KR102552846B1 - Functional aluminum windows that form antibacterial, deodorant, and antifouling screens by additionally coating water repellent composition on the outer surface coated with photocatalytic composition - Google Patents

Functional aluminum windows that form antibacterial, deodorant, and antifouling screens by additionally coating water repellent composition on the outer surface coated with photocatalytic composition Download PDF

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KR102552846B1
KR102552846B1 KR1020230029068A KR20230029068A KR102552846B1 KR 102552846 B1 KR102552846 B1 KR 102552846B1 KR 1020230029068 A KR1020230029068 A KR 1020230029068A KR 20230029068 A KR20230029068 A KR 20230029068A KR 102552846 B1 KR102552846 B1 KR 102552846B1
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composition
water repellent
net
weight
photocatalyst
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이노열
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(주)에스엔시
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    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/52—Devices affording protection against insects, e.g. fly screens; Mesh windows for other purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0573—Selenium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/002—Catalysts characterised by their physical properties
    • B01J35/004—Photocatalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D9/00—Open-work fabrics
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/52—Devices affording protection against insects, e.g. fly screens; Mesh windows for other purposes
    • E06B2009/524—Mesh details

Abstract

본 발명은 에어디톡스 기능을 가지는 광촉매조성물을 코팅한 외면에 발수작용을 하는 발수제 조성물을 추가 코팅되어 미세먼지분해, 항균, 소취, 작용과 더불어 방오작용 까지 하고, 자외선차단과 시인성이 좋은 방충망을 가지는 기능성 알루미늄 창호에 관한 것으로서, 에어디톡스는 제거하다는 의미의 de와 독이란 의미의 tox를 결합시켜서 만든 합성어를 광촉매에 적용시켜 공기 중에 함유된 독소를 제거한다는 의미를 나타내고, 광촉매 작용을 하는 조성물이 코팅된 외면에 발수작용 조성물을 추가코팅한 방충망을 만들어 창호에 설치함으로써, 방충망을 통해 실내에 유입되는 공기중의 미세먼지를 광촉매로 분해정화, 항균, 소취하고, 방충망에 접근하는 오염물을 배척하고, 자가 세척하여 침착을 예방함으로써, 망지의 시인성을 높이고, 자외선 차단까지 하는 기능성 알루미늄 창호이다. In the present invention, a water repellent composition that has a water repellent action is additionally coated on the outer surface coated with a photocatalyst composition having an air detox function, so that it has fine dust decomposition, antibacterial, deodorizing, and antifouling effects, and has an insect screen with excellent UV protection and visibility. As it relates to functional aluminum windows and doors, air detox is a compound word made by combining de meaning to remove and tox meaning poison, and is applied to a photocatalyst to remove toxins contained in the air. By making an insect screen additionally coated with a water-repellent composition on the outer surface of the screen and installing it on the window, fine dust in the air entering the room through the screen is decomposed and purified with a photocatalyst, antibacterial, deodorizing, and pollutants approaching the screen are excluded, It is a functional aluminum window that prevents deposition by self-cleaning, increasing the visibility of netting and even blocking UV rays.

Description

광촉매조성물이 코팅된 외면에 발수제 조성물이 추가로 코팅되어 항균, 소취, 방오 방충망을 형성하는 기능성 알루미늄 창호{Functional aluminum windows that form antibacterial, deodorant, and antifouling screens by additionally coating water repellent composition on the outer surface coated with photocatalytic composition}Functional aluminum windows that form antibacterial, deodorant, and antifouling screens by additionally coating water repellent composition on the outer surface coated with photocatalytic composition}

본 발명은 에어디톡스 기능을 가지는 광촉매조성물을 코팅한 외면에 발수작용을 하는 발수제 조성물을 추가 코팅하여 미세먼지분해, 항균, 소취, 작용과 더불어 방오작용 까지 하고, 자외선차단과 시인성이 좋은 방충망을 가지는 기능성 알루미늄 창호에 관한 것이다. The present invention additionally coats a water repellent composition that has a water repellent action on the outer surface coated with a photocatalyst composition having an air detox function, thereby decomposing fine dust, antibacterial, deodorizing, and antifouling as well as having an insect screen with excellent UV protection and visibility. It is about functional aluminum windows.

