KR102630748B1 - Polymer waterproof material for preventing leakage of reservoir diversion tunnel and their manufacturing method - Google Patents
Polymer waterproof material for preventing leakage of reservoir diversion tunnel and their manufacturing method Download PDFInfo
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- 239000000463 material Substances 0.000 title claims abstract description 57
- 229920000642 polymer Polymers 0.000 title claims abstract description 49
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 71
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 54
- 230000004888 barrier function Effects 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 30
- 230000008439 repair process Effects 0.000 claims abstract description 20
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 14
- 239000000654 additive Substances 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims abstract description 9
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 30
- 230000008569 process Effects 0.000 claims description 21
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 15
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims description 14
- 210000002784 stomach Anatomy 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- 239000003999 initiator Substances 0.000 claims description 12
- 238000010276 construction Methods 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 239000004971 Cross linker Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 238000004078 waterproofing Methods 0.000 claims description 3
- 230000002522 swelling effect Effects 0.000 abstract description 6
- 230000000052 comparative effect Effects 0.000 description 27
- 229940117913 acrylamide Drugs 0.000 description 7
- 239000004567 concrete Substances 0.000 description 6
- 230000008961 swelling Effects 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 230000002262 irrigation Effects 0.000 description 3
- 238000003973 irrigation Methods 0.000 description 3
- 230000036632 reaction speed Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 208000004998 Abdominal Pain Diseases 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003621 irrigation water Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011150 reinforced concrete Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
- C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02B—HYDRAULIC ENGINEERING
- E02B13/00—Irrigation ditches, i.e. gravity flow, open channel water distribution systems
Abstract
본 발명은 폴리머 차수재 및 이의 제조방법에 관한 것으로서, 상세하게는 단량체인 아크릴아마이드(acrylamide), 가교제인 MBAA(N-Methylenebisacrylamide), 첨가제인 MMA(Methylmethacrylate) 및 유화제인 EG(Ethylene glycol)를 혼합하여 폴리머 차수재를 제조함으로써 인장강도, 팽윤성 및 반응속도가 개선된 저수지 복통의 누수 보수용 폴리머 차수재 및 이의 제조 방법에 관한 것이다.The present invention relates to a polymer barrier material and a method for manufacturing the same, and specifically, to mixing acrylamide as a monomer, N-Methylenebisacrylamide (MBAA) as a crosslinking agent, Methylmethacrylate (MMA) as an additive, and ethylene glycol (EG) as an emulsifier. The present invention relates to a polymer barrier material for water leak repair in a reservoir tank with improved tensile strength, swelling properties, and reaction rate by manufacturing a polymer barrier material, and a method for manufacturing the same.
Description
본 발명은 폴리머 차수재 및 이의 제조방법에 관한 것으로서, 상세하게는 폴리머 차수재에 가교제, 첨가제 및 유화제를 혼합하여 팽윤성 및 반응속도가 개선된 저수지 복통의 누수 보수용 폴리머 차수재 및 이의 제조 방법에 관한 것이다.The present invention relates to a polymer barrier material and a method for manufacturing the same, and more specifically, to a polymer barrier material for repairing water leaks in a reservoir stomach with improved swelling properties and reaction rates by mixing a polymer barrier material with a crosslinker, additive, and emulsifier, and to a method for manufacturing the same. It's about.
복통은 일반적으로 저수지에서 취수시설의 하나로 방류부(도수부)에 해당되며, 저류수를 제체 하류로 도수하기 위하여 제체 내부를 횡단하여 설치하는 시설이고, 취수터널은 제체와 분리시켜 인접된 산을 관통하여 설치하는 시설이다.Botong is generally one of the water intake facilities in a reservoir and corresponds to the discharge part (discharge part). It is a facility installed across the inside of the reservoir to deliver stored water to the downstream of the reservoir, and the water intake tunnel is separated from the reservoir and connects the adjacent mountain. It is a facility installed through a penetrating device.
농업용 저수지는 취수터널 형식도 있으나, 일반적으로 복통 형식으로 설치하는 경우가 많으며, 단면의 규모도 대체로 크지 않은 편이다. 그러므로 복통의 규모는 작은 구경의 단면인 관체(콘크리트관, 흄관, 철관 등)를 철근콘크리트로 감싸는 구조로 되어 있으며 제고가 높거나 규모가 큰 저수지에서는 콘크리트 라이닝 구조(말굽형, 원형, 반원형, 박스형 등)로 되어 있다.Agricultural reservoirs can take the form of water intake tunnels, but they are generally installed in the form of a double tube, and the cross-sectional size is generally not large. Therefore, the size of the barrel is a structure that surrounds a small-diameter cross-sectional pipe (concrete pipe, Hume pipe, iron pipe, etc.) with reinforced concrete, and in reservoirs with high elevation or large size, a concrete lining structure (horseshoe-shaped, circular, semi-circular, box-shaped) is used. etc.).
