KR102597212B1 - a functional shoe bottom and the shoes using thereof - Google Patents
a functional shoe bottom and the shoes using thereof Download PDFInfo
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- KR102597212B1 KR102597212B1 KR1020210112970A KR20210112970A KR102597212B1 KR 102597212 B1 KR102597212 B1 KR 102597212B1 KR 1020210112970 A KR1020210112970 A KR 1020210112970A KR 20210112970 A KR20210112970 A KR 20210112970A KR 102597212 B1 KR102597212 B1 KR 102597212B1
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- South Korea
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- buffer
- present
- sole
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- 239000011148 porous material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- FWMUJAIKEJWSSY-UHFFFAOYSA-N sulfur dichloride Chemical compound ClSCl FWMUJAIKEJWSSY-UHFFFAOYSA-N 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 210000003371 toe Anatomy 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
- A43B13/18—Resilient soles
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/0009—Footwear characterised by the material made at least partially of alveolar or honeycomb material
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/026—Composites, e.g. carbon fibre or aramid fibre; the sole, one or more sole layers or sole part being made of a composite
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/12—Soles with several layers of different materials
- A43B13/125—Soles with several layers of different materials characterised by the midsole or middle layer
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
- A43B13/18—Resilient soles
- A43B13/181—Resiliency achieved by the structure of the sole
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/28—Soles; Sole-and-heel integral units characterised by their attachment, also attachment of combined soles and heels
- A43B13/32—Soles; Sole-and-heel integral units characterised by their attachment, also attachment of combined soles and heels by adhesives
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B7/00—Footwear with health or hygienic arrangements
- A43B7/32—Footwear with health or hygienic arrangements with shock-absorbing means
Abstract
본 발명은 신발용 바닥부에 관한 것으로, 더욱 구체적으로는 고강도 내마모성 엘라스토머를 사용하고, 새로운 바닥부 구조를 적용하여 쿠션용 발포 입자들이 벌집 구조를 형성하는 기능성 신발용 바닥부 및 이를 이용한 신발에 관한 것이다.
본 발명은 바닥본체부(210), 완충부(220)가 포함되어 구성되어 되되,
상기한 완충부(220)는 완충입자부(221), 완충접합부(222)를 포함하여 구성되어 있고,
상기한 완충입자부(221)는 완충입자(221-1)가 다수로 결합하여 형성되되 벌집 구조를 이루고 있는 것을 특징으로 하는 기능성 신발용 바닥부(200)를 제공한다.
또한 본 발명은 상기한 완충입자부(221)의 완충입자(221-1)는 폴리우레탄 재질로 된 것이고,
완충접합부(222)는 고분자 엘라스토머로 된 것을 특징으로 하는 기능성 신발용 바닥부(200)를 제공한다.
또한 본 발명은 상기한 바닥부(200)를 포함하는 신발(300)을 제공한다.The present invention relates to soles for shoes, and more specifically, to soles for functional shoes in which foam particles for cushioning form a honeycomb structure by using a high-strength, wear-resistant elastomer and applying a new sole structure, and to shoes using the same. will be.
The present invention is comprised of a floor body portion 210 and a buffer portion 220,
The above-described buffer part 220 includes a buffer particle part 221 and a buffer joint part 222,
The above-described cushioning particle portion 221 is formed by combining a plurality of cushioning particles 221-1 and provides a functional shoe sole 200, which is characterized in that it forms a honeycomb structure.
In addition, in the present invention, the buffer particles 221-1 of the buffer particle unit 221 are made of polyurethane material,
The cushioning joint 222 provides a functional shoe sole 200, which is made of polymer elastomer.
The present invention also provides a shoe 300 including the sole 200 described above.
Description
본 발명은 신발용 바닥부에 관한 것으로, 더욱 구체적으로는 고강도 내마모성 엘라스토머를 사용하고, 새로운 바닥부 구조를 적용하여 쿠션용 발포 입자들이 벌집 구조를 형성하는 기능성 신발용 바닥부 및 이를 이용한 신발에 관한 것이다.The present invention relates to soles for shoes, and more specifically, to soles for functional shoes in which foam particles for cushioning form a honeycomb structure by using high-strength, wear-resistant elastomer and applying a new sole structure, and to shoes using the same. will be.
일반적으로 신발은 인체의 발부위를 보호하기 위하여 착용하는 것으로서 매우 다양한 형태와 종류로 제작되어 시판되고 있으나, 통상적으로는 발등과 발목 부위을 덮어서 보호하는 갑피(甲皮)와, 발바닥을 보호하면서 지면과의 마찰력을 높여 보행성을 향상시키도록 하는 동시에, 보행시 발바닥에 가해지는 충격을 완화시키도록 하는 신발밑창으로 구성되고 있다.In general, shoes are worn to protect the feet of the human body and are manufactured and sold in a wide variety of shapes and types. However, they usually consist of an upper that covers and protects the instep and ankle area, and an upper that protects the sole of the foot and protects the ground and the ground. It consists of a shoe sole that improves walking ability by increasing friction and at the same time relieves the shock applied to the sole of the foot when walking.
상기와 같은 통상적인 신발의 경우 보행시 지면으로부터 발바닥으로 전해지는 충격을 흡수할 수 있도록, 신발의 내측 바닥면에 깔창을 깔거나 신발밑창과 뒤축 부분을 완충력이 우수한 고무 및 발포 스폰지 재질로 제작하거나, 또는 에어백(Air bag)이나 스프링 등의 탄성복원체를 신발밑창에 내장시키도록 한 것이 알려져 있다.In the case of conventional shoes as described above, in order to absorb the shock transmitted from the ground to the sole of the foot when walking, an insole is placed on the inner sole of the shoe, or the sole and heel are made of rubber or foam sponge material with excellent cushioning power. It is known that elastic restorers such as air bags or springs are built into shoe soles.
상기와 같이 고무나 발포 스폰지 재질로 신발밑창을 제조하거나 또는 에어백이나 스프링 등의 탄성복원체를 신발밑창에 내장시킨 경우에는 단순한 충격 흡수의 기능만을 수행할 수 있을 뿐이며, 보행자의 발뒤꿈치로부터 발가락에 이르기까지 개략 원호 형상을 가지면서 지면과 접촉하게 되는 보행경로를 기준으로 할 경우, 종래의 일반적인 신발밑창은 자연적이고 능률적인 보행을 수행토록 하는 측면에 거의 기여하지 못하는 문제점이 있었다.As described above, when shoe soles are made of rubber or foam sponge, or when elastic restorers such as airbags or springs are built into shoe soles, they can only perform a simple shock absorption function, and can only perform the function of simple shock absorption, and can affect the pedestrian's heels and toes. When based on a walking path that has a roughly circular shape and is in contact with the ground, conventional shoe soles have a problem in that they hardly contribute to the aspect of performing natural and efficient walking.
또한 종래 기술의 모든 발포 신발 밑창에는 문제점이 있는데, 예를 들어 EVA, PU, 아디다스 팝콘, PU 발포 팝콘 등은 착용시 물을 흡수하고 냄새가 나며, 공공장소(병원 등) 출입시 더러운 물을 빨아 들여 세균 등을 집으로 가져오게 된다.In addition, all foam shoe soles in the prior art have problems. For example, EVA, PU, Adidas popcorn, PU foam popcorn, etc. absorb water and smell when worn, and suck dirty water when entering public places (hospitals, etc.). You bring germs and germs into your home.
또한 밑창의 경우 내부를 청소할 수 없으며, 연결된 통풍구 등의 전도 효과로 인해 겨울에는 땅에서 추위를, 여름에는 땅에서 열을 흡수하는 문제점이 있다.Additionally, the inside of the sole cannot be cleaned, and due to the conduction effect of connected vents, there is a problem of absorbing cold from the ground in winter and heat from the ground in summer.
