KR19980056090A

KR19980056090A - Ink composition for ink jet printer

Info

Publication number: KR19980056090A
Application number: KR1019960075354A
Authority: KR
Inventors: 유승민; 김성진
Original assignee: 김광호; 삼성전자 주식회사
Priority date: 1996-12-28
Filing date: 1996-12-28
Publication date: 1998-09-25

Abstract

본 발명은 잉크 젯트 프린터용 잉크 조성물을 개시하고 있는데, 상기 조성물에는 올리고머 분산제, 안료 및 용매를 포함하고 있다. 본 발명에 따른 잉크 조성물을 이용하면, 제조하기가 용이하고, 인쇄적성, 내수성 및 내광성이 우수할 뿐만 아니라 저장안정성이 매우 양호하다.The present invention discloses an ink composition for an ink jet printer, which comprises an oligomer dispersant, a pigment and a solvent. By using the ink composition according to the present invention, it is easy to produce, has excellent printability, water resistance, light resistance and storage stability as well.

Description

Ink composition for ink jet printer

본 발명은 잉크 젯트 프린터용 잉크 조성물에 관한 것으로서, 상세하기로는 잉크 젯트 프린터에 사용되는 안료중심의 수용성 잉크 조성물로서, 제조하기가 용이한 동시에 내수성, 내광성 및 저장안정성이 우수한 잉크 젯트 프린터용 잉크 조성물에 관한 것이다.The present invention relates to an ink composition for an inkjet printer, and more particularly, to a pigment-based water-soluble ink composition used in an ink jet printer, which is easy to produce and has excellent water resistance, light resistance and storage stability .

잉크 젯트 프린팅(ink jet printing)은 컴퓨터로부터 나온 정보를 인쇄하는 것으로서, 프린터(잉크토출기구, 이하 프린터헤드(printerhead)라고 칭함)안에 형성된 방울이 토출되어 기록매체에 기록되는 방법이다. 상용화된 잉크 젯트 프린팅 방식의 대표적인 것으로는 써멀 버블 잉크 젯트(thermal bubble ink jet)와 압전(壓電)식 버블 잉크 젯트(piezoelectic bubble ink jet) 방식이 있다.Ink jet printing is a method of printing information from a computer, in which droplets formed in a printer (ink ejection mechanism, hereinafter referred to as printer head) are ejected and recorded on a recording medium. Typical examples of the commercialized ink jet printing method include a thermal bubble ink jet and a piezoelectric bubble ink jet method.

써멀 버블 잉크 젯트 방식에서는, 프린터헤더의 발열체에 의하여 잉크가 그 비등점 이상으로 가열될 때 기포가 형성된다. 그리고 이러한 기포들이 성장하여 큰 기포를 만들어낸다. 이와 같이 큰 기포가 형성되면 주변의 잉크에 압력이 가해져 잉크가 토출구를 통하여 토출되면서 인쇄된다.In the thermal bubble ink jet method, bubbles are formed when the ink is heated to a temperature higher than the boiling point by the heating element of the printer header. These bubbles grow and produce big bubbles. When large bubbles are formed as described above, pressure is applied to the surrounding ink, and the ink is printed while being ejected through the ejection opening.

압전식 버블 잉크 젯트 방식은 압전식 요소에 전압이 가해질 때 나타나는 부피 변화에 따라 형성된 압력이 잉크에 가해져서 잉크가 토출구를 통하여 토출되면서 인쇄되는 방식이다.In the piezoelectric type bubble ink jet method, a pressure formed in accordance with a change in volume when a voltage is applied to a piezoelectric element is applied to the ink so that the ink is printed while being ejected through the ejection opening.

잉크 젯트 프린터용 잉크 조성물은 염료, 안료 등의 착색제, 물, 흡수제 등과 같은 첨가제로 구성된다. 이 때 착색제로서 염료를 사용하는 경우에는 소망하는 바대로 칼라 인쇄가 가능한 염료를 선정한다는 것이 매우 어렵고, 내수성과 내광성이 크게 떨어져 그 사용이 제한적이다. 이와 비교하여 착색제로서 안료를 사용하는 경우에는 상기 염료의 경우보다 우수한 내수성과 내광성을 나타낸다.The ink composition for an ink jet printer is composed of additives such as dyes, colorants such as pigments, water, absorbents and the like. In this case, when a dye is used as a coloring agent, it is very difficult to select a dye capable of color printing as desired, and the use of the dye is limited due to a large water resistance and light resistance. In contrast, when a pigment is used as a colorant, it exhibits better water resistance and light resistance than the dye.

그런데, 착색제로서 안료를 이용한 잉크 조성물 제조공정중, 건조과정에서 반데르 바알스 인력(van der waals attraction)에 의한 친수성 응집(hydrophilic aggregation)에 의하여 안료 입자가 뭉쳐져 덩어리를 형성하게 된다. 그런데 이렇게 형성된 안료 덩어리는 잉크 토출구를 막기 때문에, 이러한 현상을 사전에 예방하기 위해서는 안료 덩어리를 분쇄하는 것이 매우 중요하다. 일반적으로 안료 입자의 크기가 작으면 작을수록 색의 강도, 광택, 밝기, 투명도 등이 양호하여 화질 특성이 향상된다.However, in the process of manufacturing an ink composition using a pigment as a colorant, pigment particles aggregate due to hydrophilic aggregation by van der waals attraction during the drying process to form agglomerates. However, since the pigment agglomerates thus formed block the ink ejection openings, it is very important to crush the pigment agglomerates to prevent such phenomena in advance. Generally, the smaller the size of the pigment particle, the better the color strength, gloss, brightness, transparency, and the like, so that the image quality characteristics are improved.

그런데 안료 덩어리를 분쇄하는 경우, 일단 분쇄된 입자라고 하더라도 다시 서로 뭉치려는 경향이 있으므로 총 표면 에너지를 최소화시켜 분쇄된 입자가 다시 뭉치는 것을 방지하는 과정 즉, 분산공정이 필수적이다. 분산공정을 거친 안료는 정전기적 안정화(electric stabilization), 안정화제를 이용한 입체 안정화(steric stabilization) 및 정전기와 입체 안정화가 복합된 안정화(electro-steric stabilization)에 의하여 안정화된 상태를 유지할 수 있게 된다. 그런데 분산매질중 전해질의 유뮤에 따라 영향을 받는 정전기적 안정화보다는 전해질의 영향을 적게 받는 입체 안정화가 일반적으로 사용되었다.However, in the case of pulverizing pigment agglomerates, once the pulverized particles tend to aggregate together again, a process of minimizing the total surface energy to prevent the re-aggregation of the pulverized particles, that is, the dispersion process, is essential. The pigment after the dispersion process can be stabilized by electric stabilization, steric stabilization using a stabilizer, and electro-steric stabilization combined with electrostatic and steric stabilization. However, steric stabilization, which is less affected by the electrolyte than the electrostatic stabilization that is influenced by the presence of the electrolyte in the dispersion medium, is generally used.

종래에는 분산제로서 주로 고분자 분산제를 사용하였다. 이 고분자 분산제는 친수성기와 소수성기를 함께 갖고 있는 공중합체로서, 소수성기는 안료와 작용하여 안료의 분산을 안정화시키는 역할을 하며, 친수성기는 수용성 용매와 작용하여 입체 안정성을 부여하는 역할을 수행한다.In the past, a polymer dispersant was mainly used as a dispersant. This polymeric dispersant is a copolymer having a hydrophilic group and a hydrophobic group together. The hydrophobic group acts on the pigment to stabilize the dispersion of the pigment, and the hydrophilic group acts on the water-soluble solvent to impart stereoscopic stability.

그런데 고분자 분산제는 대체적으로 분자량이 크기 때문에 그 첨가 함량을 약간만 변화시킨다고 하더라도 잉크 조성물의 물성(예로써 점도)이 매우 달라지므로 잉크 조성물 제조시 분산제 함량을 제어한다는 것이 매우 어려운 과제이다. 또한 고분자내에 친수성기가 함유되어 있다고 하더라도 전체 화합물에 대한 친수성기의 분율(fraction)이 작기 때문에 물에 대한 용해도가 충분치 않게 되고 그 결과 용해시 많은 시간이 소요된다. 그리고 노즐 주변에 있는 잉크 조성물내의 수분이 증발되면 상술한 바와 같이 물에 대한 용해도가 작기 때문에 고분자가 석출되면서 노즐 구멍을 막을 우려가 있다. 이러한 바람직하지 못한 현상을 막기 위해서 추가적으로 흡습제를 사용해야 하는데, 이러한 흡습제의 사용은 지면에 인쇄되었을 때 잉크 건조시간을 연장시킨다는 문제점이 있다.However, since the polymer dispersant generally has a large molecular weight, it is very difficult to control the dispersant content in the ink composition because the physical properties (for example, viscosity) of the ink composition vary even if the addition amount is slightly changed. Even if a hydrophilic group is contained in the polymer, since the fraction of the hydrophilic group to the whole compound is small, the solubility in water becomes insufficient, resulting in a long time for dissolution. When the water content in the ink composition around the nozzle is evaporated, the solubility in water is low as described above, so that the polymer may precipitate and block the nozzle hole. In order to prevent such an undesirable phenomenon, it is necessary to additionally use a desiccant. The use of such a desiccant has a problem in that it causes the ink drying time to be prolonged when printed on the ground.

이러한 문제점을 해결하기 위하여 분산제로서 고분자대신 AB타입의 올리고머(여기에서, A는 반복성이 없는 단일성분으로서, 상기 안료와 작용하는 정착그룹을 나타내며, B부는 (C-D)_c-(E-F)_e-(H-I)_h-R₁와 같은 화학식으로 표현되는 반복단위로서, 친수성그룹을 나타냄)를 사용한 잉크젯트 프린팅용 잉크 조성물을 제안하였다.In order to solve such a problem, an AB type oligomer instead of a polymer as a dispersing agent, wherein A represents a fixing group acting as a single component having no repetition and acts on the pigment, and part B represents (CD) _c - (EF) _e - HI) _h- R ₁ , which is a repeating unit represented by the general formula, such as a hydrophilic group.

그런데, 상술한 바와 같은 AB타입의 올리고머를 함유하고 있는 잉크 조성물은 내광성, 내수성 및 저장성 특성은 우수하지만, 상기 올리고머를 제조하는 데 있어서 A부를 B부에 도입하는 데 장시간이 걸리거나 반응조건이 대단히 격렬해야 하는 등과 같은 어려운 점이 있다.However, the ink composition containing the AB type oligomer described above is excellent in light resistance, water resistance and storage property, but it takes a long time to introduce the A moiety into the B moiety in the production of the oligomer, There are difficulties such as being intense.

이에 본 발명자들은 상기한 문제점을 해결하기 위하여 제조하기가 용이한 헤테로 원자를 포함한 AB타입의 올리고머 분산제를 합성하고, 이를 이용한 잉크젯트 프린팅용 잉크 조성물에 관한 본원발명을 완성하기에 이르렀다.Accordingly, the inventors of the present invention have completed the present invention relating to an ink composition for inkjet printing using an AB type oligomer dispersant containing a hetero atom, which is easy to manufacture, in order to solve the above problems.

본 발명이 이루고자 하는 기술적 과제는 상기 문제점을 해결하여 제조하기가 용이하고 작용기가 갖고 있는 헤테로원자의 비공유전자쌍들에 의한 안료와의 향상된 반응으로 안료분산이 용이할 뿐만 아니라, 내광성, 내수성 및 우수한 저장성을 갖는 잉크 젯트 프린팅용 잉크 조성물을 제공하는 것이다.Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made in view of the above problems, and it is an object of the present invention to provide a pigment dispersant which is easy to produce and has a functional group, To provide an ink composition for ink jet printing.

상기 과제를 이루기 위하여 본 발명은 안료, 분산제 및 용매를 포함하는 잉크 젯트 프린터용 잉크 조성물에 있어서, 상기 분산제가 AB 타입의 올리고머(oligomer)인 것을 특징으로 하는 잉크 젯트 프린터용 잉크 조성물을 제공한다.In order to achieve the above object, the present invention provides an ink composition for an ink jet printer comprising a pigment, a dispersant and a solvent, wherein the dispersant is an AB type oligomer.

[여기에서, A부는 반복성이 없는 단일성분으로서,상기 안료와 작용하는 정착 그룹(anchoring group)을 나타내는데, C₁∼C₃₀알킬옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬옥시, C₁∼C₂₀알케닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐옥시, C₁∼C₃₀알키닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알키닐옥시, C₁∼C₃₀사이클로알킬옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬옥시, C₁∼C₃₀사이클로알케닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐옥시, C₁∼C₃₀사이클로알키닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐옥시, C₁∼C₃₀헤테로사이클로알킬옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬옥시, C₁∼C₃₀헤테로사이클로알케닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐옥시, C₁∼C₃₀헤테로사이클로알키닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐옥시, 단당류, 다당류 및 다당류 옥시, 솔비탄 옥시, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족 옥시 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족 옥시, C₁∼C₃₀알킬티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬티오, C₁∼C₃₀알케닐티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐티오, C₁∼C₃₀알키닐티올 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알키닐티오, C₁∼C₃₀사이클로알킬티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬티오, C₁∼C₃₀사이클로알케닐티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐티오, C₁∼C₃₀사이클로알키닐티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐티오, C₁∼C₃₀헤테로사이클로알킬티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬티오, C₁∼C₂₀헤테로사이클로알케닐티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐티오, C₁∼C₃₀헤테로사이클로알키닐티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐티오, 단당류, 다당류 및 다당류 티오, 솔비탄티오, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족티오 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족티오, C₁∼C₃₀알킬아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬아민, C₁∼C₃₀알킬옥시아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬옥시아민, C₁∼C₃₀알케닐 아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐아민, C₁∼C₃₀알키닐아민 또는 적어도 하나의 치환기(G)를 갖는 알키닐아민, C₁∼C₃₀사이클로알킬(cycloalkyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬아민, C₁∼C₃₀사이클로알케닐(cycloalkenyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐아민, C₁∼C₃₀사이클로알키닐(cycloalkynyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐아민, C₁∼C₃₀헤테로사이클로알킬(cycloalkyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬아민, C₁∼C₃₀헤테로사이클로알케닐(cycloalkenyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐아민, C₁∼C₃₀헤테로사이클로알키닐(cycloalkynyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐아민, 단당류, 이당류 및 다당류아민, 솔비탄(sorbitan)아민, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아민 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아민, C₁∼C₃₀알킬아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬아미드, C₁∼C₃₀알킬옥시아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬옥시아미드, C₁∼C₃₀알케닐아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐아미드, C₁∼C₃₀알키닐아미드 또는 적어도 하나의 치환기(G)를 갖는 알키닐아미드, C₁∼C₃₀사이클로알킬(cycloalkyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬아미드, C₁∼C₃₀사이클로알케닐(cycloalkenyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐아미드, C₁∼C₃₀사이클로알키닐(cycloalkynyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐아미드, C₁∼C₃₀헤테로사이클로알킬(cycloalkyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬아미드, C₁∼C₃₀헤테로사이클로알케닐(cycloalkenyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐아미드, C₁∼C₃₀헤테로사이클로알키닐(cycloalkynyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐아미드, 단당류, 이당류 및 다당류아미드, 솔비탄(sorbitan)아미드, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아미드 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아미드로 이루어진군으로부터 선택되고, (여기에서, 치환기(G)는 C₁∼C₃₀알킬, C₁∼C₃₀하이드록시알킬, C₁∼C₃₀하이드로티오알킬, C₁∼C₃₀니트로알킬, C₁∼C₃₀시아노알킬, C₁∼C₃₀티오시아노알킬, C₁∼C₃₀알킬옥시, C₁∼C₃₀알킬티오, C₁∼C₃₀알케닐, C₁∼C₃₀하이드록시알케닐, C₁∼C₃₀하이드로티오알케닐, C₁∼C₃₀니트로알케닐, C₁∼C₃₀시아노알케닐, C₁∼C₃₀티오시아노알케닐, C₁∼C₃₀알케닐옥시, C₁∼C₃₀알케닐티오, C₁∼C₃₀알키닐, C₁∼C₃₀하이드록시알키닐, C₁∼C₃₀하이드로티오알키닐, C₁∼C₃₀니트로알키닐, C₁∼C₃₀시아노알키닐, C₁∼C₃₀티오시아노알키닐, C₁∼C₃₀알키닐옥시, C₁∼C₃₀알키닐티오, C₁∼C₃₀사이클로알킬, C₁∼C₃₀하이드록시사이클로알킬, C₁∼C₃₀하이드로티오사이클로알킬, C₁∼C₃₀니트로사이크클로알킬, C₁∼C₃₀시아노사이클로알킬, C₁∼C₃₀티오시아노사이클로알킬, C₁∼C₃₀사이클로알킬옥시, C₁∼C₃₀사이클로알킬티오, C₁∼C₃₀사이클로알케닐, C₁∼C₃₀하이드록시사이클로알케닐, C₁∼C₃₀하이드로티오사이클로알케닐, C₁∼C₃₀니트로사이클로알케닐, C₁∼C₃₀시아노사이클로알케닐, C₁∼C₃₀티오시아노사이클로알케닐, C₁∼C₃₀사이클로알케닐옥시, C₁∼C₃₀사이클로알케닐티오, C₁∼C₃₀사이클로알키닐, C₁∼C₃₀하이드록시사이클로알키닐, C₁∼C₃₀하이드로티오사이클로알키닐, C₁∼C₃₀니트로사이클로알키닐, C₁∼C₃₀시아노사이클로알키닐, C₁∼C₃₀티오시아노사이클로알키닐, C₁∼C₃₀사이클로알키닐옥시, C₁∼C₃₀사이클로알키닐티오, C₁∼C₃₀헤테로사이클로알킬, C₁∼C₃₀하이드록시헤테로사이클로알킬, C₁∼C₃₀하이드로티오헤테로사이클로알킬, C₁∼C₃₀니트로헤테로사이크클로알킬, C₁∼C₃₀시아노헤테로사이클로알킬, C₁∼C₃₀티오시아노헤테로사이클로알킬, C₁∼C₃₀헤테로사이클로알킬옥시, C₁∼C₃₀헤테로사이클로알킬티오, C₁∼C₃₀헤테로사이클로알케닐, C₁∼C₃₀하이드록시헤테로사이클로알케닐, C₁∼C₃₀하이드로티오헤테로사이클로알케닐, C₁∼C₃₀니트로헤테로사이클로알케닐, C₁∼C₃₀시아노헤테로사이클로알케닐, C₁∼C₃₀티오시아노헤테로사이클로알케닐, C₁∼C₃₀헤테로사이클로알케닐옥시, C₁∼C₃₀헤테로사이클로알케닐티오, C₁∼C₃₀헤테로사이클로알키닐, C₁∼C₃₀하이드록시헤테로사이클로알키닐, C₁∼C₃₀하이드로티오헤테로사이클로알키닐, C₁∼C₃₀니트로헤테로사이클로알키닐, C₁∼C₃₀시아노헤테로사이클로알키닐, C₁∼C₃₀티오시아노헤테로사이클로알키닐, C₁∼C₃₀헤테로사이클로알키닐옥시, C₁∼C₃₀헤테로사이클로알키닐티오, C₆∼C₃₀의 방향족, C₆∼C₃₀의 치환된 방향족, 아미노, 치환된 아미노, 이민, 치환된 이민, 아미디노(amidino), 히드라진, 히드라존, 치환된 히드라진, 치환된 히드라존, 아미드, 치환된 아미드, 할라이드(halide), 하이드록시(OH), 니트로기(NO₂), 시아노(CN), 티오시아노(SCN), 티올(SH), 카르복실(COOH), 카르복실산의 알칼리염(COO^_M⁺, 여기에서 M은 알칼리금속임), 술폰산(SO₃H), 술폰산의 알칼리염(SO₃ ^-M^-, 여기에서 M은 알칼리금속임), 인산(H₃PO₄) 및 인산의 알칼리염(H₂PO₄ ^-M⁺, 여기에서 M은 알칼리금속임)으로 이루어진 군으로부터 선택됨); B부는 화학식 1의 구조식을 갖는다Wherein A is a non-repeatable, non-repeatable, anchoring group which reacts with the pigment, C ₁ -C ₃₀ alkyloxy or C ₁ -C ₃₀ alkyl having at least one substituent (G) oxy, C ₁ ~C ₂₀ alkenyloxy, or C ₁ ~ with at least one substituent (G) C ₁ ~C ₃₀ alkenyloxy, C ₁ ~C ₃₀ alkynyloxy or at least one substituent (G) having a C ₃₀ alkynyloxy, C ₁ ~C ₃₀ cycloalkyloxy or C ₁ ~C ₃₀ cycloalkyloxy, C ₁ ~C ₃₀ cycloalkyl alkenyloxy or at least one substituent (G) having at least one substituent (G) C ₁ -C ₃₀ cycloalkenyloxy, C ₁ -C ₃₀ cycloalkynyloxy or C ₁ -C ₃₀ cycloalkynyloxy having at least one substituent (G), C ₁ -C ₃₀ heterocycloalkyloxy Or C ₁ -C ₃₀ heterocycloalkyloxy having at least one substituent (G), C ₁ -C ₁ ~ C ₃₀ heterocycloalkyl having alkenyloxy or at least one substituent (G) C ₁ ~C ₃₀ heterocycloalkyl alkenyloxy, C ₁ ~C ₃₀ heterocycloalkyl alkynyloxy or at least one substituent (G) having a C ₃₀ heterocycloalkynyloxy, monosaccharides, polysaccharides and polysaccharides oxy, sorbitan oxy, C ₆ -C ₅₀ unsubstituted mono-, di-, tri- and polycyclic ring aromatic oxy or C ₆ ~C ₅₀ cyclic substituted mono, bi, tri and poly Whanin aromatic-oxy, C ₁ ~C ₃₀ alkylthio or at least one substituent (G) C ₁ ~C ₃₀ alkylthio, C ₁ ~C ₃₀ having an Al alkenyl thio or C ₁ ~C ₃₀ alkenyl, thio, C ₁ ~C ₃₀ alkynyl, thiol or C ₁ ~C ₃₀ alkynyl, thio having at least one substituent (G), C ₁ having at least one substituent (G) ~C ₃₀ cycloalkyl alkylthio or C ₁ having at least one substituent (G) Cycloalkyl C ₃₀ alkylthio, C ₁ ~C ₃₀ cycloalkenyl alkylthio or C ₁ ~C ₃₀ cycloalkenyl alkylthio, C ₁ ~C ₃₀ cycloalkyl alkynyl thio or at least one substituent having at least one substituent (G) ( G) a C ₁ ~C ₃₀ cycloalkyl alkynyl, thio, C ₁ ~C ₃₀ heterocycloalkyl alkylthio or having at least one substituent (G) C ₁ ~C ₃₀ heterocycloalkyl alkylthio, C ₁ ~C ₂₀ heterocycloalkyl having alkenyl thio or C ₁ ~C having at least one substituent (G) ₃₀ hetero cycloalkenyl alkylthio, C ₁ ~C ₃₀ heterocycloalkyl alkynyl thio or C ₁ ~C ₃₀ heteroaryl having at least one substituent (G) Polysaccharides and polysaccharides, thio, sorbitan thio, C ₆ -C ₅₀ unsubstituted mono-, di-, tri-, and polycyclic ring aromatic thio groups or C ₆ -C ₆ heteroaromatic groups having at least one substituent (G) ₅₀ substituted mono, bi, tri and poly Click Whanin aromatic thio, C ₁ ~C ₃₀ alkyl amine or C having at least one substituent (G) C ₁ ~C ₃₀ alkyl amines, C ₁ ~C ₃₀ alkyloxy amine or at least one substituent (G) having a ₁ ~C ₃₀ alkyloxy amines, C ₁ ~C ₃₀ alkenyl amine or at least one of substituents C ₁ ~C ₃₀ alkenyl amine having a (G), C ₁ ~C ₃₀ alkynyl amine or at least one of substituents (G C _{1 to} C ₃₀ cycloalkyl amines or C ₁ to C ₃₀ cycloalkylamines having at least one substituent (G), C _{1 to} C ₃₀ cycloalkenyl amines or C ₁ -C ₃₀ cycloalkenylamines having at least one substituent (G), C ₁ -C ₃₀ cycloalkynylamines or C ₁ -C ₃₀ cycloalkynylamines having at least one substituent (G) , ₁ ~C C ₃₀ heterocycloalkyl (cycloalkyl) C ₁ ~C ₃₀ with an amine or at least one substituent (G) Interrogating cycloalkyl amine, C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) amines, or at least one of substituents C ₁ ~C ₃₀ hetero cycloalkenyl amine having a (G), C ₁ ~C ₃₀ alkynyl heterocycloalkyl (cycloalkynyl Or C ₁ -C ₃₀ heterocycloalkenylamines, monosaccharides, disaccharides and polysaccharide amines having at least one substituent (G), sorbitan amines, C ₆ -C ₅₀ unsubstituted mono-, bi, tri and Aromatic amine which is a polycyclic ring or an aromatic amine which is a C ₆ -C ₅₀ substituted mono-, bi-, tri- and polycyclic ring having at least one substituent (G), a C ₁ -C ₃₀ alkylamide or at least one substituent C ₁ -C ₃₀ alkyl amides having at least one substituent (s), C ₁ -C ₃₀ alkyloxyamides or C ₁ -C ₃₀ alkyloxyamides having at least one substituent (G), C ₁ -C ₃₀ alkenyl amides or at least one C ₁ -C ₃₀ alkenyl amides having a substituent (G) , C ₁ -C ₃₀ alkynyl amides or C ₁ -C ₃₀ cycloalkyl amides having at least one substituent (G), C ₁ -C ₃₀ cycloalkyl amides or C ₁ -C ₃₀ cycloalkyl having at least one substituent (G) C ₁ -C ₃₀ cycloalkenyl amides or C ₁ -C ₃₀ cycloalkenyl amides having at least one substituent (G), C ₁ -C ₃₀ cycloalkynyl amides or at least one C ₁ ~C having a substituent group (G) of ₃₀ cycloalkyl alkynyl amide, C ₁ ~C ₃₀ heterocycloalkyl (cycloalkyl) amide, or at least one C ₁ ~C ₃₀ heterocycloalkyl amide having a substituent (G), C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) amide, or C ₁ ~C ₃₀ hetero cycloalkenyl amide, C ₁ ~C ₃₀ alkynyl heterocycloalkyl (cycloalkynyl) amide, or at least one having at least one substituent (G) of C ₁ having a substituent (G) C ₃₀ heterocycloalkyl alkynyl amides, monosaccharides, disaccharides, and polysaccharides, amide, sorbitan (sorbitan) amide, C ₆ ~C ₅₀ Beach cyclic mono, bi, tri, and poly-aromatic ring Whanin amide or at least one substituent (G) C ₆ ~C ₅₀ cyclic substituted mono, bi, tri and poly having Whanin is selected from the group consisting of aromatic amides (wherein the substituent (G) is a C ₁ ~C ₃₀ alkyl, C ₁ ~C ₃₀ Hyde hydroxyalkyl, C ₁ ~C ₃₀ dihydro-thioalkyl, C ₁ ~C ₃₀ alkyl nitro, C ₁ ~C ₃₀ cyanoalkyl, C ₁ ~C ₃₀ alkyl thio cyano, C ₁ ~C ₃₀ alkyloxy, C ₁ ~ C ₃₀ alkylthio, C ₁ ~C ₃₀ alkenyl, C ₁ ~C ₃₀ hydroxyalkyl alkenyl, C ₁ ~C ₃₀ alkenyl dihydro-thio, C ₁ ~C ₃₀ alkenyl, nitro, C ₁ ~C ₃₀ alkenyl cyano noal , C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ alkenyloxy, C ₁ ~C ₃₀ alkenyl, thio, C ₁ ~C ₃₀ alkynyl, C ₁ ~C ₃₀ hydroxyalkyl alkynyl , C ₁ ~C ₃₀ dihydro-thio alkynyl, C ₁ ~C ₃₀ alkynyl, nitro, C ₁ ~C _{30-cyano-alkynyl,} C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ alkynyloxy, C ₁ ~C ₃₀ alkynyl, thio, C ₁ ~C ₃₀ cycloalkyl, C ₁ ~C ₃₀ hydroxyalkyl cycloalkyl, C ₁ ~C ₃₀ cycloalkyl dihydro-thio, C ₁ ~C ₃₀ alkyl, nitro sayikeu chloride, C ₁ ~ C ₃₀ cycloalkyl, cyano, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ cycloalkyloxy, C ₁ ~C ₃₀ cycloalkyl alkylthio, C ₁ ~C ₃₀ cycloalkenyl, C ₁ ~C ₃₀ C _{1 to} C ₃₀ hydroxycycloalkenyl, C _{1 to} C ₃₀ hydrothiocycloalkenyl, C _{1 to} C ₃₀ nitrocycloalkenyl, C _{1 to} C ₃₀ cyanocycloalkenyl, C _{1 to} C ₃₀ thiocycloalkenyl, C _{1 to} C ₃₀ cycloalkenyloxy, C _{1 to} C ₃₀ cycloalkenylthio, C _{1 to} C ₃₀ cycloalkynyl, C _{1 to} C ₃₀ hydroxycycloalkenyl, C _{1 to} C ₃₀ lower Jethro thio cycloalkyl alkynyl, C ₁ ~C ₃₀ cycloalkyl alkynyl, nitro, C ₁ ~C _{30-cyano-alkynyl} cycloalkyl, C ₁ ~C ₃₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₃₀ cycloalkyl alkynyloxy, C ₁ ~C ₃₀ cycloalkyl alkynyl, thio, C ₁ ~C ₃₀ heterocycloalkyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl, C ₁ ~C ₃₀ dihydro-thio-heterocycloalkyl, C ₁ ~C ₃₀ alkyl, nitro heteroaryl sayikeu claw , C ₁ ~C _{30-cyano-heterocycloalkyl,} C ₁ ~C ₃₀ thio-dicyano-heterocycloalkyl, C ₁ ~C ₃₀ hetero cycloalkyloxy, C ₁ ~C ₃₀ heterocycloalkyl alkylthio, C ₁ ~C ₃₀ hetero C ₁ -C ₃₀ hydroxyheterocycloalkenyl, C ₁ -C ₃₀ hydrothioheterocycloalkenyl, C ₁ -C ₃₀ nitroheterocycloalkenyl, C ₁ -C ₃₀ cyanoheterocycloalkenyl , C ₁ -C ₃₀ thiocyanoheterocycloalkenyl, C ₁ ~C ₃₀ heterocycloalkyl alkenyloxy, C ₁ ~C ₃₀ hetero cycloalkenyl alkylthio, C ₁ ~C ₃₀ heterocycloalkyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkynyl, C ₁ ~C ₃₀ hetero-dihydro-thio alkynyl cycloalkyl, C ₁ ~C ₃₀ nitro heterocycloalkyl alkynyl, C ₁ ~C _{30-cyano-heterocycloalkyl} alkynyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkynyl, C ₁ ~C ₃₀ heterocycloalkyl alkynyloxy , C _{1 to} C ₃₀ heterocycloalkynylthio, C _{6 to} C ₃₀ aromatic, C _{6 to} C ₃₀ substituted aromatic, amino, substituted amino, imine, substituted imine, amidino, hydrazine, (OH), a nitro group (NO ₂ ), a cyano (CN), a thiocano (SCN), a thiol, a thiol (SH), carboxyl (COOH), carboxylic alkali salt of the carboxylic acid (COO ^_ M ^+, where M is an alkali metal Im), alcohol Acid (SO ₃ H), alkali salt of the sulfonic acid (SO ₃ ^{^-} M ^-, wherein M is an alkali metal Im), phosphoric acid (H ₃ PO ₄₎ and alkali salt of phosphoric acid _{_{^{^{(H 2 PO 4 - M +}}}} , where And M is an alkali metal); Part B has the structural formula (1)

