KR102450090B1 - Composition for printing cotton fabric - Google Patents

Composition for printing cotton fabric Download PDF

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KR102450090B1
KR102450090B1 KR1020220103358A KR20220103358A KR102450090B1 KR 102450090 B1 KR102450090 B1 KR 102450090B1 KR 1020220103358 A KR1020220103358 A KR 1020220103358A KR 20220103358 A KR20220103358 A KR 20220103358A KR 102450090 B1 KR102450090 B1 KR 102450090B1
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weight
printing
composition
dye
cotton fabric
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KR1020220103358A
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Korean (ko)
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박동섭
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박동섭
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/002—Locally enhancing dye affinity of a textile material by chemical means
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/66—Natural or regenerated cellulose using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/001—Special chemical aspects of printing textile materials

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The present invention relates to a composition for printing on cotton fabric, wherein the composition is made by mixing water, sodium alginate, a composite coating agent, an anti-reducing agent, a preservative, sodium hexametaphosphate, sodium bicarbonate, and a reaction promoting mixture. The reaction promoting mixture is made of a mixture of heavy-treated paraffin refined oil, mineral oil (mineral oil), ethoxylated alcohols, hydroxypoly (oxy-1 2-ethanediyl), triethanol amine, and ethoxylated propoxylated. The present invention improves the dissolution and dispersion of a dye mixed in printing coating during cotton fabric printing by including a reaction promoting mixture that replaces an element used in the printing of cotton fabric, and helps penetrate into the fiber tissue, thereby having excellent leveling and dye fixation promotion effects while not only can environmental pollution be reduced by suppressing the generation of nitrogenous wastewater and economic feasibility is also improved by reducing the cost burden of wastewater treatment, thereby lowering the production cost of cotton fabric printing and dyeing.

Description

면직물 날염용 조성물{COMPOSITION FOR PRINTING COTTON FABRIC}Composition for printing cotton fabrics {COMPOSITION FOR PRINTING COTTON FABRIC}

본 발명은 면직물 날염용 조성물에 관한 것으로, 더욱 상세하게는 면직물의 날염시 사용되는 요소를 대체하는 반응촉진혼합물을 포함하여 구성함으로써 면직물 날염시 날염호에 혼합된 염료의 용해 및 분산 상태를 좋게 하고, 섬유 조직 속 침투를 도와 균염 및 염료 고착 촉진 효과가 우수하면서도, 질소화합물 폐수의 발생을 억제하여 폐수처리에 따른 비용 부담을 저감시킬 수 있는 면직물 날염용 조성물에 관한 것이다. The present invention relates to a composition for printing cotton fabric, and more particularly, by including a reaction promoting mixture that replaces elements used in printing cotton fabric to improve the dissolution and dispersion state of the dye mixed in the printing pad when printing cotton fabric, , It relates to a composition for cotton textile printing that can reduce the cost burden of wastewater treatment by suppressing the generation of nitrogen compound wastewater while having excellent effects of promoting leveling and dyeing by helping penetration into the textile tissue.

일반적으로 섬유제품은 질감, 촉감, 심미감, 기능성, 실용성 등에 의해 제품의 가치가 달라지는데, 특히 섬유제품의 심미감에 가장 큰 영향을 미치는 것이 섬유제품의 색상이기 때문에 섬유제품에 색상을 부여하는 날염(피륙에 부분적으로 착색하여 무늬가 나타나게 하는 방법)의 중요성이 더욱 커지고 있다.In general, textile products have different values depending on texture, touch, aesthetics, functionality, and practicality. The importance of (a method of partially coloring the fabric to make a pattern appear) is growing in importance.

즉, 산업화, 도시화와 더불어 경제 규모가 커지면서 화려한 색상과 다양한 패턴을 가진 고급 섬유제품의 수요가 크게 증가함에 따라, 섬유 상태에서 염색된 실이나 실 자체를 염색한 상태로 제작하여 섬유 원단을 직조하는 선염과 달리, 직조된 섬유 원단에 색상이나 패턴을 부여함으로써 선염보다 더 다양한 색상과 더욱 화려한 패턴의 형성이 용이한 날염(‘나염’또는 ‘후염’이라고도 함) 가공에 대한 중요성이 커지고 있다.In other words, as the economic scale grows along with industrialization and urbanization, the demand for high-quality textile products with colorful colors and various patterns increases significantly. Unlike ombre dyeing, the importance of printing (also called 'printing' or 'post-dying') processing, which makes it easier to form more diverse colors and more colorful patterns than ombre dyeing, is growing in importance by giving colors or patterns to woven textile fabrics.

일반적인 날염은, 날염호 준비 → 인날(Printing) → 건조 → 염료 고착(Steaming) → 후처리(Soaping 및 수세 등)의 공정 순으로 이루어지게 된다.In general, printing is performed in the following order: preparation of printing paper → printing → drying → dyeing (steaming) → post-treatment (soaping and washing with water).

날염을 위하여 염료나 조제 및 호료 등을 배합한 것을 날염호(염료 조성물)라고 하는데, 섬유제품의 종류에 따라 날염호를 구성하는 염료, 조제 및 호료 등은 달라지게 된다.For printing, a mixture of dyes, additives, and dyes is called a printing paper (dye composition), and the dyes, preparations, and dyes constituting the printing paper vary depending on the type of textile product.

특히, 다양한 섬유제품 중 셀룰로오스 섬유(면, 레이온, 마 등)의 날염 시에는 반응성 염료를 염착시키기 위한 수단으로 고착제(알칼리, 주로 중조를 사용함)와 함께 다량의 요소가 사용되는데, 요소는 날염시 날염호에 혼합된 염료의 용해 및 분산 상태를 좋게 하고, 섬유 조직 속 침투를 도와 균염 효과를 향상시켜주기 때문에 염료 고착 촉진제로서 많은 양이 사용된다.In particular, when printing cellulose fibers (cotton, rayon, hemp, etc.) among various textile products, a large amount of urea is used together with a fixing agent (alkali, mainly sodium bicarbonate) as a means for dyeing reactive dyes. It is used in a large amount as a dye adhesion promoter because it improves the dissolution and dispersion of the dye mixed in the printed fabric and improves the leveling effect by helping the penetration into the fibrous tissue.

