KR102436340B1 - Fabric having bactericidal function and its - Google Patents

Fabric having bactericidal function and its Download PDF

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KR102436340B1
KR102436340B1 KR1020220046399A KR20220046399A KR102436340B1 KR 102436340 B1 KR102436340 B1 KR 102436340B1 KR 1020220046399 A KR1020220046399 A KR 1020220046399A KR 20220046399 A KR20220046399 A KR 20220046399A KR 102436340 B1 KR102436340 B1 KR 102436340B1
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fabric
weight
parts
coating solution
deodorizing
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Korean (ko)
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한근진
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한근진
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/02—Acyclic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • D06B15/02—Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours by squeezing rollers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B19/00—Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
    • D06B19/0005—Fixing of chemicals, e.g. dyestuffs, on textile materials
    • D06B19/0011—Fixing of chemicals, e.g. dyestuffs, on textile materials by heated air
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/78—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon; with halides or oxyhalides of silicon; with fluorosilicates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
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  • Environmental Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention relates to a fabric having a sterilizing function and a manufacturing method thereof. More specifically, a fabric used for a curtain, sofa, wallpaper, bedding, etc. is impregnated with a coating liquid in which, based on 1,000 parts by weight of water, 5-10 parts by weight of a sterilizer, 50-150 parts by weight of a binder, and 30-50 parts by weight of zeolite are mixed. The fabric which absorbs deodorizing and sterilizing substances is passed through a pressure roller (R) to remove some of the extra coating liquid, and then the fabric is preheated for 15-20 seconds at 80-100 ℃ in a heating chamber with hot air. After the pre-heating, while the fabric is continuously heated in a chamber for 25-40 seconds at 150-180 ℃ and dried, curing is carried out so that the deodorizing and sterilizing substances enter the inside of yarn weaving the fabric. The fabric, which is cured to prevent the deodorizing and sterilizing substances located in an interior portion from escaping to an outside of the fabric, is continuously quenched with cold air at 3-20 ℃ and post-processed. Accordingly, penetration of dust, sweat and moisture into a cushion layer of a sofa can be prevented.

Description

살균기능을 갖는 직물 및 그 제조방법{FABRIC HAVING BACTERICIDAL FUNCTION AND ITS}Fabric having sterilization function and manufacturing method thereof

본 발명은 살균기능을 갖는 직물에 관한 것으로서, 더욱 상세하게는, 커텐 소파 벽지 침구류 등에 사용하는 직물을 살균하는 인체에 유해하지 않는 살균제와 항균작용하는 제올라이트 혼합한 수성용액으로 코팅하여 살균기능을 갖는 직물 및 그 제조방법에 관한 것이다.The present invention relates to a fabric having a sterilization function, and more specifically, by coating it with an aqueous solution mixed with a sterilizing agent that is not harmful to the human body and a zeolite having an antibacterial action that sterilizes fabrics used for curtain sofa, wallpaper, bedding, etc. It relates to a fabric having a fabric and a method for manufacturing the same.

일반적으로 소파(sofa)는 스폰지 등의 푹신한 것으로 체워 앉아서 등을 기대는 경사진 등받이와 앉는 좌대로 여려명이 앉거나 기댈 수 있는 것으로, 근대에 활성화된 대표적인 기구이다.In general, a sofa is a soft material such as a sponge, with a sloping back and a pedestal on which to sit and lean back, so that several people can sit or lean on it.

인체에서 분비되는 땀과 기타 지방이나 단백질 등의 유기물에 의해 세균이나 미생물이 번식하게 되며집 먼지, 박테리아, 곰팡이, 미생물, 진드기, 세균과 같은 병원균으로 인하여 많은 질환이 발생하고 있으며, 특히 소파 베개나, 침대시트, 매트리스와 같은 침구류에는 많은 세균이 존재하게 된다. Bacteria and microorganisms are propagated by sweat and other organic substances such as fat or protein, which are secreted from the human body, and many diseases are caused by pathogens such as house dust, bacteria, mold, microorganisms, mites, and bacteria. Bedding, such as bed sheets, mattresses, etc., contains many bacteria.

특히 박테리아, 균류, 바이러스, 및 박테리아 포자와 같은 병원체는 인간 및 동물 질병의 원인이 된다.Pathogens, particularly bacteria, fungi, viruses, and bacterial spores, cause disease in humans and animals.

