl Ammonium Bromide, Lauryl Dimethyl Ammonium Chloride, Stearyl Dimethyl Cetyl Ditallow Dimethyl Ammonium Chloride, Dicetyl Monium chloride, dicetyl ammonium bromide, dilauryl ammonium chloride, dilauryl ammonium bromide, distearyl ammonium chloride, distearyl ammonium bromide, dicetyl methyl ammonium chloride, dicetyl methyl ammonium bromide, dilauryl methyl ammonium chloride, dilauryl Methyl ammonium bromide, distearyl methyl ammonium chloride, distearyl dimethyl ammonium chloride, distearyl methyl ammonium bromide, and mixtures thereof. Additional quaternary ammonium salts include, but are not limited to, those whose C _12-14 alkyl carbon chains are derived from tallow fatty acids or coconut fatty acids. The term "tallow" refers to an alkyl group derived from tallow fatty acid (typically hydrogenated tallow fatty acid), which typically has a mixture of C _16-18 alkyl chains. The term "coconut" refers to an alkyl group derived from coconut fatty acid, which typically has a mixture of C _12-14 alkyl chains. Examples of quaternary ammonium salts derived from tallow and coconut raw materials are ditallow dimethyl ammonium chloride, ditallow dimethyl ammonium methyl sulfate, di (hydrogenated tallow) dimethyl ammonium chloride, di (hydrogenated tallow) dimethyl ammonium acetate, dital Low Dipropyl Ammonium Phosphate, Ditlow Dimethyl Ammonium Nitrate, Di (coconutalkyl) Dimethyl Ammonium Chloride, Di (coconutalkyl) Dimethyl Ammonium Bromide, Tallow Ammonium Chloride, Coconut Ammonium Chloride, Stearamidopropyl PG-Dimmonium Chloride Phosphate , Stearamidopropyl ethyldimonium ethosulfate, stearamidopropyl dimethyl (myristyl acetate) ammonium chloride, stearamidopropyl dimethyl cetearyl ammonium tosylate, stearamidopropyl dimethyl ammonium chloride, And aralkyl amido include propyl dimethyl ammonium lactate, and mixtures thereof.

Preferred cationic surfactants useful herein are from the group consisting of dilauryl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride, dimyristyl dimethyl ammonium chloride, dipalmityl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride and mixtures thereof Contains the ones selected.

Other optional ingredients

The composition of the present invention may include a wide variety of other optional ingredients. Such additional ingredients must be pharmaceutically acceptable. The CTFA Cosmetic Ingredient Handbook, Second Edition, 1992, which is hereby incorporated by reference in its entirety, discloses a wide range of non-limiting cosmetic and pharmaceutical applications commonly used in the skin care industry, suitable for use in the compositions of the present invention. The components are described. Examples of functionally classified components are disclosed on page 537 of the document, but are not limited to such. Examples of these and other functional classes include abrasives, absorbents, dispersants, antioxidants, vitamins, binders, biological additives, buffers, swelling agents, chelating agents, chemical additives, colorants, cosmetic astringents, cosmetic fungicides, denaturants, drug astringents External analgesics, film formers, fragrance ingredients, humectants, milk whitening agents, pH adjusting agents, preservatives, propellants, reducing agents, skin bleaches, and sunscreens.

Also useful herein are aesthetic ingredients such as fragrances, pigments, colorants, essence oils, skin sensates, astringents, skin soothing agents and skin healing agents.

Manufacturing method

Disposable single-use personal protective cleansing and conditioning products of the present invention are prepared by separately or simultaneously adding or incorporating foaming surfactants and conditioning agents in a water-insoluble substrate, and the products produced are substantially dry. By "separately" is meant that the surfactant and the conditioning agent are added one after the other so as not to be mixed together first. By "simultaneously" is meant that the surfactant and the conditioning agent are added simultaneously with or without mixing first.

For example, the foaming surfactant may be first added or incorporated into the water-insoluble substrate and then the conditioning agent may be added or incorporated or vice versa. Alternatively, foaming surfactants and conditioning agents can be added or incorporated simultaneously into the water-insoluble substrate. Alternatively, the foaming surfactant and conditioning agent can be premixed before addition or incorporation into the water insoluble substrate.

Surfactants, conditioning agents and any optional ingredients may be added to the water-insoluble substrate by any method known to those skilled in the art, such as spraying, laser printing, splash, dipping or coating. Can be embedded.