위와 같이 날염시 사용된 요소는 염료 고착(증열) 후에는 후처리공정(수세공정)에서 제거되어 폐수로 혼입되는데, 요소의 BOD5는 90,000ppm으로 폐수에서의 부하량이 크고, 대기중으로 암모니아(Ammonia)화하기 때문에 환경오염에 큰 몫을 차지할 뿐만 아니라, 폐수에 혼입된 요소 및 그 분해물은 물에 용해되어 분자 단위당 46~48%(w/w)의 질소 성분이 배출되는데, 세계적으로 진행되고 있는 질소화합물의 수질 생태계 오염에 대한 관심이 높아지면서 우리나라에서도 질소화합물의 폐수 배출기준이 대폭 강화되었다.As above, urea used for printing is removed in the post-treatment process (water washing process) after dye fixing (vapor heat) and mixed into wastewater. In addition, urea and its decomposition products mixed in wastewater are dissolved in water to release 46~48% (w/w) of nitrogen per molecular unit. As interest in the contamination of water ecosystems by chemical compounds has increased, the emission standards for nitrogen compounds in wastewater have been greatly strengthened in Korea.

현재 우리나라는 폐수 관련 법규로서 총질소를 규제하고 있는데, 그 기준은 청정지역 30ppm, 일반지역 60ppm으로 관리되고 있다.Currently, Korea regulates total nitrogen as a wastewater-related law, and the standards are managed at 30ppm in clean areas and 60ppm in general areas.

그러나, 대부분 날염업체의 경우 현실적으로 정부가 규제하고 있는 폐수 관련 규정을 맞추기 어려워 별도의 폐수 배출 부과금을 물어가며 날염 제품을 생산함에 따라 제조원가 인상 및 경영상의 부담이 가중되고 있다.However, in the case of most printing companies, it is difficult to meet the wastewater-related regulations regulated by the government in reality.

따라서 날염시 사용되는 요소를 저감시킬 수 있는 기술의 개발이 절실한 실정이다.Therefore, there is an urgent need to develop a technology that can reduce the factors used in printing.

공개특허공보 제10-1997-0062006호Laid-Open Patent Publication No. 10-1997-0062006

상술한 바와 같은 종래의 단점을 해결하기 위하여 본 발명은 면직물의 날염시 사용되는 요소를 대체하는 반응촉진혼합물을 포함하여 구성함으로써 면직물 날염시 날염호에 혼합된 염료의 용해 및 분산 상태를 좋게 하고, 섬유 조직 속 침투를 도와 균염 및 염료 고착 촉진 효과가 우수하면서도, 질소화합물 폐수의 발생을 억제하여 폐수처리에 따른 비용 부담을 저감시킬 수 있는 면직물 날염용 조성물을 제공하는 것을 목적으로 한다. In order to solve the disadvantages of the prior art as described above, the present invention includes a reaction-promoting mixture that replaces the elements used in the printing of cotton fabric, thereby improving the dissolution and dispersion state of the dye mixed in the printing pad when printing cotton fabric, An object of the present invention is to provide a composition for cotton textile printing that can help penetration into the fibrous tissue and reduce the cost burden of wastewater treatment by suppressing the generation of nitrogenous compound wastewater while having excellent effects of promoting leveling and dyeing.

상술한 바와 같은 목적의 달성을 위하여 본 발명의 면직물 날염용 조성물은, 물, 알긴산나트륨(sodium alginate), 복합호료, 환원방지제, 방부제, 헥사메타인산소다(sodium hexametaphosphate), 중탄산나트륨(Sodium bicarbonate), 반응촉진혼합물(요소 대체 혼합물)을 포함하는 것을 특징으로 한다. In order to achieve the above object, the composition for printing cotton fabric of the present invention is water, sodium alginate, complex dye, reduction inhibitor, preservative, sodium hexametaphosphate (sodium hexametaphosphate), sodium bicarbonate (Sodium bicarbonate) , characterized in that it contains a reaction promoting mixture (urea replacement mixture).

일 실시 예에서 본 발명의 면직물 날염용 조성물은, 물 85 중량%; 알긴산나트륨 1 내지 3 중량%; 복합호료 1 내지 4 중량%; 환원방지제 0.5 내지 1 중량%; 방부제 0.5 내지 1 중량%; 헥사메타인산소다 0.5 내지 1 중량%; 중탄산나트륨 2 내지 5 중량%; 반응촉진혼합물 2 내지 6 중량%; 를 포함하는 것을 특징으로 한다. In one embodiment, the composition for cotton textile printing of the present invention comprises: 85% by weight of water; 1 to 3% by weight of sodium alginate; 1 to 4% by weight of the complex dye; 0.5 to 1% by weight of an anti-reduction agent; 0.5 to 1% by weight of a preservative; 0.5 to 1% by weight of sodium hexametaphosphate; 2 to 5% by weight of sodium bicarbonate; 2 to 6% by weight of the reaction accelerator mixture; It is characterized in that it includes.

일 실시 예에서 상기 반응촉진혼합물은, 중질 처리된 파리핀 정제유, 미네랄오일(광유), 에톡실레이티드 알코올(ethoxylated alcohols), 하이드록시폴리(hydroxypoly(oxy-1 2-ethanediyl)), 트리에탄올아민(triethanol amine), 에톡실레이티드 프로폭실레이티드(ethoxylated propoxylated)를 포함하는 것을 특징으로 한다. In one embodiment, the reaction promoting mixture is a heavy treated paraffin refined oil, mineral oil (mineral oil), ethoxylated alcohols, hydroxypoly (oxy-1 2-ethanediyl), triethanolamine (triethanol amine), characterized in that it contains ethoxylated propoxylated (ethoxylated propoxylated).

