KR102598796B1 - High internal phase low viscosity eye make-up cosmetic composition - Google Patents

Abstract

The present invention provides a wax portion containing 10% by weight or more of carnauba wax based on the total weight of the composition; And an emulsifier part containing a first fatty acid ether emulsifier, a second fatty acid ether emulsifier, and a PEG-silicone emulsifier; a high internal phase, low viscosity eye makeup composition containing 20 to 60% by weight of the inner phase based on the total weight of the composition. Begin. Specifically, the eye makeup composition according to the present invention contains a high content of wax present in the inner phase, and can exhibit excellent setting effects (curling retention) and volume effects, and has a low point of 10,000 to 100,000 cps while containing a high content of wax. It is formed from a coating composition and can be applied neatly without clumping.

Description

High internal injury low viscosity eye makeup composition {HIGH INTERNAL PHASE LOW VISCOSITY EYE MAKE-UP COSMETIC COMPOSITION}

The present invention relates to an eye makeup composition, and to an eye makeup composition with a high internal phase and low viscosity in which the internal phase is made of wax.

In general, the function of mascara is to apply it to the eyelashes to curl the eyelashes longer and add volume to emphasize the eyes. Volume in mascara refers to the fact that mascara is applied abundantly to the eyelashes, making the eyelashes appear thicker and fuller than their original state.

Accordingly, many methods have been developed to improve the volume function, and among them, wax emulsification is the main method because the wax contained in the inner layer of mascara affects the setting function (curling durability) and eyelash volume.

However, as the content of wax present in the inner phase increases, the viscosity increases significantly, making it impossible to apply. In terms of formulation, most emulsions with high internal phase mainly contain oil in the inner phase, which gives volume to eyelashes. The effect is weak, and the higher the oil content, the worse the smearing under the eyes becomes.

In addition, if it contains powder, it can easily create volume as the powder content increases, so it is commonly used in volume-type mascara. However, in the case of spherical powder, the adhesion area to the surface of eyelashes is small, so if it is not applied evenly and reapplied, it may cause damage to the eyelashes. It has the disadvantage of falling off and causing the powder to fall off, and in the case of plate-shaped powder, the amount spread is small, which reduces the volume. To solve this problem, if the powder content is increased, there is a problem that the mascara spreads in clumps or the texture of the mascara becomes rough.

Republic of Korea Patent Publication No. 10-2018-0024839

In order to solve the above problems, the present invention provides a high-viscosity, low-viscosity eye makeup composition that contains a high amount of wax that provides a volume function to eyelashes and has a low viscosity, thereby providing a clean volume effect without clumping. The purpose is to

In order to achieve the above object, an embodiment of the present invention includes a wax portion containing 10% by weight or more of carnauba wax based on the total weight of the composition; And an emulsifier part containing a first fatty acid ether emulsifier, a second fatty acid ether emulsifier, and a PEG-silicone emulsifier; a high internal phase, low viscosity eye makeup composition containing 20 to 60% by weight of the inner phase based on the total weight of the composition. to provide.

The eye makeup composition according to the present invention contains a high content of wax present in the inner phase, and can exhibit excellent setting effects (curling retention) and volume effects. It is a low-viscosity composition of 10,000 to 100,000 cps while containing a high content of wax. It can be formed and applied neatly without clumping.

Hereinafter, the present invention will be described in detail.

In one aspect, the present invention provides a wax portion containing 10% by weight or more of carnauba wax based on the total weight of the composition; and an emulsifier unit comprising a first fatty acid ether-based emulsifier, a second fatty acid ether-based emulsifier, and a PEG-silicone-based emulsifier; It may relate to a high internal phase, low viscosity eye makeup composition containing 20 to 60% by weight of the internal phase based on the total weight of the composition.

In this specification, high internal phase refers to a high content of internal phase, and specifically refers to a case where the content of the internal phase is 20% by weight or more, 30% by weight, 40% by weight, or 50% by weight or more based on the total weight of the composition. do.

As used herein, low viscosity means a viscosity of 500,000 cps or less, 400,000 cps or less, 300,000 cps or less, 200,000 cps or less, or 100,000 cps or less, and preferably means a viscosity of 100,000 cps or less.

