KR102575239B1 - Method for producing whole been curd using mineral water and Ilex paraguayensis - Google Patents

Method for producing whole been curd using mineral water and Ilex paraguayensis Download PDF

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KR102575239B1
KR102575239B1 KR1020220180369A KR20220180369A KR102575239B1 KR 102575239 B1 KR102575239 B1 KR 102575239B1 KR 1020220180369 A KR1020220180369 A KR 1020220180369A KR 20220180369 A KR20220180369 A KR 20220180369A KR 102575239 B1 KR102575239 B1 KR 102575239B1
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mixture
mate
prepared
weight
soymilk
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KR1020220180369A
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Korean (ko)
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조명식
허종수
김경식
정기창
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주식회사 비움사랑
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L11/00Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
    • A23L11/40Pulse curds
    • A23L11/45Soy bean curds, e.g. tofu
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/40Table salts; Dietetic salt substitutes
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J43/00Implements for preparing or holding food, not provided for in other groups of this subclass
    • A47J43/04Machines for domestic use not covered elsewhere, e.g. for grinding, mixing, stirring, kneading, emulsifying, whipping or beating foodstuffs, e.g. power-driven
    • A47J43/07Parts or details, e.g. mixing tools, whipping tools
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2200/00Function of food ingredients
    • A23V2200/20Ingredients acting on or related to the structure
    • A23V2200/218Coagulant
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/15Inorganic Compounds
    • A23V2250/156Mineral combination
    • A23V2250/1638Undefined mineral extract
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/20Natural extracts
    • A23V2250/21Plant extracts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2300/00Processes
    • A23V2300/14Extraction

Abstract

본 발명은 마테 혼합물에 물을 첨가한 후 추출하고 여과하여 추출액을 제조하는 단계; 콩가루 및 물을 섞은 후 끓여 두유를 제조하는 단계; 상기 제조한 두유에 상기 제조한 추출액과 미네랄수 및 소금을 넣어 섞은 두유 혼합물을 식히는 단계; 및 상기 식힌 두유 혼합물에 응고제를 넣어 응고시킨 후 성형하는 단계를 포함하여 제조하는 것을 특징으로 하는 전두부의 제조방법 및 상기 방법으로 제조된 전두부에 관한 것이다.The present invention comprises the steps of adding water to the mate mixture, followed by extraction and filtration to prepare an extract; Mixing soybean flour and water and then boiling to prepare soymilk; Cooling the soymilk mixture by adding the prepared extract, mineral water, and salt to the prepared soymilk; and adding a coagulant to the cooled soymilk mixture to coagulate and then forming the tofu.

Description

미네랄수 및 마테를 이용한 전두부의 제조방법{Method for producing whole been curd using mineral water and Ilex paraguayensis}Method for producing whole tofu using mineral water and mate {Method for producing whole been curd using mineral water and Ilex paraguayensis}

본 발명은 전두부 제조 시 마테, 핑거루트, 여주, 미네랄수 등의 재료를 사용하여 제조하는 것을 특징으로 하는 전두부의 제조방법 및 상기 방법으로 제조된 전두부에 관한 것이다.The present invention relates to a method for manufacturing frontal tofu, characterized in that the frontal tofu is manufactured using materials such as mate, finger root, bitter melon, mineral water, etc., and frontal tofu manufactured by the method.

콩은 밭의 고기라고도 하며, 예로부터 한국 국민의 중요한 단백질 공급원으로 이용되어 왔으며, 그 조리방법도 100여 종이 넘을 만큼 다양하다. 두부는 콩을 재료로 한 제품 가운데 가장 대중적인 가공품으로 양질의 식물성 단백질이 풍부한 식품이다. 두부는 중국 고대 한(漢) 회남왕(淮南王) 시기에 유안(劉安)이 처음 발명한 것으로 기록되어 있고, 우리나라 문헌상에서는 고려 말기에 처음 기록이 나타나는 것으로 보아 고려 말기에 원(元)으로부터 전해 내려왔을 가능성이 높다.Beans are also called field meat, and have been used as an important protein source for the Korean people since ancient times, and their cooking methods are diverse enough to exceed 100 species. Tofu is the most popular processed product among soybean-based products and is rich in high-quality vegetable protein. It is recorded that tofu was first invented by Yuan during the reign of King Huainan of the Han Dynasty in ancient China. It is very likely that it came down

두부는 기본적으로 단백질이 풍부하고 그 이외에 지방도 함유되어 있다. 단백질은 필수아미노산을 많이 함유해 품질이 좋고 소화흡수율도 매우 높다. 두부의 주요 성분은 가식부 100 g당 84 kcal, 수분 82.8%, 단백질 8.5 g, 지질 5.6 g, 회분 0.9 g, 당질 1.4 g, 섬유소 0.2 g, 칼슘 126 ㎎, 인 140 ㎎, 철 1.5 ㎎, 나트륨 5 ㎎, 칼륨 90 ㎎, 비타민 B1 0.03 ㎎, 비타민 B2 0.02 ㎎, 나이아신 0.2 ㎎ 등이 함유되어 있다.Tofu is basically rich in protein and contains fat as well. Protein contains a lot of essential amino acids, so the quality is good and the rate of digestion and absorption is very high. The main components of tofu per 100 g of edible part are 84 kcal, 82.8% moisture, 8.5 g protein, 5.6 g lipid, ash 0.9 g, 1.4 g sugar, 0.2 g fiber, 126 mg calcium, 140 mg phosphorus, 1.5 mg iron, and 5 sodium. mg, potassium 90 mg, vitamin B1 0.03 mg, vitamin B2 0.02 mg, and niacin 0.2 mg.