농업용 저수지는 약 100일간의 관개기간동안 경지에 관개용수를 공급하다가 비관개기인 동절기에는 혹한에 노출됨으로써 관개기 동안 콘크리트 조직내부 공극으로 스며든 물이 동절기에 동결하는 현상(동해)이 발생하여 동결압에 의한 콘크리트 균열발생 등 성능저하 현상이 나타난다.Agricultural reservoirs supply irrigation water to farmland for an irrigation period of about 100 days, but are exposed to extreme cold during the non-irrigation winter season, causing water that seeps into the pores within the concrete structure during the irrigation period to freeze in the winter (frost damage). Performance deterioration phenomena such as cracks in concrete due to pressure appear.
이러한 복통의 결함 사항은 콘크리트의 열화현상에 의하여 누수, 균열, 박리, 박락, 백태, 철근부식, 축제재료인 점토 유출현상이 나타나며, 손상부위는 도 1에 도시된 바와 같이 시공이음부에서 많이 발생하고 있고, 시공이음부의 손상으로 인해 누수가 발생한다.These abdominal pain defects occur due to the deterioration of concrete, such as water leakage, cracks, peeling, delamination, whitening, corrosion of reinforcing bars, and leakage of clay, which is a construction material, and the damaged area often occurs at the construction joint as shown in Figure 1. Water leaks occur due to damage to construction joints.
이러한 시공이음부에서 발생하는 누수 현상을 보수하기 위해, 아크릴 지수재 등을 시공이음부에 주입하는 방법이 많이 이용되고 있으나, 아크릴 수지재는 0.3mm 이하의 미세공극에서 최대의 성능을 발휘하기 때문에 사용에 제한이 있다. 그리고 누수에 의해 아크릴 지수재가 유실될 수 있기 때문에, 차수 성능이 반감되고 반복적으로 아크릴 지수재를 재시공해야 하는 단점이 있다.In order to repair water leakage that occurs at such construction joints, the method of injecting acrylic water-stopping material, etc. into the construction joint is widely used. However, acrylic resin material is used because it exhibits maximum performance in micropores of 0.3 mm or less. There is a limit to And because the acrylic water stopper can be lost due to water leakage, there is a disadvantage in that the waterproofing performance is halved and the acrylic water stopper must be repeatedly reinstalled.
이러한 문제점을 해결하기 위하여, 본 출원인에 의해 국내 등록특허 제10-1920120호인 폴리머 차수재 및 폴리머 차수재를 이용하는 콘크리트 댐 구조물의 누수 보수 방법이 개발되었다.In order to solve this problem, the present applicant has developed a polymer barrier material and a water leakage repair method for a concrete dam structure using a polymer barrier material, which is Korean Patent No. 10-1920120.
상기 폴리머 차수재는 단량체인 아크릴아마이드, 가교제인 PEGDA 및 개시제인 APS를 포함하며, 상기 가교제의 몰수와, 상기 단량체 및 상기 가교제의 몰수 합의 비율은 1 내지 2%이며, 상기 단량체 및 상기 가교제의 질량 합과, 상기 단량체, 가교제 및 개시제가 수용액에 용해된 용액의 질량의 비율은 25 내지 35%이며, 상기 개시제의 몰수는 수학식 1과 같다.The polymer barrier material includes acrylamide as a monomer, PEGDA as a cross-linking agent, and APS as an initiator, and the ratio of the number of moles of the cross-linking agent to the sum of the number of moles of the monomer and the cross-linking agent is 1 to 2%, and the sum of the masses of the monomer and the cross-linking agent And, the mass ratio of the monomer, cross-linking agent, and initiator dissolved in the aqueous solution is 25 to 35%, and the number of moles of the initiator is as shown in Equation 1.