관련된 종래기술로 등록특허 10-1644454호(충격흡수, 이물질 낌 방지 및 미끄럼방지 구조를 가지는 신발밑창)는,As a related prior art, registered patent No. 10-1644454 (shoe sole with shock absorption, foreign matter prevention, and anti-slip structure),
"밑판과, 상기 밑판에 다수 개의 조각구가 돌출 형성된 신발밑창에 있어서, 상기 조각구는, 내측에서 외측으로 절개된 복수 개의 분할홈에 의해 구획된 단위조각구가 형성되어 지면과 맞닿아 충격을 흡수하고, 상기 조각구 각각 사이에는 연결구로 연결되어 상기 단위조각구의 충격하중을 분산하는 것을 특징으로 하고, 조각구 사이의 간격을 조각구 높이보다 동일 또는 그 이상으로 하여 이물질 낌 현상을 방지하여 조각구 간격을 좁혀 밀착력, 충격흡수 및 미끄럼방지 기능을 향상시킨 신발밑창"을 제시한바 있다."In a shoe sole having a sole plate and a plurality of sculpture holes protruding from the sole plate, the sculpture holes are formed as unit sculpture spheres divided by a plurality of split grooves cut from the inside to the outside, and come into contact with the ground to absorb shock. And, each of the sculpture spheres is connected by a connector to distribute the impact load of the unit sculpture sphere, and the spacing between the sculpture spheres is made equal to or greater than the height of the sculpture spheres to prevent the phenomenon of foreign matter sticking to the sculpture sphere. A shoe sole that narrows the gap and improves adhesion, shock absorption, and anti-slip functions has been proposed.
상기한 종래기술 및 선행기술은 밑창의 쿠션부가 발포입자로 되어 있지만 이러한 발포입자 쿠션부에 통풍구가 형성되어 있어, 착용시 물을 흡수하고 냄새가 나며, 공공장소(병원 등) 출입시 더러운 물을 빨아 들여 세균 등을 집으로 가져오게 되는 문제점 및 연결된 통풍구에 따른 전도 효과로 인해 겨울에는 땅에서 추위를, 여름에는 땅에서 열을 흡수하는 문제점을 있는바,In the above-described prior art and prior art, the cushion part of the sole is made of foam particles, but vents are formed in the foam particle cushion part, so it absorbs water and generates odor when worn, and dirty water is discharged when entering and exiting public places (hospitals, etc.). There is the problem of sucking in germs and bringing them into the house, and the problem of absorbing cold from the ground in winter and heat from the ground in summer due to the conduction effect of connected vents.
본 발명은 상기한 문제점을 해결하는 기능성 신발용 바닥부 및 이를 이용한 신발을 제공하고자 한다.The present invention seeks to provide a functional shoe sole that solves the above problems and a shoe using the same.
또한 본 발명은 발포된 완충입자부가 닳아도 오염된 물과 세균은 표면에 입자층만 남게되어 깊은 내부로 빨려 들어 가지 않기 때문에 자연 건조 및 살균이 용이하게 되며, 또한, 완충접합부가 투명하여 직사광선으로 살균하는 기능도 수행할 수 있는 기능성 신발용 바닥부 및 이를 이용한 신발을 제공하고자 한다.In addition, the present invention facilitates natural drying and sterilization because even when the foamed buffer particle part wears out, only the particle layer remains on the surface and the contaminated water and bacteria are not sucked deep into the interior. In addition, the buffer joint is transparent, so it can be sterilized by direct sunlight. The goal is to provide functional shoe soles that can also perform the following functions and shoes using them.
본 발명은 상기한 문제점 및 요구를 해결하기 위하여,The present invention is intended to solve the above-mentioned problems and needs,
바닥본체부(210), 완충부(220)가 포함되어 구성되어 되되,It is composed of a floor body part 210 and a buffer part 220,
상기한 완충부(220)는 완충입자부(221), 완충접합부(222)를 포함하여 구성되어 있고,The above-described buffer part 220 includes a buffer particle part 221 and a buffer joint part 222,
상기한 완충입자부(221)는 완충입자(221-1)가 다수로 결합하여 형성되되 벌집 구조를 이루고 있는 것을 특징으로 하는 기능성 신발용 바닥부(200)를 제공한다.The above-described cushioning particle portion 221 is formed by combining a plurality of cushioning particles 221-1 and provides a functional shoe sole 200, which is characterized in that it forms a honeycomb structure.
또한 본 발명은 상기한 완충입자부(221)의 완충입자(221-1)는 폴리우레탄 재질로 된 것이고,In addition, in the present invention, the buffer particles 221-1 of the buffer particle unit 221 are made of polyurethane material,
완충접합부(222)는 고분자 엘라스토머로 된 것을 특징으로 하는 기능성 신발용 바닥부(200)를 제공한다.The cushioning joint 222 provides a functional shoe sole 200, which is made of polymer elastomer.
또한 본 발명은 상기한 바닥부(200)를 포함하는 신발(300)을 제공한다.The present invention also provides a shoe 300 including the sole 200 described above.
종래기술 및 선행기술이 밑창의 쿠션부가 발포입자로 되어 있고 이러한 발포입자 쿠션부에 통풍구가 형성되어 있어, 착용시 물을 흡수하고 냄새가 나며, 공공장소(병원 등) 출입시 더러운 물을 빨아 들여 세균 등을 집으로 가져오게 되는 문제점 및 연결된 통풍구에 따른 전도 효과로 인해 겨울에는 땅에서 추위를, 여름에는 땅에서 열을 흡수하는 문제점을 있는 반면,In the prior art and prior art, the cushion part of the sole is made of foam particles and a ventilation hole is formed in the foam particle cushion part, so it absorbs water and generates odor when worn, and absorbs dirty water when entering and exiting public places (hospitals, etc.). There is the problem of bringing germs into the house, and the problem of absorbing cold from the ground in winter and heat from the ground in summer due to the conduction effect of connected vents.
본 발명에 따른 기능성 신발용 바닥부 및 이를 이용한 신발은 완충입자부 및 완충접합부를 구비한 완충부의 구조와 특성으로 인하여 상기한 문제점을 완전히 해결하는 효과가 나타난다.The functional shoe sole according to the present invention and the shoes using the same have the effect of completely solving the above-mentioned problems due to the structure and characteristics of the cushioning portion including the cushioning particle portion and the cushioning joint portion.
또한 본 발명에 따른 기능성 신발용 바닥부 및 이를 이용한 신발은 발포된 완충입자부가 닳아도 오염된 물과 세균은 표면에 입자층만 남게되어 깊은 내부로 빨려 들어 가지 않기 때문에 자연 건조 및 살균이 용이하게 되며, 또한, 완충접합부가 투명하여 직사광선으로 살균하는 기능도 수행할 수 있는 효과가 나타난다.In addition, the functional shoe sole according to the present invention and the shoes using the same can be easily dried and sterilized naturally because even if the foamed cushioning particle portion is worn away, contaminated water and bacteria remain on the surface and are not sucked deep into the interior. , In addition, the buffer joint is transparent, which has the effect of performing the function of sterilization by direct sunlight.
도 1은 본 발명에 따른 기능성 신발용 바닥부를 이용한 신발 구조도.
도 2는 본 발명에 따른 기능성 신발용 바닥부의 구조도.
도 2b는 본 발명에 따른 기능성 신발용 바닥부의 일 실시도.
도 3은 본 발명에 따른 기능성 신발용 바닥부의 완충부의 일 실시도.1 is a structural diagram of a shoe using a sole for a functional shoe according to the present invention.