[화학식 1][Chemical Formula 1]

(C-D)_c-(E-F)_e-(H-I)_h-R₁ (CD) _c - (EF) _e - (HI) _{h -} R ₁

상기식중, C, E 및 H는 서로 독립적으로 선택되며, C₁∼C₂₀알킬 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬, C₁∼C₂₀알케닐 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐, C₁∼C₂₀알키닐 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐, C₁∼C₂₀사이클로알킬(cycloalkyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬, C₁∼C₂₀사이클로알케닐(cycloalkenyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐, C₁∼C₂₀사이클로알키닐(cycloalkynyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐, C₁∼C₂₀헤테로사이클로알킬(cycloalkyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬, C₁∼C₂₀헤테로사이클로알케닐(cycloalkenyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐, C₁∼C₂₀헤테로사이클로알키닐(cycloalkynyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐, 단당류, 이당류 및 다당류, 솔비탄(sorbitan), C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족, C₁∼C₂₀알킬옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬옥시, C₁∼C₂₀알케닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐옥시, C₁∼C₂₀알키닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐옥시, C₁∼C₂₀사이클로알킬옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬옥시, C₁∼C₂₀사이클로알케닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐옥시, C₁∼C₂₀사이클로알키닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐옥시, C₁∼C₂₀헤테로사이클로알킬옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬옥시, C₁∼C₂₀헤테로사이클로알케닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐옥시, C₁∼C₂₀헤테로사이클로알키닐옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐옥시, 단당류, 다당류 및 다당류 옥시, 솔비탄 옥시, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족 옥시 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족 옥시, C₁∼C₂₀알킬티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬티오, C₁∼C₂₀알케닐티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐티오, C₁∼C₂₀알키닐티올 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐티오, C₁∼C₂₀사이클로알킬티올 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬티오, C₁∼C₂₀사이클로알케닐티올 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐티오, C₁∼C₂₀사이클로알키닐티올 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐티오, C₁∼C₂₀헤테로사이클로알킬티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬티오, C₁∼C₂₀헤테로사이클로알케닐티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐티오, C₁∼C₂₀헤테로사이클로알키닐티오 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐티오, 단당류, 다당류 및 다당류 티오, 솔비탄티오, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족티오 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족티오, C₁∼C₂₀알킬아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬아민, C₁∼C₂₀알킬옥시아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬옥시아민, C₁∼C₂₀알케닐 아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐아민, C₁∼C₂₀알키닐아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐아민, C₁∼C₂₀사이클로알킬(cycloalkyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬아민, C₁∼C₂₀사이클로알케닐(cycloalkenyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐아민, C₁∼C₂₀사이클로알키닐(cycloalkynyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐아민, C₁∼C₂₀헤테로사이클로알킬(cycloalkyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬아민, C₁∼C₂₀헤테로사이클로알케닐(cycloalkenyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐아민, C₁∼C₂₀헤테로사이클로알키닐(cycloalkynyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐아민, 단당류, 이당류 및 다당류아민, 솔비탄(sorbitan)아민, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아민 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족, C₁∼C₂₀알킬아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬아미드, C₁∼C₂₀알킬옥시아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬옥시아미드, C₁∼C₂₀알케닐아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐아미드, C₁∼C₂₀알키닐아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐아미드, C₁∼C₂₀사이클로알킬(cycloalkyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬아미드, C₁∼C₂₀사이클로알케닐(cycloalkenyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐아미드, C₁∼C₂₀사이클로알키닐(cycloalkynyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐아미드, C₁∼C₂₀헤테로사이클로알킬(cycloalkyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬아미드, C₁∼C₂₀헤테로사이클로알케닐(cycloalkenyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐아미드, C₁∼C₂₀헤테로사이클로알키닐(cycloalkynyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐아미드, 단당류, 이당류 및 다당류아미드, 솔비탄(sorbitan)아미드, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아미드 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아미드로 이루어진 군으로부터 선택되고, (여기에서, 치환기(G)는 C₁∼C₃₀알킬, C₁∼C₃₀하이드록시알킬, C₁∼C₃₀하이드로티오알킬, C₁∼C₃₀니트로알킬, C₁∼C₃₀시아노알킬, C₁∼C₃₀하이드로티오시아노알킬, C₁∼C₃₀알킬옥시, C₁∼C₃₀알킬티오, C₁∼C₃₀알케닐, C₁∼C₃₀하이드록시알케닐, C₁∼C₃₀티오알케닐, C₁∼C₃₀니트로알케닐, C₁∼C₃₀시아노알케닐, C₁∼C₃₀티오시아노알케닐, C₁∼C₃₀알케닐옥시, C₁∼C₃₀알케닐티오, C₁∼C₃₀알키닐, C₁∼C₃₀하이드록시알키닐, C₁∼C₃₀하이드로티오알키닐, C₁∼C₃₀니트로알키닐, C₁∼C₃₀시아노알키닐, C₁∼C₃₀티오시아노알키닐, C₁∼C₃₀알키닐옥시, C₁∼C₃₀알키닐티오, C₁∼C₃₀사이클로알킬, C₁∼C₃₀하이드록시사이클로알킬, C₁∼C₃₀하이드로티오사이클로알킬, C₁∼C₃₀니트로사이크클로알킬, C₁∼C₃₀시아노사이클로알킬, C₁∼C₃₀티오시아노사이클로알킬, C₁∼C₃₀사이클로알킬옥시, C₁∼C₃₀사이클로알킬티오, C₁∼C₃₀사이클로알케닐, C₁∼C₃₀하이드록시사이클로알케닐, C₁∼C₃₀하이드로티오사이클로알케닐, C₁∼C₃₀니트로사이클로알케닐, C₁∼C₃₀시아노사이클로알케닐, C₁∼C₃₀티오시아노사이클로알케닐, C₁∼C₃₀사이클로알케닐옥시, C₁∼C₃₀사이클로알케닐티오, C₁∼C₃₀사이클로알키닐, C₁∼C₃₀하이드록시사이클로알키닐, C₁∼C₃₀하이드로티오사이클로알키닐, C₁∼C₃₀니트로사이클로알키닐, C₁∼C₃₀시아노사이클로알키닐, C₁∼C₃₀티오시아노사이클로알키닐, C₁∼C₃₀사이클로알키닐옥시. C₁∼C₃₀사이클로알키닐티오, C₁∼C₃₀헤테로사이클로알킬, C₁∼C₃₀하이드록시헤테로사이클로알킬, C₁∼C₃₀하이드로티오헤테로사이클로알킬, C₁∼C₃₀니트로헤테로사이크클로알킬, C₁∼C₃₀시아노헤테로사이클로알킬, C₁∼C₃₀티오시아노헤테로사이클로알킬, C₁∼C₃₀헤테로사이클로알킬티오, C₁∼C₃₀헤테로사이클로알케닐, C₁∼C₃₀하이드록시헤테로사이클로알케닐, C₁∼C₃₀하이드로티오헤테로사이클로알케닐, C₁∼C₃₀니트로헤테로사이클로알케닐, C₁∼C₃₀시아노헤테로사이클로알케닐, C₁∼C₃₀티오시아노헤테로사이클로알케닐, C₁∼C₃₀헤테로사이클로알케닐티오, C₁∼C₃₀헤테로사이클로알키닐, C₁∼C₃₀하이드록시헤테로사이클로알키닐, C₁∼C₃₀티오헤테로사이클로알키닐, C₁∼C₃₀니트로헤테로사이클로알키닐, C₁∼C₃₀시아노헤테로사이클로알키닐, C₁∼C₃₀티오시아노헤테로사이클로알키닐, C₁∼C₃₀헤테로사이클로알키닐옥시, C₁∼C₃₀헤테로사이클로알키닐티오, C₆∼C₃₀의 방향족, C₆∼C₃₀의 치환된 방향족, 아미노, 치환된 아미노, 이민, 치환된 이민, 아미디노(amidino), 히드라진, 히드라존, 치환된 히드라진, 치환된 히드라존, 아미드, 치환된 아미드, 할라이드(halide), 하이드록시(OH), 니트로기(NO₂), 시아노(CN), 티오시아노(SCN), 티올(SH), 카르복실(COOH), 카르복실산의 알칼리염(COO^_M⁺, 여기에서 M은 알칼리금속임), 술폰산(SO₃H), 술폰산의 알칼리염(SO₃ ^-M^-, 여기에서 M은 알칼리금속임), 인산(H₃PO₄) 및 인산의 알칼리염(H₂PO₄ ^-M⁺, 여기에서 M은 알칼리금속임)으로 이루어진 군으로부터 선택됨); R₁은 수소 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬, C₁∼C₂₀알케닐, C₁∼C₂₀알키닐, C₁∼C₂₀사이클로알킬, C₁∼C₂₀사이클로알케닐, C₁∼C₂₀사이클로알키닐, C₁∼C₂₀헤테로사이클로알킬, C₁∼C₂₀헤테로사이클로알케닐, C₁∼C₂₀사이클로알키닐, 적어도 하나의 치환기(G)를 갖는 C₆∼C₃₀모노, 바이, 트라이 및 폴리사이클릭환인 방향족, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 사이클로알케닐, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 사이클로알키닐, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐, C₁∼C₂₀알킬, C₁∼C₂₀알케닐, C₁∼C₂₀알키닐, C₁∼C₂₀사이클로알킬, C₁∼C₂₀사이클로알케닐, C₁∼C₂₀사이클로알키닐, C₁∼C₂₀헤테로사이클로알킬, C₁∼C₂₀헤테로사이클로알케닐 및 C₁∼C₂₀헤테로사이클로알키닐로 이루어진 군으로부터 선택된 치환기와 적어도 하나의 치환기(G)를 갖는 C₆∼C₃₀방향족, C₁∼C₂₀알킬아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬아민, C₁∼C₂알킬옥시아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬옥시아민, C₁∼C₂₀알케닐아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐아민, C₁∼C₂₀알키닐아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐아민, C₁∼C₂₀사이클로알킬아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬아민, C₁∼C₂₀사이클로알케닐아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐아민, C₁∼C₂₀사이클로알키닐아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐아민, C₁∼C₂₀헤테로사이클로알킬아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬아민, C₁∼C₂₀헤테로사이클로알케닐아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐아민, C₁∼C₂₀헤테로사이클로알키닐아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐아민, C₆∼C₃₀모노, 바이, 트라이 및 폴리사이클릭환인 방향족아민 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₃₀모노, 바이, 트라이 및 폴리사이클릭환인 방향족아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐아민, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐아민, C₁∼C₂₀알킬, C₁∼C₂₀알킬옥시, C₁∼C₂₀알케닐, C₁∼C₂₀알키닐, C₁∼C₂₀사이클알킬, C₁∼C₂₀사이클로알케닐, C₁∼C₂₀사이클로알키닐, C₁∼C₂₀헤테로사이클로알킬, C₁∼C₂₀헤테로사이클로알케닐 및 C₁∼C₂₀헤테로사이클로알키닐로 이루어진 군으로부터 선택된 치환기와 적어도 하나의 치환기(G)를 갖는 C₆∼C₃₀방향족아민, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬옥시아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐아미드, 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐아미드 적어도 하나의 치환기를 갖는 C₆∼C₃₀모노, 바이, 트라이 및 폴리사이클릭환인 방향족 아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알킬아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알케닐아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀알키닐아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알킬아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알케닐아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀사이클로알키닐아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알킬아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알케닐아미드, C₆∼C₃₀방향족 치환기와 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀헤테로사이클로알키닐아미드, C₁∼C₂₀알킬, C₁∼C₂₀알케닐, C₁∼C₂₀알키닐, C₁∼C₂₀사이클로알킬, C₁∼C₂₀사이클로알케닐, C₁∼C₂₀사이클로알키닐, C₁∼C₂₀헤테로사이클로알킬, C₁∼C₂₀헤테로사이클로알케닐 및 C₁∼C₂₀헤테로사이클로알키닐중에서 선택된 치환기와 적어도 하나의 치환기(G)를 갖는 C₆∼C₃₀방향족아미드로 이루어진 군으로부터 선택되고, (여기에서, 치환기(G)는 C₁∼C₂₀하이드록시알킬, C₁∼C₂₀하이드록시알케닐, C₁∼C₂₀하이드록시알키닐, C₁∼C₂₀하이드록시사이클로알킬, C₁∼C₂₀하이드록시사이클로알케닐, C₁∼C₂₀하이드록시사이클로알키닐, C₁∼C₂₀하이드록시헤테로사이클로알킬, C₁∼C₂₀하이드록시헤테로사이클로알케닐, C₁∼C₂₀하이드록시헤테로사이클로알키닐, C₁∼C₂₀하이드로티오알킬, C₁∼C₂₀하이드로티오알케닐, C₁∼C₂₀하이드로티오알키닐, C₁∼C₂₀하이드로티오사이클로알킬, C₁∼C₂₀하이드로티오사이클로알케닐, C₁∼C₂₀하이드로티오사이클로알키닐, C₁∼C₂₀하이드로티오헤테로사이클로알킬, C₁∼C₂₀하이드로티오헤테로사이클로알케닐, C₁∼C₂₀하이드로티오헤테로사이클로알키닐, C₁∼C₂₀니트로알킬, C₁∼C₂₀니트로알케닐, C₁∼C₂₀니트로알키닐, C₁∼C₂₀니트로사이클로알킬, C₁∼C₂₀니트로사이클로알케닐, C₁∼C₂₀니트로사이클로알키닐, C₁∼C₂₀니트로헤테로사이클로알킬, C₁∼C₂₀니트로헤테로사이클로알케닐, C₁∼C₂₀니트로헤테로사이클로알키닐, C₁∼C₂₀시아노알킬, C₁∼C₂₀시아노알케닐, C₁∼C₂₀시아노알키닐, C₁∼C₂₀시아노사이클로알킬, C₁∼C₂₀시아노사이클로알케닐, C₁∼C₂₀시아노사이클로알키닐, C₁∼C₂₀시아노헤테로사이클로알킬, C₁∼C₂₀시아노헤테로사이클로알케닐, C₁∼C₂₀시아노헤테로사이클로알키닐, C₁∼C₂₀티오시아노알킬, C₁∼C₂₀티오시아노알케닐, C₁∼C₂₀티오시아노알키닐, C₁∼C₂₀티오시아노사이클로알킬, C₁∼C₂₀티오시아노사이클로알케닐, C₁∼C₂₀티오시아노사이클로알키닐, C₁∼C₂₀티오시아노헤테로사이클로알킬, C₁∼C₂₀티오시아노헤테로사이클로알케닐, C₁∼C₂₀티오시아노헤테로사이클로알키닐, C₁∼C₂₀아미노알킬, C₁∼C₂₀아미노알케닐, C₁∼C₂₀아미노알키닐, C₁∼C₂₀아미노사이클로알킬, C₁∼C₂₀아미노사이클로알케닐, C₁∼C₂₀아미노사이클로알키닐, C₁∼C₂₀아미노헤테로사이클로알킬, C₁∼C₂₀아미노헤테로사이클로알케닐, C₁∼C₂₀아미노헤테로사이클로알키닐, C₁∼C₂₀알칸산(alkanoic acid), C₁∼C₂₀알켄산, C₁∼C₂₀알킨산, C₁∼C₂₀사이클로알칸산, C₁∼C₂₀사이클로알켄산, C₁∼C₂₀사이클로알킨산, C₁∼C₂₀헤테로사이클로알칸산, C₁∼C₂₀헤테로사이클로알켄산, C₁∼C₂₀헤테로사이클로알킨산, C₆∼C₃₀하이드록시방향족, C₆∼C₃₀하이드로티오방향족, C₆∼C₃₀나이트로방향족, C₆∼C₃₀시아노방향족, C₆∼C₃₀방향족산, C₆∼C₃₀티오시아노방향족, C₆∼C₃₀아미노방향족, 아미노, 치환된 아미노, 이민, 치환된 이민, 아미디노(amidino), 히드라진, 치환된 히드라진, 히드라존, 치환된 히드라존, 아미드, 치환된 아미드, 할라이드(halide), 하이드록시(OH), 니트로기(NO₂), 시아노(CN), 티오시아노(SCN), 티올(SH), 카르복실(COOH), 카르복실산의 알칼리염(COO^_M⁺, 여기에서 M은 알칼리금속임), 술폰산(SO₃H), 술폰산의 알칼리염(SO₃ ^-M^-, 여기에서 M은 알칼리금속임), 인산(H₃PO₄) 및 인산의 알칼리염(H₂PO₄ ^-M⁺, 여기에서 M은 알칼리금속임)으로 이루어진 군으로부터 선택됨); D, F 및 I는 서로 독립적으로 선택되며, 산소(O), 황(S), 인(P) 및 질소(N)로 이루어진 군으로부터 선택된 헤테로원자이고, 단, 0≤c≤30, 0≤e≤30, 0≤h≤30, 0＜c+e+h＜60임].Wherein C, E and H are independently selected from C ₁ -C ₂₀ alkyl or C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkenyl having at least one substituent (G), or at least one C ₁ -C ₂₀ alkenyl having a substituent (G), C ₁ -C ₂₀ alkynyl or C ₁ -C ₂₀ alkynyl having at least one substituent (G), C ₁ -C ₂₀ cycloalkyl or C ₁ ~C ₂₀ cycloalkyl, C ₁ ~C ₂₀ cycloalkenyl (cycloalkenyl) or C ₁ ~C ₂₀ cycloalkenyl having at least one substituent (G), C ₁ ~ with at least one substituent (G) C ₂₀ cycloalkyl alkynyl (cycloalkynyl) or C ₁ ~C ₂₀ cycloalkyl alkynyl, C ₁ ~C ₂₀ heterocycloalkyl (cycloalkyl) or C ₁ having at least one substituent (G) having at least one substituent (G) ~C ₂₀ heterocycloalkyl, C ₁ ~C ₂₀ hetero cycloalkenyl (cycloalkenyl) or C ₁ ~C ₂₀ H. having at least one substituent (G) C ₁ -C ₂₀ heterocycloalkynyl or C ₁ -C ₂₀ heterocycloalkynyl, monosaccharides, disaccharides and polysaccharides having at least one substituent (G), sorbitan, C ₆ ~C ₅₀ unsubstituted mono-, bi-, tri and polycyclic aromatic Whanin or C ₆ ~C ₅₀ cyclic substituted mono, bi, tri and poly having at least one substituent (G) Whanin aromatic, C ₁ ~ C ₂₀ alkyloxy or at least one substituent (G) C ₁ ~C ₂₀ alkyloxy, C ₁ ~C ₂₀ alkenyloxy or at least one C ₁ ~C ₂₀ alkenyl group having a substituent (G) having an oxy, C ₁ ~C ₂₀ alkynyloxy or C ₁ ~C having at least one substituent (G) ₂₀ alkynyloxy, C ₁ ~C ₂₀ cycloalkyloxy or C ₁ ~C ₂₀ cycloalkyl having at least one substituent (G) alkyloxy, C ₁ ~C ₂₀ cycloalkenyl C ₁ having an oxy or at least one substituent (G) Cycloalkyl C ₂₀ alkenyloxy, C ₁ ~C ₂₀ cycloalkyl alkynyloxy or C ₁ ~C having at least one substituent (G) ₂₀ cycloalkyl alkynyloxy, C ₁ ~C ₂₀ hetero cycloalkyloxy or at least one substituent C ₁ ~C having a (G) _{20-heterocycloalkyl-oxy,} C ₁ ~C ₂₀ heterocycloalkyl alkenyloxy or C ₁ ~C ₂₀ heterocycloalkyl alkenyloxy having at least one substituent (G), C ₁ ~C ₂₀ heterocycloalkyl alkynyloxy or C ₁ ~C having at least one substituent (G) ₂₀ heterocycloalkyl alkynyloxy, monosaccharides, polysaccharides and polysaccharide oxy, sorbitan aryloxy, C ₆ ~C ₅₀ unsubstituted mono-, bi-, Aromatic oxy which is a tri- and polycyclic ring or aromatic oxy, which is a C ₆ -C ₅₀ substituted mono-, bi-, tri- and polycyclic ring having at least one substituent (G), C ₁ -C ₂₀ alkylthio or at least one substituent C ₁ ~C ₂₀ having a (G) Kill alkylthio, C ₁ ~C ₂₀ alkenyl alkenyl thio or C ₁ ~C ₂₀ Al having at least one substituent (G) thio, C ₁ ~C ₂₀ alkynyl, thiol or C ₁ having at least one substituent (G) ~C ₂₀ alkynyl, thio, C ₁ ~C ₂₀ cycloalkyl, thiol or C ₁ ~C ₂₀ cycloalkyl alkylthio, C ₁ ~C ₂₀ cycloalkenyl thiol or at least one substituent group having at least one substituent (G) (G C ₁ -C ₂₀ cycloalkenylthio, C ₁ -C ₂₀ cycloalkynylthiol or C ₁ -C ₂₀ cycloalkynylthio having at least one substituent (G), C ₁ -C ₂₀ heterocycloalkyl alkylthio or C ₁ ~C ₂₀ heterocycloalkyl alkylthio, C ₁ ~C ₂₀ hetero cycloalkenyl alkylthio or C ₁ ~C ₂₀ hetero cycloalkenyl having at least one substituent (G) having at least one substituent (G) Thio, C ₁ -C ₂₀ heterocycloalkynylthio, or at least one substituent (G) Is selected from the group consisting of C ₁ -C ₂₀ heterocycloalkynylthio, monosaccharides, polysaccharides and polysaccharides thio, sorbitan thio, C ₆ -C ₅₀ unsubstituted mono-, bi, tri and polycyclic ring aromatic thio or at least one substituent G ) having a C ₆ ~C ₅₀ between the substituted mono, bi, tri and poly click Whanin aromatic thio, C ₁ ~C ₂₀ alkyl amine or C ₁ ~C ₂₀ alkyl amine having at least one substituent (G), C ₁ ~C ₂₀ alkyloxy amine or C ₁ ~C ₂₀ alkyloxy amines, C ₁ ~C ₂₀ alkenyl amine or a C ₁ ~C ₂₀ alkenyl group having at least one substituent (G) having at least one substituent (G) amine, C ₁ ~C ₂₀ alkynyl or amine having at least one substituent (G) C ₁ ~C ₂₀ alkynyl amines, C ₁ ~C ₂₀ cycloalkyl, (cycloalkyl) amine or at least one substituent (G) having a C ₁ -C ₂₀ cycloalkylamine, C ₁ -C ₂₀ cycloalkenyl amine or at least one Substituents (G) having a C ₁ ~C ₂₀ cycloalkenyl amine, C ₁ ~C ₂₀ cycloalkyl alkynyl (cycloalkynyl) C ₁ ~C ₂₀ cycloalkyl alkynyl amine, C ₁ having the amine or at least one substituent (G) ~C ₂₀ heterocycloalkyl (cycloalkyl) amine or at least one C ₁ ~C ₂₀ heterocycloalkyl amine having a substituent (G), C ₁ ~C ₂₀ hetero cycloalkenyl (cycloalkenyl) amines, or at least one of substituents (G ), the C ₁ ~C ₂₀ hetero cycloalkenyl amine, C ₁ ~C ₂₀ alkynyl heterocycloalkyl (cycloalkynyl) or C ₁ ~C ₂₀ heterocycloalkyl alkynyl amine, monosaccharide, disaccharide having at least one substituent (G) having and polysaccharides, amines, sorbitan (sorbitan) amine, C ₆ ~C ₅₀ Beach C ₆ ~C ₅₀ mono-substituted with an unsubstituted mono-, bi-, tri and polycyclic Whanin aromatic amine or at least one substituent (G), Aromatic, polycyclic ring of C ₁ -C ₂₀ Alkyl amide or C ₁ ~C having at least one substituent (G) ₂₀ alkylamide, C ₁ ~C ₂₀ alkyloxy amide or C ₁ ~C ₂₀ alkyloxy amides having at least one substituent (G), C ₁ ~ C ₂₀ alkenyl amides or C ₁ -C ₂₀ alkenyl amides having at least one substituent (G), C ₁ -C ₂₀ alkynyl amides or C ₁ -C ₂₀ alkynyl amides having at least one substituent (G) C ₁ -C ₂₀ cycloalkyl amide or C ₁ -C ₂₀ cycloalkyl amide having at least one substituent (G), C ₁ -C ₂₀ cycloalkenyl amide or at least one substituent (G ) having a C ₁ ~C ₂₀ cycloalkyl alkenyl amides, C ₁ ~C ₂₀ cycloalkyl alkynyl (cycloalkynyl) amide, or C ₁ ~C ₂₀ cycloalkyl alkynyl amide, C ₁ ~C ₂₀ having at least one substituent (G) A cycloalkyl amide or C ₁ < RTI ID = 0.0 > ~C ₂₀ heterocycloalkyl amide, C ₁ ~C ₂₀ hetero cycloalkenyl (cycloalkenyl) amide, or at least one C ₁ ~C ₂₀ hetero cycloalkenyl amide having a substituent (G), C ₁ ~C ₂₀ alkynyl heterocycloalkyl Cycloalkynyl amides or C ₁ -C ₂₀ heterocycloalkynyl amides, monosaccharides, disaccharides and polysaccharide amides having at least one substituent (G), sorbitan amide, C ₆ -C ₅₀ unsubstituted mono, Aromatic amide which is a mono-, bi-, tri- and polycyclic ring, or an aromatic amide which is a C ₆ -C ₅₀ substituted mono-, bi, tri and polycyclic ring having at least one substituent (G) substituents (G) is a C ₁ ~C ₃₀ alkyl, C ₁ ~C ₃₀ hydroxyalkyl, C ₁ ~C ₃₀ dihydro-thioalkyl, C ₁ ~C ₃₀ alkyl nitro, C ₁ ~C ₃₀ cyanoalkyl, C ₁ ~ C ₃₀ dihydro-dicyano thio alkyl, C ₁ ~C ₃₀ alkyloxy C ₁ -C ₃₀ alkylthio, C ₁ -C ₃₀ alkenyl, C ₁ -C ₃₀ hydroxyalkenyl, C ₁ -C ₃₀ thioalkenyl, C ₁ -C ₃₀ nitroalkenyl, C ₁ -C cyano noal ₃₀ alkenyl, C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ alkenyloxy, C ₁ ~C ₃₀ alkenyl, thio, C ₁ ~C ₃₀ alkynyl, C ₁ ~C ₃₀ hydroxyalkyl alkynyl carbonyl, C ₁ ~C ₃₀ dihydro-thio alkynyl, C ₁ ~C ₃₀ alkynyl, nitro, C ₁ ~C _{30-cyano-alkynyl,} C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ alkynyloxy , C ₁ -C ₃₀ alkynylthio, C ₁ -C ₃₀ cycloalkyl, C ₁ -C ₃₀ hydroxycycloalkyl, C ₁ -C ₃₀ hydrothiocycloalkyl, C ₁ -C ₃₀ nitrocycloalkyl, C ₁ ~C ₃₀ cycloalkyl, cyano, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ cycloalkyloxy, C ₁ ~C ₃₀ cycloalkyl alkylthio, C ₁ ~C ₃₀ cycloalkenyl, C ₁ ~C ₃₀ hydroxy cycloalkenyl, C ₁ ~C ₃₀ dihydro-thio four Claw alkenyl, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C _30-cyano cycloalkenyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkenyloxy, C ₁ ~ C ₃₀ cycloalkenyl alkylthio, C ₁ ~C ₃₀ cycloalkyl alkynyl, C ₁ ~C ₃₀ hydroxycyclohexyl alkynyl, C ₁ ~C ₃₀ dihydro-thio-alkynyl cycloalkyl, C ₁ ~C ₃₀ cycloalkyl alkynyl, nitro, C ₁ ~C _{30-cyano-alkynyl} cycloalkyl, C ₁ ~C ₃₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₃₀ cycloalkyl alkynyloxy. C ₁ -C ₃₀ cycloalkynylthio, C ₁ -C ₃₀ heterocycloalkyl, C ₁ -C ₃₀ hydroxyheterocycloalkyl, C ₁ -C ₃₀ hydrothioheterocycloalkyl, C ₁ -C ₃₀ nitroheterocycloalkyl alkyl, C ₁ ~C _{30-cyano-heterocycloalkyl,} C ₁ ~C ₃₀ thio-dicyano-heterocycloalkyl, C ₁ ~C ₃₀ heterocycloalkyl alkylthio, C ₁ ~C ₃₀ alkenyl heterocycloalkyl, C ₁ ~C ₃₀ hydroxy-alkenyl heterocycloalkyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkenyl, C ₁ ~C ₃₀ hetero nitro cycloalkenyl, C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C ₃₀ thio-dicyano C _{1 to} C ₃₀ heterocycloalkenyl, C _{1 to} C ₃₀ heterocycloalkenylthio, C _{1 to} C ₃₀ heterocycloalkynyl, C _{1 to} C ₃₀ hydroxyheterocycloalkynyl, C _{1 to} C ₃₀ thioheterocycloalkynyl, C ₁ ~C ₃₀ nitro heterocycloalkyl alkynyl, C ₁ ~C ₃₀ C ₁ -C ₃₀ thiocyanoheterocycloalkynyl, C ₁ -C ₃₀ heterocycloalkynyloxy, C ₁ -C ₃₀ heterocycloalkynylthio, C ₆ -C ₃₀ aromatic, C ₆ -C ₃₀ substituted aromatic, amino, substituted amino, imine, substituted imine, amidino, hydrazine, hydrazone, substituted hydrazine, substituted hydrazone, amide, substituted amide, halide halide), hydroxy (OH), nitro group (nO _2), cyano (CN), thio-dicyano (SCN), thiol (SH), carboxyl (COOH), alkali salts of carboxylic acid (COO ^_ M ⁺ , Where M is an alkali metal), sulfonic acid (SO ₃ H), alkali salts of sulfonic acids (SO ₃ ^- M ^- where M is an alkali metal), phosphoric acid (H ₃ PO ₄ ) (H ₂ PO ₄ ^- M ⁺ , wherein M is an alkali metal); R ₁ is C ₁ ~C ₂₀ alkyl, C ₁ ~C ₂₀ alkenyl, C ₁ ~C ₂₀ alkynyl, C ₁ ~C ₂₀ cycloalkyl, C ₁ ~C ₂₀ having a hydrogen or at least one substituent (G) C ₁ -C ₂₀ cycloalkenyl, C ₁ -C ₂₀ cycloalkynyl, C ₁ -C ₂₀ heterocycloalkyl, C ₁ -C ₂₀ heterocycloalkenyl, C ₁ -C ₂₀ cycloalkynyl, and at least one substituent (G) C ₆ ~C ₃₀ mono-, bi-cyclic, tri and poly Whanin _{_{_{aromatic, C 6 ~C 30 C 1 ~C}}} 20 alkyl having at least one substituent (G) with an aromatic substituent, C ₆ ~C ₃₀ aromatic substituent at least C ₁ -C ₂₀ alkenyl having one substituent (G), C ₁ -C ₂₀ alkynyl having a C ₆ -C ₃₀ aromatic substituent and at least one substituent (G), a C ₆ -C ₃₀ aromatic substituent and at least C ₁ ~C ₂₀ cycloalkyl, C ₆ ~C ₃₀ aromatic substituent, and cycloalkenyl having at least one substituent (G), C ₆ ~C ₃₀ room having one substituent (G) Cycloalkynyl having a phenyl substituent and at least one substituent (G), C ₁ -C ₂₀ heterocycloalkyl having a C ₆ -C ₃₀ aromatic substituent and at least one substituent (G), a C ₆ -C ₃₀ aromatic substituent and at least one C ₁ ~C ₂₀ hetero cycloalkenyl having substituent _{_{(G), C 6 ~C 30}} C 1 ~C having at least one substituent (G) and an aromatic heterocycle substituent ₂₀ alkynyl, C ₁ ~C ₂₀ alkyl, C ₁ ~C ₂₀ alkenyl, C ₁ ~C ₂₀ alkynyl, C ₁ ~C ₂₀ cycloalkyl, C ₁ ~C ₂₀ cycloalkenyl, C ₁ ~C ₂₀ cycloalkyl alkynyl, C ₁ ~C ₂₀ heterocycloalkyl, C ₁ ~C ₂₀ hetero cycloalkenyl, and C ₁ ~C ₂₀ C ₆ having at least one substituent (G) and the substituent from the group consisting of alkynyl heterocycloalkyl ~C ₃₀ aromatic, C ₁ ~C ₂₀ alkylamine or a C ₁ -C ₂₀ alkylamine having at least one substituent (G), a C ₁ -C ₂ alkyloxyamine Or C ₁ ~C ₂₀ alkyloxy amines, C ₁ ~C ₂₀ alkenyl amine or a C ₁ ~C ₂₀ alkenyl amine having at least one substituent (G), C ₁ ~C having at least one substituent (G) ₂₀ alkynylamines or C ₁ -C ₂₀ alkynylamines having at least one substituent (G), C ₁ -C ₂₀ cycloalkylamines or C ₁ -C ₂₀ cycloalkylamines having at least one substituent (G) C ₁ ~C ₂₀ cycloalkenyl amine or at least one substituent (G) C ₁ ~C ₂₀ cycloalkenyl having alkenyl amine, C ₁ ~C ₂₀ cycloalkyl alkynyl amine or a C ₁ having at least one substituent (G) ~C ₂₀ cycloalkyl alkynyl amine, C ₁ ~C ₂₀ alkyl amine or heterocycloalkyl C ₁ ~C ₂₀ heterocycloalkyl amine having at least one substituent (G), C ₁ ~C ₂₀ hetero cycloalkenyl amine, or at least one a C ₁ ~C ₂₀ hetero cycloalkenyl having substituent (G) amine, C ₁ ~C ₂₀ hetero Inc. Claw alkynyl amine or a C ₁ ~C ₂₀ heterocycloalkyl alkynyl amine, C ₆ ~C ₃₀ mono, bi, tri and polycyclic Whanin aromatic amine or at least one substituent (G) having at least one substituent (G) C ₆ ~C ₃₀ mono, bi, tri and polycyclic aromatic amines having Whanin, C ₆ ~C ₃₀ aromatic substituted with C ₁ ~C ₂₀ alkyl amines, C ₆ ~C ₃₀ having at least one substituent (G) alkenyl C ₁ ~C ₂₀ Al having at least one substituent (G) with an aromatic amine substituent, C ₆ ~C ₃₀ aromatic substituted with C ₁ ~C having at least one substituent (G) ₂₀ alkynyl amines, C ₆ ~ C ₃₀ aromatic substituent, and at least one substituent (G) a C ₁ ~C ₂₀ cycloalkyl amine, C ₆ ~C ₃₀ aromatic substituted with at least one substituent (G) C ₁ ~C ₂₀ cycloalkenyl having alkenyl amine having, C ₆ ~C ₃₀ aromatic substituted with C ₁ ~C ₂₀ cycloalkenyl having at least one substituent (G) Carbonyl amine, C ₁ ~ C ₆ ~C ₃₀ aromatic substituent having at least one substituent (G) at least one substituent (G), and C ₁ ~C ₂₀ hetero cycloalkyl amine, C ₆ ~C ₃₀ aromatic substituent having C ₂₀ heterocycloalkenylamines, C ₁ -C ₂₀ heterocycloalkynylamines having a C ₆ -C ₃₀ aromatic substituent and at least one substituent (G), C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyloxy , C ₁ -C ₂₀ alkenyl, C ₁ -C ₂₀ alkynyl, C ₁ -C ₂₀ cycloalkyl, C ₁ -C ₂₀ cycloalkenyl, C ₁ -C ₂₀ cycloalkynyl, C ₁ -C ₂₀ heterocyclo A C ₆ -C ₃₀ aromatic amine having at least one substituent (G) with a substituent selected from the group consisting of alkyl, C ₁ -C ₂₀ heterocycloalkenyl and C ₁ -C ₂₀ heterocycloalkynyl, at least one substituent G) C ₁ ~C ₂₀ alkyloxy amide having a C ₁ ~C ₂₀ alkyl amide, at least one substituent (G) having the note C ₁ ~C ₂₀ cycloalkyl having one substituent (G) C ₁ ~C ₂₀ alkenyl amide, at least one substituent (G) C ₁ ~C ₂₀ alkynyl amide, at least one substituent (G) having a having a Alkyl amide, a C ₁ -C ₂₀ cycloalkenyl amide having at least one substituent (G), a C ₁ -C ₂₀ cycloalkynyl amide having at least one substituent (G), at least one substituent (G) C ₁ -C ₂₀ heterocycloalkylamides, C ₁ -C ₂₀ heterocycloalkenylamides having at least one substituent (G), C ₁ -C ₂₀ heterocycloalkynylamides having at least one substituent (G) C ₆ ~C ₃₀ having one substituent mono, bi, tri and polycyclic aromatic amide _{_{_{Whanin, C 6 ~C 30 C 1 ~C}}} 20 alkyl amide having at least one substituent (G) with an aromatic substituent, C ₆ (C) having at least one substituent (G) and a C ₃₀ aromatic substituent ₁ ~C ₂₀ alkenyl amides, C ₆ ~C ₃₀ aromatic substituted with at least one substituent (G) C ₁ ~C ₂₀ alkynyl amides, C ₆ ~C ₃₀ aromatic substituted with at least one substituent (G) having a having C ₁ ~C ₂₀ cycloalkyl amide, C ₆ ~C ₃₀ aromatic substituent, and at least a C ₁ ~C ₂₀ cycloalkenyl amide, C ₆ ~C ₃₀ aromatic substituted with at least one substituent having one substituent (G) ( G) a C ₁ ~C ₂₀ cycloalkyl alkynyl amide, C ₆ ~C ₃₀ aromatic substituted with at least one substituent (G) a C ₁ ~C ₂₀ heterocycloalkyl amide, C ₆ ~C ₃₀ aromatic substituent having at least having C ₁ ~C ₂₀ hetero cycloalkenyl amide, C ₆ ~C ₃₀ aromatic substituted with at least one C ₁ ~C ₂₀ heterocycloalkyl alkynyl amide having a substituent (G), C ₁ ~ having one substituent (G) C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkenyl, C ₁ -C ₂₀ alkynyl, C ₁ -C ₂₀ cycloalkyl, C ₁ -C ₂₀ cycloalkenyl, C ₁ ~C ₂₀ cycloalkyl alkynyl, C ₁ ~C ₂₀ heterocycloalkyl, C ₁ ~C ₂₀ alkenyl heterocycloalkyl and heterocycloalkyl C ₁ ~C ₂₀ alkynyl substituted with at least one substituent selected from the group consisting of (G) selected from the group consisting of a C ₆ ~C ₃₀ aromatic amide, and having a (wherein the substituent (G) is a C ₁ ~C ₂₀ hydroxyalkyl, C ₁ ~C ₂₀ hydroxyalkyl alkenyl, C ₁ ~ C ₂₀ hydroxy alkynyl, C ₁ ~C ₂₀ hydroxyalkyl cycloalkyl, C ₁ ~C ₂₀ hydroxy cycloalkenyl, C ₁ ~C ₂₀ hydroxycyclohexyl alkynyl, C ₁ ~C ₂₀ hydroxyalkyl heterocycloalkyl, C ₁ ~C ₂₀ hydroxyalkyl heterocycloalkyl alkenyl, C ₁ ~C ₂₀ hydroxyalkyl heterocycloalkyl alkynyl, C ₁ ~C ₂₀ dihydro-thioalkyl, C ₁ ~C ₂₀ alkenyl dihydro-thio, C ₁ ~C ₂₀ dihydro-thio alkynyl, C ₁ ~C ₂₀ cycloalkyl dihydro-thio, C ₁ ~C ₂₀ Hyde Thio cycloalkenyl, C ₁ ~C ₂₀ dihydro-thio-alkynyl cycloalkyl, C ₁ ~C ₂₀ dihydro-thio-heterocycloalkyl, C ₁ ~C ₂₀ dihydro-thio heterocycloalkyl alkenyl, C ₁ ~C ₂₀ dihydro-thio-alkynyl heterocycloalkyl , C ₁ ~C ₂₀ alkyl nitro, C ₁ ~C ₂₀ alkenyl, nitro, C ₁ ~C ₂₀ alkynyl, nitro, C ₁ ~C ₂₀ cycloalkyl nitro, C ₁ ~C ₂₀ nitro cycloalkenyl, C ₁ ~C _{20-nitro-alkynyl} cycloalkyl, C ₁ ~C _{20-nitro-heterocycloalkyl,} C ₁ ~C ₂₀ hetero nitro cycloalkenyl, C ₁ ~C ₂₀ nitro heterocycloalkyl alkynyl, C ₁ ~C ₂₀ cyanoalkyl, C ₁ ~ alkenyl C ₂₀ noal cyano, C ₁ ~C _{20-cyano-alkynyl,} C ₁ ~C ₂₀ cycloalkyl, cyano, C ₁ ~C _20-cyano cycloalkenyl, C ₁ ~C ₂₀ cycloalkyl cyano alkynyl, C ₁ ~C _{20-cyano-heterocycloalkyl,} C ₁ ~C ₂₀ hetero cycloalkenyl cyano, C ₁ ~C ₂₀ hetero-cyano Cycle to alkynyl, C ₁ ~C ₂₀ alkyl thio cyano, C ₁ ~C ₂₀ thio-dicyano alkenyl, C ₁ ~C ₂₀ thio-dicyano alkynyl, C ₁ ~C ₂₀ thio-dicyano-cycloalkyl, C ₁ ~C ₂₀ thio-dicyano cycloalkenyl, C ₁ ~C ₂₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₂₀ thio-dicyano-heterocycloalkyl, C ₁ ~C ₂₀ thio-dicyano heterocycloalkyl alkenyl, C ₁ ~ C ₂₀ alkylthio-dicyano heterocycloalkyl alkynyl, C ₁ ~C ₂₀ aminoalkyl, C ₁ ~C ₂₀ alkenyl, amino, C ₁ ~C ₂₀ amino alkynyl, C ₁ ~C ₂₀ cycloalkyl-amino, C ₁ ~C ₂₀ amino cycloalkenyl, C ₁ ~C ₂₀ cycloalkyl amino alkynyl, C ₁ ~C ₂₀ amino heterocycloalkyl, C ₁ ~C ₂₀ amino heterocycloalkyl alkenyl, C ₁ ~C ₂₀ amino heterocycloalkyl alkynyl, C ₁ ~ C ₂₀ alkanoic acid _{(alkanoic acid), C 1 ~C} 20 Al kensan, C ₁ ~C ₂₀ alkynyl acids, C ₁ ~C ₂₀ cycloalkyl alkanoic acid, C ₁ ~C ₂₀ kensan cycloalkenyl, C ₁ ~C ₂₀ Cycle as acid alkynyl, C ₁ ~C ₂₀ heterocycloalkyl alkanoic acid, C ₁ ~C ₂₀ hetero cycloalkenyl kensan, C ₁ ~C ₂₀ alkynyl heterocycloalkyl acid, C ₆ ~C ₃₀ aromatic hydroxy, C ₆ ~C ₃₀ Hydro Thioaromatic, C ₆ -C ₃₀ nitroaromatic, C ₆ -C ₃₀ cyanoaromatic, C ₆ -C ₃₀ aromatic acid, C ₆ -C ₃₀ thiocanoaromatic, C ₆ -C ₃₀ aminoaromatic, amino, substituted (OH), a nitro group (NO), a substituted amino group, an imine, a substituted imine, an amidino, a hydrazine, a substituted hydrazine, a hydrazone, a substituted hydrazone, an amide, a substituted amide, a halide, _2), cyano (CN), thio-dicyano (SCN), thiol (SH), carboxyl (COOH), carboxylic alkali salt of the carboxylic acid (COO ^_ M ^+, where M are the alkali metals), acid ( SO ₃ H), an alkali salt of a sulfonic acid (SO ₃ ^- M ^- where M is an alkali metal), phosphoric acid (H ₃ PO ₄ ) and an alkali salt of phosphoric acid (H ₂ PO ₄ ^- M ⁺ Alkali metal) Selected from the group consisting of); D, F and I are independently selected from each other and are a heteroatom selected from the group consisting of oxygen (O), sulfur (S), phosphorus (P) and nitrogen (N) 30, 0? h? 30, 0 <c + e + h <60].