이처럼 두부는 맛과 영양이 우수하고, 체내 대사와 성장 및 발육에 필요한 아미노산, 칼슘, 철분 및 미네랄 등이 다량 함유된 단백질 식품이지만, 전통적인 두부는 콩을 주원료로 생산하기 때문에 맛과 영양분을 다양화하는데 한계가 있었다.As such, tofu is a protein food that has excellent taste and nutrition and contains a large amount of amino acids, calcium, iron and minerals necessary for metabolism, growth and development in the body. There was a limit to doing it.

두부의 종류에는 모두부, 순두부, 전두부 등이 있는데, 모두부는 통상 찌개용, 부침용으로 사용되는 두부이고, 순두부는 압착 과정이 없는 두부이다. 전두부는 비지를 제거하지 않고 만든 두부로, 모두부와 순두부가 수용성 단백질만을 응고하기 때문에 다른 수용성 성분과 불용성 단백질의 손실이 많다면 전두부는 비지를 제거하지 않아 영양성분의 손실이 적다. 실제 일반 두부와 전두부를 비교했더니 식이섬유, 비타민 K1, 나이아신 등의 함량이 높았다는 연구 결과도 있다. 또한, 일반 두부보다 콩의 맛이 진하거나 식감이 치즈와 비슷하다.Types of tofu include modubu, silken tofu, and frontal tofu. Modubu is usually tofu used for stews and pancakes, and silken tofu is tofu without a pressing process. Frontal tofu is tofu made without removing the bean curd. Since all and soft tofu coagulate only water-soluble protein, there is a lot of loss of other water-soluble ingredients and insoluble protein, while front tofu does not remove the bean curd, so there is little loss of nutrients. In fact, when comparing normal tofu with frontal tofu, there is also a research result that the content of dietary fiber, vitamin K1, and niacin was high. In addition, the taste of soybeans is stronger than that of normal tofu, and the texture is similar to that of cheese.

한국등록특허 제0787490호에는 전두부의 제조방법이 개시되어 있고, 한국등록특허 제1935593호에는 기능성 흑울금 두부의 제조방법이 개시되어 있으나, 본 발명의 미네랄수를 이용한 전두부의 제조방법과는 상이하다.Korean Patent No. 0787490 discloses a method for producing frontal tofu, and Korean Patent No. 1935593 discloses a method for producing functional black turmeric tofu, but it is different from the method for producing frontal tofu using mineral water of the present invention. .

본 발명은 상기와 같은 요구에 의해 도출된 것으로서, 본 발명의 목적은 품질 및 기호도가 우수한 전두부를 제조하기 위해, 부재료 선정, 배합, 가열 등의 제조조건을 최적화하여, 고소한 맛 및 향과 식감이 향상되고, 재료 유래 다양한 영양성분을 포함하는 고품질의 전두부의 제조방법을 제공하는 데 있다.The present invention was derived from the above needs, and an object of the present invention is to optimize the manufacturing conditions such as sub-material selection, blending, and heating to produce frontal tofu with excellent quality and preference, so that the savory taste, aroma, and texture are improved. It is an object of the present invention to provide a method for manufacturing high-quality tofu containing various nutrients derived from materials.

상기 과제를 해결하기 위해, 본 발명은 (1) 마테, 핑거루트, 여주, 감초, 산사나무, 모과 및 해당화를 혼합하여 마테 혼합물을 제조하는 단계; (2) 상기 (1)단계의 제조한 마테 혼합물에 물을 첨가한 후 추출하고 여과하여 추출액을 제조하는 단계; (3) 콩가루 및 물을 섞은 후 끓여 두유를 제조하는 단계; (4) 상기 (3)단계의 제조한 두유에 상기 (2)단계의 제조한 추출액과 미네랄수 및 소금을 넣어 섞은 두유 혼합물을 식히는 단계; 및 (5) 상기 (4)단계의 식힌 두유 혼합물에 응고제를 넣어 응고시킨 후 성형하는 단계를 포함하여 제조하는 것을 특징으로 하는 전두부의 제조방법을 제공한다.In order to solve the above problems, the present invention provides (1) preparing a mate mixture by mixing mate, finger root, bitter gourd, licorice, hawthorn, quince and sugarcane; (2) preparing an extract by adding water to the mate mixture prepared in step (1), followed by extraction and filtration; (3) preparing soymilk by mixing  bean flour and  water and then boiling; (4) cooling the soymilk mixture by adding the extract from step (2), mineral water, and salt to the soymilk prepared in step (3); and (5) adding a coagulant to the cooled soymilk mixture of step (4) to coagulate it, and then forming the tofu.

또한, 본 발명은 상기 방법으로 제조된 전두부를 제공한다.In addition, the present invention provides a frontal part prepared by the above method.

본 발명의 전두부는 미네랄수 유래 다양한 미네랄 성분과 마테 등을 포함하는 추출액을 사용하여, 상기 재료 유래 영양성분을 함유하여 품질이 우수한 이점이 있다. 또한, 재료들의 맛과 향이 잘 어우러지고, 고소한 맛 및 향과 식감이 더욱 향상된 전두부를 제조할 수 있다.The tofu of the present invention uses an extract containing various mineral components derived from mineral water and mate, etc., and contains nutrients derived from the above materials, thereby having an advantage of excellent quality. In addition, the taste and aroma of the ingredients are well harmonized, and the savory taste, aroma, and texture of the front tofu can be further improved.

