KR19990073604A - Glass discoloration device using polyacetylene - Google Patents

Glass discoloration device using polyacetylene Download PDF

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Publication number
KR19990073604A
KR19990073604A KR1019990030959A KR19990030959A KR19990073604A KR 19990073604 A KR19990073604 A KR 19990073604A KR 1019990030959 A KR1019990030959 A KR 1019990030959A KR 19990030959 A KR19990030959 A KR 19990030959A KR 19990073604 A KR19990073604 A KR 19990073604A
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South Korea
Prior art keywords
polyacetylene
glass
iodine
thin film
fluoride
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KR1019990030959A
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Korean (ko)
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강보선
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강보선
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Priority to KR1019990030959A priority Critical patent/KR19990073604A/en
Publication of KR19990073604A publication Critical patent/KR19990073604A/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
    • B32B17/10201—Dielectric coatings
    • B32B17/10211—Doped dielectric layer, electrically conductive, e.g. SnO2:F
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10293—Edge features, e.g. inserts or holes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10431—Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
    • B32B17/10467—Variable transmission
    • B32B17/10495—Variable transmission optoelectronic, i.e. optical valve
    • B32B17/10513—Electrochromic layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10715—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyether

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  • Laminated Bodies (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

본 발명은 폴리아세틸렌을 이용하여 전기 에너지에 의한 유리의 색을 조절할 수 있는 장치를 제공하는 것을 목적으로 한다.An object of the present invention is to provide a device that can control the color of the glass by the electrical energy using polyacetylene.

본 발명에 구성되는 프라스틱의 일종인 폴리아세틸렌(2)은 원래 절연체이지만 불화비소(ASF3)와 요오드(I2)의 증기속에 지글러 방식의 촉매에 의해서 중합하여 얻은 폴리 아세틸렌 분말을 8시간 정도 방치하여 두면 절연체의 폴리 아세틸렌 분말은 불화비소(ASF3)와 요오드(I2)와 도핑하여 전도체의 폴리아세틸렌으로 변하게 된다.Polyacetylene (2), which is a kind of plastic of the present invention, is originally an insulator, but the polyacetylene powder obtained by polymerizing a acetylene powder obtained by a Ziegler-type catalyst in a vapor of arsenic fluoride (A S F 3 ) and iodine (I 2 ) for 8 hours. If left to the extent, the polyacetylene powder of the insulator is doped with arsenic fluoride (A S F3) and iodine (I 2 ) to change into polyacetylene of the conductor.

상기한 방식에 의해서 얻은 폴리아세틸렌 분말을 유리판(1A)에 진공 증착시켜 2∼3 미크론의 폴리 아세틸렌 박막(2)을 형성시킨 후 다시 그위에 유리판(1B)을 결합시킨 후 폴리아세틸렌박막(2)의 양쪽 측면은 동박막판(3A,3B)과 접하게 하여 각각 +. - 전극단자 역활을 하여 전압을 가했을시 불화비소(ASF3)와 요오드(I2)와 도핑된 폴리아세틸렌(2)에 전하의 이동에 의해서 색깔이 변하게 되어 자동차나 집에 장착된 유리를 통한 빛에 의한 열의 양을 조절할 수 있으므로 에너지 절감 및 자동차 운전시 빛에 의한 운전자의 시야를 방해하지 않도록 할수 있으므로 사고예방에도 도움이 되는 전기 에너지에 의한 폴리 아세틸렌을 이용한 유리 변색장치이다.The polyacetylene powder obtained by the above method was vacuum deposited on the glass plate 1A to form a polyacetylene thin film 2 of 2 to 3 microns, and then the glass plate 1B was bonded thereon, and then the polyacetylene thin film 2 Both sides of the copper foil plate (3A, 3B) in contact with each other. -When a voltage is applied by acting as an electrode terminal, the color of fluoride (A S F 3 ), iodine (I 2 ) and doped polyacetylene (2) is changed due to the transfer of electric charge. It is a glass discoloration device using polyacetylene by electric energy that can help to prevent accidents because it can control the amount of heat by light through, so that it can prevent energy saving and obstruct the driver's view by light when driving a car.

