KR19990064591A - The Making Method of Sewi-petwaueut Antibiotic Synthetic Leather - Google Patents
The Making Method of Sewi-petwaueut Antibiotic Synthetic Leather Download PDFInfo
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- KR19990064591A KR19990064591A KR1019990013409A KR19990013409A KR19990064591A KR 19990064591 A KR19990064591 A KR 19990064591A KR 1019990013409 A KR1019990013409 A KR 1019990013409A KR 19990013409 A KR19990013409 A KR 19990013409A KR 19990064591 A KR19990064591 A KR 19990064591A
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- resin
- weight
- synthetic leather
- zeolite
- slurry state
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- 239000002649 leather substitute Substances 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims description 20
- 230000003115 biocidal effect Effects 0.000 title 1
- 239000011347 resin Substances 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 36
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000010457 zeolite Substances 0.000 claims abstract description 14
- 229920002635 polyurethane Polymers 0.000 claims abstract description 9
- 239000004814 polyurethane Substances 0.000 claims abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims abstract description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 12
- 230000000845 anti-microbial effect Effects 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000004599 antimicrobial Substances 0.000 claims description 8
- 239000000725 suspension Substances 0.000 claims description 8
- 229920002994 synthetic fiber Polymers 0.000 claims description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 4
- 238000007865 diluting Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 238000005245 sintering Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 8
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 238000005054 agglomeration Methods 0.000 abstract description 3
- 230000002776 aggregation Effects 0.000 abstract description 3
- 201000010099 disease Diseases 0.000 abstract description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 3
- 230000002538 fungal effect Effects 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 3
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 3
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 3
- 206010012438 Dermatitis atopic Diseases 0.000 abstract description 2
- 201000009961 allergic asthma Diseases 0.000 abstract description 2
- 208000006673 asthma Diseases 0.000 abstract description 2
- 201000008937 atopic dermatitis Diseases 0.000 abstract description 2
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 3
- 241000233866 Fungi Species 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41F—GARMENT FASTENINGS; SUSPENDERS
- A41F15/00—Shoulder or like straps
- A41F15/002—Shoulder or like straps separable or adjustable
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41F—GARMENT FASTENINGS; SUSPENDERS
- A41F15/00—Shoulder or like straps
- A41F15/02—Means for retaining the straps in position
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
본 발명은 항균력은 유지되면서 입자크기 2㎛∼5㎛의 고분자 파우더로 된 제올라이트(Zeolite)를 가지고 열경화성 폴리우레탄(Polyurethane) 혹은 피브시(Polyvinyl Chloride)의 레진(Resin)에 고르게 분산시켜 합첨한 후 본 주제의 액상이 트러블 또는 뭉쳐지는 현상이 생기지 않도록 한 후 코튼(Cotton), 합성섬유 등 면상 위에 0.1mm ∼ 2mm단위까지 얇게 코팅(Coating)하여 제조하는 과정을 거쳐 기능성 합성피혁을 만든 후 우리 생활에 필요로 하는 각종 생필품 등에 접목시키어서 우리의 생활 주변에 인체 유해성 세균은 물론 곰팡이 균주까지 포함되는 균주들은 각종의 질병들을 일으키는 주범으로서 알레르기 천식과 아토피성 피부염 등을 동반하는 세균들로부터 보호하도록 하므로서 우리의 삶에 건강을 유지하도록 한 것이다.The present invention has a zeolite made of a polymer powder having a particle size of 2 μm to 5 μm while maintaining antibacterial activity, and then uniformly dispersing it in a resin of a thermosetting polyurethane or polyvinyl chloride, and then bonding it. After the liquid phase of the subject prevents trouble or agglomeration, it is coated with 0.1mm to 2mm units on cotton and cotton to make functional synthetic leather. By incorporating various necessities needed in the life cycle, the strains including human harmful bacteria as well as fungal strains around our lives are the main culprit causing various diseases, so that they are protected from allergic asthma and atopic dermatitis. It is to keep our lives healthy.
Description
본 발명은 향균력은 유지되면서 입자크기 2㎛∼5㎛의 고분자 파우더로 된 제올라이트(Zeolite)를 가지고 열경화성 폴리우레탄(Polyurethane)혹은 피브시(Polyvinyl Chloride)의 레진(Resin)에 고르게 분산시켜 합첨한 후 본 주제의 액상이 트러블 또는 뭉쳐지는 현상이 생기지 않도록 한 후 코튼(Cotton), 합성섬유 등 면상 위에 0.1mm ∼ 2mm단위까지 얇게 코팅(Coating)하여 제조하는 과정 후 기능성 합성피혁을 만든 후 우리 생활에 필요로 하는 각종 생필품 등에 접목시키어서 우리의 생활 주변에 인체 유해성 세균은 물론 곰팡이 균주까지 포함되는 균주들은 각종의 질병들을 일으키는 주범으로서 알레르기 천식과 아토피성 피부염 등을 동반하는 세균들로부터 보호하도록 하므로서 우리의 삶에 건강을 유지하도록 한 것이다.The present invention has a zeolite made of a polymer powder having a particle size of 2㎛ to 5㎛ while maintaining the antibacterial force and evenly dispersed in a resin of thermosetting polyurethane or Polyvinyl Chloride and then bonded together. After preventing the liquid from trouble or agglomeration of the subject matter, we make a thin coating from 0.1mm to 2mm unit on cotton, cotton, synthetic fiber, etc. and make functional synthetic leather. By integrating various necessities, such as human harmful bacteria as well as fungal strains around our lives, the main culprit of various diseases is to protect them from allergic asthma and atopic dermatitis. To stay healthy in your life.