상술한 AB타입의 올리고머는 B부와 결합되는 A부 영역에 헤테로원자 성분이 존재하기 때문에 합성이 용이하며, A부의 헤테로원자가 갖고 있는 비공유전자쌍이 올리고머 분산제의 직용기인 A부의 입체구조를 안료와 작용하기 유리하게 형성시킬 뿐만 아니라 직접 안료입자와 반응하므로 안료분산이 더욱 용이해진다.Since the AB type oligomer described above has a heteroatom component in the A moiety bonded to the B moiety, it is easy to synthesize, and a three-dimensional structure of the A moiety, in which the non-covalent electron pair having the hetero atom of A moiety is a homopolymer of the oligomer dispersant, But also reacts directly with the pigment particles, so that pigment dispersion becomes easier.

본 발명의 잉크 조성물에서는 정착그룹(A부)와 친수성그룹(B부)을 갖는 올리고머에 의하여 안료가 용매에 안정하게 분산되어 있다. 올리고머 분산제에서 상기 정착그룹은 안료와의 화학적 친화력(chemical affinity) 등의 반응성을 향상시켜주는 역할을 하며, 흡착성을 증가하기 위하여 이 정착그룹에 산성이나 염기성을 띠는 그룹, 티올기, 시아노기, 이소시아노기, 질화(nitride)기 등과 치환기를 도입할 수 있다.In the ink composition of the present invention, the pigment is stably dispersed in the solvent by the oligomer having the fixing group (A portion) and the hydrophilic group (B portion). In the oligomer dispersant, the fixing group serves to improve the reactivity such as chemical affinity with the pigment. In order to increase the adsorption property, the fixing group includes an acid group or a basic group, a thiol group, a cyano group, An isocyanato group, a nitride group, and the like.

상술한 바와 같은 정착그룹(A부)와 친수성그룹(B부)을 갖는 올리고머는 다음의 2가지 방법으로 제조가능하다.The oligomer having the fixing group (A portion) and the hydrophilic group (B portion) as described above can be prepared by the following two methods.

첫째, 친수성기를 갖고 있는 올리고머와 정착그룹을 갖는 화합물의 치환반응으로 상기 올리고머에 정착그룹을 도입할 수 있다.First, the substitution reaction of the oligomer having a hydrophilic group and the compound having a fixing group can introduce a fixing group into the oligomer.

둘째, 정착그룹을 갖는 화합물과 모노머를 반응시킨 후, 이 화합물을 중합함으로써 제조된다.Second, a compound having a fixing group is reacted with a monomer, followed by polymerization of the compound.

상기와 같은 제조방법에 따라 제조된 올리고머 분산제는 분자량이 크지 않아서 물에 쉽게 용해되어 안료와의 반응에 의한 흡착이 증가함으로써 분산이 매우 용이해진다.The oligomer dispersant prepared according to the above production method has a low molecular weight and is easily dissolved in water, so that adsorption due to the reaction with the pigment increases, so that dispersion becomes very easy.

그 결과, 종래의 고분자 분산제를 사용한 경우보다 올리고머 분산제가 흡착된 입자 크기 및 분자량이 상당히 작아진다. 따라서 분산된 안료의 농도가 증가하며, 종래에는 노즐에서 잉크가 증발하여 고분자가 석출되던 것과는 달리, 잉크 증발에 따른 올리고머의 석출이 매우 감소된다. 이와 같이 올리고머 분산제를 사용하면, 노즐의 막힘 현상이 현저하게 감소되고 안료에 부착된 분산제의 크기가 비교적 작기 때문에 분산된 안료의 구조가 간단해진다. 이로 인하여 잉크 토출기구내에서 안료 잉크의 흐름이 용이하고 고속 출력에 많은 도움을 준다.As a result, the particle size and the molecular weight adsorbed by the oligomer dispersant are significantly smaller than in the case of using the conventional polymer dispersant. Therefore, the concentration of the dispersed pigment increases, and precipitation of the oligomer by evaporation of the ink is greatly reduced, unlike the case where the ink is evaporated and the polymer is conventionally deposited in the nozzle. When the oligomer dispersant is used as described above, the clogging of the nozzle is remarkably reduced and the size of the dispersant adhered to the pigment is relatively small, so that the structure of the dispersed pigment is simplified. As a result, the flow of the pigment ink in the ink ejection mechanism is easy and it is very helpful for the high speed output.

본 발명에서는 올리고머 분산제의 분산 효과를 향상시키기 위하여 안료에 따라 2종류이상의 분산제를 함께 사용할 수 있다.In the present invention, two or more kinds of dispersing agents may be used together according to the pigment in order to improve the dispersing effect of the oligomer dispersing agent.

상기 올리고머 분산제의 분자량은 300 내지 3000인 것이 바람직하며, 그 함량은 전체 조성에서 0.1 내지 20중량%, 특히 0.5 내지 15중량%가 바람직하다. 안료로는 무기안료 및 유기안료가 사용되고 있으며, 이 안료 입자의 크기는 분산 안정도, 색농도(color strength), 광택(gloss) 등에 중요한 영향을 미치므로 10 내지 50μm의 노즐을 통과할 수 있을 정도로 작은 크기를 갖는 것이 바람직하다.The molecular weight of the oligomer dispersant is preferably 300 to 3000, and the content thereof is preferably 0.1 to 20% by weight, particularly 0.5 to 15% by weight in the total composition. An inorganic pigment and an organic pigment are used as the pigment, and the size of the pigment particle is important for dispersion stability, color strength, gloss and the like, so that it is small enough to pass through a nozzle of 10 to 50 μm Size.

안료의 함량은 전체 조성에서 0.1 내지 20중량%, 특히 0.5 내지 15중량%가 바람직하다. 안료는 분산제의 정착 그룹과 상호작용을 원활하게 할 수 있도록 하기 치환기(K)를 함유할 수 있다.The content of the pigment is preferably from 0.1 to 20% by weight, more preferably from 0.5 to 15% by weight in the whole composition. The pigments may contain substituents (K) to facilitate interaction with the fixing groups of the dispersant.