Description

폴리 아세틸렌을 이용한 유리변색 장치{.}Glass discoloration apparatus using polyacetylene {.}

본 발명은 불화비소(ASF3)와 요오드(I2)와 도핑되어 전도체가 된 폴리아세틸렌 박막(2)을 두장의 유리 (1A. 1B)사이에 결합시킨 후 폴리아세틸렌 박막(2)에 전압을 가했을시 전압의 정도에 따라 폴리 아세틸렌 박막(2)의 색이 변하게 하여 유리(1A.1B)를 통해 들어오는 빛의 양을 조절할 수 있는 것을 목적으로 하는 불화비소(ASF3)와 요오드(I2)와 도핑된 투명 폴리아세틸렌 박막에 의한 유리 변색장치의 제공을 목적으로 한다.According to the present invention, a polyacetylene thin film (2) doped with arsenic fluoride (A S F 3 ) and iodine (I 2 ) becomes a conductor between two sheets of glass (1A. 1B), and then is attached to the polyacetylene thin film (2). Arsenic fluoride (A S F 3 ) and iodine for the purpose of controlling the amount of light entering through the glass (1A.1B) by changing the color of the polyacetylene thin film (2) according to the degree of voltage when a voltage is applied. An object of the present invention is to provide a glass discoloration apparatus using a transparent polyacetylene thin film doped with (I 2 ).

본 발명은 유리의 색을 변하게 하는 장치에 관한 것으로서, 기존에는 열이나 빛에 의해서 감광성 원료와 화합된 유리의 화학적인 현상에 의해 변색 하였으므로 사용자의 의도와는 상관없이 변하므로 사용자가 원하는데로 유리의 색을 변화 시킬수는 없었다.The present invention relates to a device for changing the color of the glass, conventionally changed color irrespective of the user's intention because the color change due to the chemical phenomenon of the glass combined with the photosensitive raw material by heat or light, so that the user of the glass I could not change the color.

본 발명은 상기한바와 같은 불편한 점을 해고하고자. 투명한 유리(1A.1B)사이에 불화비소(ASF3)와 요오드(I2)의 성분과 도핑된 폴리 아세틸렌 박막(2)을 증착시켜 폴리아세틸렌 박막(2)의 양쪽 측면에 접한 동박막판(3A.3B)에 각각 플러스, 마이너스극을 연결시켜 전압을 가했을시 전압의 정도에 따라 폴리 아세틸렌 박막(2)의 색이 변하게하여 유리 (1A.1B)를 통하여 들어오는 빛의 양을 조절함으로서 열의 양 또한 조절이 가능함으로서 자동차 내부와 집안의 온도를 조절할 수 있는 불화비소(ASF3)와 요오드(I2)와 도핑된 투명 폴리아세틸렌 박막(2)에 의한 유리변색장치를 개발하게 되었다.The present invention seeks to dismiss such inconvenience as described above. Copper thin film sheet contacting both sides of the polyacetylene thin film 2 by depositing a polyacetylene thin film 2 doped with arsenic fluoride (A S F 3 ) and iodine (I 2 ) between the transparent glass (1A.1B) When the positive and negative poles are connected to (3A.3B) and the voltage is applied, the color of the polyacetylene thin film 2 changes according to the degree of voltage, thereby controlling the amount of light entering through the glass 1A.1B. The amount can also be adjusted to develop a glass discoloration device using arsenic fluoride (A S F 3 ), iodine (I 2 ), and a doped transparent polyacetylene thin film (2) that can control the temperature inside and inside the car.

본 발명은 프라스틱의 일종으로서 절연체인 폴리 아세틸렌을 전도체로 만들기 위해서 불화비소(ASF3)와 요오드(I2)의 증기에 의해 불화비소(ASF3)와 요오드(I2)의 성분이 폴리아세틸렌 분말과 도핑되도록 불화비소(ASF3)와 요오드(I2)의 증기속에서 8시간 이상 방치하여 폴리 아세틸렌 분말을 전도체가 되도록 하여, 두장의 유리 사이에 2∼3 미크론 정도의 두께로 증착시킨 후 양쪽 측면에는 동박막판(3A.3B)과 접하게 하여 각각에 플러스극과 마이너스극을 연결시켜 폴리 아세틸렌 박막(2)에 전하의 이동이 가능하게 하여 전압에 강도에 따라 폴리아세틸렌 박막(2)의 색을 변화하도록 유리(1A.1B)를 통한 빛의 강도를 조절할 수 있는 불화비소(ASF3)와 요오드(I2)와 도핑된 폴리아세틸렌(2)박막에 의한 유리 변색장치의 제공을 목적으로 한다.The present invention is a kind of plastic component of arsenic fluoride (A S F 3 ) and iodine (I 2 ) by the vapor of arsenic fluoride (A S F 3 ) and iodine (I 2 ) to make polyacetylene as an insulator as a conductor. In order to be doped with the polyacetylene powder, it is left in the vapor of arsenic fluoride (A S F 3 ) and iodine (I 2 ) for 8 hours or more to form a polyacetylene powder as a conductor, which is about 2 to 3 microns between two glasses. After deposition in thickness, both sides are in contact with the copper thin film plate (3A.3B), and the positive and negative electrodes are connected to each side to enable the transfer of charge to the polyacetylene thin film (2). Glass discoloration due to arsenic fluoride (A S F 3 ) and iodine (I 2 ) and doped polyacetylene (2) thin films to control the intensity of light through the glass (1A.1B) to change the color of (2) It is for the purpose of providing a device.