따라서 유리의 삶에 편리함과 편안함을 주기 위한 가구류에 소파 및 의자에 화학 성분에서 빼낸 각종의 실(Yarn)을 이용하여 만들어진 각종 직물류와 레진(Resin)을 이용하여 만들어진 합성 피혁류 들은 우리의 생활을 편리함과 편안함을 가져와 주었던 현대의 문명이었다.Therefore, various kinds of fabrics made of various yarns extracted from chemicals on sofas and chairs and synthetic leathers made of resin are used to provide convenience and comfort to glass life. It was a modern civilization that brought convenience and comfort.
그러나 이에 따르는 부작용도 적지 않았다. 즉 화학 소재로 만들어진 섬유 합성 피혁에서는 인체의 유해성 세균들로부터 무방비 상태로 노출되어 있으나 이에 대한 대응 방안은 갖출 수 있는 조건이 없었으며 그러므로 우리의 일상생활의 생필품류들을 오염이나 세균의 감염이 되었을 때 물 또는 합성 세제류, 유기성 약품 등으로 씻거나 살포하는 등의 방법으로 사용하여 왔다.However, the side effects were not small. In other words, in synthetic fiber made of chemical material, it is exposed to human body's harmful bacteria, but there is no condition to deal with it. Therefore, when daily necessities of our daily life are contaminated or infected by bacteria It has been used by washing or spraying with water or synthetic detergents, organic chemicals and the like.
따라서 이 또한 화공약품 또는 유해 성질을 가진 수세물이 하수로 배출되어 최종적으로 우리의 삶의 터전을 위협하는 물질로 다시 생성, 매우 다양한 화합물과 오염원이 되는 형태가 진행되고 있는 실정이다.Therefore, this is also a situation in which chemicals or harmful water washes are discharged to sewage and finally regenerated into a material that threatens the place of our lives, forming a variety of compounds and pollutants.
그러므로서 위와 같이 복잡하고 다양한 문제점들을 해결하기 위해서 버려진 퇴출수에서 제2차의 화합물이 생성이 되지 않는 무기소재로 개발하고 응용하여 일상생활에 접목 사용하고저 하는 열망이 선진국에서는 매우 활발하게 진행중에 있으나 이에 대한 한계선에서 문제점들이 도출되고 있다.Therefore, in order to solve such complex and diverse problems, the desire to develop and apply inorganic materials that do not form secondary compounds in abandoned leachate is applied and used in daily life is very active in developed countries. However, problems are being derived from the limit line.
무기소재를 이용하여 합첨시 열에 의하여 고유의 성분이 파괴되거나 트러블이 발생하여 기능을 상실시켜 실패를 할 수밖에 없었다.When using inorganic materials, inherent components are destroyed or troubles occur due to heat when they are bonded.
본 발명은 상기한 지금까지 문제점을 감안하여 항균력은 그대로 유지되면서 무기항균제인 제올라이트(Zeolite)소재의 입자크기가 2㎛-5㎛인 고분자 파우더를 엄선하여 화학성분의 폴리우레탄(Polyurethane), 피브이시(Polyvinyl Chloride)등의 레진(Resin) 합첨 시킨 후 컴파운딩(Compounding)시 분산 상태가 좋게 함으로 뭉쳐지는 현상, 불균형적인 엠보싱(Embossing)형태를 방지하면서 즉 트러블이 발생하지 않도록 하여 기능성이 소멸되지 않는 항균용 합성피혁으로 제품화하는데 문제점이 없도록 한 것이다.The present invention in view of the above problems up to now, while maintaining the antimicrobial activity, the particle size of the inorganic antimicrobial zeolite (Zeolite) material is carefully selected by selecting a polymer powder of 2㎛-5㎛ chemical composition of polyurethane, Antimicrobial that prevents the occurrence of trouble by preventing the formation of agglomeration, imbalanced embossing form by compounding a good dispersion state when compounding after adding resin such as Polyvinyl Chloride There is no problem in commercializing synthetic leather.