그러나, 폴리머 차수재는 50㎜ 이하의 이음부 사이로 친수성 차수재를 백업제로 쓰여지기 때문에 누수 발생시 팽윤성이 높아야 하고, 갑작스런 누수 발생에 대응하기 위하여 초기반응 속도가 빨라야 하는 데, 이러한 종래의 폴리머 차수재는 습윤상태일 때 115~132% 정도 부피가 증가되고, 실험결과 완전 습윤상태에서 50시간 경과시 부피비가 165%, 120%, 도달까지 걸리는 시간은 약 200분으로 초기 부피 증가 속도가 느려 누수 발생에 대응이 쉽지 않는 문제점이 있다.However, because polymer barrier materials are used as a backup agent for hydrophilic barrier materials between joints of 50 mm or less, they must have high swelling properties when water leaks occur and must have a fast initial reaction speed to respond to sudden water leaks. When in normal condition, the volume increases by about 115-132%, and as a result of the experiment, after 50 hours in a fully wet state, the volume ratio increases to 165% and 120%, and the time it takes to reach is about 200 minutes, so the initial volume increase rate is slow, responding to water leaks. There is a problem that is not easy to solve.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 폴리머 차수재에 가교제, 첨가제 및 유화제를 혼합하여 팽윤성 및 반응속도가 개선된 저수지 복통의 누수 보수용 폴리머 차수재 및 이의 제조 방법을 제공하는데 그 목적이 있다.The present invention is intended to solve the above problems, and the purpose of the present invention is to provide a polymer water barrier material for repairing water leaks in a reservoir tank with improved swelling properties and reaction rates by mixing a crosslinker, additive, and emulsifier in the polymer water barrier material, and a method for manufacturing the same. There is.
상기와 같은 목적을 달성하기 위한 본 발명의 특징은,The features of the present invention for achieving the above object are:
저수지 복통의 시공이음부 사이에 주입되어 누수를 보수하는 폴리머 차수재에 있어서, 상기 폴리머 차수재는 수용액인 물 10~80중량%, 단량체인 아크릴아마이드(acrylamide) 5~45중량%, 유화제인 EG(Ethylene glycol) 5~45중량%, 가교제인 MBAA(N-Methylenebisacrylamide) 0.2~1.0중량%, 첨가제인 MMA(Methylmethacrylate) 0.5~2.0중량%, 개시제인 APS(Ammonium persulfate) 0.5~2.0중량%로 혼합되는 것을 특징으로 한다.In the polymer barrier material that is injected between the construction joints of the reservoir tank to repair water leaks, the polymer barrier material contains 10 to 80% by weight of water as an aqueous solution, 5 to 45% by weight of acrylamide as a monomer, and EG (EG) as an emulsifier. Ethylene glycol) 5-45% by weight, MBAA (N-Methylenebisacrylamide) 0.2-1.0% by weight as a crosslinking agent, MMA (Methylmethacrylate) 0.5-2.0% by weight as an additive, and 0.5-2.0% by weight of APS (Ammonium persulfate) as an initiator. It is characterized by
여기에서, 상기 저수지 복통의 누수 보수용 폴리머 차수재는 연쇄 중합반응 속도를 높이기 위해 촉매인 TEMED(Tetramethylethylenediamine)가 전체 용액 중량 대비 0.01~0.1중량% 더 혼합된다.Here, the polymer barrier material for water leak repair in the reservoir stomach is mixed with TEMED (Tetramethylethylenediamine), a catalyst, in an amount of 0.01 to 0.1% by weight based on the total solution weight to increase the chain polymerization reaction rate.
여기에서 또한, 상기 저수지 복통의 누수 보수용 폴리머 차수재는 원기둥 또는 사각기둥 형상이다.Here again, the polymer barrier material for repairing water leaks in the reservoir tube has a cylindrical or square pillar shape.
본 발명의 다른 특징은,Another feature of the present invention is,
상기의 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법에 있어서, 단량체인 아크릴아마이드(acrylamide), 가교제인 MBAA(N-Methylenebisacrylamide), 첨가제인 MMA(Methylmethacrylate)를 수용액인 물에 혼합하여 원통형 탱크에서 1~2시간 믹싱하는 1차 믹싱 공정과; 1차 믹싱 후, 개시제인 APS(Ammonium persulfate) 및 유화제인 EG(Ethylene glycol)를 상기 원통형 탱크에 각각 투입하여 1~6시간 다시 믹싱하는 2차 믹싱 공정을 포함하는 것을 특징으로 한다.In the method of manufacturing the polymer barrier material for repairing water leaks in the reservoir stomach, the monomer acrylamide, the cross-linking agent MBAA (N-Methylenebisacrylamide), and the additive MMA (Methylmethacrylate) are mixed with an aqueous solution of water in a cylindrical tank. A first mixing process of mixing for 1 to 2 hours; After the first mixing, the initiator APS (Ammonium persulfate) and the emulsifier EG (Ethylene glycol) are respectively added to the cylindrical tank and mixed again for 1 to 6 hours.