일 실시 예에서 상기 반응촉진혼합물은, 중질 처리된 파리핀 정제유 10 내지 20 중량%; 미네랄오일(광유) 20 내지 30 중량%; 에톡실레이티드 알코올(ethoxylated alcohols) 3 내지 10 중량%; 하이드록시폴리(hydroxypoly(oxy-1 2-ethanediyl)) 20 내지 30 중량%; 트리에탄올아민(triethanol amine) 20 내지 30 중량%; 에톡실레이티드 프로폭실레이티드(ethoxylated propoxylated) 3 내지 10 중량%; 를 포함하는 것을 특징으로 한다. In one embodiment, the reaction promoting mixture may include 10 to 20 wt% of heavy-treated paraffin refined oil; 20 to 30% by weight of mineral oil (mineral oil); 3 to 10% by weight of ethoxylated alcohols; 20 to 30% by weight of hydroxypoly(oxy-1 2-ethanediyl); 20 to 30% by weight of triethanolamine; 3 to 10% by weight of ethoxylated propoxylated; It is characterized in that it includes.

본 발명은, 면직물의 날염시 사용되는 요소를 대체하는 반응촉진혼합물을 포함하여 구성함으로써 면직물 날염시 날염호에 혼합된 염료의 용해 및 분산 상태를 좋게 하고, 섬유 조직 속 침투를 도와 균염 및 염료 고착 촉진 효과가 우수하면서도, 질소화합물 폐수의 발생을 억제함으로써 환경오염을 줄일 수 있을 뿐만 아니라, 폐수처리에 따른 비용 부담이 감소함으로써 면직물 날염에 따른 생산원가를 낮춰 경제성이 향상되는 효과가 있다. The present invention improves the dissolution and dispersion state of the dye mixed in the printing pad when printing cotton fabric by including a reaction promoting mixture that replaces the elements used in the printing of cotton fabric, and helps the penetration into the textile tissue to fix the leveling and dye While excellent in promoting effect, it is possible to reduce environmental pollution by suppressing the generation of nitrogenous wastewater, as well as to reduce the cost burden of wastewater treatment, thereby lowering the production cost due to cotton textile printing and improving economic efficiency.

도 1은 요소가 사용된 종래의 날염용 조성물을 이용한 면직물 날염 샘플과, 본 발명의 바람직한 실시 예에 따른 면직물 날염용 조성물을 이용한 면직물 날염 샘플을 비교한 사진.1 is a photograph comparing a cotton textile printing sample using a conventional printing composition using urea and a cotton textile printing sample using a cotton textile printing composition according to a preferred embodiment of the present invention.

아래에서는 첨부한 도면을 참고로 하여 본 발명의 실시 예에 대하여 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 상세히 설명한다. Hereinafter, with reference to the accompanying drawings, embodiments of the present invention will be described in detail so that those of ordinary skill in the art can easily implement them.

본 발명에 관한 설명은 구조적이나 기능적 설명을 위한 실시 예에 불과하므로, 본 발명의 권리범위는 본문에 설명된 실시 예에 의하여 제한되는 것으로 해석되어서는 아니 된다.Since the description of the present invention is merely an embodiment for structural or functional description, the scope of the present invention should not be construed as being limited by the embodiment described in the text.

즉, 실시 예는 다양한 변경이 가능하고 여러 가지 형태를 가질 수 있으므로 본 발명의 권리범위는 기술적 사상을 실현할 수 있는 균등물들을 포함하는 것으로 이해되어야 한다. That is, since the embodiment may have various changes and may have various forms, it should be understood that the scope of the present invention includes equivalents capable of realizing the technical idea.

또한, 본 발명에서 제시된 목적 또는 효과는 특정 실시예가 이를 전부 포함하여야 한다거나 그러한 효과만을 포함하여야 한다는 의미는 아니므로, 본 발명의 권리범위는 이에 의하여 제한되는 것으로 이해되어서는 아니 될 것이다.In addition, since the object or effect presented in the present invention does not mean that a specific embodiment should include all of them or only such effects, it should not be understood that the scope of the present invention is limited thereby.

본 발명에 관한 설명에서 사용되는 모든 용어는 다르게 정의되지 않는 한, 본 발명이 속하는 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미가 있다. All terms used in the description of the present invention have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention belongs, unless otherwise defined.

일반적으로 사용되는 사전에 정의된 용어들은 관련 기술의 문맥상 가지는 의미와 일치하는 것으로 해석되어야 하며, 본 발명에서 명백하게 정의하지 않는 한 이상적이거나 과도하게 형식적인 의미를 지니는 것으로 해석될 수 없다.Terms defined in the dictionary should be interpreted as being consistent with the meaning of the context of the related art, and cannot be interpreted as having an ideal or excessively formal meaning unless explicitly defined in the present invention.

또한, "제1", "제2" 등의 용어는 서로 다른 구성 요소임을 구분하기 위해서 지칭할 것일 뿐, 제조된 순서에 구애받지 않는 것이며, 이들 용어에 의해 권리범위가 한정되어서는 아니 된다.In addition, terms such as "first" and "second" will only refer to distinguishing elements from each other, and are not limited by the order of manufacture, and the scope of rights should not be limited by these terms.

본 발명의 면직물 날염용 조성물은 요소 없이도 면직물의 날염이 가능하도록 물, 알긴산나트륨(sodium alginate), 복합호료, 환원방지제, 방부제, 헥사메타인산소다, 중탄산나트륨, 반응촉진혼합물을 포함한다.The composition for cotton textile printing of the present invention includes water, sodium alginate, a complex dye, a reduction inhibitor, a preservative, sodium hexametaphosphate, sodium bicarbonate, and a reaction promoting mixture to enable printing of cotton textiles without urea.

즉, 본 발명의 면직물 날염용 조성물은 물 85 중량%; 알긴산나트륨(sodium alginate) 1 내지 3 중량%; 복합호료 1 내지 4 중량%; 환원방지제 0.5 내지 1 중량%; 방부제 0.5 내지 1 중량%; 헥사메타인산소다 0.5 내지 1 중량%; 중탄산나트륨 2 내지 5 중량%; 반응촉진혼합물 2 내지 6 중량%(요소 대체 혼합물)를 포함하여 구성된다.That is, the composition for cotton textile printing of the present invention contains 85% by weight of water; 1 to 3% by weight of sodium alginate; 1 to 4% by weight of the complex dye; 0.5 to 1% by weight of an anti-reduction agent; 0.5 to 1% by weight of a preservative; 0.5 to 1% by weight of sodium hexametaphosphate; 2 to 5% by weight of sodium bicarbonate; It is composed of 2 to 6% by weight of the reaction accelerator mixture (urea replacement mixture).