직물로 겉면을 감싸는 직물지소파는 부드러운 느낌을 주는 장점이 있지만 반면에 주거공간에 노출된 집먼지 진드기 등의 알레르기를 유발시키는 알레르겐(allergen) 물질의 증가와 먼지, 땀, 습기가 쿠션층으로 쉽게 침투되고 각종 피부질환이나 호흡기질환의 원인이되는 많은 세균이 번식으로 수많은 세균에 그대로 노출되어 각종 질병을 일의키는 원인이 된다. The fabric sofa has the advantage of giving it a soft feel, but on the other hand, an increase in allergen substances that cause allergies, such as house dust mites, exposed to the living space, and dust, sweat, and moisture easily penetrate into the cushion layer. Many bacteria that cause various skin diseases and respiratory diseases reproduce and are exposed to numerous bacteria as they are, leading to various diseases.

한편, 애완동물을 키우는 가구들이 급격하게 늘어 애완동물과 사람이 함께 주거공간에서 생활하게 됨에 따라 애완동물들의 털이나 소변을 가리지 못할 때는 소파 등을 흥건하게 적시는 경우가 많고, 일반적인 소파는 방수가 잘 안되기 때문에 기재인 스펀지나 솜까지 스며들어 오래될 경우 역겨운 악취를 풍기고 속이 썩거나 하여 불결할 뿐만 아니라 위생상으로도 좋지 않았다On the other hand, as the number of households raising pets has increased rapidly and people and pets are living together in a living space, when it is not possible to cover the fur or urine of the pets, the sofa is often wetted, and the general sofa is not waterproof. Because it does not work well, even the sponge or cotton, which is the base material, permeates, giving off a disgusting stench and rotting the inside, making it unclean and not good for hygiene.

이와 같은 직물지 소파의 단점을 방지하기 위하여 종래는 소파등을 만드는 직물지에 우레탄 등으로 코팅하여 사용하였으나, 코팅된 표면에 남아 있는 애완동물용 오줌을 닦아 낸다고 해도 단순히 물을 묻혀 닦아내는 것이므로 세척력이 약해 위생상으로도 좋지 않아 세균이 서식하는 것을 완전하게 해결할 수 없기 때문에 소파용 직물지 가공하는 과정에서 항균처리한 소파용 직물지는 세균이 서식하는 것을 다소 예방할 수는 있지만 살균하지 못해 위생에 해롭게 되는 단점이 있었다.In order to prevent such shortcomings of fabric sofas, conventionally, urethane was coated on fabric paper for making sofas, etc., but even if you wipe off the pet urine remaining on the coated surface, the cleaning power is weak because it is simply wiping with water. Because it is not sanitary enough to completely solve the inhabitation of bacteria, the sofa textile paper treated with antibacterial treatment in the process of processing the sofa textile can somewhat prevent bacteria from growing, but the disadvantage is that it is harmful to hygiene because it cannot be sterilized. there was.

또 벽지는 건물 내벽이나 천장에 바르는 종이로 건축물의 벽체를 형성시킨 상태에서 그 표면을 매끈하게 하는 미장작업을 실시하고, 미장된 벽면에 벽지를 발라 인테리어를 마감하는 것이나 실내를 장식하는 건축자재를 유기화합물 등의 유해물질의 방사하는 사용으로 실내공기의 질을 떨어지고 세균 및 곰팡이 등의 의한 공기 오염돠고 인테리어 제품 등에서 악취를 발생시켜 많은 불쾌감을 발생시킨다. 따라서, 최근에는 공기질의 향상이 국민적인 관심이 증대되오 쾌적하고 인체에 무해한 친환경적인 벽지를 요구하고 있다.In addition, wallpaper is a paper applied to the inner wall or ceiling of a building, and a plastering operation is performed to smooth the surface while the wall of the building is formed. The use of emitting harmful substances such as organic compounds reduces the quality of indoor air, pollutes the air by bacteria and mold, and generates odors in interior products, which causes a lot of discomfort. Therefore, in recent years, public interest in improving air quality has increased, and there is a demand for environmentally friendly wallpaper that is comfortable and harmless to the human body.