여기에서, 상기 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법은 상기 2차 믹싱 공정 중 연쇄 중합반응 속도를 높이기 위해 촉매인 TEMED(Tetramethylethylenediamine)를 투입하는 촉매 투입 공정을 더 포함한다.Here, the method of manufacturing the polymer barrier material for repairing water leaks in the reservoir stomach further includes a catalyst input process in which TEMED (Tetramethylethylenediamine), a catalyst, is added to increase the rate of chain polymerization reaction during the secondary mixing process.
여기에서 또한, 상기 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법은 상기 1차 믹싱 공정, 2차 믹싱 공정, 촉매 투입 공정은 공기중 산소와 혼합물이 접촉하여 원치 않는 반응이 일어나는 것을 차단하도록 상기 원통형 탱크로 질소를 지속적으로 주입하여 산소와의 접촉을 차단한다.Here, in the method of manufacturing the polymer barrier material for water leak repair in the reservoir stomach, the first mixing process, the second mixing process, and the catalyst introduction process are performed to prevent unwanted reactions from occurring due to contact between the mixture and oxygen in the air. Nitrogen is continuously injected into the cylindrical tank to block contact with oxygen.
여기에서 또, 상기 2차 믹싱 공정은 상기 원통형 탱크 내부를 상온보다 낮은 저온으로 유지시켜 젤 상태의 폴리머 차수재를 제조하도록 16~19℃의 물이 담긴 수조에 넣은 상태에서 1~6시간 동안 배치한다.Here again, the secondary mixing process is placed in a water tank containing water at 16 to 19°C for 1 to 6 hours to produce a gel-like polymer barrier material by maintaining the inside of the cylindrical tank at a temperature lower than room temperature. do.
상기와 같이 구성되는 본 발명인 저수지 복통의 누수 보수용 폴리머 차수재 및 이의 제조 방법에 따르면, 초기 누수 진행에 대한 반응속도와, 최종 부피비를 향상시켜 시공이음부 차수 백업제로 최적의 차수재를 제공할 수 있다.According to the present invention, a polymer barrier material for water leak repair in a reservoir stomach constructed as described above, and its manufacturing method, the reaction rate to the initial water leak progress and the final volume ratio can be improved to provide an optimal water barrier material as a water barrier backup agent for construction joints. You can.
도 1은 저수지 복통의 시공이음부에서 발생하는 누수 현상을 설명하기 위한 도면이다.
도 2는 본 발명에 따른 저수지 복통의 누수 보수용 폴리머 차수재가 저수지 복통의 시공이음부에 시공된 모습을 나타낸 도면이다.
도 3은 본 발명의 실시예, 비교예1, 2의 인장강도를 나타낸 그래프이다.
도 4는 본 발명의 실시예, 비교예1, 2의 초기 반응속도를 나타낸 그래프이다.
도 5는 본 발명의 실시예, 비교예1, 2의 팽윤도를 나타낸 그래프이다.
도 6은 본 발명의 실시예, 비교예1, 2의 팽윤도 변화 사진이다.Figure 1 is a diagram for explaining the water leak phenomenon occurring at the construction joint of the reservoir stomach.
Figure 2 is a view showing the polymer barrier material for repairing water leaks in the reservoir tube according to the present invention being installed at the construction joint of the reservoir tube.
Figure 3 is a graph showing the tensile strength of Examples and Comparative Examples 1 and 2 of the present invention.
Figure 4 is a graph showing the initial reaction rates of Examples and Comparative Examples 1 and 2 of the present invention.
Figure 5 is a graph showing the swelling degree of Examples and Comparative Examples 1 and 2 of the present invention.
Figure 6 is a photograph of the change in swelling degree of Examples and Comparative Examples 1 and 2 of the present invention.
이하, 본 발명에 따른 저수지 복통의 누수 보수용 폴리머 차수재를 첨부된 도면을 참조하여 상세하게 설명하면 다음과 같다.Hereinafter, the polymer barrier material for repairing water leaks in a reservoir tank according to the present invention will be described in detail with reference to the attached drawings.
하기에서 본 발명을 설명함에 있어, 관련된 공지 기능 또는 구성에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명은 생략할 것이다. 그리고 후술되는 용어들은 본 발명에서의 기능을 고려하여 정의된 용어들로서 이는 사용자, 운용자의 의도 또는 관례 등에 따라 달라질 수 있다. 그러므로 그 정의는 본 명세서 전반에 걸친 내용을 토대로 내려져야 할 것이다.In the following description of the present invention, if it is determined that a detailed description of a related known function or configuration may unnecessarily obscure the gist of the present invention, the detailed description will be omitted. The terms described below are defined in consideration of the functions in the present invention, and may vary depending on the intention or custom of the user or operator. Therefore, the definition should be made based on the contents throughout this specification.