The wax portion may contribute to the eyelash setting function and volume effect of the eye makeup composition of the present invention. As an example, the carnauba wax included in the wax portion is 10% by weight or more, 15% by weight, 20% by weight, 25% by weight, 30% by weight, 35% by weight or more, or It may be 40% by weight or more, 45% by weight or less, 40% by weight or less, 35% by weight or less, 30% by weight or less, 25% by weight or less, 20% by weight or less, or 15% by weight or less. Within the above range, eyelash setting function and volume effect may be excellent.

In one embodiment, the wax portion may further include additional wax in addition to the carnauba wax, and the additional wax may be a high-melting point wax with a melting point of 70°C to 105°C. The high melting point wax has a melting point of 70°C to 105°C, and when included in a high content in the inner phase, clumping may become severe or the viscosity may increase to the point where it cannot be used as a mascara formulation. However, in the case of the present invention, the high melting point wax is used in high content. It is characterized by realizing a low-viscosity formulation that contains and does not clump.

The melting point of the high melting point wax is, for example, 70°C or higher, 71°C or higher, 72°C or higher, 73°C or higher, 74°C or higher, 75°C or higher, 76°C or higher, 77°C or higher, 78°C or higher, 79°C or higher. , 80℃ or higher, 81℃ or higher, 82℃ or higher, 83℃ or higher, 84℃ or higher, 85℃ or higher, 86℃ or higher, 87℃ or higher, 88℃ or higher, 89℃ or higher, 90℃ or higher, 95℃ or higher, or Above 100℃, below 105℃, below 100℃, below 95℃, below 90℃, below 89℃, below 88℃, below 87℃, below 86℃, below 85℃, below 84℃, below 83℃, 82 It may be ℃ or less, 81℃ or less, 80℃ or less, 79℃ or less, 78℃ or less, 77℃ or less, 76℃ or less, 75℃ or less, 74℃ or less, 73℃ or less, 72℃ or less, or 71℃ or less.

Examples of the high melting point wax include sunflower seed wax, bees wax, candelilla wax, jojoba seed wax, jasmine flower wax, and orchid. Examples include ozokerite, paraffin, and synthetic wax, and may further include one or more selected from among these, but are not limited thereto. Also, preferably, the wax portion may include two or more types of high melting point wax.

In one embodiment, the wax portion may be contained in an amount of 20 to 50% by weight based on the total weight of the composition. As an example, the content of the wax portion is 20% by weight or more, 23% by weight or more, 25% by weight or more, 27% by weight or more, 30% by weight or more, 33% by weight or more, 35% by weight or more, 37% by weight or more, based on the total weight of the composition. wt% or more, 40 wt% or more, 43 wt% or more, 45 wt% or more, or 47 wt% or more, and 47 wt% or less, 45 wt% or less, 43 wt% or less, 40 wt% or less, 37 wt% or less. , may be 35% by weight or less, 33% by weight or less, 30% by weight or less, 27% by weight or less, 25% by weight or less, or 23% by weight or less. Within the above range, eyelash setting function and volume effect may be excellent.

The emulsifier part is a component included in the inner phase together with the wax part, and can contribute to implementing the composition as a low-viscosity formulation.

In one embodiment, the emulsifier unit may include a first fatty acid ether-based emulsifier, a second fatty acid ether-based emulsifier, and a PEG-silicone-based emulsifier.

The fatty acid ether emulsifier varies depending on the combination of fatty acid and ether group (-OCH ₂ CH ₂ ), for example, the fatty acid is lauryl-, myristyl, depending on the type of fatty acid having 12 to 18 carbon atoms. It may be a -(myristyl-), palmityl-, or stearyl-) group, and the total number of carbon atoms contained in the ether group may be 2 to 30, depending on the number of ether groups.

For example, laureth-2, laureth-3, laureth-4, laureth-5, laureth-6 ), laureth-7, laureth-8, laureth-30, myristeth-7, steareth-2 2), Steareth-4, Steareth-10, Steareth-20, Steareth-21, Steareth-30 ), etc., but is not limited thereto.

For example, the first fatty acid ether emulsifier may be one of the various fatty acid ether compounds with an ether group having 20 to 30 carbon atoms, and preferably may be steareth-21.

The second fatty acid ether emulsifier may be, for example, one of the various fatty acid ether compounds with a total number of carbon atoms in the ether group of 2 to 19, and is preferably laureth-2 or steareth-2. It can be 2(steareth-2).