Figure 2 is a structural diagram of the sole for functional shoes according to the present invention.
Figure 2b is an embodiment of the sole for functional shoes according to the present invention.
Figure 3 is an embodiment of a buffer portion of the sole for functional shoes according to the present invention.
이하 본 발명을 도면을 참고하여 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the drawings.
본 발명은 기능성 신발용 바닥부(200)를 제공한다.The present invention provides a sole 200 for functional shoes.
본 발명은 상기한 기능성 신발용 바닥부(200)를 이용한 신발(300)을 제공한다.The present invention provides a shoe (300) using the functional shoe sole (200) described above.
도 1에서 보는 바와 같이, 본 발명의 신발(300)은 갑피(100), 바닥부(200)를 포함하여 구성되어 있다.As shown in FIG. 1, the shoe 300 of the present invention includes an upper 100 and a bottom 200.
본 발명의 갚피(100)는 신발의 외형을 형성하는 기능을 수행하는 것으로 가죽, 텍스타일, 고분자 물질 등의 재질로 형성할 수 있다.The leather 100 of the present invention performs the function of forming the exterior of the shoe and can be made of materials such as leather, textile, and polymer materials.
본 발명의 바닥부(200)는 신발의 바닥을 형성하는 기능을 수행하는 것으로 가죽, 텍스타일, 고분자 물질 등의 재질로 형성할 수 있다.The bottom portion 200 of the present invention functions to form the bottom of a shoe and can be made of a material such as leather, textile, or polymer material.
도 1에서 보는 바와 같이, 본 발명의 바닥부(200)는 갚피(100)와 결합되어 형성되어 있으며, 발의 편의성과 완충 기능을 수행한다.As shown in Figure 1, the bottom portion 200 of the present invention is formed by being combined with the top 100, and performs a cushioning function and convenience for the feet.
본 발명의 기술적 특징은 상기한 기능성 신발용 바닥부(200)가 발의 편의성뿐만 아니라 완충 기능과 충격분산 기능 및 미생물 살균 기능을 수행하게 되는 점이다.The technical feature of the present invention is that the functional shoe sole 200 not only provides foot comfort but also performs a cushioning function, a shock dispersion function, and a microbial sterilization function.
본 발명의 상기한 바닥부(200)는 바닥본체부(210), 완충부(220)가 포함되어 구성되어 있다.The floor portion 200 of the present invention includes a floor body portion 210 and a buffer portion 220.
본 발명의 바닥본체부(210)는 바닥부(200)의 기본 골격을 형성하는 구조로 되어 있으며 상기한 완충부(220)와 결합되어 바닥부를 형성하는 기능을 수행한다.The floor body portion 210 of the present invention has a structure that forms the basic skeleton of the floor portion 200 and is combined with the above-described buffer portion 220 to form the bottom portion.
도 2 내지 도 2b에서 보는 것처럼, 상기한 바닥본체부(210)는 통상의 고분자 물질 , 면(textile) 또는/및 합성섬유 등으로 이루어져 있고 발의 사이즈에 맞는 형태로 준비하게 된다.As shown in FIGS. 2 to 2B, the sole body portion 210 is made of common polymer materials, cotton, or/and synthetic fibers, and is prepared in a form suitable for the size of the foot.
바람직하게는 바닥본체부(210)의 재질은 고분자 물질로 된 것이 좋으며, 더욱 바람직하게는 가황 고무, 미세 다공성 고무, "바이오 라벨" 미세 다공성 고무, 이중-밀도 폴리우레탄 및 일반적으로 열가소성 재료와 같은 재료를 사용하는 것이 좋다.Preferably, the material of the bottom body 210 is made of a polymer material, more preferably a polymer material such as vulcanized rubber, microporous rubber, “biolabel” microporous rubber, double-density polyurethane and generally thermoplastic materials. It is better to use materials.
본 발명의 완충부(220)는 완충입자부(221), 완충접합부(222)를 포함하여 구성되어 있다.The buffer part 220 of the present invention includes a buffer particle part 221 and a buffer joint part 222.
도 3에서 보는 것처럼, 상기한 완충입자부(221)는 완충기능을 수행하는 완충 입자(221-1)가 다수로 결합되어 형성되어 있으며, 완충 입자들의 재질은 고분자 물질이며 입자들은 이러한 재질 또는 이러한 재질이 발포된 것으로 구성될 수 있다.As shown in Figure 3, the buffer particle unit 221 is formed by combining a plurality of buffer particles 221-1 that perform a buffering function. The material of the buffer particles is a polymer material, and the particles are made of this material or these materials. The material may be composed of foam.
상기한 완충입자(221-1)를 제조하기 위한 고분자 물질은 탄성이 있는 것이 바람직하며, 고무, 실리콘 또는 폴리우레탄으로 된 것이 좋다.The polymer material for producing the above-described buffer particle 221-1 is preferably elastic, and is preferably made of rubber, silicone, or polyurethane.
본 발명의 상기한 완충입자(221-1)는 바람직하게는 폴리우레탄 재질로 발포된 것을 사용하는 것이 효과적이다.It is effective to use the above-described buffer particles (221-1) of the present invention, preferably foamed with polyurethane material.
본 발명의 상기한 폴리우레탄 재질은 통상의 폴리우레탄을 사용할 수 있다.The above-described polyurethane material of the present invention can be used as a conventional polyurethane.
본 발명에서 상기한 폴리우레탄 재질은 폴리올, 폴리이소시아네이트, 촉매, 발포제를 포함하여 구성되어 있는 폴리우레탄을 사용하는 것이 탄성면에서 효과적이다.In the present invention, it is effective in terms of elasticity to use polyurethane containing polyol, polyisocyanate, catalyst, and foaming agent as the polyurethane material.
바람직하게는 폴리올 100중량부에 폴리이소시아네이트 20~150중량부, 촉매 2~20중량부, 발포제 1~5중량부를 포함하여 구성되어 있는 것이 좋다.Preferably, 100 parts by weight of polyol includes 20 to 150 parts by weight of polyisocyanate, 2 to 20 parts by weight of catalyst, and 1 to 5 parts by weight of blowing agent.
상기한 폴리올은 폴리이소시아네이트 성분과 반응하는 성분이며, 수산기가가 15∼60mgKOH/g, 관능기수가 2∼4인 폴리에테르계 폴리올 및 분자량이 60∼200, 관능기수가 2∼4인 쇄연장제를 포함한다.The above-described polyol is a component that reacts with the polyisocyanate component, and includes a polyether-based polyol with a hydroxyl value of 15 to 60 mgKOH/g and a functional group count of 2 to 4, and a chain extender with a molecular weight of 60 to 200 and a functional group count of 2 to 4. do.
상기한 폴리에테르계 폴리올은 수산기가가 15∼60mgKOH/g 및 관능기수가 2∼4인 것이면 특별히 한정은 없고, 폴리우레탄을 제조할 때에 일반적으로 이용되고 있는 것을 사용할 수 있다.The above-described polyether-based polyol is not particularly limited as long as it has a hydroxyl value of 15 to 60 mgKOH/g and a functional group number of 2 to 4, and those generally used in producing polyurethane can be used.
이러한 수산기가와 관능기수를 가지는 폴리에테르계 폴리올의 대표예로서는 폴리옥시알킬렌계 폴리올, 테트라히드로푸란의 개환중합에 의해 제조할 수 있는 폴리테트라메틸렌에테르글리콜 등을 들 수 있다.Representative examples of polyether-based polyols having such hydroxyl value and number of functional groups include polyoxyalkylene-based polyols and polytetramethylene ether glycol, which can be produced by ring-opening polymerization of tetrahydrofuran.