본 발명에 따른 저수지 복통의 누수 보수용 폴리머 차수재는 도 2에 도시된 바와 같이 저수지 복통의 시공이음부 사이에 주입되어 누수를 보수한다.The polymer water barrier material for water leak repair in the reservoir tank according to the present invention is injected between the construction joints of the reservoir tank, as shown in Figure 2, to repair the water leak.
본 발명에 따른 저수지 복통의 누수 보수용 폴리머 차수재는 수용액인 물 10~80중량%, 단량체인 아크릴아마이드(acrylamide) 5~45중량%, 유화제인 EG(Ethylene glycol) 5~45중량%, 가교제인 MBAA(N-Methylenebisacrylamide) 0.2~1.0중량%, 첨가제인 MMA(Methylmethacrylate) 0.5~2.0중량%, 개시제인 APS(Ammonium persulfate) 0.5~2.0중량%로 혼합된다.The polymer barrier material for repairing water leaks in the reservoir stomach according to the present invention consists of 10 to 80% by weight of water as an aqueous solution, 5 to 45% by weight of acrylamide as a monomer, 5 to 45% by weight of EG (Ethylene glycol) as an emulsifier, and 5 to 45% by weight as a crosslinking agent. It is mixed with 0.2~1.0% by weight of MBAA (N-Methylenebisacrylamide), 0.5~2.0% by weight of MMA (Methylmethacrylate) as an additive, and 0.5~2.0% by weight of APS (Ammonium persulfate) as an initiator.
이때, 유화제는 첨가제인 MMA(Methylmethacrylate)의 인장강도가 떨어질 수 있어, 인장강도를 높이기 위하여 분자량이 작은 폴리올계 물질인 EG(Ethylene glycol)를 첨가하여 MMA(Methylmethacrylate) 첨가에 따른 인장강도 저하를 보완하였다.At this time, the emulsifier may reduce the tensile strength of the additive MMA (Methylmethacrylate), so to increase the tensile strength, EG (Ethylene glycol), a polyol-based material with a low molecular weight, is added to compensate for the decrease in tensile strength caused by the addition of MMA (Methylmethacrylate). did.
또한, 단량체, 유화제, 가교제, 첨가제 및 개시제가 중량 범위에 미달하거나 초과하는 경우 반응속도나 팽윤성 개선효과가 미비하였고, 재료 분리현상이 발생한다.In addition, if the monomer, emulsifier, crosslinker, additive, and initiator are below or exceed the weight range, the effect of improving the reaction rate or swelling property is minimal, and material separation occurs.
표 1은 본 발명에 따른 저수지 복통의 누수 보수용 폴리머 차수재의 최적의 배합비를 나타낸 것이다.Table 1 shows the optimal mixing ratio of the polymer barrier material for water leak repair in the reservoir tank according to the present invention.
한편, 본 발명에 따른 저수지 복통의 누수 보수용 폴리머 차수재는 연쇄 중합반응 속도를 높이기 위해 촉매인 TEMED(Tetramethylethylenediamine)가 전체 용액 중량 대비 0.01~0.1중량% 더 혼합되는 것이 바람직하다.Meanwhile, in the polymer barrier material for repairing water leakage in a reservoir tank according to the present invention, it is preferable that 0.01 to 0.1% by weight of TEMED (Tetramethylethylenediamine), a catalyst, be added to the total solution weight to increase the chain polymerization reaction rate.
그리고, 저수지 복통의 누수 보수용 폴리머 차수재는 도 2에 도시된 바와 같이 사각기둥 또는 원기둥 형상을 이루어는 것이 바람직하다.Also, it is preferable that the polymer barrier material for water leak repair in the reservoir tube has a square or cylindrical shape as shown in FIG. 2.
이하, 본 발명에 따른 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법을 상세하게 설명하면 다음과 같다.Hereinafter, the method of manufacturing the polymer barrier material for repairing water leaks in the reservoir tank according to the present invention will be described in detail as follows.
《1차 믹싱 공정》《First mixing process》
먼저, 단량체인 아크릴아마이드(acrylamide), 가교제인 MBAA(N-Methylenebisacrylamide), 첨가제인 MMA(Methylmethacrylate)를 수용액인 물에 혼합하여 원통형 탱크에서 1~2시간 믹싱한다.First, the monomer acrylamide, the crosslinking agent MBAA (N-Methylenebisacrylamide), and the additive MMA (Methylmethacrylate) are mixed in an aqueous solution of water and mixed for 1 to 2 hours in a cylindrical tank.