In the manufacturing process, when water or moisture is used or present, the treated substrate is dried to substantially remove water. The treated substrate can be dried by any method known to those skilled in the art. Examples of known drying methods include, but are not limited to, the use of convection ovens, radiant heat sources, microwave ovens, forced air ovens, and heating rollers or cans. Drying also includes air drying without addition of heating energy other than the surrounding environment at that time.

How to clean and condition your skin or hair

The invention also relates to a method for cleaning and conditioning the skin or hair with the personal cleansing product of the invention. The method includes wetting a substantially dry, disposable, single-use personal cleansing product comprising a water-insoluble substrate, a foaming surfactant, and a conditioning component, and contacting the wet product with skin or hair. . In another embodiment, the present invention is also useful for delivering various active ingredients to the skin or hair.

The product of the present invention is substantially dry and wetted by water before being used. The product is wetted by being immersed in water or placed under water lines. Foam is generated from the product by mechanical agitation and / or by deformation of the product before or during contact with the skin or hair. The foam obtained is useful for cleaning and conditioning the skin or hair. During the process of rinsing with water and then rinsing, the conditioning agent and the active ingredients adhere to the skin or hair. The adhesion of the conditioning agent and the active ingredients is increased as physical contact of the substrate with the skin or hair.

Attachment of Conditioning Ingredients and Any Active Ingredients to Skin or Hair

The composition of the present invention is useful for attaching the conditioning component of the present invention to skin or hair. In another embodiment in which the active ingredient is present, the composition is also useful for attaching the active ingredient to skin or hair.

During use of the product, the compositions of the present invention contain more than about 2.5 μg / cm 2 of conditioning components in the skin or hair, preferably more than about 5 μg / cm 2, more preferably more than 10 μg / cm 2, most Preferably more than 25 μg / cm 2.

The invention also provides a conditioning component on the surface of the skin or hair of more than about 2.5 μg / cm 2, preferably more than about 5 μg / cm 2, more preferably more than 10 μg / cm 2, most preferably 25 It relates to a method of attaching more than μg / cm 2.

The amount of conditioning component attached to the skin or hair can be measured by using various standard analytical techniques known to chemists of ordinary skill in the art. The method may, for example, extract the skin or hair area with a suitable solvent, followed by chromatography (eg gas chromatography, liquid chromatography, supercritical fluid chromatography, etc.), IR spectroscopy, UV / VIS spectroscopy, mass Analysis by spectroscopy or the like. Direct measurements can be performed on the skin or hair, for example by IR spectroscopy, UV / VIS spectroscopy, opacity measurements, fluorescence spectroscopy, ESCA spectroscopy and other method techniques.

In a typical method of measuring adhesion, the product of the present invention is wetted with water, pressed and stirred to generate foam. The product is then rubbed for about 15 seconds into the skin or hair area of about 25 to 300 cm 2, preferably about 50 to about 100 cm 2, bounded by a suitable indelible marker. The area is rinsed for about 10 seconds and then air dried for about 10 minutes. The regions are then extracted using any of the techniques exemplified above to analyze the extract or directly.

The following examples further illustrate and represent embodiments that fall within the scope of the invention. In the examples below, all ingredients are listed in active amounts. The examples are provided for illustrative purposes only and should not be construed as limiting the invention as many variations may be made without departing from the spirit and scope of the invention.

Ingredients are represented by chemical or CTFA names.

Examples 1-4

Personal protective cleaning and conditioning products are prepared as follows:

Water Insoluble Substrate

A hydroapertured nonwoven substrate having a basis weight of about 60 gsy including 50% rayon and 50% polyester, about 6 inches by 7.6 inches in area, and about 20 mils thick.

In a suitable vessel, the Phase A ingredients were mixed at room temperature to form a dispersion and heated with stirring at 65 ° C. Phase B ingredients were mixed in a separate suitable container and heated at 65 ° C. When the temperature was the same, the B phase components were mixed in a container containing the A phase components, and then cooled at 45 ° C. Phase C components were then mixed at room temperature in a separate vessel. To the vessel containing the mixture of phase A and phase B, the phase C mixture was added at room temperature. 1.5 g of the resulting solution was sprayed onto each substrate. Alternatively, the substrate can be immersed in the obtained solution. The treated substrate was then dried in an oven to keep the weight constant. Alternatively, the treated substrate was dried in a convection oven at 45 ° C. to keep the weight constant.

The resulting cleaning composition is used wetted with water and is useful for cleaning skin or hair and for attaching conditioning agents to the skin or hair.

In other methods of preparation, the foaming surfactant, conditioning agent and optional ingredients may be added or incorporated separately or simultaneously to the water insoluble substrate by spraying, laser printing, splashing, dipping or coating.