상기 치환기(K)는 C₁∼C₃₀알킬 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬, C₁∼C₃₀알킬옥시 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬옥시, C₁∼C₃₀알케닐 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐, C₁∼C₃₀알키닐 또는 적어도 하나의 치환기(G)를 갖는 알키닐, C₁∼C₃₀사이클로알킬(cycloalkyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬, C₁∼C₃₀사이클로알케닐(cycloalkenyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐, C₁∼C₃₀사이클로알키닐(cycloalkynyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐, C₁∼C₃₀헤테로사이클로알킬(cycloalkyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬, C₁∼C₃₀헤테로사이클로알케닐(cycloalkenyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐, C₁∼C₃₀헤테로사이클로알키닐(cycloalkynyl) 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐, 단당류, 이당류 및 다당류, 솔비탄(sorbitan), C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족, C₁∼C₃₀알킬아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬아민, C₁∼C₃₀알킬옥시아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬옥시아민, C₁∼C₃₀알케닐 아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐아민, C₁∼C₃₀알키닐아민 또는 적어도 하나의 치환기(G)를 갖는 알키닐아민, C₁∼C₃₀사이클로알킬(cycloalkyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬아민, C₁∼C₃₀사이클로알케닐(cycloalkenyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐아민, C₁∼C₃₀사이클로알키닐(cycloalkynyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐아민, C₁∼C₃₀헤테로사이클로알킬(cycloalkyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬아민, C₁∼C₃₀헤테로사이클로알케닐(cycloalkenyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐아민, C₁∼C₃₀헤테로사이클로알키닐(cycloalkynyl)아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐아민, 단당류, 이당류 및 다당류아민, 솔비탄(sorbitan)아민, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아민 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₅₀치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아민, C₁∼C₃₀알킬아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬아미드, C₁∼C₃₀알킬옥시아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬옥시아미드, C₁∼C₃₀알케닐아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐아미드, C₁∼C₃₀알키닐아미드 또는 적어도 하나의 치환기(G)를 갖는 알키닐아미드, C₁∼C₃₀사이클로알킬(cycloalkyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬아미드, C₁∼C₃₀사이클로알케닐(cycloalkenyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐아미드, C₁∼C₃₀사이클로알키닐(cycloalkynyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐아미드, C₁∼C₃₀헤테로사이클로알킬(cycloalkyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬아미드, C₁∼C₃₀헤테로사이클로알케닐(cycloalkenyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐아미드, C₁∼C₃₀헤테로사이클로알키닐(cycloalkynyl)아미드 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐아미드, 단당류, 이당류 및 다당류아미드, 솔비탄(sorbitan)아미드, C₆∼C₅₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족아미드 또는 적어도 하나의 치환기(G)를 갖는 모노, 바이, 트리 및 폴리사이클릭환인 방향족아미드, 단당류, 이당류 및 다당류아미드, 솔비탄 아미드, 비치환된 스테로이드 또는 적어도 하나의 치환기를 갖는 스테로이드 등으로 이루어진 군으로부터 선택된다(여기에서, 치환기(G)는 C₁∼C₃₀알킬, C₁∼C₃₀알킬옥시, C₁∼C₃₀알케닐, C₁∼C₃₀알키닐, C₁∼C₃₀사이클로알킬, C₁∼C₃₀사이클로알케닐, C₁∼C₃₀사이클로알키닐, C₁∼C₃₀헤테로사이클로알킬, C₁∼C₃₀헤테로사이클로알케닐, C₁∼C₃₀헤테로사이클로알키닐, C₁∼C₃₀하이드록시알킬, C₁∼C₃₀하이드록시알케닐, C₁∼C₃₀하이드록시알키닐, C₁∼C₃₀하이드록시사이클로알킬, C₁∼C₃₀하이드록시사이클로알케닐, C₁∼C₃₀하이드록시사이클로알키닐, C₁∼C₃₀하이드록시헤테로사이클로알킬, C₁∼C₃₀하이드록시헤테로사이클로알케닐, C₁∼C₃₀하이드록시헤테로사이클로알키닐, C₁∼C₃₀하이드로티오알킬, C₁∼C₃₀하이드로티오알케닐, C₁∼C₃₀하이드로티오알키닐, C₁∼C₃₀하이드로티오사이클로알킬, C₁∼C₃₀하이드로티오사이클로알케닐, C₁∼C₃₀하이드로티오사이클로알키닐, C₁∼C₃₀하이드로티오헤테로사이클로알킬, C₁∼C₃₀하이드로티오헤테로사이클로알케닐, C₁∼C₃₀하이드로티오헤테로사이클로알키닐, C₁∼C₃₀니트로알킬, C₁∼C₃₀니트로알케닐, C₁∼C₃₀니트로알키닐, C₁∼C₃₀니트로사이클로알킬, C₁∼C₃₀니트로사이클로알케닐, C₁∼C₃₀니트로사이클로알키닐, C₁∼C₃₀니트로헤테로사이클로알킬, C₁∼C₃₀니트로헤테로사이클로알케닐, C₁∼C₃₀니트로헤테로사이클로알키닐, C₁∼C₃₀시아노알킬, C₁∼C₃₀시아노알케닐, C₁∼C₃₀시아노알키닐, C₁∼C₃₀시아노사이클로알킬, C₁∼C₃₀시아노사이클로알케닐, C₁∼C₃₀시아노사이클로알키닐, C₁∼C₃₀시아노헤테로사이클로알킬, C₁∼C₃₀시아노헤테로사이클로알케닐, C₁∼C₃₀시아노헤테로사이클로알키닐, C₁∼C₃₀티오시아노알킬, C₁∼C₃₀티오시아노알케닐, C₁∼C₃₀티오시아노알키닐, C₁∼C₃₀티오시아노사이클로알킬, C₁∼C₃₀티오시아노사이클로알케닐, C₁∼C₃₀티오시아노사이클로알키닐, C₁∼C₃₀티오시아노헤테로사이클로알킬, C₁∼C₃₀티오시아노헤테로사이클로알케닐, C₁∼C₃₀티오시아노헤테로사이클로알키닐, C₁∼C₃₀아미노알킬, C₁∼C₃₀아미노알케닐, C₁∼C₃₀아미노알키닐, C₁∼C₃₀아미노사이클로알킬, C₁∼C₃₀아미노사이클로알케닐, C₁∼C₃₀아미노사이클로알키닐, C₁∼C₃₀아미노헤테로사이클로알킬, C₁∼C₃₀아미노헤테로사이클로알케닐, C₁∼C₃₀아미노헤테로사이클로알키닐, C₁∼C₃₀알칸산(alkanoic acid), C₁∼C₃₀알켄산, C₁∼C₃₀알킨산, C₁∼C₃₀사이클로알칸산, C₁∼C₃₀사이클로알켄산, C₁∼C₃₀사이클로알킨산, C₁∼C₃₀헤테로사이클로알칸산, C₁∼C₃₀헤테로사이클로알켄산, C₁∼C₃₀헤테로사이클로알킨산, C₆∼C₃₀방향족, C₆∼C₃₀하이드록시방향족, C₆∼C₃₀하이드로티오방향족, C₆∼C₃₀나이트로방향족, C₆∼C₃₀시아노방향족, C₆∼C₃₀티오시아노방향족, C₆∼C₃₀방향족산, C₆∼C₃₀아미노방향족, 아미노, 치환된 아미노, 이민, 치환된 이민, 아미디노(amidino), 히드라진, 치환된 히드라진, 히드라존, 치환된 히드라존, 아미드, 치환된 아미드, 할라이드(halide), 하이드록시(OH), 니트로기(NO₂), 시아노(CN), 티오시아노(SCN), 티올(SH), 카르복실(COOH), 카르복실산의 알칼리염(COO^_M⁺, 여기에서 M은 알칼리금속임), 술폰산(SO₃H), 술폰산의 알칼리염(SO₃ ^-M^-, 여기에서 M은 알칼리금속임), 인산(H₃PO₄) 및 인산의 알칼리염(H₂PO₄ ^-M⁺, 여기에서 M은 알칼리금속임)으로 이루어진 군으로부터 선택됨).The substituent (K) is a C ₁ ~C ₃₀ alkyl or C ₁ ~C ₃₀ alkyl having at least one substituent (G), C ₁ ~C ₃₀ alkyloxy or C ₁ ~C having at least one substituent (G) ₃₀ alkyloxy, C ₁ ~C ₃₀ alkenyl, or C ₁ ~C ₃₀ alkenyl group having at least one substituent (G), C ₁ ~C ₃₀ alkynyl or alkynyl, C having at least one substituent (G) ₁ ~C ₃₀ cycloalkyl, (cycloalkyl) or C ₁ ~C ₃₀ cycloalkyl having at least one substituent (G), C ₁ ~C ₃₀ cycloalkenyl (cycloalkenyl) or C ₁ having at least one substituent (G) ~C ₃₀ cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkynyl (cycloalkynyl) or at least one substituent (G) a C ₁ ~C ₃₀ cycloalkyl alkynyl, C ₁ ~C ₃₀ heterocycloalkyl (cycloalkyl), or at least having one substituent (G) a C ₁ ~C ₃₀ heterocycloalkyl, C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) or at least having My having substituent (G) C ₁ ~C ₃₀ alkenyl heterocycloalkyl, C ₁ ~C ₃₀ alkynyl heterocycloalkyl C ₁ ~C ₃₀ heterocycloalkyl alkynyl, monosaccharides having the (cycloalkynyl) or at least one substituent (G) , Disaccharides and polysaccharides, sorbitan, C ₆ -C ₅₀ unsubstituted mono-, di-, tri- and polycyclic ring aromatic or C ₆ -C ₅₀ -substituted mono-, bi- or polycarboxylic acids having at least one substituent (G) , tri and polycyclic aromatic Whanin, C ₁ ~C ₃₀ alkyl amine or C ₁ ~C ₃₀ alkyl amines, C ₁ ~C ₃₀ alkyloxy amine or at least one substituent (G) having at least one substituent (G) C ₁ -C ₃₀ alkyloxyamine, C ₁ -C ₃₀ alkenylamine or C ₁ -C ₃₀ alkenylamine having at least one substituent (G), C ₁ -C ₃₀ alkynylamine or at least one substituents (G) an alkynyl amine, C ₁ ~C ₃₀ cycloalkyl, (cycloalkyl) amine, or at least having to The substituent (G) having a C ₁ ~C ₃₀ cycloalkyl amine, C ₁ ~C ₃₀ cycloalkenyl (cycloalkenyl) C ₁ ~C ₃₀ cycloalkenyl amine, C ₁ having the amine or at least one substituent (G) ~C ₃₀ cycloalkyl alkynyl (cycloalkynyl) amine or a C ₁ ~C ₃₀ cycloalkyl alkynyl amine, C ₁ ~C ₃₀ heterocycloalkyl (cycloalkyl) amine or at least one substituent (G) having at least one substituent (G) having a C ₁ ~C ₃₀ hetero cycloalkyl amine, C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) amines, or at least one substituent (G) C ₁ ~C ₃₀ hetero cycloalkenyl having alkenyl amine, C ₁ ~C ₃₀ heterocycloalkynyl amine or a C ₁ -C ₃₀ heterocycloalkynylamine, monosaccharide, disaccharide and polysaccharide amine having at least one substituent (G), sorbitan amine, C ₆ -C ₅₀ Aromatic < / RTI > aryl, which is a mono, bi, tri and polycyclic ring, Or C ₁ ~ with at least one substituent (G) C ₆ ~C ₅₀ substituted mono, bi, tri and polycyclic Whanin aromatic amine, C ₁ ~C ₃₀ alkyl amide, or at least one substituent (G) having a C ₃₀ alkylamide, C ₁ ~C ₃₀ alkyloxy or amide having at least one substituent (G) C ₁ ~C ₃₀ alkyloxy amide, C ₁ ~C ₃₀ alkenyl amides, or at least one substituent (G) having a C ₁ -C ₃₀ alkenyl amides, C ₁ -C ₃₀ alkynyl amides or alkynyl amides having at least one substituent (G), C ₁ -C ₃₀ cycloalkyl amides or at least one substituent (G) a C ₁ ~C ₃₀ cycloalkyl amide, C ₁ ~C ₃₀ cycloalkenyl (cycloalkenyl) amide, or at least one C ₁ ~C ₃₀ cycloalkyl alkenyl amide having a substituent (G), C ₁ ~C ₃₀ cycloalkyl having alkynyl carbonyl (cycloalkynyl) amide, or C ₁ ~C ₃₀ having at least one substituent (G) Cycle to alkynyl amide, C ₁ ~C ₃₀ heterocycloalkyl (cycloalkyl) amide, or C ₁ ~C ₃₀ heterocycloalkyl amide, C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) having at least one substituent (G) amide, or C ₁ ~C ₃₀ hetero cycloalkenyl having at least one substituent (G) amides, C ₁ ~C ₃₀ alkynyl heterocycloalkyl (cycloalkynyl) amide, or C ₁ ~C ₃₀ having at least one substituent (G) Having at least one substituent (G), with at least one substituent (s) selected from the group consisting of monocarboxylic acids, heterocycloalkynyl amides, monosaccharides, disaccharides and polysaccharide amides, sorbitan amides, C ₆ -C ₅₀ unsubstituted mono-, Aromatic amides, monosaccharides, disaccharides and polysaccharide amides which are mono, bi, tri and polycyclic, sulphonamides, unsubstituted steroids or steroids with at least one substituent Wherein the substituent (G) is selected from the group consisting of C ₁ -C ₃₀ alkyl, C ₁ -C ₃₀ alkyloxy, C ₁ -C ₃₀ alkenyl, C ₁ -C ₃₀ alkynyl, C ₁ -C ₃₀ C _{1 to} C ₃₀ cycloalkenyl, C _{1 to} C ₃₀ cycloalkynyl, C _{1 to} C ₃₀ heterocycloalkyl, C _{1 to} C ₃₀ heterocycloalkenyl, C _{1 to} C ₃₀ heterocycloalkynyl, C _{1 to} C ₃₀ hydroxyalkyl, C _{1 to} C ₃₀ hydroxyalkenyl, C _{1 to} C ₃₀ hydroxyalkynyl, C _{1 to} C ₃₀ hydroxycycloalkyl, C _{1 to} C ₃₀ hydroxycycloalkenyl, C ₁ -C ₃₀ hydroxycycloalkenyl, C ₁ -C ₃₀ hydroxyheterocycloalkyl, C ₁ -C ₃₀ hydroxyheterocycloalkenyl, C ₁ -C ₃₀ hydroxyheterocycloalkynyl, C ₁ -C _{30-dihydro-thioalkyl,} C ₁ ~C ₃₀ alkenyl dihydro-thio, C ₁ ~C _{30-dihydro-thio-alkynyl,} C ₁ ~C _{30-dihydro-thio-cycloalkyl,} C ₁ ~C _{30-dihydro-thio} cycloalkenyl, C ₁ ~C ₃₀ dihydro-thio-alkynyl cycloalkyl, C ₁ ~C ₃₀ dihydro-thio-heterocycloalkyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkenyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkyl nitro, C ₁ ~C ₃₀ alkenyl, nitro, C ₁ ~C ₃₀ alkynyl, nitro, C ₁ ~C ₃₀ cycloalkyl nitro, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl nitro alkynyl, C ₁ ~C _{30-nitro-heterocycloalkyl,} C ₁ ~C ₃₀ hetero nitro cycloalkenyl, C ₁ ~C ₃₀ nitro heterocycloalkyl alkynyl, C ₁ ~C ₃₀ cyanoalkyl, C ₁ ~C ₃₀ alkenyl noal cyano, C ₁ ~C _{30-cyano-alkynyl,} cyano C ₁ ~C ₃₀ cycloalkyl, C ₁ ~C _30-cyano cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl cyano alkynyl, C ₁ ~C _{30-cyano-heterocycloalkyl,} C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C ₃₀ when No heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkyl thio cyano, C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₃₀ thio-dicyano-heterocycloalkyl, C ₁ ~C ₃₀ thio-dicyano hetero cycloalkenyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkynyl, C ₁ ~C ₃₀ aminoalkyl, C ₁ ~C ₃₀ alkenyl, amino, C ₁ ~C ₃₀ amino alkynyl, C ₁ ~C ₃₀ cycloalkyl-amino, C ₁ ~C _{30-amino-cycloalkenyl,} C ₁ ~C ₃₀ cycloalkyl amino alkynyl, C ₁ ~C ₃₀ amino heterocycloalkyl, C ₁ ~C ₃₀ amino heterocycloalkyl alkenyl, C ₁ ~C ₃₀ amino heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkanoic acid _{(alkanoic acid), C 1 ~C} 30 Al kensan, C ₁ ~C ₃₀ alkynyl acids, C ₁ ~C ₃₀ cycloalkyl alkanoic acid, C ₁ ~C ₃₀ cycloalkenyl kensan, C ₁ ~C ₃₀ cycloalkyl acid alkynyl, C ₁ ~C ₃₀ heterocycloalkyl alkanoic acid, C ₁ ~C ₃₀ hetero cycloalkenyl kensan, C ₁ ~C ₃₀ alkynyl heterocycloalkyl acid, C ₆ ~C ₃₀ aromatic, C ₆ ~C _{30-hydroxy-aromatic,} C ₆ ~C ₃₀ aromatic hydro-thio, C ₆ ~C aromatic, C ₆ ~C ₃₀ aromatic cyano, C ₆ ~C ₃₀ aromatic thio cyano, C ₆ ~C ₃₀ aromatic nitro acid _30, C ₆ -C ₃₀ aminoaromatic, amino, substituted amino, imine, substituted imine, amidino, hydrazine, substituted hydrazine, hydrazone, substituted hydrazone, amide, substituted amide, halide, , hydroxy (OH), nitro group (nO _2), cyano (CN), thio-dicyano (SCN), thiol (SH), carboxyl (COOH), (COO ^_ M ⁺ alkali salt of a carboxylic acid, Where M is an alkali metal), sulfonic acid (SO ₃ H), sulfonic acid alkaline salt (SO ₃ ^- M ^- , where M is an alkali metal), phosphoric acid (H ₃ PO ₄ ) ₂ PO ₄ ^- M ^+, W M is selected from the group consisting of alkali metal Im)) on.

본 발명의 잉크 조성물에는 산 또는 염기가 더 포함되기도 한다. 여기에서 산 또는 염기는 용매에 대한 올리고머 분산제의 용해도를 증가시키고, 분산된 안료를 안정화시키는 역할을 하며, 그 함량은 전체 조성에서 0.1 내지 20중량%가 바람직하다.The ink composition of the present invention may further contain an acid or a base. Here, the acid or base serves to increase the solubility of the oligomer dispersant in the solvent and to stabilize the dispersed pigment, and its content is preferably 0.1 to 20% by weight in the total composition.

상기 산으로는 C₁∼C₃₀알킬카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬카르복실산, C₁∼C₃₀알케닐카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐카르복실산, C₁∼C₃₀알키닐카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알키닐카르복실산, C₁∼C₃₀사이클로알킬카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬카르복실산, C₁∼C₃₀사이클로알케닐카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐카르복실산, C₁∼C₃₀사이클로알키닐카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐카르복실산, C₁∼C₃₀헤테로사이클로알킬카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬카르복실산, C₁∼C₃₀헤테로사이클로알케닐카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐카르복실산, C₁∼C₃₀헤테로사이클로알키닐카르복실산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐카르복실산, C₆∼C₃₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족카르복실산 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₃₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족카르복실산, C₁∼C₃₀알킬술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬술폰산, C₁∼C₃₀알케닐술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐술폰산, C₁∼C₃₀알키닐술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알키닐술폰산, C₁∼C₃₀사이클로알킬술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬술폰산, C₁∼C₃₀사이클로알케닐술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐술폰산, C₁∼C₃₀사이클로알키닐술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐술폰산, C₁∼C₃₀헤테로사이클로알킬술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬술폰산, C₁∼C₃₀헤테로사이클로알케닐술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐술폰산, C₁∼C₃₀헤테로사이클로알키닐술폰산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐술폰산, C₆∼C₃₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족술폰산 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₃₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족술폰산, C₁∼C₃₀알킬인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알킬인산, C₁∼C₃₀알케닐인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알케닐인산, C₁∼C₃₀알키닐인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀알키닐인산, C₁∼C₃₀사이클로알킬인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알킬인산, C₁∼C₃₀사이클로알케닐인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알케닐인산, C₁∼C₃₀사이클로알키닐인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀사이클로알키닐인산, C₁∼C₃₀헤테로사이클로알킬인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알킬인산, C₁∼C₃₀헤테로사이클로알케닐인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알케닐인산, C₁∼C₃₀헤테로사이클로알키닐인산 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀헤테로사이클로알키닐인산, C₆∼C₃₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족인산 또는 적어도 하나의 치환기(G)를 갖는 C₆∼C₃₀비치환된 모노, 바이, 트라이 및 폴리사이클릭환인 방향족인산 및 황산으로 이루어진 군으로부터 선택된 화합물을 사용한다(여기에서, 치환기(G)는 C₁∼C₃₀알킬, C₁∼C₃₀알킬옥시, C₁∼C₃₀알케닐, C₁∼C₃₀알키닐, C₁∼C₃₀사이클로알킬, C₁∼C₃₀사이클로알케닐, C₁∼C₃₀사이클로알키닐, C₁∼C₃₀헤테로사이클로알킬, C₁∼C₃₀헤테로사이클로알케닐, C₁∼C₃₀헤테로사이클로알키닐, C₁∼C₃₀하이드록시알킬, C₁∼C₃₀하이드록시알케닐, C₁∼C₃₀하이드록시알키닐, C₁∼C₃₀하이드록시사이클로알킬, C₁∼C₃₀하이드록시사이클로알케닐, C₁∼C₃₀하이드록시사이클로알키닐, C₁∼C₃₀하이드록시헤테로사이클로알킬, C₁∼C₃₀하이드록시헤테로사이클로알케닐, C₁∼C₃₀하이드록시헤테로사이클로알키닐, C₁∼C₃₀하이드로티오알킬, C₁∼C₃₀하이드로티오알케닐, C₁∼C₃₀하이드로티오알키닐, C₁∼C₃₀하이드로티오사이클로알킬, C₁∼C₃₀하이드로티오사이클로알케닐, C₁∼C₃₀하이드로티오사이클로알키닐, C₁∼C₃₀하이드로티오헤테로사이클로알킬, C₁∼C₃₀하이드로티오헤테로사이클로알케닐, C₁∼C₃₀하이드로티오헤테로사이클로알키닐, C₁∼C₃₀니트로알킬, C₁∼C₃₀니트로알케닐, C₁∼C₃₀니트로알키닐, C₁∼C₃₀니트로사이클로알킬, C₁∼C₃₀니트로사이클로알케닐, C₁∼C₃₀니트로사이클로알키닐, C₁∼C₃₀니트로헤테로사이클로알킬, C₁∼C₃₀니트로헤테로사이클로알케닐, C₁∼C₃₀니트로헤테로사이클로알키닐, C₁∼C₃₀시아노알킬, C₁∼C₃₀시아노알케닐, C₁∼C₃₀시아노알키닐, C₁∼C₃₀시아노사이클로알킬, C₁∼C₃₀시아노사이클로알케닐, C₁∼C₃₀시아노사이클로알키닐, C₁∼C₃₀시아노헤테로사이클로알킬, C₁∼C₃₀시아노헤테로사이클로알케닐, C₁∼C₃₀시아노헤테로사이클로알키닐, C₁∼C₃₀티오시아노알킬, C₁∼C₃₀티오시아노알케닐, C₁∼C₃₀티오시아노알키닐, C₁∼C₃₀티오시아노사이클로알킬, C₁∼C₃₀티오시아노사이클로알케닐, C₁∼C₃₀티오시아노사이클로알키닐, C₁∼C₃₀티오시아노헤테로사이클로알킬, C₁∼C₃₀티오시아노헤테로사이클로알케닐, C₁∼C₃₀티오시아노헤테로사이클로알키닐, C₁∼C₃₀아미노알킬, C₁∼C₃₀아미노알케닐, C₁∼C₃₀아미노알키닐, C₁∼C₃₀아미노사이클로알킬, C₁∼C₃₀아미노사이클로알케닐, C₁∼C₃₀아미노사이클로알키닐, C₁∼C₃₀아미노헤테로사이클로알킬, C₁∼C₃₀아미노헤테로사이클로알케닐, C₁∼C₃₀아미노헤테로사이클로알키닐, C₁∼C₃₀알칸산(alkanoic acid), C₁∼C₃₀알켄산, C₁∼C₃₀알킨산, C₁∼C₃₀사이클로알칸산, C₁∼C₃₀사이클로알켄산, C₁∼C₃₀사이클로알킨산, C₁∼C₃₀헤테로사이클로알칸산, C₁∼C₃₀헤테로사이클로알켄산, C₁∼C₃₀헤테로사이클로알킨산, C₆∼C₃₀방향족, C₆∼C₃₀하이드록시방향족, C₆∼C₃₀하이드로티오방향족, C₆∼C₃₀나이트로방향족, C₆∼C₃₀시아노방향족, C₆∼C₃₀티오시아노방향족, C₆∼C₃₀방향족산, C₆∼C₃₀아미노방향족, 아미노, 치환된 아미노, 이민, 치환된 이민, 아미디노(amidino), 히드라진, 치환된 히드라진, 히드라존, 치환된 히드라존, 아미드, 치환된 아미드, 할라이드(halide), 하이드록시(OH), 니트로기(NO₂), 시아노(CN), 티오시아노(SCN), 티올(SH)로 이루어진 군으로부터 선택됨).The acid is a C ₁ ~C ₃₀ alkyl carboxylic acid, at least one substituent (G) C ₁ ~C ₃₀ alkyl carboxylic acids, C ₁ ~C ₃₀ alkenyl carboxylic acid, at least one substituent (G) having a having C ₁ ~C ₃₀ alkenyl carboxylic acids, C ₁ ~C ₃₀ alkynyl carboxylic acid, at least one substituent (G) C ₁ ~C ₃₀ alkynyl carboxylic acid having, C ₁ ~C ₃₀ cycloalkyl carboxylic acid C ₁ ~C ₃₀ cycloalkyl carboxylic acids, C ₁ ~C ₃₀ cycloalkenyl carboxylic acid C ₁ ~C ₃₀ cycloalkenyl having at least one substituent (G) having at least one substituent (G) carboxylic acid, C ₁ ~C ₃₀ cycloalkyl alkynyl carboxylic acid, at least one substituent (G) C ₁ ~C ₃₀ cycloalkyl alkynyl carboxylic acid having, C ₁ ~C ₃₀ heterocycloalkyl-carboxylic acid, at least one of C ₁ -C ₃₀ heterocycloalkylcarboxylic acids with substituents (G), C ₁ -C ₃₀ heterocycloalkenylcarboxylic acids C ₁ ~C ₃₀ hetero cycloalkenyl carboxylic acids, C ₁ ~C ₃₀ alkynyl heterocycloalkyl-carboxylic acid C ₁ ~C ₃₀ heterocycle having at least one substituent (G) having at least one substituent (G) alkynyl-carboxylic acid, C ₆ ~C ₃₀ unsubstituted mono-, bi-, tri and polycyclic Whanin aromatic carboxylic acid or a C ₆ ~C ₃₀ unsubstituted with at least one substituent (G) mono, bi, tri and polycyclic Whanin aromatic carboxylic acids, C ₁ ~C ₃₀ alkyl, C ₁ ~C ₃₀ alkyl sulfonic acid, C ₁ ~C ₃₀ alkenyl sulfonic acid at least one substituent having at least one substituent (G) (G) C ₁ ~C ₃₀ alkenyl sulfonic acid, C ₁ ~C ₃₀ alkynyl sulfonic acid C ₁ ~C ₃₀ alkynyl, C ₁ ~C ₃₀ cycloalkyl, sulfonic acid, at least one substituent having at least one substituent (G) having the ( G) C ₁ ~C ₃₀ cycloalkyl sulfonic acid having, C ₁ ~C ₃₀ cycloalkenyl sulfone C ₁ ~C ₃₀ cycloalkyl alkynyl sulfonic acid, C ₁ ~ with at least one substituent (G) C ₁ ~C ₃₀ cycloalkenyl acid, C ₁ ~C ₃₀ cycloalkyl alkynyl sulfonic acid at least one substituent (G) having a C ₃₀ heterocycloalkyl acid, at least one C ₁ ~C having a substituent group (G) of ₃₀ heterocycloalkyl acid, C ₁ ~C ₃₀ hetero cycloalkenyl acid C ₁ ~C ₃₀ heteroaryl having at least one substituent (G) cycloalkenyl acid, C ₁ ~C ₃₀ alkynyl heterocycloalkyl acid, at least one C ₁ ~C having a substituent group (G) of ₃₀ heterocycloalkyl alkynyl sulfonic acids, C ₆ ~C ₃₀ unsubstituted mono-, bi-, tri and poly cyclic Whanin aromatic sulfonic acid or at least one C ₆ ~C ₃₀ unsubstituted mono-, bi-, tri and polycyclic having a substituent (G) Whanin aromatic sulfonic acid, C ₁ ~C ₃₀ alkyl phosphate, at least one substituent (G) C ₁ ~C ₃₀ alkyl phosphate having, C ₁ ~C ₃₀ alkenyl phosphoric acid at least one substituent (G) C ₁ ~C ₃₀ alkenyl phosphoric acid, C ₁ ~C ₃₀ alkynyl phosphoric acid at least one substituent (G) C ₁ ~C ₃₀ alkynyl having having acid, C ₁ ~C ₃₀ cycloalkyl-alkyl phosphate having at least one substituent (G) C ₁ ~C ₃₀ cycloalkyl, phosphate, C ₁ ~C ₃₀ cycloalkenyl C ₁ ~C acid having at least one substituent (G) ₃₀ cycloalkenyl phosphate, C ₁ ~C ₃₀ cycloalkyl alkynyl phosphoric C ₁ ~C ₃₀ cycloalkyl alkynyl, phosphate, C ₁ ~C ₃₀ heterocycloalkyl phosphoric acid at least one substituent having at least one substituent (G) (G) a C ₁ ~C ₃₀ heterocycloalkyl acid, C ₁ ~C ₃₀ hetero cycloalkenyl acid C ₁ ~C ₃₀ hetero cycloalkenyl acid, having at least one substituent (G) C ₁ ~C ₃₀ having heterocycloalkyl alkynyl carbonyl phosphoric C ₁ ~C ₃₀ alkynyl heterocycloalkyl phosphate, C ₆ ~C ₃₀ with at least one substituent (G) Substituted mono, bi from, tri and polycyclic aromatic Whanin acid or C ₆ ~C _{30-substituted} mono, bi, tri and polycyclic aromatic Whanin the group consisting of phosphoric acid and sulfuric acid ring having at least one substituent (G) Wherein the substituent (G) is selected from the group consisting of C ₁ -C ₃₀ alkyl, C ₁ -C ₃₀ alkyloxy, C ₁ -C ₃₀ alkenyl, C ₁ -C ₃₀ alkynyl, C ₁ -C ₃₀ C _{1 to} C ₃₀ cycloalkenyl, C _{1 to} C ₃₀ cycloalkynyl, C _{1 to} C ₃₀ heterocycloalkyl, C _{1 to} C ₃₀ heterocycloalkenyl, C _{1 to} C ₃₀ heterocycloalkynyl, C _{1 to} C ₃₀ hydroxyalkyl, C _{1 to} C ₃₀ hydroxyalkenyl, C _{1 to} C ₃₀ hydroxyalkynyl, C _{1 to} C ₃₀ hydroxycycloalkyl, C _{1 to} C ₃₀ hydroxycycloalkenyl, C ₁ ~C ₃₀ hydroxycyclohexyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl, C ₁ ~C ₃₀ Hyde When heterocycloalkyl alkenyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkynyl, C ₁ ~C ₃₀ dihydro-thioalkyl, C ₁ ~C ₃₀ alkenyl dihydro-thio, C ₁ ~C ₃₀ dihydro-thio alkynyl, C ₁ ~ C ₃₀ alkylthio dihydro cycloalkyl, C ₁ ~C ₃₀ dihydro-thio cycloalkenyl, C ₁ ~C ₃₀ dihydro-thio-alkynyl cycloalkyl, C ₁ ~C ₃₀ dihydro-thio-heterocycloalkyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl al alkenyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkyl nitro, C ₁ ~C ₃₀ alkenyl, nitro, C ₁ ~C ₃₀ alkynyl, nitro, C ₁ ~C ₃₀ cycloalkyl, nitro, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkynyl, nitro, C ₁ ~C _{30-nitro-heterocycloalkyl,} C ₁ ~C ₃₀ hetero nitro cycloalkenyl, C ₁ ~C ₃₀ nitro heterocycloalkyl alkynyl , C ₁ ~C ₃₀ cyanoalkyl, C ₁ ~C ₃₀ alkenyl noal cyano, C ₁ ~ C ₃₀ alkynyl cyano, C ₁ ~C ₃₀ cycloalkyl, cyano, C ₁ ~C _30-cyano cycloalkenyl, C ₁ ~C _{30-cyano-alkynyl} cycloalkyl, C ₁ ~C _{30-cyano-heterocycloalkyl,} C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C _{30-cyano-heterocycloalkyl} alkynyl, C ₁ ~C ₃₀ alkyl thio cyano, C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₃₀ hetero thio-dicyano cycloalkyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkenyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkynyl, C ₁ ~C ₃₀ aminoalkyl, C ₁ ~C ₃₀ alkenyl, amino, C ₁ ~C _{30-amino-alkynyl,} C ₁ ~C ₃₀ cycloalkyl-amino, C ₁ ~C ₃₀ amino cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl amino alkynyl, C ₁ ~C ₃₀ hetero between amino Claw alkyl, C ₁ ~C ₃₀ amino heterocycloalkyl alkenyl, C ₁ ~C ₃₀ amino heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkanoic acid _{(alkanoic acid), C 1 ~C} 30 Al kensan, C ₁ ~C ₃₀ acid alkynyl, C ₁ ~C ₃₀ cycloalkyl alkanoic acid, C ₁ ~C ₃₀ kensan cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl acid alkynyl, C ₁ ~C ₃₀ heterocycloalkyl alkanoic acid, C ₁ ~C ₃₀ hetero cycloalkenyl kensan, C ₁ ~C ₃₀ alkynyl heterocycloalkyl acid, C ₆ ~C ₃₀ aromatic, C ₆ ~C ₃₀ aromatic hydroxy, C ₆ ~C ₃₀ aromatic hydro-thio, C ₆ ~C ₃₀ aromatic, C ₆ ~C ₃₀ nitro cyano no aromatic, C ₆ ~C ₃₀ aromatic thio cyano, C ₆ ~C ₃₀ aromatic acids, C ₆ ~C ₃₀ aromatic amino, amino, substituted amino, imine, substituted imine, amidino (amidino), hydrazine, substituted a hydrazine, hydrazone, substituted hydrazone, amide, substituted amide, halide (halide), hydroxy (OH), nitro group (nO _2), cyano (CN), thio-dicyano (SCN), T Selected from the group consisting of (SH)).