《2차 믹싱 공정》《Second mixing process》
1차 믹싱이 완료되면, 개시제인 APS(Ammonium persulfate) 및 유화제인 EG(Ethylene glycol)를 원통형 탱크에 각각 투입하여 1~6시간 다시 믹싱한다. 이때, 2차 믹싱 공정 중 연쇄 중합반응 속도를 높이기 위해 촉매인 TEMED(Tetramethylethylenediamine)를 투입한다.After the first mixing is completed, the initiator APS (Ammonium persulfate) and the emulsifier EG (Ethylene glycol) are added to the cylindrical tank and mixed again for 1 to 6 hours. At this time, the catalyst TEMED (Tetramethylethylenediamine) is added to speed up the chain polymerization reaction during the second mixing process.
또한, 2차 믹싱 공정은 원통형 탱크 내부를 상온보다 낮은 저온으로 유지시켜 젤 상태의 폴리머 차수재를 제조하도록 16~19℃의 물이 담긴 수조에 넣은 상태에서 1~6시간 동안 배치한다.In addition, the second mixing process is performed by maintaining the inside of the cylindrical tank at a temperature lower than room temperature and placing it in a water tank filled with water at 16-19°C for 1-6 hours to produce a gel-like polymer barrier material.
한편, 본 발명에 따른 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법은 1차 믹싱 공정, 2차 믹싱 공정 및 촉매 투입 공정은 공기중 산소와 혼합물이 접촉하여 원치 않는 반응이 일어나는 것을 차단하도록 원통형 탱크로 질소를 지속적으로 주입하여 산소와의 접촉을 차단하는 것이 바람직하다.Meanwhile, in the method of manufacturing a polymer barrier material for water leak repair in a reservoir tank according to the present invention, the first mixing process, the second mixing process, and the catalyst introduction process are cylindrical to prevent unwanted reactions from occurring when the mixture comes into contact with oxygen in the air. It is desirable to continuously inject nitrogen into the tank to block contact with oxygen.
이하에서는 실시예에 의거하여 본 발명을 상세히 살펴본다. 다만 아래의 실시예는 본 발명을 예시하기 위한 것일 뿐이며, 본 발명의 범위가 이로써 한정되는 것은 아니다.Hereinafter, the present invention will be examined in detail based on examples. However, the examples below are only for illustrating the present invention, and the scope of the present invention is not limited thereto.
표 2는 본 발명의 폴리머 차수재를 실시예로 하고, 종래 기술(국내 등록특허 제10-1920120호)에 따른 폴리머 차수재를 비교예1, 팽윤성 및 반응속도 증가를 위해 실시예 1 대비 유화제를 2배 증가시킨 비교예 2의 배합비를 나타낸 것이다.Table 2 shows the polymer barrier material of the present invention as an example, the polymer barrier material according to the prior art (Korea Patent No. 10-1920120) as Comparative Example 1, and an emulsifier compared to Example 1 to increase swelling properties and reaction speed. This shows the mixing ratio of Comparative Example 2, which was doubled.
《인장강도》"tensile strength"
도 3은 본 발명의 실시예, 비교예1, 2의 인장강도를 나타낸 그래프이다.Figure 3 is a graph showing the tensile strength of Examples and Comparative Examples 1 and 2 of the present invention.
도 3을 참조하면, 인장강도는 실시예가 0.1784MPa, 비교예1이 0.1528MPa, 비교예2가 0.2387MPa를 나타내었다. 실시예의 인장강도는 비교예1보다 16% 성능이 향상됨을 확인하였다. 비교예2의 인장강도는 비교예1보다 56% 인장강도가 향상되었으나, 재료 분리가 일어났다.Referring to Figure 3, the tensile strength of Example was 0.1784 MPa, Comparative Example 1 was 0.1528 MPa, and Comparative Example 2 was 0.2387 MPa. It was confirmed that the tensile strength of the example was improved by 16% compared to Comparative Example 1. The tensile strength of Comparative Example 2 was improved by 56% compared to Comparative Example 1, but material separation occurred.
《초기 반응속도》《Initial reaction speed》
도 4는 본 발명의 실시예, 비교예1, 2의 초기 반응속도를 나타낸 그래프이다.Figure 4 is a graph showing the initial reaction rates of Examples and Comparative Examples 1 and 2 of the present invention.