본 발명의 목적을 달성하기 위하여, 본 발명은In order to achieve the object of the present invention, the present invention

(1) 마테, 핑거루트, 여주, 감초, 산사나무, 모과 및 해당화를 혼합하여 마테 혼합물을 제조하는 단계;(1) preparing a mate mixture by mixing mate, finger root, bitter gourd, licorice, hawthorn, quince and sugarcane;

(2) 상기 (1)단계의 제조한 마테 혼합물에 물을 첨가한 후 추출하고 여과하여 추출액을 제조하는 단계;(2) preparing an extract by adding water to the mate mixture prepared in step (1), followed by extraction and filtration;

(3) 콩가루 및 물을 섞은 후 끓여 두유를 제조하는 단계;(3) preparing soymilk by mixing  bean flour and  water and then boiling;

(4) 상기 (3)단계의 제조한 두유에 상기 (2)단계의 제조한 추출액과 미네랄수 및 소금을 넣어 섞은 두유 혼합물을 식히는 단계; 및(4) cooling the soymilk mixture by adding the extract from step (2), mineral water, and salt to the soymilk prepared in step (3); and

(5) 상기 (4)단계의 식힌 두유 혼합물에 응고제를 넣어 응고시킨 후 성형하는 단계를 포함하여 제조하는 것을 특징으로 하는 전두부의 제조방법을 제공한다.(5) It provides a method for producing frontal tofu, characterized in that it comprises the step of adding a coagulant to the cooled soymilk mixture of step (4) to coagulate and then molding.

본 발명의 전두부의 제조방법에서, 상기 (1)단계의 마테 혼합물은 바람직하게는 마테 혼합물 총 중량 기준으로, 마테 88~92 중량%, 핑거루트 2~4 중량%, 여주 0.5~1.5 중량%, 감초 2~4 중량%, 산사나무 0.5~1.5 중량%, 모과 0.5~1.5 중량% 및 해당화 0.5~1.5 중량%를 혼합하여 제조할 수 있으며, 더욱 바람직하게는 마테 혼합물 총 중량 기준으로, 마테 90 중량%, 핑거루트 3 중량%, 여주 1 중량%, 감초 3 중량%, 산사나무 1 중량%, 모과 1 중량% 및 해당화 1 중량%를 혼합하여 제조할 수 있다.In the method for producing frontal tofu of the present invention, the mate mixture in step (1) preferably contains 88 to 92% by weight of mate, 2 to 4% by weight of finger root, 0.5 to 1.5% by weight of bitter gourd, based on the total weight of the mate mixture. It can be prepared by mixing 2 to 4% by weight of licorice, 0.5 to 1.5% by weight of hawthorn, 0.5 to 1.5% by weight of quince, and 0.5 to 1.5% by weight of sugarcane, more preferably 90% by weight of mate based on the total weight of the mate mixture. %, it can be prepared by mixing 3% by weight of finger root, 1% by weight of Bitter gourd, 3% by weight of licorice, 1% by weight of hawthorn, 1% by weight of quince and 1% by weight of sugarcane.

또한, 본 발명의 전두부의 제조방법에서, 상기 (2)단계의 추출액은 바람직하게는 마테 혼합물에 마테 혼합물 대비 물 18~22배(v/w)를 첨가한 후 90~100℃에서 15~25분 동안 추출하고 여과하여 제조할 수 있으며, 더욱 바람직하게는 마테 혼합물에 마테 혼합물 대비 물 20배(v/w)를 첨가한 후 95℃에서 20분 동안 추출하고 여과하여 제조할 수 있다. 상기 (1) 및 (2)단계와 같은 조건으로 추출액을 제조하는 것이 두부의 맛과 풍미를 더욱 향상시킬 수 있는 추출액으로 제조할 수 있었다.In addition, in the method for producing frontal tofu of the present invention, the extract in step (2) is preferably 15 to 25 times (v/w) at 90 to 100 ° C after adding 18 to 22 times (v / w) of water compared to the mate mixture to the mate mixture. It can be prepared by extracting and filtering for 20 minutes, more preferably by adding 20 times (v/w) of water compared to the mate mixture to the mate mixture, then extracting at 95 ° C. for 20 minutes and filtering. By preparing the extract under the same conditions as in the steps (1) and (2), the extract could be prepared to further improve the taste and flavor of tofu.

또한, 본 발명의 전두부의 제조방법에서, 상기 (3)단계의 두유는 바람직하게는 콩가루 300~400 g 및 물 1600~1800 mL를 섞은 후 80~100℃에서 끓여 제조할 수 있으며, 더욱 바람직하게는 콩가루 350 g 및 물 1700 mL를 섞은 후 90℃에서 끓여 제조할 수 있다. 상기와 같이 두유를 제조하는 것이 비린내가 나지 않으면서 두부 제조에 적합한 두유로 제조할 수 있었다.In addition, in the method for producing frontal tofu of the present invention, the soy milk in step (3) is preferably prepared by mixing 300 to 400 g of soy flour and 1600 to 1800 mL of water and then boiling at 80 to 100 ° C., more preferably can be prepared by mixing 350 g of soy flour and 1700 mL of water and then boiling at 90 ° C. By producing soymilk as described above, it was possible to produce soymilk suitable for tofu production without a fishy smell.

또한, 본 발명의 전두부의 제조방법에서, 상기 (4)단계는 바람직하게는 두유에 추출액 8~12 mL, 미네랄수 80~120 mL 및 소금 0.5~1.5 g을 넣어 섞은 두유 혼합물을 50~70℃로 식힐 수 있으며, 더욱 바람직하게는 두유에 추출액 10 mL, 미네랄수 100 mL 및 소금 1 g을 넣어 섞은 두유 혼합물을 60℃로 식힐 수 있다. 상기와 같이 두유 혼합물을 제조하는 것이 이취가 나지 않으면서 품질 및 기호도가 우수한 두부로 제조할 수 있었다.In addition, in the method for producing frontal tofu of the present invention, step (4) is preferably a soy milk mixture in which 8 to 12 mL of extract, 80 to 120 mL of mineral water, and 0.5 to 1.5 g of salt are added to soy milk and mixed with soy milk at 50 to 70 ° C. It can be cooled, and more preferably, the soy milk mixture mixed with 10 mL of extract, 100 mL of mineral water, and 1 g of salt in soy milk can be cooled to 60 ° C. By preparing the soymilk mixture as described above, it was possible to produce tofu with excellent quality and preference without off-flavor.