상기 염기로는 디메틸아민 에탄올, 메틸 디에탄올아민, 모노메탄올아민, 디메탄올아민, 트리에탄올아민, 모노에탄올아민, 디에탄올아민, 트리에탄올아민, 암모늄 하이드록사이드, 테트라알킬암모늄 하이드록사이드, 디메틸아미노프로필아민(DMAP), 디메틸아미노프로필-2-피롤리돈(DMAPP), 라우릴아민, 세트리모니움 브롬마이드(cetrimonium bromide), 모르폴린(morpholine) 및 n-메틸 모르폴린을 포함하는 C₁∼C₃₀지방족아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀지방족아민, C₁∼C₃₀방향족아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀방향족 아민, C₁∼C₂₀지방족 모노, 디, 트리 및 폴리알카놀아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₂₀지방족 모노, 디, 트리 및 폴리알카놀아민, C₁∼C₃₀방향족 모노, 디, 트리, 및 폴리알카놀아민 또는 적어도 하나의 치환기(G)를 갖는 C₁∼C₃₀방향족 모노, 디, 트리, 및 폴리알카놀아민으로 이루어진 군으로부터 선택된 화합물을 사용한다(여기에서, 치환기(G)는 C₁∼C₃₀알킬, C₁∼C₃₀알킬옥시, C₁∼C₃₀알케닐, C₁∼C₃₀알키닐, C₁∼C₃₀사이클로알킬, C₁∼C₃₀사이클로알케닐, C₁∼C₃₀사이클로알키닐, C₁∼C₃₀헤테로사이클로알킬, C₁∼C₃₀헤테로사이클로알케닐, C₁∼C₃₀헤테로사이클로알키닐, C₁∼C₃₀하이드록시알킬, C₁∼C₃₀하이드록시알케닐, C₁∼C₃₀하이드록시알키닐, C₁∼C₃₀하이드록시사이클로알킬, C₁∼C₃₀하이드록시사이클로알케닐, C₁∼C₃₀하이드록시사이클로알키닐, C₁∼C₃₀하이드록시헤테로사이클로알킬, C₁∼C₃₀하이드록시헤테로사이클로알케닐, C₁∼C₃₀하이드록시헤테로사이클로알키닐, C₁∼C₃₀하이드로티오알킬, C₁∼C₃₀하이드로티오알케닐, C₁∼C₃₀하이드로티오알키닐, C₁∼C₃₀하이드로티오사이클로알킬, C₁∼C₃₀하이드로티오사이클로알케닐, C₁∼C₃₀하이드로티오사이클로알키닐, C₁∼C₃₀하이드로티오헤테로사이클로알킬, C₁∼C₃₀하이드로티오헤테로사이클로알케닐, C₁∼C₃₀하이드로티오헤테로사이클로알키닐, C₁∼C₃₀니트로알킬, C₁∼C₃₀니트로알케닐, C₁∼C₃₀니트로알키닐, C₁∼C₃₀니트로사이클로알킬, C₁∼C₃₀니트로사이클로알케닐, C₁∼C₃₀니트로사이클로알키닐, C₁∼C₃₀니트로헤테로사이클로알킬, C₁∼C₃₀니트로헤테로사이클로알케닐, C₁∼C₃₀니트로헤테로사이클로알키닐, C₁∼C₃₀시아노알킬, C₁∼C₃₀시아노알케닐, C₁∼C₃₀시아노알키닐, C₁∼C₃₀시아노사이클로알킬, C₁∼C₃₀시아노사이클로알케닐, C₁∼C₃₀시아노사이클로알키닐, C₁∼C₃₀시아노헤테로사이클로알킬, C₁∼C₃₀시아노헤테로사이클로알케닐, C₁∼C₃₀시아노헤테로사이클로알키닐, C₁∼C₃₀티오시아노알킬, C₁∼C₃₀티오시아노알케닐, C₁∼C₃₀티오시아노알키닐, C₁∼C₃₀티오시아노사이클로알킬, C₁∼C₃₀티오시아노사이클로알케닐, C₁∼C₃₀티오시아노사이클로알키닐, C₁∼C₃₀티오시아노헤테로사이클로알킬, C₁∼C₃₀티오시아노헤테로사이클로알케닐, C₁∼C₃₀티오시아노헤테로사이클로알키닐, C₁∼C₃₀아미노알킬, C₁∼C₃₀아미노알케닐, C₁∼C₃₀아미노알키닐, C₁∼C₃₀아미노사이클로알킬, C₁∼C₃₀아미노사이클로알케닐, C₁∼C₃₀아미노사이클로알키닐, C₁∼C₃₀아미노헤테로사이클로알킬, C₁∼C₃₀아미노헤테로사이클로알케닐, C₁∼C₃₀아미노헤테로사이클로알키닐, C₁∼C₃₀알칸산(alkanoic acid), C₁∼C₃₀알켄산, C₁∼C₃₀알킨산, C₁∼C₃₀사이클로알칸산, C₁∼C₃₀사이클로알켄산, C₁∼C₃₀사이클로알킨산, C₁∼C₃₀헤테로사이클로알칸산, C₁∼C₃₀헤테로사이클로알켄산, C₁∼C₃₀헤테로사이클로알킨산, C₆∼C₃₀방향족, C₆∼C₃₀하이드록시방향족, C₆∼C₃₀하이드로티오방향족, C₆∼C₃₀나이트로방향족, C₆∼C₃₀시아노방향족, C₆∼C₃₀티오시아노방향족, C₆∼C₃₀방향족산, C₆∼C₃₀아미노방향족, 아미노, 치환된 아미노, 이민, 치환된 이민, 아미디노(amidino), 히드라진, 치환된 히드라진, 히드라존, 치환된 히드라존, 아미드, 치환된 아미드, 할라이드(halide), 하이드록시(OH), 니트로기(NO₂), 시아노(CN), 티오시아노(SCN), 티올(SH)로 이루어진 군으로부터 선택됨).Examples of the base include dimethylamine ethanol, methyldiethanolamine, monomethanolamine, dimethanolamine, triethanolamine, monoethanolamine, diethanolamine, triethanolamine, ammonium hydroxide, tetraalkylammonium hydroxide, dimethylaminopropyl Which comprises a C ₁ to C ₆ alkyl group, including an amine (DMAP), dimethylaminopropyl-2-pyrrolidone (DMAPP), laurylamine, cetrimonium bromide, morpholine, C ₃₀ aliphatic amine or a C ₁ ~C ₃₀ aromatic amines, C ₁ ~ with at least one of substituents C ₁ ~C ₃₀ aliphatic amines, C ₁ ~C ₃₀ aromatic amine or at least one substituent (G) having a (G) C ₂₀ aliphatic mono-, di-, tri- and poly-alkanolamines or C ₁ ~C having at least one substituent (G) ₂₀ aliphatic mono-, di-, tri- and poly-alkanolamines, C ₁ ~C ₃₀ aromatic mono, di, Tree, and polyalkanolamine or And even using a single compound selected from the C ₁ ~C ₃₀ aromatic mono, di, tri, and poly alkaryl group consisting of play Min having a substituent group (G) of (wherein the substituent (G) is a C ₁ ~C ₃₀ alkyl , C ₁ -C ₃₀ alkyloxy, C ₁ -C ₃₀ alkenyl, C ₁ -C ₃₀ alkynyl, C ₁ -C ₃₀ cycloalkyl, C ₁ -C ₃₀ cycloalkenyl, C ₁ -C ₃₀ cycloalkynyl , C ₁ -C ₃₀ heterocycloalkyl, C ₁ -C ₃₀ heterocycloalkenyl, C ₁ -C ₃₀ heterocycloalkynyl, C ₁ -C ₃₀ hydroxyalkyl, C ₁ -C ₃₀ hydroxyalkenyl, C ₁ ~C ₃₀ hydroxyalkyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl cycloalkyl, C ₁ ~C ₃₀ hydroxy cycloalkenyl, C ₁ ~C ₃₀ hydroxycyclohexyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkenyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkynyl, C ₁ ~C ₃₀ dihydro-thio al , C ₁ ~C ₃₀ alkenyl dihydro-thio, C ₁ ~C ₃₀ dihydro-thio alkynyl, C ₁ ~C ₃₀ cycloalkyl dihydro-thio, C ₁ ~C ₃₀ dihydro-thio cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl dihydro thio alkynyl, C ₁ ~C ₃₀ dihydro-thio-heterocycloalkyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkenyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkyl nitro, C ₁ ~C _{30-nitro-alkenyl,} C ₁ ~C ₃₀ alkynyl, nitro, C ₁ ~C ₃₀ cycloalkyl nitro, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkynyl, nitro, C ₁ ~C ₃₀ hetero nitro cycloalkyl, C ₁ ~C ₃₀ hetero nitro cycloalkenyl, C ₁ ~C ₃₀ nitro heterocycloalkyl alkynyl, C ₁ ~C ₃₀ cyanoalkyl, C ₁ ~C ₃₀ alkenyl noal cyano, C ₁ ~C _30-cyano alkynyl, C ₁ ~C ₃₀ cycloalkyl, cyano, C ₁ ~C _30-cyano cycloalkenyl, C ₁ ~C ₃₀ cyano Alkynyl cycloalkyl, C ₁ ~C _{30-cyano-heterocycloalkyl,} C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C _{30-cyano-heterocycloalkyl} alkynyl, C ₁ ~C ₃₀ alkyl thio cyano, C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ alkylthio cyano cycloalkyl alkynyl, C ₁ ~C ₃₀ thio-dicyano-heterocycloalkyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkenyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkynyl, C ₁ ~C ₃₀ amino Alkyl, C ₁ -C ₃₀ aminoalkenyl, C ₁ -C ₃₀ aminoalkynyl, C ₁ -C ₃₀ aminocycloalkyl, C ₁ -C ₃₀ aminocycloalkenyl, C ₁ -C ₃₀ aminocycloalkynyl, C ₁ ~C ₃₀ amino heterocycloalkyl, C ₁ ~C ₃₀ amino heterocycloalkyl alkenyl, C ₁ ~C ₃₀ amino heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkanoic acid, C ₁ -C ₃₀ alkenoic acid, C ₁ -C ₃₀ alkynoic acid, C ₁ -C ₃₀ cycloalkanoic acid, C ₁ -C ₃₀ cycloalkenoic acid, C ₁ -C ₃₀ cycloalkane acid , C ₁ ~C ₃₀ heterocycloalkyl alkanoic acid, C ₁ ~C ₃₀ hetero cycloalkenyl kensan, C ₁ ~C ₃₀ alkynyl heterocycloalkyl acid, C ₆ ~C ₃₀ aromatic, C ₆ ~C ₃₀ aromatic hydroxy, C ₆ ~ C ₃₀ aromatic hydro-thio, C ₆ aromatic, C ₆ ~C ₃₀ aromatic cyano, C ₆ ~C ₃₀ aromatic thio cyano, C ₆ ~C ₃₀ by ~C ₃₀ aromatic nitro acid, C ₆ ~C ₃₀ aromatic amino, Substituted amines, substituted amines, amidino, hydrazine, substituted hydrazine, hydrazone, substituted hydrazone, amide, substituted amide, halide, hydroxy (OH), nitro (NO ₂ ), cyano (CN), thiocano (SCN), thiol (SH).

용매의 함량은 전체 조성에서 60 내지 99.8중량%이며, 물을 주로 사용한다. 경우에 따라서는 올리고머 분산제의 용해도를 향상시키고 얻어지는 잉크 조성물의 점도 및 표면장력을 적절히 유지하기 위해서 물과 유기용매의 혼합용매를 사용하기도 한다. 이 대 유기용매의 함량은 용매 전체 조성에서 0.1 내지 20중량%인 것이 바람직하다.The content of the solvent is 60 to 99.8% by weight in the whole composition, and water is mainly used. In some cases, a mixed solvent of water and an organic solvent may be used in order to improve the solubility of the oligomer dispersant and suitably maintain the viscosity and surface tension of the resulting ink composition. The content of the organic solvent is preferably 0.1 to 20% by weight in the entire solvent composition.

상기 유기용매로는 메탄올, 에탄올, n-프로판올, i-프로판올, 부탄올, t-부탄올, i-부탄올, 헥사놀, i-헥사놀, 헵타놀, i-헵타놀, 옥타놀, i-옥타놀, 노나놀, i-노나놀 도데카놀, i-도데카놀, 헥사데카놀, i-헥사데카놀, 페놀, 푸르푸릴알콜(furfuryl alcohol), 테트라하이드로푸르푸릴 알콜 및 디아세톤 알콜로 구성된 군으로부터 선택된 알콜용매; 프로판디올, 부탄디올, 헥산디올, 메틸프로판디올, 사이클로헥산디올, 2-메틸-2,4-펜탄디올, 1,2,6-헥산트리올, 티오디글리콜(thiodiglycol), 솔비톨(sorbitol), 만니톨(mannitol), 미오이노시톨(myoinositol), 글리세롤, 에틸렌글리콜, 디에틸렌 글리콜, 트리에틸렌 글리콜, 테트라에틸렌 글리콜, 폴리에텔렌 글리콜, 폴리에틸렌 글리콜, 프로필렌 글리콜 및 폴리프로필렌 글리콜로 이루어진 군으로부터 선택된 다가알콜(polyhydric alcohol) 용매; 테트라하이드로퓨란, 디옥산; 에틸렌 글리콜 모노메틸에테르, 에틸렌 글리콜 모노에틸에테르, 에틸렌 글리콜 모노프로필에테르, 에틸렌 글리콜 모노부틸에테르, 에틸렌 글리콜 디메틸에테르, 에틸렌 글리콜 디에틸에테르, 에틸렌 글리콜 디프로필에테르, 에틸렌 글리콜 디부틸에테르, 디에틸렌 글리콜 모노메틸에테르, 디에틸렌 글리콜 모노에틸에테르, 디에틸렌 글리콜 모노프로필에테르, 디에틸렌 글리콜 모노부틸에테르, 디에틸렌 글리콜 디메틸에테르, 디에틸렌 글리콜 디에틸에테르, 디에틸렌 글리콜 디프로필에테르, 디에틸렌 글리콜 디부틸에테르, 트리에틸렌 글리콜 모노메틸에테르, 트리에틸렌 글리콜 모노에틸에테르, 트리에틸렌 글리콜 모노프로필에테르, 트리에틸렌 글리콜 모노부틸에테르, 트리에틸렌 글리콜 디메틸에테르, 트리에틸렌 글리콜 디에틸에테르, 트리에틸렌 글리콜 디프로필에테르, 트리에틸렌 글리콜 디부틸에테르, 프로필렌 글리콜 모노메틸에테르, 프로필렌 글리콜 모노에틸에테르, 프로필렌 모노프로필에테르, 프로필렌 글리콜 모노부틸에테르, 프로필렌 글리콜 디메틸에테르, 프로필렌 글리콜 디에틸에테르, 프로필렌 글리콜 디프로필에테르, 프로필렌 글리콜 디부틸에테르, 디프로필렌 글리콜 디메틸에테르, 디프로필렌 글리콜 디에틸에테르, 디프로필렌 글리콜 디프로필에테르, 디프로필렌 글리콜 디부틸에테르;에틸 아세테이트; 에틸렌 카보네이트; 프로필렌 글리콜 라우릴레이트, 에틸렌 글리콜 모노메틸 에틸에테르 아세테이트, 에틸렌 글리콜 모노메틸 프로필에테르 아세테이트, 에틸렌 글리콜 모노메틸 부틸에테르 아세테이트, 디에틸렌 글리콜 모노메틸 에틸에테르 아세테이트, 디에틸렌 글리콜 모노메틸 프로필에테르 아세테이트, 디에틸렌 글리콜 모노메틸 부틸에테르 아세테이트, 프로필렌 글리콜 모노메틸 에틸에테르 아세테이트, 프로필렌 글리콜 모노메틸 프로필에테르 아세테이트, 프로필렌 글리콜 모노메틸 부틸에테르 아세테이트, 디프로필렌 글리콜 모노메틸 에틸에테르 아세테이트, 디프로필렌 글리콜 모노메틸 프로필에테르 아세테이트, 디프로필렌 글리콜 모노메틸 부틸에테르 아세테이트; γ-부티로락톤을 포함한 락톤; 2-피롤리돈(2-pyrrolidone), N-피롤리돈(N-pyrrolidone), N-(2-하이드록시에틸)피롤리돈, N-메틸-2-피롤리돈 및 1, 3-디메틸-2-이미다졸리디논(1, 3-dimethyl-2-imidazolidinone)을 포함하는 락탐계; 셀로솔브 및 아세톤을 포함하는 케톤류; 및 술포란(sulfolane), 디메틸술폭사이드 및 테트라메틸렌 술폰(tetramethylene sulfone)을 포함하는 황(sulfur) 함유 유기용매로 이루어진 군으로부터 선택된 용매; 부탄, 헥산, 사이클로헥산, 옥탄 및 사이클로옥탄, 노난, 도데칸, 헥사데칸 및 톨루엔으로 이루어진 군으로부터 선택된 탄화수소 용매를 사용한다.Examples of the organic solvent include methanol, ethanol, n-propanol, i-propanol, butanol, t-butanol, i-butanol, hexanol, , Nonanol, i-nonanoldodecanol, i-dodecanol, hexadecanol, i-hexadecanol, phenol, furfuryl alcohol, tetrahydrofurfuryl alcohol and diacetone alcohol Alcohol solvent; Propanediol, butanediol, hexanediol, methylpropanediol, cyclohexanediol, 2-methyl-2,4-pentanediol, 1,2,6-hexanetriol, thiodiglycol, sorbitol, mannitol polyhydric alcohols selected from the group consisting of mannitol, myoinositol, glycerol, ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, polyether glycol, polyethylene glycol, propylene glycol and polypropylene glycol. alcohol) solvent; Tetrahydrofuran, dioxane; Ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dipropyl ether, ethylene glycol dibutyl ether, diethylene glycol Monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether, diethylene glycol dibutyl Ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, triethylene glycol monobutyl ether, triethylene glycol dimethyl ether, triethylene glycol diethyl ether, tri Propylene glycol monomethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol di (meth) acrylate, diethylene glycol di Propyl ether, propylene glycol dibutyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, dipropylene glycol dipropyl ether, dipropylene glycol dibutyl ether, ethyl acetate; Ethylene carbonate; Propylene glycol monomethyl ether acetate, ethylene glycol monomethyl ether acetate, ethylene glycol monomethyl ether acetate, ethylene glycol monomethyl ether acetate, diethylene glycol monomethyl ether acetate, diethylene glycol monomethyl propyl ether acetate, diethylene glycol monomethyl ether acetate, Propylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, Propylene glycol monomethyl butyl ether acetate; lactones including? -butyrolactone; Pyrrolidone, N-pyrrolidone, N- (2-hydroxyethyl) pyrrolidone, N-methyl-2-pyrrolidone and 1,3- 2-imidazolidinone); < / RTI > Ketones including cellosolve and acetone; And a sulfur-containing organic solvent including sulfolane, dimethylsulfoxide and tetramethylene sulfone; Butane, hexane, cyclohexane, octane and cyclooctane, nonane, dodecane, hexadecane and toluene.

본 발명에 따른 잉크 조성물의 제조방법은 다음과 같다.The method for producing the ink composition according to the present invention is as follows.