도1은 본 발명에 따른 유리 변색장치를 나타내는 결합사시도이다1 is a perspective view showing a glass discoloration apparatus according to the present invention.

도2는 본 발명에 따른 유리 변색장치를 나타내는 단면도이다.2 is a cross-sectional view showing a glass discoloration apparatus according to the present invention.

- 도면의 주요부분에 대한 부호설명--Code description for main parts of drawing-

1A. 1B : 유리1A. 1B: glass

2. ASF3및 I2와 도핑된 폴리아세틸렌 박막2. A S F I 3 and the polyacetylene films doped with 2

3A. 3B : 동판3A. 3B: Copper Plate

본 발명에 따른 전도체가 된 폴리아세틸렌에 의한 유리변색 장치의 구성 및 작용을 첨부된 도면 제1도 내지 제2도를 참고로 하여 설명하면 다음과 같다.The structure and function of the glass discoloration apparatus by the polyacetylene which became a conductor according to the present invention will be described with reference to FIGS. 1 to 2 as follows.

먼저, 본 발명에 구성되는 절연체인 프라스틱의 일종인 폴리아세틸렌을 전도체로 만들기 위해 불화비소(ASF3)와 요오드(I2)를 각각의 용기에 담아 전기로속에 넣어 가열시켜 증기가 발생 되도록 하여 증기속에서 지글러 방식의 촉매에 의해서 중합하여 얻은 폴리 아세틸렌 분말을 8시간 정도 방치하여 두면 불화비소(ASF3)와 요오드(I2)의 성분은 폴리아세틸렌 분말과 도핑하여 폴리아세틸렌 분말은 전도성을 지니게 된다.First, arsenic fluoride (A S F 3 ) and iodine (I 2 ) are put in each container and heated in an electric furnace to generate polyacetylene, which is a kind of plastic, which is an insulator of the present invention, so that steam is generated. If the polyacetylene powder obtained by polymerization with a Ziegler-type catalyst in steam is left to stand for about 8 hours, the components of arsenic fluoride (A S F 3 ) and iodine (I 2 ) are doped with the polyacetylene powder to make the polyacetylene powder conductive. Will have.

상기한 방식에 의해 전도체가 된 폴리아세틸렌 분말을 유리판(1A)에 진공증착 시킨 후 그위에 다른 유리판(1B)를 덮어 두장의 유리판(1A.1B)사이에 전도체가 된 투명 폴리 아세틸렌 박막(2)을 형성시킨 후 폴리 아세틸렌 양쪽측면은 동박막판(3A.3B)와 접하게 하여 전압을 가했을시 두장의 유지(1A.1B)사이의 투명 폴리 아세틸렌 박막(2)에 전하에 이동에 의해 변색작용 하여 사용자의 의도에 따라 전압의 강약을 조절함으로서 유리의 색이 변화하는 것과 같은 효과를 낼수 있으므로서 빛의 강도를 조절할 수 있는 불화비소(ASF3)와 요오드(I2)와 도핑된 폴리 아세틸렌에 의한 유리 변색장치이다.The polyacetylene powder which became a conductor by the above-mentioned method was vacuum-deposited on the glass plate 1A, and the transparent polyacetylene thin film 2 which became a conductor between two glass plates 1A.1B by covering the other glass plate 1B thereon. Both sides of the polyacetylene are in contact with the copper thin film plate (3A.3B) after the formation, and the user discolors by transfer of charge to the transparent polyacetylene thin film (2) between two holdings (1A.1B) when a voltage is applied. By adjusting the strength of the voltage according to the intention of the effect of changing the color of the glass can be adjusted to the arsenic fluoride (A S F 3 ) and iodine (I 2 ) and doped polyacetylene to control the light intensity Glass discoloration device.