에어디톡스는 제거하다는 의미의 de와 독이란 의미의 tox를 결합시켜서 만든 합성어를 광촉매에 적용시켜 공기 중에 함유된 독소를 제거한다는 의미를 나타내고, 광촉매 작용을 하는 조성물이 코팅된 외면에 발수작용 조성물을 추가코팅한 방충망을 만들어 창호에 설치함으로써, 방충망을 통해 실내에 유입되는 공기중의 미세먼지를 광촉매로 분해정화, 항균,소취하고, 방충망에 접근하는 오염물을 배척하고, 자가 세척하여 침착을 예방함으로써, 망지의 시인성을 높이고, 자외선 차단까지 하는 기능성 창호가 되게 한 것이다. Air detox is a compound word made by combining de meaning to remove and tox meaning poison, and is applied to a photocatalyst to denote the removal of toxins contained in the air. By making an additionally coated insect screen and installing it on the window, it decomposes and purifies fine dust in the air that enters the room through the insect screen with a photocatalyst, antibacterially and deodorizes it, rejects contaminants approaching the insect screen, and prevents deposition by self-cleaning. , It was made to be a functional window that enhances the visibility of the screen and even blocks ultraviolet rays.

삭제delete

이건 출원인은 알루미늄 창호 구조물을 개발하여 등록한 발명특허등록 제10-2382278호를 보유하고 있다. The applicant of Lee Geon holds Invention Patent Registration No. 10-2382278 registered by developing an aluminum window structure.

상기 특허는 알루미늄 재질의 창호구조물에 있어서 직선프레임과 모서리프레임을 조립하여 결합하고, 방진망 또는 방충망을 결합함에 있어서, 방진망 또는 방충망이 더 견고하게 결합되어 유지될 수 있도록 하는 알루미늄 창호구조물을 개발한 바 있다.The patent developed an aluminum window structure that allows the dustproof net or insecticide net to be more firmly combined and maintained in assembling and combining the straight frame and the corner frame in the window structure made of aluminum and combining the dustproof net or the insecticide net. there is.

또, 종래의 방충망은 150∼225데니어, 40∼80필라멘트 범위에 있는 저융점 폴리에스텔 필라멘트 합연사를 제1경사와 제2위사로 선택하고, 10∼50 데니어 굵기를 가지는 폴리에스텔 모노필라멘트사를 제2경사와 제2위사로 선택하여, 제2경사와 제2위사를, 제1경사와 제1경사 사이 및 제1위사와 제1위사 사이에 다수개로 배치하여, 망구멍의 크기가 가로세로 0.08∼0.4mm 되게 방충용 망지를 제직하고, 방충용 망지에 이산화티타늄에 텅스텐옥사이드, 백금, 실리카실세스퀴옥산 복합고분자수지에탄올과 물을 넣고 황산을 가열한 것에 과황화칼륨을 넣고, 인산화인을 넣어 녹인 다음 냉각시키고, 흑연을 넣고 반응시킨 후, 증류수로 희석하여 흑연을 걸러내고 그래핀 용액을 넣고 교반하여 만든 광촉매조성물을 코팅하고, 열처리하여 광촉매 작용이 있는 기능성방충망을 개시하고 있으나, 광촉매조성물의 제조가 복잡하여 비용이 많이 드는 불편이 있고, In addition, in the conventional insect screen, a low melting point polyester filament plied yarn in the range of 150 to 225 denier and 40 to 80 filament is selected as the first warp and second weft yarn, and a polyester monofilament yarn having a thickness of 10 to 50 denier is selected. Select the 2nd warp and 2nd weft, arrange the 2nd warp and 2nd weft between the 1st warp and the 1st warp and between the 1st weft and the 1st weft, and the size of the mesh hole is horizontal and vertical Weave an insect repellent netting to be 0.08∼0.4mm, add tungsten oxide, platinum, silica silsesquioxane composite polymer resin ethanol and water to titanium dioxide in the insect repellent net, heat sulfuric acid, add potassium persulfide, phosphorus phosphate After dissolving, cooling, adding graphite and reacting, diluting with distilled water to filter out graphite, coating a photocatalyst composition made by adding graphene solution and stirring, and heat treatment to disclose a functional insect screen with photocatalytic action, but a photocatalyst The preparation of the composition is complicated and expensive, which is inconvenient,

또, 방충망에는 발수작용의 기능이 없어 창호에 설치하면 미세한 방충망에 접근하는 미세먼지등와 오염물질이 쉽게 부착되어 세척이 어렵게 되므로 방충망이 막혀 시인성이 떨어지는 불편을 초래하고 있다. In addition, since the insect screen does not have a water repellent function, when installed on a window or door, fine dust and contaminants approaching the fine insect screen are easily attached, making it difficult to clean, so the insect screen is clogged and visibility is reduced, causing inconvenience.

선행기술 특허등록 제10-2104872호Prior art patent registration No. 10-2104872

본 발명은 상기 불편을 해소하기 위해 개발된 것이다. The present invention was developed to solve the above inconvenience.