In other embodiments, the other substrates are, for example, woven substrates, hydroentangled substrates, natural sponges, synthetic sponges or polymeric net meshes.

Examples 5-8

Personal protective cleaning and conditioning products are prepared as follows:

Water Insoluble Substrate

A hydrated perforated nonwoven substrate having a basis weight of about 60 gsy including 50% rayon and 50% polyester, about 6 inches by 7.6 inches in area, and about 20 mils thick.

In a suitable vessel, the Phase A ingredients were mixed at room temperature to form a dispersion and heated with stirring at 65 ° C. Phase B ingredients were mixed in a separate suitable container and heated at 65 ° C. When the temperature was the same, the B phase components were mixed in a container containing the A phase components, and then cooled at 45 ° C. Phase C components were then mixed at room temperature in a separate vessel. To the vessel containing the mixture of phase A and phase B, the phase C mixture was added at room temperature. 1.5 g of the resulting solution was sprayed onto each substrate. Alternatively, the substrate can be immersed in the obtained solution. The treated substrate was then dried in an oven to keep the weight constant. Alternatively, the treated substrate was dried in a convection oven at 45 ° C. to keep the weight constant.

The resulting cleaning composition is used wetted with water and is useful for cleaning skin or hair and for attaching conditioning agents to the skin or hair.

In other methods of preparation, the foaming surfactant, conditioning agent and optional ingredients may be added or incorporated separately or simultaneously to the water insoluble substrate by spraying, laser printing, splashing, dipping or coating.

In other embodiments, the other substrates are, for example, woven substrates, hydroentangled substrates, natural sponges, synthetic sponges or polymeric net meshes.

Claims (13)