물을 흡수하여 부피가 120% 증가하는 데 실시예는 약 45분, 비교예1은 약 200분, 비교예2는 약 35분이 걸려, 실시예와 비교예2의 반응속도가 비교예1과 비교하여 매우 빠름을 알 수 있다. 그리고 실시예의 반응속도는 비교예1보다 77% 감소하는 것을 확인하였고, 비교예2의 반응속도는 비교예1보다 82% 감소하는 것을 확인할 수 있었다.It took about 45 minutes for Example to increase the volume by 120% by absorbing water, about 200 minutes for Comparative Example 1, and about 35 minutes for Comparative Example 2, so the reaction rates of Example and Comparative Example 2 were compared to Comparative Example 1. So you can see that it is very fast. And the reaction rate of Example was confirmed to be reduced by 77% compared to Comparative Example 1, and the reaction rate of Comparative Example 2 was confirmed to be reduced by 82% compared to Comparative Example 1.
《팽윤도》《Swelling degree》
도 5는 본 발명의 실시예, 비교예1, 2의 팽윤도를 나타낸 그래프이고, 도 6은 본 발명의 실시예, 비교예1, 2의 팽윤도 변화사진이다.Figure 5 is a graph showing the swelling degree of the Examples and Comparative Examples 1 and 2 of the present invention, and Figure 6 is a photograph of the change in swelling degree of the Examples and Comparative Examples 1 and 2 of the present invention.
50시간 경과 후 부피 증가는 실시예는 약 220%, 비교예1은 약 160%, 비교예2는 24시간 경과 후 재료 분리가 일어났다. 실시예는 비교예1보다 30% 부피비가 향상됨을 확인할 수 있었다.After 50 hours, the volume increase was about 220% in Example, about 160% in Comparative Example 1, and material separation occurred in Comparative Example 2 after 24 hours. It was confirmed that the volume ratio of the example was improved by 30% compared to Comparative Example 1.
본 발명은 다양하게 변형될 수 있고 여러 가지 형태를 취할 수 있으며 상기 발명의 상세한 설명에서는 그에 따른 특별한 실시 예에 대해서만 기술하였다. 하지만 본 발명은 상세한 설명에서 언급되는 특별한 형태로 한정되는 것이 아닌 것으로 이해되어야 하며, 오히려 첨부된 청구범위에 의해 정의되는 본 발명의 정신과 범위 내에 있는 모든 변형물과 균등물 및 대체물을 포함하는 것으로 이해되어야 한다.The present invention can be modified in various ways and can take various forms, and in the detailed description of the invention, only special embodiments thereof have been described. However, it should be understood that the present invention is not limited to the particular form mentioned in the detailed description, but rather is understood to include all modifications, equivalents and substitutes within the spirit and scope of the present invention as defined by the appended claims. It has to be.
Claims (7)
상기 폴리머 차수재는,
수용액인 물 10~80중량%, 단량체인 아크릴아마이드(acrylamide) 5~45중량%, 유화제인 EG(Ethylene glycol) 5~45중량%, 가교제인 MBAA(N-Methylenebisacrylamide) 0.2~1.0중량%, 첨가제인 MMA(Methylmethacrylate) 0.5~2.0중량%, 개시제인 APS(Ammonium persulfate) 0.5~2.0중량%로 혼합되는 것을 특징으로 하는 저수지 복통의 누수 보수용 폴리머 차수재.In the polymer barrier material that repairs water leakage by being injected into perforation holes drilled in the vertical direction between the construction joints of the reservoir barrel,
The polymer barrier material is,
10 to 80% by weight of water as an aqueous solution, 5 to 45% by weight of acrylamide as a monomer, 5 to 45% by weight of EG (Ethylene glycol) as an emulsifier, 0.2 to 1.0% by weight of MBAA (N-Methylenebisacrylamide) as a crosslinker, and additives. A polymer barrier material for repairing leaks in a reservoir tank, characterized in that it is mixed with 0.5 to 2.0% by weight of MMA (Methylmethacrylate) and 0.5 to 2.0% by weight of APS (Ammonium persulfate), an initiator.
상기 저수지 복통의 누수 보수용 폴리머 차수재는,
연쇄 중합반응 속도를 높이기 위해 촉매인 TEMED(Tetramethylethylenediamine)가 전체 용액 중량 대비 0.01~0.1중량% 더 혼합되는 것을 특징으로 하는 저수지 복통의 누수 보수용 폴리머 차수재.According to claim 1,
The polymer waterproofing material for repairing water leaks in the reservoir stomach,
A polymer barrier material for repairing water leaks in a reservoir tank, characterized by mixing 0.01 to 0.1% by weight of TEMED (Tetramethylethylenediamine), a catalyst, based on the total solution weight, to increase the rate of chain polymerization reaction.
