KR19980044260A - Insect repellent coated paper and its manufacturing method - Google Patents

Insect repellent coated paper and its manufacturing method Download PDF

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Publication number
KR19980044260A
KR19980044260A KR1019960062322A KR19960062322A KR19980044260A KR 19980044260 A KR19980044260 A KR 19980044260A KR 1019960062322 A KR1019960062322 A KR 1019960062322A KR 19960062322 A KR19960062322 A KR 19960062322A KR 19980044260 A KR19980044260 A KR 19980044260A
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insect repellent
coated
coating
resin composition
parts
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KR1019960062322A
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Korean (ko)
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KR100209113B1 (en
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양정한
이재원
정인만
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구광시
주식회사 코오롱
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D121/00Coating compositions based on unspecified rubbers
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14Ethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/006Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with wool-protecting agents; with anti-moth agents

Abstract

1. 청구범위에 기재된 발명이 속한 기술분야1. TECHNICAL FIELD OF THE INVENTION

본 발명은 천연섬유, 합성섬유 및 혼방섬유로 제조된 섬유포지에 피레스로이드계 방충제를 첨가시킨 수지조성물을 코팅, 건조 및 경화시켜서 방충성이 우수한 코팅포지를 제조한다.The present invention provides a coating foam having excellent insect repellency by coating, drying and curing the resin composition to which the pyrethroid-based insect repellent is added to the fiber wrapper made of natural fibers, synthetic fibers and blended fibers.

2. 발명이 해결하려고 하는 기술적 과제2. The technical problem to be solved by the invention

해충에 의한 전염병 감염을 방지하여 쾌적한 레져생활을 도모하기 위해 코팅포지에 방충성을 부여한다.Insect repellent is applied to coated paper to prevent infectious diseases caused by pests and to promote comfortable leisure life.

3. 발명의 해결방법의 요지3. Summary of Solution to Invention

수지 100 중량부 기준으로 피레스로이드계 방충제 0.1~3.0 중량부를 첨가하여 코팅용 수지조성물을 제조하고, 이들 조성물을 섬유포지에 5~15㎛ 두께로 코팅한 후 건조 및 경화시킨다.0.1 to 3.0 parts by weight of a pyrethroid-based insect repellent is added based on 100 parts by weight of the resin to prepare a resin composition for coating, and these compositions are coated on a fiber cloth with a thickness of 5 to 15 μm, and then dried and cured.

4. 발명의 중요한 용도4. Important uses of the invention

레져생활을 위한 레져용품 및 레져용 의류 등의 제조용 포지로 사용한다.It is used as a forge for leisure goods and leisure clothing.

Description

방충성이 우수한 코팅포지 및 그의 제조방법Insect repellent coated paper and its manufacturing method

본 발명은 합성섬유, 천연섬유 또는 이들의 혼방섬유 등으로 제조된 섬유포지상에 폴리우레탄 및 아크릴 등의 코팅용 수지, 살충 및 방충효과를 지는 피레스로이드계 방충제 및 기타가공제로 구성된 코팅용 수지조성물을 코팅, 건조 및 경화시켜서 제조되는 방충효과가 우수한 코팅포지 및 그의 제조방법에 관한 것이다.The present invention is a coating resin composition consisting of a coating resin such as polyurethane and acrylic, pyrethroid insect repellent and other processing agents having a pesticidal and insect repellent effect on a fiber cloth made of synthetic fibers, natural fibers or blended fibers thereof The present invention relates to a coating paper having excellent insect repellent effect prepared by coating, drying and curing, and a method of manufacturing the same.

종래의 레져용품 및 레져용 의류 등으로 사용되는 코팅포지는 포지상에 폴리우레탄 및 아크릴 등의 수지를 일반적 건식코팅 방법에 의해 직접 도포하여 방수효과 및 방풍효과만을 부여하여 왔다.Coating coated papers used in conventional leisure articles and leisure clothing have been applied directly resins such as polyurethane and acrylic on the forge by a general dry coating method has given only a waterproof effect and windproof effect.

그러나 이와 같은 방법으로 제조된 코팅포지로 만들어진 제품 즉 텐트 등을 야외에 설치하여 사용할 때 모기, 파리, 진드기 및 바퀴벌레 등의 각종 해충으로부터 인체를 보호할 수 있는 기능이 없어 해충에 의한 말라리아 등의 전염병이 감염되기 쉽다. 이와 같은 결과들은 쾌적한 레져생활을 저해하는 요인이 되어 왔다.However, there are no infectious diseases such as malaria caused by pests because there is no function to protect the human body from various pests such as mosquitoes, flies, ticks and cockroaches when the products made of coated paper manufactured in this way, namely tents, are used outdoors. This is susceptible to infection. These results have been a detrimental factor in pleasant leisure life.

