KR19990005677A - Diaphragm for speaker and manufacturing method thereof - Google Patents

Diaphragm for speaker and manufacturing method thereof Download PDF

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Publication number
KR19990005677A
KR19990005677A KR1019970029892A KR19970029892A KR19990005677A KR 19990005677 A KR19990005677 A KR 19990005677A KR 1019970029892 A KR1019970029892 A KR 1019970029892A KR 19970029892 A KR19970029892 A KR 19970029892A KR 19990005677 A KR19990005677 A KR 19990005677A
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South Korea
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diaphragm
pulp
polyester
weight
containing polypropylene
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KR1019970029892A
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Korean (ko)
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KR100254889B1 (en
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이경화
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이형도
삼성전기 주식회사
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    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R31/00Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor
    • H04R31/003Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor for diaphragms or their outer suspension
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R7/00Diaphragms for electromechanical transducers; Cones
    • H04R7/02Diaphragms for electromechanical transducers; Cones characterised by the construction
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R2307/00Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
    • H04R2307/025Diaphragms comprising polymeric materials
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; DEAF-AID SETS; PUBLIC ADDRESS SYSTEMS
    • H04R2307/00Details of diaphragms or cones for electromechanical transducers, their suspension or their manufacture covered by H04R7/00 or H04R31/003, not provided for in any of its subgroups
    • H04R2307/029Diaphragms comprising fibres

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Signal Processing (AREA)
  • Multimedia (AREA)
  • Manufacturing & Machinery (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)

Abstract

본 발명은 스피커(speaker)용 진동판 및 그 제조방법에 관한 것이며; 그 목적은 폴리플로필렌 폴리에스터(polypropylene polyester)에 의해 부분표면코팅효과를 갖는 진동판 및 그 제조방법을 제공함에 있다.The present invention relates to a diaphragm for a speaker and a method of manufacturing the same; The object is to provide a diaphragm having a partial surface coating effect by polypropylene polyester and a method of manufacturing the same.

상기 목적 달성을 위한 본 발명은 폴리에스테르함유 폴리프로필렌(polyester containing polypropylene): 10-50중량%와 펄프원료: 90-50중량%로 조성되고, 내측 표면에는 상기 폴리에스테르함유 폴리프로필렌이 부분적으로 혼재하고 외측 표면에는 펄프만이 존재하여 구성되는 스피커용 진동판 및 이러한 진동판을 간단히 제조할 수 있는 방법에 관한 것을 그 기술적 요지로 한다.The present invention for achieving the above object is composed of a polyester containing polypropylene (polyester): 10-50% by weight and pulp material: 90-50% by weight, the polyester-containing polypropylene is partially mixed on the inner surface The technical gist of the present invention relates to a loudspeaker diaphragm in which only pulp exists on the outer surface, and a method of simply manufacturing the diaphragm.

Description

스피커용 진동판 및 그 제조방법Diaphragm for speaker and manufacturing method thereof

본 발명은 스피커(speaker)용 진동판 및 그 제조방법에 관한 것으로서, 보다 상세하게는 폴리플로필렌 폴리에스터(polypropylene polyester)에 의해 분분표면코팅효과를 갖는 진동판 및 그 제조방법에 과한 것이다.The present invention relates to a diaphragm for a speaker and a method for manufacturing the same, and more particularly, to a diaphragm having a powder surface coating effect by polypropylene polyester and a method for manufacturing the same.

