KR102524739B1 - Eco-friendly coating type anti-slip paving material and the manufacturing method thereof - Google Patents
Eco-friendly coating type anti-slip paving material and the manufacturing method thereof Download PDFInfo
- Publication number
- KR102524739B1 KR102524739B1 KR1020220081725A KR20220081725A KR102524739B1 KR 102524739 B1 KR102524739 B1 KR 102524739B1 KR 1020220081725 A KR1020220081725 A KR 1020220081725A KR 20220081725 A KR20220081725 A KR 20220081725A KR 102524739 B1 KR102524739 B1 KR 102524739B1
- Authority
- KR
- South Korea
- Prior art keywords
- slip
- eco
- extract
- agent
- packaging material
- Prior art date
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 45
- 238000000576 coating method Methods 0.000 title claims abstract description 45
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 239000000463 material Substances 0.000 title abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000005022 packaging material Substances 0.000 claims abstract description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000012748 slip agent Substances 0.000 claims abstract description 28
- 239000003973 paint Substances 0.000 claims abstract description 26
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 23
- 239000005871 repellent Substances 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 19
- 230000002940 repellent Effects 0.000 claims abstract description 19
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 25
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 24
- 239000004576 sand Substances 0.000 claims description 22
- 239000003242 anti bacterial agent Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- -1 licorice extract Substances 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 17
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 16
- 239000000284 extract Substances 0.000 claims description 16
- 239000002952 polymeric resin Substances 0.000 claims description 12
- 229920003002 synthetic resin Polymers 0.000 claims description 12
- 239000012153 distilled water Substances 0.000 claims description 11
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 10
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 229920001661 Chitosan Polymers 0.000 claims description 7
- 108010039918 Polylysine Proteins 0.000 claims description 7
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 7
- 239000003999 initiator Substances 0.000 claims description 7
- 230000001678 irradiating effect Effects 0.000 claims description 7
- 229920000656 polylysine Polymers 0.000 claims description 7
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000008119 colloidal silica Substances 0.000 claims description 6
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims description 5
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- 239000009429 Ginkgo biloba extract Substances 0.000 claims description 5
- 235000001018 Hibiscus sabdariffa Nutrition 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
- 235000011203 Origanum Nutrition 0.000 claims description 5
- 240000000783 Origanum majorana Species 0.000 claims description 5
- QNVSXXGDAPORNA-UHFFFAOYSA-N Resveratrol Natural products OC1=CC=CC(C=CC=2C=C(O)C(O)=CC=2)=C1 QNVSXXGDAPORNA-UHFFFAOYSA-N 0.000 claims description 5
- 235000005291 Rumex acetosa Nutrition 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 5
- LUKBXSAWLPMMSZ-OWOJBTEDSA-N Trans-resveratrol Chemical compound C1=CC(O)=CC=C1\C=C\C1=CC(O)=CC(O)=C1 LUKBXSAWLPMMSZ-OWOJBTEDSA-N 0.000 claims description 5
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 5
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims description 5
- 235000005487 catechin Nutrition 0.000 claims description 5
- 229950001002 cianidanol Drugs 0.000 claims description 5
- 235000020230 cinnamon extract Nutrition 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 5
- 229930003935 flavonoid Natural products 0.000 claims description 5
- 235000017173 flavonoids Nutrition 0.000 claims description 5
- 150000002215 flavonoids Chemical class 0.000 claims description 5
- 229940107702 grapefruit seed extract Drugs 0.000 claims description 5
- CJWQYWQDLBZGPD-UHFFFAOYSA-N isoflavone Natural products C1=C(OC)C(OC)=CC(OC)=C1C1=COC2=C(C=CC(C)(C)O3)C3=C(OC)C=C2C1=O CJWQYWQDLBZGPD-UHFFFAOYSA-N 0.000 claims description 5
- 235000008696 isoflavones Nutrition 0.000 claims description 5
- 239000001726 jatropha manihot extract Substances 0.000 claims description 5
- 229940069445 licorice extract Drugs 0.000 claims description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 5
- 235000021283 resveratrol Nutrition 0.000 claims description 5
- 229940016667 resveratrol Drugs 0.000 claims description 5
- 235000003513 sheep sorrel Nutrition 0.000 claims description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 5
- 229940106668 yucca extract Drugs 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 241000241413 Propolis Species 0.000 claims description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- LUYGICHXYUCIFA-UHFFFAOYSA-H calcium;dimagnesium;hexaacetate Chemical compound [Mg+2].[Mg+2].[Ca+2].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O LUYGICHXYUCIFA-UHFFFAOYSA-H 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- 150000002515 isoflavone derivatives Chemical class 0.000 claims description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 229940069949 propolis Drugs 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 229940044192 2-hydroxyethyl methacrylate Drugs 0.000 claims description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 3
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 229940076085 gold Drugs 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000007781 pre-processing Methods 0.000 claims description 3
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 claims description 3
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 claims description 3
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims description 2
- 240000007001 Rumex acetosella Species 0.000 claims 2
- 238000004806 packaging method and process Methods 0.000 claims 1
- 239000004599 antimicrobial Substances 0.000 abstract description 2
- 238000004064 recycling Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002699 waste material Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 241000237519 Bivalvia Species 0.000 description 6
- 235000020639 clam Nutrition 0.000 description 6
- 239000004342 Benzoyl peroxide Substances 0.000 description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 5
- 229960003328 benzoyl peroxide Drugs 0.000 description 5
- 235000019400 benzoyl peroxide Nutrition 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- NYMPGSQKHIOWIO-UHFFFAOYSA-N hydroxy(diphenyl)silicon Chemical class C=1C=CC=CC=1[Si](O)C1=CC=CC=C1 NYMPGSQKHIOWIO-UHFFFAOYSA-N 0.000 description 4
- 229940063559 methacrylic acid Drugs 0.000 description 4
- 240000004153 Hibiscus sabdariffa Species 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 230000008602 contraction Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229960004275 glycolic acid Drugs 0.000 description 2
- ICLMZQVLRKSOSJ-UHFFFAOYSA-N n,n-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1.CN(C)C1=CC=CC=C1 ICLMZQVLRKSOSJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- QVUSZNNDUPNAAU-UHFFFAOYSA-N 2,4-dimethylpent-2-enoic acid propan-2-yl 2-methylprop-2-enoate Chemical compound C(C)(C)C=C(C(=O)O)C.C(C(=C)C)(=O)OC(C)C QVUSZNNDUPNAAU-UHFFFAOYSA-N 0.000 description 1
- JUVSRZCUMWZBFK-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-4-methylanilino]ethanol Chemical compound CC1=CC=C(N(CCO)CCO)C=C1 JUVSRZCUMWZBFK-UHFFFAOYSA-N 0.000 description 1
- WNXTZVMMNCCZTP-UHFFFAOYSA-N 2-hydroxyethyl 2-methylprop-2-enoate 5-hydroxy-2-methylpent-2-enoic acid Chemical compound OCCC=C(C(=O)O)C.C(C(=C)C)(=O)OCCO WNXTZVMMNCCZTP-UHFFFAOYSA-N 0.000 description 1
- FRQQKWGDKVGLFI-UHFFFAOYSA-N 2-methylundecane-2-thiol Chemical compound CCCCCCCCCC(C)(C)S FRQQKWGDKVGLFI-UHFFFAOYSA-N 0.000 description 1
- OORRCVPWRPVJEK-UHFFFAOYSA-N 2-oxidanylethanoic acid Chemical compound OCC(O)=O.OCC(O)=O OORRCVPWRPVJEK-UHFFFAOYSA-N 0.000 description 1
- 235000009899 Agrostemma githago Nutrition 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- XMVGUGITNIKFRI-UHFFFAOYSA-N CN(C1=CC=C(C=C1)C)C.CN(C1=CC=C(C=C1)C)C Chemical compound CN(C1=CC=C(C=C1)C)C.CN(C1=CC=C(C=C1)C)C XMVGUGITNIKFRI-UHFFFAOYSA-N 0.000 description 1
- 241000237858 Gastropoda Species 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- 241000234435 Lilium Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 206010039203 Road traffic accident Diseases 0.000 description 1
- 244000178320 Vaccaria pyramidata Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- MIOPWDLAZRCMGE-UHFFFAOYSA-N butyl 2-methylprop-2-enoate 2-methylhept-2-enoic acid Chemical compound CCCCOC(=O)C(C)=C.CCCCC=C(C)C(O)=O MIOPWDLAZRCMGE-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- GOMNOOKGLZYEJT-UHFFFAOYSA-N isoflavone Chemical compound C=1OC2=CC=CC=C2C(=O)C=1C1=CC=CC=C1 GOMNOOKGLZYEJT-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N phenyldimethylamine Natural products CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920005651 polypropylene glycol dimethacrylate Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002062 proliferating effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- GWAZANVVNOAJSY-UHFFFAOYSA-N triethoxy(octyl)silane Chemical group CCCCCCCC[Si](OCC)(OCC)OCC.CCCCCCCC[Si](OCC)(OCC)OCC GWAZANVVNOAJSY-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/149—Antislip compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
- C09K3/185—Thawing materials
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
- E01C11/24—Methods or arrangements for preventing slipperiness or protecting against influences of the weather
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/60—Planning or developing urban green infrastructure
Abstract
Description
본 발명은 고분자 및 친환경 물질을 이용한 도막형 미끄럼 방지 포장재 및 그 제조방법에 관한 것으로, 보다 상세하게는 고분자를 바인더로 하는 미끄럼 방지 도료에 친환경 물질을 적용함으로써 도막을 형성할 시 노면과 접착성이 우수하며, 항균성, 제설성, 내마모성 및 내구성 등을 향상시킬 수 있도록 한 친환경 도막형 미끄럼 방지 포장재 및 그 제조방법에 관한 것이다.The present invention relates to a coating film-type non-slip packaging material using a polymer and an eco-friendly material and a method for manufacturing the same, and more particularly, by applying an eco-friendly material to an anti-slip paint using a polymer as a binder, when forming a coating film, adhesion to the road surface is improved. It relates to an eco-friendly coating film-type non-slip packaging material capable of improving antibacterial properties, snow removal properties, abrasion resistance and durability, and a manufacturing method thereof.