잉크에 물과 올리고머 분산제를 혼합하고, 필요에 따라서 유기용매를 부가한 다음, 안료를 넣어 분산시킨다. 이렇게 우선적으로 고농축된 잉크를 준비한 다음, 잉크 프린터용에 적합하도록 적당한 농도로 희석하여 점도, 표면장력, 색상, 밝기 등의 물리적 현상을 조절한다.Water and an oligomer dispersant are mixed in the ink, an organic solvent is added if necessary, and the pigment is dispersed by adding the pigment. Such highly concentrated ink is first prepared and then diluted to an appropriate concentration suitable for use in an ink printer to control physical phenomena such as viscosity, surface tension, color, and brightness.

이하, 본 발명을 실시예를 들어 상세히 설명하기로 하되, 본 발명이 하기 실시예로만 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.

하기 실시예 및 비교예에 따라 제조된 잉크의 특성평가는 다음과 같이 실시하였다.The properties of the inks prepared according to the following examples and comparative examples were evaluated as follows.

(1) 저장안정성(storage stability)(1) Storage stability

내열성 유리병에 잉크 100ml를 저장한 다음, 입구를 밀봉하고 60℃로 조절된 항온실에 저장하였다. 2달동안 방치한 다음, 잉크를 프린팅에 적용하였다.After storing 100 ml of ink in a heat-resistant glass bottle, the inlet was sealed and stored in a constant temperature room controlled at 60 ° C. After standing for two months, the ink was applied to the printing.

○: 이상이 발견되지 않음○: No abnormality was found

×: 잉크 토출이 어렵거나 변색이 발생됨×: Ink ejection is difficult or discoloration occurs

(2) 광학농도(Optical Density: OD)(2) Optical Density (OD)

프린트물의 광학밀도를 굴절밀도측정기(reflectodensitometer)를 이용하여 측정하였다. 황색, 청록색, 자홍색 및 흑색의 평균 O.D.가 하기 기준에 따라 평가되었다.The optical density of the print was measured using a reflectodensitometer. The average OD of yellow, cyan, magenta and black was evaluated according to the following criteria.

○: 1.0 이상○: 1.0 or more

△: 0.9∼1.0?: 0.9 to 1.0

×: 0.9 미만X: less than 0.9

(3) 번짐(bleeding)(3) bleeding

상이한 칼라를 서로 인접하여 인쇄한 칼라 시료를 준비하며, 황색(yellow), 청록색(cyan), 자홍색(magenta)의 색상을 겹쳐 돗팅(dotting)하여 형성된 7개 색상(흑색(black), 황색(yellow), 청록색(cyan), 자홍색(magenta), 적색(red), 녹색(green) 및 청색(blue)에 대한 번짐 횟수를 조사하였다.Color samples prepared by printing different colors adjacent to each other were prepared, and seven colors (black, yellow, and blue) formed by overlapping colors of yellow, cyan, and magenta were prepared. ), Cyan, magenta, red, green, and blue were examined for the number of smears.

○: 각 색상의 경계선에서 번짐이 없음○: No blurring at each color boundary

△: 많은 양의 잉크를 가했을 때, 적색, 녹색 및 청색의 경계선에서 번짐이 뚜렷함△: When a large amount of ink is applied, clear bleeding is observed at the boundaries of red, green and blue

×: 각 색상의 경계선 모두에서 번짐이 뚜렷함×: Smudge is pronounced at all boundaries of each color

(4) 토출성(ejectability 또는 maintenance)(4) Dischargeability (ejectability or maintenance)

잉크 카트리지를 6시간, 4일, 7일 및 30일동안 방치한 후, 각각의 잉크 토출여부를 측정하였다.After the ink cartridge was left for 6 hours, 4 days, 7 days, and 30 days, the ink ejection was measured.

○: 30일이후에도 토출이 잘 됨○: Good discharge after 30 days

△: 7일 이후에 노즐 막힘 현상이 관찰됨△: nozzle clogging observed after 7 days

□: 4일이후에 노즐 막힘 현상이 관찰됨□: Nozzle clogging observed after 4 days

◇: 6시간이후에 노즐 막힘 현상이 관찰됨◇: Nozzle clogging observed after 6 hours

×: 즉시 노즐이 막힘X: Immediately blocked the nozzle

(5) 내수성(water fastness)(5) Water fastness

프린터물을 물에 담갔을 때 잉크가 물에 나오는 정도를 조사하기 위하여 광학농도를 측정하였다.The optical density was measured to determine the extent to which the ink came into the water when the printer water was immersed in water.

○: 광학농도의 변화가 10% 미만임○: Change in optical density is less than 10%

△: 광학농도의 변화가 10 내지 30% 정도임DELTA: Change in optical density is about 10 to 30%

×: 광학농도의 변화가 30% 초과임X: Change in optical density exceeds 30%

(6) 내광성(light fastness)(6) Light fastness

프린터물을 UV램프(파장 : 약 254nm)아래 약 1달동안 놓았을 때에 잉크가 바래는 정도를 살펴보기 위하여 광학농도를 측정하였다.The optical density was measured to determine the extent to which the printer faded when the printer water was placed under the UV lamp (wavelength: about 254 nm) for about a month.

○: 광학농도의 변화가 5% 미만임○: Change in optical density is less than 5%

△: 광학농도의 변화가 5 내지 20%임DELTA: Change in optical density is 5 to 20%

×: 광학농도의 변화가 20% 초과함.×: Change in optical density exceeds 20%.

(7) 프린터 헤드의 신뢰성(reliability)(7) Reliability of the print head

하나의 잉크 카트리지에 500ml 이상의 잉크를 사용하였을 때 프린터 헤더에 코게이션(kogation) 현상 여부를 현미경을 이용하여 조사하였다.When more than 500 ml of ink was used in one ink cartridge, the presence or absence of kogation in the printer header was examined using a microscope.

○: 코게이션이 일어나지 않음○: No kogation occurs

×: 코게이션이 일어남X: Cogation occurs

실시예 1Example 1

프로필옥시-폴리프로필렌 글리콜 2-부틸아민(propyloxy-polypropylene glycol 2-butylamine) 4.20 중량%, 에탄올 7.00 중량% 및 물 17.80 중량%의 혼합물을 약 15분동안 교반하여 올리고머 용액을 준비하였다.A mixture of 4.20 wt% propyloxy-polypropylene glycol 2-butylamine, 7.00 wt% ethanol and 17.80 wt% water was stirred for about 15 minutes to prepare an oligomer solution.

상기 올리고머 용액에 퀸도 마젠타(Quindo Magenta: Mobay사) 5.00 중량%, 디에킬렌 글리콜 모노에틸에테르 16.00 중량% 및 물 20.00 중량%를 부가하여 충분히 혼합한 다음, 여기에 30.00 중량%의 물을 더 부가하여 희석하였다.5.00% by weight of Quindo Magenta (Mobay), 16.00% by weight of diethylene glycol monoethyl ether and 20.00% by weight of water were added to the oligomer solution, and 30.00% by weight of water was further added thereto And diluted.

상기 결과물을 여과하여 잉크 젯트 프린터용으로 사용하였다.The resultant was filtered and used for an ink jet printer.

실시예 2Example 2

메틸에틸아미노 폴리부틸렌 글리콜 벤조산(methylethylamino polybutylene glycol benzoic acid) 7.50 중량%에 1,4-부탄디올 5.00 중량% 및 물 12.50 중량%를 부가한 다음, 약 30분동안 혼합하여 올리고머 용액을 준비하였다.5.00 wt.% Of 1,4-butanediol and 12.50 wt.% Of water were added to 7.50 wt.% Of methylethylamino polybutylene glycol benzoic acid, and then mixed for about 30 minutes to prepare an oligomer solution.

상기 올리고머 용액에 카본 블랙(Raven 1170: Columbia Chemicals) 6.50 중량%, 카보왁스(carbowax) 3.50 중량%, 에틸렌 글리콜 15 중량% 및 물 20.00 중량%을 부가하여 혼합한 다음, 30.00 중량%의 물을 더 부가하여 희석하였다.6.50% by weight of carbon black (Raven 1170: Columbia Chemicals), 3.50% by weight of carbowax, 15% by weight of ethylene glycol and 20.00% by weight of water were added to the oligomer solution and then 30.00% And further diluted.

실시예 3Example 3

디에틸아미노 프로필옥시 폴리사이클로헥실렌 티오글리콜(diethylamino propyloxy polycyclohexylene glycol) 3.00 중량%, 디부틸아미노 폴리사이클로헥실렌 글리콜 글루코스(dibutylamino polycyclohexylene glycol glucose) 2.00 중량%, 메탄올 5.00중량% 및 물 15.00 중량%를 약 20분동안 혼합하여 올리고머 용액을 준비하였다.3.00% by weight of diethylaminopropyl propyloxy polycyclohexylene glycol, 2.00% by weight of dibutylaminocyclohexylene glycol glucose, 5.00% by weight of methanol and 15.00% by weight of water, The oligomer solution was prepared by mixing for about 20 minutes.

상기 올리고머 용액에 헬리오겐 블루 L690F(Heliogen blue L6901F: BASF사) 5.00 중량%, 프로필렌 글리콜 15.00 중량% 및 물 25.00 중량%를 부가한 다음, 물 30.00 중량%를 부가하여 희석하였다.To the oligomer solution, 5.00% by weight of Heliogen blue L6901F (BASF), 15.00% by weight of propylene glycol and 25.00% by weight of water were added, followed by addition of 30.00% by weight of water to dilute.

상기 결과물을 여과하여 잉크 젯트 프린터용에 사용하였다.The resultant was filtered and used for an ink jet printer.

실시예 4Example 4

비페닐아미노 폴리페닐에틸렌 티오글리콜일 2-페닐술폰산(biphenylamino polyphenylethylene thioglycolyl 2-phenylsulfuric acid) 7.00 중량%, 에탄올 4.00 중량 및 물 14.00 중량%의 혼합물을 약 15분동안 교반하여 올리고머 용액을 준비하였다.A mixture of 7.00% by weight of biphenylaminopolyphenylethylene thioglycolyl 2-phenylsulfuric acid, 4.00% by weight of ethanol and 14.00% by weight of water was stirred for about 15 minutes to prepare an oligomer solution.

상기 올리고머 용액에 크로모탈 옐로우(Chromophtal Yellow 3G: Ciba-Geigy) 7.50중량%와, 카보왁스 3.50 중량%, 에틸렌 글리콜 15.00 중량% 및 물 19.00 중량%를 부가한 다음, 물 30.00 중량%를 부가하여 희석하였다.7.50% by weight of Chromophthal Yellow (Ciba-Geigy), 3.50% by weight of carbo-wax, 15.00% by weight of ethylene glycol and 19.00% by weight of water were added to the oligomer solution, and 30.00% Respectively.

비교예 1Comparative Example 1

P(MAA/n-BA) 8.00 중량%, 디에틸아미노 에탄올(diethylamino ethanol: DMAE) 0.5중량%, 메탄올 8.00 중량% 및 물 13.00 중량%의 혼합물을 약 15분동안 교반하여 고분자 용액을 준비하였다.A polymer solution was prepared by stirring a mixture of 8.00% by weight of P (MAA / n-BA), 0.5% by weight of diethylamino ethanol (DMAE), 8.00% by weight of methanol and 13.00% by weight of water for about 15 minutes.

상기 고분자 용액에 아조메티오닌(azomethione) (Pigment yellow: BASF) 5.00 중량%와, 카르보왁스 2.50 중량%, 에틸렌 글리콜 15.00 중량% 및 물 20.00 중량%를 부가한 다음, 물 30.00 중량%를 부가하여 희석하였다.5.00% by weight of azomethione (Pigment yellow: BASF), 2.50% by weight of carbo wax, 15.00% by weight of ethylene glycol and 20.00% by weight of water were added to the polymer solution, and 30.00% Respectively.

상기 실시예 1-4 및 비교예에 따라 제조된 잉크의 pH, 점도 및 표면장력을 측정하여 다음의 표 1에 나타내었다.The pH, the viscosity and the surface tension of the ink prepared according to Examples 1-4 and Comparative Examples were measured and shown in Table 1 below.

[표 1][Table 1]

구분division pHpH 점도(cp)Viscosity (cp) 표면장력(dyne/cm)Surface tension (dyne / cm) 실시예 1Example 1 8.98.9 3.23.2 5252 실시예 2Example 2 6.56.5 3.53.5 4848 실시예 3Example 3 8.48.4 2.92.9 5252 실시예 4Example 4 6.86.8 3.53.5 4747 비교예Comparative Example 8.98.9 4.54.5 5959

표 1로부터, 합성이 용이한 올리고머 분산제를 사용하는 실시예 1-4의 경우에는 비교예에 따른 잉크 조성물에 있어서 비교예의 경우에 발생되는 층분리현상이 나타나지 않았다. 뿐만 아니라, 분산제의 농도변화에 따른 점도 등의 물리적 성질의 변화가 적기 때문에 농도 선정이 비교적 자유로왔다.From Table 1, in Examples 1-4 in which an oligomer dispersant easy to synthesize was used, no layer separation phenomenon occurred in the comparative example in the ink composition according to Comparative Example. In addition, the selection of the concentration is relatively free since the physical properties such as the viscosity change with the change of the concentration of the dispersing agent are small.

반면, 고분자 분산제를 사용한 비교예의 경우에는 용해도가 낮기 때문에 고분자 용액을 제조하는 것이 매우 힘들었으며, 안료에 대한 고분자 분산제의 선정이 어려웠을 뿐만 아니라 적은 양의 변화에 대해서도 물리적 변화가 크기 때문에 잉크 제조가 대단히 어려웠다. 또한 올리고머 용액에서는 나타나지 않았던 층분리 현상이 나타났다.On the other hand, in the case of the comparative example using a polymer dispersant, it was very difficult to prepare a polymer solution because of low solubility. In addition to the difficulty in selecting a polymer dispersant for a pigment, It was very difficult. Also, layer separation phenomenon, which was not observed in the oligomer solution, appeared.

상기 실시예 1-4 및 비교예 1에 따라 제조된 잉크 조성물에 있어서, 저장안정성, 번짐현상, 광학밀도, 토출성, 내수성, 내광성 및 프린터 헤드 특성을 측정한 결과 다음의 표 2와 같았다.The ink compositions prepared according to Examples 1-4 and Comparative Example 1 were measured for storage stability, blurring, optical density, dischargeability, water resistance, light resistance and printer head characteristics, and the results are shown in Table 2 below.

[표 2][Table 2]

구분division 저장안정성Storage stability 광학농도Optical density 번짐Smear 토출성Dischargeability 내수성Water resistance 내광성Light resistance 프린터헤드의신뢰성Printer head reliability 실시예 1Example 1 ○○ ○○ ○○ ○○ ○○ ○○ ○○ 실시예 2Example 2 ○○ ○○ ○○ ○○ ○○ ○○ ○○ 실시에 3Implementation 3 ○○ ○○ ○○ ○○ ○○ ○○ ○○ 실시예 4Example 4 ○○ ○○ ○○ ○○ ○○ ○○ ○○ 비교예 1Comparative Example 1 ×× △△ ×× ×× ○○ ○○ ××

상기 표 2로부터, 실시예 1-4의 경우에는 저장안정성 및 광학밀도가 우수할 뿐만 아니라, 각 색상의 경계선에서 번짐 횟수가 매우 적었다.From Table 2, in the case of Examples 1-4, not only the storage stability and optical density were excellent but also the number of times of spreading was very small at the border of each color.

반면, 비교예의 경우에는 상기 실시예의 경우와 비교하여 광학특성 및 번짐특성이 불량할 뿐만 아니라, 층분리로 인하여 저장안정성이 불량하였고 코게이션 현상이 뚜렷하게 관찰되었다.On the other hand, in the case of the comparative example, not only the optical characteristics and the spreading property were poor, but the storage stability was poor due to the layer separation and the kogation phenomenon was observed clearly as compared with the case of the above example.

본 발명에 따른 잉크 조성물은 제조하기가 용이할 뿐만 아니라, 친수성기와 안료와 상호작용할 수 있는 정착그룹을 갖는 올리고머 분산제를 함유하고 있어서 인쇄적성, 내수성 및 내광성이 우수할 뿐만 아니라 저장안정성이 매우 양호하다.The ink composition according to the present invention is not only easy to produce, but also contains an oligomer dispersant having a fixing group capable of interacting with a pigment and a hydrophilic group, and is excellent in printability, water resistance, light resistance and storage stability .

Claims

1. An ink composition for an ink jet printer comprising a pigment, a dispersant and a solvent,

Wherein the dispersing agent is an AB type oligomer.

Wherein A is a single component having no repeatability and represents an anchoring group which interacts with the pigment,

C ₁ ~C ₃₀ alkyloxy or C ₁ ~C ₃₀ alkyloxy, C ₁ ~C ₃₀ alkenyloxy, or C ₁ ~C ₃₀ alkenyl group having at least one substituent (G) having at least one substituent (G) oxy, C ₁ ~C ₃₀ alkynyloxy, or C ₁ ~ with at least one substituent (G) C ₁ ~C ₃₀ alkynyloxy, C ₁ ~C ₃₀ cycloalkyloxy or at least one substituent (G) having a C ₃₀ cycloalkyloxy, C ₁ ~C ₃₀ cycloalkyl alkenyloxy or at least one substituent (G) C ₁ ~C ₃₀ cycloalkyl alkenyloxy having, C ₁ ~C ₃₀ cycloalkyl alkynyloxy or at least one substituent ( C ₁ to C ₃₀ cycloalkenyloxy, C _{1 to} C ₃₀ heterocycloalkyloxy or C ₁ to C ₃₀ heterocycloalkyloxy having at least one substituent (G), C _{1 to} C ₃₀ heterocycloalkyl alkenyloxy or C ₁ ~C ₃₀ heterocycloalkyl alkenyloxy having at least one substituent (G), C ₁ C ₃₀ heterocycloalkyl alkynyloxy or C ₁ ~C having at least one substituent (G) ₃₀ heterocycloalkyl alkynyloxy, monosaccharides, polysaccharides and polysaccharide oxy, sorbitan aryloxy, C ₆ ~C ₅₀ unsubstituted mono-, bi- , Aromatic oxy which is a tri and polycyclic ring or aromatic oxy which is a C ₆ -C ₅₀ substituted mono-, bi, tri and polycyclic ring having at least one substituent (G)

C ₁ ~C ₃₀ alkylthio or C ₁ ~C ₃₀ alkylthio, C ₁ ~C ₃₀ alkenyl thio or C ₁ ~C ₃₀ alkenyl group having at least one substituent (G) having at least one substituent (G) thio, C ₁ ~ having a C ₁ ~C ₃₀ alkynyl thiol or at least one substituent (G) C ₁ ~C ₃₀ alkynyl, thio, C ₁ ~C ₃₀ cycloalkyl thio or at least one substituent (G) having a cycloalkyl C ₃₀ alkylthio, C ₁ ~C ₃₀ cycloalkenyl alkylthio or C ₁ ~C ₃₀ cycloalkenyl alkylthio, C ₁ ~C ₃₀ cycloalkyl alkynyl thio or at least one substituent having at least one substituent (G) ( G) a C ₁ ~C ₃₀ cycloalkyl alkynyl, thio, C ₁ ~C ₃₀ heterocycloalkyl alkylthio or C ₁ ~C having at least one substituent (G) heterocycloalkyl ₃₀ alkylthio, C ₁ ~C ₃₀ heterocycloalkyl having alkenyl thio or C ₁ ~C ₃₀ hetero cycloalkenyl alkylthio having at least one substituent (G), C ₁ C ₃₀ heterocycloalkyl alkynyl thio or C ₁ ~C having at least one substituent (G) ₃₀ heterocycloalkyl alkynyl thio, monosaccharides, polysaccharides and polysaccharide alkylthio, sorbitan alkylthio, C ₆ ~C ₅₀ unsubstituted mono-, bi- , Aromatic thio which is a tri and polycyclic ring, or aromatic thio which is a C ₆ -C ₅₀ substituted mono-, bi-, tri- and polycyclic ring having at least one substituent (G)

C ₁ ~C ₃₀ alkyl amine or C ₁ ~C ₃₀ alkyl amines, C ₁ ~C ₃₀ alkyl amine or oxy-C ₁ ~C ₃₀ alkyl aryloxy having at least one substituent (G) having at least one substituent (G) amine, C ₁ ~C ₃₀ alkenyl, C ₁ ~C ₃₀ alkenyl amines or Al having at least one substituent (G) amine, C ₁ ~C ₃₀ alkynyl amines or alkynyl amine having at least one substituent (G) , C ₁ ~C ₃₀ cycloalkyl, (cycloalkyl) amine or at least one substituent (G) C ₁ ~C ₃₀ cycloalkyl amine, C ₁ ~C ₃₀ cycloalkenyl (cycloalkenyl) amines, or at least one substituent group having a (G ) having a C ₁ ~C ₃₀ cycloalkenyl amine, C ₁ ~C ₃₀ cycloalkyl alkynyl (cycloalkynyl) amine or a C ₁ ~C ₃₀ cycloalkyl alkynyl amine, C ₁ ~C ₃₀ having at least one substituent (G) C ₁ -C ₃₀ heterocycloalkylamines having at least one substituent (G), C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) amines, or C ₁ ~C ₃₀ hetero cycloalkenyl amine, C ₁ ~C ₃₀ alkynyl heterocycloalkyl (cycloalkynyl) or at least one substituent having at least one substituent (G) C ₁ ~C ₃₀ heterocycloalkyl alkynyl amine, monosaccharides, disaccharides, and polysaccharides, amines, sorbitan (sorbitan) amine, C ₆ ~C ₅₀ unsubstituted mono-, bi-, tri and polycyclic having a (G) an aromatic amine Whanin or C ₆ ~C ₅₀ substituted mono, bi, tri and polycyclic having at least one substituent (G) Whanin aromatic amine,

C ₁ ~C ₃₀ alkyl amide or C ₁ ~C having at least one substituent (G) ₃₀ alkylamide, C ₁ ~C ₃₀ alkyloxy amide or C ₁ ~C ₃₀ alkyl aryloxy having at least one substituent (G) amides, C ₁ ~C ₃₀ alkenyl amides, or at least one C ₁ ~C ₃₀ alkenyl Al having a substituent (G) amides, C ₁ ~C ₃₀ alkynyl amides or alkynyl amide having at least one substituent (G) C ₁ -C ₃₀ cycloalkyl amide or C ₁ -C ₃₀ cycloalkyl amide having at least one substituent (G), C ₁ -C ₃₀ cycloalkenyl amide or at least one substituent (G ) having a C ₁ ~C ₃₀ cycloalkyl alkenyl amides, C ₁ ~C ₃₀ cycloalkyl alkynyl (cycloalkynyl) amide, or C ₁ ~C ₃₀ cycloalkyl alkynyl amide, C ₁ ~C ₃₀ having at least one substituent (G) A cycloalkyl amide or C ₁ < RTI ID = 0.0 > ~C ₃₀ heterocycloalkyl amide, C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) amide, or C having at least one substituent (G) ₁ ~C ₃₀ hetero cycloalkenyl amide, C ₁ ~C ₃₀ alkynyl heterocycloalkyl Cycloalkynyl amides or C ₁ -C ₃₀ heterocycloalkynyl amides, monosaccharides, disaccharides and polysaccharide amides having at least one substituent (G), sorbitan amide, C ₆ -C ₅₀ unsubstituted mono, And aromatic amides which are C ₆ -C ₅₀ substituted mono-, bi-, tri- and polycyclic rings having at least one substituent (G)

(Wherein the substituent (G) is a C ₁ ~C ₃₀ alkyl, C ₁ ~C ₃₀ hydroxyalkyl, C ₁ ~C ₃₀ dihydro-thioalkyl, C ₁ ~C ₃₀ alkyl nitro, C ₁ ~C ₃₀ cyanoalkyl , C ₁ -C ₃₀ thiocanoalkyl, C ₁ -C ₃₀ alkyloxy, C ₁ -C ₃₀ alkylthio, C ₁ -C ₃₀ alkenyl, C ₁ -C ₃₀ hydroxyalkenyl, C ₁ -C ₃₀ dihydro-thio alkenyl, C ₁ ~C ₃₀ alkenyl, nitro, C ₁ ~C ₃₀ alkenyl noal cyano, C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ alkenyloxy, C ₁ ~C ₃₀ alkenyl C ₁ -C ₃₀ alkynyl, C ₁ -C ₃₀ hydroxyalkynyl, C ₁ -C ₃₀ hydrothioalkynyl, C ₁ -C ₃₀ nitroalkynyl, C ₁ -C ₃₀ cyanoalkynyl, C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ alkynyloxy, C ₁ ~C ₃₀ alkynyl, thio,

C ₁ ~C ₃₀ cycloalkyl, C ₁ ~C ₃₀ hydroxyalkyl cycloalkyl, C ₁ ~C ₃₀ cycloalkyl dihydro-thio, C ₁ ~C ₃₀ alkyl, nitro sayikeu chloride, C ₁ ~C ₃₀ cycloalkyl, cyano, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ cycloalkyloxy, C ₁ ~C ₃₀ cycloalkyl alkylthio, C ₁ ~C ₃₀ cycloalkenyl, C ₁ ~C ₃₀ hydroxy cycloalkenyl, C ₁ ~ C ₃₀ alkylthio dihydro cycloalkenyl, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C _30-cyano cycloalkenyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkenyloxy C ₁ -C ₃₀ cycloalkenylthio, C ₁ -C ₃₀ cycloalkynyl, C ₁ -C ₃₀ hydroxycycloalkynyl, C ₁ -C ₃₀ hydrothothicycloalkynyl, C ₁ -C ₃₀ -nitrocycloalkoxy carbonyl, C ₁ ~C _{30-cyano-alkynyl} cycloalkyl, C ₁ ~C ₃₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₃₀ cycloalkenyl Aryloxy carbonyl, C ₁ ~C ₃₀ cycloalkyl alkynyl thio,

C ₁ -C ₃₀ heterocycloalkyl, C ₁ -C ₃₀ hydroxyheterocycloalkyl, C ₁ -C ₃₀ hydrothioheterocycloalkyl, C ₁ -C ₃₀ nitroheterocycloalkyl, C ₁ -C ₃₀ cyanohetero C ₁ -C ₃₀ thiocyanoheterocycloalkyl, C ₁ -C ₃₀ heterocycloalkyloxy, C ₁ -C ₃₀ heterocycloalkylthio, C ₁ -C ₃₀ heterocycloalkenyl, C ₁ -C ₃₀ hydroxy-alkenyl heterocycloalkyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkenyl, C ₁ ~C ₃₀ hetero nitro cycloalkenyl, C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C ₃₀ thio-dicyano C _{1 to} C ₃₀ heterocycloalkenyloxy, C _{1 to} C ₃₀ heterocycloalkenylthio, C _{1 to} C ₃₀ heterocycloalkynyl, C _{1 to} C ₃₀ hydroxyheterocycloalkynyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkynyl , C ₁ ~C ₃₀ nitro heterocycloalkyl alkynyl, C ₁ ~C _{30-cyano-heterocycloalkyl} alkynyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkynyl, C ₁ ~C ₃₀ heterocycloalkyl alkynyloxy, C ₁ To C ₃₀ heterocycloalkynylthio,