본 발명은 종래 기술의 문제점인 해충에 의한 전염병 감염 등을 방지하므로서 쾌적한 레져생활을 도모할 수 있도록 텐트 등의 레져용품용 코팅포지에 효과적으로 살충성 및 방충성을 부여하는 방법을 제공한다.The present invention provides a method for effectively providing insecticidality and insect repellent to the coating cloth for leisure goods such as tents to prevent the infectious diseases caused by pests, which is a problem of the prior art, to promote a comfortable leisure life.

본 발명은 섬유포지상에 피레스로이드계 방충제가 첨가된 코팅용 수지조성물을 코팅한 후 건조 및 경화시키서 방충성이 우수한 코팅포지를 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a coating bag having excellent insect repellency by coating a resin composition for coating to which a pyrethroid-based insect repellent is added on a fiber bag and then drying and curing.

본 발명은 위에서 언급한 각종 해충으로부터 야기되는 문제점들을 해결하기 위해서 과수 및 야채 등의 농작물 해충을 방제하는데 주로 사용되어 온 살충성, 방충성 및 내광성 등이 우수하며 인체에 독성이 적은 피레스로이드계 방충제인 화학명 3-(2,2-디클로로 에테닐)-2,2-디메틸 사이클로프로판카복시릭 액시드(3-페녹시 페닐)메틸 에스테르 [3-(2,2-DICHLORO ETHENYL)-2,2-DIMETHYL CYCLOPROPAN ECARBO XYLIC ACID(3-PHENOXY PHENYL)METHYL ESTER]의 퍼메트린(PERMETHRIN)이라고 하는 약제를 수지조성물에 첨가하여 코팅용 수지조성물을 제조하고 이들을 섬유포지에 코팅, 건조 및 경화시킨다.The present invention is a pyrethroid insect repellent excellent in insecticides, insect repellent and light resistance that has been mainly used to control crop pests such as fruit trees and vegetables in order to solve the problems caused by the various pests mentioned above Phosphorus Chemical Name 3- (2,2-dichloro ethenyl) -2,2-dimethyl cyclopropanecarboxylic acid (3-phenoxy phenyl) methyl ester [3- (2,2-DICHLORO ETHENYL) -2,2- A drug called PERMETHRIN of DIMETHYL CYCLOPROPAN ECARBO XYLIC ACID (3-PHENOXY PHENYL) METHYL ESTER] is added to the resin composition to prepare a resin composition for coating, which is coated, dried and cured on the fiber cloth.

이하 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.

본 발명 사용수지로는 폴리우레탄, 폴리염화비닐, 아크릴 및 고무 등 일반적으로 코팅에 사용할 수 있는 수지이면 가능하나 폴리우레탄 수지가 더욱 바람직하다.The resin used in the present invention may be a resin which can be generally used for coating such as polyurethane, polyvinyl chloride, acrylic and rubber, but a polyurethane resin is more preferable.

사용되는 기포로는 폴리에스테르, 나이론 및 레이온 등의 합성섬유, 면 및 마 등의 천연섬유 또는 이들의 혼방에 의해 만들어진 직물 등이 사용될 수 있으며, 수지코팅의 작업성 및 효과를 높이기 위해 코팅전에 미리 발수처리한 것을 사용할 수도 있다.As the bubbles used, synthetic fibers such as polyester, nylon and rayon, natural fibers such as cotton and hemp, or fabrics made of blends thereof may be used. Water repellent can also be used.