상기 물은 공업용수, 수돗물, 지하수, 정제수(deionized water) 중 어느 하나 이상을 사용할 수 있으나, 생산성, 제조원가 및 날염 발색성, 색감 등을 고려할 때 공업용수를 사용하는 것이 바람직하다. As the water, any one or more of industrial water, tap water, groundwater, and deionized water may be used, but it is preferable to use industrial water in consideration of productivity, manufacturing cost, printing and color development, and color.

상기 알긴산나트륨(sodium alginate)은 1 내지 3 중량%를 포함한다. The sodium alginate (sodium alginate) comprises 1 to 3% by weight.

알긴산나트륨은 날염용 조성물에 첨가되어 염료를 골고루 분산시킴으로써 염색 시 염료가 균일하게 착색될 수 있도록 하는 것이다. Sodium alginate is added to the composition for printing so that the dye can be uniformly colored during dyeing by evenly dispersing the dye.

본 발명의 면직물 날염용 조성물에서 알긴산나트륨이 1 중량% 미만으로 혼합되면 염료의 분산성이 떨어지며, 3 중량%를 초과하여 혼합되면 알긴산나트륨의 높은 점도로 인해 염료의 뭉침현상이 일어날 수 있으므로 알긴산나트륨은 1 내지 3 중량%에 한정하여 사용하는 것이 바람직하다.When sodium alginate is mixed in less than 1% by weight in the composition for printing cotton fabrics of the present invention, the dispersibility of the dye decreases, and when mixed in excess of 3% by weight, aggregation of the dye may occur due to the high viscosity of sodium alginate, so sodium alginate It is preferable to limit the amount of silver to 1 to 3% by weight.

상기 복합호료는 1 내지 4 중량%를 포함한다.The composite dye contains 1 to 4% by weight.

호료는 염료를 직물에 고착시키고, 날염용 조성물의 점도를 조절하며, 색상의 선명도와 발색도를 향상시키는 역할을 하는 것으로서, 본 발명의 면직물 날염용 조성물은, CMC(carboxymethyl cellulose) 등의 셀룰로오스 유도체, 폴리비닐알코올 등의 비닐계 유도체, 아크릴계 유도체, 우레아계 유도체 등의 합성된 복합호료를 사용하는 것이 바람직하다. The dye fixes the dye to the fabric, adjusts the viscosity of the composition for printing, and serves to improve color clarity and color development. , It is preferable to use a synthetic composite dye such as vinyl derivatives such as polyvinyl alcohol, acrylic derivatives, and urea derivatives.

본 발명의 면직물 날염용 조성물에서 복합호료가 1 중량% 미만으로 혼합되면 날염용 조성물의 도포성, 은폐력이 저하되며, 4 중량%를 초과하여 혼합되면 점도가 지나치게 높아져서 작업성이 저하된다.In the composition for cotton textile printing of the present invention, when the composite dye is mixed in an amount of less than 1% by weight, the coating properties and hiding power of the printing composition are reduced, and when mixed in an amount exceeding 4% by weight, the viscosity is excessively high and workability is reduced.

상기 환원방지제는 0.5 내지 1 중량%를 포함한다. The reduction inhibitor includes 0.5 to 1% by weight.

환원방지제는 면직물에 날염된 염료가 환원되면서 면직물이 탈색되는 것을 방지하여 발색 농도의 저하를 막을 수 있도록 하는 것이다. The reduction inhibitor prevents the dye printed on the cotton from being discolored while reducing the dye, thereby preventing a decrease in the color density.

환원방지제는 메타니트로벤젠술폰산나트륨 등과 같은 공지의 환원방지제를 사용하는 것이 바람직하다.As the reduction inhibitor, it is preferable to use a known reduction inhibitor such as sodium metanitrobenzenesulfonate.

본 발명의 면직물 날염용 조성물에서 환원방지제가 0.5 중량% 미만으로 혼합되면 염료의 환원을 방지하지 못하게 되며, 1 중량%를 초과하여 혼합되면 과도한 사용으로 인해 경제성이 떨어지기 때문에 환원방지제는 0.5 내지 1 중량%에 한정하여 사용하는 것이 바람직하다. In the composition for cotton textile printing of the present invention, when the reducing agent is mixed in an amount of less than 0.5% by weight, it is impossible to prevent the reduction of the dye, and when it is mixed in excess of 1% by weight, economical efficiency is deteriorated due to excessive use, so the reduction inhibitor is 0.5 to 1 It is preferable to limit the use by weight%.

상기 헥사메타인산소다는 0.5 내지 1 중량%를 포함한다.The sodium hexametaphosphate is included in an amount of 0.5 to 1% by weight.

헥사메타인산소다는 물에 잘 녹으며, 알코올에는 불용, 수용액은 알칼리성을 나타낸다. 수용액의 pH가 일반 알칼리 용액보다 강하며 농도에 따라 pH 변화가 적다. 친수성을 가짐으로써 분산성 및 흡착성이 우수하며, 알칼리도를 조정하는 완충작용을 갖고 있으므로 탈지의 손상이 없다.Soda hexametaphosphate is soluble in water, insoluble in alcohol, and alkaline in aqueous solution. The pH of the aqueous solution is stronger than that of a general alkaline solution, and the pH change is small depending on the concentration. Because it has hydrophilicity, it has excellent dispersibility and adsorption property, and has a buffering action to adjust alkalinity, so there is no damage to degreasing.