C ₆ ~C ₃₀ aromatic, substituted aromatic, amino, substituted amino, imine, substituted imine the C ₆ ~C _30, amidino (amidino), hydrazine, hydrazone, substituted hydrazine, substituted hydrazone, amide, substituted amide, halide (halide), hydroxy (OH), nitro group (nO _2), cyano (CN), thio-dicyano (SCN), thiol (SH), carboxyl (COOH), carboxylic alkali salt of the acid (COO ^_ M ^+, where M is an alkali metal Im), sulfonic acid (SO ₃ H), alkali salt of the sulfonic acid (SO ₃ ^{^-} M ^-, where M are the alkali metal), phosphoric acid (H ₃ PO ₄ ) and an alkali salt of phosphoric acid (H ₂ PO ₄ ^- M ⁺ , wherein M is an alkali metal);

Part B has the structural formula (1)

[Chemical Formula 1]

(CD) _c - (EF) _e - (HI) _{h -} R ₁

Wherein,

C, E and H are independently selected from C ₁ -C ₂₀ alkyl or C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkenyl or at least one substituent (G) with at least one substituent (G) C ₁ -C ₂₀ alkenyl, C ₁ -C ₂₀ alkynyl or C ₁ -C ₂₀ alkynyl having at least one substituent (G), C ₁ -C ₂₀ cycloalkyl or at least one substituent (G) C ₁ ~C ₂₀ cycloalkyl, C ₁ ~C ₂₀ cycloalkenyl (cycloalkenyl) or C ₁ ~C ₂₀ cycloalkenyl having at least one substituent (G), C ₁ ~C ₂₀ cycloalkyl alkynyl having carbonyl (cycloalkynyl) or C ₁ ~C having at least one substituent (G) ₂₀ cycloalkyl alkynyl, C ₁ ~C ₂₀ heterocycloalkyl C ₁ ~C ₂₀ hetero having a (cycloalkyl) or at least one substituent (G) cycloalkyl, C ₁ ~C ₂₀ hetero cycloalkenyl (cycloalkenyl) or C ₁ ~C ₂₀ heterocyclic having at least one substituent (G) Roal alkenyl, C ₁ ~C ₂₀ alkynyl heterocycloalkyl (cycloalkynyl) or C ₁ ~C ₂₀ heterocycloalkyl alkynyl, monosaccharides, disaccharides, and polysaccharides, sorbitan (sorbitan) having at least one substituent (G), C ₆ ~ C ₅₀ unsubstituted mono-, bi-, tri and polycyclic aromatic Whanin or at least one C ₆ ~C having a substituent group (G) of the _{50-substituted} mono, bi, tri and polycyclic aromatic Whanin,

C ₁ -C ₂₀ alkyloxy or C ₁ -C ₂₀ alkyloxy having at least one substituent (G), C ₁ -C ₂₀ alkenyloxy or C ₁ -C ₂₀ alkenyl having at least one substituent (G) oxy, C ₁ ~C ₂₀ alkynyloxy, or C ₁ ~ with at least one substituent (G) C ₁ ~C ₂₀ alkynyloxy, C ₁ ~C ₂₀ cycloalkyloxy or at least one substituent (G) having a C ₂₀ cycloalkyloxy, C ₁ ~C ₂₀ cycloalkyl alkenyloxy or C ₁ ~C having at least one substituent (G) ₂₀ cyclo alkenyloxy, C ₁ ~C ₂₀ cycloalkyl alkynyloxy or at least one substituent ( C ₁ -C ₂₀ cycloalkynyloxy, C ₁ -C ₂₀ heterocycloalkyloxy or C ₁ -C ₂₀ heterocycloalkyloxy having at least one substituent (G), C ₁ -C ₂₀ heterocycloalkyl alkenyloxy or C ₁ ~C ₂₀ heterocycloalkyl alkenyloxy having at least one substituent (G), C ₁ C ₂₀ heterocycloalkyl alkynyloxy or C ₁ ~C having at least one substituent (G) ₂₀ heterocycloalkyl alkynyloxy, monosaccharides, polysaccharides and polysaccharide oxy, sorbitan aryloxy, C ₆ ~C ₅₀ unsubstituted mono-, bi- , Aromatic oxy, which is a tri and polycyclic ring, or a C ₆ -C ₅₀ substituted mono-, bi, tri, and polycyclic ring having at least one substituent (G)

C ₁ ~C ₂₀ alkylthio or C ₁ ~C ₂₀ alkylthio, C ₁ ~C ₂₀ alkenyl thio or C ₁ ~C ₂₀ alkenyl group having at least one substituent (G) having at least one substituent (G) thio, C ₁ ~ C ₁ ~C ₂₀ alkynyl having a thiol group or at least one substituent (G) C ₁ ~C ₂₀ alkynyl, thio, C ₁ ~C ₂₀ cycloalkyl or a thiol at least one substituent (G) having a cycloalkyl C ₂₀ alkylthio, C ₁ ~C ₂₀ cycloalkenyl thiol or C ₁ ~C ₂₀ cycloalkenyl alkylthio, C ₁ ~C ₂₀ cycloalkyl alkynyl, thiol, or at least one substituent having at least one substituent (G) ( G) a C ₁ ~C ₂₀ cycloalkyl alkynyl, thio, C ₁ ~C ₂₀ heterocycloalkyl alkylthio or C ₁ ~C having at least one substituent (G) heterocycloalkyl ₂₀ alkylthio, C ₁ ~C ₂₀ heterocycloalkyl having alkenyl thio or C ₁ ~C ₂₀ hetero cycloalkenyl alkylthio having at least one substituent (G), C ₁ C ₂₀ heterocycloalkyl alkynyl thio or C ₁ ~C having at least one substituent (G) ₂₀ heterocycloalkyl alkynyl thio, monosaccharides, polysaccharides and polysaccharide alkylthio, sorbitan alkylthio, C ₆ ~C ₅₀ unsubstituted mono-, bi- , Aromatic thio which is a tri and polycyclic ring, or aromatic thio which is a C ₆ -C ₅₀ substituted mono-, bi-, tri- and polycyclic ring having at least one substituent (G)

C ₁ -C ₂₀ alkylamine or C ₁ -C ₂₀ alkylamine having at least one substituent (G), C ₁ -C ₂₀ alkyloxyamine or C ₁ -C ₂₀ alkyloxy having at least one substituent (G) amine, C ₁ ~C ₂₀ alkenyl or C ₁ ~ amine having at least one substituent (G) C ₁ ~C ₂₀ alkenyl amine, C ₁ ~C ₂₀ alkynyl amine or at least one substituent (G) having a C ₂₀ alkynyl amines, C ₁ ~C ₂₀ cycloalkyl, (cycloalkyl) amine or at least one substituent (G) a C ₁ ~C ₂₀ cycloalkyl amine, C ₁ ~C ₂₀ cycloalkenyl (cycloalkenyl) amines, or at least having C ₁ -C ₂₀ cycloalkenylamines having one substituent (G), C ₁ -C ₂₀ cycloalkynylamines or C ₁ -C ₂₀ cycloalkynylamines having at least one substituent (G) C ₁ -C ₂₀ heterocycloalkyl or C ₁ -C ₂₀ heterocycloalkyl having at least one substituent (G) C ₁ -C ₂₀ heterocycloalkenylamines or C ₁ -C ₂₀ heterocycloalkenylamines having at least one substituent (G), C ₁ -C ₂₀ heterocycloalkynyl or C ₁ -C ₂₀ heterocycloalkynylamines, monosaccharides, disaccharides and polysaccharide amines having at least one substituent (G), sorbitan amines, C ₆ -C ₅₀ unsubstituted mono-, bi-, tri- and poly- A C ₆ -C ₅₀ substituted mono-, bi, tri and polycyclic ring having at least one substituent (G)

C ₁ ~C ₂₀ alkyl amide or C ₁ ~C having at least one substituent (G) ₂₀ alkylamide, C ₁ ~C ₂₀ alkyloxy amide or C ₁ ~C ₂₀ alkyl aryloxy having at least one substituent (G) amides, C ₁ ~C ₂₀ alkenyl or C ₁ ~ amide having at least one substituent (G) C ₁ ~C ₂₀ alkenyl amides, C ₁ ~C ₂₀ alkynyl amides or at least one substituent (G) having a C ₂₀ alkynyl amides, C ₁ ~C ₂₀ cycloalkyl, (cycloalkyl) amide, or C ₁ ~C ₂₀ cycloalkyl amides having at least one substituent (G), C ₁ ~C ₂₀ cycloalkenyl (cycloalkenyl) amide, or at least one alkenyl C ₁ ~C ₂₀ cycloalkyl having a substituent (G) amides, C ₁ ~C ₂₀ cycloalkyl alkynyl (cycloalkynyl) amide, or C ₁ ~C ₂₀ cycloalkyl alkynyl amides having at least one substituent (G), C ₁ -C ₂₀ heterocycloalkyl amide or at least one substituent (G) C ₁ -C ₂₀ heterocycloalkylamides, C ₁ -C ₂₀ heterocycloalkenyl amides or C ₁ -C ₂₀ heterocycloalkenyl amides having at least one substituent (G), C ₁ -C ₂₀ Cycloalkynyl amides or C ₁ -C ₂₀ heterocycloalkynyl amides, monosaccharides, disaccharides and polysaccharide amides having at least one substituent (G), sorbitan amides, C ₆ -C ₅₀ unsubstituted rings Aromatic amide selected from the group consisting of C ₆ -C ₅₀ substituted mono-, bi-, tri-, and polycyclic rings having at least one substituent (G)

(Wherein the substituent (G) is a C ₁ ~C ₃₀ alkyl, C ₁ ~C ₃₀ hydroxyalkyl, C ₁ ~C ₃₀ dihydro-thioalkyl, C ₁ ~C ₃₀ alkyl nitro, C ₁ ~C ₃₀ cyanoalkyl , C ₁ -C ₃₀ hydrothio cyanoalkyl, C ₁ -C ₃₀ alkyloxy, C ₁ -C ₃₀ alkylthio, C ₁ -C ₃₀ alkenyl, C ₁ -C ₃₀ hydroxyalkenyl, C ₁ -C ₃₀ thio alkenyl, C ₁ ~C ₃₀ alkenyl, nitro, C ₁ ~C ₃₀ alkenyl noal cyano, C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ alkenyloxy, C ₁ ~C ₃₀ alkenyl C ₁ -C ₃₀ alkynyl, C ₁ -C ₃₀ hydroxyalkynyl, C ₁ -C ₃₀ hydrothioalkynyl, C ₁ -C ₃₀ nitroalkynyl, C ₁ -C ₃₀ cyanoalkynyl, C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ alkynyloxy, C ₁ ~C ₃₀ alkynyl, thio,

C ₁ ~C ₃₀ cycloalkyl, C ₁ ~C ₃₀ hydroxyalkyl cycloalkyl, C ₁ ~C ₃₀ cycloalkyl dihydro-thio, C ₁ ~C ₃₀ alkyl, nitro sayikeu chloride, C ₁ ~C ₃₀ cycloalkyl, cyano, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ cycloalkyloxy, C ₁ ~C ₃₀ cycloalkyl alkylthio, C ₁ ~C ₃₀ cycloalkenyl, C ₁ ~C ₃₀ hydroxy cycloalkenyl, C ₁ ~ C ₃₀ alkylthio dihydro cycloalkenyl, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C _30-cyano cycloalkenyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkenyloxy C ₁ -C ₃₀ cycloalkenylthio, C ₁ -C ₃₀ cycloalkynyl, C ₁ -C ₃₀ hydroxycycloalkynyl, C ₁ -C ₃₀ hydrothothicycloalkynyl, C ₁ -C ₃₀ -nitrocycloalkoxy carbonyl, C ₁ ~C _{30-cyano-alkynyl} cycloalkyl, C ₁ ~C ₃₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₃₀ cycloalkenyl Carbonyl oxy. C ₁ -C ₃₀ cycloalkynylthio,

C ₁ -C ₃₀ heterocycloalkyl, C ₁ -C ₃₀ hydroxyheterocycloalkyl, C ₁ -C ₃₀ hydrothioheterocycloalkyl, C ₁ -C ₃₀ nitroheterocycloalkyl, C ₁ -C ₃₀ cyanohetero cycloalkyl, C ₁ ~C ₃₀ thio-dicyano-heterocycloalkyl, C ₁ ~C ₃₀ heterocycloalkyl alkylthio, C ₁ ~C ₃₀ alkenyl heterocycloalkyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkenyl, C ₁ ~ C ₃₀ heterocyclic thio dihydro cycloalkenyl, C ₁ ~C ₃₀ hetero nitro cycloalkenyl, C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C ₃₀ hetero thio when cycloalkenyl cyano, C ₁ ~C ₃₀ C ₁ -C ₃₀ heterocycloalkynyl, C ₁ -C ₃₀ hydroxyheterocycloalkynyl, C ₁ -C ₃₀ thioheterocycloalkynyl, C ₁ -C ₃₀ nitroheterocycloalkynyl, C ₁ -C ₃₀ heterocycloalkenyl, C ₁ -C ₃₀ cyanoheterocycloalkynyl, C _{1 to} C ₃₀ thiocyanoheterocycloalkynyl, C _{1 to} C ₃₀ heterocycloalkynyloxy, C _{1 to} C ₃₀ heterocycloalkynylthio,

R ₁ is C ₁ ~C ₂₀ alkyl, C ₁ ~C ₂₀ alkenyl, C ₁ ~C ₂₀ alkynyl, C ₁ ~C ₂₀ cycloalkyl, C ₁ ~C ₂₀ having a hydrogen or at least one substituent (G) C ₁ -C ₂₀ cycloalkenyl, C ₁ -C ₂₀ cycloalkynyl, C ₁ -C ₂₀ heterocycloalkyl, C ₁ -C ₂₀ heterocycloalkenyl, C ₁ -C ₂₀ cycloalkynyl, and at least one substituent (G) C ₆ ~C ₃₀ mono-, bi-cyclic, tri and poly Whanin _{_{_{aromatic, C 6 ~C 30 C 1 ~C}}} 20 alkyl having at least one substituent (G) with an aromatic substituent, C ₆ ~C ₃₀ aromatic substituent at least C ₁ -C ₂₀ alkenyl having one substituent (G), C ₁ -C ₂₀ alkynyl having a C ₆ -C ₃₀ aromatic substituent and at least one substituent (G), a C ₆ -C ₃₀ aromatic substituent and at least C ₁ ~C ₂₀ cycloalkyl, C ₆ ~C ₃₀ aromatic substituent, and cycloalkenyl having at least one substituent (G), C ₆ ~C ₃₀ room having one substituent (G) Cycloalkynyl having a phenyl substituent and at least one substituent (G), C ₁ -C ₂₀ heterocycloalkyl having a C ₆ -C ₃₀ aromatic substituent and at least one substituent (G), a C ₆ -C ₃₀ aromatic substituent and at least one substituent (G) C ₁ ~C ₂₀ hetero _{_{_{cycloalkenyl, C 6 ~C 30 C 1 ~C}}} 20 having at least one substituent (G) an aromatic heterocycle substituent alkynyl having,

C ₁ ~C ₂₀ alkyl, C ₁ ~C ₂₀ alkenyl, C ₁ ~C ₂₀ alkynyl, C ₁ ~C ₂₀ cycloalkyl, alkenyl, C ₁ ~C ₂₀ cycloalkyl, C ₁ ~C ₂₀ cycloalkyl alkynyl, C ₁ ~C ₂₀ heterocycloalkyl, C ₁ ~C ₂₀ alkenyl heterocycloalkyl and heterocycloalkyl C ₁ ~C ₂₀ alkynyl, C ₆ ~C ₃₀ aromatic having at least one substituent (G) and a substituent from the group consisting of,

C ₁ -C ₂₀ alkylamine or C ₁ -C ₂₀ alkylamine having at least one substituent (G), C ₁ -C ₂ alkyloxyamine or C ₁ -C ₂₀ alkyloxy having at least one substituent (G) amine, C ₁ ~C ₂₀ alkenyl or C ₁ ~ amine having at least one substituent (G) C ₁ ~C ₂₀ alkenyl amine, C ₁ ~C ₂₀ alkynyl amine or at least one substituent (G) having a C ₂₀ alkynyl amines, C ₁ ~C ₂₀ cycloalkyl amine or a C ₁ ~C ₂₀ cycloalkyl amine, C ₁ ~C ₂₀ cycloalkenyl amine or at least one substituent (G) having at least one substituent (G) a C ₁ ~C ₂₀ cycloalkenyl amine, C ₁ ~C ₂₀ cycloalkyl alkynyl amine or at least one substituent (G) C ₁ ~C ₂₀ cycloalkyl alkynyl amine, C ₁ ~C ₂₀ heterocycloalkyl amine having having or C ₁ ~C ₂₀ hetero cycloalkyl amine, C ₁ ~C ₂₀ hetero cycloalkenyl having at least one substituent (G) Min or C ₁ ~C ₂₀ hetero cycloalkenyl having at least one substituent (G) amine, C ₁ ~C ₂₀ heterocycloalkyl alkynyl amine or a C ₁ ~C having at least one substituent (G) ₂₀ heterocycloalkyl alkynyl carbonyl amine, C ₆ ~C ₃₀ mono, bi, tri and polycyclic Whanin aromatic amine or C ₆ ~C ₃₀ mono, bi, tri and polycyclic having at least one substituent (G) Whanin aromatic amine,

C ₆ ~C ₃₀ aromatic substituted with at least one substituent (G) a C ₁ ~C ₂₀ alkyl amines, C ₆ ~C ₃₀ aromatic substituted with at least one of substituents C ₁ ~C ₂₀ alkenyl amine having a (G) having _{_{_{, C 6 ~C 30 C 1 ~C}}} 20 having at least one substituent (G) with an aromatic amine substituted _{_{_{alkynyl, C 6 ~C 30 C 1 ~C}}} 20 cycloalkyl having at least one substituent (G) and an aromatic substituent alkyl amine, C ₆ ~C ₃₀ aromatic substituted with C ₁ ~ with at least one substituent (G) at least one substituent (G), and C ₁ ~C ₂₀ cycloalkenyl amines, C ₆ ~C ₃₀ aromatic substituent having C ₂₀ alkynyl cycloalkyl amine, C ₆ ~C ₃₀ aromatic substituted with C ₁ ~C ₂₀ hetero cycloalkyl amine, C ₆ ~C ₃₀ aromatic substituent having at least one substituent (G) with at least one substituent (G) having C ₁ ~C ₂₀ hetero cycloalkenyl amines, C ₆ ~C ₃₀ has at least one substituent (G) and an aromatic substituent C ₁ ~C ₂₀ heterocycloalkyl alkynyl amine,

C ₁ -C ₂₀ alkyl, C ₁ -C ₂₀ alkyloxy, C ₁ -C ₂₀ alkenyl, C ₁ -C ₂₀ alkynyl, C ₁ -C ₂₀ cycloalkyl, C ₁ -C ₂₀ cycloalkenyl, C ₁ ~C ₂₀ cycloalkyl alkynyl, C ₁ ~C ₂₀ heterocycloalkyl, C ₁ ~C ₂₀ alkenyl heterocycloalkyl and heterocycloalkyl C ₁ ~C ₂₀ alkynyl substituents selected from the group consisting of with at least one substituent (G) C ₆ -C ₃₀ aromatic amine,

C ₁ ~C ₂₀ Al having at least one substituent (G) C ₁ ~C ₂₀ alkyl amide, at least one substituent (G) C ₁ ~C ₂₀ alkyloxy amide, at least one substituent (G) having a having a alkenyl amides, C ₁ ~C ₂₀ alkynyl amides, C ₁ ~C ₂₀ cycloalkyl amide, C ₁ having at least one substituent (G) having at least one substituent (G) having at least one substituent (G) ~C ₂₀ cycloalkyl alkenyl amides, C ₁ ~C ₂₀ cycloalkyl alkynyl amide, C ₁ ~C ₂₀ heterocycloalkyl amide, at least one substituent having at least one substituent (G) having at least one substituent (G) C ₁ -C ₂₀ heterocycloalkenylamides having at least one substituent (G), C ₁ -C ₂₀ heterocycloalkynylamides having at least one substituent (G) C ₆ -C ₃₀ mono, Aromatic amides such as tri and polycyclic rings,

C ₆ ~C ₃₀ C ₁ ~C ₂₀ having at least one substituent (G) and an aromatic substituent alkyl _{_{_{amide, C 6 ~C 30 C 1 ~C}}} 20 alkenyl amide having at least one substituent (G) and an aromatic substituent _{_{_{, C 6 ~C 30 C 1 ~C}}} 20 having at least one substituent (G), and an aromatic amide substituent _{_{_{alkynyl, C 6 ~C 30 C 1 ~C}}} 20 cycloalkyl having at least one substituent (G) and an aromatic substituent alkyl amide, C ₆ ~C ₃₀ aromatic substituted with C ₁ having at least one substituent (G) at least one substituent (G), and C ₁ ~C ₂₀ cycloalkenyl amide, C ₆ ~C ₃₀ aromatic substituent having ~ C ₂₀ cycloalkyl alkynyl _{_{_{amide, C 6 ~C 30 C 1 ~C}}} 20 heterocycloalkyl amides having at least one substituent (G) with an aromatic substituent, C ₆ ~C ₃₀ aromatic substituted with at least one substituent (G) C ₁ -C ₂₀ heterocycloalkenylamides having at least one C ₆ -C ₃₀ aromatic substituent, C ₁ -C ₂₀ heterocycloalkynyl amide having a substituent (G)

C ₁ ~C ₂₀ alkyl, C ₁ ~C ₂₀ alkenyl, C ₁ ~C ₂₀ alkynyl, C ₁ ~C ₂₀ cycloalkyl, alkenyl, C ₁ ~C ₂₀ cycloalkyl, C ₁ ~C ₂₀ cycloalkyl alkynyl, C ₁ ~C ₂₀ heterocycloalkyl, C ₁ ~C ₂₀ alkenyl heterocycloalkyl and heterocycloalkyl C ₁ ~C ₂₀ alkynyl substituents selected from the group consisting of carbonyl and the C ₆ ~C ₃₀ aromatic amide having at least one substituent (G) &Lt; / RTI >

Wherein the substituent (G) is selected from the group consisting of C ₁ -C ₂₀ hydroxyalkyl, C ₁ -C ₂₀ hydroxyalkenyl, C ₁ -C ₂₀ hydroxyalkynyl, C ₁ -C ₂₀ hydroxycycloalkyl, C ₁ ~C ₂₀ hydroxy cycloalkenyl, C ₁ ~C ₂₀ hydroxycyclohexyl alkynyl, C ₁ ~C ₂₀ hydroxyalkyl heterocycloalkyl, C ₁ ~C ₂₀ hydroxyalkyl heterocycloalkyl alkenyl, C ₁ ~C ₂₀ hydroxyalkyl Heterocycloalkynyl,

C ₁ -C ₂₀ hydrothioalkyl, C ₁ -C ₂₀ hydrothioalkenyl, C ₁ -C ₂₀ hydrothioalkynyl, C ₁ -C ₂₀ hydrothiocycloalkyl, C ₁ -C ₂₀ hydrothothicycloalkenyl, C ₁ ~C ₂₀ dihydro-thio-alkynyl cycloalkyl, C ₁ ~C ₂₀ dihydro-thio-heterocycloalkyl, C ₁ ~C ₂₀ dihydro-thio heterocycloalkyl alkenyl, C ₁ ~C ₂₀ dihydro-thio heterocycloalkyl alkynyl,

C ₁ ~C ₂₀ alkyl nitro, C ₁ ~C ₂₀ alkenyl, nitro, C ₁ ~C ₂₀ alkynyl, nitro, C ₁ ~C ₂₀ cycloalkyl nitro, C ₁ ~C ₂₀ nitro cycloalkenyl, C ₁ ~C ₂₀ C ₁ -C ₂₀ nitroheterocycloalkyl, C ₁ -C ₂₀ nitroheterocycloalkenyl, C ₁ -C ₂₀ nitroheterocycloalkynyl,

C ₁ -C ₂₀ cyanoalkyl, C ₁ -C ₂₀ cyanoalkenyl, C ₁ -C ₂₀ cyanoalkynyl, C ₁ -C ₂₀ cyano cycloalkyl, C ₁ -C ₂₀ cyano cycloalkenyl, C ₁ ~C _{20-cyano-alkynyl} cycloalkyl, C ₁ ~C _{20-cyano-heterocycloalkyl,} C ₁ ~C ₂₀ hetero cycloalkenyl cyano, C ₁ ~C _{20-cyano-heterocycloalkyl} alkynyl,

C ₁ -C ₂₀ thiocanoalkyl, C ₁ -C ₂₀ thiocanoalkenyl, C ₁ -C ₂₀ thiocanoalkynyl, C ₁ -C ₂₀ thiocyanoCycloalkyl, C ₁ -C ₂₀ thio C ₁ -C ₂₀ thiocycloalkenyl, C ₁ -C ₂₀ thiocycloalkenyl, C ₁ -C ₂₀ thiocyanoheterocycloalkyl, C ₁ -C ₂₀ thiocanoheterocycloalkenyl, C ₁ -C ₂₀ thiocano Heterocycloalkynyl,

C ₁ -C ₂₀ aminoalkyl, C ₁ -C ₂₀ aminoalkenyl, C ₁ -C ₂₀ aminoalkynyl, C ₁ -C ₂₀ aminocycloalkyl, C ₁ -C ₂₀ aminocycloalkenyl, C ₁ -C ₂₀ aminocyclopropyl alkynyl, C ₁ ~C ₂₀ amino heterocycloalkyl, C ₁ ~C ₂₀ amino heterocycloalkyl alkenyl, C ₁ ~C ₂₀ amino heterocycloalkyl alkynyl,

C ₁ -C ₂₀ alkanoic acid, C ₁ -C ₂₀ alkenoic acid, C ₁ -C ₂₀ alkynoic acid, C ₁ -C ₂₀ cycloalkanoic acid, C ₁ -C ₂₀ cycloalkenoic acid, C ₁ -C ₂₀ cycles acid alkynyl, C ₁ ~C ₂₀ heterocycloalkyl alkanoic acid, C ₁ ~C ₂₀ hetero cycloalkenyl kensan, C ₁ ~C ₂₀ alkynyl heterocycloalkyl acid,

C ₆ -C ₃₀ hydroxyaromatic, C ₆ -C ₃₀ hydrothioaromatic, C ₆ -C ₃₀ nitroaromatic, C ₆ -C ₃₀ cyanoaromatic, C ₆ -C ₃₀ aromatic acid, C ₆ -C ₃₀ thio Cyanoaromatic, C ₆ -C ₃₀ aminoaromatic,

Substituted amines, substituted amines, amidino, hydrazine, substituted hydrazine, hydrazone, substituted hydrazone, amide, substituted amide, halide, hydroxy (OH), nitro group (nO _2), cyano (CN), thio-dicyano (SCN), thiol (SH), carboxyl (COOH), carboxylic alkali salt of the carboxylic acid (COO ^_ M ^+, where M are the alkali metals) , sulfonate (SO ₃ H), sulfonic acid alkali salt (SO ₃ ^{^-} M ^-, wherein M is an alkali metal Im), phosphoric acid (H ₃ PO ₄₎ and alkali salt of phosphoric acid _{_{^{^{(H 2 PO 4 - M +}}}} , where Wherein M is an alkali metal;

D, F and I are independently selected from each other and are a heteroatom selected from the group consisting of oxygen (O), sulfur (S), phosphorus (P) and nitrogen (N)

Wherein 0? C? 30, 0? E? 30, 0? H? 30, 0 <c + e + h <60.