폴리옥시알킬렌계 폴리올은, 수산기, 1급 아미노기, 2급 아미노기, 또는 그 밖의 활성수소함유기인 관능기를 2개 이상 가지는 화합물 등을 출발원료로, 알킬렌옥시드를 개환 부가반응시켜서 제조할 수 있다. 또한 상기의 2개 이상의 관능기는 각각 같아도, 다른 것이라도 좋다.Polyoxyalkylene-based polyol can be produced by subjecting alkylene oxide to a ring-opening addition reaction using a compound having two or more functional groups that are hydroxyl groups, primary amino groups, secondary amino groups, or other active hydrogen-containing groups as starting materials. Additionally, the above two or more functional groups may be the same or different.
상기한 쇄연장제의 예로서는 에틸렌글리콜, 디에틸렌글리콜, 트리에틸렌글리콜, 1,4-부탄디올, 1,6-헥산디올, 네오펜틸글리콜, 트리메틸올프로판, 펜타에리스리톨 등의 다가알코올, 에탄올아민, 디에탄올아민, 트리에탄올아민, 메틸디에탄올아민 등의 알카놀아민, 에틸렌디아민, 1,6-헥산디아민, 디에틸렌트리아민, 트리에틸렌펜타아민 등의 다가아민 등을 들 수 있고, 이들은 각각 단독으로 또는 2종 이상을 혼합하여 이용할 수 있다. 이들 중에서는, 경도 특성을 높이는 관점에서 에틸렌글리콜, 반응성을 높이는 관점에서 에탄올아민, 디에탄올아민, 트리에탄올아민이 바람직하다.Examples of the above chain extenders include polyhydric alcohols such as ethylene glycol, diethylene glycol, triethylene glycol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, trimethylolpropane, and pentaerythritol, ethanolamine, and Alkanolamines such as ethanolamine, triethanolamine, and methyldiethanolamine; polyamines such as ethylenediamine, 1,6-hexanediamine, diethylenetriamine, and triethylenepentamine; and these may be used alone or Two or more types can be mixed and used. Among these, ethylene glycol is preferable from the viewpoint of improving hardness characteristics, and ethanolamine, diethanolamine, and triethanolamine are preferable from the viewpoint of enhancing reactivity.
본 발명의 상기한 폴리이소시아네이트는 지방족 및/또는 지환족 폴리이소시아네이트 및 상기 폴리이소시아네이트의 이소시아누레이트 변성체를 함유한 것을 사용할 수 있다.The above-described polyisocyanate of the present invention can be used containing aliphatic and/or cycloaliphatic polyisocyanate and isocyanurate modified form of the polyisocyanate.
상기한 지방족 및/또는 지환족 폴리이소시아네이트로서, 헥사메틸렌디이소시아네이트, 이소포론디이소시아네이트, 노르보르난디이소시아네이트, 수첨(水添)디페닐메탄디이소시아네이트, 수첨m-크실렌디이소시아네이트 등에서 얻어지는 폴리이소시아네이트를 들 수 있고, 이들은 각각 단독으로 또는 2종 이상을 혼합하여 이용할 수 있다.Examples of the above-mentioned aliphatic and/or alicyclic polyisocyanates include polyisocyanates obtained from hexamethylene diisocyanate, isophorone diisocyanate, norbornane diisocyanate, hydrogenated diphenylmethane diisocyanate, and hydrogenated m-xylene diisocyanate. These can be used individually or in combination of two or more types.
본 발명의 상기한 촉매는 유기산 비스무트를 사용한다. 유기산 비스무트로서는 트리스(2-에틸헥산산)비스무트 등의 트리스(카르본산)비스무트, 수지산 비스무트 등을 들 수 있고, 촉매활성의 관점에서, 트리스(카르본산)비스무트가 바람직하다.The above-described catalyst of the present invention uses the organic acid bismuth. Examples of the organic acid bismuth include tris(carboxylic acid)bismuth such as tris(2-ethylhexanoic acid)bismuth, and bismuth resin acid. From the viewpoint of catalytic activity, tris(carboxylic acid)bismuth is preferable.
상기한 촉매에 디라우린산디부틸주석, 디네오데칸산디부틸주석, 디초산디부틸주석 등의 디카르본산디알킬주석, 그들의 2량체 및 그들의 변성물, 및 1,8-디아자비시클로[540]운데센-7,1,5-디아자비시클로[430]노넨-5 등의 디아조비시클로알켄 및 그들의 유기산염 등을 들 수 있고, 그들의 1종 이상을 촉매에 함유해도 좋다.The above-described catalysts include dialkyl tin dicarboxylic acids such as dibutyltin dilaurate, dibutyltin dineodecanoate, and dibutyltin diacetate, their dimers and their modified products, and 1,8-diazabicyclo[540]unde. Diazobicycloalkenes such as cen-7,1,5-diazabicyclo[430]nonene-5 and their organic acid salts may be included, and one or more types thereof may be contained in the catalyst.
이 경우 상기한 촉매는 유기산 비스무트가 70~90중량% 포함되는 것이 바람직하다.In this case, the above catalyst preferably contains 70 to 90% by weight of the organic acid bismuth.
본 발명의 발포체는 가압 유체를 사용할 수 있다. The foam of the present invention can be used with pressurized fluids.
상기한 가압 유체라 함은 가압 상태하에 놓인 유체를 의미하는 것이며, 그 중에서도 초임계 상태의 유체 혹은 아임계(亞臨界) 상태의 유체인 것이 바람직하고, 초임계 상태의 유체, 즉 초임계 가스인 것이 보다 바람직하다. 또한, 초임계 상태하 및 아임계 상태하라 함은 가압하의 하위개념이며, "초임계 상태"라 함은 일반적으로 압력이 임계압력 이상이면서, 동시에 온도가 임계온도 이상인 상태를 의미하고, "아임계 상태"라 함은 통상 온도가 3중점 이상 임계점 이하이면서 또한 압력이 포화증기압 이상의 압력으로써 온도-압력영역이 초임계 상태에 준하는 상태를 의미한다. 본 발명에 있어서 "아임계 상태"라 함은 더욱 상세하게는 발포제가 이산화탄소인 경우, 온도 및 압력이, 25℃이상 311℃미만, 738MPa초과의 범위, 및 25 ℃이상 45℃이하, 4MPa이상 738MPa미만의 범위에 있는 상태를 포함한다.The above-mentioned pressurized fluid refers to a fluid placed under a pressurized state. Among these, it is preferable to be a fluid in a supercritical state or a fluid in a subcritical state, and a fluid in a supercritical state, that is, a supercritical gas. It is more preferable. In addition, under supercritical state and subcritical state are sub-concepts of under pressure, and “supercritical state” generally means a state in which the pressure is above the critical pressure and the temperature is above the critical temperature, and “subcritical condition” “State” usually refers to a state in which the temperature is above the triple point and below the critical point and the pressure is above the saturated vapor pressure, so that the temperature-pressure region is equivalent to a supercritical state. In the present invention, the "subcritical state" is more specifically, when the foaming agent is carbon dioxide, the temperature and pressure are in the range of 25 ℃ to 311 ℃, exceeding 738 MPa, and 25 ℃ to 45 ℃, 4 MPa to 738 MPa. Includes conditions in the range below.
