KR20000030331A - Antibacterial & far-infrared-emission funtio manufacturing method of wallpaper - Google Patents

Antibacterial & far-infrared-emission funtio manufacturing method of wallpaper Download PDF

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KR20000030331A
KR20000030331A KR1020000008641A KR20000008641A KR20000030331A KR 20000030331 A KR20000030331 A KR 20000030331A KR 1020000008641 A KR1020000008641 A KR 1020000008641A KR 20000008641 A KR20000008641 A KR 20000008641A KR 20000030331 A KR20000030331 A KR 20000030331A
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sericite
weight
far
infrared
infrared ray
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KR1020000008641A
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Korean (ko)
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김현채
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김현채
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/20Flexible structures being applied by the user, e.g. wallpaper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00Special paper or cardboard not otherwise provided for
    • D21H5/0082Wall papers

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)

Abstract

PURPOSE: Provided is a process for preparing wall paper having antivirus activity and far infrared ray emitting functionality which has strong antivirus activities and antibacterial activities by using sericite, moscovite and other mineral as starting material. Thereby, it is possible to appear synergy effect useful for the sterilizing agent by using the wall paper having antivirus activity and far infrared ray emitting functionality. CONSTITUTION: The process contains the following the steps of: positioning a sericite in the furnace to solve the sericite at 1400°C for 24hour; depositing the sericite in the ball mill of water type to drive it for 24-48 hour; obtaining 7 micrometer of high powder; addition of 2-3% by weight of 0.2-0.3 micrometer of medium particle size of photo catalyst having excellent heat resistant and bacterial resistant to 3-5% by weight of far infrared ray emitting high powder in the stirrer to stir sufficiently; stirring the mixed material to 94-97% by weight of suspension of slurry to obtain paper matrix to desired size at 50-200°C of temperature.

Description

항균 및 원적외선 방사 기능성 벽지 제조방법{Antibacterial & far-infrared-emission funtio manufacturing method of wallpaper}Antibacterial & far-infrared-emission funtio manufacturing method of wallpaper

본 발명은 원적외선의 메카니즘(Mechanism)에 기인하는 원리를 응용하여 무기광물질인 세리사이트(sericite), 견운모(Mica), 백운모(Moscovite) 및 기타광물들을 출발물질로 이용하여 불순물들을 제거시킨 후 화인세라믹스(fine ceramics)로 전환시켜 준 후 입자크기(particle size) 5㎛ ∼ 10㎛이내로 박분화 상태로 잘게 쪼개어 원적외선 방사율을 높이어 주도록 하여 상온℃에서도 원적외선 방사량을 극대화를 시켜주어 원적외선 방사체 소재로 응용하고 광촉매(Photo catalyst)의 특성 및 성질을 건드리는 "즉" 트러블이 발생하지 않도록 조성물을 형성시켜 주어 광 촉매제가 갖고 있는(387nm 빛의 파장만 받아도 기능이 발휘됨)기능으로 실내 및 태양 빛(光)파장으로 인한 대기 속에 서식되는 각종의 먼지 세균류는 물론이거니와 우리 인체에서 떨어져 나오는 피부 조각을 먹고사는 각종 피부 알러지를 일으키는 진드기류의 세균들을 터치 사멸은 물론이거니와 근접된 세균류들을 차례 차례 끌어당겨 멸균을 시키고 지속적으로 산화·환원 반응을 일으키게 되는데 이때 자신은 산화되지 않고 제2차의 오염 및 감염 없이 처음과 같은 항균력이 지속적으로 나오도록 한 것이다.The present invention is applied to the principle due to the mechanism of far-infrared radiation (Sericite), mica, Mica, Moscovite and other minerals by using the inorganic minerals as starting materials to remove impurities and fine ceramics After conversion to (fine ceramics), the particle size is divided into finely divided within 5㎛ ~ 10㎛ in the state of thinning to increase the far-infrared emissivity to maximize the far-infrared radiation at room temperature and apply it as a far-infrared radiator material and photocatalyst The composition of the photocatalyst prevents "trouble" problems that affect the properties and properties of the photo catalyst, which is a function of the photocatalyst (function is achieved even with a wavelength of 387 nm light). In addition to the various types of dust bacteria living in the atmosphere caused by the wavelengths, Touch kills germs of various ticks causing skin allergies, as well as sterilizes them by turn to sterilize adjacent bacteria in turn and continuously causes oxidation and reduction reactions. The same antimicrobial activity as the first one is to continue to come out.

이로써 원적외선, 항균의 메카니즘(Mechanism)으로 상호 보안작용으로 시너지(Synergy) 효과를 주고 반영구적으로 반영토록 해주고 특히 강 알카리성 시멘트의 독성을 중성화시켜 주며 상온℃ 에서도 원적외선 방사율을 높이어줌으로써 원적외선 방사를 희망하는 자(者)에게 별도의 장치물을 설치하지 않고 원적외선 조사(照射)를 받을 수 있도록 할 것이다.By this, the mechanism of anti-infrared and antimicrobial (Mechanism) provides a synergy effect by mutual security action, semi-permanent reflection, neutralizing the toxicity of strong alkaline cements, and increasing far-infrared emissivity even at room temperature. He shall be able to receive far-infrared radiation without installing any additional equipment.