따라서 각종 질병을 예방하기 위해서는 피부의 청결과 더불어 커텐, 침구류를 세탁하는 것이 제일 좋은 수단이나 카텐 침구류는 부피가 커서 세탁하기가 어렵고 벽지는 기존벽지를 제거하고 다시 시공해야하고 특히 소파는 세탁할 수 없어 소파의 커버인 소파직물을 교환한다든지 별도의 소파를 구입하여야 하므로 고비용이 낭비되는 단점이 있다 Therefore, in order to prevent various diseases, it is best to wash curtains and bedding as well as skin cleanliness, but curtain bedding is bulky and difficult to wash. There is a disadvantage in that high costs are wasted because the sofa fabric, which is the cover of the sofa, must be replaced or a separate sofa must be purchased.

상기와 같은 문제점을 해결하기 위해서, 본 발명은 직물지의 표면과 이면에 살균제와 제올라이리트를 혼합한 수성용액으로 코팅을 하므로서 소파의 쿠션층에 먼지, 땀, 습기가 침투하는 것을 방지함과 동시에 직물의 외피에 존재하는 균을 살균하는 살균작용과 항균 방취할수 있도록 하는 직물지를 제공하는데 그 목적이 있다.In order to solve the above problems, the present invention prevents the penetration of dust, sweat, and moisture into the cushion layer of the sofa by coating the surface and the back surface of the fabric with an aqueous solution mixed with a disinfectant and zeolite. An object of the present invention is to provide a fabric paper that can sterilize bacteria existing on the outer skin of the fabric and provide antibacterial and deodorizing properties.

이와 같은 목적을 달성하기 위해서, 본 발명은 공지의 직물을 물 1000중량부를 기준으로 살균제 5 내지 10중량부, 바인더 50 내지 150중량부. 제올라이트 30 내지 50중량부를 혼합한 코팅액에 함침하여 탈취 및 살균 물질을 흡수한 직물을 가압로울러(R) 사이로 통과시켜 여분의 코팅액 일부가 제거된 직물을 열풍으로 가열챔버에서 80∼100℃에서 15 내지 20초 동안 예비가열하고 상기 예비가열후 연속하여 150 내지 180℃의 챔버에서 25 내지 40초동안 가열하여 건조하면서 탈취 및 살균 물질이 직물을 제직하는 실의 내부까지 들어가는 큐어링을 실시하여 실내부에 위치한 탈취 및 살균 물질이 직물지 외부로 빠져나오는 못하게 큐어링된 직물을 연속하여 3 ∼ 20℃ 냉풍으로 급냉하고 후가공 처리하는 것을 특징으로 한다.In order to achieve this object, the present invention is a known fabric, based on 1000 parts by weight of water, 5 to 10 parts by weight of the disinfectant, 50 to 150 parts by weight of the binder. By impregnating the coating solution mixed with 30 to 50 parts by weight of zeolite and passing the fabric absorbing the deodorizing and sterilizing material between the pressure rollers (R), the excess coating solution is removed from the fabric with hot air in a heating chamber at 80 to 100 ° C. After pre-heating for 20 seconds, and continuously heating for 25 to 40 seconds in a chamber at 150 to 180° C. after the pre-heating, curing is performed so that deodorizing and sterilizing substances enter the interior of the yarn weaving the fabric while drying. It is characterized in that the cured fabric is continuously cooled with cold air at 3 to 20° C. and post-processing is performed to prevent the located deodorizing and sterilizing material from escaping to the outside of the fabric.

또한, 살균제는 피피 (PP, POLYPROPYLENE) 97중량%, 알루미노실리케이(ALUMINO SILICATES)3∼8중량%, 알루미노규산나트륨(ALUMINIUM SODIUM SILICATE)3중량%, 에틸아크릴(ETHYL ACRYLATE)2∼5중량%, n부틸아크릴(N-BUTYL ACRYLATE)2∼5중량%, 칼슘옥사이드(CALCIUM OXIDE) 1중량% 미만, 아크릴산(ACRYLIC ACID)1중량% 미만, 노닐페놀에톡시레이트 (NONYLPHENOL ETHOXYLATE) 1중량% 미만으로 구성되는 것을 특징으로 한다.In addition, the disinfectant is PP (PP, POLYPROPYLENE) 97% by weight, ALUMINO SILICATES 3 to 8% by weight, ALUMINIUM SODIUM SILICATE 3% by weight, ethyl acrylic (ETHYL ACRYLATE) 2 to 5 wt%, n-butyl acrylic (N-BUTYL ACRYLATE) 2-5 wt%, calcium oxide (CALCIUM OXIDE) less than 1 wt%, acrylic acid (ACRYLIC ACID) less than 1 wt%, nonylphenol ethoxylate (NONYLPHENOL ETHOXYLATE) 1 wt% It is characterized in that it is composed of less than %.