일반적으로 미끄럼방지 포장은 포장의 미끄럼 저항을 높여 자동차의 안전한 주행을 도모하기 위한 시설로서, 노면의 미끄럼 저항이 낮아진 곳, 도로의 평면 및 종단 선형이 불량한 곳 등에 포장면의 미끄럼 저항을 높여주어 자동차의 제동거리를 짧게 하거나 또는 학교 통학로, 횡단보도 등과 같이 사람들이 보행하는 도로의 식별력을 높여 교통사고를 예방하기 위한 목적으로 설치되는 시설을 말한다.In general, anti-slip pavement is a facility to promote safe driving of vehicles by increasing the slip resistance of the pavement. It increases the slip resistance of the pavement in places where the slip resistance of the road surface is low and where the horizontal and vertical alignment of the road are poor. It refers to a facility installed for the purpose of preventing traffic accidents by shortening the braking distance of a vehicle or increasing the discrimination of roads where people walk, such as school commuting routes and crosswalks.
그리고 미끄럼방지 포장은 도로의 기하구조 및 교통 특성에 따라 요구되는 수준의 미끄럼 저항이 확보되지 못하는 구간에 설치하여 마찰력을 증진시키는데 목적이 있다. 즉, 도로의 사용 기간이 증가함에 따라 포장의 미끄럼 저항이 전 구간에 걸쳐서 일정 수준 이하로 떨어지는 경우에는 포장의 유지관리 측면에서 근본적으로 미끄럼 저항을 높이기 위해 미끄럼방지용 도료 조성물을 이용하여 도로를 보수하며, 최근 이러한 미끄럼방지용 도료 조성물은 도로 이외에도 보행 시 미끄러지기 쉬운 장소인 건축물의 옥상, 야외 주차장, 공원 등에도 도포함에 따라 그 수요가 급증하고 있다.In addition, the anti-skid pavement is installed in sections where the required level of slip resistance is not secured according to the geometric structure and traffic characteristics of the road to increase frictional force. That is, when the slip resistance of the pavement falls below a certain level over the entire section as the period of use of the road increases, the road is repaired using an anti-slip paint composition to fundamentally increase the slip resistance in terms of maintenance of the pavement. Recently, the demand for such anti-slip paint compositions is rapidly increasing as they are applied not only to roads but also to rooftops of buildings, outdoor parking lots, and parks, which are slippery places when walking.
하지만 종래의 미끄럼 방지 포장 기술은 교통과 자연환경의 영향으로(차량의 충격, 압착과 대기의 침식, 노면의 침강, 이동, 시공 후 양생의 부족 등) 노면이 손상 받는 현상이 많아지고 있다. 이에 포장 면들이 쉽게 균열하거나 골재의 마모로 인해 시간이 지날수록 미끄럼 방지 효과가 크게 줄어들고 있다. However, the conventional non-slip pavement technology is increasingly damaged due to the influence of traffic and the natural environment (vehicle impact, compression and atmospheric erosion, road subsidence, movement, lack of curing after construction, etc.). As a result, the anti-slip effect is greatly reduced over time due to easy cracking of the pavement surfaces or abrasion of the aggregate.
또한, 기온의 변화에 따라 지속적으로 수축, 팽창이 발생하고 있으며, 노면에 가해지는 하중에 의해 소성변형(Rutting), 피로균열(Fatigue crack) 등의 문제점들이 발생하고 있을 뿐만 아니라, 미끄럼 방지 포장재는 시공시 수축, 팽창 차이로 인한 노면과의 들뜸 현상 및 탈락이 발생하는 문제점이 있었다.In addition, contraction and expansion continue to occur with changes in temperature, and problems such as rutting and fatigue cracks occur due to the load applied to the road surface. During construction, there was a problem of lifting and falling off from the road surface due to the difference in contraction and expansion.
본 발명은 상술한 문제점을 해결하기 위해 자연에서 얻을 수 있는 친환경 물질을 이용하여 미끄럼방지기능을 적용함으로써 환경폐기물도 줄일 수 있고, 이를 통하여 바닥 표면의 마찰계수를 향상시켜 미끄러짐을 저하하며, 발수성 및 제설성이 뛰어나 비나 눈에 의하여 마모되지 않고, 노면과의 접착성, 항균성, 내마모성 및 내구성이 뛰어난 친환경 도막형 미끄럼 방지 포장재 및 그 제조방법을 제공하기 위한 것이다.In order to solve the above problems, the present invention can reduce environmental waste by applying an anti-slip function using eco-friendly materials obtained from nature, and through this, the friction coefficient of the floor surface is improved to reduce slippage, water repellency and It is an object of the present invention to provide an eco-friendly coating-type non-slip packaging material having excellent deicing properties, not being abraded by rain or snow, excellent adhesion to the road surface, antibacterial property, abrasion resistance and durability, and a method for manufacturing the same.
본 발명은 고분자 수지, 경화촉진제, 경화개시제 및 가교제 중 어느 하나 이상을 혼합하여 이루어지는 미끄럼 방지 도료; 항균성 물질로 이루어지는 항균제; 패각, 규사를 포함하는 미끄럼 방지제;를 포함한다.The present invention is an anti-slip paint made by mixing at least one of a polymer resin, a curing accelerator, a curing initiator, and a crosslinking agent; an antibacterial agent made of an antibacterial substance; It includes; a shell and an anti-slip agent including silica sand.
일 유형으로, 상기 친환경 도막형 미끄럼 방지 포장재 100중량부를 기준으로, 상기 미끄럼 방지 도료는 40 내지 55 중량부이고, 상기 항균제는 10 내지 15중량부이고, 상기 미끄럼 방지제는 15 내지 35중량부를 포함한다.In one type, based on 100 parts by weight of the eco-friendly coating film type anti-slip packaging material, the anti-slip paint is 40 to 55 parts by weight, the antibacterial agent is 10 to 15 parts by weight, and the anti-slip agent is 15 to 35 parts by weight. .
일 유형으로, 상기 고분자 수지는 에폭시 수지, 아크릴 수지, MMA수지, 우레탄 수지, 우레아 수지 및 스틸렌 단량체 중 어느 하나 이상을 포함하고, 상기 미끄럼 방지제 중 포함된 상기 패각과 규사의 혼합비는 1.5~2.0 : 1.2~1.7 중량비로 혼합되는 것을 특징으로 한다.In one type, the polymer resin includes any one or more of epoxy resin, acrylic resin, MMA resin, urethane resin, urea resin, and styrene monomer, and the mixing ratio of the shell and silica sand included in the anti-slip agent is 1.5 to 2.0: It is characterized in that it is mixed in a weight ratio of 1.2 to 1.7.
일 유형으로, 상기 친환경 도막형 미끄럼 방지 포장재는 비불소계 발수제를 더 포함하고, 상기 비불소계 발수제는 MMA계 수지 모노머에 유화제를 첨가하여 유화 중합반응으로 생성되고, 상기 친환경 도막형 미끄럼 방지 포장재 100중량부에 대하여 상기 비불소계 발수제 5 내지 12중량부를 포함하는 것을 특징으로 한다.In one type, the eco-friendly coating film-type non-slip packaging material further includes a fluorine-free water repellent agent, the fluorine-free water repellent agent is produced by emulsion polymerization by adding an emulsifier to an MMA-based resin monomer, and the eco-friendly coating film-type anti-slip packaging material 100 weight It is characterized in that it comprises 5 to 12 parts by weight of the fluorine-free water repellent with respect to the part.
일 유형으로, 상기 비불소계 발수제는 상기 MMA계 수지 모노머와 유화제 및 증류수를 0.45~0.5 : 0.2~0.27 :1.0의 중량비로 희석하여 희석된 혼합물을 제조하고, 상기 희석된 혼합물을 30℃ 내지 40℃에서 3시간 내지 4시간동안 초음파를 조사하여 유화 중합하여 제조되는 것을 특징으로 한다.In one type, the fluorine-free water repellent agent prepares a diluted mixture by diluting the MMA-based resin monomer, emulsifier, and distilled water in a weight ratio of 0.45 to 0.5: 0.2 to 0.27: 1.0, and the diluted mixture is heated to 30 ° C to 40 ° C. It is characterized in that it is produced by emulsion polymerization by irradiating ultrasonic waves for 3 to 4 hours in.
일 유형으로, 상기 MMA계 수지 모노머는 메틸메타크릴레이트 (MethylMethacrylate), 메타크릴산 (Methacrylicacid), 폴리메틸메타크릴레이트 (PolymethylMethacrylate), 부틸메타크릴레이트 (ButylMethacrylate), n-부틸메타크릴레이트 (n-ButylMethacrylate), 이소부틸메타크릴레이트 (IsobutylMethacrylate), 에틸메타크릴레이트 (EthylMethacrylate), 이소프로필메타크릴레이트 (IsopropylMethacrylate) 및 하이드록시에틸메타크릴레이트 (2-HydroxyethylMethacrylate) 중 적어도 어느 하나 이상을 포함할 수 있다.In one type, the MMA-based resin monomer is methylmethacrylate (MethylMethacrylate), methacrylic acid (Methacrylicacid), polymethylmethacrylate (PolymethylMethacrylate), butyl methacrylate (ButylMethacrylate), n-butyl methacrylate (n -ButylMethacrylate), isobutylmethacrylate (IsobutylMethacrylate), ethylmethacrylate (EthylMethacrylate), isopropylmethacrylate (IsopropylMethacrylate) and hydroxyethyl methacrylate (2-HydroxyethylMethacrylate) may include at least one or more there is.
일 유형으로, 상기 유화제는 테트라도데실매르캅탄 (tert-dodecylmercaptane), 폴리옥시에틸렌라우릴에테르 (polyoxyethylenelaurylether), 트리메틸스테아릴암모늄염화물 (trimethylstearylammoniumchloride), 글리콜산(glycolicacid) 및 폴리프로필렌글리콜 (polypropyleneglycol) 중 적어도 어느 하나 이상을 포함할 수 있다.In one type, the emulsifier is tetradodecylmercaptan (tert-dodecylmercaptane), polyoxyethylene lauryl ether (polyoxyethylene laurylether), trimethylstearylammonium chloride (trimethylstearylammoniumchloride), glycolic acid (glycolicacid) and polypropylene glycol (polypropyleneglycol) At least any one or more may be included.