The PEG-silicone emulsifiers include PEG-3 dimethicone, PEG-6 dimethicone, PEG-7 dimethicone, PEG-8 dimethicone, PEG-9 dimethicone, PEG-10 dimethicone, PEG-12 dimethicone, PEG- It may be one or more selected from the group consisting of 14 dimethicone and PEG-17 dimethicone, but is not limited thereto, and PEG-10 dimethicone is preferably used.

The first fatty acid ether-based emulsifier, the second fatty acid ether-based emulsifier, and the PEG-silicone-based emulsifier may be contained in a weight ratio of 2 to 12:1 to 2:0.5 to 1, and within this range, a high content of wax is stably emulsified. You can do it. Additionally, as an example, it may preferably be contained in a weight ratio of 3:1:1.

In one embodiment, the emulsifier unit may further include fatty acid alcohol as an emulsification aid to further stabilize the emulsion film. The fatty acid alcohol is, for example, cetyl alcohol, stearyl alcohol, cetearyl alcohol, oleyl alcohol, lauryl alcohol, behenyl. It may be one or more selected from the group consisting of behenyl alcohol and linoleyl alcohol, but is not limited thereto, and is preferably behenyl alcohol.

In one embodiment, the first ether-based emulsifier, the second ether-based emulsifier, the PEG-silicone-based emulsifier and the fatty acid alcohol may be contained in a weight ratio of 2 to 12:1 to 2:0.5 to 1:0.5 to 1, Within this range, a high content of wax can be stably emulsified. Additionally, as an example, it may preferably be contained in a weight ratio of 3:1:1:1.

In one embodiment, the eye makeup composition of the present invention is formed as a low-viscosity formulation with a viscosity of 10,000 to 100,000 cps, so that it does not clump and has excellent spreadability. For example, the composition may have a viscosity of at least 10,000 cps, at least 15,000 cps, at least 20,000 cps, at least 25,000 cps, at least 30,000 cps, at least 35,000 cps, at least 40,000 cps, at least 45,000 cps, at least 50,000 cps, at least 55,000 cps, 60,000 cps or higher, 65,000 cps or higher, 70,000 cps or higher, 75,000 cps or higher, 80,000 cps or higher, 85,000 cps or higher, 90,000 cps or higher, or 95,000 cps or higher and 100,000 cps or lower, 95,000 cps or lower, 90,000 cps or lower, 85,0 00 cps or less, 80,000 cps or less, 75,000 cps or less, 70,000 cps or less, 65,000 cps or less, 60,000 cps or less, 55,000 cps or less, 50,000 cps or less, 45,000 cps or less, 40,000 cps or less, 35,000 cps or less, 30,000 cps or less, 25,000 c ps or less, 20,000 cps or less , or may be less than 15,000 cps. Within the above range, it does not have a thick cream-like feel and can be applied without clumping. The composition according to the present invention can stably contain a high content of wax in a low-viscosity formulation, and can simultaneously exhibit the characteristics of a low-viscosity formulation with excellent application ability without clumping and an excellent curling retention effect and volume effect.

The eye makeup composition of the present invention may be included in a formulation containing mascara, eye shadow, eyebrow pencil, and eye liner, and may specifically be used for mascara, but is not limited thereto.

Meanwhile, the composition may contain aqueous components commonly used in the technical field, for example, water, glycerin, butylene glycol, dipropylene glycol, dipropylene glycol, pentylene glycol, etc. However, it is not limited to this.

In addition, it optionally further includes colorants, powders, dispersants, preservatives, thickeners, antioxidants, dyes, pigments, or any other functional ingredients commonly used in cosmetics, to the extent that they do not impair the purpose and effect of the present invention. It can be done, and the amount is introduced as the amount commonly used in the art.

Hereinafter, the contents of the present invention will be described in more detail through examples and test examples. However, these examples and test examples are only presented to understand the content of the present invention, and the scope of the present invention is not limited to these examples and test examples. Modifications and substitutions commonly known in the art and insertion, etc. can be performed, and this is also included in the scope of the present invention.