본 발명의 면직물 날염용 조성물에서 헥사메타인산소다가 0.5 중량% 미만으로 혼합되면 날염용 조성물의 분산성 및 흡착성이 떨어지고, 1 중량%를 초과하여 혼합되면 알카리도가 안정되지 않아 염료의 반응이 일어나기 어렵기 때문에, 헥사메타인산소다는 0.5 내지 1 중량%에 한정하여 사용하는 것이 바람직하다. When sodium hexametaphosphate is mixed in less than 0.5% by weight in the composition for printing cotton fabrics of the present invention, the dispersibility and adsorption properties of the printing composition are deteriorated. Therefore, it is preferable to limit the use of sodium hexametaphosphate to 0.5 to 1% by weight.

상기 중탄산나트륨은 2 내지 5 중량%를 포함한다.The sodium bicarbonate comprises 2 to 5% by weight.

중탄산나트륨은 알카리도를 떨어뜨려 pH를 조절하도록 함으로써 반응성 염료와 면섬유를 탈색없이 균일하게 화학적으로 고착되게 한다. Sodium bicarbonate lowers the alkalinity to adjust the pH so that the reactive dye and the cotton fiber are chemically fixed uniformly without discoloration.

즉, 중탄산나트륨을 이용하여 본 발명의 날염용 조성물의 pH를 7 내지 8의 알칼리성으로 조절하면, 인날된 염료의 색상, 채도, 명도가 모두 향상되는 효과가 있다. That is, when the pH of the printing composition of the present invention is adjusted to an alkalinity of 7 to 8 using sodium bicarbonate, the color, saturation, and brightness of the printed dye are all improved.

발명의 면직물 날염용 조성물에서 중탄산나트륨이 2 중량% 미만으로 혼합되면 염료 반응이 늦어져 면섬유의 염료 고착이 저하되고, 5 중량%를 초과하여 혼합되면 염색에 소요되는 시간은 단축되는 반면, 염료가 날아가 탈색 가능성이 증가하기 때문에 중탄산나트륨은 2 내지 5 중량%에 한정하여 사용하는 것이 바람직하다. When sodium bicarbonate is mixed in an amount of less than 2% by weight in the composition for printing cotton fabrics of the present invention, the dye reaction is delayed and the dye fixation of the cotton fibers is lowered. It is preferable to limit the use of sodium bicarbonate to 2 to 5% by weight of sodium bicarbonate because the possibility of discoloration increases.

상기 반응촉진혼합물은 2 내지 6 중량%를 포함한다. The reaction promoting mixture contains 2 to 6% by weight.

반응촉진혼합물은 면직물 날염에 사용되는 요소의 대체제로서 염료의 용해성을 증가시켜 변색을 방지하고, 날염 후공정인 증열시 함수율을 증가시켜 냉각 작용을 하도록 한다.The reaction-promoting mixture is a substitute for urea used in cotton textile printing, preventing discoloration by increasing the solubility of dyes, and increasing the moisture content during steaming, the post-printing process, to act as a cooling agent.

본 발명의 면직물 날염용 조성물에서 반응촉진혼합물이 2 중량% 미만으로 혼합되면 변색이 발생할 수 있으며, 6 중량%를 초과하면 경제성이 떨어지기 때문에 반응촉진혼합물은 2 내지 6 중량%에 한정하여 사용하는 것이 바람직하다. In the composition for cotton textile printing of the present invention, when the reaction promoting mixture is mixed at less than 2% by weight, discoloration may occur, and when it exceeds 6% by weight, economic feasibility is deteriorated, so the reaction promoting mixture is limited to 2 to 6% by weight. it is preferable

상기 반응촉진혼합물은, 중질 처리된 파라핀 정제유, 미네랄오일(광유), 에톡실레이티드 알코올(ethoxylated alcohols), 하이드록시폴리(hydroxypoly(oxy-1 2-ethanediyl)), 트리에탄올아민(triethanol amine), 에톡실레이티드 프로폭실레이티드(ethoxylated propoxylated)를 포함한다. The reaction promoting mixture is heavy-treated paraffin refined oil, mineral oil (mineral oil), ethoxylated alcohols, hydroxypoly (oxy-1 2-ethanediyl), triethanolamine, ethoxylated propoxylated.

일 실시 예에서 상기 반응촉진혼합물은, 중질 처리된 파리핀 정제유 10 내지 20 중량%; 미네랄오일(광유) 20 내지 30 중량%; 에톡실레이티드 알코올(ethoxylated alcohols) 3 내지 10 중량%; 하이드록시폴리(hydroxypoly(oxy-1 2-ethanediyl)) 20 내지 30 중량%; 트리에탄올아민(triethanol amine) 20 내지 30 중량%; 에톡실레이티드 프로폭실레이티드(ethoxylated propoxylated) 3 내지 10 중량%; 를 포함하는 것을 특징으로 한다. In one embodiment, the reaction promoting mixture may include 10 to 20 wt% of heavy-treated paraffin refined oil; 20 to 30% by weight of mineral oil (mineral oil); 3 to 10% by weight of ethoxylated alcohols; 20 to 30% by weight of hydroxypoly(oxy-1 2-ethanediyl); 20 to 30% by weight of triethanolamine; 3 to 10% by weight of ethoxylated propoxylated; It is characterized in that it includes.

이상과 같이 구성된 반응촉진혼합물은 국내 화학물질관리법에 의한 규제 및 위험물안전관리법에 의한 규제에 해당하지 않으며, 화학물질의 수생환경 유해기준에 있어서 유해성이 낮은 물질로 구성된다.The reaction promoting mixture composed as described above does not fall under the regulations under the Domestic Chemicals Control Act or the Dangerous Substances Safety Management Act, and is composed of substances with low toxicity in the aquatic environment hazard standards of chemical substances.

이상과 같이 구성된 본 발명의 면직물 날염용 조성물은 염료와 소정 비율로 혼합된 후, 면 뿐만 아니라, 레이온, 마 등 셀룰로오스 섬유의 날염에 사용된다.The composition for printing cotton fabric of the present invention configured as described above is mixed with a dye in a predetermined ratio, and then used for printing not only cotton, but also cellulose fibers such as rayon and hemp.