또한, 제올라이트는 분말로 만들어 사용하는 것을 특징으로 구성되는 것을 특징으로 한다.In addition, the zeolite is characterized in that it is characterized in that it is used by making it into a powder.

또한 직물은 코팅액에 광촉매액을 50내지 100중량부를 혼합하여 광촉매가 코팅된 것을 특징으로 한다.In addition, the fabric is characterized in that the photocatalyst is coated by mixing 50 to 100 parts by weight of the photocatalyst solution with the coating solution.

살균기능을 갖는 직물 제조방법은 직물을 준비하는 단계(100)와; 직물를 코팅액으로 탈취 및 살균 물질을 코팅하는 코팅단계(200)와; 코팅액의 일부를 제거하는 직물지 가압 단계(300)와; 코팅액의 일부를 제거한 직물을 가열하는 예비가열단계(400)와; 가열하여 건조하면서 탈취 및 살균 물질이 직물의 내부까지 들어가도록 하는 큐어링하는 단계(500)와; 큐어링으로 직물의 내부까지 들어가 있는 탈취 및 살균 물질이 직물지외부로 빠져나오는 못하게 냉풍으로 냉각하는 급냉단계(600)와; 급냉한 직물을 텐타 등 후가공단계(700)로 구성된 것을 특징으로 한다 A method of manufacturing a fabric having a sterilization function includes the steps of preparing a fabric (100); A coating step 200 of coating the fabric with a deodorizing and sterilizing material with a coating solution; A fabric pressing step 300 for removing a portion of the coating solution and; A preheating step 400 of heating the fabric from which a part of the coating solution is removed; Curing (500) to allow the deodorizing and sterilizing material to enter the interior of the fabric while drying by heating; A rapid cooling step 600 of cooling with cold air so that the deodorizing and sterilizing material that has entered the inside of the fabric by curing does not escape to the outside of the fabric; It is characterized in that it is composed of a post-processing step 700 such as tenter of the quenched fabric.

본 발명은 커텐 소파 벽지 침구류에 사용하는 직물의 표면과 이면에 인체에 유해하지 않는 샬균제와 제올라이리트를 혼합한 수성용액으로 코팅을 하여 소파의 쿠션층에 먼지, 땀, 습기가 침투하는 것을 방지함과 동시에 직물의 외피에 존재하는 균을 박테라이 등과 같은 세균을 죽이는 살균작용과 항균 방취할수 있는 효과를 갖는다.The present invention is to coat the surface and back of the fabric used for curtain sofa wallpaper and bedding with an aqueous solution mixed with a disinfectant and zeolite that is not harmful to the human body, so that dust, sweat, and moisture penetrate into the cushion layer of the sofa. At the same time, it has the effect of sterilizing and deodorizing bacteria that are present on the outer skin of the fabric, such as Bacteria.

도 1은 본 발명에 따른 살균기능을 갖는 직물 생산을 보인 개략도.
도 2는 본 발명에 따른 살균기능을 갖는 직물을 제조방법 공정도.1 is a schematic view showing the production of a fabric having a sterilization function according to the present invention.
Figure 2 is a process diagram of a method for manufacturing a fabric having a sterilization function according to the present invention.

본 발명을 충분히 이해하기 위해서 본 발명의 바람직한 실시예를 첨부 도면을 참조하여 설명한다.In order to fully understand the present invention, preferred embodiments of the present invention will be described with reference to the accompanying drawings.

본 발명의 실시예는 여러가지 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상세히 설명하는 실시예로 한정되는 것으로 해석되어서는 안된다. 본 실시예는 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 안전하게 설명하기 위하여 제공되는 것이다.Embodiments of the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the embodiments described in detail below. This embodiment is provided to more safely explain the present invention to those of ordinary skill in the art.