전기에너지를 음향에너지로 바꾸는 음향변환기인 스피커의 음질은 진동판에 의해 결정된다고 해도 과언이 아니다. 그 만큼 진동판은 스피커에 있어 중요한 부품이다. 구체적으로 스피커의 음질은 진동판의 형상이나 소재에 따라 크게 좌우된다. 진동판 소재의 경우 탄성율이 높고 중량은 스피커의 능률을 올리기 위해 가벼운 소재가 이상적인 조건이라고 알려져 있다. 또한, 진동판 소재는 내부손실(tan δ)이 큰 것이 좋다. 그리고, 진동판의 물성을 변화시키면 스피커의 음질과 주파수특성이 변하여 광역의 주파수 특성과 좋은 음질의 재생이 가능하다고 알려져 있다.It is no exaggeration to say that the sound quality of a speaker, an acoustic transducer that converts electrical energy into acoustic energy, is determined by the diaphragm. The diaphragm is an important part of the speaker. In particular, the sound quality of the speaker depends greatly on the shape and the material of the diaphragm. In the case of diaphragm material, high elastic modulus and light weight are known to be ideal conditions for lighter speakers. In addition, the diaphragm material is preferably a large internal loss (tan δ). In addition, when the physical properties of the diaphragm are changed, it is known that the sound quality and frequency characteristics of the speaker are changed, so that a wide frequency characteristic and good sound quality can be reproduced.

일반적으로 스피커 진동판은 펄프(pulp)를 이용하여 제조된다. 종래 펄프를 이용한 진동판의 제조과정은, 우선 이해(離解)과정에서 부풀린 펄프원료를 고해기(beater)에 의해 고해(叩解;beating)시킨 다음, 고해된 펄프원료를 탱크내에서 진동판(cone paper)모양의 초망판(抄網板)을 이용하여 기초적인 형상을 초상(抄上)하고, 이 초지(抄紙)를 탈수처리한다. 이후, 탈수된 초지는 금형에 삽입하여 약 150-160℃의 온도 범위에서 약 15초 정도 가열하면 진동판이 얻어진다. 이와는 달리 현재는 펄프원료로 제조된 진동판의 표면에 약품을 코팅하거나 기타 부자재를 추가로 접착, 합성하여 보다 고음질 고특성의 스피커용 진동판을 제조하는 방법도 알려져 있다. 또한, 카본시트(carbon sheet)등의 단일체를 이용하여 진동판을 제작하는 방법도 있다. 그러나, 아직까지는 상기방법으로부터 얻어지는 진동판들은 스피커의 음질면에서 미흡할 뿐만아니라 제조공정이 복잡하여 대량생산에는 적합치 못한 실정이다.In general, speaker diaphragms are manufactured using pulp. In the conventional manufacturing process of the diaphragm using pulp, first, the pulp material inflated in the process of beating is beaten by a beater, and then the beaten pulp material in a tank is cone paper. A basic mesh is used to form a basic shape, and the paper is dehydrated. Then, the dehydrated paper is inserted into the mold and heated for about 15 seconds in the temperature range of about 150-160 ℃ to obtain a diaphragm. On the other hand, a method of manufacturing a diaphragm for loudspeaker of higher quality and high quality is also known by coating a chemical on the surface of the diaphragm made of pulp material or by further bonding and synthesizing other subsidiary materials. There is also a method of producing a diaphragm using a single body such as a carbon sheet. However, up to now, the diaphragms obtained from the above method are not suitable for mass production due to the lack of sound quality of the speaker and the complicated manufacturing process.

따라서, 본 발명은 펄프진동판의 부드러움과 합성섬유의 강한소리를 동시에 발생할 수 있어 고음질의 원음재생과 광역의 주파수 대역을 갖는 스피커용 진동판을 제공함에 그 목적이 있다.Accordingly, an object of the present invention is to provide a soft vibration of the pulp vibration plate and a strong sound of the synthetic fiber at the same time to provide a high-quality original sound reproduction and a diaphragm for a speaker having a wide frequency band.

본 발명의 다른 목적은 상기한 진동판을 간단한 공정을 통해 제조할 수 있는 방법을 제공함에 있다.Another object of the present invention is to provide a method capable of manufacturing the above-mentioned diaphragm through a simple process.