즉, 염료는 본 발명의 면직물 날염용 조성물 100 중량부에 대하여 1 내지 10중량부가 혼합되는 것이 바람직하며, 염료는 면직물의 날염에 사용되는 공지의 여러 반응성 염료를 사용하는 것이 바람직할 것이나 이에 한정하는 것은 아님을 미리 밝혀둔다.That is, the dye is preferably mixed in an amount of 1 to 10 parts by weight based on 100 parts by weight of the composition for printing cotton fabrics of the present invention, and as the dye, it is preferable to use various known reactive dyes used for printing cotton fabrics. It is stated in advance that it is not

또한, 날염에 사용되는 날염법은 본 발명의 기술분야에서 통상적으로 사용되는 롤러 날염(roller printing), 스크린 날염(screen printing), 로터리 날염(rotary printing), 수날염법(hand printing), 전사날염(transfer printing) 등 모든 날염법에 제한 없이 사용 가능함을 미리 밝혀둔다.In addition, the printing method used for printing includes roller printing, screen printing, rotary printing, hand printing, transfer printing, which are commonly used in the technical field of the present invention. (transfer printing), etc., make it clear in advance that it can be used without restrictions.

이하, 실시 예 및 실험 예를 통해 본 발명을 보다 구체적으로 설명한다. 그러나 이들 예는 본 발명의 이해를 돕기 위한 것일 뿐 어떠한 의미로든 본 발명의 범위가 이들 예로 한정되는 것은 아님을 미리 밝혀둔다.Hereinafter, the present invention will be described in more detail through Examples and Experimental Examples. However, these examples are intended to help the understanding of the present invention, and it is to be noted in advance that the scope of the present invention is not limited to these examples in any sense.

[실시예 1] [Example 1]

물 85 중량%, 알긴산나트륨 1 중량%, 복합호료 3 중량%, 환원방지제 0.5 중량%, 방부제 0.5 중량%, 헥사메타인산소다 1 중량%, 중탄산나트륨 3 중량%; 반응촉진혼합물 6 중량%를 혼합, 교반하여 날염 조성물을 제조하고, 그 날염 조성물 100 중량부에 대하여 염료 5 중량부를 혼합하여 pH 7.5의 염료 조성물을 제조하였다.85 wt% of water, 1 wt% of sodium alginate, 3 wt% of complex dye, 0.5 wt% of a reduction inhibitor, 0.5 wt% of a preservative, 1 wt% of sodium hexametaphosphate, 3 wt% of sodium bicarbonate; A printing composition was prepared by mixing and stirring 6% by weight of the reaction accelerator mixture, and 5 parts by weight of a dye was mixed with respect to 100 parts by weight of the printing composition to prepare a dye composition having a pH of 7.5.

상기 제조된 염료 조성물을 스크린 날염법으로 면직물에 인날하고, 130℃ 온도에서 1분간 건조한 후, 105℃ 온도에서 10분간 증열하고, 증열이 완료된 후 수세하여 호료, 미고착 염료 등 잔여물을 제거하여 면직물에 소정 모양으로 여러 색상을 날염하였다. The prepared dye composition is printed on cotton fabric by screen printing method, dried at 130 ° C. for 1 minute, heated at 105 ° C. for 10 minutes, and washed with water after completion of steaming to remove residues such as dye and unfixed dye. Various colors were printed on the cotton fabric in a predetermined shape.

날염된 면직물의 색상은 육안으로 평가하여 그 결과를 표 1과 같이 나타내었다. The color of the printed cotton fabric was visually evaluated and the results are shown in Table 1.

[실시예 2] [Example 2]

물 85 중량%, 알긴산나트륨 1.5 중량%, 복합호료 3 중량%, 환원방지제 0.5 중량%, 방부제 1 중량%, 헥사메타인산소다 1 중량%, 중탄산나트륨 3 중량%; 반응촉진혼합물 5 중량%를 혼합, 교반하여 날염 조성물을 제조하고, 그 날염 조성물 100 중량부에 대하여 염료 5 중량부를 혼합하여 pH 7.5의 염료 조성물을 제조하였다.Water 85% by weight, sodium alginate 1.5% by weight, complex dye 3% by weight, reduction inhibitor 0.5% by weight, preservative 1% by weight, sodium hexametaphosphate 1% by weight, sodium bicarbonate 3% by weight; A printing composition was prepared by mixing and stirring 5% by weight of the reaction accelerator mixture, and 5 parts by weight of a dye was mixed with respect to 100 parts by weight of the printing composition to prepare a dye composition having a pH of 7.5.

상기 제조된 염료 조성물을 스크린 날염법으로 면직물에 인날하고, 130℃ 온도에서 1분간 건조한 후, 105℃ 온도에서 10분간 증열하고, 증열이 완료된 후 수세하여 호료, 미고착 염료 등 잔여물을 제거하여 면직물에 소정 모양으로 여러 색상을 날염하였다. The prepared dye composition is printed on cotton fabric by screen printing method, dried at 130 ° C. for 1 minute, heated at 105 ° C. for 10 minutes, and washed with water after completion of steaming to remove residues such as dye and unfixed dye. Various colors were printed on the cotton fabric in a predetermined shape.

날염된 면직물의 색상은 육안으로 평가하여 그 결과를 표 1과 같이 나타내었다. The color of the printed cotton fabric was visually evaluated and the results are shown in Table 1.

[실시예 3] [Example 3]

물 85 중량%, 알긴산나트륨 2 중량%, 복합호료 3 중량%, 환원방지제 1 중량%, 방부제 1 중량%, 헥사메타인산소다 1 중량%, 중탄산나트륨 3 중량%; 반응촉진혼합물 4 중량%를 혼합, 교반하여 날염 조성물을 제조하고, 그 날염 조성물 100 중량부에 대하여 염료 5 중량부를 혼합하여 pH 7.5의 염료 조성물을 제조하였다.Water 85% by weight, sodium alginate 2% by weight, complex dye 3% by weight, reduction inhibitor 1% by weight, preservative 1% by weight, sodium hexametaphosphate 1% by weight, sodium bicarbonate 3% by weight; A printing composition was prepared by mixing and stirring 4% by weight of the reaction accelerator mixture, and 5 parts by weight of a dye was mixed with respect to 100 parts by weight of the printing composition to prepare a dye composition having a pH of 7.5.