The ink composition for an inkjet printer according to claim 1, wherein the pigment is a compound containing the following substituent (K).

[The substituent (K) is a C ₁ ~ having a C ₁ ~C ₃₀ alkyl, or at least one substituent (G) C ₁ ~C ₃₀ alkyl, C ₁ ~C ₃₀ alkyloxy or at least one substituent (G) having a alkyl C ₃₀ alkynyl having a oxy, C ₁ ~C ₃₀ alkenyl or at least one substituent (G) C ₁ ~C ₃₀ alkenyl, C ₁ ~C ₃₀ alkynyl or at least one substituent (G) having a carbonyl, C ₁ ~C ₃₀ C with a cycloalkyl, (cycloalkyl) or at least one substituent (G) alkenyl (cycloalkenyl) or at least one substituent (G) C ₁ ~C ₃₀ cycloalkyl, C ₁ ~C ₃₀ cycloalkenyl having ₁ ~C ₃₀ cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkynyl (cycloalkynyl) or at least one substituent (G) a C ₁ ~C ₃₀ cycloalkyl alkynyl, C ₁ ~C ₃₀ heterocycloalkyl (cycloalkyl), or with C ₁ -C ₃₀ heterocycloalkyl having at least one substituent (G), C ₁ -C ₃₀ heterocycloalkenyl, or at least C ₁ -C ₃₀ heterocycloalkenyl having one substituent (G), C ₁ -C ₃₀ heterocycloalkynyl or C ₁ -C ₃₀ heterocycloalkynyl having at least one substituent (G) Monosaccharides, disaccharides and polysaccharides, sorbitan, C ₆ -C ₅₀ unsubstituted mono-, bi, tri and polycyclic rings, aromatic or C ₆ -C ₅₀ -substituted mono- or polyunsaturated with at least one substituent (G) Aromatic, aromatic, polycyclic,

C ₁ ~C ₃₀ alkyl amine or C ₁ ~C ₃₀ alkyl amines, C ₁ ~C ₃₀ alkyl amine or oxy-C ₁ ~C ₃₀ alkyl aryloxy having at least one substituent (G) having at least one substituent (G) amine, C ₁ ~C ₃₀ alkenyl, C ₁ ~C ₃₀ alkenyl amines or Al having at least one substituent (G) amine, C ₁ ~C ₃₀ alkynyl amines or alkynyl amine having at least one substituent (G) , C ₁ ~C ₃₀ cycloalkyl, (cycloalkyl) amine or at least one substituent (G) C ₁ ~C ₃₀ cycloalkyl amine, C ₁ ~C ₃₀ cycloalkenyl (cycloalkenyl) amines, or at least one substituent group having a (G ) having a C ₁ ~C ₃₀ cycloalkenyl amine, C ₁ ~C ₃₀ cycloalkyl alkynyl (cycloalkynyl) amine or a C ₁ ~C ₃₀ cycloalkyl alkynyl amine, C ₁ ~C ₃₀ having at least one substituent (G) C ₁ -C ₃₀ heterocycloalkylamines having at least one substituent (G), C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) amines, or C ₁ ~C having at least one substituent (G) ₃₀ hetero cycloalkenyl amine, C ₁ ~C ₃₀ alkynyl heterocycloalkyl (cycloalkynyl) amine or at least one C ₁ -C ₃₀ heterocycloalkynylamines, monosaccharides, disaccharides and polysaccharide amines having substituents (G), sorbitan amines, C ₆ -C ₅₀ unsubstituted mono-, bi, tri and polycyclic Amine or a C ₆ -C ₅₀ substituted mono-, bi-, tri- and polycyclic ring having at least one substituent (G)

C ₁ ~C ₃₀ alkyl amide or C ₁ ~C having at least one substituent (G) ₃₀ alkylamide, C ₁ ~C ₃₀ alkyloxy amide or C ₁ ~C ₃₀ alkyl aryloxy having at least one substituent (G) amides, C ₁ ~C ₃₀ alkenyl amides, or at least one C ₁ ~C ₃₀ alkenyl Al having a substituent (G) amides, C ₁ ~C ₃₀ alkynyl amides or alkynyl amide having at least one substituent (G) C ₁ -C ₃₀ cycloalkyl amide or C ₁ -C ₃₀ cycloalkyl amide having at least one substituent (G), C ₁ -C ₃₀ cycloalkenyl amide or at least one substituent (G ) having a C ₁ ~C ₃₀ cycloalkyl alkenyl amides, C ₁ ~C ₃₀ cycloalkyl alkynyl (cycloalkynyl) amide, or C ₁ ~C ₃₀ cycloalkyl alkynyl amide, C ₁ ~C ₃₀ having at least one substituent (G) A cycloalkyl amide or C ₁ < RTI ID = 0.0 > ~C ₃₀ heterocycloalkyl amide, C ₁ ~C ₃₀ hetero cycloalkenyl (cycloalkenyl) amide, or C having at least one substituent (G) ₁ ~C ₃₀ hetero cycloalkenyl amide, C ₁ ~C ₃₀ alkynyl heterocycloalkyl Cycloalkynyl amides or C ₁ -C ₃₀ heterocycloalkynyl amides, monosaccharides, disaccharides and polysaccharide amides having at least one substituent (G), sorbitan amide, C ₆ -C ₅₀ unsubstituted mono, Aromatic amides which are mono-, bi-, tri- and polycyclic rings or aromatic amides, mono-, di- and polysaccharide amides which are mono-, bi-, tri- and polycyclic rings with at least one substituent (G), sorbitanamides,

An unsubstituted steroid or a steroid having at least one substituent, wherein the substituent (G) is selected from the group consisting of C ₁ -C ₃₀ alkyl, C ₁ -C ₃₀ alkyloxy, C ₁ -C ₃₀ alkenyl , C ₁ -C ₃₀ alkynyl, C ₁ -C ₃₀ cycloalkyl, C ₁ -C ₃₀ cycloalkenyl, C ₁ -C ₃₀ cycloalkynyl, C ₁ -C ₃₀ heterocycloalkyl, C ₁ -C ₃₀ hetero C ₁ -C ₃₀ hydroxyalkenyl, C ₁ -C ₃₀ heterocycloalkynyl, C ₁ -C ₃₀ hydroxyalkyl, C ₁ -C ₃₀ hydroxyalkenyl, C ₁ -C ₃₀ hydroxyalkynyl, C ₁ -C ₃₀ hydroxy cycloalkyl, C ₁ ~C ₃₀ hydroxy cycloalkenyl, C ₁ ~C ₃₀ hydroxycyclohexyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl, C ₁ ~C ₃₀ hydroxyalkyl hetero cycloalkenyl, C ₁ To C ₃₀ hydroxyheterocycloalkynyl, C ₁ -C ₃₀ hydrothioalkyl, C ₁ -C ₃₀ hydrothioal Alkenyl, C ₁ ~C ₃₀ dihydro-thio alkynyl, C ₁ ~C ₃₀ cycloalkyl dihydro-thio, C ₁ ~C ₃₀ dihydro-thio cycloalkenyl, C ₁ ~C ₃₀ dihydro-thio-alkynyl cycloalkyl, C ₁ ~C ₃₀ Hydro C ₁ -C ₃₀ hydrothioheterocycloalkenyl, C ₁ -C ₃₀ hydrothioheterocycloalkynyl, C ₁ -C ₃₀ nitroalkyl, C ₁ -C ₃₀ nitroalkenyl, C ₁ -C ₃₀ alkynyl, nitro, C ₁ ~C ₃₀ cycloalkyl nitro, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkynyl, nitro, C ₁ ~C _{30-nitro-heterocycloalkyl,} C ₁ ~C _30-nitro heterocycloalkyl alkenyl, C ₁ ~C ₃₀ nitro heterocycloalkyl alkynyl, C ₁ ~C ₃₀ cyanoalkyl, C ₁ ~C ₃₀ alkenyl noal cyano, C ₁ ~C _{30-cyano-alkynyl,} cyano C ₁ ~C ₃₀ Cycloalkyl, C _{1 to} C ₃₀ cyano cycloalkenyl, C _{1 to} C ₃₀ cyano cycloalkynyl, C _{1 to} C ₃₀ Cyano-heterocycloalkyl, C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C _{30-cyano-heterocycloalkyl} alkynyl, C ₁ ~C ₃₀ alkyl thio cyano, C ₁ ~C ₃₀ alkenyl thio-dicyano , C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl thio-dicyano alkynyl, C ₁ ~ C ₃₀ alkylthio-dicyano-heterocycloalkyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkenyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkynyl,

C ₁ ~C ₃₀ aminoalkyl, C ₁ ~C ₃₀ alkenyl, amino, C ₁ ~C ₃₀ amino alkynyl, C ₁ ~C ₃₀ cycloalkyl-amino, C ₁ ~C ₃₀ amino cycloalkenyl, C ₁ ~C ₃₀ aminocyclopropyl alkynyl, C ₁ ~C ₃₀ amino heterocycloalkyl, C ₁ ~C ₃₀ amino heterocycloalkyl alkenyl, C ₁ ~C ₃₀ amino heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkanoic acid (alkanoic acid), C ₁ ~C ₃₀ Al kensan, C ₁ ~C ₃₀ alkynyl acids, C ₁ ~C ₃₀ cycloalkyl alkanoic acid, C ₁ ~C ₃₀ kensan cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl acid alkynyl, C ₁ ~C ₃₀ heterocycloalkyl alkane acid, C ₁ ~C ₃₀ hetero cycloalkenyl kensan, C ₁ ~C ₃₀ alkynyl heterocycloalkyl acid,

C ₆ ~C ₃₀ aromatic, C ₆ ~C ₃₀ aromatic hydroxy, C ₆ ~C ₃₀ aromatic hydro-thio, C ₆ ~C ₃₀ aromatic with nitro, C ₆ ~C ₃₀ aromatic cyano, C ₆ ~C ₃₀ alkylthio during cyano aromatic, C ₆ ~C ₃₀ aromatic acids, C ₆ ~C ₃₀ aromatic amino, amino, substituted amino, imine, substituted imine, amidino (amidino), hydrazine, substituted hydrazine, hydrazone, substituted hydrazone , amide, substituted amide, halide (halide), hydroxy (OH), nitro group (nO _2), cyano (CN), thio-dicyano (SCN), thiol (SH), carboxyl (COOH), carboxylic alkali salt of the carboxylic acid (COO ^_ M ^+, where M is an alkali metal Im), sulfonic acid (SO ₃ H), alkali salt of the sulfonic acid (SO ₃ ^{^-} M ^-, where M are the alkali metal), phosphoric acid (H ₃ PO ₄ ) and an alkali salt of phosphoric acid (H ₂ PO ₄ ^- M ⁺ , where M is an alkali metal)

The ink composition for an ink jet printer according to claim 1, further comprising an acid or a base.

The ink composition for an ink jet printer according to claim 3, wherein the content of the acid or base in the total composition is 0.1 to 20% by weight.

4. The method of claim 3 wherein the acid is C ₁ ~C ₃₀ alkyl carboxylic acid at least a C ₁ ~C ₃₀ alkyl carboxylic acids, C ₁ ~C ₃₀ alkenyl carboxylic acid at least one substituent having one substituent (G) C ₁ ~C ₃₀ alkenyl group having a (G) a carboxylic acid, C ₁ ~C ₃₀ alkynyl carboxylic acid, at least one substituent (G) C ₁ ~C ₃₀ alkynyl carboxylic acid having, C ₁ ~C ₃₀ C ₁ ~C having a cycloalkyl carboxylic acid, at least one substituent (G) _{30-cycloalkyl-carboxylic} acid, C ₁ ~C ₃₀ cycloalkenyl C ₁ ~C carboxylic acid having at least one substituent (G) ₃₀ cycloalkenyl carboxylic acids, C ₁ ~C ₃₀ cycloalkyl alkynyl carboxylic acid C ₁ ~C ₃₀ cycloalkyl having at least one substituent (G) alkynyl-carboxylic acid, C ₁ ~C ₃₀ heterocycloalkyl-carboxylic C ₁ -C ₃₀ heterocycloalkylcarboxylic acids having at least one substituent (G), C ₁ -C ₃₀ heterocycloalkenyl Carboxylic acid C ₁ ~C having at least one substituent (G) C ₁ ~C ₃₀ hetero cycloalkenyl carboxylic acids, C ₁ ~C ₃₀ alkynyl heterocycloalkyl-carboxylic acid, at least one substituent (G) having a ₃₀ heterocycloalkyl alkynyl carboxylic acid, C ₆ ~C ₃₀ unsubstituted mono-, bi-, tri and polycyclic Whanin aromatic carboxylic acid or a C ₆ ~C ₃₀ unsubstituted mono having at least one substituent (G) , Aromatic carboxylic acids such as bi, tri and polycyclic rings,

C ₁ ~C ₃₀ alkyl, C ₁ ~C acid having at least one substituent (G) ₃₀ alkylsulfonate, C ₁ ~C ₃₀ alkenyl, C ₁ ~C ₃₀ alkenyl sulfonic acid having at least one substituent (G), C ₁ ~C ₃₀ alkynyl sulfonic acid C ₁ ~C ₃₀ alkynyl, C ₁ ~C ₃₀ cycloalkyl acid C ₁ ~C ₃₀ cycloalkyl having at least one substituent (G) having at least one substituent (G) acid, C ₁ ~C ₃₀ cycloalkenyl acid C ₁ ~C ₃₀ cycloalkenyl having at least one substituent (G) acid, C ₁ ~C ₃₀ cycloalkyl C ₁ acid alkynyl having at least one substituent (G) ~C ₃₀ cycloalkyl alkynyl sulfonic acid, C ₁ ~C ₃₀ heterocycloalkyl C ₁ ~C acid having at least one substituent (G) ₃₀ heterocycloalkyl acid, C ₁ ~C ₃₀ hetero cycloalkenyl acid at least one substituent (G) C ₁ ~C ₃₀ hetero cycloalkenyl acid, C ₁ ~C ₃₀ having a Interrogating cycloalkyl alkynyl acid C ₁ ~C ₃₀ heterocycloalkyl alkynyl sulfonate, C ₆ ~C ₃₀ Beach cyclic mono, bi, tri, and poly-aromatic ring Whanin acid or at least one substituent having at least one substituent (G) Aromatic sulfonic acids which are C ₆ -C ₃₀ unsubstituted mono-, bi, tri and polycyclic rings having (G)

C ₁ ~C ₃₀ alkyl, C ₁ ~C acid having at least one substituent (G) _30-alkyl phosphate, C ₁ ~C ₃₀ alkenyl, C ₁ ~C ₃₀ alkenyl phosphoric acid having at least one substituent (G), C ₁ ~C ₃₀ alkynyl, C ₁ ~C ₃₀ phosphoric acid alkynyl, C ₁ ~C ₃₀ cycloalkyl acid C ₁ ~C ₃₀ cycloalkyl having at least one substituent (G) having at least one substituent (G) acid, C ₁ ~C ₃₀ cycloalkenyl C ₁ ~C ₃₀ cycloalkenyl acid, phosphoric acid having at least one substituent (G) C ₁ ~C ₃₀ cycloalkyl C ₁ phosphate alkynyl having at least one substituent (G) ~C ₃₀ cycloalkyl alkynyl, phosphate, C ₁ ~C ₃₀ heterocycloalkyl phosphate at least C ₁ ~C ₃₀ heterocycloalkyl phosphate, C ₁ ~C ₃₀ hetero cycloalkenyl phosphoric acid at least one substituent having one substituent (G) (G) a C ₁ ~C ₃₀ hetero cycloalkenyl phosphate, C ₁ ~C ₃₀ alkynyl heterocycloalkyl and phosphoric acid having at least C ₁ having a my substituent (G) ~C ₃₀ alkynyl heterocycloalkyl phosphate, C ₆ ~C ₃₀ unsubstituted mono-, bi-, tri and polycyclic C ₆ Whanin having an aromatic acid or at least one substituent (G) ~C ₃₀ substituted mono, bi, tri and polycyclic aromatic Whanin ink jet ink composition for a printer agent, characterized in that phosphoric acid is selected from the group consisting of sulfuric acid (wherein the substituent (G) is a C ₁ ~C ₃₀ alkyl , C ₁ -C ₃₀ alkyloxy, C ₁ -C ₃₀ alkenyl, C ₁ -C ₃₀ alkynyl, C ₁ -C ₃₀ cycloalkyl, C ₁ -C ₃₀ cycloalkenyl, C ₁ -C ₃₀ cycloalkynyl , C ₁ -C ₃₀ heterocycloalkyl, C ₁ -C ₃₀ heterocycloalkenyl, C ₁ -C ₃₀ heterocycloalkynyl, C ₁ -C ₃₀ hydroxyalkyl, C ₁ -C ₃₀ hydroxyalkenyl, C ₁ ~C ₃₀ hydroxyalkyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl cycloalkyl, C ₁ ~C ₃₀ hydroxycyclohexyl Alkenyl, C ₁ ~C ₃₀ hydroxycyclohexyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkenyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkynyl, C ₁ dihydro ~C ₃₀ thioalkyl, C ₁ ~C ₃₀ alkenyl dihydro-thio, C ₁ ~C ₃₀ dihydro-thio alkynyl, C ₁ ~C ₃₀ cycloalkyl dihydro-thio, C ₁ ~C ₃₀ dihydro-thio cycloalkenyl, C ₁ ~C ₃₀ dihydro-thio-alkynyl cycloalkyl, C ₁ ~C ₃₀ dihydro-thio-heterocycloalkyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkenyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkynyl, C ₁ ~C _30-nitro alkyl, C ₁ ~C ₃₀ alkenyl, nitro, C ₁ ~C ₃₀ alkynyl, nitro, C ₁ ~C ₃₀ cycloalkyl nitro, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkynyl, nitro, C ₁ ~C _{30-nitro-heterocycloalkyl,} C ₁ ~C ₃₀ hetero between nitro Claw alkenyl, C ₁ ~C ₃₀ nitro heterocycloalkyl alkynyl, C ₁ ~C ₃₀ cyanoalkyl, C ₁ ~C ₃₀ alkenyl noal cyano, C ₁ ~C _{30-cyano-alkynyl,} C ₁ ~C _30-cyano cycloalkyl, C ₁ ~C _30-cyano cycloalkenyl, C ₁ ~C _{30-cyano-alkynyl} cycloalkyl, C ₁ ~C _{30-cyano-heterocycloalkyl,} C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C _{30-cyano-heterocycloalkyl} alkynyl, C ₁ ~C ₃₀ alkyl thio cyano, C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ thio-dicyano cycloalkyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₃₀ thio-dicyano-heterocycloalkyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl al C ₁ -C ₃₀ thiocyanoheterocycloalkynyl,

C ₆ ~C ₃₀ aromatic, C ₆ ~C ₃₀ aromatic hydroxy, C ₆ ~C ₃₀ aromatic hydro-thio, C ₆ ~C ₃₀ aromatic with nitro, C ₆ ~C ₃₀ aromatic cyano, C ₆ ~C ₃₀ alkylthio during cyano aromatic, C ₆ ~C ₃₀ aromatic acids, C ₆ ~C ₃₀ aromatic amino, amino, substituted amino, imine, substituted imine, amidino (amidino), hydrazine, substituted hydrazine, hydrazone, substituted hydrazone (Amide), substituted amide, halide, hydroxy (OH), nitro group (NO ₂ ), cyano (CN), thiocano (SCN), thiol (SH).

4. The method of claim 3, wherein the base is selected from the group consisting of dimethylamine ethanol, methyldiethanolamine, monomethanolamine, dimethanolamine, triethanolamine, monoethanolamine, diethanolamine, triethanolamine, ammonium hydroxide, tetraalkylammonium hydroxide Dimethylaminopropylamine (DMAPP), laurylamine, cetrimonium bromide, morpholine and n-methylmorpholine are added to the reaction mixture, C ₁ ~C ₃₀ aromatic group having a C ₁ ~C ₃₀ aliphatic amine or at least one of substituents C ₁ ~C ₃₀ aliphatic amines, C ₁ ~C ₃₀ aromatic amine or at least one substituent (G) having a (G) comprising Amine, C ₁ -C ₂₀ aliphatic mono, di, tri and polyalkanolamines or C ₁ -C ₂₀ aliphatic mono-, di- and polyalkanolamines having at least one substituent (G), C ₁ -C ₃₀ Aromatic mono, di-tri, and polyalkane In the Nu play or inkjet ink composition agent (here, characterized in that the at least one selected from the C ₁ ~C ₃₀ aromatic mono, di, tri, and poly alkaryl group consisting of play Min having a substituent (G), the substituent (G Is selected from the group consisting of C ₁ -C ₃₀ alkyl, C ₁ -C ₃₀ alkyloxy, C ₁ -C ₃₀ alkenyl, C ₁ -C ₃₀ alkynyl, C ₁ -C ₃₀ cycloalkyl, C ₁ -C ₃₀ cycloalkenyl, C ₁ ~C ₃₀ cycloalkyl alkynyl, C ₁ ~C ₃₀ heterocycloalkyl, C ₁ ~C ₃₀ hetero cycloalkenyl, heterocycloalkyl C ₁ ~C ₃₀ alkynyl, C ₁ ~C ₃₀ hydroxyalkyl, C ₁ ~ C ₃₀ hydroxyalkyl alkenyl, C ₁ ~C ₃₀ hydroxyalkyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl cycloalkyl, C ₁ ~C ₃₀ hydroxy cycloalkenyl, C ₁ ~C ₃₀ hydroxycyclohexyl alkynyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl, C ₁ ~C ₃₀ hydroxyalkyl heterocycloalkyl alkenyl, C ₁ ~C ₃₀ hydroxyalkyl four hetero Claw alkynyl, C ₁ ~C ₃₀ dihydro-thioalkyl, C ₁ ~C ₃₀ alkenyl dihydro-thio, C ₁ ~C ₃₀ dihydro-thio alkynyl, C ₁ ~C ₃₀ cycloalkyl dihydro-thio, C ₁ ~C ₃₀ dihydro-thio cycloalkenyl, C ₁ ~C ₃₀ dihydro-thio-alkynyl cycloalkyl, C ₁ ~C ₃₀ dihydro-thio-heterocycloalkyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkenyl, C ₁ ~C ₃₀ dihydro-thio heterocycloalkyl alkynyl, C ₁ ~C ₃₀ alkyl nitro, C ₁ ~C ₃₀ alkenyl, nitro, C ₁ ~C ₃₀ alkynyl, nitro, C ₁ ~C ₃₀ cycloalkyl nitro, C ₁ ~C ₃₀ nitro cycloalkenyl, C ₁ ~C ₃₀ C ₁ -C ₃₀ nitroheterocycloalkyl, C ₁ -C ₃₀ nitroheterocycloalkenyl, C ₁ -C ₃₀ nitroheterocycloalkynyl, C ₁ -C ₃₀ cyanoalkyl, C ₁ -C cyano noal ₃₀ alkenyl, C ₁ ~C _{30-cyano-alkynyl,} C ₁ ~C ₃₀ cycloalkyl, cyano, C ₁ ~C _{3 0-cyano-cycloalkenyl,} C ₁ ~C _{30-cyano-alkynyl} cycloalkyl, C ₁ ~C _{30-cyano-heterocycloalkyl,} C ₁ ~C ₃₀ hetero cycloalkenyl cyano, C ₁ ~C _{30-cyano-heterocycle} alkynyl, C ₁ ~C ₃₀ alkyl thio cyano, C ₁ ~C ₃₀ thio-dicyano alkenyl, C ₁ ~C ₃₀ thio-dicyano alkynyl, C ₁ ~C ₃₀ thio-dicyano-cycloalkyl, C ₁ ~C ₃₀ thio-dicyano cycloalkenyl, C ₁ ~C ₃₀ thio-dicyano-alkynyl cycloalkyl, C ₁ ~C ₃₀ thio-dicyano-heterocycloalkyl, C ₁ ~C ₃₀ thio-dicyano heterocycloalkyl alkenyl, C ₁ ~C ₃₀ Thiocyanoheterocycloalkynyl,

The ink composition for an inkjet printer according to claim 1, wherein the content of the pigment is 0.1 to 20% by weight in the total composition.

The ink composition for an ink jet printer according to claim 1, wherein the content of the dispersing agent is 0.1 to 20% by weight in the total composition.

The ink composition for an inkjet printer according to claim 1, wherein the content of the solvent is 60 to 99.8% by weight in the total composition.

The ink composition for an ink jet printer according to claim 1, wherein the solvent is water or a mixed solvent of water and an organic solvent.

11. The ink composition according to claim 10, wherein the content of the organic solvent is 0.1 to 20% by weight based on the total solvent.

11. The method of claim 10, wherein the organic solvent is selected from the group consisting of methanol, ethanol, n-propanol, i-propanol, butanol, t-butanol, i-butanol, hexanol, , i-octanol, nonanol, i-nonanoldodecanol, i-dodecanol, hexadecanol, i-hexadecanol, phenol, furfuryl alcohol, tetrahydrofurfuryl alcohol and diacetone alcohol &Lt; RTI ID = 0.0 > 1, < / RTI >

11. The method of claim 10, wherein the organic solvent is selected from the group consisting of propanediol, butanediol, hexanediol, methylpropanediol, cyclohexanediol, 2-methyl-2,4-pentanediol, 1,2,6-hexanetriol, but are not limited to, thiodiglycol, sorbitol, mannitol, myoinositol, glycerol, ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, polyether glycol, polyethylene glycol, Wherein the polyhydric alcohol is a polyhydric alcohol selected from the group consisting of glycols and polyhydric alcohols.

11. The method of claim 10, wherein the organic solvent is selected from the group consisting of tetrahydrofuran, dioxane;

Ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dipropyl ether, ethylene glycol dibutyl ether, diethylene glycol Monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether, diethylene glycol dibutyl Ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monopropyl ether, triethylene glycol monobutyl ether, triethylene glycol dimethyl ether, triethylene glycol diethyl ether, tri Propylene glycol monomethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, propylene glycol dimethyl ether, propylene glycol diethyl ether, propylene glycol di (meth) acrylate, diethylene glycol di Propyl ether, propylene glycol dibutyl ether, dipropylene glycol dimethyl ether, dipropylene glycol diethyl ether, dipropylene glycol dipropyl ether, dipropylene glycol dibutyl ether, ethyl acetate; Ethylene carbonate; Propylene glycol monomethyl ether acetate, ethylene glycol monomethyl ether acetate, ethylene glycol monomethyl ether acetate, ethylene glycol monomethyl ether acetate, diethylene glycol monomethyl ether acetate, diethylene glycol monomethyl propyl ether acetate, diethylene glycol monomethyl ether acetate, Propylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, dipropylene glycol monomethyl ether acetate, Propylene glycol monomethyl butyl ether acetate;

lactones including? -butyrolactone;

Pyrrolidone, N-pyrrolidone, N- (2-hydroxyethyl) pyrrolidone, N-methyl-2-pyrrolidone and 1,3- 2-imidazolidinone); < / RTI >

Ketones including cellosolve and acetone; And

Wherein the organic solvent is selected from the group consisting of sulfolane, dimethylsulfoxide, and a sulfur-containing organic solvent including tetramethylene sulfone.

11. The ink composition according to claim 10, wherein the organic solvent is selected from the group consisting of butane, hexane, cyclohexane, octane and cyclooctane, nonane, dodecane, hexadecane and toluene.