본 발명은 150∼225데니어 굵기를 가지는 합성섬유 모노필라멘트사를 제1경사(1)와 제1위사(2)로 선택하고, 10∼50데니어 굵기를 가지는 합성섬유모노필라멘트사를 제2경사(3)와, 제2위사(4)로 선택하여, 망구멍의 가로세로 길이가 0.07∼0.4mm 되게 직조되어 미세먼지 차단기능이 양호한 망지(5)를 제조하고, In the present invention, a synthetic monofilament yarn having a thickness of 150 to 225 denier is selected as the first warp yarn (1) and a first weft yarn (2), and a synthetic fiber monofilament yarn having a thickness of 10 to 50 denier is selected as the second warp yarn ( 3) and the second weft yarn (4) are selected, and the mesh hole is woven so that the length and width of the net hole is 0.07 to 0.4 mm to manufacture a net (5) with good fine dust blocking function,

상기 망지에 1차 광촉매조성물(6)을 코팅하고, 1차광촉매조성물이 코팅된 외면에 발수작용이 있는 발수제조성물(7)을 추가 코팅하여, 망지를 통해 실내로 유입되는 공기의 항균, 소취 정화작용과 미세먼지 또는 오염물의 침착이 방지되는 방오작용을 하는 기능성 방충망(50)을 제조하고, 이를 알루미늄 창호(8)의 망고정홈(8a)에 결합하여, 고정부재(9)와 탄성체 망고정자(10)로 창호에 결합하는 기능성 알루미늄창호를 형성한다. The first photocatalyst composition (6) is coated on the net, and the outer surface coated with the first photocatalyst composition is additionally coated with a water repellent composition (7) having a water repellent action, thereby purifying antibacterial and deodorizing air flowing into the room through the net. Manufacture a functional insect screen 50 that has an antifouling effect and prevents the deposition of fine dust or contaminants, and combines it with the net fixing groove 8a of the aluminum window 8 to form a fixing member 9 and an elastic net fixer (10) to form a functional aluminum window that is bonded to the window.

본 발명에 사용하는 광촉매조성물(6)은 셀레늄졸에 이산화티탄 광촉매제를 결합하여 이루어진다. The photocatalyst composition 6 used in the present invention is made by combining a titanium dioxide photocatalyst with selenium sol.

셀레늄졸은 셀레늄을 질산 70%, 용액 100㎖에 증류수 30㎖를 혼합하여 희질산용액으로 만든 것에 용액의 10중량%에 해당하는 비율로 넣고, 수산화칼륨 30중량%를 넣으면서 교반하여 PH를 8∼9로 되게 제조하고, Selenium sol is prepared by mixing 70% of selenium in nitric acid and 30 ml of distilled water in 100 ml of the solution to make a dilute nitric acid solution, adding 10% by weight of selenium and stirring while adding 30% by weight of potassium hydroxide to adjust the PH to 8-9. It is manufactured to be

산화티탄 3∼4중량%를 혼합하여, 100℃내의 온도에서 10분이내로 가열교반하여 졸형태로 제조한다. It is prepared in the form of a sol by mixing 3 to 4% by weight of titanium oxide and heating and stirring at a temperature of 100° C. within 10 minutes.

이때, 무기질 바인터졸은 셀레늄 함양을 10중량% 범위로 제한하는 것이 바람직하고, At this time, it is preferable to limit the content of selenium in the inorganic binder sol to 10% by weight,

셀레늄졸을 사용함으로써, 도포면에 접착력이 높으면서 투명형태를 이루어 광합성율을 양호하게 할 수 있다.By using selenium sol, it is possible to improve the photosynthesis rate by forming a transparent form while having high adhesion to the coated surface.

본 발명의 발수제조성물(7)은 옥시비스프로판올(OXYBISPROPANOL) 5∼15중량%, The water repellent composition (7) of the present invention contains 5 to 15% by weight of OXYBISPROPANOL,

알파 도데실 오메가 하이드록시 폴리옥시에틸렌 0.1∼5중량%, 0.1 to 5% by weight of alpha dodecyl omega hydroxy polyoxyethylene;

퍼플루오르올킬 아크릴레이트 코포리머(perfluoroalkyl acrylate copolymer) 25∼35중량%, 25 to 35% by weight of a perfluoroalkyl acrylate copolymer,

물 60∼70중량%로 이루어진다.It consists of 60 to 70% by weight of water.