상기 저수지 복통의 누수 보수용 폴리머 차수재는,
원기둥 또는 사각기둥 형상인 것을 특징으로 하는 저수지 복통의 누수 보수용 폴리머 차수재.According to claim 1,
The polymer waterproofing material for repairing water leaks in the reservoir stomach,
A polymer barrier material for water leak repair in a reservoir tank, characterized in that it has a cylindrical or square column shape.
단량체인 아크릴아마이드(acrylamide), 가교제인 MBAA(N-Methylenebisacrylamide), 첨가제인 MMA(Methylmethacrylate)를 수용액인 물에 혼합하여 원통형 탱크에서 1~2시간 믹싱하는 1차 믹싱 공정과;
1차 믹싱 후, 개시제인 APS(Ammonium persulfate) 및 유화제인 EG(Ethylene glycol)를 상기 원통형 탱크에 각각 투입하여 1~6시간 다시 믹싱하는 2차 믹싱 공정을 포함하는 것을 특징으로 하는 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법.In the method of manufacturing a polymer barrier material for water leak repair in the reservoir stomach of claim 1,
A first mixing process in which the monomer acrylamide, the crosslinking agent MBAA (N-Methylenebisacrylamide), and the additive MMA (Methylmethacrylate) are mixed in an aqueous solution of water and mixed in a cylindrical tank for 1 to 2 hours;
After the first mixing, the initiator APS (Ammonium persulfate) and the emulsifier EG (Ethylene glycol) are added to the cylindrical tank and mixed again for 1 to 6 hours. Method for manufacturing polymer water barrier material for repairs.
상기 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법은,
상기 2차 믹싱 공정 중 연쇄 중합반응 속도를 높이기 위해 촉매인 TEMED(Tetramethylethylenediamine)를 투입하는 촉매 투입 공정을 더 포함하는 것을 특징으로 하는 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법.According to claim 4,
The method of manufacturing the polymer water barrier material for water leak repair in the reservoir stomach is,
A method of manufacturing a polymer barrier material for repairing water leaks in a reservoir tank, further comprising a catalyst introduction process of adding TEMED (Tetramethylethylenediamine), a catalyst, to increase the rate of chain polymerization reaction during the secondary mixing process.
상기 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법은,
상기 1차 믹싱 공정, 2차 믹싱 공정, 촉매 투입 공정은 공기중 산소와 혼합물이 접촉하여 원치 않는 반응이 일어나는 것을 차단하도록 상기 원통형 탱크로 질소를 지속적으로 주입하여 산소와의 접촉을 차단하는 것을 특징으로 하는 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법.According to claim 5,
The method of manufacturing the polymer water barrier material for water leak repair in the reservoir stomach is,
The first mixing process, the second mixing process, and the catalyst introduction process are characterized by continuously injecting nitrogen into the cylindrical tank to block contact with oxygen to prevent unwanted reactions from occurring due to contact between the mixture and oxygen in the air. A method of manufacturing a polymer barrier material for water leak repair in a reservoir tank.
상기 2차 믹싱 공정은,
상기 원통형 탱크의 내부를 상온보다 낮은 저온으로 유지시켜 젤 상태의 폴리머 차수재를 제조하도록 16~19℃의 물이 담긴 수조에 넣은 상태에서 1~6시간 동안 배치하는 것을 특징으로 하는 저수지 복통의 누수 보수용 폴리머 차수재의 제조 방법.According to claim 4,
The secondary mixing process is,
Leakage of the reservoir stomach, characterized in that the interior of the cylindrical tank is maintained at a temperature lower than room temperature and placed in a water tank containing water at 16 to 19 ° C for 1 to 6 hours to produce a gel-like polymer barrier material. Method for manufacturing polymer water barrier material for repairs.
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| KR0174745B1 (en) * | 1990-01-31 | 1999-04-01 | 마쓰다 히로하루 | Process for production of water-absorbent resin |
| KR101920120B1 (en) | 2016-04-18 | 2018-11-19 | 한양대학교 산학협력단 | Polymer waterproof material and method for preventing leakage of concrete dam structure using polymer waterproof material |
| KR20220084674A (en) * | 2020-12-14 | 2022-06-21 | 한국지역난방공사 | Water-soluble polymer for pipe plugging |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR0174745B1 (en) * | 1990-01-31 | 1999-04-01 | 마쓰다 히로하루 | Process for production of water-absorbent resin |
| KR101920120B1 (en) | 2016-04-18 | 2018-11-19 | 한양대학교 산학협력단 | Polymer waterproof material and method for preventing leakage of concrete dam structure using polymer waterproof material |
| KR20220084674A (en) * | 2020-12-14 | 2022-06-21 | 한국지역난방공사 | Water-soluble polymer for pipe plugging |
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