따라서 도면에서의 요소의 형상 등은 보다 명확한 설명을 강조하기 위해서 과장되어 표현될 수 있다. 각 도면에서 동일한 부재는 동일한 참조부호로 도시한 경우가 있음을 유의하여야 한다.Accordingly, the shape of elements in the drawings may be exaggerated to emphasize a clearer description. It should be noted that the same members in each drawing are sometimes shown with the same reference numerals.

도 1은 도 1은 본 발명에 따른 살균기능을 갖는 직물 생산을 보인 개략도이고, 도 2는 본 발명에 따른 살균기능을 갖는 직물을 제조방법 공정도이다Figure 1 is a schematic diagram showing the production of a fabric having a sterilization function according to the present invention, Figure 2 is a process diagram of a manufacturing method of a fabric having a sterilization function according to the present invention

본 발명에 따른 살균기능을 갖는 직물지를 도 1 및 도2에 도시된 것을 참고하여 상세하게 설명하면 다음과 같다.The fabric paper having a sterilization function according to the present invention will be described in detail with reference to FIGS. 1 and 2 .

본 발명의 살균기능을 갖는 직물지는 면, 마 등으로 제직한 천연섬유, 재생섬유, 합성섬유로 제직한 직물을 물 1000중량부를 기준으로 살균제 5 내지 10중량부, 바인더 50 내지 150중량부. 제올라이트 30 내지 50중량부를 혼합한 코팅액을 충진한 용기(100)에 함침하여 탈취 및 살균 물질을 흡수한 직물을 가압 로울러(R) 사이로 통과시켜 직물 표면에 코팅액이 평활한 코팅하고 여분의 코팅액 일부가 제거되게 짠 직물을 가열챔버(20)로 보내 먼저 예비가열하고 건조하면서 탈취 및 살균 물질이 직물지를 제직하는 실의 내부까지 들어가게 하는 큐어링하는 본가열챔버(30)에서 높은 온도의 열풍으로 가열하여 큐어링되어 직물의 제작하는 실내부에 위치한 탈취 및 살균 물질이 직물지 외부로 빠져 나오는 못하게 급냉하고 후가공 처리한다. The textile paper having a sterilizing function of the present invention is based on 1000 parts by weight of water for a fabric woven with natural fibers, regenerated fibers, and synthetic fibers woven from cotton, hemp, etc., 5 to 10 parts by weight of a disinfectant, and 50 to 150 parts by weight of a binder. By impregnating the container 100 filled with the coating solution mixed with 30 to 50 parts by weight of zeolite, and passing the fabric absorbing the deodorizing and sterilizing material through the pressure rollers (R), the coating solution is smooth on the surface of the fabric, and some of the extra coating solution is By sending the woven fabric to be removed to the heating chamber 20, it is first preheated and dried with a high-temperature hot air in the main heating chamber 30, which cures the deodorizing and sterilizing material to enter the inside of the weaving thread. It is quenched and post-processed to prevent the deodorizing and sterilizing substances located in the interior part of the cured fabric from escaping to the outside of the fabric.

직물은 소파용 직물이나 케텐 침구류 벽지 등으로 시용되는 것으로 면, 마 등으로 제직한 천연섬유, 재생섬유 및 합성섬유 등의 다양한 재질로 제직한 통상의 직물지를 사용한다. The fabric is used for sofa fabrics, ketene bedding, wallpaper, etc., and ordinary fabrics woven with various materials such as natural fibers woven from cotton, hemp, etc., regenerated fibers and synthetic fibers are used.

상기 직물는 경사 및 위사로 공급되는 원사는 나일론사, PET사, 및 저온PET사 중 1종만을 사용할 수도 있고, 2종 이상을 사용할 수도 있으며, 바람직하게는 3종을 이용하여 제직할 수 있으면 제직하지 않는 부직포를 사용할 수도 있다. In the fabric, the yarns supplied as warp and weft yarns may use only one of nylon yarn, PET yarn, and low-temperature PET yarn, or two or more types, and preferably three types if weaving is possible using three types. Non-woven fabrics may also be used.

또 소파나 커튼의 기능성을 고려하여 통상의 방식으로 만들어진 원사라면 제한되지 않고 직물지는 공지의 다양한 제직기를 이용하여 제직될 수 있다.In addition, it is not limited as long as it is a yarn made in a conventional manner in consideration of the functionality of a sofa or curtain, and the fabric may be woven using various known weaving machines.