일 유형으로, 상기 비불소계 발수제는 실란 : 실록산 = 1.0~1.5 : 2.0~2.2의 중량비 또는 부피비로 혼합된 혼합물을 추가로 포함하고, 상기 실란은 n-옥틸트리에톡시실란 (n-Octyltriethoxysilane), 디메틸에톡시실란 (Dimethyldimethoxysilane), 메틸트라이메톡시실란 (Methyltrimethoxysilane) 및 페닐트리메톡시실란 (Phenyltrimethoxysilane) 중 적어도 어느 하나 이상을 포함하며, 상기 실록산은 말단에 메톡시기를 가지는 아미노실세스퀴옥산 (Methoxy-terminatedaminosilsesquioxane), 메틸페닐실록산 (Methylphenylsiloxane) 및 디페닐실록산 (Diphenylsiloxane) 중 선택된 어느 하나 이상을 포함할 수 있다.In one type, the fluorine-free water repellent agent further includes a mixture of silane: siloxane = 1.0 to 1.5: 2.0 to 2.2 in a weight ratio or volume ratio, and the silane is n-octyltriethoxysilane (n-Octyltriethoxysilane), It includes at least one or more of dimethyldimethoxysilane, methyltrimethoxysilane, and phenyltrimethoxysilane, and the siloxane is aminosilsesquioxane having a methoxy group at the terminal (Methoxy -terminated aminosilsesquioxane), methylphenylsiloxane (Methylphenylsiloxane), and diphenylsiloxane (Diphenylsiloxane).
일 유형으로, 상기 항균제는 수용성 키토산, 마조람추출물, 은행잎추출물, 감초추출물, 유카추출물, 황금추출물, 계피추출물, 자몽종자추출물 및 소리쟁이추출물 중에서 선택된 1종에 의한 제 1항균물질 : 폴리라이신, 프로폴리스, 카테킨, 플라보노이드, 레스베라트롤 및 이소플라본 중에서 선택된 1종에 의한 제 2항균물질 = 5.5~6.0 : 2.1~2.7의 중량비 또는 부피비로 혼합된 혼합물을 포함하는 구성일 수 있다.In one type, the antibacterial agent is water-soluble chitosan, marjoram extract, ginkgo leaf extract, licorice extract, yucca extract, golden extract, cinnamon extract, grapefruit seed extract, and sorrel extract, the first antibacterial substance by one selected from: polylysine, The second antibacterial substance by one selected from polis, catechin, flavonoid, resveratrol, and isoflavone = 5.5 to 6.0: It may be configured to include a mixture mixed in a weight ratio or volume ratio of 2.1 to 2.7.
일 유형으로, 상기 미끄럼방지제는 미끄럼 방지 효과를 향상시키는 나노 콜로이달 실리카를 더 포함하고, 상기 나노 콜로이달 실리카는 입자 평균이 10 내지 15nm이고 비중이 1.90 내지 2.3인 실리카에 아민계 알칼리 촉매를 반응시켜 제조되는 것을 특징으로 한다.In one type, the anti-slip agent further comprises nano colloidal silica that improves the anti-slip effect, and the nano colloidal silica has a particle average of 10 to 15 nm and a specific gravity of 1.90 to 2.3 Reacting an amine-based alkali catalyst with silica It is characterized in that it is produced by.
일 유형으로, 칼슘마그네슘아세테이트 [CaMg2(CH3CO2)6], 요소 [(NH2)2CO] 중 적어도 어느 하나 이상으로 이루어지는 비염화물계 제설제 5 내지 10중량부를 추가적으로 포함할 수 있다.As one type, calcium magnesium acetate [CaMg 2 (CH 3 CO 2 ) 6 ], urea [(NH 2 ) 2 CO] may further include 5 to 10 parts by weight of a non-chloride-based snow removal agent consisting of at least one or more. .
본 발명의 친환경 도막형 미끄럼 방지 포장재의 제조방법은 고분자 수지, 경화촉진제, 경화개시제 및 가교제 중 어느 하나 이상을 혼합하여 이루어지는 미끄럼 방지 도료; 항균성 물질로 이루어지는 항균제; 및 패각, 규사를 포함하는 미끄럼 방지제;를 준비하는 준비단계;와 상기 미끄럼방지 도료, 항균제 및 미끄럼 방지제를 혼합하는 혼합단계;를 포함한다.A method for manufacturing an eco-friendly coating film-type anti-slip packaging material of the present invention includes an anti-slip paint obtained by mixing at least one of a polymer resin, a curing accelerator, a curing initiator, and a crosslinking agent; an antibacterial agent made of an antibacterial substance; and a preparation step of preparing a shell and an anti-slip agent including silica sand; and a mixing step of mixing the anti-slip paint, the anti-slip agent and the anti-slip agent.
상기 준비단계는 상기 패각의 전처리단계 포함하고, 상기 전처리단계는 흐르는 물에 세척하는 세척단계; 증류수에 24시간 내지 36시간 동안 침수하는 단계; 30 내지 50 kHz의 주파수로 30분 내지 60분동안 초음파 조사하는 단계; 24시간 내지 36시간 동안 건조하는 단계; 및 질산과 증류수를 1:20 내지 1:40의 비율로 희석한 혼합물에 10분 내지 30분동안 침지시키는 단계;를 포함하여 상기 패각 내부의 염분 및 이물질을 제거하는 것을 특징으로 한다.The preparation step includes a pretreatment step of the shell, and the pretreatment step includes a washing step of washing in running water; immersion in distilled water for 24 to 36 hours; irradiating ultrasonic waves at a frequency of 30 to 50 kHz for 30 to 60 minutes; drying for 24 to 36 hours; and immersing for 10 minutes to 30 minutes in a mixture diluted with nitric acid and distilled water at a ratio of 1:20 to 1:40, including removing salt and foreign matter inside the shell.
상기 고분자 수지는 에폭시 수지, 아크릴 수지, MMA수지, 우레탄 수지, 우레아 수지 및 스틸렌 단량체 중 적어도 어느 하나 이상을 포함하고, 상기 미끄럼 방지제 중 포함된 상기 패각과 규사의 혼합비는 1.5~2.0 : 1.2~1.7 중량비로 혼합되는 것을 특징으로 한다.The polymer resin includes at least one of an epoxy resin, an acrylic resin, an MMA resin, a urethane resin, a urea resin, and a styrene monomer, and the mixing ratio of the shell and silica sand included in the anti-slip agent is 1.5 to 2.0: 1.2 to 1.7 It is characterized in that it is mixed in a weight ratio.
상기 항균제는 수용성 키토산, 마조람추출물, 은행잎추출물, 감초추출물, 유카추출물, 황금추출물, 계피추출물, 자몽종자추출물 및 소리쟁이추출물 중에서 선택된 1종에 의한 제 1항균물질 : 폴리라이신, 프로폴리스, 카테킨, 플라보노이드, 레스베라트롤 및 이소플라본 중에서 선택된 1종에 의한 제 2항균물질 = 5.5~6.0 : 2.1~2.7의 중량비 또는 부피비로 혼합된 혼합물을 포함하는 것을 특징으로 한다.The antibacterial agent is water-soluble chitosan, marjoram extract, ginkgo leaf extract, licorice extract, yucca extract, gold extract, cinnamon extract, grapefruit seed extract, and sorrel extract, the first antibacterial substance by one selected from: polylysine, propolis, catechin, The second antimicrobial substance by one selected from flavonoids, resveratrol and isoflavones = 5.5 to 6.0: characterized in that it comprises a mixture mixed in a weight ratio or volume ratio of 2.1 to 2.7.
본 발명에 따르면 친환경 도막형 미끄럼 방지 포장재는 미끄럼 방지 도료에 친환경 물질을 적용하여 도막을 형성하기 때문에 노면과 접착성이 우수하며, 내마모성 및 내구성이 향상된 친환경 도막형 미끄럼 방지 포장재 및 그 제조방법을 제공할 수 있다.According to the present invention, an eco-friendly coating film-type anti-slip packaging material having excellent adhesion to the road surface and improved abrasion resistance and durability since a coating film is formed by applying an eco-friendly material to the anti-slip paint, and a method for manufacturing the same can do.
또한, 자연에서 얻을 수 있는 친환경 물질을 이용하기 때문에 환경폐기물도 줄일 수 있고, 이를 통하여 바닥 표면의 마찰계수를 향상시켜 미끄러짐을 저하하며, 발수성이 뛰어나 우천시 수막현상을 해소할 수 있으며, 제설제를 추가로 포함할 수 있어 제설성이 뛰어나고, 습도에 강하여 비나 눈에 의해 마모되지 않으며, 항균제를 이용하여 항균성이 뛰어난 친환경 도막형 미끄럼 방지 포장재 및 그 제조방법을 제공할 수 있다.In addition, since eco-friendly materials obtained from nature are used, environmental waste can be reduced, and through this, the friction coefficient of the floor surface is improved to reduce slippage, and water repellency is excellent, which can solve the hydroplaning phenomenon in rainy weather. It is possible to provide an eco-friendly coating type non-slip packaging material with excellent anti-slipping properties and a method of manufacturing the same, which can be additionally included, has excellent snow removal properties, is resistant to humidity and is not worn by rain or snow, and has excellent antibacterial properties by using an antibacterial agent.
기존의 인·보도, 차도의 미끄럼방지포장, 자전거도로포장, 어린이보호구역, 공원구역, 버스전용차로, 건축물의 옥상콘크리트, 철골형의 자동차주차장과 같은 미끄럼 방지가 필요한 곳에 적용하여 더욱 향상된 미끄럼방지 효과를 얻을 수 있다.Improved anti-skid by applying to places where anti-slip is needed, such as existing sidewalks, anti-slip pavement of driveways, pavement for bicycle roads, children's protection areas, park areas, bus lanes, rooftop concrete of buildings, and steel-framed car parking lots effect can be obtained.
도 1은 본 발명의 친환경 도막형 미끄럼 방지 포장재의 제조공정도.1 is a manufacturing process diagram of an eco-friendly coating type non-slip packaging material of the present invention.
본 발명의 친환경 도막형 미끄럼 방지 포장재는 미끄럼 방지도료, 항균제, 미끄럼 방지제를 포함하여 구성된다.The eco-friendly coating film-type anti-slip packaging material of the present invention includes an anti-slip paint, an antibacterial agent, and an anti-slip agent.