또한, 본 발명의 전두부의 제조방법에서, 상기 (5)단계는 바람직하게는 식힌 두유 혼합물에 응고제 25~35 g을 넣어 응고시킨 후 성형할 수 있으며, 더욱 바람직하게는 식힌 두유 혼합물에 응고제 30 g을 넣어 응고시킨 후 성형할 수 있다.In addition, in the method for producing frontal tofu of the present invention, step (5) can be preferably formed by adding 25 to 35 g of coagulant to the cooled soymilk mixture and coagulating it, more preferably adding 30 g of coagulant to the chilled soymilk mixture. After solidification, it can be molded.

상기 응고제는 염도 20~30%인 간수일 수 있으며, 상기 간수 외에 염화칼슘, 염화마그네슘, 황산칼슘 또는 염화칼륨과 같은 응고제를 사용할 수 있으나, 이에 제한되지 않는다.The coagulant may be bittern having a salinity of 20 to 30%, and a coagulant such as calcium chloride, magnesium chloride, calcium sulfate or potassium chloride may be used in addition to the bittern, but is not limited thereto.

본 발명의 전두부의 제조방법은, 보다 구체적으로는The method for producing the front tofu of the present invention is more specifically

(1) 마테 혼합물 총 중량 기준으로, 마테 88~92 중량%, 핑거루트 2~4 중량%, 여주 0.5~1.5 중량%, 감초 2~4 중량%, 산사나무 0.5~1.5 중량%, 모과 0.5~1.5 중량% 및 해당화 0.5~1.5 중량%를 혼합하여 마테 혼합물을 제조하는 단계;(1) Based on the total weight of the mate mixture, mate 88-92 wt%, finger root 2-4 wt%, bitter gourd 0.5-1.5 wt%, licorice 2-4 wt%, hawthorn 0.5-1.5 wt%, quince 0.5-1.5 wt% Preparing a mate mixture by mixing 1.5% by weight and 0.5 to 1.5% by weight of glycolysis;

(2) 상기 (1)단계의 제조한 마테 혼합물에 마테 혼합물 대비 물 18~22배(v/w)를 첨가한 후 90~100℃에서 15~25분 동안 추출하고 여과하여 추출액을 제조하는 단계;(2) Preparing an extract solution by adding 18 to 22 times (v/w) of water compared to the mate mixture to the mate mixture prepared in step (1), extracting at 90 to 100 ° C for 15 to 25 minutes, and filtering ;

(3) 콩가루 300~400 g 및 물 1600~1800 mL를 섞은 후 80~100℃에서 끓여 두유를 제조하는 단계;(3) preparing soy milk by mixing 300-400 g of soybean flour and 1600-1800 mL of water and then boiling at 80-100 ° C;

(4) 상기 (3)단계의 제조한 두유에 상기 (2)단계의 제조한 추출액 8~12 mL와 미네랄수 80~120 mL 및 소금 0.5~1.5 g을 넣어 섞은 두유 혼합물을 50~70℃로 식히는 단계; 및(4) The soy milk mixture prepared by adding 8 to 12 mL of the extract prepared in step (2), 80 to 120 mL of mineral water, and 0.5 to 1.5 g of salt to the soymilk prepared in step (3) above is heated to 50 to 70 ° C. cooling down; and

(5) 상기 (4)단계의 식힌 두유 혼합물에 응고제 25~35 g을 넣어 응고시킨 후 성형하는 단계를 포함할 수 있으며,(5) adding 25 to 35 g of a coagulant to the cooled soymilk mixture in step (4) above, coagulating it, and molding it;

더욱 구체적으로는more specifically

(1) 마테 혼합물 총 중량 기준으로, 마테 90 중량%, 핑거루트 3 중량%, 여주 1 중량%, 감초 3 중량%, 산사나무 1 중량%, 모과 1 중량% 및 해당화 1 중량%를 혼합하여 마테 혼합물을 제조하는 단계;(1) Based on the total weight of the mate mixture, 90% by weight of mate, 3% by weight of finger root, 1% by weight of bitter gourd, 3% by weight of licorice, 1% by weight of hawthorn, 1% by weight of quince, and 1% by weight of sugarcane were mixed to obtain mate preparing a mixture;

(2) 상기 (1)단계의 제조한 마테 혼합물에 마테 혼합물 대비 물 20배(v/w)를 첨가한 후 95℃에서 20분 동안 추출하고 여과하여 추출액을 제조하는 단계;(2) preparing an extract by adding 20 times (v/w) of water to the mate mixture prepared in step (1), extracting at 95° C. for 20 minutes, and filtering;

(3) 콩가루 350 g 및 물 1700 mL를 섞은 후 90℃에서 끓여 두유를 제조하는 단계;(3) preparing soy milk by mixing 350 g of soybean flour and 1700 mL of water and then boiling at 90 ° C;

(4) 상기 (3)단계의 제조한 두유에 상기 (2)단계의 제조한 추출액 10 mL와 미네랄수 100 mL 및 소금 1 g을 넣어 섞은 두유 혼합물을 60℃로 식히는 단계; 및(4) cooling the soymilk mixture by adding 10 mL of the extract prepared in step (2), 100 mL of mineral water, and 1 g of salt to the soymilk prepared in step (3) to 60 ° C; and

(5) 상기 (4)단계의 식힌 두유 혼합물에 응고제 30 g을 넣어 응고시킨 후 성형하는 단계를 포함할 수 있다.(5) adding 30 g of a coagulant to the cooled soymilk mixture in step (4) above, coagulating it, and then molding it.

본 발명은 또한, 상기 방법으로 제조된 전두부를 제공한다.The present invention also provides a frontal part prepared by the above method.