직물을 코팅하는 코팅액은 물 1000중량부를 기준으로 살균제 5 내지 10중량부, 바인더 50 내지 150중량부, 제올라이트 30 내지 50중량부를 혼합한다. The coating solution for coating the fabric is mixed with 5 to 10 parts by weight of a disinfectant, 50 to 150 parts by weight of a binder, and 30 to 50 parts by weight of a zeolite based on 1000 parts by weight of water.

직물을 코팅하는 코팅액은 용매로 물을 사용하여 수용액으로 만들어 사용한다. The coating solution for coating the fabric is used as an aqueous solution using water as a solvent.

상기 직물을 코팅하는 코팅액의 사용하는 물은 용매로서 분산력을 증가시키는 작용으로 코팅액에 첨가하는 살균제 바인더 제올라이트 등이 균일하게 혼합되도록 하면서, 살균제의 규산나트륨과 알루미늄규산염은 내열성을 증진시키고 바인더 간의 결합력을 높이는 작용을 한다.The water used in the coating solution for coating the fabric acts as a solvent to increase the dispersion power, so that the disinfectant binder zeolite, etc. added to the coating solution is uniformly mixed, while sodium silicate and aluminum silicate of the disinfectant enhance heat resistance and increase the bonding force between the binders. height works.

살균제는 물 1000중량부를 기준으로 5 내지 10중량부를 혼합한다. The disinfectant is mixed with 5 to 10 parts by weight based on 1000 parts by weight of water.

상기 살균제는 피피(PP, POLYPROPYLENE) 97중량%, 알루미노실리케이트(ALUMINO SILICATES) 3∼8중량%, 알루미노규산나트륨(ALUMINIUM SODIUM SILICATE) 3중량%, 에틸아크릴(ETHYL ACRYLATE) 2∼5중량%, n부틸아크릴(N-BUTYL ACRYLATE) 2∼5중량%, 칼슘옥사이드(CALCIUM OXIDE) 1중량% 미만, 아크릴산(ACRYLIC ACID) 1중량% 미만, 노닐페놀에톡시레이트 (NONYLPHENOL ETHOXYLATE) 1중량% 미만으로 구성된다. The disinfectant is PP (PP, POLYPROPYLENE) 97% by weight, aluminosilicate (ALUMINO SILICATES) 3 to 8% by weight, sodium aluminosilicate (ALUMINIUM SODIUM SILICATE) 3% by weight, ethyl acrylic (ETHYL ACRYLATE) 2 to 5% by weight , n-butyl acrylic (N-BUTYL ACRYLATE) 2-5% by weight, calcium oxide (CALCIUM OXIDE) less than 1% by weight, acrylic acid (ACRYLIC ACID) less than 1% by weight, nonylphenol ethoxylate (NONYLPHENOL ETHOXYLATE) less than 1% by weight is composed of

상기 살균제에 첨가하는 피피(PP, POLYPROPYLENE)는 열가소성수지로 인장강도와 충격강도, 표면강도가 우수하고, 각각의 성분을 균질하게 믹싱되게 하고 기재와의 접착이 잘되도록 하면서 기재상에 얇은 고분자 층을 형성되도록하는 것이다. PP, POLYPROPYLENE, added to the disinfectant, is a thermoplastic resin that has excellent tensile strength, impact strength, and surface strength. to be formed.

살균제에는 피피(PP, POLYPROPYLENE) 97중량%를 첨가한다. 97% by weight of PP, POLYPROPYLENE is added to the disinfectant.

상기 살균제에 첨가하는 알루미노실리케이트(alumino silicate)는 결합제로서의 역할을 하는데, 살균제의 내구성이 유지된다.Alumino silicate added to the disinfectant acts as a binder, and the durability of the disinfectant is maintained.