상기 친환경 도막형 미끄럼 방지 포장재 100중량부를 기준으로, 상기 미끄럼 방지 도료는 40 내지 55 중량부를 포함하고, 상기 항균제는 10 내지 15중량부를 포함하고, 상기 미끄럼 방지제는 15 내지 35중량부를 포함하는 것이 바람직하다.Based on 100 parts by weight of the eco-friendly coating film-type anti-slip packaging material, the anti-slip paint preferably contains 40 to 55 parts by weight, the antibacterial agent contains 10 to 15 parts by weight, and the anti-slip agent contains 15 to 35 parts by weight. do.
상기 미끄럼 방지 도료는 고분자 수지, 경화촉진제, 경화개시제 및 가교제 중 어느 하나 이상을 혼합하여 사용하는 것이 바람직하다.The anti-slip paint is preferably used by mixing at least one of a polymer resin, a curing accelerator, a curing initiator, and a crosslinking agent.
상기 고분자 수지는 에폭시 수지, 아크릴 수지, MMA수지, 우레탄 수지, 우레아 수지, 스틸렌 단량체 중 어느 하나 이상을 포함하는 것이 바람직하다.The polymer resin preferably includes at least one of an epoxy resin, an acrylic resin, an MMA resin, a urethane resin, a urea resin, and a styrene monomer.
상기 MMA수지는 메틸메타크릴레이트 (MethylMethacrylate), 메타크릴산 (Methacrylicacid), 폴리메틸메타크릴레이트 (PolymethylMethacrylate), 부틸메타크릴레이트 (ButylMethacrylate), n-부틸메타크릴레이트 (n-ButylMethacrylate), 이소부틸메타크릴레이트 (IsobutylMethacrylate), 에틸메타크릴레이트 (EthylMethacrylate), 이소프로필메타크릴레이트 (IsopropylMethacrylate), 하이드록시에틸메타크릴레이트 (2-HydroxyethylMethacrylate) 중 적어도 어느 하나 이상을 포함할 수 있다.The MMA resin is methylmethacrylate, methacrylic acid, polymethylmethacrylate, butylmethacrylate, n-butylmethacrylate, isobutyl At least one of IsobutylMethacrylate, EthylMethacrylate, IsopropylMethacrylate, and 2-HydroxyethylMethacrylate may be included.
상기 가교제는 폴리에틸렌글리콜디메타크릴레이트 (PolyEthyleneGlycolDimethacrylate), 폴리프로필렌글리콜디메타크릴레이트 (PolyPropyleneGlycolDimethacrylate), 폴리헥실렌글리콜디메타크릴레이트 (PolyHexyleneGlycolDimethacrylate), 부탄디올디메타크릴레이트 (ButanediolDimethacrylate) 중 적어도 어느 하나 이상을 사용할 수 있다.The crosslinking agent is at least one of PolyEthyleneGlycolDimethacrylate, PolyPropyleneGlycolDimethacrylate, PolyHexyleneGlycolDimethacrylate, and ButanediolDimethacrylate. can be used
상기 가교제는 다량의 에테르 결합체를 함유하고 있어 상기 여러 수지들과 혼합하여 사용할 경우 상기 미끄럼방지 도료의 파단시 신장율과 강도 및 유연성을 향상시키는 역할을 한다. 형성되는 도막의 탄성을 높이는 동시에 양 말단에 반응성 이중결합이 가교반응을 유도하여 가교밀도를 높임으로써 도막의 강도를 높이는 역할을 한다.The crosslinking agent contains a large amount of ether conjugate, and when used in combination with the various resins, serves to improve the elongation, strength and flexibility of the anti-slip paint at break. At the same time as increasing the elasticity of the formed coating, the reactive double bonds at both ends induce a crosslinking reaction to increase the crosslinking density, thereby increasing the strength of the coating.
상기 경화 촉진제로는 과산화벤조일(BenzoylPeroxide)을 사용할 수 있다.BenzoylPeroxide may be used as the curing accelerator.
상기 경화 개시제로는 과산화벤조일과 N,N-디메틸아닐린 (N,N-Dimethylaniline)의 혼합물, 과산화벤조일과 N,N-디메틸-p-톨루이딘 (N,N-Dimethyl-p-toluidine)의 혼합물, 과산화벤조일과 N,N-디하이드록시에틸-p-톨루이딘 (N,N-Dihydroxyethyl-p-toluidine)의 혼합물 중 어느 하나 이상일 수 있다.The curing initiator is a mixture of benzoyl peroxide and N,N-dimethylaniline (N,N-Dimethylaniline), a mixture of benzoyl peroxide and N,N-dimethyl-p-toluidine (N,N-Dimethyl-p-toluidine), It may be any one or more of mixtures of benzoyl peroxide and N,N-dihydroxyethyl-p-toluidine.
또한, 상기 미끄럼 방지 도료는 레벨링제, 소포제 중 어느 하나 이상을 더 포함할 수 있다.In addition, the anti-skid paint may further include any one or more of a leveling agent and an antifoaming agent.
상기 레벨링제는 도막의 유동성을 개량하는 첨가제이다. 건조과정에서 도막의 점성변화에 영향을 미치는 것으로 방향족계, 케톤계, 에스텔계 등과 같은 수지에 대한 도막에서의 용제증발속도를 조정하는 역할을 한다.The leveling agent is an additive that improves the fluidity of the coating film. It affects the viscosity change of the coating film during the drying process, and plays a role in adjusting the solvent evaporation rate in the coating film for resins such as aromatic, ketone, and ester systems.
상기 소포제는 기포를 제거하는데 사용하는 물질로, 일반적으로 휘발성이 적고 확산력이 큰 기름상의 물질 혹은 수용성 계면활성제가 이용된다. 이는 거품생성을 방지 및 감소시키는 물질이다. The antifoaming agent is a material used to remove bubbles, and generally an oily material or a water-soluble surfactant having low volatility and high diffusion power is used. It is a substance that prevents and reduces foaming.
본 발명의 친환경 도막형 미끄럼 방지 포장재는 비불소계 발수제를 더 포함할 수 있다.The eco-friendly coating film-type non-slip packaging material of the present invention may further include a non-fluorine-based water repellent.
상기 비불소계 발수제는 5 내지 12중량부를 포함하는 것이 바람직하며, MMA계 수지 모노머에 유화제를 첨가하여 유화 중합반응을 일으켜 생성할 수 있다.The non-fluorine-based water repellent agent preferably contains 5 to 12 parts by weight, and may be produced by adding an emulsifier to an MMA-based resin monomer to cause an emulsion polymerization reaction.
상기 비불소계 발수제가 5중량부 미만일 경우에는 수분의 흡수를 차단하는 기능이 떨어져 발수효과가 나타나기 어려움이 있고, 12중량부를 초과할 경우에는 발수효과가 뛰어나 미끄럼 방지 포장재에 물 고임 현상이 일어날 수 있어 어려움이 있다. 따라서 상기 비불소계 발수제는 5 내지 12중량부가 가장 바람직하다.If the non-fluorine-based water repellent is less than 5 parts by weight, the ability to block the absorption of moisture is reduced, making it difficult to achieve a water repellent effect. There are difficulties. Therefore, the fluorine-free water repellent agent is most preferably 5 to 12 parts by weight.
상기 비불소계 발수제는 상기 MMA계 수지 모노머와 유화제 및 증류수를 0.45~0.5 : 0.2~0.27 :1.0의 중량비 또는 부피비로 희석하여 희석된 혼합물을 제조하고, 상기 희석된 혼합물을 30℃ 내지 40℃에서 3시간 내지 4시간동안 초음파를 조사하여 유화 중합하여 제조할 수 있다.The fluorine-free water repellent agent is prepared by diluting the MMA-based resin monomer, emulsifier, and distilled water in a weight ratio or volume ratio of 0.45 to 0.5: 0.2 to 0.27: 1.0 to prepare a diluted mixture, and the diluted mixture is 3 at 30 ℃ to 40 ℃. It can be produced by emulsion polymerization by irradiating ultrasonic waves for 1 to 4 hours.
상기 MMA계 수지 모노머는 메틸메타크릴레이트 (MethylMethacrylate), 메타크릴산 (Methacrylicacid), 폴리메틸메타크릴레이트 (PolymethylMethacrylate), 부틸메타크릴레이트 (ButylMethacrylate), n-부틸메타크릴레이트 (n-ButylMethacrylate), 이소부틸메타크릴레이트 (IsobutylMethacrylate), 에틸메타크릴레이트 (EthylMethacrylate), 이소프로필메타크릴레이트 (IsopropylMethacrylate) 및 하이드록시에틸메타크릴레이트 (2-HydroxyethylMethacrylate) 중 적어도 어느 하나 이상을 포함할 수 있다.The MMA-based resin monomer is methylmethacrylate, methacrylic acid, polymethylmethacrylate, butylmethacrylate, n-butylmethacrylate, It may include at least one or more of isobutylmethacrylate, ethylmethacrylate, isopropylmethacrylate, and 2-HydroxyethylMethacrylate.
상기 유화제는 테트라도데실매르캅탄 (tert-dodecylmercaptane), 폴리옥시에틸렌라우릴에테르 (polyoxyethylenelaurylether), 트리메틸스테아릴암모늄염화물 (trimethylstearylammoniumchloride), 글리콜산 (glycolic acid) 및 폴리프로필렌글리콜 (polypropyleneglycol) 중 적어도 어느 하나 이상을 사용할 수 있다.The emulsifier is at least one of tetradodecylmercaptane, polyoxyethylene laurylether, trimethylstearylammoniumchloride, glycolic acid and polypropylene glycol. more can be used.
상기 메틸메타크릴레이트(MMA)는 흔히 아크릴이라 부르며, 플렉시블 글라스의 주요한 원자재이다. 광고판, 간판, 자동차, 디스플레이, 의료 등 다양한 분야에 널리 사용되고 있으며, 건설 구조물에서는 방수재, 미끄럼방지 노면 도포재, 바닥 마감재 및 콘크리트 보수재 등으로 다양한 계열의 제품에 사용되고 있다.The methyl methacrylate (MMA) is commonly referred to as acrylic and is a major raw material for flexible glass. It is widely used in various fields such as billboards, signboards, automobiles, displays, and medical care. In construction structures, it is used in various products such as waterproofing materials, non-slip road coating materials, floor finishing materials, and concrete repair materials.