도1은 종래 및 본 발명의 진동판에 대한 주파수에 따른 음질특성비교도1 is a comparison of sound quality characteristics according to frequency for the diaphragm of the prior art and the present invention

도2는 종래 및 본 발명의 진동판의 내측표면에 대한 조직사진Figure 2 is a tissue photograph of the inner surface of the vibration plate of the prior art and the present invention

상기 목적달성을 위한 본 발명은 폴리에스테르함유 폴리플로필렌 (polypropylene polyester): 10-50중량%와 펄프원료: 90-50중량%로 조성되고, 내측 표면에는 상기 폴리에스테르함유 폴리프로필렌이 부분적으로 혼재하고 외측 표면에는 펄프만이 존재하여 구성되는 스피커용 진동판에 관한 것이다.The present invention for achieving the above object is composed of a polyester-containing polypropylene (polypropylene polyester): 10-50% by weight and pulp material: 90-50% by weight, the polyester-containing polypropylene is partially mixed on the inner surface And it relates to a diaphragm for a speaker consisting of only the pulp on the outer surface.

또한, 본 발명은 펄프원료: 50-90중량%와 폴리에스테르함유 폴리프로필렌: 50-10중량%를 혼초(混抄)하여 이해시키는 단계; 이해된 펄프를 고해기로 고해 하는 단계; 고해된 펄프를 진동판모양의 초망판으로 초상하는 단계; 및 초상된 초지를 탈수한 다음, 탈수된 초지를 초지내의 폴리에스테르함유 폴리프로필렌이 녹을 정도로 가열된 금형에서 성형하는 단계; 를 포함하여 구성되는 스피커용 진동판의 제조방법에 관한 것이다.In addition, the present invention comprises the steps of mixing the pulp material: 50-90% by weight and polyester-containing polypropylene: 50-10% by weight; Confessing the understood pulp to confession; Poring the beaten pulp into a diaphragm shaped mesh plate; And dewatering the corrugated paper, and then molding the dewatered paper into a mold heated to melt the polyester-containing polypropylene in the paper. It relates to a method of manufacturing a diaphragm for a speaker configured to include.

이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명의 스피커용 진동판은 폴리에스테르함유 폴리프로필렌(이하, 단지 'PP')과 펄프가 함유되어 상기 PP가 진동판의 내측 표면에 부분적으로 혼재되어 PP가 부분적으로 펄프 표면에 코팅된 효과를 나타낸다.The diaphragm for the speaker of the present invention contains polyester-containing polypropylene (hereinafter, only 'PP') and pulp so that the PP is partially mixed with the inner surface of the diaphragm, so that the PP is partially coated on the pulp surface.

상기 PP와 펄프는 각각 10-50중량% 및 90-50중량% 정도 함유됨이 바람직하다.The PP and pulp is preferably contained in about 10-50% by weight and 90-50% by weight, respectively.

만일 PP가 10중량%미만으로 되거나 펄프가 90중량%를 초과하는 경우에는 PP의 혼초(混抄)에 의한 부분적인 코팅효과가 미흡하고, 반대로 PP가 50중량%를 초과하거나 펄프가 50중량%미만으로 되면 스피커의 음속전달은 양호하나 진동판의 부드러움이 부족하여 원음재생이 미흡하다.If the PP content is less than 10% by weight or the pulp is more than 90% by weight, the partial coating effect due to the blending of the PP is insufficient, on the contrary, the PP content is more than 50% or the pulp is less than 50% by weight. In this case, the sound velocity of the speaker is good, but the softness of the diaphragm is insufficient, so that the reproduction of the original sound is insufficient.

본 발명에서 사용되는 PP는 폴리프로필펜수지에 폴리에스테르수지(polyester)가 혼합된 합성수지로서 단섬유형태가 보다 바람직하다. 이러한 PP는 펄프보다 비중이 가벼워 초상공정시 진동판의 내측 표면으로의 부상이 용이하게 될 수 있다.PP used in the present invention is a synthetic resin in which a polyester resin (polyester) is mixed with the polypropyl pen resin is more preferably in the form of short fibers. Such PP may have a specific gravity lower than that of pulp, and thus may easily float to the inner surface of the diaphragm during the portrait process.

이하, 본 발명의 진동판에 대한 제조방법을 상세히 설명한다.Hereinafter, the manufacturing method for the diaphragm of the present invention will be described in detail.

