KR102538512B1 - Composition for coating agent of incombustible panel board comprising bio-ceramic powder and ceramic binder as effective component and manufacturing method of incombustible panel board using the same - Google Patents
Composition for coating agent of incombustible panel board comprising bio-ceramic powder and ceramic binder as effective component and manufacturing method of incombustible panel board using the same Download PDFInfo
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Abstract
본 발명은 바이오 세라믹 분말 및 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅제 조성물 및 이를 이용하는 불연성 판넬 보드의 제조방법에 관한 것으로, 본 발명의 제조방법에 따라 제조된 불연성 판넬은 착화가 잘되지 않고, 착화되더라도 연소 확대가 잘 되지 않는 효과가 있는 것이다.The present invention relates to a coating composition for a non-combustible eco-friendly panel board containing bioceramic powder and a ceramic binder as active ingredients and a method for manufacturing a non-combustible panel board using the same. It does not, and even if it is ignited, there is an effect that the expansion of combustion does not work well.
Description
본 발명은 바이오 세라믹 분말 및 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅제 조성물 및 이를 이용하는 불연성 판넬 보드의 제조방법에 관한 것이다.The present invention relates to a coating agent composition for a non-flammable eco-friendly panel board containing bio-ceramic powder and a ceramic binder as active ingredients and a method for manufacturing a non-flammable panel board using the same.
세라믹(ceramic)은 무기물질이 주원료인 산화물(oxide), 질화물(nitride), 탄화물(carbide) 등의 재료를 의미한다. 이러한 재료들은 금속재료, 유기재료에 비하여 내식성, 내열성, 내마모성 등이 매우 크며, 광학적 기능, 생체적 기능, 전자기적 기능, 기계적 기능 등의 다양한 기능을 갖는다고 알려져 있다. 따라서, 시멘트, 유리, 법랑, 내화물, 단열재, 건축용 점토제품, 도자기, 유리섬유 등 우리 주변에서 흔히 볼 수 있는 제품은 물론, 컴퓨터의 기억 소자, 반도체, 특수 무기 제품, 초전도 제품 등 첨단 제품의 주재료로 사용되고 있다.Ceramic refers to materials such as oxide, nitride, and carbide, of which inorganic materials are the main raw materials. These materials are known to have very high corrosion resistance, heat resistance, and abrasion resistance compared to metal materials and organic materials, and to have various functions such as optical, biological, electromagnetic, and mechanical functions. Therefore, it is a main material for high-tech products such as computer memory devices, semiconductors, special weapons products, and superconducting products, as well as products commonly seen around us, such as cement, glass, enamel, refractories, insulation materials, building clay products, ceramics, and glass fibers. is being used as
특히, 세라믹은 종류에 따라 열을 가하게 되면 전자파의 일종인 원적외선이 방출된다고 알려지고 있어 이를 이용하여 원적외선을 방출하는 세라믹을 함유함으로써 건강이 증진되도록 제조된 의복, 세라믹이 함유되어 원적외선이 방출되는 파스, 세라믹을 함유한 찜질용 매트 등 세라믹의 원적외선 방출을 이용한 제품들이 개발되고 있다. In particular, it is known that far-infrared rays, a type of electromagnetic wave, are emitted when heat is applied to certain types of ceramics. Clothing manufactured to improve health by containing ceramics that emit far-infrared rays, and pas containing ceramics that emit far-infrared rays Products using far-infrared ray emission from ceramics, such as steam mats containing ceramics, are being developed.
또한, 세라믹은 항균 제품에도 이용이 되고 있는데, 세라믹을 이용한 항균 제품의 경우, 항균력이 그다지 높지 않다는 단점이 있다. 따라서, 원적외선 방출이나 음이온 방출 효과 및 강력한 항균 효과를 갖고 있을 뿐만 아니라, 보다 다양한 기능을 갖는 세라믹 제품에 대한 요구가 높아지고 있다.In addition, ceramics are also used in antibacterial products, but in the case of antibacterial products using ceramics, there is a disadvantage that the antimicrobial activity is not very high. Therefore, there is an increasing demand for ceramic products having far-infrared ray emission, negative ion emission effects, and strong antibacterial effects as well as more diverse functions.