(A) a water insoluble substrate, (B) a lathering surfactant, and (C) a conditioning component comprising (i) a water soluble conditioning agent and (ii) an oil soluble conditioning agent Wherein the cleaning product adheres more than about 2.5 μg / cm ² of conditioning component to the surface of the skin or hair, A substantially dry, single use, single use personal protective cleansing and conditioning product. The method of claim 1, The foaming surfactant comprises 0.5 to 12.5% by weight of the water-insoluble substrate, the conditioning component comprises 3 to 99% by weight of the water-insoluble substrate, and preferably the weight ratio of the foaming surfactant to the conditioning component is 40 : Less than 7 products. The method according to claim 1 or 2, Water-insoluble substrate, silk; keratin; Cellulose, preferably wood pulp, cotton, hemp, jute and flax; Acetates, preferably polyvinyl acetates; Acrylic, preferably modacrylic; Cellulose esters; Polyamides, preferably nylon; Polyester; Polyolefins, preferably polypropylene and polyethylene; Polyvinyl alcohol; Polyurethane; Rayon; And at least one substance selected from the group consisting of: a mixture thereof. The method according to any one of claims 1 to 3, The water insoluble substrate may be a nonwoven substrate, preferably a nonwoven sheet of fibers selected from the group consisting of rayon fibers, cellulose fibers, polyester fibers and mixtures thereof; Woven substrate; Hydroentangled substrates; Natural sponge; Synthetic sponges; Polymeric net mesh; Forming film; And mixtures thereof. The method according to any one of claims 1 to 4, An article in which the water-insoluble substrate alternately comprises two or more fibrous sheets having different textures. The method according to any one of claims 1 to 5, Foaming surfactants are preferably sarcosinates, sulfates, isethionates, phosphates, taurates and mixtures thereof, more preferably ammonium lauroyl sarcosinate, sodium trideset sulfate, sodium lauroyl Sarcosinate, ammonium laureth sulfate, sodium laureth sulfate, ammonium lauryl sulfate, sodium lauryl sulfate, ammonium cocoyl isethionate, sodium cocoyl isethionate, sodium lauroyl isethionate, sodium cetyl sulfate and Anionic foaming surfactants selected from the group consisting of mixtures thereof; Preferably amine oxides, alkyl glucosides, alkyl polyglucosides, polyhydroxy fatty acid amides, alkoxylated fatty acid esters, sucrose esters and mixtures thereof, more preferably lauamine oxide, cocoamine oxide, decyl poly Nonionic foaming surfactants selected from the group consisting of glucose, lauryl polyglucose, C _12-14 glucose amide, sucrose cocoate, sucrose laurate and mixtures thereof; Preferably betaine, sultaine, hydroxysulfine, alkyliminoacetate, iminodialkanoate, aminoalkanoate and mixtures thereof, more preferably disodium lauroampodiacetate, sodium lauroampo Amphoteric foaming surfactants selected from the group consisting of acetate, cetyl dimethyl betaine, cocoamidopropyl betaine, cocoamidopropyl hydroxy sultaine and mixtures thereof; And mixtures thereof. The method according to any one of claims 1 to 6, The oil-soluble conditioning agent is selected from one or more oil-soluble conditioning agents having a weighted arithmetic mean solubility parameter of 10.5 or less of the oil-soluble conditioning agent, and preferably the oil-soluble conditioning agent is a fatty acid, polyol polyester, glycerin mono-ester, glycerin di-ester , Glycerin tri-esters, epidermal and sebaceous hydrocarbons, lanolin, mineral oils, silicone oils, silicone gums, vegetable oils, vegetable oil adducts, waselin, nonionic polymers and mixtures thereof, The water soluble conditioning agent is selected from one or more water soluble conditioning agents whose weighted arithmetic mean solubility parameter of the water soluble conditioning agent is greater than 10.5, preferably the water soluble conditioning agent is glycerin, glycerol, propylene glycol, polypropylene glycol, polyethylene glycol, Product selected from the group consisting of ethyl hexanediol, hexylene glycol, other aliphatic alcohols, panthenol, urea, cationic polymers, polyols, glycolic acid, lactic acid and mixtures thereof. The method according to any one of claims 1 to 7, Anti-acne active ingredients, preferably salicylic acid, resorcinol, cis-retinoic acid, trans-retinoic acid, N-acetyl L-cysteine, lipoic acid, benzoyl peroxide, azelaic acid, phenoxyethanol, phenoxypropanol and phenoxy Siisopropanol; Anti-wrinkle and anti-wrinkle active ingredients, preferably cis-retinoic acid, trans-retinoic acid, retinol, retinyl palmitate, niacinamide, salicylic acid, N-acetyl L-cysteine, phytic acid, lipoic acid, glycolic acid and lactic acid ; Nonsteroidal anti-inflammatory active ingredients, preferably ibuprofen, naproxen and hydrocortisone; Local anesthetics; Artificial tanning agents and tanning accelerators, preferably dihydroxyacetone; Antibacterial and antifungal agents, preferably 2,4,4'-trichloro-2'-hydroxy diphenyl ether and 3,4,4'-trichlorocarbinide; Sunscreen active ingredients, preferably 2-ethylhexyl p-methoxycinnamic acid, oxybenzone and 2-phenylbenzimidazole-5-sulfonic acid; Antioxidants; And at least one active ingredient selected from the group consisting of a mixture thereof, in a safe and effective amount. (A) a water insoluble substrate, and (B) a foaming surfactant which preferably comprises 1 to 75% by weight of the cleaning and conditioning composition, and (ii) preferably 15 to 99% by weight of the cleaning and conditioning composition, Cleaning and conditioning compositions comprising a conditioning component comprising (a) a water soluble conditioning agent and (b) an oil soluble conditioning agent Wherein the foaming surfactant, the water soluble conditioning agent and the oil soluble conditioning agent are added to or incorporated into the water insoluble substrate separately or simultaneously, and wherein the weight ratio of foaming surfactant to conditioning component is 40: Less than 7 and the cleaning product adheres more than about 2.5 μg / cm ² of conditioning ingredients to the surface of the skin or hair, A substantially dry, single use, single use personal protective cleansing and conditioning product. A conditioning component comprising (A) a foaming surfactant and (B) (i) a water soluble conditioning agent and (ii) an oil soluble conditioning agent is preferably sprayed, laser printed, splashed, immersed or Adding onto or incorporating onto the water-insoluble substrate separately or simultaneously by coating; A substantially dry, disposable, single-use personal use with a foaming surfactant to conditioning component of less than 40: 7 and the cleaning product attaching more than about 2.5 μg / cm ² of conditioning component to the surface of the skin or hair A method of making protective cleaning and conditioning products. The method of claim 10, A foaming surfactant and conditioning component are added together on a water insoluble substrate or mixed together before incorporation into the substrate. A method of attaching more than 2.5 μg / cm ² of conditioning component to the surface of skin or hair by contacting the product of claim ^{1 with} skin or hair. A foaming interface comprising (A) a water-insoluble substrate, (ii) a foaming surfactant, and (iii) a (a) water-soluble conditioning agent and (b) a water-soluble conditioning agent. A substantially dry disposable single-use personal cleansing product having a weight ratio of active agent to conditioning component less than 40: 7 and wherein the cleaning product adheres more than about 2.5 μg / cm ² of conditioning component to the surface of the skin or hair. Soaking with water; And (B) contacting the skin or hair with the wet product A method comprising washing and conditioning the skin or hair with a personal cleansing product comprising a.