초임계 가스의 유체종으로서는 특별히 한정은 없고, 이산화탄소, 질소 등의 불활성 가스를 들 수 있고, 폴리우레탄 원료에의 높은 용해성의 면에서 이산화탄소가 바람직하다. 본 발명에 있어서의 초임계 가스라 함은, 온도나 압력을 조정하여, 초임계 상태가 된 태양(態樣)의 가스, 가스를 다른 성분 등에 혼합한 후에, 온도나 압력을 조정하여 초임계 상태가 된 태양의 가스, 및 양자의 태양을 포함하는 가스를 말한다.There is no particular limitation on the type of fluid of the supercritical gas, and examples include inert gases such as carbon dioxide and nitrogen, and carbon dioxide is preferable in view of its high solubility in polyurethane raw materials. Supercritical gas in the present invention refers to a gas that has reached a supercritical state by adjusting the temperature or pressure, or a gas that is in a supercritical state after mixing the gas with other components, etc. by adjusting the temperature or pressure. refers to the gas of the sun that has become , and the gas that contains the sun of protons.
본 발명은 상기한 폴리우레탄에 기능성 첨가물을 첨가하여 탄성력을 높이고 강도를 강화하는 기능을 수행한다.The present invention performs the function of increasing elasticity and strengthening strength by adding functional additives to the above-described polyurethane.
상기한 기능성 첨가물은 폴리우레탄 100중량부에 0.5~5 중량부를 포함하는 것이 바람직하다.The functional additives described above are preferably contained in an amount of 0.5 to 5 parts by weight per 100 parts by weight of polyurethane.
상기한 기능성 첨가물은 중탄산나트륨, 인산암모늄, 메틸렌비스 아크릴아마이드, 글리시딜 메타크릴레이트, 메타그릴산을 포함하여 조성한 조성물이다.The above-mentioned functional additive is a composition containing sodium bicarbonate, ammonium phosphate, methylenebis acrylamide, glycidyl methacrylate, and methacrylic acid.
바람직하게는, 기능성 첨가물은 중탄산나트륨 100 중량부에 인산암모늄 10~60 중량부, 메틸렌비스 아크릴아마이드 10~30 중량부, 글리시딜 메타크릴레이트 20~80 중량부, 메타그릴산 5~40 중량부를 포함하여 조성하는 것이 효과적이다.Preferably, the functional additive is 10 to 60 parts by weight of ammonium phosphate, 10 to 30 parts by weight of methylenebis acrylamide, 20 to 80 parts by weight of glycidyl methacrylate, and 5 to 40 parts by weight of methacrylic acid per 100 parts by weight of sodium bicarbonate. It is effective to create a fund that includes wealth.
본 발명은 상기한 기능성 첨가물의 첨가로 폴리우레탄의 탄성력을 1.3~1.9배로 증진시키는 기능을 수행한다.The present invention functions to increase the elasticity of polyurethane by 1.3 to 1.9 times by adding the above-described functional additives.
본 발명은 상기한 폴리우레탄에 천연 첨가물을 첨가하여 신발 바닥에 작용하는 지속적인 충격과 무게에 따른 피로도에 대한 내구성을 현저히 높이고 고분자 물질이 산화되어 약화되는 문제를 방지하는 높은 효과를 나타내게 된다.The present invention adds natural additives to the polyurethane, which significantly increases durability against fatigue due to continuous impact and weight acting on the sole of the shoe, and has a high effect of preventing the problem of polymer materials being oxidized and weakened.
상기한 천연 첨가물은 폴리우레탄 100중량부를 기준으로 0.001~0.005중량부를 혼합하는 것이 바람직하다.It is preferable to mix 0.001 to 0.005 parts by weight of the above-mentioned natural additives based on 100 parts by weight of polyurethane.
상기한 천연 첨가물은 맥문동 100중량부에 위령선 80~120 중량부, 패란 80~120 중량부, 곽향 10~30중량부, 절국대 10~30중량부, 선퇴 80~120 중량부, 반하 10~30중량부, 속단 50~80중량부를 혼합하여 추출한 조성물을 의미한다.The above-mentioned natural additives are 80-120 parts by weight of Wiryeongseon, 80-120 parts by weight of Paeran, 10-30 parts by weight of Gwakhyang, 10-30 parts by weight of Jeolgukdae, 80-120 parts by weight of Seontoe, and 10-30 parts of Banha for 100 parts by weight of Macmundong. It refers to a composition extracted by mixing 50 to 80 parts by weight of quick-cut.
상기한 천연 첨가물을 추출하는 방법으로는 상기의 혼합한 원재료 100 중량부에 75~85%[질량%] 에탄올 1000중량부를 넣고, 2~4시간 동안 환류 추출하고 여액을 rotary evaporator를 이용하여 감압, 농축하는 방법으로 추출할 수 있다.The method of extracting the above-mentioned natural additives includes adding 1000 parts by weight of 75-85% [mass %] ethanol to 100 parts by weight of the above mixed raw materials, extracting under reflux for 2-4 hours, and depressurizing the filtrate using a rotary evaporator. It can be extracted by concentrating.
이와 같은 추출물은 혼합한 원재료 100중량부를 기준으로 분말 형태로 5~25중량부 정도 추출될 수 있으며 이러한 분말 형태의 추출물을 첨가하는 것이 바람직하다.This extract can be extracted in powder form in an amount of 5 to 25 parts by weight based on 100 parts by weight of the mixed raw materials, and it is preferable to add the extract in powder form.
본 발명의 상기한 완충입자부(221)는 완충입자(221-1)가 다수로 결합되어 형성되되 벌집 구조를 이루고 있는 것을 기술적 특징으로 한다.The above-described buffer particle unit 221 of the present invention has a technical feature in that it is formed by combining a plurality of buffer particles 221-1 and forms a honeycomb structure.
이와 같은 벌집 구조의 완충입자부(221)의 구조적 기능으로 완충 기능을 현저히 증진시키며 완충입자부(221)의 재료의 양을 줄일 수 있는 기술적 특징이 있다.The structural function of the honeycomb particle portion 221 has a technical feature that significantly improves the buffering function and reduces the amount of material of the buffer particle portion 221.
본 발명의 상기한 완충접합부(222)는 완충입자(221-1)를 서로 접합시키는 기능을 수행하는 구조 또는 수단을 의미한다.The above-mentioned buffer joint 222 of the present invention refers to a structure or means that performs the function of bonding the buffer particles 221-1 to each other.
상기한 완충접합부(222)는 접합력이 있는 고분자 물질로 되어 있으며 바람직하게는 투명한 재질로 된 것이 좋다.The above-described buffer joint 222 is made of a polymer material with bonding force, and is preferably made of a transparent material.
이와 같은 투명한 재질로 된 완충접합부에 의하여 완충부(220)는 투명하게 되어 바닥부로 직사광선을 비출수가 있게 되어 항균 기능을 수행한다.Due to the buffer joint made of such a transparent material, the buffer portion 220 becomes transparent and allows direct sunlight to shine on the bottom, thereby performing an antibacterial function.
상기한 완충접합부(222)의 재질은 상기한 고무, 실리콘 또는 고분자 엘라스토머일 수 있다.The material of the above-described buffer joint 222 may be the above-mentioned rubber, silicone, or polymer elastomer.
더욱 바람직하게는 고분자 엘라스토머인 것이 접착력 및 완충 기능면에서 유리하다.More preferably, it is a polymer elastomer, which is advantageous in terms of adhesion and cushioning function.
상기한 고분자 엘라스토머는 고강도 내모마모성 엘라스토머인 것이 효과적이다.It is effective that the above-mentioned polymer elastomer is a high-strength abrasion-resistant elastomer.
본 발명의 고분자 엘라스토머는 고무, 가교제, 충전제, 폴리이소시아네이트, 첨가제를 혼합하여 조성한 엘라스토머 조성물을 의미한다.The polymer elastomer of the present invention refers to an elastomer composition made by mixing rubber, crosslinking agent, filler, polyisocyanate, and additives.