게다가 환풍 및 환기가 잘 되지 않는 집은 벽면에 곰팡이가 생기게 되는데 홈인테리어나 거실 또는 방 벽체에 적용되어 곰팡이 생성을 방지하고 탈취 기능을 나타내는 제품은 거의 전무한 실정이며, 실내 인테리어에 많이 사용되고 있는 인조 대리석은 화재에 취약한 부분이 있는데, 이를 보완하여 화재 예방에 도움이 되는 인조 대리석의 개발도 요구되고 있다. In addition, mold is formed on the walls of houses with poor ventilation and ventilation. There are almost no products that prevent mold formation and deodorize when applied to walls of home interiors, living rooms, or rooms. There is a part that is vulnerable to fire, and the development of artificial marble to help prevent fire by supplementing this is also required.
또한, 건축물의 내부를 구성하는 내외장재는 화재시 직접 노출되어 제일 먼저 착화 및 연소 확대되는 주요 매체이기 때문에, 이들 내외장재는 착화가 잘되지 않고 착화되더라도 연소 확대가 잘 되지 않도록 난연화된 제품들로 사용하여야 한다. 예컨대, 난연화된 제품으로 가장 많이 사용되는 종류로는 유리섬유와 석면 등이 있는데, 유리섬유, 석면 및 암면은 난연 1등급으로 분류되긴 하지만 화재 발생시 높은 온도의 화염에는 지속적으로 견디지 못하고 용융하게 된다. 즉 유리섬유의 경우에는 시간이 경과함에 따라 화염의 온도가 상승하여 화재에 견딜 수 있는 한계 초과로 공기 중에 비산되어 호흡기를 통해 인체에 흡입되는 문제점이 있으며, 석면의 경우에는 건축용 자재의 충진재로 주로 사용됨에도 불구하고 시간이 지남에 따라 균열된 틈 사이로 비산되어 먼지와 함께 호흡기로 침투해 암을 유발하는 문제점이 있다.In addition, since the interior and exterior materials constituting the interior of a building are directly exposed in the event of a fire and are the main media that ignite and expand combustion first, these interior and exterior materials are used as flame retardant products so that ignition does not occur well and combustion does not spread well even if ignited. shall. For example, the most commonly used types of flame retardant products include glass fiber and asbestos. Although glass fiber, asbestos, and rock wool are classified as first-class flame retardants, they cannot withstand high-temperature flames in the event of a fire and melt. . That is, in the case of glass fiber, the temperature of the flame rises over time, and it is scattered in the air beyond the limit that can withstand fire and is inhaled into the human body through the respiratory system. In the case of asbestos, it is mainly used as a filler for building materials. Despite being used, there is a problem in that it is scattered through cracks over time and penetrates into the respiratory tract along with dust, causing cancer.
한편, 한국등록특허 제2104627호에 기능성 세라믹 블록의 제조방법 및 이에 의해 제조된 기능성 세라믹 블록에 대해 개시되어 있고, 한국등록특허 제0554718호에 불연성과 내열성을 동시에 구비하도록 하는 점토류 광물을 이용한 불연성 내열판넬 및 그 제조방법이 개시되어 있으나, 아직까지는 본 발명의 바이오 세라믹 분말 및 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅제 조성물 및 이를 이용하는 불연성 판넬 보드의 제조방법에 대해 개시된 바 없다. On the other hand, Korean Patent No. 2104627 discloses a method for manufacturing a functional ceramic block and a functional ceramic block produced thereby, and Korean Patent No. 0554718 discloses a non-combustible method using clay minerals to provide both non-combustibility and heat resistance. Although a heat-resistant panel and a method for manufacturing the same have been disclosed, a coating composition for a non-flammable eco-friendly panel board containing the bioceramic powder and a ceramic binder of the present invention as active ingredients and a method for manufacturing a non-flammable panel board using the same have not been disclosed yet.
본 발명은 상기와 같은 요구에 의해 도출된 것으로서, 본 발명은 바이오 세라믹 분말 및 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅제 조성물 및 이를 이용하는 불연성 판넬 보드의 제조방법을 제공하고, 본 발명의 제조방법에 따라 제조된 시험체(불연성 보드)는 착화가 잘되지 않고, 착화되더라도 연소 확대가 잘 되지 않는다는 것을 확인함으로써, 본 발명을 완성하였다.The present invention has been derived from the above needs, and the present invention provides a coating agent composition for a non-flammable eco-friendly panel board containing bio-ceramic powder and a ceramic binder as active ingredients and a method for manufacturing a non-flammable panel board using the same, and the present invention The present invention was completed by confirming that the test body (non-combustible board) manufactured according to the manufacturing method did not ignite well, and even if ignited, the expansion of combustion did not work well.