무기 광물질인 견운모(Mica), 백운모(Moscovite), 세리사이트(Sericite) 기타 무기광물 중 택일하여 광물 속에 녹아 있는 인체 유독 성분들인 불순물을 제거하여 화인세라믹스(fine ceramics) 로 전환 박분화(particle size 5㎛∼10㎛e)된 파우더로 전환시킨 후 무기 항균제인 광 촉매제와 충분하게 교반(compounding) 시킨 후 슬러리(Slurry) 상태의 종이 모재(母材,Matrix)에 분상 상태가 좋도록 충분하게 교반 후 제조공법에 맞는 열을 가해서 만들어진 각종 종이 및 벽지가 된다. 상기의 공정에서 만들어진 내 기능성 종이는 각종 세균의 멸균작용은 물론이거니와 원적외선 방사로 인한 우리 인체에는 매우 유익한 기능성 종이로 만들어지며 본 기능성 종이는 우리 삶에 활력은 물론 우리인체를 건강하게 만들어 주는 효과를 이끌어 주게 된다.Inorganic minerals such as Mica, Moscovite, Sericite, and other inorganic minerals can be used to remove impurities from human toxic components dissolved in minerals and convert them into fine ceramics. After converting to a powder having a thickness of 10 µm to 10 µm), the mixture was sufficiently stirred with a photocatalyst, an inorganic antimicrobial agent, and then sufficiently stirred so as to have a good powder phase in a slurry paper matrix. Various papers and wallpaper made by applying heat according to the manufacturing method are obtained. The functional paper made in the above process is not only sterilization of various bacteria but also made of functional paper which is very beneficial to our human body due to far-infrared radiation. This functional paper has the effect of vitalizing our lives and making our body healthy. Will lead.

도1은 본 발명을 실시하는데 따른 공정흐름 예시도.1 is an exemplary process flow diagram for practicing the present invention.

본 발명을 실시 예에 의거 더욱 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to Examples.

실시예1;Example 1;

세리사이트(Sericite)를 용해로에 넣은 후 1,400℃에서 24시간 동안 용해를 시킨 후 급랭 수식(水式)타입(Type)의 볼밀(Ball mill)에 투입시켜 얻고자 하는 타입의 사이즈(Size)를 24hr∼48hr 동안 운전을 한 후 평균 7㎛ 고분말 파우더(Powder)를 얻은 물질을 원적외선 방사체의 소재의 출발물질로 하고 반영구적으로 항균력이 소멸되지 않고 내한성, 고온 내열성, 내 약품성 내식성 등에 매우 안정적인 광 촉매(Photo catalyst)를 항균제로 사용 혼합출발물질 부재로 사용하여 광 촉매가 갖고 있는 다양한 기능성을 주고자 한다. 특히 공기 부유균들과 우리 생활 주거공간에서 서식되는 각종 박테리아 세균들로부터 우리인간들에게 치명성을 주게 하는데 우리 인체에 매우 해로운 각종 세균류들로 부터 보호를 받고 여러 가지 기능성들로 인한 인간에 유익성을 주는 광 촉매제는 공기중 수분을 함수하고 있는 곳에는 빛(光)을 받아서 여기 전자를 띄고 쌍 정공이 형성 수산기(OH)를 갖게 된다. 이때(H )양이온 수소기와 (O)산소가 분리되기도 하며 이산화탄소(CO2)등이 발생되면서 각종 세균류들을 사멸시키고 이어서 단백질 성분을 분해시켜 제2차의 오염원은 물론 세균들을 원천적으로 서식이 불가능케 하는 역할을 감당하는 광 촉매제(Photo Catalyst)이다.After sericite is put into the melting furnace, it is dissolved for 24 hours at 1,400 ℃, and then put into a ball mill of a quench type type to obtain a size of 24 hr. After operating for 48 hours, the average 7㎛ high powder powder is used as the starting material of the far-infrared emitter. Photo catalyst is used as an antimicrobial agent It is intended to give various functionalities of photo catalyst by using mixed starting materials. In particular, it gives fatality to humans from airborne bacteria and various bacteria bacteria living in our living spaces. It is protected from various germs that are very harmful to our body and beneficial to humans due to various functions. The main photocatalyst receives light where it is functioning moisture in the air, attracts excitation electrons, and has a hydroxyl group (OH) formed by the twin holes. At this time, the (H) cation hydrogen group and (O) oxygen are separated and carbon dioxide (CO 2 ) is generated to kill various bacteria and then to decompose protein components to make it impossible to inhabit bacteria as well as secondary sources of contamination. It is a photo catalyst that plays a role.