상기 제조된 염료 조성물을 스크린 날염법으로 면직물에 인날하고, 130℃ 온도에서 1분간 건조한 후, 105℃ 온도에서 10분간 증열하고, 증열이 완료된 후 수세하여 호료, 미고착 염료 등 잔여물을 제거하여 면직물에 소정 모양으로 여러 색상을 날염하였다. The prepared dye composition is printed on cotton fabric by screen printing method, dried at 130 ° C. for 1 minute, heated at 105 ° C. for 10 minutes, and washed with water after completion of steaming to remove residues such as paint and unfixed dye. Various colors were printed on the cotton fabric in a predetermined shape.

날염된 면직물의 색상은 육안으로 평가하여 그 결과를 표 1과 같이 나타내었다. The color of the printed cotton fabric was visually evaluated and the results are shown in Table 1.

[실시예 4] [Example 4]

물 85 중량%, 알긴산나트륨 2.5 중량%, 복합호료 3.5 중량%, 환원방지제 1 중량%, 방부제 1 중량%, 헥사메타인산소다 0.5 중량%, 중탄산나트륨 3 중량%; 반응촉진혼합물 3.5 중량%를 혼합, 교반하여 날염 조성물을 제조하고, 그 날염 조성물 100 중량부에 대하여 염료 5 중량부를 혼합하여 pH 7.5의 염료 조성물을 제조하였다.85% by weight of water, 2.5% by weight of sodium alginate, 3.5% by weight of complex dye, 1% by weight of reduction inhibitor, 1% by weight of preservative, 0.5% by weight of sodium hexametaphosphate, 3% by weight of sodium bicarbonate; A printing composition was prepared by mixing and stirring 3.5% by weight of the reaction accelerator mixture, and 5 parts by weight of a dye was mixed with respect to 100 parts by weight of the printing composition to prepare a dye composition having a pH of 7.5.

상기 제조된 염료 조성물을 스크린 날염법으로 면직물에 인날하고, 130℃ 온도에서 1분간 건조한 후, 105℃ 온도에서 10분간 증열하고, 증열이 완료된 후 수세하여 호료, 미고착 염료 등 잔여물을 제거하여 면직물에 소정 모양으로 여러 색상을 날염하였다. The prepared dye composition is printed on cotton fabric by screen printing method, dried at 130 ° C. for 1 minute, heated at 105 ° C. for 10 minutes, and washed with water after completion of steaming to remove residues such as dye and unfixed dye. Various colors were printed on the cotton fabric in a predetermined shape.

날염된 면직물의 색상은 육안으로 평가하여 그 결과를 표 1과 같이 나타내었다. The color of the printed cotton fabric was visually evaluated and the results are shown in Table 1.

[실시예 5] [Example 5]

물 85 중량%, 알긴산나트륨 3 중량%, 복합호료 4 중량%, 환원방지제 1 중량%, 방부제 0.5 중량%, 헥사메타인산소다 0.5 중량%, 중탄산나트륨 3 중량%; 반응촉진혼합물 3 중량%를 혼합, 교반하여 날염 조성물을 제조하고, 그 날염 조성물 100 중량부에 대하여 염료 5 중량부를 혼합하여 pH 7.5의 염료 조성물을 제조하였다.85% by weight of water, 3% by weight of sodium alginate, 4% by weight of complex dye, 1% by weight of reduction inhibitor, 0.5% by weight of preservative, 0.5% by weight of sodium hexametaphosphate, 3% by weight of sodium bicarbonate; A printing composition was prepared by mixing and stirring 3% by weight of the reaction accelerator mixture, and 5 parts by weight of a dye was mixed with respect to 100 parts by weight of the printing composition to prepare a dye composition having a pH of 7.5.

상기 제조된 염료 조성물을 스크린 날염법으로 면직물에 인날하고, 130℃ 온도에서 1분간 건조한 후, 105℃ 온도에서 10분간 증열하고, 증열이 완료된 후 수세하여 호료, 미고착 염료 등 잔여물을 제거하여 면직물에 소정 모양으로 여러 색상을 날염하였다. The prepared dye composition is printed on cotton fabric by screen printing method, dried at 130 ° C. for 1 minute, heated at 105 ° C. for 10 minutes, and washed with water after completion of steaming to remove residues such as dye and unfixed dye. Various colors were printed on the cotton fabric in a predetermined shape.

날염된 면직물의 색상은 육안으로 평가하여 그 결과를 표 1과 같이 나타내었다. The color of the printed cotton fabric was visually evaluated and the results are shown in Table 1.

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 실시예 5Example 5 남색 선명도blue sharpness 양호Good 우수Great 우수Great 양호Good 양호Good 적색 선명도red sharpness 우수Great 우수Great 양호Good 우수Great 양호Good 황색 선명도yellow sharpness 우수Great 우수Great 양호Good 양호Good 우수Great 청색 선명도blue sharpness 양호Good 우수Great 우수Great 양호Good 양호Good 하늘색 선명도sky blue sharpness 양호Good 우수Great 우수Great 양호Good 양호Good 갈색 선명도brown sharpness 양호Good 양호Good 양호Good 우수Great 우수Great

[실험 예 1][Experimental Example 1]

상기 실시예 1 내지 실시예 5의 실험에서 가장 우수한 결과값을 가지는 실시예 2의 면직물 날염용 조성물에서 반응촉진혼합물 대신 요소를 첨가하여 날염 조성물을 제조하고, 그 날염 조성물 100 중량부에 대하여 염료 5 중량부를 혼합하여 pH 7.5의 염료 조성물을 제조하였다.In the composition for printing cotton fabric of Example 2, which has the best results in the experiments of Examples 1 to 5, a printing composition was prepared by adding urea instead of the reaction promoting mixture, and dye 5 based on 100 parts by weight of the printing composition A dye composition of pH 7.5 was prepared by mixing parts by weight.