방충성 약제로는 피레스로이드계의 3-(2,2-디클로로 에테닐)-2,2-디메틸사이크로프로판카복시릭 액시드(3-페녹시 페닐)메틸 에스테르 [3-(2,2-DICHLORO ETH EN YL)-2,2-DIMETHYL CYCLOPROPANECARBOXYLIC ACID(3-PHENOXY PHENY L)METHYL ESTER]의 퍼메트린(PERMETHRIN)이 사용될 수 있으며 사용량은 수지에 대하여 0.1~3.0 중량부가 바람직하다. 방충제 사용량이 너무 적으면 방충효과가 부족하고, 방충제 사용량이 너무 많으면 인체에 영향을 줄 수도 있고, 첨가량에 비해 효과의 증대가 미미하며, 코팅작업성 또한 저하된다.Insect repellents include pyrethroid 3- (2,2-dichloroethenyl) -2,2-dimethylcyclopropanecarboxylic acid (3-phenoxy phenyl) methyl ester [3- (2,2- PERMETHRIN of DICHLORO ETH EN YL) -2,2-DIMETHYL CYCLOPROPANECARBOXYLIC ACID (3-PHENOXY PHENY L) METHYL ESTER] can be used and the amount used is preferably 0.1 to 3.0 parts by weight relative to the resin. If the amount of insecticide used is too small, the insect repellent effect is insufficient, too much insecticide used may affect the human body, the increase of the effect is insignificant compared to the added amount, coating workability is also reduced.

또한 수지조성물에는 방충제이외에 항균성, 방염성, 발수성, 유연성 및 코팅액의 안정성 등을 부여하기 위한 조제, 가교제, 계면활성제 및 증점제 등을 첨가하여 사용할 수 있다.In addition to the insect repellent, a resin, a crosslinking agent, a surfactant, a thickener, and the like for imparting antimicrobial, flame retardant, water repellency, flexibility and stability of the coating solution may be used.

항균제로는 메타졸, 키토산, 4급암모늄염 및 금속무기염 등에서 선택된 1종 또는 2종 이상의 화합물을 혼합하여 사용할 수 있다. 이러한 것으로는 아연, 구리, 은 등의 금속이온이 도입된 제오라이트, 벤즈알코늄 크로라이드, 폴리옥시알킬렌트리알킬암모늄염 및 3-(트리메톡시실릴)-프로필디메틸옥타데실암모늄크로라이드 등이 있다.As an antimicrobial agent, one or two or more compounds selected from metasols, chitosan, quaternary ammonium salts and metal inorganic salts may be used in combination. These include zeolites, benzalkonium chromides, polyoxyalkylenetrialkylammonium salts, and 3- (trimethoxysilyl) -propyldimethyloctadecylammonium chlorides in which metal ions such as zinc, copper and silver are introduced. .

방염성을 높이기 위한 것으로는 브롬계, 실리카계 및 안티몬계 방염제 등을 단독 또는 혼합하여 사용할 수 있고, 발수제로는 불소계 및 왁스계 등을 사용할 수 있다.As the flame retardant, the bromine-based, silica-based and antimony-based flame retardants may be used alone or in combination, and as the water repellent, fluorine-based and wax-based may be used.

유연제로는 실리콘계 등을 사용할 수 있다. 가교제로는 이소시아네이트계 가교제를 사용할 수 있으며, 증점제로는 메틸셀룰로즈계, 아크릴계 코폴리머 등을 사용할 수 있다.Silicone type etc. can be used as a softening agent. An isocyanate crosslinking agent can be used as a crosslinking agent, and a methylcellulose type, an acrylic copolymer etc. can be used as a thickener.

이와 같이 조성된 수지조성물을 포지상에 통상의 코팅기를 이용하여 도포한 후 이들을 건조 및 경화시킴으로서 본 발명이 완성된다. 코팅두께는 통상 5~15㎛이 적당하다. 코팅두께가 너무 얇으면 방풍성이 부족하거나 코팅면이 박리되기 쉬운 단점이 있으며, 코팅두께가 너무 두꺼우면 원단이 너무 뻣뻣하며 촉감이 나쁘고 사용에 불편하다.The present invention is completed by applying the resin composition thus formed on a paper using a common coater and then drying and curing them. The coating thickness is usually 5 ~ 15㎛. If the coating thickness is too thin, there is a shortage of wind resistance or the coating surface is easy to peel off, if the coating thickness is too thick, the fabric is too stiff, the touch is bad and uncomfortable to use.

본 발명으로 제조된 코팅포지는 코팅용 수지조성물내에 피레스로이드계 방충제가 첨가됨에 따라 살충성 및 방충성이 우수하다.The coated cloth prepared by the present invention has excellent insecticidal and insect repellent properties as the pyrethroid insect repellent is added to the resin composition for coating.

본 발명을 실시예 및 비교실시예를 통하여 보다 상세히 설명한다.The present invention will be described in more detail through Examples and Comparative Examples.