본 발명의 진동판을 제조하기 위해서는, 먼저 50-90중량%의 펄프원료를 물에 풀어서 이해한다. 이때, 이해과정에서 펄프원료에 상기 PP를 약 10-50중량% 정도 혼초한다. 이해된 펄프는 고해기에서 일반 고해과정과 같이 고해처리(beating)하여 일정한 크기로 잘라준다.In order to manufacture the diaphragm of the present invention, it is understood that 50-90% by weight of pulp material is first dissolved in water. At this time, about 10-50% by weight of the PP kneaded in the pulp material in the process of understanding. The understood pulp is beated and cut to a certain size in the same way as in the normal blasting process.

일정크기로 고해된 펄프는 탱크내에 설치된 초망판에서 진동판 모양의 초지로 초상한다. 상기 PP는 펄프보다 비중이 가볍기 때문에 초상된 초지내에서 부상하게 된다. 따라서, 진동판의 내측 표면에는 상기 PP가 부분적으로 잔존하게 되고, 진동판의 외측 표면에는 펄프만이 잔존하게 된다.The pulp, which is beaten to a certain size, is portrait from a mesh plate installed in the tank into a diaphragm-shaped sheet of paper. Since PP has a lighter specific gravity than pulp, it rises in portrait paper. Therefore, the PP remains partially on the inner surface of the diaphragm, and only pulp remains on the outer surface of the diaphragm.

그 다음, 탱크내의 물을 배수하여 초상된 초지를 충분히 탈수한다. 그리고, 탈수된 초지를 초지내의 폴리에스테르함유 폴리프로필렌이 녹을 정도로 가열된 금형에서 성형한다. 성형은 약 220-230℃의 온도범위가 적당하다. 상기 성형은 220℃미만에서 행하면 PP가 완전히 녹지않아 PP에 의한 코팅효과가 미흡하며, 230℃를 초과한 온도에서 행하면 금형과의 이형이 곤란하게 되어 바람직하지 않다. 이렇게 성형된 진동판내에는 PP가 녹아 진동판의 내측 표면에 마치 PP코팅을 한 것과 같은 효과가 생긴다. 이로인해 본 발명의 진동판은 펄프가 가지고 있는 부드러움과 PP자체의 강인함이 어우려져 종래의 진동판과는 전혀 다른 음질을 발생시킨다.Then, the water in the tank is drained to sufficiently dewater the treated grassland. The dehydrated paper is then molded in a mold heated to the extent that the polyester-containing polypropylene in the paper melts. Molding is suitable for a temperature range of about 220-230 ° C. When the molding is performed at a temperature below 220 ° C., the PP is not completely melted and thus the coating effect by the PP is insufficient. When the molding is performed at a temperature exceeding 230 ° C., the mold is difficult to be released from the mold. In the molded diaphragm, the PP melts and the effect is as if the PP coating was applied to the inner surface of the diaphragm. As a result, the diaphragm of the present invention combines the softness of the pulp with the toughness of the PP itself, resulting in a completely different sound quality than the conventional diaphragm.

이하, 본 발명은 실시예를 통하여 구체적으로 설명한다.Hereinafter, the present invention will be described in detail through examples.

[실시예 1]Example 1

하기표1과 같이 펄프원료와 폴리에스테르함유 폴리프로필렌 단섬유를 혼초하고 혼초된 펄프원료를 100배수의 물로 혼합하여 펄프섬유를 충분히 이해시켰다.As shown in Table 1, pulp material and polyester-containing polypropylene short fibers were kneaded and the mixed pulp material was mixed with 100 times of water to fully understand pulp fibers.

이해된 펄프를 고해기로 일정크기로 고해하고, 고해된 펄프를 진동판모양의 초망판으로 초상하였다. 그 다음, 초상된 초지를 탈수하고, 탈수된 초지를 225℃로 가열된 금형에서 15초간 가압하여 0.4mm두께의 진동판으로 성형하였다.The pulp understood was beaten to a certain size with a pulverizer, and the beaten pulp was portrayed as a diaphragm-shaped mesh plate. Then, the dehydrated paper was dehydrated, and the dehydrated paper was pressed in a mold heated to 225 ° C. for 15 seconds to form a 0.4 mm thick diaphragm.