기능성 방충망(50)의 제조 Manufacture of functional insect screen 50

방충망용 망지(5)를 광촉매조성물(6)이 수용된 디핑조(60)에 디핑한 후, 인출하면서 과잉도포물을 압착롤러(61)(62)로 압착하여 일정량이 도포되게 하고, 텐터기(63)에 투입하여, 120∼150℃의 열풍으로 열처리하여 건조시키면서 평탄화 작업함으로써, 광촉매조성물이 코팅된 망지(5a)를 제조하고, 광촉매조성물이 코팅된 망지(5a)를 발수제조성물(7)이 수용된 디핑조(70)에 디핑한 후, 인출하면서 표면에 묻은 과잉 발수조성물을 압착롤러(71)(72)로 압착하여 일정량이 도포되게 하고, 텐터기(73)에 투입하여 120∼150℃의 열풍으로 열처리하여 건조시키면서, 평판화시켜 광촉매조성물이 코팅된 외면에 발수제조성물이 추가 코팅된 기능성 망충망(50)을 제조한다. After dipping the netting for insect screen 5 in the dipping tank 60 containing the photocatalyst composition 6, and then compressing the excess coating material with the compression rollers 61 and 62 while drawing it out, a certain amount is applied, and the tenter machine ( 63), heat treatment with hot air at 120 to 150 ° C., and flattening while drying to prepare the photocatalyst composition-coated netting 5a, and the water-repellent composition 7 After dipping in the accommodated dipping tank 70, the excess water-repellent composition adhered to the surface is compressed with compression rollers 71 and 72 while being withdrawn to apply a certain amount, and put into a tenter 73 to obtain a temperature of 120 to 150 ° C. While drying by heat treatment with hot air, it is flattened to prepare a functional netting net 50 additionally coated with a water repellent composition on the outer surface coated with the photocatalyst composition.

기능성 방충망(50)은 외주연을 알루미늄 창호(8)의 망고정홈(8a)에 투입하여 고정부재(9)로 고정하여 기능성 방충망이 결합된 기능성 알루미늄 창호를 제조한다. The functional insect screen 50 is inserted into the net fixing groove 8a of the aluminum window 8 and fixed with a fixing member 9 to manufacture a functional aluminum window combined with a functional insect screen.

상기에서 망고정홈(8a)은 개방부(8b) 양측에 걸림턱(8c)이 돌출되고, 바닥에 탄성체 망고정자(10)가 개입되며, 망고정홈(8a)에는 내면 양측에 한쌍의 압착돌기(9a)(9b)가 형성된 사이에 망고정자 고정홈(9c)이 형성되어 망고정자(10)를 수용하고, 압착돌기(9a)(9b) 외측단 양측에 망고정홈(8a)의 걸림턱(8c)이 결합하는 걸림홈(9d)이 형성되어 망고정홈(8a)에 강제 결합하는 고정부재(9)에 의하여 망을 고정시킴으로써, 기능성 방충망(50)과 창호가 일체로 결합되는 기능성 창호가 형성되는 구성이다. In the mang fixing groove 8a, locking protrusions 8c protrude on both sides of the opening 8b, the elastic mang fixer 10 is interposed on the bottom, and a pair of compression is provided on both sides of the inner surface of the mang fixing groove 8a. Between the protrusions 9a and 9b, a mango fixing groove 9c is formed to accommodate the mango stator 10, and the mang fixing groove 8a is caught on both sides of the outer ends of the compression protrusions 9a and 9b. A locking groove 9d coupled to the jaw 8c is formed and the net is fixed by the fixing member 9 forcibly coupled to the net fixing groove 8a, so that the functional insect screen 50 and the window are integrally combined. It is the composition of which the window is formed.

이와 같이 된 본 발명은 150∼225데니어 되는 합성섬유 모노필라멘트섬유를 제1경사와 제1위사로 하고, 10∼50데니어 굵기를 가지는 합성섬유모노필라멘트사를 제2경사와 제2위사로 선택하여 망지를 제조함으로써, 망구멍의 크기가 0.07∼0.4mm 되는 망지(5)를 직조할 수 있고, Thus, the present invention uses synthetic monofilament fibers of 150 to 225 denier as the first warp and first weft yarns, and selects synthetic monofilament yarns having a thickness of 10 to 50 denier as the second warp yarn and the second weft yarn. By manufacturing netting, it is possible to weave netting 5 having a net hole size of 0.07 to 0.4 mm,