또한, 상기 메틸메타크릴레이트(MMA)를 주원료로 하여 바닥 도포재로 사용할 경우 골재 및 첨가제 등과 가교 경화반응을 일으켜 고강도의 도막을 빠르게 형성할 수 있다. 경화 시간이 빠르고 간단하며, 영하 30℃까지 작업이 가능하여 날씨의 영향을 받지 않는 특징이 있다.In addition, when the methyl methacrylate (MMA) is used as a floor coating material as a main raw material, a high-strength coating film can be quickly formed by causing a crosslinking and curing reaction with aggregates and additives. Curing time is fast and simple, and it is possible to work at -30℃, so it is not affected by the weather.
또한, 상기 비불소계 발수제는 실란 : 실록산 = 1.0~1.5 : 2.0~2.2의 중량비 또는 부피비로 혼합된 혼합물을 더 포함할 수 있다.In addition, the non-fluorine-based water repellent agent may further include a mixture mixed in a weight ratio or volume ratio of silane : siloxane = 1.0 to 1.5 : 2.0 to 2.2.
상기 실란은 n-옥틸트리에톡시실란 (n-Octyltriethoxysilane), 디메틸에톡시실란 (Dimethyldimethoxysilane), 메틸트라이메톡시실란 (Methyltrimethoxysilane) 및 페닐트리메톡시실란 (Phenyltrimethoxysilane) 중 선택된 어느 하나 이상일 수 있다.The silane may be at least one selected from n-Octyltriethoxysilane, dimethyldimethoxysilane, methyltrimethoxysilane, and phenyltrimethoxysilane.
상기 실록산은 말단에 메톡시기를 가지는 아미노실세스퀴옥산 (Methoxy-terminated amino silsesquioxane), 메틸페닐실록산 (Methylphenyl siloxane) 및 디페닐실록산 (Diphenyl siloxane) 중 선택된 어느 하나 이상일 수 있다.The siloxane may be at least one selected from amino silsesquioxane having a methoxy group at the terminal (Methoxy-terminated amino silsesquioxane), methylphenyl siloxane (Methylphenyl siloxane) and diphenyl siloxane (Diphenyl siloxane).
상기 항균제는 수용성 키토산 : 폴리라이신 = 5.5~6.0 : 2.1~2.7의 중량비 또는 부피비로 혼합된 혼합물을 포함할 수 있고, 10 내지 15중량부를 포함하는 것이 바람직하다.The antimicrobial agent may include a water-soluble chitosan: polylysine = 5.5 to 6.0: 2.1 to 2.7 weight ratio or volume ratio of the mixed mixture, preferably 10 to 15 parts by weight.
여기에서, 상기 수용성 키토산은 마조람추출물, 은행잎추출물, 감초추출물, 유카추출물, 황금추출물, 계피추출물, 자몽종자추출물 및 소리쟁이추출물 중에서 선택된 어느 1종으로 대체할 수 있으며, 추출물은 액상 또는 분말일 수 있다.Here, the water-soluble chitosan may be replaced with any one selected from marjoram extract, ginkgo leaf extract, licorice extract, yucca extract, golden extract, cinnamon extract, grapefruit seed extract, and sorrel extract, and the extract may be liquid or powder. there is.
여기에서, 상기 폴리라이신은 프로폴리스, 카테킨, 플라보노이드, 레스베라트롤 및 이소플라본 중에서 선택된 어느 1종으로 대체할 수 있다.Here, the polylysine may be replaced with any one selected from propolis, catechin, flavonoids, resveratrol, and isoflavones.
상기 미끄럼 방지제는 상기 미끄럼 방지 도료에 패각 : 규사 = 1.5~2.0 : 1.2~1.7의 중량비로 혼합하여 포함되고, 15 내지 35중량부를 포함하는 것이 바람직하다.The anti-slip agent is included in the anti-slip paint in a weight ratio of shell: silica sand = 1.5 to 2.0: 1.2 to 1.7, preferably 15 to 35 parts by weight.
상기 패각은 굴, 전복, 바지락, 꼬막, 소라, 고둥, 개조개, 맛조개, 모시조개, 대합, 홍합, 백합, 재첩, 동죽 중 어느 하나 이상 포함하는 것을 특징으로 한다.The shell is characterized in that it comprises any one or more of oysters, abalone, clams, cockles, conch, snails, clams, taste clams, ramie clams, clams, mussels, lilies, clams, and dongjuk.
상기 패각은 전처리를 실시하여 상기 패각 내부의 염분 및 이물질을 제거하여 사용할 수 있다.The shell may be used by performing a pretreatment to remove salt and foreign substances inside the shell.
상기 패각의 전처리 단계는 흐르는 물에 세척하는 세척단계; 증류수에 24시간 내지 36시간 동안 침수하는 단계; 30 내지 50 kHz의 주파수로 30분 내지 60분동안 초음파 조사하는 단계; 24시간 내지 36시간 동안 건조하는 단계 및 질산과 증류수를 1:20 내지 1:40의 비율로 희석한 혼합물에 10분 내지 30분동안 침지시키는 단계;를 포함할 수 있다.The pretreatment step of the shell is a washing step of washing in running water; immersion in distilled water for 24 to 36 hours; irradiating ultrasonic waves at a frequency of 30 to 50 kHz for 30 to 60 minutes; It may include a step of drying for 24 hours to 36 hours and immersing for 10 minutes to 30 minutes in a mixture diluted with nitric acid and distilled water at a ratio of 1:20 to 1:40.
상기 패각은 마찰성 부여 등 미끄럼 방지기능을 수행함과 더불어 유해 증식균을 억제하는 항균 활성기능을 함께 구현할 수 있다.In addition to performing anti-slip functions such as imparting frictional properties, the shells can also implement an antibacterial activity function that suppresses harmful proliferative bacteria.
상기 규사는 천연석으로부터 수득되는 자연 골재로, 건축 재료나 바닥 포장재의 표층으로 많이 사용되는 투수성이 높은 친환경 재료이다. 실리카(SiO2)를 주성분으로 이루어진 광물 또는 암석류를 칭하는 것으로, 물리적 성질로서 색상은 백색, 황색, 도색 및 자색 등을 띠고 있어 색상의 선택 폭이 넓고 주변환경에 잘 어우러지며 유지비용이 저렴하다는 장점이 있다. The silica sand is a natural aggregate obtained from natural stones, and is an eco-friendly material with high water permeability that is often used as a surface layer of building materials or floor paving materials. It refers to minerals or rocks whose main component is silica (SiO 2 ), and as a physical property, the color is white, yellow, painted, and purple. There are advantages.
또한, 상기 규사는 일반적으로 호수에 따라 용도가 규격화 되어있다. 예를 들면, 2호는 2.5~4.0mm의 크기를 가지며 미끄럼 방지용도로 사용되고, 3호는 1.5~2.5mm의 크기를 가지며 벙커사, 여과사, 그라우팅, 하드너 및 샌딩사 등의 용도로 사용되고 있다. In addition, the use of the silica sand is generally standardized according to the lake. For example, No. 2 has a size of 2.5 to 4.0 mm and is used for anti-skid purposes, and No. 3 has a size of 1.5 to 2.5 mm and is used for bunker sand, filter sand, grouting, hardener, and sanding sand.
여기에서, 상기 패각은 분말의 형태로 사용되며 그 크기는 3.15mm 내지 4.7mm로 분쇄하는 것이 바람직하고, 상기 규사는 미끄럼방지 용도로 사용되는 2호 크기인 2.5mm 내지 4.0mm로 이루어지는 것을 사용하는 것이 바람직하다.Here, the shell is used in the form of powder, and the size is preferably pulverized to 3.15 mm to 4.7 mm, and the silica sand is used for non-slip purposes, using a No. 2 size consisting of 2.5 mm to 4.0 mm. it is desirable
상기 패각과 상기 규사 혼합물은 유사한 크기로 도입되어 서로 유기적인 관계로 작용하여 미끄럼방지 기능을 향상시킬 수 있다.The shell and the silica sand mixture may be introduced in a similar size and act in an organic relationship with each other to improve the anti-slip function.
상기 미끄럼 방지제는 패각 : 규사 : 폐목재 칩 = 1.5~2.0 : 1.2~1.7 : 1.0~1.2의 중량비로 혼합하여 형태로 추가하는 구성일 수 있다.The anti-slip agent may be added in the form of mixing in a weight ratio of shell : silica sand : waste wood chip = 1.5~2.0 : 1.2~1.7 : 1.0~1.2.
상기 폐목재 칩은 벌채나 후동목 등 활용되지 못하는 임목부산물을 자원화 한 것으로 건설현장이나 제조사업장에서 버려지는 폐목재를 잘게 파쇄하여 칩 형태로 제작한 것이다. 이는 환경 친화적 보도포장재로 사용될 수 있으며, 투수성이 높아 빗물을 침투시키고 통기성에 의해 산소를 공급하여 토양의 산소결핍 방지 및 가로수 생육 촉진에 도움을 줄 수 있다. 또한, 보도의 물고임 방지 및 미끄럼 저항성 증진에 의해 쾌적하고 안전한 보행 환경의 제공하는 기능을 제공할 수 있다.The waste wood chips are resources made of forest by-products that are not utilized, such as felling or post-dongmok, and are produced in the form of chips by finely shredding waste wood discarded at construction sites or manufacturing sites. It can be used as an environmentally friendly sidewalk paving material, and it can help prevent oxygen deficiency in the soil and promote the growth of street trees by infiltrating rainwater and supplying oxygen through air permeability due to its high permeability. In addition, it is possible to provide a function of providing a pleasant and safe walking environment by preventing water puddles and improving slip resistance of the sidewalk.
또한, 상기 미끄럼 방지제는 미끄럼 방지 효과를 향상시키는 나노 콜로이달 실리카를 더 포함하고, 상기 나노 콜로이달 실리카는 입자 평균이 10 내지 15nm이고 비중이 1.90 내지 2.3인 실리카에 아민계 알칼리 촉매를 반응시켜 제조함으로써 마찰성을 향상시킬 수 있다.In addition, the anti-slip agent further comprises nano colloidal silica that improves the anti-slip effect, and the nano-colloidal silica is prepared by reacting an amine-based alkali catalyst with silica having a particle average of 10 to 15 nm and a specific gravity of 1.90 to 2.3 By doing so, friction can be improved.