상기 목적을 달성하기 위하여, 본 발명은 (1) Na2O 100 중량부에 대하여, 300~350 중량부의 SiO2, 0.02~0.08 중량부의 MgO, 0.3~0.9 중량부의 Al2O3, 0.1~0.4 중량부의 SO3, 0.3~0.7 중량부의 Cl, 0.07~0.11 중량부의 K2O, 0.01~0.05 중량부의 CaO, 0.05~0.3 중량부의 TiO2, 0.1~0.5 중량부의 Fe2O3, 0.005~0.015 중량부의 ZnO 및 0.005~0.015 중량부의 ZrO2를 포함하는 액상 바이오 세라믹을 가열하여 발포시키는 단계; 및In order to achieve the above object, the present invention (1) Na 2 O 100 parts by weight, 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , 0.1 to 0.4 parts by weight of SO 3 , 0.3 to 0.7 parts by weight of Cl, 0.07 to 0.11 parts by weight of K 2 O, 0.01 to 0.05 parts by weight of CaO, 0.05 to 0.3 parts by weight of TiO 2 , 0.1 to 0.5 parts by weight of Fe 2 O 3 , 0.005 to 0.015 parts by weight heating and foaming a liquid bio-ceramic containing part of ZnO and 0.005 to 0.015 part by weight of ZrO 2 ; and
(2) 상기 단계 (1)에서 발포시켜 고체화된 바이오 세라믹을 분말화하는 단계;를 포함하는 제조방법으로 제조된 바이오 세라믹 분말과, 불연성 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅제 조성물을 제공한다.(2) Powdering the solidified bioceramic by foaming in step (1); coating agent composition for a nonflammable, eco-friendly panel board containing bioceramic powder prepared by a manufacturing method including, and a nonflammable ceramic binder as an active ingredient. provides
또한, 본 발명은 (1) 화학 조성이 Na2O 100 중량부에 대하여, 300~350 중량부의 SiO2, 0.02~0.08 중량부의 MgO, 0.3~0.9 중량부의 Al2O3, 0.1~0.4 중량부의 SO3, 0.3~0.7 중량부의 Cl, 0.07~0.11 중량부의 K2O, 0.01~0.05 중량부의 CaO, 0.05~0.3 중량부의 TiO2, 0.1~0.5 중량부의 Fe2O3, 0.005~0.015 중량부의 ZnO 및 0.005~0.015 중량부의 ZrO2인 액상 바이오 세라믹을 제조하는 단계; In the present invention, (1) the chemical composition is 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , and 0.1 to 0.4 parts by weight, based on 100 parts by weight of Na 2 O. SO 3 , 0.3 to 0.7 parts by weight of Cl, 0.07 to 0.11 parts by weight of K 2 O, 0.01 to 0.05 parts by weight of CaO, 0.05 to 0.3 parts by weight of TiO 2 , 0.1 to 0.5 parts by weight of Fe 2 O 3 , 0.005 to 0.015 parts by weight of ZnO and 0.005 to 0.015 parts by weight of ZrO 2 preparing a liquid bio-ceramic;
(2) 상기 단계 (1)에서 제조한 액상 바이오 세라믹을 내열 코팅된 용기에서 200~400℃의 온도로 3~25분 동안 가열하여 발포시켜 고체로 변화시키는 단계;(2) heating the liquid bio-ceramic prepared in step (1) at a temperature of 200 to 400 ° C. for 3 to 25 minutes in a heat-resistant coated container to foam it and change it into a solid;
(3) 상기 단계 (2) 이후에, 고체의 바이오 세라믹을 분말화하는 단계;(3) after step (2), powdering the solid bio-ceramic;
(4) 상기 단계 (3) 이후에, 바이오 세라믹 분말에 불연성 세라믹 바인더를 첨가하여 혼합하는 단계; 및(4) adding a nonflammable ceramic binder to the bio-ceramic powder and mixing it after step (3); and
(5) 상기 단계 (4)의 혼합물을 판넬 보드에 압착하여 코팅시키는 단계;를 포함하는 불연성 친환경 판넬 보드의 제조방법을 제공한다.(5) compressing and coating the mixture of step (4) on the panel board;
또한, 본 발명은 상기 제조방법으로 제조된 불연성 친환경 판넬 보드를 제공한다.In addition, the present invention provides a non-flammable eco-friendly panel board manufactured by the above manufacturing method.
본 발명은 바이오 세라믹 분말 및 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅제 조성물 및 이를 이용하는 불연성 판넬 보드의 제조방법에 관한 것으로, 본 발명의 제조방법에 따라 제조된 불연성 보드(시험체)는 착화가 잘되지 않고, 착화되더라도 연소 확대가 잘 되지 않는 효과가 있는 것이다.The present invention relates to a coating composition for a non-combustible eco-friendly panel board containing bioceramic powder and a ceramic binder as active ingredients and a method for manufacturing a non-combustible panel board using the same. Ignition is not good, and even if it is ignited, there is an effect that the expansion of combustion is not good.