상기 망지에 광촉매조성물(6)를 1차코팅하고, 광촉매조성물이 코팅된 외면에 다시 발수기능을 가지는 발수제조성물(7)을 2차코팅하였기 때문에, 망지에는 광촉매조성물과 발수제조성물을 이중으로 코팅되어 광촉매조성물에 의하여 망지에 접촉하는 공기중의 미세먼지를 분해하여 정화하고, 미세먼지에 포함된 냄새를 소취하며, 항균작용을 하게 되고, 추가로 코팅된 발수제조성물의 발수작용으로 망지에 접촉하는 미세먼지를 배척하고, 자가세척을 하므로 오염물의 침착을 방지하여 망구멍의 막힘을 해소하므로, 공기소통이 원활하고, 실내에서 밖을 볼 때, 시인성이 확립되는 이점을 얻을 수 있고, 망지의 색상으로 자외선을 차단하므로, 미세먼지분해,정화, 소취와 자가세척과 자외선차단, 항오염, 시인성확보의 작용을 입체적으로 수행할 수 있는 이점이 있으며, 방충망지를 알루미늄 창호에 결합할 때, 망고정홈(8a)에 탄성체 망고정자(10)를 개입시키고, 망지의 외주를 망고정홈(8a)에 끼운 후, 고정부재(9)를 강제 결합시키면, 고정부재(9)의 걸림홈(9d)에 망고정홈(8a)의 걸림턱(8c)이 결합되고, 망고정자고정홈(9e)에 망고정자(10)와 방충망이 결합하여 이완이 방지되므로, 내구적인 망고정이 이루어져, 알루미늄 창호의 기능이 개선되는 효과를 얻을 수 있다. Since the photocatalyst composition 6 is first coated on the net, and the water repellent composition 7 having a water repellent function is secondarily coated on the outer surface coated with the photocatalyst composition, the net is double coated with the photocatalyst composition and the water repellent composition The photocatalyst composition decomposes and purifies fine dust in the air that comes in contact with the netting, deodorizes the odor contained in the fine dust, and has an antibacterial action. Since it removes dust and self-cleans, it prevents deposition of contaminants and eliminates clogging of the net hole, so it is possible to obtain the advantages of smooth air communication and visibility when looking outside from the inside, and the color of the net Since it blocks ultraviolet rays, it has the advantage of being able to perform the action of fine dust decomposition, purification, deodorization, self-cleaning, UV blocking, anti-pollution, and securing visibility in three dimensions, and when combining the insect screen with aluminum windows, the net fixing groove ( 8a) is intervened with the elastic net anchor 10, the outer circumference of the net is inserted into the net fixing groove 8a, and then the fixing member 9 is forcibly coupled to the locking groove 9d of the fixing member 9. The locking jaw 8c of the fixing groove 8a is combined, and the mang stator 10 and the insect screen are combined with the mang stator fixing groove 9e to prevent loosening, so that the mang fixation is durable and the function of aluminum windows is improved. effect can be obtained.

도 1은 본 발명의 망지 구성도
도 2는 본 발명의 방충망 단면도
도 3은 본 발명의 방충망 구성도
도 4는 본 발명의 망지에 광촉매조성물을 코팅하는 예시도
도 5는 본 발명의 망지에 발수제조성물을 코팅하는 예시도
도 6은 본 발명 알루미늄창틀의 망고정홈 구성도
도 7은 본 발명의 기능성 방충망이 알루미늄창호에 결합된 단면도이다. 1 is a network configuration diagram of the present invention
2 is a cross-sectional view of the insect screen of the present invention
3 is a block diagram of the insect screen of the present invention
Figure 4 is an exemplary view of coating the photocatalyst composition on the net of the present invention
Figure 5 is an exemplary view of coating the water repellent composition on the net of the present invention
Figure 6 is a network fixing groove configuration diagram of the aluminum window frame of the present invention
7 is a cross-sectional view of the functional insect screen of the present invention coupled to aluminum windows and doors.

본 발명은 150∼225데니어 굵기를 가지는 합성섬유 모노필라멘트사를 제1경사(1)와 제1위사(2)로 선택하고, 10∼50데니어 굵기를 가지는 합성섬유모노필라멘트사를 제2경사(3)와, 제2위사(4)로 선택하여 망구멍(5')의 가로세로 길이가 0.07∼0.4mm 되게 직조되어 미세먼지 차단기능이 양호한 망지(5)를 제조하고, In the present invention, a synthetic monofilament yarn having a thickness of 150 to 225 denier is selected as the first warp yarn (1) and a first weft yarn (2), and a synthetic fiber monofilament yarn having a thickness of 10 to 50 denier is selected as the second warp yarn ( 3) and the second weft yarn (4) are selected and weaved so that the vertical and horizontal length of the net hole (5') is 0.07 to 0.4 mm to manufacture a netting (5) with good fine dust blocking function,

상기 망지에 1차 광촉매조성물(6)을 코팅하고, 광촉매조성물이 코팅된 외면에 발수작용이 있는 발수제조성물(7)을 코팅하여 망지를 통해 실내로 유입되는 공기의 항균, 소취 정화작용과 미세먼지 또는 오염물의 침착이 방지되는 방오작용을 하는 기능성 방충망(50)을 제조하고, 이를 알루미늄 창호(8)의 망고정홈(8a)에 결합하여, 고정부재(9)와 탄성체 망고정자(10)로 창호에 결합되는 기능성 알루미늄 창호를 형성한다. The first photocatalyst composition (6) is coated on the net, and the water repellent composition (7) having a water repellent action is coated on the outer surface coated with the photocatalyst composition to provide antibacterial, deodorant and purifying action of air flowing into the room through the net and fine dust. Alternatively, a functional insect screen 50 having an antifouling effect that prevents deposition of contaminants is manufactured, and it is combined with the net fixing groove 8a of the aluminum window 8 to form a fixing member 9 and an elastic net fixator 10. It forms functional aluminum windows and doors that are combined with windows and doors.