[Test Example 1] Evaluation of viscosity and agglomeration according to the type of emulsifier

An eye makeup composition containing 10% by weight of wax based on the total weight of the composition was prepared using the composition shown in Table 1 below, and the viscosity of each was measured at 30°C using a HADV-III U Rheometer (Brookfield). In addition, the degree of clumping was determined by four expert panelists applying the eye makeup composition shown in Table 1 to the eyelashes and then checking the clumping between eyelashes, based on no clumping (X), clumping present (○), and severe clumping (◎). evaluated. The application method was specifically applied to the eyelashes divided into the front of the eye (1), the middle of the eye (2), and the tail of the eye (3). 1) After applying the composition with a brush in the order 2-3-1, 2) Before the composition dries, apply a second time in the order 2-3-1-2-3-2, then after 15 seconds, 3) after the composition dries, apply 3 times in the order 2-3-1-2-3-2 Tea was applied to confirm strand aggregation.

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 awards department Purified water to 100 to 100 to 100 to 100 Disodium EDTA 0.1 0.1 0.1 0.1 Hydroxyethyl acrylate/sodium acryloyldimethyl copolymer 0.2 0.2 0.2 0.2 polyvinylpyrrolidone 10.0 10.0 10.0 10.0 carbon black 5.0 5.0 5.0 5.0 alumina 2.0 2.0 2.0 2.0 Acrylate copolymer 20.0 20.0 20.0 20.0 Phenoxyethanol 0.4 0.4 0.4 0.4 wax part carnauba wax 5.0 5.0 5.0 5.0 paraffin 5.0 5.0 5.0 5.0 Emulsifier part Steareth-21 3.0 Laureth-2 1.0 behenyl alcohol 1.0 PEG-10 Dimethicone 1.0 Cetearyl Glucoside/Cetearyl Alcohol 3.5 Polysorbate 60 1.2 stearic acid 5.5 Aminomethylpropanediol 1.5 PEG-15 Glyceryl Stearate 4.0 Polysorbate 20 1.0 Viscosity (℃, cps) 60,800 313,000 332,000 62,400 lump X ◎ ○ X

From the results in Table 1, the viscosity of Comparative Example 1 containing Steareth-21, Laureth-2, PEG-10 dimethicone and Behenyl alcohol as emulsifiers according to the present invention at a weight ratio of 3:1:1:1 It was confirmed that the was the lowest and there was no clumping. On the other hand, in the case of Comparative Examples 2 and 3, which did not contain the fatty acid ether-based emulsifier and PEG-silicone-based emulsifier according to the present invention as emulsifiers, the viscosity was very high, over 300,000 cps, and agglomeration was severe. Meanwhile, in the case of Comparative Example 4, similar to Comparative Example 1, it was found that there was no agglomeration due to low viscosity. However, through Test Example 2 below, it was confirmed that the wax could hardly be emulsified when the inner wax content increased to 25% by weight. did.

[Test Example 2] Viscosity evaluation according to the type of emulsifier when containing a high content of wax

An eye makeup composition containing 25% by weight of wax based on the total weight of the composition was prepared using the composition shown in Table 2 below, and each viscosity was measured in the same manner as in Test Example 1.

Example 1 Comparative Example 5 awards department Purified water to 100 to 100 Disodium EDTA 0.1 0.1 Hydroxyethyl acrylate/sodium acryloyldimethyl copolymer 0.2 0.2 polyvinylpyrrolidone 10.0 10.0 carbon black 5.0 5.0 alumina 2.0 2.0 Acrylate copolymer 20.0 20.0 Phenoxyethanol 0.4 0.4 wax part candelilla wax 5.0 5.0 carnauba wax 10.0 10.0 paraffin 10.0 10.0 Emulsifier part Steareth-21 3.0 Laureth-2 1.0 behenyl alcohol 1.0 PEG-10 Dimethicone 1.0 PEG-15 Glyceryl Stearate 4.0 Polysorbate 20 1.0 Viscosity (℃, cps) 60,000 Error
(over 400,000)

From the results in Table 2, it was confirmed that Example 1 according to the present invention was implemented as a low-viscosity formulation with a viscosity of 60,000 cps while containing a high content of wax. On the other hand, in the case of Comparative Example 5, which contained the same emulsifier composition as Comparative Example 4 in Table 1 but increased the content of the wax portion, the viscosity was realized at an extremely high viscosity of 400,000 or more, and it was confirmed that the wax portion was hardly emulsified.

[Test Example 3] Viscosity evaluation according to the content of inner wax

Eye makeup containing 25% by weight (inner box content: 31% by weight), 50% by weight (inner box content: 62% by weight), and 62.5% by weight (inner box content: 74.5% by weight) based on the total weight of the composition as shown in Table 3 below. A composition was prepared and each viscosity was measured in the same manner as Test Example 1.