또한, 본 발명과의 비교를 위하여 종래의 100% 펄프만을 사용한 진동판(종래재)을 제조하였다.In addition, a diaphragm (traditional material) using only conventional 100% pulp was prepared for comparison with the present invention.

이와같이 제조된 각각의 진동판에 대하여 음속, 탄성율, 및 내부손실을 측정하고 그 결과를 하기표1에 나타내었다.For each diaphragm thus manufactured, the sound velocity, elastic modulus, and internal loss were measured, and the results are shown in Table 1 below.

또한, 종래재와 발명재(2)에 대하여 주파수에 따른 음압을 측정하고, 그 결과를 도1에 나타내었다.In addition, the sound pressure according to frequency was measured about the conventional material and the invention material (2), and the result is shown in FIG.

[표 1] TABLE 1

상기표1에 나타난 바와 같이, 발명재(1-3)의 경우 종래 100% 펄프를 사용했을 때보다 음속이 빠르고, 탄성율 및 내부손실이 커 스피커용 진동판으로서 우수한 특성을 나타냄을 알 수 있었다.As shown in Table 1, the invention (1-3) was found to exhibit excellent characteristics as a diaphragm for a speaker because the sound velocity is faster than the conventional 100% pulp, the elastic modulus and internal loss is large.

또한, 도1에 도시된 바와 같이, 본 발명재(2)의 경우 종래재의 경우보다 광역주파수대역에서 음질이 매우 안정함을 알 수 있었다.In addition, as shown in Figure 1, the present invention (2) was found to be very stable sound quality in the wide frequency band than the case of the conventional material.

이렇게 본 발명재가 종래의 펄프진동판보다 우수한 이유는, 종래재와 발명재(2)의 진동판의 내측 표면조직을 나타내고 있는 도2의 결과에서도 확인되고 있다. 도2a는 종래의 펄프진동판의 내측표면을 각각 50배, 250배로 관찰한 조직이며, 도2b는 발명재(2)의 진동판의 내측표면을 각각 50배, 250배로 관찰한 조직이다. 즉, 도2에서와 같이, 종래재의 경우 펄프섬유끼리만 엉켜 결합되어 있는 반면 발명재(2)의 경우는 펄프섬유에 PP가 결합되어 부분적으로 PP코팅이 이루어져 있슴이 확인되고 있다.The reason why this invention material is superior to the conventional pulp vibration plate is confirmed also in the result of FIG. 2 which shows the inner surface structure of the vibration plate of the conventional material and the invention material (2). Fig. 2A is a structure in which the inner surface of the conventional pulp vibration plate is observed 50 times and 250 times, respectively, and Fig. 2B is a structure in which the inner surface of the vibration plate of the invention material 2 is observed 50 times and 250 times, respectively. That is, as shown in Figure 2, in the case of the conventional material, only pulp fibers are entangled with each other, while in the case of the invention material (2), it is confirmed that PP is partially formed by combining PP with pulp fibers.

한편, 본 발명재의 경우 대체로 PP함유량이 증가함에 따라 음속, 탄성율이 증가하나 음질에 영향을 미치는 내부손실은 PP함유량이 증가함에 따라 증가하다 감소한다. 이는 PP의 함량이 증가함에 따라 진동판에 내부에 PP가 증가하여 진동판 자체가 경화되는 효과가 있고 일정량이상 첨가되는 경우 내부손실이 감소되기 때문인 것으로 생각된다.On the other hand, in the case of the present invention, the sound velocity and elastic modulus increase as the PP content increases, but the internal loss affecting the sound quality increases and decreases as the PP content increases. This is thought to be because the increase in the PP content inside the diaphragm increases the content of the diaphragm, thereby hardening the diaphragm itself and reducing the internal loss when a certain amount is added.