본 발명에 사용하는 광촉매조성물(6)은 셀레늄졸에 이산화티탄 광촉매제를 결합하여 이루어진다. The photocatalyst composition 6 used in the present invention is made by combining a titanium dioxide photocatalyst with selenium sol.

셀레늄졸은 셀레늄을 질산 70%, 용액 100㎖에 증류수 30㎖를 혼합하여 희질산용액으로 만든 것에 용액의 10중량%에 해당하는 비율로 넣고, 수산화칼륨 30중량%를 넣으면서 교반하여 PH를 8∼9로 조성하고, Selenium sol is prepared by mixing 70% of selenium in nitric acid and 30 ml of distilled water in 100 ml of the solution to make a dilute nitric acid solution, adding 10% by weight of selenium and stirring while adding 30% by weight of potassium hydroxide to adjust the PH to 8-9. made up of,

산화티탄 3∼4중량%를 혼합하여, 100℃내의 온도에서 10분이내로 가열교반하여 졸형태로 제조한다. It is prepared in the form of a sol by mixing 3 to 4% by weight of titanium oxide and heating and stirring at a temperature of 100° C. within 10 minutes.

이때, 무기질 바인더인 셀레늄졸은 셀레늄 함양을 10중량% 범위로 제한하는 것이 바람직하고, At this time, it is preferable to limit the content of selenium in the inorganic binder selenium sol to 10% by weight,

셀레늄졸을 사용함으로써, 도포면에서의 응착력이 높으면서 투명형태를 이루어 산화티탄의 광합성율을 양호하게 할 수 있다.By using selenium sol, it is possible to improve the photosynthetic rate of titanium oxide by forming a transparent form while having high adhesion on the coated surface.

본 발명의 발수제조성물(7)은
옥시비스프로판올(OXYBISPROPANOL) 5∼15중량%, The water repellent composition (7) of the present invention
5 to 15% by weight of oxybispropanol (OXYBISPROPANOL),

알파 도데실 오메가 하이드록시 폴리옥시에틸렌 0.1∼5중량%, 0.1 to 5% by weight of alpha dodecyl omega hydroxy polyoxyethylene;

퍼플루오르올킬 아크릴레이트 코포리머(perfluoroalkyl acrylate copolymer) 25∼35중량%, 25 to 35% by weight of a perfluoroalkyl acrylate copolymer,

물 60∼70중량%로 이루어진다. It consists of 60 to 70% by weight of water.

기능성 방충망(50)의 제조 Manufacture of functional insect screen 50

방충망용 망지(5)를 광촉매조성물(6)이 수용된 디핑조(60)에 디핑한 후, 인출하면서 과잉도포물을 압착롤러(61)(62)로 압착하여 일정량이 도포되게 하고, 텐터기(63)에 투입하여, 120∼150℃의 열풍으로 열처리하여 건조시키면서 평탄화 작업함으로써, 광촉매조성물이 코팅된 망지(5a)를 제조하고, 광촉매조성물이 코팅된 망지(5a)를 발수제조성물(7)이 수용된 디핑조(70)에 디핑한 후, 인출하면서 표면에 묻은 과잉발수제조성물을 압착롤러(71)(72)로 압착하여 일정량이 도포되게 하고, 텐터기(73)에 투입하여 조성물이 코팅된 외면에 120∼150℃의 열풍으로 열처리하여 건조시키면서, 평판화시켜 광촉매 위에 발수제조성물이 추가 코팅된 기능성 망충망(50)을 제조한다. After dipping the netting for insect screen 5 in the dipping tank 60 containing the photocatalyst composition 6, and then compressing the excess coating material with the compression rollers 61 and 62 while drawing it out, a certain amount is applied, and the tenter machine ( 63), heat treatment with hot air at 120 to 150 ° C., and flattening while drying to prepare the photocatalyst composition-coated netting 5a, and the water-repellent composition 7 After dipping in the accommodated dipping tank 70, the excess water-repellent agent composition adhered to the surface is compressed with the pressure rollers 71 and 72 while drawing out to apply a certain amount, and put into the tenter 73 so that the outer surface coated with the composition While drying by heat treatment with hot air at 120 to 150 ° C., flattening is performed to prepare a functional netting net 50 additionally coated with a water repellent composition on the photocatalyst.

기능성 방충망(50)은 외주연을 알루미늄 창호(8)의 망고정홈(8a)에 투입하여 고정부재(9)로 고정하여 기능성 방충망이 결합된 기능성 알루미늄 창호로 제조한다. The functional insect screen 50 is manufactured by inserting the outer periphery into the net fixing groove 8a of the aluminum window 8 and fixing it with a fixing member 9 to form a functional aluminum window combined with a functional insect screen.