상기 아민계 알칼리 촉매는 메틸기, 에틸기, 프로필기, 이소프로필기, 부틸기, 펜틸기 및 헥실기 중 어느 하나 이상 포함하고, 알킬기에 1차아민, 2차아민 및 3차아민 중 어느 하나 이상 포함하는 것이 바람직하다.The amine-based alkali catalyst includes at least one of a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a pentyl group, and a hexyl group, and at least one of primary amine, secondary amine, and tertiary amine is included in the alkyl group. It is desirable to do
본 발명의 친환경 도막형 미끄럼 방지 포장재는 칼슘마그네슘아세테이트 [CaMg2(CH3CO2)6], 요소 [(NH2)2CO] 중 적어도 어느 하나 이상으로 이루어지는 비염화물계 제설제를 더 포함할 수 있고, 5 내지 10중량부를 포함하는 것이 바람직하다.The eco-friendly coating-type non-slip packaging material of the present invention may further include a non-chloride-based snow removal agent composed of at least one of calcium magnesium acetate [CaMg 2 (CH 3 CO 2 ) 6 ] and urea [(NH 2 ) 2 CO]. It may be, and it is preferable to include 5 to 10 parts by weight.
상기 비염화물계 제설제는 염소이온에 의한 부식을 방지하기 위하여 개발되고 있으며, 주차장, 다리, 공항 내부도로 등 특수환경의 도로와 외부에 주로 사용되어지고 있고, 제설성이 우수하다.The non-chloride-based snow removal agent is being developed to prevent corrosion by chlorine ions, and is mainly used for roads and exteriors in special environments such as parking lots, bridges, and airport internal roads, and has excellent snow removal properties.
상기 칼슘마그네슘아세테이트는 고농축 아세트산과 석회석의 반응을 통하여 제조된다. 아세트산은 옥수수 발효공정을 통하여 제조되므로 친환경적이다.The calcium magnesium acetate is prepared through the reaction of highly concentrated acetic acid and limestone. Acetic acid is eco-friendly because it is produced through the corn fermentation process.
또한, 본 발명은 친환경 도막형 미끄럼 방지 포장재의 제조방법을 제공한다. In addition, the present invention provides a method for manufacturing an eco-friendly coating film type non-slip packaging material.
본 발명의 친환경 도막형 미끄럼 방지 포장재의 제조방법은 전술한 친환경 도막형 미끄럼 방지 포장재의 기술적인 특징을 공유하므로 따라서 중첩되는 부분에 대한 설명은 생략하기로 한다.Since the manufacturing method of the eco-friendly coating film-type anti-slip packaging material of the present invention shares the technical characteristics of the above-described eco-friendly coating film-type anti-slip packaging material, description of overlapping parts will be omitted.
본 발명은 친환경 도막형 미끄럼 방지 포장재의 제조방법은 도 1의 제조공정도를 참조하여 하기에 설명하도록 한다.The present invention will be described below with reference to the manufacturing process diagram of FIG.
도 1은 본 발명의 친환경 도막형 미끄럼 방지 포장재의 제조방법을 개략적으로 도시한 제조공정도이다.1 is a manufacturing process diagram schematically showing a manufacturing method of an eco-friendly coating film-type non-slip packaging material of the present invention.
도 1에 따르면, 본 발명의 친환경 도막형 미끄럼 방지 포장재의 제조방법은 상기 친환경 도막형 미끄럼 방지 포장재의 고분자 수지, 경화촉진제, 경화개시제 및 가교제 중 어느 하나 이상을 혼합하여 이루어지는 미끄럼 방지 도료; 항균성 물질로 이루어지는 항균제; 및 패각, 규사를 포함하는 미끄럼 방지제;를 준비하는 준비단계; 상기 미끄럼방지 도료, 항균제 및 미끄럼 방지제를 혼합하는 혼합단계;를 포함한다.According to Figure 1, the manufacturing method of the eco-friendly coating film-type non-slip packaging material of the present invention is an anti-slip paint obtained by mixing at least one of a polymer resin, a curing accelerator, a curing initiator, and a crosslinking agent of the eco-friendly coating film-type anti-slip packaging material; an antibacterial agent made of an antibacterial substance; And a shell, anti-slip agent containing silica sand; a preparation step of preparing; A mixing step of mixing the anti-slip paint, antibacterial agent and anti-slip agent; includes.
여기에서, 상기 준비단계는 상기 패각의 전처리단계를 포함한다. Here, the preparation step includes a pre-processing step of the shell.
상기 패각은 전처리를 실시하여 상기 패각 내부의 염분 및 이물질을 제거하여 사용할 수 있다.The shell may be used by performing a pretreatment to remove salt and foreign substances inside the shell.
상기 패각의 전처리 단계는 흐르는 물에 세척하는 세척단계; 증류수에 24시간 내지 36시간 동안 침수하는 단계; 30 내지 50 kHz의 주파수로 30분 내지 60분동안 초음파 조사하는 단계; 24시간 내지 36시간 동안 건조하는 단계 및 질산과 증류수를 1:20 내지 1:40의 비율로 희석한 혼합물에 10분 내지 30분동안 침지시키는 단계;를 포함하는 것이 바람직하다. The pretreatment step of the shell is a washing step of washing in running water; immersion in distilled water for 24 to 36 hours; irradiating ultrasonic waves at a frequency of 30 to 50 kHz for 30 to 60 minutes; It is preferable to include; drying for 24 hours to 36 hours and immersing in a mixture diluted with nitric acid and distilled water in a ratio of 1:20 to 1:40 for 10 minutes to 30 minutes.
본 발명의 친환경 도막형 미끄럼 방지 포장재 및 그 제조방법을 이용하여 인·보도, 차도의 미끄럼방지포장, 자전거도로포장, 어린이보호구역, 공원구역, 버스전용차로, 건축물의 옥상콘크리트, 철골형의 자동차주차장 등에 도포하여 미끄럼방지층을 형성할 수 있다.Anti-slip pavement of sidewalks and roads, bicycle road pavement, children's protection area, park area, bus lane, rooftop concrete of buildings, and steel-framed automobiles It can be applied to a parking lot or the like to form an anti-slip layer.
이하, 본 발명은 실시 예를 통하여 더욱 구체적으로 설명되나, 본 발명이 이러한 실시 예에 의하여 한정되는 것은 아니다. Hereinafter, the present invention will be described in more detail through examples, but the present invention is not limited by these examples.
(실시 예1)(Example 1)
본 발명의 친환경 도막형 미끄럼 방지 포장재 제조Manufacturing of eco-friendly coating type non-slip packaging material of the present invention
메틸메타크릴레이트 20중량부, 부틸아크릴레이트 20중량부, 폴리에틸렌글리콜디메타크릴레이트 14중량부를 혼합한 고분자 수지에 과산화벤조일과 N,N-디메틸 아닐린 (N,N-Dimethylaniline)을 1:1로 희석한 혼합물 0.8중량부를 혼합하여 미끄럼방지 도료를 제조하였다.20 parts by weight of methyl methacrylate, 20 parts by weight of butyl acrylate, and 14 parts by weight of polyethylene glycol dimethacrylate were mixed with a polymer resin containing benzoyl peroxide and N,N-dimethylaniline at a ratio of 1:1 An anti-slip paint was prepared by mixing 0.8 parts by weight of the diluted mixture.
MMA계 수지 모노머 10중량부에 테트라도데실매르캅탄 5중량부, 글리콜산 2중량부로 이루어지는 유화제를 첨가한 후 초음파를 조사하여 유화중합함으로써 발수제를 제조하여 상기 미끄럼방지 도료에 첨가하였다.An emulsifier consisting of 5 parts by weight of tetradodecylmercaptan and 2 parts by weight of glycolic acid was added to 10 parts by weight of MMA-based resin monomer, and then irradiated with ultrasonic waves to perform emulsion polymerization to prepare a water repellent and added to the anti-slip paint.
상기 발수처리가 완료된 미끄럼방지 도료에 수용성 키토산 : 폴리라이신 = 5.5 : 2.1의 중량비로 혼합된 항균제와 전처리를 완료한 패각 : 규사 = 1.5:1.2의 중량비로 혼합된 미끄럼 방지제를 첨가하여 친환경 도막형 미끄럼방지 포장재를 제조하였다.To the water-repellent anti-slip paint, water-soluble chitosan: polylysine = 5.5: 2.1 in weight ratio and pre-treated shell: silica sand = 1.5: 1.2 by adding anti-slip agent mixed in weight ratio to eco-friendly coating type slip A protective packaging material was prepared.
(시험 예1)(Test Example 1)
상기 실시 예1에 의하여 제조된 친환경 도막형 미끄럼 방지 포장재의 물성평가Evaluation of physical properties of the eco-friendly coating type non-slip packaging material prepared in Example 1
상기 실시 예1에 의하여 제조된 친환경 도막형 미끄럼 방지 포장재를 노면에 도포한 후, 하기와 같은 특성을 비교하여 그 결과를 하기 표 1에 나타내었다.After applying the eco-friendly coating film-type anti-slip packaging material prepared in Example 1 to the road surface, the following characteristics were compared and the results are shown in Table 1 below.
비교 예1은 실시 예1과 같은 방법으로 미끄럼방지 도료조성물을 제조한 후 미끄럼방지제로 패각만 사용하여 미끄럼방지 포장재를 제조하였다.In Comparative Example 1, an anti-slip coating composition was prepared in the same manner as in Example 1, and then an anti-slip packaging material was prepared using only shells as an anti-slip agent.
비교 예2는 실시 예1과 같은 방법으로 미끄럼방지 도료조성물을 제조한 후 미끄럼방지제로 규사만 사용하여 도막형 미끄럼방지 포장재를 제조하였다. In Comparative Example 2, an anti-slip coating composition was prepared in the same manner as in Example 1, and then a coating-type anti-slip packaging material was prepared using only silica sand as an anti-slip agent.
비교 예3은 실시 예1과 같은 방법으로 미끄럼방지 도료조성물을 제조한 후 미끄럼방지제로 폐목재 칩만 사용하여 도막형 미끄럼방지 포장재를 제조하였다. In Comparative Example 3, an anti-slip coating composition was prepared in the same manner as in Example 1, and then a coating-type anti-slip packaging material was prepared using only waste wood chips as an anti-slip agent.
또한, KS F 2375(노면의 미끄럼 저항성 시험방법)에 의해 미끄럼 저항성(BPN)을 측정하였다. In addition, slip resistance (BPN) was measured according to KS F 2375 (road surface slip resistance test method).