바람직하게는 고무 100중량부에 가교제 1~20중량부, 충전제 1~30중량부, 폴리이소시아네이트 5~50중량부, 첨가제 1~10중량부를 혼합하여 조성한 것이 효과적이다.Preferably, it is effective to mix 1 to 20 parts by weight of crosslinking agent, 1 to 30 parts by weight of filler, 5 to 50 parts by weight of polyisocyanate, and 1 to 10 parts by weight of additive with 100 parts by weight of rubber.
본 발명의 엘라스토머는 20℃에서 그의 길이의 15배 이상으로 반복적으로 신장될 수 있고 일단 신장에 요구되는 힘이 제거되는 경우 곧바로 대략적으로 그의 초기 치수를 되찾는 엘라스토머적 거동을 지니는 폴리머이다.The elastomer of the present invention is a polymer with elastomeric behavior that can be repeatedly stretched to more than 15 times its length at 20°C and immediately regains approximately its initial dimensions once the force required for stretching is removed.
상기한 고무는 부타디엔 고무(BR), 스티렌-부타디엔 고무(SBR), 이소프렌 고무(IR), 스티렌-이소프렌-부타디엔 고무(SIBR), 아크릴로니트릴-부타디엔 고무(NBR), 클로로프렌 고무(CR), 이소부텐-이소프렌 고무(IIR), 천연 고무(NR)를 사용할 수 있다.The above rubbers include butadiene rubber (BR), styrene-butadiene rubber (SBR), isoprene rubber (IR), styrene-isoprene-butadiene rubber (SIBR), acrylonitrile-butadiene rubber (NBR), chloroprene rubber (CR), Isobutene-isoprene rubber (IIR) and natural rubber (NR) can be used.
상기한 가교제는 고무의 가교 결합을 유도할 수 있는 임의 화합물을 의미하며, 1 이상의 가황 화학 물질을 포함한다.The cross-linking agent refers to any compound capable of inducing cross-linking of rubber and includes one or more vulcanizing chemicals.
상기한 가황 화학 물질은 이염화황, 이염화이황, 디모폴릴 디설파이드, 2-모폴리노디티오벤조티아졸, 카프로락탐 디설파이드, 디펜타메틸렌티우람 테트라설파이드, 이소프로필크산틱 테트라설파이드 또는 원소 황(elemental sulfur), 또는 무황 가교제, 예컨대 과산화물, 퀴논 디옥시민(dioximine), 폴리메틸올페놀 수지를 포함한다.The above mentioned vulcanizing chemicals include sulfur dichloride, disulfur dichloride, dimorpholyl disulfide, 2-morpholinodithiobenzothiazole, caprolactam disulfide, dipentamethylenethiuram tetrasulfide, isopropylxanthic tetrasulfide or elemental sulfur. sulfur), or sulfur-free crosslinking agents such as peroxide, quinone dioximine, and polymethylolphenol resin.
상기한 충전제는 광물질 입자 또는 폴리머 입자와 같은 임의 고체 화합물을 포함한다.The above-mentioned fillers include any solid compounds such as mineral particles or polymer particles.
상기한 광물질 입자는 카본 블랙, 실리카, 규산염, 카올린과 같은 규산알루미늄, 탄산염, 탄산칼슘, 황산바륨, 결정질 이산화규소, 미분 석영(ground quartz), 금속 산화물, 아연 산화물, 금속 수산화물, 수산화알루미늄 등을 의미한다.The above mineral particles include carbon black, silica, silicate, aluminum silicate such as kaolin, carbonate, calcium carbonate, barium sulfate, crystalline silicon dioxide, ground quartz, metal oxide, zinc oxide, metal hydroxide, aluminum hydroxide, etc. it means.
상기한 폴리머 입자는 폴리스티렌 또는 폴리스티렌-아크릴로니트릴(SAN), 또는 에틸렌-비닐 아세테이트(EVA), 폴리에틸렌, 폴리프로필렌, 폴리카보네이트, 열가소성 플라스틱 폴리우레탄(TPU), 폴리비닐 클로라이드(PVC), 스티렌-부타디엔-스티렌 블록 코폴리머를 의미한다.Said polymer particles may be polystyrene or polystyrene-acrylonitrile (SAN), or ethylene-vinyl acetate (EVA), polyethylene, polypropylene, polycarbonate, thermoplastic polyurethane (TPU), polyvinyl chloride (PVC), styrene- It refers to butadiene-styrene block copolymer.
상기한 폴리이소시아네이트는 이소시아네이트 폴리머로서 1 이상의 이소시아네이트 기를 포함할 수 있으며 바람직하게는 분자당 1 내지 5, 보다 바람직하게는 2 내지 3, 구체적으로 2 개의 이소시아네이트 기를 가지는 것이 좋다.The above-mentioned polyisocyanate is an isocyanate polymer and may contain one or more isocyanate groups, preferably 1 to 5, more preferably 2 to 3, and specifically 2 isocyanate groups per molecule.
본 발명의 폴리이소시아네이트는 공지된 지방족, 지환족, 및 방향족 일작용성, 이작용성 또는 다작용성 이소시아네이트 중 임의이거나, 또는 이와 달리 이들의 임의 원하는 혼합물이다. The polyisocyanates of the present invention are any of the known aliphatic, cycloaliphatic, and aromatic mono-, di- or polyfunctional isocyanates, or alternatively any desired mixture thereof.
예로는 디페닐메탄 4,4'-, 2,4'-, 및 2,2'-디이소시아네이트, 모노머 디페닐메탄 디이소시아네이트로 그리고 더 많은 수의 고리를 갖는 디페닐메탄 디이소시아네이트 동족체(폴리머 MDI)로 이루어진 혼합물, 테트라메틸렌 디이소시아네이트, 헥사메틸렌 디이소시아네이트(HDI), 이소포론 디이소시아네이트(IPDI), 나프탈렌 1,5-디이소시아네이트(NDI), 톨루엔 2,4,6-트리이소시아네이트, 및 톨루엔 2,4- 및 2,6-디이소시아네이트(TDI), 또는 이들의 혼합물을 사용할 수 있다.Examples include diphenylmethane 4,4'-, 2,4'-, and 2,2'-diisocyanates, the monomeric diphenylmethane diisocyanate and the higher number of ring-containing diphenylmethane diisocyanate congeners (polymeric MDI). ), tetramethylene diisocyanate, hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), naphthalene 1,5-diisocyanate (NDI), toluene 2,4,6-triisocyanate, and toluene 2 , 4- and 2,6-diisocyanate (TDI), or mixtures thereof can be used.
상기한 첨가제는 통상의 엘라스토머를 제조하는데 사용하는 것으로 안정제, 활제(lubricant), 충격보강제, 커플링에이전트의 하나 아상을 포함하는 것을 의미한다.The above-mentioned additives are used to manufacture general elastomers and include one or more of a stabilizer, lubricant, impact modifier, and coupling agent.
안정제는 고분자물질의 상용화된 것(플라스틱) 등에 열화(劣化)를 방지하거나 또는 억제하기 위해서 첨가하는 화학약품이다. 플라스틱 등은 열·빛·산소의 영향을 받아 열화해 가므로 이를 방지해야 한다. 대표적인 것에 열안정제·산화방지제·광안정제 등이 있다. 따라서 안정제는 본 발명의 고분자 물질에 맞게 사용되는 통상의 안정제를 의미한다. 예를 들면, UV안정제, 열안정제, 에폭시 화합물, 스테아린산아연·스테아린산칼슘 등의 유기산금속류 등이 있다.Stabilizers are chemicals added to prevent or suppress deterioration of commercially available polymer materials (plastics). Plastics, etc. deteriorate under the influence of heat, light, and oxygen, so this must be prevented. Representative examples include heat stabilizers, antioxidants, and light stabilizers. Therefore, the stabilizer refers to a conventional stabilizer used for the polymer material of the present invention. For example, there are UV stabilizers, heat stabilizers, epoxy compounds, and organic acid metals such as zinc stearate and calcium stearate.