상기에서 망고정홈(8a)은 개방부(8b) 양측에 걸림턱(8c)이 대향 돌출되고, 망고정홈 바닥에 탄성체 망고정자(10)가 개입되며, 망고정홈(8a)에는 내면 양측에 한쌍의 압착돌기(9a)(9b)가 형성된 사이에 망고정자 고정홈(9c)이 형성되어, 망고정자(10)를 수용하고, 압착돌기(9a)(9b) 외측단 양측에 망고정홈(8a)의 걸림턱(8c)이 결합하는 걸림홈(9d)이 형성되어 망고정홈(8a)에 강제 결합하는 고정부재(9)에 의하여 망을 고정시킴으로써, 기능성 방충망(50)과 창호가 일체로 결합되는 기능성 창호가 형성되는 구성이다. In the above mang fixing groove 8a, locking protrusions 8c protrude from both sides of the opening 8b, the elastic mang stator 10 intervenes at the bottom of the mang fixing groove, and both sides of the inner surface of the mang fixing groove 8a. A mangap fixing groove 9c is formed between a pair of crimping protrusions 9a and 9b to accommodate the mang stator 10, and a mang fixing groove on both sides of the outer ends of the crimping protrusions 9a and 9b. A locking groove 9d coupled to the locking jaw 8c of (8a) is formed and the net is fixed by the fixing member 9 forcibly coupled to the net fixing groove 8a, so that the functional insect screen 50 and the window It is a configuration in which functional windows and doors that are integrally combined are formed.

1 : 제1경사 2 : 제1위사
3 : 제2경사 4 : 제2위사
5 : 망지 5' : 망구멍
5a : 망지 6 : 광촉매조성물
7 : 발수제조성물 8 : 알루미늄 창호
8a : 망고정홈 8b : 개방부
8c : 걸림턱 9 : 고정부재
9a,9b : 압착돌기 9c : 고정홈
9d : 걸림홈 10 : 탄성체 망고정자
50 : 기능성 방충망 60 : 디핑조
61,62 : 압착롤러 63 : 텐터기
70 : 디핑조 71,72 : 압착롤러
73 : 텐터기1: 1st warp 2: 1st weft
3: 2nd warp 4: 2nd weft
5: net 5': net hole
5a: net 6: photocatalytic composition
7: water repellent composition 8: aluminum windows
8a: mang fixing groove 8b: opening
8c: locking jaw 9: fixing member
9a, 9b: compression projection 9c: fixing groove
9d: hooking groove 10: elastic mango fixer
50: functional insect screen 60: dipping tank
61,62: compression roller 63: tenter
70: dipping jaw 71,72: compression roller
73: tenter

Claims (4)