[실시예 2]Example 2

발명재(2)와 같은 조성으로 혼초된 펄프와 PP를 하기표2와 같은 조건으로 성형한 것을 제외하고는 실시예와 동일한 방법으로 진동판을 제조하였다.A diaphragm was manufactured in the same manner as in Example, except that pulp and PP mixed with the same composition as the inventive material 2 were molded under the same conditions as in Table 2 below.

[표 2] TABLE 2

상기표2에도 나타난 바와 같이, 본 발명에 의한 제조공정에서 성형은 무엇보다도 PP가 완전 녹을 정도의 온도에서 행해져야 바람직함을 알 수 있었다. 그리고, 성형온도는 약 220-230℃의 온도범위가 최적임을 알 수 있었다.As shown in Table 2, in the manufacturing process according to the present invention was found that it is preferable to be carried out at a temperature such that PP is completely melted above all. And, the molding temperature was found to be the optimum temperature range of about 220-230 ℃.

상술한 바와 같이, 본 발명의 진동판은 PP가 녹아 진동판의 내측 표면이 마치 PP코팅을 한 것과 같이 되어 펄프진동판이 갖는 부드러움과 합성섬유의 강인함이 조화되어 기존의 진동판에 비하여 고음질의 원음재생과 광역의 주파수 대역을 갖는 효과가 있다. 또한, 그 제조과정도 종래의 코팅방식보다도 매우 간단하여 대량생산에도 적합한 효과가 있다.As described above, the diaphragm of the present invention is melted PP and the inner surface of the diaphragm is like PP coating, so that the softness of the pulp vibrating plate and the strength of the synthetic fiber are combined, resulting in higher sound quality and wider range of original sound than the conventional diaphragm. It is effective to have a frequency band of. In addition, the manufacturing process is also much simpler than the conventional coating method has an effect suitable for mass production.

Claims (5)

폴리에스테르함유 폴리프로필렌: 10-50중량%와 펄프원료: 90-50중량%로 조성되고, 내측 표면에는 상기 폴리에스테르함유 폴리프로필렌이 부분적으로 혼재하고 외측 표면에는 펄프만이 존재하여 구성되는 스피커용 진동판Polyester-containing polypropylene: 10-50% by weight and pulp material: 90-50% by weight, the inner surface of the polyester polypropylene is partially mixed and the outer surface of the speaker consisting of only pulp tympanum 펄프원료: 50-90중량%와 폴리에스테르함유 폴리프로필렌: 50-10중량%를 혼초하여 이해시키는 단계; 이해된 펄프를 고해기로 고해하는 단계; 고해된 펄프를 진동판모양의 초망판으로 초상하는 단계; 및 초상된 초지를 탈수한 다음, 탈수된 초지를 초지내의 폴리에스테르함유 폴리프로필렌이 녹을 정도로 가열된 금형에서 성형하는 단계; 를 포함하여 구성되는 스피커용 진동판의 제조방법Mixing and understanding pulp material: 50-90% by weight and polyester-containing polypropylene: 50-10% by weight; Beating the understood pulp with a fryer; Poring the beaten pulp into a diaphragm shaped mesh plate; And dewatering the corrugated paper, and then molding the dewatered paper into a mold heated to melt the polyester-containing polypropylene in the paper. Method for manufacturing a diaphragm for speakers comprising a 제2항에 있어서, 상기 폴리에스테르함유 폴리프로필렌은 단섬유 형태임을 특징으로 하는 제조방법The method of claim 2, wherein the polyester-containing polypropylene is in the form of short fibers. 제2항에 있어서, 상기 초상은 초지의 내측 표면에 폴리에스테르함유 폴리프로 필렌이 부상되도록 물을 배수함을 특징으로 하는 제조방법The method of claim 2, wherein the portrait is drained water so that the polyester-containing polypropylene floats on the inner surface of the paper 제2항에 있어서, 상기 성형은 220-230℃의 온도범위에서 행함을 특징으로 하는 제조방법The method of claim 2, wherein the molding is performed in a temperature range of 220-230 ° C.
KR1019970029892A 1997-06-30 1997-06-30 Speaker's diaphragm and its manufacturing method KR100254889B1 (en)

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