그러므로 합성피혁은 화학섬유류 혹은 자연섬유 등 면상 위에 무기항균제가 골고루 잘 분산시킨 레진(Resin)을 나이프(Knife)코팅 후 적당한 열을 가하여 면상에 고착시켜 완성시켜 주는 과정을 거치게 된다.Therefore, synthetic leather undergoes a process of fixing resin on the surface of chemical fiber or natural fiber evenly and evenly dispersing the resin (Knife) to fix it on the surface by applying appropriate heat.
위와 같은 과정을 걸쳐 완성된 합성피혁은 각종의 생활용품등에 응용하여 사용하게 되는데 우리의 생활 주변에 서식하고 있는 즉 질병을 유발시키는 공기 중의 부유균, 몸에서 떨어져 나오는 피부 조각을 먹고사는 먼지세균, 곰팡이 포자 균까지 광범위하게 사멸력을 갖고있으며 퇴치해 줌으로서 우리 인체의 유해한 세균들로부터 안전하게 보호해 주면 건강한 삶을 유지 할 수 있도록 한 것이다.Synthetic leather completed through the above process is applied to a variety of daily necessities, such as living in the surroundings of our lives, causing airborne bacteria that cause disease, dust bacteria living on a piece of skin that falls off the body, Fungal spores have a wide range of killing powers and help to keep healthy lives by protecting them from harmful bacteria.
도1은 본 발명을 실시하는데 따른 공정흐름 예시도.1 is an exemplary process flow diagram for practicing the present invention.
상기한 목적을 달성하기 위한 본 발명을 실시 예에 따라 상세히 설명하면 다음과 같다.When explaining the present invention in detail according to the embodiment for achieving the above object is as follows.
실시예1;Example 1;
폴리우레탄(Polyurethane), 고형분(NOV)50∼60% 40∼50중량%에 MEK, 아세톤, 톨루엔 중 택일하여 10∼20중량%를 교반기에 넣은 후 수지를 묽게 풀어 주는 공정과,Polyurethane, solid content (NOV) 50 to 60% 40-50% by weight of MEK, acetone, toluene alternatively put 10 to 20% by weight in a stirrer, and then loosen the resin,
향균제인 제올라이트(Zeolite)를 MEK를 제올라이트의 중량 100%중 1:2의 비율로 희석하여 항균제 현탁액을 만드는 공정과,Diluting the zeolite, an antimicrobial agent, in a ratio of 1: 2 of MEK in 100% by weight of the zeolite to form an antimicrobial suspension,
이를 다시 상기 묽게 만든 수지에 다시 넣어 서서히 교반시켜 입자가 골고루 분산되어지는 과정을 관찰하는 공정과,Putting it back into the diluted resin and slowly stirring to observe the process of evenly dispersing the particles;
상기한 현탁액이 슬러리(Slurry) 상태로 된 것을 확인 후 합성직물 (폴리99.9%) 면상에 슬러리 상태의 수지를 붓는 공정과,After checking that the suspension is in a slurry state, pouring a slurry resin on the surface of the synthetic fabric (poly 99.9%),
상기 공정에서 쏟아놓은 슬러리 상태의 수지를 나이프(Knife)형태의 쇠막대는 수지를 이송해주는 파이프관을 통하여 부어진 수지를 0.1mm∼2mm의 두께를 얇게 하는 공정과,The iron rod in the form of a knife (Knife) of the resin in the slurry state poured in the process is a process of thinning the thickness of the resin poured through the pipe pipe to transfer the resin 0.1mm ~ 2mm,
상기의 중합공정에서 얻어진 이를 다시 수지소결로에 넣어 간접상태의 열 120℃∼130℃의 온도에서 3분 동안 가열 후 꺼내는 제조 공정으로하여 항균기능성을 가진 합성피혁 제품을 얻을 수 있는 제조공정이다.It is a manufacturing process to obtain a synthetic leather product having antibacterial function as a manufacturing process that is obtained by the polymerization process again put into a resin sintering furnace and heated and taken out at a temperature of 120 ℃ to 130 ℃ indirect state for 3 minutes.