도 1은 본 발명의 제조방법으로 제조된 불연성 친환경 판넬 보드 시험체의 사진이다.1 is a photograph of a non-flammable eco-friendly panel board test specimen manufactured by the manufacturing method of the present invention.
본 발명은 바이오 세라믹 분말과 불연성 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅제 조성물에 관한 것이며, 구체적으로는 The present invention relates to a coating composition for a non-flammable eco-friendly panel board containing bioceramic powder and a non-flammable ceramic binder as active ingredients, specifically,
(1) Na2O 100 중량부에 대하여, 300~350 중량부의 SiO2, 0.02~0.08 중량부의 MgO, 0.3~0.9 중량부의 Al2O3, 0.1~0.4 중량부의 SO3, 0.3~0.7 중량부의 Cl, 0.07~0.11 중량부의 K2O, 0.01~0.05 중량부의 CaO, 0.05~0.3 중량부의 TiO2, 0.1~0.5 중량부의 Fe2O3, 0.005~0.015 중량부의 ZnO 및 0.005~0.015 중량부의 ZrO2를 포함하는 액상 바이오 세라믹을 가열하여 발포시키는 단계; 및(1) Based on 100 parts by weight of Na 2 O , 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , 0.1 to 0.4 parts by weight of SO 3 , 0.3 to 0.7 parts by weight Cl, 0.07-0.11 parts by weight K 2 O, 0.01-0.05 parts by weight CaO, 0.05-0.3 parts by weight TiO 2 , 0.1-0.5 parts by weight Fe 2 O 3 , 0.005-0.015 parts by weight ZnO and 0.005-0.015 parts by weight ZrO 2 Foaming by heating a liquid bio-ceramic comprising; and
(2) 상기 단계 (1)에서 발포시켜 고체화된 바이오 세라믹을 분말화하는 단계;를 포함하는 제조방법으로 제조된 바이오 세라믹 분말과, 불연성 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅제 조성물에 관한 것이다.(2) Powdering the solidified bioceramic by foaming in step (1); coating agent composition for a nonflammable, eco-friendly panel board containing bioceramic powder prepared by a manufacturing method including, and a nonflammable ceramic binder as an active ingredient. It is about.
본 발명의 제조단계 (1)에서 제조하는 액상 바이오 세라믹의 바람직한 화학 조성은 Na2O 100 중량부에 대하여, 300~350 중량부의 SiO2, 0.02~0.08 중량부의 MgO, 0.3~0.9 중량부의 Al2O3, 0.1~0.4 중량부의 SO3, 0.3~0.7 중량부의 Cl, 0.07~0.11 중량부의 K2O, 0.01~0.05 중량부의 CaO, 0.05~0.3 중량부의 TiO2, 0.1~0.5 중량부의 Fe2O3, 0.005~0.015 중량부의 ZnO 및 0.005~0.015 중량부의 ZrO2를 포함하는 것이며, A preferred chemical composition of the liquid bioceramic prepared in the manufacturing step (1) of the present invention is 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, and 0.3 to 0.9 parts by weight of Al 2 based on 100 parts by weight of Na 2 O . O 3 , 0.1 to 0.4 parts by weight of SO 3 , 0.3 to 0.7 parts by weight of Cl, 0.07 to 0.11 parts by weight of K 2 O, 0.01 to 0.05 parts by weight of CaO, 0.05 to 0.3 parts by weight of TiO 2 , 0.1 to 0.5 parts by weight of Fe 2 O 3 , 0.005 to 0.015 parts by weight of ZnO and 0.005 to 0.015 parts by weight of ZrO 2 It includes,
더 바람직하게는 화학조성이 Na2O 100 중량부에 대하여, 320~330 중량부의 SiO2, 0.04~0.06 중량부의 MgO, 0.5~0.7 중량부의 Al2O3, 0.2~0.3 중량부의 SO3, 0.4~0.6 중량부의 Cl, 0.08~0.10 중량부의 K2O, 0.02~0.04 중량부의 CaO, 0.1~0.2 중량부의 TiO2, 0.2~0.3 중량부의 Fe2O3, 0.008~0.010 중량부의 ZnO 및 0.009~0.011 중량부의 ZrO2를 포함하는 것이고, More preferably, the chemical composition is 320 to 330 parts by weight of SiO 2 , 0.04 to 0.06 parts by weight of MgO, 0.5 to 0.7 parts by weight of Al 2 O 3 , 0.2 to 0.3 parts by weight of SO 3 , 0.4 parts by weight, based on 100 parts by weight of Na 2 O. ~0.6 parts by weight of Cl, 0.08 to 0.10 parts by weight of K 2 O, 0.02 to 0.04 parts by weight of CaO, 0.1 to 0.2 parts by weight of TiO 2 , 0.2 to 0.3 parts by weight of Fe 2 O 3 , 0.008 to 0.010 parts by weight of ZnO and 0.009 to 0.011 It contains parts by weight of ZrO 2 ,