Example 2 Comparative Example 6 Comparative Example 7 awards department Purified water to 100 to 100 to 100 Disodium EDTA 0.1 0.1 0.1 Hydroxyethyl acrylate/sodium acryloyldimethyl copolymer 0.2 0.2 0.2 polyvinylpyrrolidone 2.0 2.0 2.0 carbon black 5.0 5.0 5.0 alumina 2.0 2.0 2.0 Phenoxyethanol 0.4 0.4 0.4 wax part candelilla wax 5.0 10.0 12.5 carnauba wax 10.0 20.0 25.0 paraffin 10.0 20.0 25.0 Emulsifier part Steareth-21 3.0 6.0 6.0 Laureth-2 1.0 2.0 2.0 behenyl alcohol 1.0 2.0 2.0 PEG-10 Dimethicone 1.0 2.0 2.0 Viscosity (℃, cps) 14,400 315,000 Error

From the results in Table 3, in the case of Example 2 according to the present invention, the inner phase contained 25% by weight of wax, and the total inner phase was 31% by weight, which corresponds to a composition with a high internal phase as a formulation containing wax in the inner phase. However, it was confirmed that it was implemented with a significantly low viscosity of 14,400 cps. On the other hand, in the case of Comparative Examples 6 and 7, where the contents of the inner wax were 50% by weight and 62.5% by weight, respectively, it was confirmed that the viscosity did not increase significantly to 315,000 cps, or that the emulsification did not occur to the extent that the viscosity could not be measured.

That is, according to the present invention, a high internal image eye makeup composition containing 20 to 45% by weight of internal wax, and containing a first fatty acid ether-based emulsifier, a second fatty acid ether-based emulsifier, a PEG-silicone-based emulsifier, and fatty acid alcohol in a specific ratio. In the case of , it contains a high content of wax and is formulated with a low viscosity, so it can provide the eyelash setting function and volume effect of wax while providing an excellent feeling of use without clumping.

[Test Example 4] Evaluation of viscosity and emulsion stability according to the type of emulsifier

An eye makeup composition containing PEG-10 dimethicone as a PEG-silicone-based emulsifier in the emulsifier part as shown in Table 4 below, and an eye makeup composition containing potassium cetyl phosphate as an alkyl phosphate-based emulsifier rather than a PEG-silicone-based emulsifier. Compositions were prepared and their viscosity and emulsion stability were evaluated. Viscosity was measured in the same way as Test Example 1, and emulsion stability was determined by observing emulsion collapse of the sample while storing it for a week under frozen, refrigerated, room temperature, 30°C, 45°C, and 55°C conditions.

Example 2 Example 3 Comparative Example 8 Comparative Example 9 Comparative Example 10 Comparative Example 11 awards department Purified water to 100 to 100 to 100 to 100 to 100 to 100 Disodium EDTA 0.1 0.1 0.1 0.1 0.1 0.1 Hydroxyethyl acrylate/sodium acryloyldimethyl copolymer 0.2 0.2 0.2 0.2 0.2 0.2 polyvinylpyrrolidone 2.0 2.0 2.0 2.0 2.0 2.0 carbon black 5.0 5.0 5.0 5.0 5.0 5.0 alumina 2.0 2.0 2.0 2.0 2.0 2.0 Phenoxyethanol 0.4 0.4 0.4 0.4 0.4 0.4 wax part Polyglyceryl-3 Beeswax - 5.0 5.0 - - - beeswax - 10.0 10.0 - - - candelilla wax 5.0 - - 5.0 5.0 5.0 carnauba wax 10.0 10.0 10.0 10.0 10.0 10.0 paraffin 10.0 - - 10.0 10.0 10.0 Emulsifier part Steareth-21 3.0 3.0 3.0 3.0 3.0 3.0 Laureth-2 1.0 1.0 1.0 1.0 1.0 - behenyl alcohol 1.0 1.0 1.0 1.0 - 1.0 Potassium Cetyl Phosphate - - 1.0 - - - PEG-10 Dimethicone 1.0 1.0 - - 1.0 1.0 Viscosity (℃, cps) 14,400 36,000 40,000 oil painting broken 9,500 Oil painting is broken Emulsion stability ◎ ◎ △ X △ X