[실시예 1]Example 1

아래와 같은 조성으로 코팅용 수지조성물을 제조한다. 제조된 코팅용 수지조성물을 나이프 오버 에어 코팅방식으로 발수처리된 폴리에스테르 직물에 10㎛ 두께로 코팅한다. 제조된 코팅물을 120℃에서 30초간 건조한 후 160℃에서 30초간 경화시켜서 코팅포지를 제조하였다.A resin composition for coating is prepared by the following composition. The prepared resin composition for coating is coated on a water repellent polyester fabric by a knife over air coating method to a thickness of 10㎛. The coated coating was dried at 120 ° C. for 30 seconds and then cured at 160 ° C. for 30 seconds to prepare a coated paper.

조 성Furtherance

폴리우레탄수지 100 중량부100 parts by weight of polyurethane resin

방충제 [퍼메트린(PERMETHRIN)]0.5 중량부Insect Repellent [PERMETHRIN] 0.5 parts by weight

항균제 (메타졸 티케이-100)0.5 중량부Antibacterial (Metazole TK-100) 0.5 parts by weight

유연제 (실리콘수지)3.0 중량부Softener (Silicone Resin) 3.0 parts by weight

계면활성제0.5 중량부0.5 parts by weight of surfactant

방염제 (안티몬트리옥사이드)5.0 중량부Flame retardant (antimony trioxide) 5.0 parts by weight

가교제 (이소시아네이트계)2.0 중량부Crosslinking agent (isocyanate type) 2.0 parts by weight

발수제 (지르코늄왁스컴플렉스)5.0 중량부Water repellent (zirconium wax complex) 5.0 parts by weight

증점제 (아크릴코폴리머)0.5 중량부Thickener (Acrylic copolymer) 0.5 parts by weight

유기용제 (톨루엔)20.0 중량부Organic solvent (toluene) 20.0 parts by weight

[실시예 2]Example 2

방충제의 함량을 2.5 중량부로 한 것 외에는 실시예 1과 동일하게 실시하여 코팅포지를 제조하였다.Except the amount of the insect repellent to 2.5 parts by weight was carried out in the same manner as in Example 1 to prepare a coated paper.

[실시예 3]Example 3

방충제의 함량을 1.0 중량부로 한 것 외에는 실시예 1과 동일하게 실시하여 코팅포지를 제조하였다A coated paper was prepared in the same manner as in Example 1 except that the insecticide content was 1.0 part by weight.

[실시예 4]Example 4

방충제의 함량을 0.1 중량부로 한 것 외에는 실시예 1과 동일하게 실시하여 코팅포지를 제조하였다.Except the amount of the insect repellent to 0.1 parts by weight was carried out in the same manner as in Example 1 to prepare a coated paper.

[비교실시예 1]Comparative Example 1

방충제를 첨가하지 않은 것을 제외하고는 실시예 1과 동일하게 실시하여 코팅포지를 제조하였다.Except not adding the insect repellent was carried out in the same manner as in Example 1 to prepare a coated paper.

실시예 1~4 및 비교실시예 1에서 제조된 코팅포지의 방충성을 평가 비교한 결과는 표 1 과 같다.Evaluation results of the evaluation of the insect repellency of the coated cloth prepared in Examples 1 to 4 and Comparative Example 1 are shown in Table 1.

- 방충성 평가 방법 --Insect repellent evaluation method-

실시예 1~4 및 비교실시예 1에서 제조된 코팅포지로 넓이 1.0m, 높이 1.0m, 길이 1m의 미니텐트를 각각 제작하고, 채집한 모기를 1회 50마리씩 스크린 도-어를 통해 제조된 각각의 텐트내에 집어 넣고, 3시간동안 문을 닫고 방치한 후 죽거나 날지 못하는 모기수를 확인하여 아래와 같은 공식으로 백분율을 환산하였다. 실험횟수는 5회이다.The mini-tents of 1.0 m in width, 1.0 m in height, and 1 m in length were prepared using the coated foams prepared in Examples 1 to 4 and Comparative Example 1, and 50 collected mosquitoes were prepared by screen doors. They were placed in each tent, closed for 3 hours, left, and then checked for dead or non-flying mosquitoes. The number of experiments is five.