더욱더 바람직하게는 Na2O 100 중량 부에 대하여, 329 중량부의 SiO2, 0.051 중량부의 MgO, 0.647 중량부의 Al2O3, 0.246 중량부의 SO3, 0.534 중량부의 Cl, 0.094 중량부의 K2O, 0.031 중량부의 CaO, 0.136 중량부의 TiO2, 0.245 중량부의 Fe2O3, 0.009 중량부의 ZnO 및 0.010 중량부의 ZrO2를 포함할 수 있지만, 이에 제한되는 것은 아니다. Even more preferably, based on 100 parts by weight of Na 2 O, 329 parts by weight of SiO 2 , 0.051 parts by weight of MgO, 0.647 parts by weight of Al 2 O 3 , 0.246 parts by weight of SO 3 , 0.534 parts by weight of Cl, 0.094 parts by weight of K 2 O, 0.031 parts by weight of CaO, 0.136 parts by weight of TiO 2 , 0.245 parts by weight of Fe 2 O 3 , 0.009 parts by weight of ZnO and 0.010 parts by weight of ZrO 2 may be included, but is not limited thereto.
상기 유효성분 중에서, 불연성 세라믹 바인더는 바이오 세라믹 분말 100중량부에 대하여, 1~7중량부가 되도록 첨가하여 혼합하는 것이 바람직하지만 이에 한정하는 것은 아니며, 상기 불연성 세라믹 바인더는 바이오 세라믹 분말과 판넬 보드 등의 건축용 소재와의 결합력을 상승시키기 위한 것으로서, 당업계에서 통상적으로 사용될 수 있는 것이라면 무방하게 사용될 수 있다.Among the active ingredients, the non-combustible ceramic binder is preferably added and mixed in an amount of 1 to 7 parts by weight based on 100 parts by weight of the bioceramic powder, but is not limited thereto. As for increasing the bonding strength with building materials, any material that can be commonly used in the art may be used.
또한, 본 발명은 1) 화학 조성이 Na2O 100 중량부에 대하여, 300~350 중량부의 SiO2, 0.02~0.08 중량부의 MgO, 0.3~0.9 중량부의 Al2O3, 0.1~0.4 중량부의 SO3, 0.3~0.7 중량부의 Cl, 0.07~0.11 중량부의 K2O, 0.01~0.05 중량부의 CaO, 0.05~0.3 중량부의 TiO2, 0.1~0.5 중량부의 Fe2O3, 0.005~0.015 중량부의 ZnO 및 0.005~0.015 중량부의 ZrO2인 액상 바이오 세라믹을 제조하는 단계; In addition, the present invention 1) the chemical composition is 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , and 0.1 to 0.4 parts by weight of SO based on 100 parts by weight of Na 2 O 3 , 0.3 to 0.7 parts by weight of Cl, 0.07 to 0.11 parts by weight of K 2 O, 0.01 to 0.05 parts by weight of CaO, 0.05 to 0.3 parts by weight of TiO 2 , 0.1 to 0.5 parts by weight of Fe 2 O 3 , 0.005 to 0.015 parts by weight of ZnO, and Preparing a liquid bio-ceramic of 0.005 to 0.015 parts by weight of ZrO 2 ;
2) 상기 단계 1)에서 제조한 액상 바이오 세라믹을 내열 코팅된 용기에서 200~400℃의 온도로 3~25분 동안 가열하여 발포시켜 고체로 변화시키는 단계;2) converting the liquid bio-ceramic prepared in step 1) into a solid by heating it at a temperature of 200 to 400 ° C. for 3 to 25 minutes in a heat-resistant coated container to foam it;
(3) 상기 단계 (2) 이후에, 고체의 바이오 세라믹을 분말화하는 단계;(3) after step (2), powdering the solid bio-ceramic;
(4) 상기 단계 (3) 이후에, 바이오 세라믹 분말에 불연성 세라믹 바인더를 첨가하여 혼합하는 단계; 및(4) adding a nonflammable ceramic binder to the bio-ceramic powder and mixing it after step (3); and