From the results in Table 4, in the case of Examples 2 and 3 according to the present invention, unlike Comparative Example 8, emulsification was achieved with low viscosity of 14,400 cps and 36,000 cps, respectively, by containing PEG-10 dimethicone in the emulsifier part. It was confirmed that stability was also excellent. On the other hand, in the case of Comparative Examples 9 and 8, which did not contain a PEG-silicone-based emulsifier or instead contained an alkyl phosphate-based emulsifier in the emulsifier part, it was confirmed that the emulsion stability was significantly lower than that of Examples 2 and 3, and also, in the emulsifier part, In the case of Comparative Example 11, which did not contain Laureth-2, it was confirmed that the emulsification was broken and the emulsion stability was significantly low, and in the case of Comparative Example 10, which did not contain behenyl alcohol in the emulsifier part, emulsification was achieved, but the viscosity was greatly reduced. It was confirmed that the emulsion stability was unstable.

[Test Example 5] Comparative evaluation of setting power according to the content of carnauba wax

Eye makeup compositions were prepared with the compositions shown in Table 5 below, and their viscosity and setting power were evaluated. Viscosity was measured in the same way as Test Example 1, and setting power was measured by applying the eye makeup composition in Table 1 below to eyelashes using the same method as the method for checking the degree of clumping in Test Example 1, targeting four professional panelists, and then measuring the drying speed and curling. Using formability as an evaluation item, it was evaluated based on poor setting power ( Judgment was focused.

Example 4 Comparative Example 12 awards department Purified water to 100 to 100 Disodium EDTA 0.1 0.1 Hydroxyethyl acrylate/sodium acryloyldimethyl copolymer 0.2 0.2 polyvinylpyrrolidone 2.0 2.0 carbon black 5.0 5.0 alumina 2.0 2.0 Phenoxyethanol 0.4 0.4 wax part Polyglyceryl-3 Beeswax 5.0 10.0 beeswax 10.0 15.0 carnauba wax 10.0 5.0 Emulsifier part Steareth-21 3.0 3.0 Laureth-2 1.0 1.0 behenyl alcohol 1.0 1.0 PEG-10 Dimethicone 1.0 1.0 Viscosity (℃, cps) 36,000 10,000 or less Setting power ◎ X

From the results in Table 5, in the case of Example 4, which contains 10% by weight of carnauba wax according to the present invention, it shows very excellent setting power while realizing a low viscosity of 36,000 cps, while carnauba wax is included at 5% by weight. In the case of Comparative Example 9, the viscosity was below 10,000 cps, which was difficult to measure with a viscometer, and appeared to be at the liquid level. As a result, it was confirmed that when applied to the eyelashes, it was almost swept away without adhering to the eyelashes and the setting power was greatly reduced. It has been done.

[Test Example 6] Evaluation of viscosity and emulsion stability according to the mixing ratio of emulsifier

Eye makeup compositions were prepared with the compositions shown in Table 6 below, and their viscosity and emulsion stability were evaluated. Viscosity was measured in the same way as in Test Example 1, and emulsion stability was measured in the same way as in Test Example 4.

Example 2 Example 5 Comparative Example 13 Comparative Example 14 Comparative Example 15 Comparative Example 16 awards department Purified water to 100 to 100 to 100 to 100 to 100 to 100 Disodium EDTA 0.1 0.1 0.1 0.1 0.1 0.1 Hydroxyethyl acrylate/sodium acryloyldimethyl copolymer 0.2 0.2 0.2 0.2 0.2 0.2 polyvinylpyrrolidone 2.0 2.0 2.0 2.0 2.0 2.0 carbon black 5.0 5.0 5.0 5.0 5.0 5.0 alumina 2.0 2.0 2.0 2.0 2.0 2.0 Phenoxyethanol 0.4 0.4 0.4 0.4 0.4 0.4 wax part candelilla wax 5.0 5.0 5.0 5.0 5.0 5.0 carnauba wax 10.0 10.0 10.0 10.0 10.0 10.0 paraffin 10.0 10.0 10.0 10.0 10.0 10.0 Emulsifier part Steareth-21 3.0 6.0 3.0 3.0 1.0 2.0 Laureth-2 1.0 1.0 1.0 1.0 1.0 1.0 behenyl alcohol 1.0 1.0 1.0 1.0 1.0 1.0 PEG-10 Dimethicone 1.0 1.0 - 0.5 1.0 1.0 Viscosity (℃, cps) 14,400 10,000 Oil painting is broken 12,300 Oil painting is broken 14,000 Emulsion stability ◎ ◎ X ○ X ○

From the results in Table 6, according to the present invention, the first ether-based emulsifier, the second ether-based emulsifier, the PEG-silicone-based emulsifier and the fatty acid alcohol are included in a mixing ratio of 3:1:1:1 and 6:1:1:1, respectively. In the case of Examples 2 and 5, it was confirmed that each was implemented at a low viscosity and the emulsion stability was also very excellent.