상기 제조된 염료 조성물을 스크린 날염법으로 면직물에 인날하고, 130℃ 온도에서 1분간 건조한 후, 105℃ 온도에서 10분간 증열하고, 증열이 완료된 후 수세하여 호료, 미고착 염료 등 잔여물을 제거하여 면직물에 소정 모양으로 여러 색상을 날염하였다. The prepared dye composition is printed on cotton fabric by screen printing method, dried at 130 ° C. for 1 minute, heated at 105 ° C. for 10 minutes, and washed with water after completion of steaming to remove residues such as paint and unfixed dye. Various colors were printed on the cotton fabric in a predetermined shape.

도 1과 같이 요소가 혼합된 면직물 날염용 조성물과 실시예 2의 면직물 날염용 조성물에 의해 날염된 면직물의 색상을 비교한 결과, 적색 선명도와 갈색 선명도는 요소 첨가 날염 샘플이 우수한 반면, 남색 선명도, 황색 선명도, 청색 선명도, 하늘색 선명도에서는 실시예 2의 반응촉진혼합물 첨가 날염 샘플이 우수하게 날염되었다. As a result of comparing the colors of the cotton textile printing composition in which urea is mixed with the cotton textile printing composition of Example 2 as shown in FIG. In terms of yellow sharpness, blue sharpness, and sky blue sharpness, the printing sample containing the reaction accelerator mixture of Example 2 was excellently printed.

따라서 본 발명은 요소를 대체하는 반응촉진혼합물이 혼합된 면직물 날염용 조성물을 이용함으로써 염료의 용해 및 분산 상태가 향상되어 발색성 및 색감이 향상될 뿐만 아니라, 섬유 조직 속 침투를 도와 균염 및 염료 고착 촉진 효과가 우수하면서도, 질소화합물 폐수의 발생을 억제하여 폐수처리에 따른 비용 부담을 저감시킬 수 있게 된다. Therefore, in the present invention, by using the composition for cotton textile printing mixed with the reaction promoting mixture replacing the urea, the dissolution and dispersion state of the dye is improved, so that the color development and color are improved, as well as the penetration into the fiber tissue to promote leveling and dye adhesion While the effect is excellent, it is possible to reduce the cost burden of wastewater treatment by suppressing the generation of nitrogenous compound wastewater.

이상에서 본 발명은 비록 한정된 실시 예에 대하여 설명되었으나, 본 발명의 권리범위는 이에 한정되는 것은 아니며, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자에 의해 본 발명의 기술사상과 아래의 청구범위의 균등범위 내에서 이루어지는 여러 다양한 변형 및 개량 형태 또한 본 발명의 권리범위에 속한다 할 것이다. In the above, although the present invention has been described with respect to a limited embodiment, the scope of the present invention is not limited thereto, and the technical idea of the present invention and the following claims by those of ordinary skill in the art to which the present invention pertains. Various modifications and improvements made within the equivalent range of the scope will also fall within the scope of the present invention.

Claims (4)

물, 알긴산나트륨(sodium alginate), 복합호료, 환원방지제, 방부제, 헥사메타인산소다(sodium hexametaphosphate), 중탄산나트륨(Sodium bicarbonate), 반응촉진혼합물이 혼합되며,
상기 반응촉진혼합물은, 중질 처리된 파리핀 정제유, 미네랄오일(광유), 에톡실레이티드 알코올(ethoxylated alcohols), 하이드록시폴리(hydroxypoly(oxy-1 2-ethanediyl)), 트리에탄올아민(triethanol amine), 에톡실레이티드 프로폭실레이티드(ethoxylated propoxylated)가 혼합되어 이루어지는 것을 특징으로 하는 면직물 날염용 조성물.
Water, sodium alginate, complex dye, reduction inhibitor, preservative, sodium hexametaphosphate, sodium bicarbonate, reaction promoting mixture are mixed,
The reaction accelerating mixture is a heavy treated paraffin refined oil, mineral oil (mineral oil), ethoxylated alcohols, hydroxypoly (oxy-1 2-ethanediyl), triethanolamine (triethanol amine) , ethoxylated propoxylated (ethoxylated propoxylated) cotton fabric printing composition characterized in that it is made by mixing.
 제1항에 있어서 상기 반응촉진혼합물은,
중질 처리된 파리핀 정제유 10 내지 20 중량%; 미네랄오일(광유) 20 내지 30 중량%; 에톡실레이티드 알코올(ethoxylated alcohols) 3 내지 10 중량%; 하이드록시폴리(hydroxypoly(oxy-1 2-ethanediyl)) 20 내지 30 중량%; 트리에탄올아민(triethanol amine) 20 내지 30 중량%; 에톡실레이티드 프로폭실레이티드(ethoxylated propoxylated) 3 내지 10 중량%; 를 포함하는 것을 특징으로 하는 면직물 날염용 조성물.According to claim 1, wherein the reaction promoting mixture,
10 to 20% by weight of heavy-treated paraffin refined oil; 20 to 30% by weight of mineral oil (mineral oil); 3 to 10% by weight of ethoxylated alcohols; 20 to 30% by weight of hydroxypoly(oxy-1 2-ethanediyl); 20 to 30% by weight of triethanolamine; 3 to 10% by weight of ethoxylated propoxylated; A composition for cotton textile printing comprising a. 삭제delete 삭제delete
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970062006A (en) 1997-06-16 1997-09-12 남정한 Method for producing a printing foil and composition thereof
KR19990007010A (en) * 1997-06-17 1999-01-25 봅 피로스카 랍 Printing method of textile material
CN112323514A (en) * 2020-11-20 2021-02-05 浙江理工大学 Low-ammonia-nitrogen urea substitute with high color-obtaining performance and active printing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970062006A (en) 1997-06-16 1997-09-12 남정한 Method for producing a printing foil and composition thereof
KR19990007010A (en) * 1997-06-17 1999-01-25 봅 피로스카 랍 Printing method of textile material
CN112323514A (en) * 2020-11-20 2021-02-05 浙江理工大学 Low-ammonia-nitrogen urea substitute with high color-obtaining performance and active printing method thereof

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