사망 또는 날지못하는 모기(%) = (사망 또는 날지못하는 모기의 수/50)×100% Death or flightless mosquito = (number of deaths or flightless mosquitoes / 50) × 100

내용 없음No content

Claims (10)

섬유포지에 코팅용 수지조성물을 코팅, 건조 및 경화시켜 코팅포지를 제조함에 있어서, 코팅용 수지조성물에 피레스로이드계 방충제를 첨가시킴을 특징으로 하는 방충성이 우수한 코팅포지의 제조방법.A method for producing a coating foam having excellent insect repellency, characterized in that the coating resin composition is coated, dried, and cured on a fiber cloth to produce a coating foam. 1 항에 있어서, 피레스로이드계 방충제가 [3-(2,2-디클로로 에테닐)-2,2-디메틸 사이클로프로판카복시릭 액시드(3-페녹시 페닐)메틸 에스테르]의 퍼메트린(PERMETHRIN)인 것을 특징으로 하는 방충성이 우수한 코팅포지의 제조방법.The pyrethroid insect repellent is permethrin of [3- (2,2-dichloroethenyl) -2,2-dimethyl cyclopropanecarboxylic acid (3-phenoxy phenyl) methyl ester]. Method for producing a coated foam excellent insect repellent, characterized in that. 1 항에 있어서, 피레스로이드계 방충제의 첨가량이 수지 100 중량부에 대하여 0.1~3.0 중량부인 것을 특징으로 하는 방충성이 우수한 코팅포지의 제조방법.The method according to claim 1, wherein the addition amount of the pyrethroid insect repellent is 0.1 to 3.0 parts by weight based on 100 parts by weight of the resin. 1 항에 있어서, 코팅용 수지조성물에 항균제, 방염제, 유연제 및 가교제가 선택적으로 첨가됨을 특징으로 하는 방충성이 우수한 코팅포지의 제조방법.The method of claim 1, wherein an antimicrobial agent, a flame retardant, a softening agent and a crosslinking agent are selectively added to the resin composition for coating. 1 항에 있어서, 섬유포지에 코팅용 수지조성물을 5~15㎛ 두께로 코팅함을 특징으로 하는 방충성이 우수한 코팅포지의 제조방법.The method according to claim 1, wherein the coating resin composition is coated on a fiber cloth with a thickness of 5 to 15㎛. 1 항에 있어서, 사용수지가 폴리우레탄, 폴리염화비닐, 아크릴 및 고무중에서 선택됨을 특징으로 하는 방충성이 우수한 코팅포지의 제조방법.The method according to claim 1, wherein the resin used is selected from polyurethane, polyvinyl chloride, acrylic and rubber. 피레스로이드계 방충제가 포함된 코팅용 수지조성물로 코팅된 방충성이 우수한 코팅포지.Excellent coated insect repellent coated with resin composition for coating containing pyrethroid insect repellent. 7 항에 있어서, 피레스로이드계 방충제가 [3-(2,2-디클로로 에테닐)-2,2-디메틸 사이클로프로판카복시릭 액시드(3-페녹시 페닐)메틸 에스테르]의 퍼메트린(PERMETHRIN)인 방충성이 우수한 코팅포지.8. The pyrethroid insect repellent is permethrin of [3- (2,2-dichloroethenyl) -2,2-dimethyl cyclopropanecarboxylic acid (3-phenoxy phenyl) methyl ester]. Insect repellent coated paper. 7 항에 있어서, 피레스로이드계 방충제의 첨가량이 수지 100 중량부에 대하여 0.1~3.0 중량부인 방충성이 우수한 코팅포지.The coated paper according to claim 7, wherein the addition amount of the pyrethroid insect repellent is 0.1 to 3.0 parts by weight based on 100 parts by weight of the resin. 7 항에 있어서, 섬유포지에 코팅용 수지조성물을 5~15㎛ 두께로 코팅된 방충성이 우수한 코팅포지.The coated foam according to claim 7, wherein the coated resin composition is coated on a fibrous substrate with a thickness of 5 to 15 µm.
KR1019960062322A 1996-12-06 1996-12-06 Coating fabric KR100209113B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100338685B1 (en) * 1999-07-07 2002-05-30 전 순 표 Method of treating mosquito repellent to clothing
KR100727253B1 (en) * 2001-11-27 2007-06-11 주식회사 효성 a mite-proof carpet

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100338685B1 (en) * 1999-07-07 2002-05-30 전 순 표 Method of treating mosquito repellent to clothing
KR100727253B1 (en) * 2001-11-27 2007-06-11 주식회사 효성 a mite-proof carpet

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