On the other hand, in the case of Comparative Example 10, which does not contain fatty acid alcohol, the emulsion stability was found to be so poor that viscosity measurement was impossible, and the emulsifier was used at a mixing ratio of 3:1:1:0.5, 1, which is outside the range according to the present invention, respectively. In the case of Comparative Examples 11 to 13 containing mixing ratios of :1:1:1, 2:1:1:1, the emulsion stability was shown to be so poor that viscosity measurement was impossible, as in Comparative Example 10, or It was confirmed that the emulsion stability was lower compared to Examples 2 and 5.

Claims (14)

A wax portion containing 10% by weight or more of carnauba wax based on the total weight of the composition; and
A first fatty acid ether emulsifier consisting of a fatty acid having 12 to 18 carbon atoms and an ether group having 20 to 30 carbon atoms, a second fatty acid ether emulsifier consisting of a fatty acid having 12 to 18 carbon atoms and an ether group having 2 to 19 carbon atoms, and a PEG-silicone emulsifier. Emulsifier part containing;
Contains an internal phase containing 20 to 60% by weight based on the total weight of the composition,
A high-viscosity, low-viscosity eye makeup composition containing the wax portion in an amount of 20 to 45% by weight based on the total weight of the composition. According to paragraph 1,
The wax portion further includes additional wax in addition to the carnauba wax, and the additional wax is a high melting point wax with a melting point of 70°C to 105°C,
The high-melting point wax includes PE wax (polyethylene wax), rice bran wax, sunflower seed wax, polyglyceryl-3 bees wax, and bees wax. , candelilla wax, jojoba seed wax, jasmine flower wax, ozokerite, paraffin, and synthetic wax. A high scratch resistance, low viscosity eye makeup composition, characterized in that it contains one or more types. delete delete According to paragraph 1,
A high internal damage, low viscosity eye makeup composition, characterized in that the first fatty acid ether-based emulsifier, the second fatty acid ether-based emulsifier and the PEG-silicone-based emulsifier are contained in a weight ratio of 2 to 12:1 to 2:0.5 to 1. According to paragraph 1,
A high-viscosity, low-viscosity eye makeup composition, wherein the first fatty acid ether-based emulsifier is Steareth-21. According to paragraph 1,
A high-viscosity, low-viscosity eye makeup composition, wherein the second fatty acid ether emulsifier is laureth-2 or steareth-2. According to paragraph 1,
The PEG-silicone emulsifiers include PEG-3 dimethicone, PEG-6 dimethicone, PEG-7 dimethicone, PEG-8 dimethicone, PEG-9 dimethicone, PEG-10 dimethicone, PEG-12 dimethicone, PEG- A high-viscosity, low-viscosity eye makeup composition comprising at least one selected from the group consisting of 14 dimethicone and PEG-17 dimethicone. According to paragraph 1,
A high-viscosity, low-viscosity eye makeup composition, wherein the emulsifier part further includes fatty acid alcohol as an emulsification aid. According to clause 9,
The fatty acid alcohol is cetyl alcohol, stearyl alcohol, cetearyl alcohol, oleyl alcohol, lauryl alcohol, and behenyl alcohol. ) and linoleyl alcohol. A high-viscosity eye makeup composition, characterized in that it is at least one selected from the group consisting of linoleyl alcohol. According to clause 9,
A high internal injury, low viscosity eye makeup composition, wherein the fatty acid alcohol is behenyl alcohol. According to clause 9,
The first ether-based emulsifier, the second ether-based emulsifier, the PEG-silicone-based emulsifier and the fatty acid alcohol are contained in a weight ratio of 2 to 12:1 to 2:0.5 to 1:0.5 to 1. Eye makeup composition. According to paragraph 1,
A high-viscosity, low-viscosity eye makeup composition, characterized in that the viscosity of the composition is 10,000 to 100,000 cps. According to paragraph 1,
A high internal scratch, low viscosity eye makeup composition, characterized in that the composition is for mascara.