실시예2;Example 2;

상기의 공정에서 화인세라믹으로 전환시켜 원적외선이 방사될 수 있는 고분말 파우더 입자크기 7㎛(평균입도)를 3∼5 중량%에 내항균력을 갖고 있는 광 촉매제(Photo Catalyst) 평균입도 2㎛와 2∼3 중량%를 교반기에 넣은후 충분하게 교반시킨후 종이 제조공정시 슬러리(Slurry)상태의 현택액에 94∼97 중량%에 이를 다시 충분하게 섞이도록 교반시킨다.In the above process, the average particle size of the photocatalyst having the antimicrobial resistance at 3 to 5% by weight of the high powder powder particle size 7 μm (average particle size) capable of emitting far infrared rays by converting to fine ceramics is 2 μm and 2 After adding 3% by weight to the stirrer, the mixture is sufficiently stirred, and then stirred until 94-97% by weight of the suspension in the slurry state is sufficiently mixed in the paper manufacturing process.

상기의 교반 공정을 마친 슬러리(Slurry)상태의 종이 매트릭스(Matrix)는 생산하고자 하는 종이의 재질에 따라서 50℃∼200℃열을 가해 건조하여 완성되는 제조공정이며 상기의 공정도에서 완료된 종이는 항균용 벽지 항균용 각종 종이로서 널리 응용할 수 있으며 우리 인간에게 매우 유익한 내기능성 종이로 만들어진다.Slurry paper matrix (Slurry) is a manufacturing process is completed by applying 50 ℃ ~ 200 ℃ heat to dry according to the material of the paper to be produced and the paper completed in the above process chart is antibacterial It is widely used as a paper for antibacterial wallpaper and is made of a functional paper which is very beneficial to us.

상기한 방법으로 얻어진 항균 및 원적외선 방사체용 종이는 벽지 장기보존용 책, 노트 ,포장지, 초벌용 벽지등 우리 일상생활에 매우 밀접한 곳에 사용되는 범위가 매우 폭 넓게 자리를 차지할 수 있으며 특히 주거 생활공간인 주택내부의 벽지등에 이용할시 원적외선으로 기인되는 메카니즘(Mechanism)으로 인해 강 알카리성(PH 13∼14) 콘크리트 독성을 중성으로 중화시켜 우리 인체의유해성을 차단시켜 주는 역할을 시너지(Synergy)적 역할까지 해준다. 더욱이 인체 무해성 항균제는 반영구적으로 내기능성은 소멸되지 않아 인체의 유해한 세균들로부터 광촉매로 인체를 보호하도록 하여 건강한 삶을 유지하며 살도록 한 매우 유익한 발명이다.The antimicrobial and far-infrared radiator paper obtained by the above-mentioned method can occupy a very wide range of places that are used very close to our daily life such as wallpaper, books for long-term preservation, notes, wrapping papers, and wallpaper for the first time. When used for wallpaper inside a house, the mechanism that is caused by far-infrared rays neutralizes the strong alkaline concrete toxicity to neutral to neutralize the harmfulness of our human body. It also plays a role of synergy. . Furthermore, the harmless antimicrobial agent is a semi-permanent invention that is not semi-permanently extinguished in functionality, so as to protect the human body with photocatalysts from harmful germs of the human body to maintain a healthy life.

Claims (2)

원적외선 방사체 세리사이트(Sericite), 견운모(Mica), 백운모(Moscovite)중 택일하여 1,400℃의 고온 용해로에 24시간동안 용해시킨후 수식(水式)타입의 볼밀에 투입 24hr∼48hr 동안 운전시킨후 평균7㎛ 고분말 파우더를 얻는다.Far-infrared radiator Sericite, Mica, Moscovite are alternatively dissolved in a high temperature furnace at 1,400 ℃ for 24 hours, and then put into a ball mill of a water-type type and operated for 24hr ~ 48hr. Obtain 7 μm high powder powder. 상기 공정에서 얻어진 원적외선 방사체 고분말 파우더 3∼5 중량7%에 내열성 및 내항균력이 우수한 광 촉매제 평균입자크기 0.2㎛∼0.3㎛ 2∼3 중량%를 교반기에 넣은후 충분하게 교반 시키는 공정이다.3 to 5% by weight of the far-infrared radiant high powder powder obtained in the above process is added to the stirrer with an average particle size of 0.2 µm to 0.3 µm to 2 to 3% by weight, which is excellent in heat resistance and antibacterial resistance, and then sufficiently stirred. 상기 공정에서 얻어진 혼합된 소재를 종이 모재인 슬러리(Slurry)상태의 현탁액에 94∼97 중량%에 이를 다시 충분하게 섞이도록 교반 시킨 후 생산하고자 하는 두께에 따라 종이 매트릭스(Matrix)는 생산공정 및 두께에 따라The mixed material obtained in the above process was stirred to sufficiently mix it in 94 to 97% by weight in a slurry of a paper base material, and then the paper matrix was produced according to the thickness to be produced. Depending on the 50℃∼200℃의 열을 가해 생산시켜 완성되는 제조 공법이다.It is a manufacturing method that is completed by applying 50 ° C to 200 ° C heat.
KR1020000008641A 2000-02-22 2000-02-22 Antibacterial & far-infrared-emission funtio manufacturing method of wallpaper KR20000030331A (en)

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KR100501058B1 (en) * 2002-02-25 2005-07-18 윤장호 wall paper
KR20210006126A (en) * 2019-07-08 2021-01-18 김종환 manufacturing methods for functional board using application of a waste paper

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