활제(lubricant)는 본 발명의 고분자 물질에 맞게 사용되는 통상의 활제를 의미하며, 폴리에틸렌계 또는 폴리프로필렌계 등에 통상 사용되는 것으로, 스테아린산 등 지방산류; 스테아린산 아미드, 올레인산 아미드 등 지방산 아미드류; 파라핀 왁스, 폴리에틸렌 왁스 등 왁스류 등을 들 수 있으며, 이들이 단독 또는 적정 비율로 혼합되어 사용하는 것이 효과적이다.Lubricant refers to a common lubricant used for the polymer material of the present invention, and is commonly used for polyethylene or polypropylene, such as fatty acids such as stearic acid; Fatty acid amides such as stearic acid amide and oleic acid amide; Examples include waxes such as paraffin wax and polyethylene wax, and it is effective to use them alone or mixed in an appropriate ratio.
충격보강제는 분열, 인장, 압축, 휨, 충격강도를 증가시키기 위해 플라스틱에 첨가하는 섬유상 불용성 물질을 의미한다. 본 발명에 사용되는 충격보강제는 Acrylic, CPE(Chlorinated Polyethylene), EVA(Ethylene Vinyl Acetate), 메틸메타크릴레이트-부타디엔-스틸렌(MBS)수지, 아크릴로니트릴-부타디엔-스틸렌(ABS)수지 등을 들 수 있다.Impact modifier refers to a fibrous insoluble substance added to plastic to increase splitting, tensile, compression, bending, and impact strength. Impact modifiers used in the present invention include Acrylic, CPE (Chlorinated Polyethylene), EVA (Ethylene Vinyl Acetate), methyl methacrylate-butadiene-styrene (MBS) resin, and acrylonitrile-butadiene-styrene (ABS) resin. You can.
본 발명은 엘라스토머 조성물에 기능성 첨가제를 포함하여 완충접합부(222)가 완충입자(221-1)가 잘 접합할 수 있게 하는 기능을 수행하고 내마모성과 탄성력을 현저히 증진시키는 기능을 수행한다.The present invention includes a functional additive in the elastomer composition to enable the buffer joint 222 to adhere well to the buffer particles 221-1 and to significantly improve wear resistance and elasticity.
상기한 기능성 첨가제는 고무 100중량부에 0.1~3중량부를 혼합하여 조성하는 것이 바람직하다.It is preferable to mix 0.1 to 3 parts by weight of the above functional additives with 100 parts by weight of rubber.
상기한 기능성 첨가제는 알킬페닐폴리글리콜에테르 100 중량부에 폴리옥시알킬렌화 알킬 에테르 10~20중량부, 폴리옥시알킬렌화 소르비탄 에스테르 10~20중량부, 폴리옥시알킬렌화 에스테르 10~20중량부, 폴리옥시알킬렌화 알킬페닐 에테르 1~5중량부, 에톡실화 아미드 1~5중량부를 혼합하여 조성한 것을 의미한다.The above functional additives include 10 to 20 parts by weight of polyoxyalkylenated alkyl ether, 10 to 20 parts by weight of polyoxyalkylenated sorbitan ester, 10 to 20 parts by weight of polyoxyalkylenated ester, per 100 parts by weight of alkylphenyl polyglycol ether, It means a composition prepared by mixing 1 to 5 parts by weight of polyoxyalkylenated alkylphenyl ether and 1 to 5 parts by weight of ethoxylated amide.
또한 본 발명은 상기한 엘라스토머 조성물에 천연 보강 첨가제를 포함하여 엘라스토머 조성물이 고분자 물질로서의 환경호르몬의 발생 억제를 강화하고, 엘라스토머 조성물의 변성을 방지하고 내산성 및 내염기성을 강화하는 기능을 수행한다.In addition, the present invention includes a natural reinforcing additive in the elastomer composition, so that the elastomer composition enhances the inhibition of environmental hormones as a polymer material, prevents denaturation of the elastomer composition, and enhances acid and base resistance.
상기한 천연 보강 첨가제는 고무 100중량부에 0.01~1중량부를 혼합하여 조성하는 것이 바람직하다.It is preferable to mix 0.01 to 1 part by weight of the above-mentioned natural reinforcing additive with 100 parts by weight of rubber.
상기한 천연 보강 첨가제는 우슬 100중량부에 산약 80~120 중량부, 속단 80~120중량부, 여정실 80~120중량부, 백창포 80~120 중량부, 마치현 80~120중량부, 백선피 80~120중량부를 혼합하여 추출한 조성물을 의미한다.The above-mentioned natural reinforcing additives include 80 to 120 parts by weight of acid, 80 to 120 parts by weight of quicksand, 80 to 120 parts by weight of red iris, 80 to 120 parts by weight of white iris, 80 to 120 parts by weight of portulaca quince, and 80 to 120 parts by weight of white iris per 100 parts by weight of sycamore. It refers to a composition extracted by mixing 120 parts by weight.
또한 본 발명은 상기한 엘라스토머 조성물에 천연 강화 첨가제를 포함하여 엘라스토머 조성물의 적외선에 의한 산화를 현저히 방지하고 내구성을 강화하는 기능을 수행한다.In addition, the present invention includes a natural reinforcing additive in the elastomer composition, which significantly prevents oxidation by infrared rays and enhances durability of the elastomer composition.
상기한 천연 강화 첨가제는 고무 100중량부에 0.001~0.5중량부를 혼합하여 조성하는 것이 바람직하다.The above-mentioned natural reinforcing additive is preferably formulated by mixing 0.001 to 0.5 parts by weight with 100 parts by weight of rubber.
상기한 천연 강화 첨가제는 백출 100중량부에 토사자 10~40중량부, 생지황 110~150중량부, 지부자 50~80중량부, 패모 10~30중량부, 선퇴 80~120 중량부, 반하 10~30중량부, 천궁 50~80중량부를 혼합하여 추출한 조성물을 의미한다.The above-mentioned natural strengthening additives include 10 to 40 parts by weight of tosaja, 110 to 150 parts by weight of raw rehmannia root, 50 to 80 parts by weight of branched hair, 10 to 30 parts by weight of shellfish, 80 to 120 parts by weight of seonchoe, and 10 to 30 parts by weight of banha for 100 parts by weight of baekchul. It refers to a composition extracted by mixing 50 to 80 parts by weight of Cheongung.
상기한 천연 보강 첨가제 및 천연 강화 첨가제를 추출하는 방법으로는 상기의 혼합한 원재료 100 중량부에 75~85%[질량%] 에탄올 1000중량부를 넣고, 2~4시간 동안 환류 추출하고 여액을 rotary evaporator를 이용하여 감압, 농축하는 방법으로 추출할 수 있다.The method of extracting the natural reinforcing additives and natural reinforcing additives described above is to add 1000 parts by weight of 75 to 85% [mass%] ethanol to 100 parts by weight of the mixed raw materials, reflux and extract for 2 to 4 hours, and transfer the filtrate to a rotary evaporator. It can be extracted by reducing pressure and concentrating.
이와 같은 추출물은 혼합한 원재료 100중량부를 기준으로 분말 형태로 5~25중량부 정도 추출될 수 있으며 이러한 분말 형태의 추출물을 첨가하는 것이 바람직하다.This extract can be extracted in powder form in an amount of 5 to 25 parts by weight based on 100 parts by weight of the mixed raw materials, and it is preferable to add the extract in powder form.