상기 표 1에 따르면, 실시 예1의 미끄럼 저항성(BPN) 기준치인 40BPN 보다 높은 90BPN으로 매우 강력한 미끄럼 저항성을 가지는 것으로 나타났고, 투수성, 제설성 및 마모상태도 비교 예1 내지 비교 예3에 비하여 우수한 것으로 나타났다.According to Table 1, it was found to have very strong slip resistance with 90 BPN, which is higher than the slip resistance (BPN) standard of 40 BPN of Example 1, and water permeability, snow removal and abrasion conditions were also compared to Comparative Examples 1 to 3 appeared to be excellent.
이에 따라, 상술한 본 발명을 통해서는 고분자를 포함하는 미끄럼 방지 도료에 친환경 물질을 적용함으로써 도막 형성 시 노면과 접착성이 우수하고 내마모성 및 내구성이 향상되며, 특히 바닥 표면의 마찰계수를 향상시켜 미끄러짐을 저하시킬 수 있으며, 항균제의 접목으로 우수한 항균성을 발휘할 수 있고 제설제의 접목으로 우수한 제설성을 발휘할 수 있는 친환경 도막형 미끄럼 방지 포장재를 제공할 수 있다.Accordingly, through the present invention described above, by applying an eco-friendly material to an anti-slip paint containing a polymer, adhesion to the road surface is excellent and wear resistance and durability are improved when forming a coating film, and in particular, the friction coefficient of the floor surface is improved to prevent slipping It is possible to provide an eco-friendly coating-type anti-slip packaging material capable of exhibiting excellent antibacterial properties by grafting antibacterial agents and excellent snow removal properties by grafting antibacterial agents.
본 발명이 속하는 기술분야의 통상의 지식을 가진 자는 본 발명이 그 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다. 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구의 범위에 의하여 나타내어지며, 특허청구의 범위의 의미 및 범위 그리고 그 균등 개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.Those skilled in the art to which the present invention pertains will understand that the present invention can be embodied in other specific forms without changing its technical spirit or essential features. Therefore, the embodiments described above should be understood as illustrative in all respects and not limiting. The scope of the present invention is indicated by the claims to be described later rather than the detailed description above, and all changes or modifications derived from the meaning and scope of the claims and equivalent concepts thereof are included in the scope of the present invention. should be interpreted
Claims (12)
고분자 수지, 경화촉진제, 경화개시제 및 가교제 중 적어도 어느 하나 이상을 혼합하여 이루어지는 미끄럼 방지 도료;
항균성 물질로 이루어지는 항균제; 및
패각, 규사를 포함하는 미끄럼 방지제;를 포함하고,
상기 친환경 도막형 미끄럼 방지 포장재 100중량부를 기준으로, 상기 미끄럼 방지 도료는 40 내지 55 중량부이고, 상기 항균제는 10 내지 15중량부이고, 상기 미끄럼 방지제는 15 내지 35중량부로 이루어지고,
상기 고분자 수지는 에폭시 수지, 아크릴 수지, MMA수지, 우레탄 수지, 우레아 수지 및 스틸렌 단량체 중 적어도 어느 하나 이상을 포함하고,
상기 미끄럼 방지제 중 포함된 상기 패각과 규사의 혼합비는 1.5~2.0 : 1.2~1.7 중량비로 혼합되고,
상기 미끄럼방지제는 미끄럼 방지 효과를 향상시키는 나노 콜로이달 실리카를 더 포함하되,
상기 나노 콜로이달 실리카는 입자 평균이 10 내지 15nm이고 비중이 1.90 내지 2.3인 실리카에 아민계 알칼리 촉매를 반응시켜 제조되고,
상기 항균제는 수용성 키토산, 마조람추출물, 은행잎추출물, 감초추출물, 유카추출물, 황금추출물, 계피추출물, 자몽종자추출물 및 소리쟁이추출물 중에서 선택된 1종에 의한 제 1항균물질 : 폴리라이신, 프로폴리스, 카테킨, 플라보노이드, 레스베라트롤 및 이소플라본 중에서 선택된 1종에 의한 제 2항균물질 = 5.5~6.0 : 2.1~2.7의 중량비 또는 부피비로 혼합된 혼합물을 포함하는 것을 특징으로 하는 친환경 도막형 미끄럼 방지 포장재.In the eco-friendly coating type non-slip packaging material,
An anti-slip paint obtained by mixing at least one of a polymer resin, a curing accelerator, a curing initiator, and a crosslinking agent;
an antibacterial agent made of an antibacterial substance; and
Including; shell, anti-slip agent containing silica sand;
Based on 100 parts by weight of the eco-friendly coating type anti-slip packaging material, the anti-slip paint is 40 to 55 parts by weight, the antibacterial agent is 10 to 15 parts by weight, and the anti-slip agent is 15 to 35 parts by weight,
The polymer resin includes at least one or more of an epoxy resin, an acrylic resin, an MMA resin, a urethane resin, a urea resin, and a styrene monomer,
The mixing ratio of the shell and silica sand included in the anti-slip agent is 1.5 to 2.0: 1.2 to 1.7 in a weight ratio,
The anti-slip agent further comprises nano colloidal silica to improve the anti-slip effect,
The nano colloidal silica is prepared by reacting an amine-based alkali catalyst with silica having a particle average of 10 to 15 nm and a specific gravity of 1.90 to 2.3,
The antibacterial agent is water-soluble chitosan, marjoram extract, ginkgo leaf extract, licorice extract, yucca extract, gold extract, cinnamon extract, grapefruit seed extract, and sorrel extract, the first antibacterial substance by one selected from: polylysine, propolis, catechin, A second antibacterial substance by one selected from flavonoids, resveratrol, and isoflavones = 5.5 to 6.0: An eco-friendly coating type non-slip packaging material comprising a mixture mixed in a weight ratio or volume ratio of 2.1 to 2.7.
상기 친환경 도막형 미끄럼 방지 포장재는 비불소계 발수제를 더 포함하고,
상기 비불소계 발수제는 MMA계 수지 모노머에 유화제를 첨가하여 유화 중합반응으로 생성되고,
상기 친환경 도막형 미끄럼 방지 포장재 100중량부에 대하여 상기 비불소계 발수제 5 내지 12중량부를 포함하는 것을 특징으로 하는 친환경 도막형 미끄럼 방지 포장재.According to claim 1,
The eco-friendly coating film-type non-slip packaging material further includes a fluorine-free water repellent,
The fluorine-free water repellent is produced by emulsion polymerization by adding an emulsifier to an MMA-based resin monomer,
Eco-friendly coating film-type anti-slip packaging material, characterized in that it comprises 5 to 12 parts by weight of the fluorine-free water repellent based on 100 parts by weight of the eco-friendly coating film-type anti-slip packaging material.
상기 비불소계 발수제는,
상기 MMA계 수지 모노머와 유화제 및 증류수를 0.45~0.5 : 0.2~0.27 :1.0의 중량비로 희석하여 희석된 혼합물을 제조하고,
상기 희석된 혼합물을 30℃ 내지 40℃에서 3시간 내지 4시간동안 초음파를 조사하여 유화 중합하여 제조되는 것을 특징으로 하는 친환경 도막형 미끄럼 방지 포장재.According to claim 2,
The fluorine-free water repellent,
Diluting the MMA-based resin monomer, emulsifier, and distilled water in a weight ratio of 0.45 to 0.5: 0.2 to 0.27: 1.0 to prepare a diluted mixture,
Eco-friendly coating type non-slip packaging material, characterized in that prepared by emulsion polymerization of the diluted mixture by irradiating ultrasonic waves at 30 ° C to 40 ° C for 3 to 4 hours.
상기 MMA계 수지 모노머는 메틸메타크릴레이트 (MethylMethacrylate), 메타크릴산 (Methacrylicacid), 폴리메틸메타크릴레이트 (PolymethylMethacrylate), 부틸메타크릴레이트 (ButylMethacrylate), n-부틸메타크릴레이트 (n-ButylMethacrylate), 이소부틸메타크릴레이트 (IsobutylMethacrylate), 에틸메타크릴레이트 (EthylMethacrylate), 이소프로필메타크릴레이트 (IsopropylMethacrylate) 및 하이드록시에틸메타크릴레이트 (2-HydroxyethylMethacrylate) 중 적어도 어느 하나 이상을 포함하고,
상기 유화제는 테트라도데실매르캅탄 (tert-dodecylmercaptane), 폴리옥시에틸렌라우릴에테르 (polyoxyethylenelaurylether), 트리메틸스테아릴암모늄염화물 (trimethyl stearyl ammonium chloride), 글리콜산 (glycolicacid) 및 폴리프로필렌글리콜 (polypropyleneglycol) 중 적어도 어느 하나 이상을 포함하는 것을 특징으로 하는 친환경 도막형 미끄럼 방지 포장재.According to claim 2,
The MMA-based resin monomer is methylmethacrylate, methacrylic acid, polymethylmethacrylate, butylmethacrylate, n-butylmethacrylate, At least one or more of isobutylmethacrylate, ethylmethacrylate, isopropylmethacrylate and 2-HydroxyethylMethacrylate,
The emulsifier is at least one of tetradodecylmercaptane, polyoxyethylene laurylether, trimethyl stearyl ammonium chloride, glycolic acid and polypropylene glycol. An eco-friendly coating-type non-slip packaging material comprising at least one.
상기 비불소계 발수제는,
실란 : 실록산 = 1.0~1.5 : 2.0~2.2의 중량비로 혼합된 혼합물을 더 포함하고,
상기 실란은 n-옥틸트리에톡시실란 (n-Octyltriethoxysilane), 디메틸에톡시실란 (Dimethyldimethoxysilane), 메틸트라이메톡시실란 (Methyltrimethoxysilane) 및 페닐트리메톡시실란 (Phenyltrimethoxysilane) 중 적어도 어느 하나 이상을 포함하며,
상기 실록산은 말단에 메톡시기를 가지는 아미노실세스퀴옥산 (Methoxy-terminatedaminosilsesquioxane), 메틸페닐실록산 (Methylphenylsiloxane) 및 디페닐실록산 (Diphenylsiloxane) 중 적어도 어느 하나 이상을 포함하는 것을 특징으로 하는 친환경 도막형 미끄럼 방지 포장재.According to claim 2,
The fluorine-free water repellent,
Further comprising a mixture mixed in a weight ratio of silane: siloxane = 1.0 to 1.5: 2.0 to 2.2,
The silane includes at least one or more of n-octyltriethoxysilane, dimethyldimethoxysilane, methyltrimethoxysilane, and phenyltrimethoxysilane,
The siloxane is an eco-friendly coating type non-slip packaging material, characterized in that it contains at least one of aminosilsesquioxane having a methoxy group at the terminal (Methoxy-terminated aminosilsesquioxane), methylphenylsiloxane and diphenylsiloxane (Diphenylsiloxane) .