이하, 본 발명의 제조예 및 실시예를 들어 상세히 설명한다. 단, 하기 제조예 및 실시예는 본 발명을 예시하는 것일 뿐, 본 발명의 내용이 하기 제조예 및 실시예에 한정되는 것은 아니다.Hereinafter, production examples and examples of the present invention will be described in detail. However, the following Preparation Examples and Examples are only to illustrate the present invention, and the content of the present invention is not limited to the following Preparation Examples and Examples.

제조예 1. 전두부Preparation Example 1. Front head

(1) 지하수를 정제하여 고전압(220~1,000V) 발생장치가 부착된 저장탱크에 넣고, 당사가 제작한 미네랄을 투입 후 고전압을 발생시켜 미네랄을 이온화시켜 미네랄수를 제조하였다. 상기 제조한 미네랄수에는 칼륨 2.3 ㎎/L, 나트륨 7.2 ㎎/L, 칼슘 15.2 ㎎/L 및 마그네슘 3.5 ㎎/L 등이 포함되어 있다.(1) After purifying groundwater, put it in a storage tank equipped with a high voltage (220~1,000V) generator, add minerals manufactured by our company, and generate high voltage to ionize the minerals to produce mineral water. The prepared mineral water contains 2.3 mg/L of potassium, 7.2 mg/L of sodium, 15.2 mg/L of calcium, and 3.5 mg/L of magnesium.

(2) 마테차 혼합물 총 중량 기준으로, 마테차(판매: 초원한방플러스) 90 중량%, 건조핑거루트 차(판매: 갑당약초) 3 중량%, 건여주 1 중량%, 감초 3 중량%, 산사나무 열매 1 중량%, 모과 열매 1 중량% 및 해당화꽃 1 중량%를 혼합하여 마테차 혼합물을 제조하였다.(2) Based on the total weight of the mate tea mixture, 90% by weight of mate tea (sales: Chowon Oriental Medicine Plus), 3% by weight of dried finger root tea (sales: Gapdang Herbs), 1% by weight of dry bitter gourd, 3% by weight of licorice, hawthorn fruit A mate tea mixture was prepared by mixing 1% by weight, 1% by weight of quince fruit, and 1% by weight of sugar flower.

(3) 상기 (2)단계의 제조한 마테차 혼합물에 마테차 혼합물 대비 정제수 20배(v/w)를 첨가한 후 95℃에서 20분 동안 추출한 후 여과하여 추출액을 제조하였다.(3) After adding 20 times (v / w) of purified water compared to the mate tea mixture to the mate tea mixture prepared in step (2), extraction was performed at 95 ° C. for 20 minutes, and then filtered to prepare an extract.

(4) 콩가루 350 g 및 물 1700 L를 믹서기에 넣어 잘 섞어주고, 90℃에서 끓여 두유를 제조하였다.(4) 350 g of soybean flour and 1700 L of water were put in a blender, mixed well, and boiled at 90 ° C to prepare soymilk.

(5) 상기 (4)단계의 제조한 두유에 상기 (1)단계의 제조한 미네랄수 100 mL, 상기 (3)단계의 제조한 추출액 10 mL, 소금(미네랄 소금) 1 g을 넣어 잘 섞은 두유 혼합물을 60℃로 식혀주었다.(5) Add 100 mL of mineral water from step (1), 10 mL of extract from step (3), and 1 g of salt (mineral salt) to the soymilk prepared in step (4) and mix well. The mixture was cooled to 60 °C.

(6) 상기 (5)단계의 식힌 두유 혼합물에 식물성 응고제(간수) 30 g을 넣어 잘 섞어주어 응고시킨 후, 틀에 넣어 압착하여 성형하고, 10℃ 이하의 냉장에서 6시간 이상 냉각시켰다.(6) Add 30 g of a vegetable coagulant (bitter) to the cooled soymilk mixture in step (5) above, mix well to coagulate, press and mold in a mold, and cool in a refrigerator at 10 ° C or lower for 6 hours or more.

비교예 1. 전두부Comparative Example 1. Front head

(1) 지하수를 정제하여 고전압(220~1,000V) 발생장치가 부착된 저장탱크에 넣고, 당사가 제작한 미네랄을 투입 후 고전압을 발생시켜 미네랄을 이온화시켜 미네랄수를 제조하였다. 상기 제조한 미네랄수에는 칼륨 2.3 ㎎/L, 나트륨 7.2 ㎎/L, 칼슘 15.2 ㎎/L 및 마그네슘 3.5 ㎎/L 등이 포함되어 있다.(1) After purifying groundwater, put it in a storage tank equipped with a high voltage (220~1,000V) generator, add minerals manufactured by our company, and generate high voltage to ionize the minerals to produce mineral water. The prepared mineral water contains 2.3 mg/L of potassium, 7.2 mg/L of sodium, 15.2 mg/L of calcium, and 3.5 mg/L of magnesium.

(2) 콩가루 350 g 및 물 1700 L를 믹서기에 넣어 잘 섞어주고, 90℃에서 끓여 두유를 제조하였다.(2) 350 g of soybean flour and 1700 L of water were put in a blender, mixed well, and boiled at 90 ° C to prepare soymilk.

(3) 상기 (2)단계의 제조한 두유에 상기 (1)단계의 제조한 미네랄수 110 mL 및 소금(미네랄 소금) 1 g을 넣어 잘 섞은 두유 혼합물을 60℃로 식혀주었다.(3) 110 mL of mineral water prepared in step (1) and 1 g of salt (mineral salt) were added to the soymilk prepared in step (2), and the well-mixed soymilk mixture was cooled to 60 ° C.

(4) 상기 (3)단계의 식힌 두유 혼합물에 식물성 응고제(간수) 30 g을 넣어 잘 섞어주어 응고시킨 후, 틀에 넣어 압착하여 성형하고, 10℃ 이하의 냉장에서 6시간 이상 냉각시켰다.(4) Add 30 g of vegetable coagulant (bitter) to the cooled soymilk mixture in step (3) above, mix well to coagulate, press and mold in a mold, and cool in a refrigerator at 10 ° C or less for 6 hours or more.

비교예 2. 전두부Comparative Example 2. Front head

(1) 지하수를 정제하여 고전압(220~1,000V) 발생장치가 부착된 저장탱크에 넣고, 당사가 제작한 미네랄을 투입 후 고전압을 발생시켜 미네랄을 이온화시켜 미네랄수를 제조하였다. 상기 제조한 미네랄수에는 칼륨 2.3 ㎎/L, 나트륨 7.2 ㎎/L, 칼슘 15.2 ㎎/L 및 마그네슘 3.5 ㎎/L 등이 포함되어 있다.(1) After purifying groundwater, put it in a storage tank equipped with a high voltage (220~1,000V) generator, add minerals manufactured by our company, and generate high voltage to ionize the minerals to produce mineral water. The prepared mineral water contains 2.3 mg/L of potassium, 7.2 mg/L of sodium, 15.2 mg/L of calcium, and 3.5 mg/L of magnesium.

(2) 마테차 혼합물 총 중량 기준으로, 마테차(판매: 초원한방플러스) 93 중량%, 건조핑거루트 차(판매: 갑당약초) 3 중량%, 건여주 1 중량% 및 감초 3 중량%를 혼합하여 마테차 혼합물을 제조하였다.(2) Based on the total weight of the mate tea mixture, 93% by weight of mate tea (sales: Chowon Oriental Medicine Plus), 3% by weight of dried finger root tea (sales: Gabdang herbal medicine), 1% by weight of dry bitter gourd, and 3% by weight of licorice were mixed to obtain mate tea A mixture was prepared.

(3) 상기 (2)단계의 제조한 마테차 혼합물에 마테차 혼합물 대비 정제수 20배(v/w)를 첨가한 후 95℃에서 20분 동안 추출한 후 여과하여 추출액을 제조하였다.(3) After adding 20 times (v / w) of purified water compared to the mate tea mixture to the mate tea mixture prepared in step (2), extraction was performed at 95 ° C. for 20 minutes, and then filtered to prepare an extract.

(4) 상기 (1)단계의 제조한 미네랄수와 상기 (3)단계의 제조한 추출액을 이용하여, 제조예 1의 (4) 내지 (6)단계와 동일한 방법으로 전두부를 제조하였다.(4) Using the mineral water prepared in step (1) and the extract prepared in step (3), the front tofu was prepared in the same manner as steps (4) to (6) of Preparation Example 1.

비교예 3. 전두부Comparative Example 3. Front head

(1) 지하수를 정제하여 고전압(220~1,000V) 발생장치가 부착된 저장탱크에 넣고, 당사가 제작한 미네랄을 투입 후 고전압을 발생시켜 미네랄을 이온화시켜 미네랄수를 제조하였다. 상기 제조한 미네랄수에는 칼륨 2.3 ㎎/L, 나트륨 7.2 ㎎/L, 칼슘 15.2 ㎎/L 및 마그네슘 3.5 ㎎/L 등이 포함되어 있다.(1) After purifying groundwater, put it in a storage tank equipped with a high voltage (220~1,000V) generator, add minerals manufactured by our company, and generate high voltage to ionize the minerals to produce mineral water. The prepared mineral water contains 2.3 mg/L of potassium, 7.2 mg/L of sodium, 15.2 mg/L of calcium, and 3.5 mg/L of magnesium.

(2) 마테차 혼합물 총 중량 기준으로, 마테차(판매: 초원한방플러스) 91 중량%, 산사나무 열매 3 중량%, 모과 열매 3 중량% 및 해당화꽃 3 중량%를 혼합하여 마테차 혼합물을 제조하였다.(2) Based on the total weight of the mate tea mixture, a mate tea mixture was prepared by mixing 91% by weight of mate tea (sales: Chowon Oriental Medicine Plus), 3% by weight of hawthorn fruit, 3% by weight of quince fruit, and 3% by weight of sugar flower.

(3) 상기 (2)단계의 제조한 마테차 혼합물에 마테차 혼합물 대비 정제수 20배(v/w)를 첨가한 후 95℃에서 20분 동안 추출한 후 여과하여 추출액을 제조하였다.(3) After adding 20 times (v / w) of purified water compared to the mate tea mixture to the mate tea mixture prepared in step (2), extraction was performed at 95 ° C. for 20 minutes, and then filtered to prepare an extract.

(4) 상기 (1)단계의 제조한 미네랄수와 상기 (3)단계의 제조한 추출액을 이용하여, 제조예 1의 (4) 내지 (6)단계와 동일한 방법으로 전두부를 제조하였다.(4) Using the mineral water prepared in step (1) and the extract prepared in step (3), the front tofu was prepared in the same manner as steps (4) to (6) of Preparation Example 1.

실시예 1. DPPH 라디칼 소거능 시험Example 1. DPPH radical scavenging ability test

수소전자공여능에 의해 항산화 활성을 측정하기 위해 시료를 메탄올 용매로 용해하여, 900 ㎕의 DPPH 용액(100 uM)과 희석한 각 시료 100 ㎕를 혼합하여 교반하였다. 이 혼합 시료를 암소에서 30분간 반응시킨 후 517 nm에서 흡광도를 측정하였다. 수소전자공여능은 각 실험을 3회 반복하여 평균을 낸 다음 대조구에 대한 흡광도의 감소 정도를 다음 식에 의하여 계산하였다.In order to measure the antioxidant activity by hydrogen electron donating ability, the sample was dissolved in a methanol solvent, and 900 μl of DPPH solution (100 uM) and 100 μl of each diluted sample were mixed and stirred. After reacting this mixed sample for 30 minutes in the dark, the absorbance was measured at 517 nm. The hydrogen electron donating ability was averaged by repeating each experiment three times, and then the degree of decrease in absorbance with respect to the control was calculated by the following equation.

DPPH 라디칼 소거능에 대한 항산화 활성(%) = (A-B)/A × 100Antioxidant activity (%) for DPPH radical scavenging activity = (A-B) / A × 100

A: 시료가 첨가되지 않은 DPPH 용액의 흡광도A: Absorbance of DPPH solution to which no sample was added

B: 반응용액 중의 DPPH와 시료의 반응한 흡광도B: Absorbance of reaction between DPPH and sample in reaction solution

전두부의 DPPH 라디칼 소거능 시험DPPH radical scavenging ability test of the frontal region 전두부 종류frontal type DPPH 라디칼 소거능 시험(1000 ppm)DPPH radical scavenging ability test (1000 ppm) 제조예 1Preparation Example 1 61.2±3.661.2±3.6 비교예 1Comparative Example 1 36.7±1.836.7±1.8 비교예 2Comparative Example 2 49.3±2.649.3±2.6 비교예 3Comparative Example 3 53.5±3.153.5±3.1

제조예 1과 비교예 1 내지 3의 방법으로 제조된 전두부를 가지고 DPPH 라디칼 소거능 측정 결과는 상기 표 1에 나타내었다. 시료 추출물 1,000 ppm에서 제조예 1의 전두부가 가장 높은 활성을 나타내었고, 비교예 1의 전두부가 가장 낮은 활성을 나타내었다.The results of measuring the DPPH radical scavenging ability with the frontal parts prepared by the methods of Preparation Example 1 and Comparative Examples 1 to 3 are shown in Table 1 above. At 1,000 ppm of the sample extract, the frontal part of Preparation Example 1 showed the highest activity, and the frontal part of Comparative Example 1 showed the lowest activity.

실시예 2. 재료 종류에 따른 전두부 관능검사Example 2. Frontal sensory test according to material type

제조예 1과 비교예 1 내지 3의 전두부를 가지고, 관능검사 요원 35명을 대상으로 시식하게 한 후, 향, 맛, 식감 및 종합 기호도를 평가하게 하였다. 평가는 5점 척도법(1점: 매우 나쁨, 2점: 나쁨, 3점: 보통, 4점: 좋음, 5점: 매우 좋음)으로 점수를 매겨 그 결과를 표 2에 나타내었다.With the front tofu of Preparation Example 1 and Comparative Examples 1 to 3, 35 sensory test agents were sampled, and then the aroma, taste, texture, and overall acceptability were evaluated. The evaluation was scored on a 5-point scale (1 point: very bad, 2 points: bad, 3 points: average, 4 points: good, 5 points: very good), and the results are shown in Table 2.

재료 종류에 따른 전두부의 관능검사Sensory test of the frontal part according to the material type 전두부 종류frontal type incense taste 식감texture 종합 기호도Comprehensive Symbol 제조예 1Preparation Example 1 4.24.2 4.44.4 4.24.2 4.34.3 비교예 1Comparative Example 1 3.43.4 3.63.6 3.83.8 3.53.5 비교예 2Comparative Example 2 4.04.0 4.04.0 3.93.9 3.93.9 비교예 3Comparative Example 3 3.83.8 3.93.9 3.93.9 3.83.8

그 결과, 비교예들의 전두부에 비해 제조예 1의 전두부가 모든 항목에서 높은 선호도를 나타냄을 확인할 수 있었고, 비교예 1의 전두부가 가장 낮은 점수를 나타내었다. 따라서, 제조예 1과 같은 재료 종류를 모두 사용하여 전두부를 제조하는 것이 전두부와 잘 어우러져 더 선호함을 확인하였다As a result, it was confirmed that the front head of Preparation Example 1 showed a high preference in all items compared to the front head of Comparative Examples, and the front head of Comparative Example 1 showed the lowest score. Therefore, it was confirmed that manufacturing the front tofu using all the same types of materials as in Preparation Example 1 is preferred because it blends well with the front tofu.

Claims (5)

(1) 마테, 핑거루트, 여주, 감초, 산사나무, 모과 및 해당화를 혼합하여 마테 혼합물을 제조하는 단계;
(2) 상기 (1)단계의 제조한 마테 혼합물에 물을 첨가한 후 추출하고 여과하여 추출액을 제조하는 단계;
(3) 콩가루 및 물을 섞은 후 끓여 두유를 제조하는 단계;
(4) 상기 (3)단계의 제조한 두유에 상기 (2)단계의 제조한 추출액과 미네랄수 및 소금을 넣어 섞은 두유 혼합물을 식히는 단계; 및
(5) 상기 (4)단계의 식힌 두유 혼합물에 응고제를 넣어 응고시킨 후 성형하는 단계를 포함하여 제조하는 것을 특징으로 하는 전두부의 제조방법.
(1) preparing a mate mixture by mixing mate, finger root, bitter gourd, licorice, hawthorn, quince and sugarcane;
(2) preparing an extract by adding water to the mate mixture prepared in step (1), followed by extraction and filtration;
(3) preparing soybean milk by boiling after mixing soy flour and water;
(4) cooling the soymilk mixture by adding the extract from step (2), mineral water, and salt to the soymilk prepared in step (3); and
(5) A method for producing frontal tofu, characterized in that it is produced by adding a coagulant to the cooled soymilk mixture in step (4) to coagulate and then molding.
제1항에 있어서, 상기 (1)단계의 마테 혼합물은 마테 혼합물 총 중량 기준으로, 마테 88~92 중량%, 핑거루트 2~4 중량%, 여주 0.5~1.5 중량%, 감초 2~4 중량%, 산사나무 0.5~1.5 중량%, 모과 0.5~1.5 중량% 및 해당화 0.5~1.5 중량%를 혼합하여 제조하는 것을 특징으로 하는 전두부의 제조방법.The method of claim 1, wherein the mate mixture in step (1) contains 88 to 92% by weight of mate, 2 to 4% by weight of finger root, 0.5 to 1.5% by weight of bitter melon, and 2 to 4% by weight of licorice, based on the total weight of the mate mixture. , A method for producing frontal tofu, characterized in that it is prepared by mixing 0.5 to 1.5% by weight of hawthorn, 0.5 to 1.5% by weight of quince, and 0.5 to 1.5% by weight of sugarcane. 제1항에 있어서,
(1) 마테 혼합물 총 중량 기준으로, 마테 88~92 중량%, 핑거루트 2~4 중량%, 여주 0.5~1.5 중량%, 감초 2~4 중량%, 산사나무 0.5~1.5 중량%, 모과 0.5~1.5 중량% 및 해당화 0.5~1.5 중량%를 혼합하여 마테 혼합물을 제조하는 단계;
(2) 상기 (1)단계의 제조한 마테 혼합물에 마테 혼합물 대비 물 18~22배(v/w)를 첨가한 후 추출하고 여과하여 추출액을 제조하는 단계;
(3) 콩가루 300~400 g 및 물 1600~1800 mL를 섞은 후 끓여 두유를 제조하는 단계;
(4) 상기 (3)단계의 제조한 두유에 상기 (2)단계의 제조한 추출액 8~12 mL와 미네랄수 80~120 mL 및 소금 0.5~1.5 g을 넣어 섞은 두유 혼합물을 식히는 단계; 및
(5) 상기 (4)단계의 식힌 두유 혼합물에 응고제 25~35 g을 넣어 응고시킨 후 성형하는 단계를 포함하여 제조하는 것을 특징으로 하는 전두부의 제조방법.
According to claim 1,
(1) Based on the total weight of the mate mixture, mate 88-92 wt%, finger root 2-4 wt%, bitter gourd 0.5-1.5 wt%, licorice 2-4 wt%, hawthorn 0.5-1.5 wt%, quince 0.5-1.5 wt% Preparing a mate mixture by mixing 1.5% by weight and 0.5 to 1.5% by weight of glycolysis;
(2) preparing an extract by adding 18 to 22 times (v/w) of water compared to the mate mixture to the mate mixture prepared in step (1), followed by extraction and filtration;
(3) mixing 300-400 g of soy flour and 1600-1800 mL of water and then boiling to prepare soymilk;
(4) cooling the soymilk mixture by adding 8 to 12 mL of the extract prepared in step (2), 80 to 120 mL of mineral water, and 0.5 to 1.5 g of salt to the soymilk prepared in step (3); and
(5) A method for producing frontal tofu, characterized in that it is prepared by adding 25 to 35 g of coagulant to the cooled soymilk mixture in step (4) to coagulate and then molding.
제1항에 있어서,
(1) 마테 혼합물 총 중량 기준으로, 마테 88~92 중량%, 핑거루트 2~4 중량%, 여주 0.5~1.5 중량%, 감초 2~4 중량%, 산사나무 0.5~1.5 중량%, 모과 0.5~1.5 중량% 및 해당화 0.5~1.5 중량%를 혼합하여 마테 혼합물을 제조하는 단계;
(2) 상기 (1)단계의 제조한 마테 혼합물에 마테 혼합물 대비 물 18~22배(v/w)를 첨가한 후 90~100℃에서 15~25분 동안 추출하고 여과하여 추출액을 제조하는 단계;
(3) 콩가루 300~400 g 및 물 1600~1800 mL를 섞은 후 80~100℃에서 끓여 두유를 제조하는 단계;
(4) 상기 (3)단계의 제조한 두유에 상기 (2)단계의 제조한 추출액 8~12 mL와 미네랄수 80~120 mL 및 소금 0.5~1.5 g을 넣어 섞은 두유 혼합물을 50~70℃로 식히는 단계; 및
(5) 상기 (4)단계의 식힌 두유 혼합물에 응고제 25~35 g을 넣어 응고시킨 후 성형하는 단계를 포함하여 제조하는 것을 특징으로 하는 전두부의 제조방법.
According to claim 1,
(1) Based on the total weight of the mate mixture, mate 88-92 wt%, finger root 2-4 wt%, bitter gourd 0.5-1.5 wt%, licorice 2-4 wt%, hawthorn 0.5-1.5 wt%, quince 0.5-1.5 wt% Preparing a mate mixture by mixing 1.5% by weight and 0.5 to 1.5% by weight of glycolysis;
(2) Preparing an extract solution by adding 18 to 22 times (v/w) of water compared to the mate mixture to the mate mixture prepared in step (1), extracting at 90 to 100 ° C for 15 to 25 minutes, and filtering ;
(3) preparing soy milk by mixing 300-400 g of soybean flour and 1600-1800 mL of water and boiling at 80-100 ° C;
(4) The soy milk mixture prepared by adding 8 to 12 mL of the extract prepared in step (2), 80 to 120 mL of mineral water, and 0.5 to 1.5 g of salt to the soymilk prepared in step (3) above is heated to 50 to 70 ° C. cooling down; and
(5) A method for producing frontal tofu, characterized in that it is prepared by adding 25 to 35 g of coagulant to the cooled soymilk mixture in step (4) to coagulate and then molding.
제1항 내지 4항 중 어느 한 항의 방법으로 제조된 전두부.Claims 1 to 4 of the frontal prepared by any one of the methods.
KR1020220180369A 2022-12-21 2022-12-21 Method for producing whole been curd using mineral water and Ilex paraguayensis KR102575239B1 (en)

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