(5) 상기 단계 (4)의 혼합물을 판넬 보드에 압착하여 코팅시키는 단계;를 포함하는 불연성 친환경 판넬 보드의 제조방법에 관한 것이다.(5) compressing and coating the mixture of step (4) on the panel board;
상기 단계 (2)의 가열 발포는 액상 바이오 세라믹을 내열 코팅된 용기에서 200~400℃의 온도로 3~25분 동안 가열하여 발포시키는 것일 수 있고, 바람직하게는 액상 바이오 세라믹을 밀폐된 내열 코팅된 용기에서 200~400℃의 온도로 10~20분 동안 가열하여, 액상 바이오 세라믹 부피 대비 15~25배의 부피로 완전 발포시켜 고체화하는 것이며, 더 바람직하게는 액상 바이오 세라믹을 밀폐된 내열 코팅된 용기에서 350℃의 온도로 15분 동안 가열하여, 액상 바이오 세라믹 부피 대비 20배의 부피로 완전 발포시켜 고체화하는 것이지만, 이에 한정하는 것은 아니다.Heating and foaming of the step (2) may be performed by heating the liquid bioceramic in a heat-resistant coated container at a temperature of 200 to 400° C. for 3 to 25 minutes, and preferably, the liquid bioceramic is heated and foamed in a sealed heat-resistant coated container. It is heated in a container at a temperature of 200 to 400 ° C for 10 to 20 minutes to completely foam and solidify in a volume 15 to 25 times the volume of the liquid bioceramic. More preferably, the liquid bioceramic is sealed and heat-resistant coated container. by heating at a temperature of 350 ° C. for 15 minutes to fully foam and solidify in a volume 20 times the volume of the liquid bioceramic, but is not limited thereto.
상기 판넬 보드의 소재는 종이류, 천연 또는 가공 목재, 고무, 플라스틱, 우레탄 폼 및 스치로폼 중에서 선택된 어느 하나인 것이 바람직하지만 이에 한정하지 않는다. 상기 가공목재는 MDF, 파티클보드(PB) 또는 합판 등이 포함될 수 있고, 그 종류에 한정하는 것은 아니다. The material of the panel board is preferably any one selected from paper, natural or processed wood, rubber, plastic, urethane foam and styrofoam, but is not limited thereto. The processed wood may include, but is not limited to, MDF, particle board (PB) or plywood.
또한, 본 발명은 상기 제조방법으로 제조된 불연성 친환경 판넬 보드에 관한 것은 아니다. 상기 불연성 친환경 판넬 보드는 기계설비용 단열보드, 자동차 또는 선박의 내열기관용 단열보드, 건축용 바닥재, 천정텍스 및 벽체 보드 중에서 선택된 어느 하나의 용도로 사용되는 것이 바람직하지만 이에 한정하지 않으며, 상기 불연성 친환경 판넬 보드는 항균, 탈취, 음이온 발생 및 원적외선 방사 기능을 갖는 것이 바람직하지만 이에 한정하지 않는다. In addition, the present invention does not relate to a non-flammable eco-friendly panel board manufactured by the above manufacturing method. The non-combustible eco-friendly panel board is preferably used for any one selected from insulation boards for mechanical equipment, insulation boards for heat-resistant engines of automobiles or ships, building flooring materials, ceiling textures, and wall boards, but is not limited thereto, and the non-combustible eco-friendly panels The board preferably has antibacterial, deodorizing, negative ion generating and far-infrared radiation functions, but is not limited thereto.
이하, 실시예를 이용하여 본 발명을 더욱 상세하게 설명하고자 한다. 이들 실시예는 오로지 본 발명을 보다 구체적으로 설명하기 위한 것으로 본 발명의 범위가 이들에 의해 제한되지 않는다는 것은 당해 기술분야에서 통상의 지식을 가진 자에게 있어 자명한 것이다. Hereinafter, the present invention will be described in more detail using examples. These examples are only for explaining the present invention in more detail, and it is obvious to those skilled in the art that the scope of the present invention is not limited thereto.
제조예 1. 불연성 친환경 판넬 보드의 코팅제 및 불연성 판넬 보드의 제조Preparation Example 1. Manufacturing of non-flammable eco-friendly panel board coating agent and non-flammable panel board
Na2O 100 중량 부에 대하여, 329 중량부의 SiO2, 0.051 중량부의 MgO, 0.647 중량부의 Al2O3, 0.246 중량부의 SO3, 0.534 중량부의 Cl, 0.094 중량부의 K2O, 0.031 중량부의 CaO, 0.136 중량부의 TiO2, 0.245 중량부의 Fe2O3, 0.009 중량부의 ZnO 및 0.010 중량부의 ZrO2를 포함하는 화학 조성물을 4일 동안 상온(20±5℃)에서 저온 숙성 반응시켜 액상 바이오 세라믹을 제조하였다. 이 후 상기 액상 바이오 세라믹을 밀폐된 내열 코팅된 스텐레스 용기에서 350℃의 온도로 15분 동안 가열하여, 액상 바이오 세라믹 부피 대비 20배의 부피로 완전 발포시켜 세라믹 블록을 제조하였다. 이후에, 고체의 세라믹 블록을 분말화한 후, 상기 분말화한 세라믹 블록 100중량부에 대하여 불연성 세라믹 바인더 2.5중량부를 첨가하여 혼합하여 불연성 친환경 판넬 보드의 코팅제를 제조하였다.329 parts by weight of SiO 2 , 0.051 parts by weight of MgO, 0.647 parts by weight of Al 2 O 3 , 0.246 parts by weight of SO 3 , 0.534 parts by weight of Cl, 0.094 parts by weight of K 2 O, 0.031 parts by weight of CaO, relative to 100 parts by weight of Na 2 O. , 0.136 parts by weight of TiO 2 , 0.245 parts by weight of Fe 2 O 3 , 0.009 parts by weight of ZnO, and 0.010 parts by weight of ZrO 2 . manufactured. Thereafter, the liquid bioceramic was heated for 15 minutes at a temperature of 350° C. in a sealed, heat-resistant coated stainless container, and completely foamed to a volume 20 times that of the liquid bioceramic to prepare a ceramic block. Then, after powdering the solid ceramic block, 2.5 parts by weight of an incombustible ceramic binder was added and mixed with respect to 100 parts by weight of the powdered ceramic block to prepare a coating agent for an incombustible and eco-friendly panel board.
상기 불연성 친환경 판넬 보드의 코팅제의 불연성 시험을 위하여, 시험체로서, 본 발명의 불연성 친환경 판넬 보드의 코팅제를 스티로폼에 46mm의 두께로 압착하여 코팅한 스티로폼 준불연 보드를 도 1 및 표 1에 개시된 바와 같은 크기로 제조하였다. In order to test the incombustibility of the coating agent of the non-combustible eco-friendly panel board, as a test specimen, a styrofoam semi-non-combustible board coated by pressing the coating agent of the non-combustible eco-friendly panel board of the present invention to a thickness of 46 mm on styrofoam as shown in FIG. 1 and Table 1 made to size.
실시예 2. 준불연성 시험Example 2. Quasi-incombustibility test
상기 제조예 1에서 제조한 시험체를 이용하여 국토교통부 고시 제2015-744호에 개시한 시험 및 검사 방법에 따라, 총열방출량, 200kW/m2 초과 시간, 준불연성 시험 후의 시험체 검사 및 가스 유해성 검사를 실시하였다. According to the test and inspection method disclosed in Ministry of Land, Infrastructure and Transport Notice No. 2015-744 using the test body prepared in Preparation Example 1, total heat emission, time exceeding 200 kW / m 2 , test sample after semi-incombustibility test and gas hazard test conducted.
그 결과 하기 표 1에 개시한 바와 같이 준불연 효과가 우수하다는 것을 확인하였다. As a result, as disclosed in Table 1 below, it was confirmed that the quasi-incombustible effect was excellent.
실시예 3. 열전도율 시험Example 3. Thermal conductivity test
상기 제조예 1에서 제조한 시험체(#4)를 이용하여 KS L 9016 시험방법에 따라, 초기 열전도율(W/m·K) 분석을 실시하였으며, 그 결과, 초기 열전도율(W/m·K)은 0.034W/m·K인 것을 확인하였다. Initial thermal conductivity (W / m K) analysis was performed according to the KS L 9016 test method using the test specimen (# 4) prepared in Preparation Example 1, and as a result, the initial thermal conductivity (W / m K) was It was confirmed that it was 0.034 W/m·K.
Claims (6)
(2) 상기 단계 (1)에서 발포시켜 고체화된 바이오 세라믹을 분말화하는 단계;를 포함하는 제조방법으로 제조된 바이오 세라믹 분말과, 불연성 세라믹 바인더를 유효성분으로 포함하는 불연성 친환경 판넬 보드의 코팅용 조성물로서,
상기 불연성 친환경 판넬 보드의 소재는 고무, 우레탄폼, 및 스치로폼 중에서 선택된 어느 하나이고,
상기 불연성 친환경 판넬 보드는 기계설비용 단열보드, 자동차 또는 선박의 내열기관용 단열보드, 건축용 바닥재, 천정텍스 및 벽체 보드 중에서 선택된 어느 하나의 용도로 사용되는 것을 특징으로 하는 불연성 친환경 판넬 보드의 코팅용 조성물.(1) Based on 100 parts by weight of Na 2 O , 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , 0.1 to 0.4 parts by weight of SO 3 , 0.3 to 0.7 parts by weight Cl, 0.07-0.11 parts by weight K 2 O, 0.01-0.05 parts by weight CaO, 0.05-0.3 parts by weight TiO 2 , 0.1-0.5 parts by weight Fe 2 O 3 , 0.005-0.015 parts by weight ZnO and 0.005-0.015 parts by weight ZrO 2 Foaming by heating a liquid bio-ceramic comprising; and
(2) powderizing the bioceramic solidified by foaming in step (1); for coating a nonflammable eco-friendly panel board containing bioceramic powder prepared by a manufacturing method including a nonflammable ceramic binder as an active ingredient; As a composition,
The material of the non-flammable eco-friendly panel board is any one selected from rubber, urethane foam, and styrofoam,
The non-flammable eco-friendly panel board is a composition for coating a non-flammable eco-friendly panel board, characterized in that it is used for any one selected from insulation boards for mechanical equipment, insulation boards for heat-resistant engines of automobiles or ships, flooring materials for construction, ceiling textures, and wall boards. .
(2) 상기 단계 (1)에서 제조한 액상 바이오 세라믹을 내열 코팅된 용기에서 200~400℃의 온도로 3~25분 동안 가열하여 발포시켜 고체로 변화시키는 단계;
(3) 상기 단계 (2) 이후에, 고체의 바이오 세라믹을 분말화하는 단계;
(4) 상기 단계 (3) 이후에, 바이오 세라믹 분말에 불연성 세라믹 바인더를 첨가하여 혼합하는 단계; 및
(5) 상기 단계 (4)의 혼합물을 판넬 보드에 압착하여 코팅시키는 단계;를 포함하는 불연성 친환경 판넬 보드의 제조방법으로서,
상기 불연성 친환경 판넬 보드의 소재는 고무, 우레탄폼, 및 스치로폼 중에서 선택된 어느 하나이고,
상기 불연성 친환경 판넬 보드는 기계설비용 단열보드, 자동차 또는 선박의 내열기관용 단열보드, 건축용 바닥재, 천정텍스 및 벽체 보드 중에서 선택된 어느 하나의 용도로 사용되는 것을 특징으로 하는 불연성 친환경 판넬 보드의 제조방법.(1) The chemical composition is 300 to 350 parts by weight of SiO 2 , 0.02 to 0.08 parts by weight of MgO, 0.3 to 0.9 parts by weight of Al 2 O 3 , 0.1 to 0.4 parts by weight of SO 3 , 0.3 to 0.3 to 100 parts by weight of Na 2 O . 0.7 parts by weight of Cl, 0.07 to 0.11 parts by weight of K 2 O, 0.01 to 0.05 parts by weight of CaO, 0.05 to 0.3 parts by weight of TiO 2 , 0.1 to 0.5 parts by weight of Fe 2 O 3 , 0.005 to 0.015 parts by weight of ZnO and 0.005 to 0.015 parts by weight Preparing a liquid bioceramic of negative ZrO 2 ;
(2) heating the liquid bio-ceramic prepared in step (1) at a temperature of 200 to 400 ° C. for 3 to 25 minutes in a heat-resistant coated container to foam it and change it into a solid;
(3) after step (2), powdering the solid bio-ceramic;
(4) adding a nonflammable ceramic binder to the bio-ceramic powder and mixing it after step (3); and
(5) compressing and coating the mixture of step (4) on the panel board;
The material of the non-flammable eco-friendly panel board is any one selected from rubber, urethane foam, and styrofoam,
The non-flammable eco-friendly panel board is used for any one selected from insulation boards for mechanical equipment, insulation boards for heat-resistant engines of automobiles or ships, building flooring materials, ceiling textures, and wall boards Manufacturing method of non-flammable eco-friendly panel boards.
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| KR20180128815A (en) * | 2017-05-24 | 2018-12-04 | 서진호 | Method for fabricating of noncombustible styrofoam panel |
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