칼슘마그네슘아세테이트[CaMg2(CH3CO2)6], 요소[(NH2)2CO] 중 적어도 어느 하나 이상으로 이루어지는 비염화물계 제설제 5 내지 10중량부를 더 포함하는 것을 특징으로 하는 친환경 도막형 미끄럼 방지 포장재.According to claim 1,
Eco-friendly coating film characterized in that it further comprises 5 to 10 parts by weight of a non-chloride-based snow removal agent consisting of at least one of calcium magnesium acetate [CaMg 2 (CH 3 CO 2 ) 6 ] and urea [(NH 2 ) 2 CO] anti-skid packaging.
상기 미끄럼방지 도료, 항균제 및 미끄럼 방지제를 혼합하는 혼합단계;를 포함하여 제조되고,
상기 준비단계는 상기 패각의 전처리단계 포함하고,
상기 전처리단계는,
흐르는 물에 세척하는 세척단계;
증류수에 24시간 내지 36시간 동안 침수하는 단계;
30 내지 50 kHz의 주파수로 30분 내지 60분동안 초음파 조사하는 단계;
24시간 내지 36시간 동안 건조하는 단계; 및
질산과 증류수를 1:20 내지 1:40의 비율로 희석한 혼합물에 10분 내지 30분동안 침지시키는 단계;를 포함하여 상기 패각 내부의 염분 및 이물질을 제거하고,
상기 항균제는 수용성 키토산, 마조람추출물, 은행잎추출물, 감초추출물, 유카추출물, 황금추출물, 계피추출물, 자몽종자추출물 및 소리쟁이추출물 중에서 선택된 1종에 의한 제 1항균물질 : 폴리라이신, 프로폴리스, 카테킨, 플라보노이드, 레스베라트롤 및 이소플라본 중에서 선택된 1종에 의한 제 2항균물질 = 5.5~6.0 : 2.1~2.7의 중량비 또는 부피비로 혼합된 혼합물을 포함하는 것을 특징으로 하는 친환경 도막형 미끄럼 방지 포장재의 제조방법.An anti-slip paint obtained by mixing at least one of a polymer resin, a curing accelerator, a curing initiator, and a crosslinking agent; an antibacterial agent made of an antibacterial substance; And a shell, anti-slip agent containing silica sand; a preparation step of preparing;
A mixing step of mixing the anti-slip paint, antibacterial agent and anti-slip agent;
The preparation step includes a pre-processing step of the shell,
In the preprocessing step,
Washing step of washing with running water;
immersion in distilled water for 24 to 36 hours;
irradiating ultrasonic waves at a frequency of 30 to 50 kHz for 30 to 60 minutes;
drying for 24 to 36 hours; and
immersing for 10 minutes to 30 minutes in a mixture diluted with nitric acid and distilled water at a ratio of 1:20 to 1:40; to remove salt and foreign substances inside the shell,
The antibacterial agent is water-soluble chitosan, marjoram extract, ginkgo leaf extract, licorice extract, yucca extract, gold extract, cinnamon extract, grapefruit seed extract, and sorrel extract, the first antibacterial substance by one selected from: polylysine, propolis, catechin, A method for producing an eco-friendly coating-type non-slip packaging material comprising a mixture mixed in a weight ratio or volume ratio of 2.1 to 2.7 with a second antibacterial substance by one selected from flavonoids, resveratrol and isoflavones = 5.5 to 6.0.
상기 고분자 수지는 에폭시 수지, 아크릴 수지, MMA수지, 우레탄 수지, 우레아 수지 및 스틸렌 단량체 중 적어도 어느 하나 이상을 포함하고,
상기 미끄럼 방지제 중 포함된 상기 패각과 규사의 혼합비는 1.5~2.0 : 1.2~1.7 중량비로 혼합되는 것을 특징으로 하는 친환경 도막형 미끄럼 방지 포장재의 제조방법.According to claim 9,
The polymer resin includes at least one or more of an epoxy resin, an acrylic resin, an MMA resin, a urethane resin, a urea resin, and a styrene monomer,
The mixing ratio of the shell and silica sand contained in the anti-slip agent is 1.5 to 2.0: 1.2 to 1.7 Method for producing an eco-friendly coating type anti-slip packaging material, characterized in that mixed in a weight ratio.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020220081725A KR102524739B1 (en) | 2022-07-04 | 2022-07-04 | Eco-friendly coating type anti-slip paving material and the manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020220081725A KR102524739B1 (en) | 2022-07-04 | 2022-07-04 | Eco-friendly coating type anti-slip paving material and the manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR102524739B1 true KR102524739B1 (en) | 2023-04-24 |
Family
ID=86141828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020220081725A KR102524739B1 (en) | 2022-07-04 | 2022-07-04 | Eco-friendly coating type anti-slip paving material and the manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR102524739B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102661707B1 (en) | 2024-02-16 | 2024-04-29 | 주식회사 영신테크 | Non-slip pavement agent and pavement method using it |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100955458B1 (en) * | 2009-12-29 | 2010-04-29 | 이윤호 | Eco-Friendly Acrylic Emulsion Anti-Slip Paint Composition |
| KR100985558B1 (en) * | 2009-10-21 | 2010-10-05 | 이랜드체육산업 (주) | Water permeable elasticity pavement having oyster shell and manufacturing method and construction method thereof |
| KR101001949B1 (en) * | 2010-04-15 | 2010-12-17 | (주)원탑건설 | Pavement method for easy maintenance in winter |
| KR101045361B1 (en) | 2011-01-24 | 2011-06-30 | 우리개발주식회사 | Environment friendly pavement and coating floor for non slip using yellow soil |
| KR20120029264A (en) * | 2010-09-16 | 2012-03-26 | 주식회사 패턴크리트 | Eco-friendly, non-slip and anti-bacteria paving composite, manufacturing method of the same and road paving method of using the same |
| KR101440512B1 (en) * | 2014-04-15 | 2014-09-17 | 문진호 | Antiskid paving material comprising hybrid composites of methylmetacrylate-tetraethylorthosilicate and method for manufacturing thereof |
-
2022
- 2022-07-04 KR KR1020220081725A patent/KR102524739B1/en active IP Right Grant
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100985558B1 (en) * | 2009-10-21 | 2010-10-05 | 이랜드체육산업 (주) | Water permeable elasticity pavement having oyster shell and manufacturing method and construction method thereof |
| KR100955458B1 (en) * | 2009-12-29 | 2010-04-29 | 이윤호 | Eco-Friendly Acrylic Emulsion Anti-Slip Paint Composition |
| KR101001949B1 (en) * | 2010-04-15 | 2010-12-17 | (주)원탑건설 | Pavement method for easy maintenance in winter |
| KR20120029264A (en) * | 2010-09-16 | 2012-03-26 | 주식회사 패턴크리트 | Eco-friendly, non-slip and anti-bacteria paving composite, manufacturing method of the same and road paving method of using the same |
| KR101045361B1 (en) | 2011-01-24 | 2011-06-30 | 우리개발주식회사 | Environment friendly pavement and coating floor for non slip using yellow soil |
| KR101440512B1 (en) * | 2014-04-15 | 2014-09-17 | 문진호 | Antiskid paving material comprising hybrid composites of methylmetacrylate-tetraethylorthosilicate and method for manufacturing thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102661707B1 (en) | 2024-02-16 | 2024-04-29 | 주식회사 영신테크 | Non-slip pavement agent and pavement method using it |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111548592B (en) | MMA polymer thin-layer color antiskid paving material and preparation method and construction method thereof | |
| KR101462203B1 (en) | Environment-friendly Hardfacing and Waterproofing Composition for Non-Slip Grooving and Constructing Methods using Thereof | |
| KR100927665B1 (en) | High elastic mma resin and strengthening method for poruos asphalt pavements using the same | |
| KR101022197B1 (en) | Pavement composition for anti-slip | |
| MX2011001966A (en) | Composition and process of using an asphalt emulsion to convert an unpaved surface into a paved surface. | |
| KR100757235B1 (en) | Colored and nonskid cement composition and pavement method of the same | |
| KR101663584B1 (en) | Asphalt Concrete Composition of Improving Durability for Paving Using Seaweeds and Constructing Methods Using Thereof | |
| KR101045361B1 (en) | Environment friendly pavement and coating floor for non slip using yellow soil | |
| KR20010074609A (en) | A functional non-slip paint use of profile for road and the manufacturing method of the same | |
| KR100780574B1 (en) | The method and paved road to protect sliding | |
| KR102524739B1 (en) | Eco-friendly coating type anti-slip paving material and the manufacturing method thereof | |
| KR100526414B1 (en) | Color paving-material for non-slip | |
| KR20200032392A (en) | Acrylic anti-slip coating composition | |
| KR100991501B1 (en) | Permeable concrete and paving method for road using the same | |
| JPH11181707A (en) | Pavement method using water-permeable resin pavement material, and manufacture of block | |
| KR101442536B1 (en) | Non-slip pavement composition, method for producing and constructing the same | |
| KR101045359B1 (en) | Environment friendly pavement and coating floor for non slip using yellow soil | |
| CN202208874U (en) | Anti-skid permeable road mat | |
| KR101106529B1 (en) | Paving material composion for bike-path containing polystyrene and paving method using the same | |
| KR101764201B1 (en) | Paving repair materials composition and method for forming paving repair materials layer | |
| US20090196690A1 (en) | Anti-slip composition and method of forming anti-slip layer using the same | |
| KR20100093183A (en) | Polymer color concreteand and pavement method of thereof | |
| KR100775993B1 (en) | Color permeable stone and pavement method thereof | |
| KR102187159B1 (en) | Slip-resistant non-slip composition using cement mixture and slip-resistant construction method using it | |
| KR101032041B1 (en) | Road paving materials using bottom ash |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant |