KR19990058303A - Moisture proof coating composition of liner paper surface for corrugated box - Google Patents

Moisture proof coating composition of liner paper surface for corrugated box Download PDF

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Publication number
KR19990058303A
KR19990058303A KR1019970078402A KR19970078402A KR19990058303A KR 19990058303 A KR19990058303 A KR 19990058303A KR 1019970078402 A KR1019970078402 A KR 1019970078402A KR 19970078402 A KR19970078402 A KR 19970078402A KR 19990058303 A KR19990058303 A KR 19990058303A
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South Korea
Prior art keywords
liner paper
coating composition
proof coating
moisture
weight
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KR1019970078402A
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Korean (ko)
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KR100249431B1 (en
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김승욱
권희록
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김승욱
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Publication of KR100249431B1 publication Critical patent/KR100249431B1/en

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/38Coatings with pigments characterised by the pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents
    • D21H21/20Wet strength agents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

본 발명은 골판지 상자용 라이너지 표면의 방습 코팅조성물을 제공한다. 본 발명은 조성물을 발수제인 파라핀왁스 또는 오일왁스에 수성접착제인 아크릴수지나 아크릴스틸렌공중합물질을 사용하므로 라이너지의 회수재생사용이 가능하며 증점제로서 폴리아크릴산소다 또는 폴리비닐알코올을 사용하므로 단 1회 도포로도 표면이 균질한 라이너지를 얻을 수 있는 뛰어난 효과가 있다.The present invention provides a moisture proof coating composition of the linerboard surface for a cardboard box. The present invention uses acrylic resin or acrylic styrene copolymer which is an aqueous adhesive to paraffin wax or oil wax as a water repellent, and thus can be used for recovery and recovery of liner paper and apply only once because polyacrylic acid or polyvinyl alcohol is used as a thickener. Even with a homogeneous surface liner paper has an excellent effect.

Description

골판지 상자용 라이너지 표면의 방습 코팅조성물Moisture proof coating composition of liner paper surface for corrugated box

본 발명은 재생이 가능한 방습성 골판지 상자용 라이너지 표면의 코팅조성물에 관한 것이다.The present invention relates to a coating composition of a liner paper surface for a moisture-proof corrugated cardboard box which can be recycled.

종래에도 방습성이 있는 라이너지를 얻기 위하여 폴리에틸렌계수지 등을 녹여 압출하여 라이너지 표면에 도포하여 사용한 것이 있었으나 이는 방습효과가 그리 뛰어나지 못하였다.Conventionally, in order to obtain a moisture-proof liner paper, polyethylene resin or the like was melted and extruded and used on the surface of the liner paper, but this was not very good.

한편, 이와는 달리 일본특허 제2563071호의와 같이 아크릴계 소수성수지를 UV코팅하거나 초산비닐계수지를 사용하는 것이 있었으나 이와같은 방습제들은 유성(油性)방습제이어서 재생사용하기가 곤란하고 라이너지에 반드시 2회정도 반복하여 코팅하여야 표면이 균일한 라이너지를 얻을 수 있는 단점이 있었다.On the other hand, as in Japanese Patent No. 2563071, acrylic hydrophobic resins were UV-coated or vinyl acetate resins were used. However, these desiccants are oil-based desiccants, which are difficult to regenerate. The coating had a disadvantage of obtaining a liner paper with a uniform surface.

본 발명은 상기 종래기술들의 단점을 해결하고자 안출한 것으로 본 발명은 라이너지를 재생사용할 수 있는 방습코팅조성물을 제공함을 그 목적으로 한다. 본 발명의 다른 목적은 단1회의 코팅(도포)에 의하여도 방습이 뛰어나고 표면이 균일한 라이너지를 얻는 데 있다.The present invention has been made to solve the shortcomings of the prior art, the present invention is to provide a moisture-proof coating composition that can be used to recycle the liner paper. Another object of the present invention is to obtain a liner paper having excellent moisture resistance and a uniform surface even with a single coating (coating).

본 발명의 또다른 목적은 라이너지의 재생사용은 물론 단 1회코팅으로 뛰어난 방습효과가 있는 라이너지에 다양한 색상을 넣은 방습유색 포장상자를 제공함에 있다.Still another object of the present invention is to provide a moisture-proof color packaging box in which various colors are put into liner paper having excellent moisture-proofing effect with only one coating as well as regeneration of liner paper.

본 발명은 상기와 같은 목적을 달성하기 위하여 수성방습제를 사용하고 여기에 중점제를 적정비율 혼합사용하여 완성하였다.The present invention has been completed by using an aqueous desiccant in order to achieve the above object and using a mixture of the middle agent in the proper ratio.

이하, 본 발명의 구체적인 구성과 작용을 상세히 설명한다.Hereinafter, the specific configuration and operation of the present invention will be described in detail.

도 1은 본 발명은 방습 코팅조성물을 1회도포하여서 된 라이너지의 사진도.1 is a photographic view of the liner made by coating the moisture-proof coating composition once.

도 2는 본 발명의 또다른 방습 코팅조성물을 1회 도포하여서된 라이너지의 사진도.Figure 2 is a photograph of a liner paper by applying another moisture-proof coating composition of the present invention once.

본 발명의 재생가능하고 단 1회 도포로도 표면이 유려한 라이너지의 방습코팅조성물을 얻기 위하여 발수제로서 parapin wax또는 oil wax를 사용하고 여기에 접착제(Binder)로서 아크릴계수지 에멀션 또는 아크릴스틸렌 공중합물질을 혼합한 다음 안료와 증점제를 추가하고 이어 가수(H2O)하여서 되는 것이다.Paraffin wax or oil wax is used as a water repellent and an acrylic resin emulsion or acrylic styrene copolymer is used as a binder to obtain a moisture-repellent coating composition of a liner paper having a reproducible and smooth surface even with a single application of the present invention. After mixing, the pigment and the thickener are added, followed by hydrolysis (H 2 O).

이하 본 발명의 구체적인 구성 및 작용을 실시예를 들어 설명하지만, 본 발명의 권리범위는 이들 실시예에만 제한되지 아니한다.Hereinafter, the specific configuration and operation of the present invention will be described with reference to Examples, but the scope of the present invention is not limited only to these Examples.

본 발명의 포장상자용 라이너지의 표면 방습 코팅조성물은 하기 실시예1과 같다.Surface moisture-proof coating composition of the liner paper for packaging of the present invention is the same as in Example 1.

실시예 1 본 발명의 방습코팅조성물Example 1 Moisture-proof coating composition of the present invention

A 방습제 조성비A desiccant composition costs

Parapin wax 또는 oil wax 1.0 ∼ 6.0%(중량)Parapin wax or oil wax 1.0-6.0% (weight)

B 접착제B glue

아크릴수지 에밀션 또는 아크릴스틸렌 공중합물질 15 ∼ 40%(중량)Acrylic resin emulsion or acrylic styrene copolymer 15 to 40% (weight)

C 색소C pigment

안료 30 ∼ 55%(중량)Pigment 30-55% (weight)

D 증점제D thickener

폴리아크릴산소다 또는 폴리비닐알코올(PVA) 24 ∼ 44%(중량)Sodium polyacrylate or polyvinyl alcohol (PVA) 24 to 44% (weight)

실시예 2 : 본 발명 방습코팅조성물의 제조방법Example 2 Preparation Method of the Moisture-Proof Coating Composition

실시예 1의 방습코팅조성물을 구성하는 화학물질 중 parapin wax 6중량%, 아크릴수지에멀션 40중량%, 안료 30중량%, 폴리아크릴산소다 24중량%를 혼합하고 여기에 3배의 물을 가수한 다음 상온에서 Dynomill(신성기계)에서 균질하게 분산시켰다.Among the chemicals constituting the moisture-proof coating composition of Example 1, 6% by weight of parapin wax, 40% by weight of acrylic resin emulsion, 30% by weight of pigment, and 24% by weight of sodium polyacrylate were mixed with 3 times water. Disperse homogeneously in Dynomill (Natural machine) at room temperature.

실시예 3 :Example 3:

실시예 2와 동일하게 하여 본 발명 방습코팅조성물을 제조하되 oil wax 1.0중량%, 아크릴스틸렌 공중합물질 15중량%, 안료 40%중량, 폴리비닐알코올 44중량%로 조성하고 여기에 2배의 물을 가수하였다.The moisture-proof coating composition of the present invention was prepared in the same manner as in Example 2, except that 1.0 wt% of oil wax, 15 wt% of acryl styrene copolymer, 40 wt% of pigment, and 44 wt% of polyvinyl alcohol were added thereto. Singer

실시예 4 : 라이너지의 표면 방습코팅처리Example 4 Surface Moisture Proof Coating of Liner Paper

상기 실시예 2와 실시예 3을 통하여 제조된 조성물을 골판지 상자용 라이너지의 표면 방습코팅을 실시하기 위하여 Coater(Michelman사 제품)를 사용하여 1회도포한 후 건조하면서 Roller로 감아내었다.The composition prepared in Examples 2 and 3 was coated with a coater (manufactured by Michelman Co., Ltd.) once and then wound with a roller to dry the surface of the corrugated cardboard liner.

실시예 2와 실시예 3의 조성물에 따라 라이너지의 방습코팅처리된 라이너지의 표면은 매우 균일한 특징이 있다. 최종제품은 사진도 1과 사진 도 2에 각각 표시하여 두었다.According to the compositions of Examples 2 and 3, the surface of the liner paper with moisture proof coating of the liner paper has a very uniform feature. The final product is shown in Figure 1 and Figure 2 respectively.

이상 실험예와 실시예를 통하여 확인할 수 있는 바와같이 본 발명은 수성 접착제를 수성아크릴계수지 또는 아크릴스틸렌 공중합물질을 사용하여 라이너지의 회수 재생사용이 가능하므로 환경친화기술을 제공하는 효과가 있으며 증점제로서 폴리아크릴산소다 또는 폴리비닐알코올을 사용하므로서 수지가 라이너지에 침투되는 것을 방지하여 표면의 방습코팅처리가 균일하게 이루어져 제품의 품질향상이 뛰어난 효과가 있으므로 포장상자 및 라이너지제조산업상 매우 유용한 발명인 것이다.As can be seen through the above experimental examples and examples, the present invention has an effect of providing an environmentally friendly technology because the aqueous adhesive can be used to recover and use the liner paper using an aqueous acrylic resin or an acrylic styrene copolymer, and as a thickener, The use of sodium acrylate or polyvinyl alcohol prevents the resin from penetrating into the liner paper, so that the moisture-proof coating of the surface is made uniform, thus improving the quality of the product, which is a very useful invention in the packaging box and liner paper manufacturing industry.

Claims (2)

골판지 상자용 라이너지 표면의 방습코팅조성물이 하기 조성비율을 갖는 것을 특징으로 하는 조성물Composition characterized in that the moisture-proof coating composition of the liner paper surface for the cardboard box has the following composition ratio 발수제(A)는 파리핀왁스 또는 오일왁스로서 1.0∼6.0중량%Water repellent (A) is 1.0 to 6.0% by weight as paraffin wax or oil wax 접착제(B)는 아크릴수지에밀션 또는 아크릴스틸렌공중합물질 15∼40중량%Adhesive (B) is 15 to 40% by weight of acrylic resin emulsion or acrylic styrene copolymer 색소(C)는 안료 30∼55중량%Pigment (C) is 30 to 55% by weight pigment 증점제(D)는 폴리아크릴산소다 또는 폴리비닐알코올 24∼44중량%Thickener (D) is 24 to 44% by weight of sodium polyacrylate or polyvinyl alcohol 증점제가 포함된 방습코팅조성물이 단 1회 도포되어서 되는 라이너지가 접착된 포장용 상자.A liner-bonded packaging box in which a moisture proof coating composition containing a thickener is applied only once.
KR1019970078402A 1997-12-30 1997-12-30 Chemical composition using for water proof liner paper of paper vessel KR100249431B1 (en)

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KR1019970078402A KR100249431B1 (en) 1997-12-30 1997-12-30 Chemical composition using for water proof liner paper of paper vessel

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Application Number Priority Date Filing Date Title
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Publication number Priority date Publication date Assignee Title
KR100746155B1 (en) 2005-05-19 2007-08-09 은광판지포장 주식회사 A corrugated cardboard as a flooring
KR101329259B1 (en) 2011-11-25 2013-11-14 이풍우 Packing paper having waterproofing and its manufacturing method
CN115897284B (en) * 2022-12-19 2024-02-09 杭州永晶科技有限公司 Production method of waterproof wear-resistant corrugated board

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JPH06316878A (en) * 1993-05-06 1994-11-15 Tokai Senko Kk Printing paste composition for cellulosic fiber-structural article
JP3442523B2 (en) * 1995-02-20 2003-09-02 日本製紙株式会社 Moisture proof paper with excellent blocking resistance and slip resistance

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