실시예2;Example 2;
폴리우레탄(Polyurethane), 고형분(NOV)50∼60% 40∼45중량%에 MEK, 아세톤, 톨루엔 중 택일하여 10∼20중량%를 교반기에 넣은 후 수지를 묽게 풀어 주는 공정과,Polyurethane, solid content (NOV) 50 to 60% 40 to 45% by weight of MEK, acetone, toluene alternatively 10 to 20% by weight in a stirrer, and then the resin is diluted to loosen,
향균제인 제올라이트(Zeolite)를 MEK를 제올라이트의 중량 100%중 1:2의 비율로 희석하여 항균제 현탁액을 만드는 공정과,Diluting the zeolite, an antimicrobial agent, in a ratio of 1: 2 of MEK in 100% by weight of the zeolite to form an antimicrobial suspension,
이를 다시 상기 묽게 만든 수지에 다시 넣어 서서히 교반시켜 입자가 골고루 분산되어지는 과정을 관찰하는 공정과,Putting it back into the diluted resin and slowly stirring to observe the process of evenly dispersing the particles;
상기한 현탁액이 슬러리(Slurry) 상태로 된 것을 확인 후 합성직물(폴리99.9%) 면상에 슬러리 상태의 수지를 붓는 공정과,Pouring the resin in the slurry state onto the surface of the synthetic fabric (99.9% of poly) after confirming that the suspension is in a slurry state;
상기 공정에서 쏟아놓은 슬러리 상태의 수지를 나이프(Knife)형태의 쇠막대는 수지를 이송해주는 파이프 관을 통하여 부어진 수지를 0.1mm∼2mm의 두께를 얇게 하는 공정과,The iron rod in the form of a knife (Knife) of the resin in the slurry state poured in the process is a process of thinning the thickness of the resin poured through the pipe pipe to transfer the resin 0.1mm ~ 2mm,
상기의 중합공정에서 얻어진 이를 다시 수지소결로에 넣어 간접상태의 열 120℃∼130℃의 온도에서 3분 동안 가열 후 꺼내는 제조 공정으로 하여 항균기능성을 가진 합성피혁 제품을 얻을 수 있는 제조공정이다.It is a manufacturing process that can obtain a synthetic leather product having antibacterial function by putting the obtained in the polymerization process again into a resin sintering furnace to take out after heating for 3 minutes at a temperature of 120 ℃ to 130 ℃ indirect state.
상기 공정 속에서 얻어진 항균성 합성피혁은 놀링을 하여 포장하는 단계로 모든 제조 공정을 끝마치며 주문자의 요구에 따라 미터(m)량을 50m∼100m까지 감아주는 제조공정이다.The antimicrobial synthetic leather obtained in the process is a manufacturing process to wrap the meter (m) up to 50m ~ 100m according to the request of the orderer to finish all the manufacturing process to the packaging step by the noling.
상기한 방법으로 얻어진 본 발명은 800℃까지 기능이 소실되지 않으면서도 열경화성 폴리우레탄(Polyurethane)이나 피브시(Polyrinyl Chloride)계열의 레진(Resin) 등에 합첨하여 제품화로 만들어져 나왔을 시 무기항균제인 제올라이트(Zeolite)의 기능이 그대로 유지되면서 위와 같이 완성된 합성피혁은 인체에 무해하며 항균기능이 반영구적으로 남아있도록 한것이며 제2차의 환경오염원으로부터 보호해주고 또한 우리 인간에게는 유해성질을 지니고 있는 각종 세균류는 물론 곰팡이 포자균류들로부터 보호해주어 우리 인간들을 행복하고 건강하게 삶을 영위할 수 있도록 한 매우 유용한 발명이다.The present invention obtained by the above-mentioned method is an inorganic antibacterial zeolite (Zeolite) when it is produced by combining with a thermosetting polyurethane (Polyurethane) or resin (Polyrinyl Chloride) resin, etc. without losing its function up to 800 ℃ The synthetic leather finished as above is harmless to the human body and the antibacterial function remains semi-permanent. It protects from the secondary environmental pollutants and also has a variety of bacteria and fungi that are harmful to humans. It is a very useful invention that protects us from spore fungi so that we can live happy and healthy lives.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20010066984A (en) * | 2000-09-29 | 2001-07-12 | 마상만 | Composition ingredients of natural leather for absorption of electromagnetic wave and bacteria repression, and manufacture method thereof |
KR20040016341A (en) * | 2002-08-16 | 2004-02-21 | 박재영 | How to make artificial leather |
KR100616186B1 (en) * | 2000-05-20 | 2006-08-25 | 주식회사 코오롱 | Preparation of seat for artificial leather having good antibiosis and deorderization |
KR20230094232A (en) * | 2021-12-20 | 2023-06-28 | (주)엘엑스하우시스 | Bio artificial leather |
-
1999
- 1999-04-15 KR KR1019990013409A patent/KR19990064591A/en not_active Application Discontinuation
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100616186B1 (en) * | 2000-05-20 | 2006-08-25 | 주식회사 코오롱 | Preparation of seat for artificial leather having good antibiosis and deorderization |
KR20010066984A (en) * | 2000-09-29 | 2001-07-12 | 마상만 | Composition ingredients of natural leather for absorption of electromagnetic wave and bacteria repression, and manufacture method thereof |
KR20040016341A (en) * | 2002-08-16 | 2004-02-21 | 박재영 | How to make artificial leather |
KR20230094232A (en) * | 2021-12-20 | 2023-06-28 | (주)엘엑스하우시스 | Bio artificial leather |
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