150∼225데니어 굵기를 가지는 합성섬유 모노필라멘트사를 제1경사(1)와 제1위사(2)로 선택하고, 10∼50데니어 굵기를 가지는 합성섬유모노필라멘트사를 제2 경사(3)와, 제2위사(4)로 선택하여 망구멍(5')의 가로세로 길이가 0.07∼0.4mm 되게 직조한 망지(5)를 형성하여,
상기 망지(5)에 광촉매조성물(6)을 코팅하고, 광촉매조성물이 코팅된 외면에 발수제조성물(7)을 추가 코팅함으로써, 망지(5)를 통해 실내로 유입되는 공기의 정화, 항균, 소취 작용과 더불어 미세먼지 또는 오염물이 망지에 침착되는 것을 방지하도록 한 기능성 방충망(50)을 형성하고,
광촉매조성물(6)은 셀레늄졸에 이산화티탄 광촉매제를 결합하여 이루어지고,
상기 셀레늄졸은 셀레늄을 질산 70%, 용액 100㎖에 증류수 30㎖를 혼합하여 희질산용액으로 만든 것에 용액의 10중량%에 해당하는 비율로 넣고, 수산화칼륨 30중량%를 넣으면서 교반하여 PH를 8∼9로 조정하면서 산화티탄 3∼4중량%를 혼합하고, 100℃ 내의 온도에서 10분이내로 가열교반하여 졸형태로 제조한 것을 선택하고,
발수제 조성물(7)은
옥시비스프로판올(OXYBISPROPANOL) 5∼15중량%,
알파 도데실 오메가 하이드록시 폴리옥시에틸렌 0.1∼5중량%,
퍼플루오르올킬 아크릴레이트 코포리머(perfluoroalkyl acrylate copolymer) 25∼35중량%,
물 60∼70중량%로 이루어지는 것을 선택하여 코팅함으로써, 망지에 형성된 광촉매조성물과 발수제조성물에 의거 항균, 소취와 더불어 방오기능을 가지는 방충망이 형성되고,
알루미늄창호(8)에 형성되는 망고정홈(8a)은 개방부(8b)의 입구측에 서로 마주보는 걸림턱(8c)을 대향돌출시키고, 망고정홈 바닥에 탄성체 망고정자(10)를 개입시키며, 망고정홈(8a)에는 내면 양측에 한쌍의 압착돌기(9a)(9b)가 형성된 사이에 망고정자 고정홈(9c)이 형성되고, 압착돌기(9a)(9b) 외측단 양측에 망고정홈(8a)의 걸림턱(8c)이 결합되는 걸림홈(9d)을 형성한 고정부재(9)를 갖추어서 기능성 방충망(50)을 알루미늄창호(8)에 고정할 수 있게 구성한 광촉매조성물이 코팅된 외면에 발수제 조성물이 추가로 코팅되어 항균, 소취, 방오 방충망을 형성하는 기능성 알루미늄 창호.
A synthetic fiber monofilament yarn having a thickness of 150 to 225 denier is selected as the first warp yarn (1) and a first weft yarn (2), and a synthetic fiber monofilament yarn having a thickness of 10 to 50 denier is selected as the second warp yarn (3) and the second warp yarn (3). , By selecting the second weft yarn (4) to form a mesh (5) woven so that the vertical and horizontal length of the net hole (5') is 0.07 to 0.4 mm,
By coating the photocatalyst composition 6 on the netting paper 5 and additionally coating the water repellent composition 7 on the outer surface coated with the photocatalyst composition, the air introduced into the room through the netting paper 5 acts as a purifier, antibacterial, and deodorizing. In addition, to form a functional insect screen 50 to prevent fine dust or contaminants from being deposited on the net,
The photocatalyst composition 6 is made by combining a titanium dioxide photocatalyst with selenium sol,
The selenium sol is prepared by mixing 70% of selenium with nitric acid and 30 ml of distilled water in 100 ml of the solution to make a dilute nitric acid solution, which is added at a rate corresponding to 10% by weight of the solution, and stirred while adding 30% by weight of potassium hydroxide to adjust the PH to 8-8. While adjusting to 9, 3 to 4% by weight of titanium oxide was mixed and heated and stirred within 10 minutes at a temperature of 100 ° C. to select one prepared in the form of a sol,
The water repellent composition (7) is
5 to 15% by weight of oxybispropanol (OXYBISPROPANOL),
0.1 to 5% by weight of alpha dodecyl omega hydroxy polyoxyethylene;
25 to 35% by weight of a perfluoroalkyl acrylate copolymer,
By selecting and coating one composed of 60 to 70% by weight of water, an insect screen having antibacterial and deodorizing and antifouling functions based on the photocatalyst composition and the water repellent composition formed on the net is formed,
In the mang fixing groove (8a) formed in the aluminum window (8), the locking jaws (8c) facing each other protrude from the entrance side of the opening (8b), and the elastic mang fixator (10) intervenes at the bottom of the mang fixing groove. In the mang fixing groove 8a, a mang fixer fixing groove 9c is formed between a pair of crimping protrusions 9a and 9b formed on both sides of the inner surface, and a net stator fixing groove 9c is formed on both sides of the outer ends of the crimping protrusions 9a and 9b. A photocatalyst composition having a fixing member 9 having a locking groove 9d to which the locking jaw 8c of the fixing groove 8a is coupled so that the functional insect screen 50 can be fixed to the aluminum window 8 A functional aluminum window that is additionally coated with a water repellent composition on the coated outer surface to form an antibacterial, deodorant, and antifouling insect screen.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020087277A (en) * 2001-05-15 2002-11-22 주식회사 엔바이오니아 Photocatalytic composition having functions of air purification and antimicrobial activity and a moth-proof net coated with the composition
KR20110133377A (en) * 2010-06-04 2011-12-12 김민경 Insect net having yellow sand excluding function
KR20150126801A (en) * 2015-10-28 2015-11-13 (주) 텍스토머 Fiber mesh fixing apparatus for safety and prevention of falling
KR102104872B1 (en) 2020-02-06 2020-04-27 신영두 a screen for blocking fine dust with anti-bacterial, purifying and odor-prevention

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020087277A (en) * 2001-05-15 2002-11-22 주식회사 엔바이오니아 Photocatalytic composition having functions of air purification and antimicrobial activity and a moth-proof net coated with the composition
KR20110133377A (en) * 2010-06-04 2011-12-12 김민경 Insect net having yellow sand excluding function
KR20150126801A (en) * 2015-10-28 2015-11-13 (주) 텍스토머 Fiber mesh fixing apparatus for safety and prevention of falling
KR102104872B1 (en) 2020-02-06 2020-04-27 신영두 a screen for blocking fine dust with anti-bacterial, purifying and odor-prevention

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