상기한바와 같이 불화비소(ASF3)와 요오드(I2)와 도핑되어 전도체가 된 폴리아세틸렌에 의한 유리변색장치는 자동차의 유리나 집의 유리 또는 안정유리에 장착하였을시 사용자의 의도에 따라 전압을 조절하여 유리의 색을 변색시킬수 있으므로 유리를 투과하는 빛의 양을 조절함으로 빛에 의한 열량의 조절또한 가능함으로서 에너지 절감효과 및 쾌적한 생활을 영위하는데 편리함을 도모할 수 있는 불화비소(ASF3)와 요오드(I2)와 도핑된 폴리아세틸렌에 의한 유리변색장치이다.As described above, the glass discoloration apparatus made of polyacetylene doped with arsenic fluoride (A S F 3 ) and iodine (I 2 ) as a conductor according to the intention of the user when mounted on the glass of a car, the glass of a house, or the stable glass since by adjusting the voltage sikilsu fade the color of the glass fluoride to promote the convenience for by adjusting the amount of heat caused by light is also possible by adjusting the amount of light transmitted through the glass lead to energy saving and comfortable life arsenic (a S F 3 ) and iodine (I 2 ) and glass discoloration apparatus by doping polyacetylene.

Claims (3)

각각의 용기에 담긴 불화비소(AsF3)와 요오드(I2)를 전기로속에 넣은후 증기를 분출하는 온도에 맞추어 놓고 지글러 방식에 촉매에 의해서 중합하여 얻은 폴리아세틸렌 분말을 약8시간동안 불화비소(AsF3)와 요오드(I2)의 증기와 접하게 하여 폴리아세틸렌 분말이 불화비소(AsF3)와 요오드(I2)의 성분과 도핑하도록 하여 폴리아세틸렌 분말은 전도체의 폴리아세틸렌(2)이 되도록 한 것을 특징으로 하는 폴리아세틸렌에 의한 유리변색장치.Arsenic fluoride (AsF 3 ) and iodine (I 2 ) contained in each vessel were put in an electric furnace, and the polyacetylene powder obtained by polymerization by a catalyst in a Ziegler method for about 8 hours was introduced into an electric furnace. AsF 3) and one such that the vapor and exposed to polyacetylene powder is polyacetylene (2) to be doped with the components of the fluoride arsenic (AsF 3) and iodine (I 2) polyacetylene powder is the conductor of the iodine (I 2) Glass discoloration apparatus by polyacetylene, characterized in that. 전도체가 된 폴리아세틸렌 분말(2)을 유리판(1A)위에 진공증착시켜 2∼3 미크론 두께로 도포한 후 다시 유리판(1B)을 덮어 결합체를 이루게 한 것을 특징으로 하는 폴리아세틸렌에 의한 유리변색장치.A polyacetylene glass discoloration apparatus, characterized in that the polyacetylene powder (2), which becomes a conductor, is vacuum-deposited on a glass plate (1A), applied to a thickness of 2 to 3 microns, and then covered with a glass plate (1B) to form a binder. 두장의 유리판(1A.1B)사이에 낀 폴리아세틸렌 박막(2)의 양쪽 측면에 동박막판(3A.3B)을 접하게 하여 플러스. 마이너스의 전극판 역할을 하게한 것을 특징으로 하는 폴리아세틸렌에 의한 유리변색 장치.The copper thin film plate 3A.3B is brought into contact with both sides of the polyacetylene thin film 2 sandwiched between two glass plates 1A.1B. A glass discoloration device using polyacetylene, characterized in that it serves as a negative electrode plate.
KR1019990030959A 1999-07-28 1999-07-28 Glass discoloration device using polyacetylene KR19990073604A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010000447A (en) * 2000-09-27 2001-01-05 홍순삼 Process for controlling amount of sunlight by glass coating using deposition method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20010000447A (en) * 2000-09-27 2001-01-05 홍순삼 Process for controlling amount of sunlight by glass coating using deposition method

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