도 3에서 보는 바처럼, 완충부(220)는 상기한 바닥부(200)의 내부에 안치되어 형성되는 구조로 되어 있다.As shown in FIG. 3, the buffer portion 220 is structured to be placed inside the bottom portion 200 described above.
또한 상기한 완충부(220)는 바닥본체부(210)와 결합하여 형성될 수 있으며 완충부(220)의 일부는 바닥에 직접 접촉할 수 있는 구조로 형성될 수 있다.Additionally, the buffer unit 220 may be formed in combination with the floor body unit 210, and a portion of the buffer unit 220 may be formed in a structure that can directly contact the floor.
본 발명의 이와 같은 완충부는 투명하고 통풍구가 연결되어 있지 않고 접착제를 사용하지 않는 특징을 갖는다,This buffer part of the present invention has the characteristics of being transparent, not connected to ventilation holes, and using no adhesive.
또한 본 발명은 완충입자부(221)와 완충접합부(222)가 결합하여 일체로 형성되어 발포 입자 사이의 기공을 밀봉하고 채우게 되며 발포 입자 사이에 연결된 통풍구가 없기 때문에 종래 기술의 발포 입자를 사용하는 경우의 문제점을 해결하게 된다.In addition, the present invention is formed by combining the cushioning particle portion 221 and the cushioning joint portion 222 to seal and fill the pores between the foam particles. Since there is no ventilation hole connected between the foam particles, it is possible to use foam particles of the prior art. This solves the problem in the case.
즉, 본 발명은 종래기술의 쿠션용 밑창을 가진 신발의 경우 쿠션부가 발포입자로 되고 이러한 발포입자 쿠션부에 통풍구가 형성되어 있어 신발 착용시 물을 흡수하고 냄새가 나며, 공공장소(병원 등) 출입시 더러운 물을 빨아 들여 세균 등을 집으로 가져오게 되는 문제점이 있고, 또한 종래기술의 경우 쿠션부의 통풍구에 의한 전도 효과로 인해 겨울에는 땅에서 추위를, 여름에는 땅에서 열을 흡수하는 문제점을 있는 데 이를 완전히 해결하게 된다.That is, in the present invention, in the case of shoes with a conventional cushion sole, the cushion part is made of foam particles and a ventilation hole is formed in the foam particle cushion part, so that water is absorbed and odor is generated when the shoe is worn, and it is used in public places (hospitals, etc.) There is a problem of sucking in dirty water and bringing germs into the house when entering and exiting, and in the case of the prior art, there is a problem of absorbing cold from the ground in winter and heat from the ground in summer due to the conduction effect caused by the vents in the cushion part. This will be completely resolved.
또한, 발포된 완충입자부(221)가 닳아도 오염 된 물과 세균은 표면에 입자층 만 남게되어 깊은 내부로 빨려 들어 가지 않기 때문에 자연 건조 및 살균이 용이하게 되며, 또한, 엘라스토머를 주재료로 한 완충접합부(222)는 투명하여 직사광선으로 직접 바닥부를 살균하는 기능도 수행하게 된다.In addition, even if the foamed cushioning particle part 221 wears out, only the particle layer remains on the surface and the contaminated water and bacteria are not sucked into the deep interior, making natural drying and sterilization easy. In addition, the cushioning material made of elastomer is easy. The joint 222 is transparent, so it also performs the function of sterilizing the bottom directly with direct sunlight.
본 발명은 상기한 구성과 기능으로 이루어진 기능성 신발용 바닥부 및 이를 이용한 신발을 제공한다.The present invention provides a functional shoe sole having the above-described structure and function, and a shoe using the same.
본 발명은 신발 밑창(바닥부)을 생산, 제조, 판매, 유통, 연구하는 산업 및 이에 부대하는 산업에 매우 유용하다.The present invention is very useful in industries that produce, manufacture, sell, distribute, and research shoe soles (bottom parts), as well as industries accompanying these.
특히 본 발명은 상기한 신발 밑창(바닥부)을 포함하는 기능성 신발을 생산, 제조, 판매, 유통, 연구하는 산업에 매우 유용하다.In particular, the present invention is very useful in the industry that produces, manufactures, sells, distributes, and researches functional shoes including the shoe soles (bottoms) described above.
바닥본체부(210),
완충부(220),
완충입자부(221), 완충입자(221-1),
완충접합부(222),
바닥부(200),
신발(300).Bottom main body (210),
Buffer section 220,
Buffer particle unit (221), buffer particle (221-1),
Buffer joint (222),
Bottom part 200,
Shoes (300).
Claims (3)
상기한 완충부(220)는 완충입자부(221), 완충접합부(222)를 포함하여 구성되어 있고,
상기한 완충입자부(221)는 완충입자(221-1)가 다수로 결합하여 형성되되 벌집 구조를 이루고 있고,
상기한 완충입자부(221)의 완충입자(221-1)는 폴리우레탄 재질로 된 것으로서,
상기 폴리우레탄 재질은 폴리올 100중량부에 폴리이소시아네이트 20~150중량부, 촉매 2~20중량부, 발포제 1~5중량부를 포함하여 구성되어 있는 폴리우레탄이며,
상기한 폴리우레탄에 기능성 첨가물을 첨가하여 탄성력을 높이고 강도를 강화하는 기능을 수행하되,
상기한 기능성 첨가물은 중탄산나트륨 100 중량부에 인산암모늄 10~60 중량부, 메틸렌비스 아크릴아마이드 10~30 중량부, 글리시딜 메타크릴레이트 20~80 중량부, 메타그릴산 5~40 중량부를 포함하여 조성하고,
완충접합부(222)는 고분자 엘라스토머로 된 것을 특징으로 하는 기능성 신발용 바닥부(200).
It is composed of a floor body part 210 and a buffer part 220,
The above-described buffer part 220 includes a buffer particle part 221 and a buffer joint part 222,
The above-described buffer particle portion 221 is formed by combining a plurality of buffer particles 221-1 and forms a honeycomb structure,
The buffer particles 221-1 of the buffer particle unit 221 are made of polyurethane material,
The polyurethane material is a polyurethane composed of 100 parts by weight of polyol, 20 to 150 parts by weight of polyisocyanate, 2 to 20 parts by weight of catalyst, and 1 to 5 parts by weight of foaming agent,
Functional additives are added to the above-described polyurethane to increase elasticity and strengthen strength.
The above functional additives include 10 to 60 parts by weight of ammonium phosphate, 10 to 30 parts by weight of methylenebis acrylamide, 20 to 80 parts by weight of glycidyl methacrylate, and 5 to 40 parts by weight of methacrylic acid per 100 parts by weight of sodium bicarbonate. Established by
The cushioning joint 222 is a functional shoe sole 200, wherein the cushioning joint 222 is made of a polymer elastomer.
상기한 폴리우레탄 재질에서 촉매는 유기산 비스무트이고,
상기한 발포제는 가압 유체인 것을 특징으로 하는 기능성 신발용 바닥부(200).
According to paragraph 1,
In the above polyurethane material, the catalyst is the organic acid bismuth,
The sole 200 for a functional shoe, characterized in that the foaming agent is a pressurized fluid.
A shoe (300) including the sole (200) of claim 1 or 2.
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| JP2018143802A (en) * | 2013-02-13 | 2018-09-20 | アディダス アーゲー | Methods for manufacturing cushioning elements for sports apparel |
| JP2020110631A (en) * | 2015-03-23 | 2020-07-27 | アディダス アーゲー | Sole and shoe |
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| JP2018143802A (en) * | 2013-02-13 | 2018-09-20 | アディダス アーゲー | Methods for manufacturing cushioning elements for sports apparel |
| JP2020110631A (en) * | 2015-03-23 | 2020-07-27 | アディダス アーゲー | Sole and shoe |
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