상기 알루미노실리케이트는 마이크로다공성 표면을 가져 기체상의 수분이 쉽게 흡착될 수 있어 수화반응이 활발히 일어날 수 있도록 발열제로 사용하는데 알루미노실리케이트 발열제는 0.1 내지 2㎚의 직경을 갖는 나노-(nano-), 2 내지 50㎚의 직경을 갖는 메조-(meso-) 및/또는 50 ㎚ 이상, 특히 50 내지 950㎛의 지경의 마크로기공(macropores)을 가지며, 적어도 300 ㎡/g, 특히 300 내지 5,000 ㎡/g의 BET 표면을 가지는 것이 바람직하다. The aluminosilicate has a microporous surface so that moisture in the gas phase can be easily adsorbed and thus used as a heat generating agent so that the hydration reaction can actively occur. The aluminosilicate heat generating agent has a diameter of 0.1 to 2 nm. meso- with a diameter of 2 to 50 nm and/or macropores with a diameter of at least 50 nm, in particular 50 to 950 μm, at least 300 m 2 /g, in particular 300 to 5,000 m 2 /g It is desirable to have a BET surface of

상기 알루미노 실리케이트를 3 중량% 미만 첨가하는 경우 발열에 따른 방향성 증폭 효과가 제대로 발현되지 않으며, 8 중량% 초과 첨가하는 경우 과도한 발열되므로 상기 알루미노 실리케이트는 전체 살균제의 3 내지 8 중량% 첨가하는 것이 좋다. When the aluminosilicate is added in less than 3% by weight, the directional amplification effect due to the exotherm is not properly expressed, and when it is added in more than 8% by weight, excessive heat is generated. good night.

살균제에 첨가하는 알루미노 실리케이트는 3 내지 8 중량% 첨가하는 것이 좋다.It is preferable to add 3 to 8 wt% of aluminosilicate added to the disinfectant.

상기 살균제의 혼합사용하는 알루미노규산나트륨(ALUMINIUM SODIUM SILICATE)은 물에 의해 분산력을 증가하여 내열성을 증진시키고 바인더 간의 결합력을 높이는 작용을 한다.Sodium aluminosilicate (ALUMINIUM SODIUM SILICATE), which is mixed with the disinfectant, increases the dispersing power by water to improve heat resistance and increase the bonding strength between binders.

살균제에 첨가하는 알루미노규산나트륨(ALUMINIUM SODIUM SILICATE) 3중량%첨가하는 것이 좋다.It is recommended to add 3% by weight of sodium aluminosilicate (ALUMINIUM SODIUM SILICATE) added to the disinfectant.

상기 살균제에 혼합첨가하는 노닐페놀 에톡실레이트(nonylphenol ethoxylates, NPEs)는 물과 기름에 대한 친화성이 좋아 계면 활성제로 및 유화제(특히, 음이온성 계면활성제의 생산에 이용), 윤활제, 정전기 방지제, 고성능 섬유-정련제, 농약용 유화제, 항산화제(특히, 고무 및 플라스틱 제조에 이용), 및 윤활유 첨가제로 많이 이용되고 있다.Nonylphenol ethoxylates (NPEs) mixed and added to the disinfectant have good affinity for water and oil, so they are used as surfactants and emulsifiers (especially for the production of anionic surfactants), lubricants, antistatic agents, It is widely used as a high-performance fiber-refining agent, an emulsifier for agrochemicals, an antioxidant (especially used in the manufacture of rubber and plastics), and a lubricant additive.

상기 살균제에 혼합첨가하는 에틸아크릴(ETHYL ACRYLATE)은 주로 다양한 중합체 조제에 사용하는데 살균작용을 한다. Ethyl acrylic (ETHYL ACRYLATE) mixed and added to the sterilizing agent is mainly used for preparing various polymers and has a sterilizing action.

살균제에 첨가하는 에틸아크릴(ETHYL ACRYLATE) 2∼5중량%를 첨가하는 것이 좋다. It is good to add 2-5 wt% of ethyl acryl (ETHYL ACRYLATE) added to the disinfectant.

상기 살균제에 혼합첨가하는 n부틸아크릴(N-BUTYL ACRYLATE)은 향긋한 과일 냄새가 나는 무색의 액체로 코팅제, 페인트, 가죽 및 섬유 마감제, 접착제, 코팅제, 유화제에서 아크릴수지 및 중합체와 공중합체의 생산 시 사용되는 단량체이다.N-BUTYL ACRYLATE, which is mixed and added to the above disinfectant, is a colorless liquid with a fragrant fruity odor. It is used in coatings, paints, leather and textile finishes, adhesives, coatings, and emulsifiers in the production of acrylic resins and polymers and copolymers. the monomer used.

살균제에 첨가하는 n부틸아크릴(N-BUTYL ACRYLATE) 2∼5중량% 첨가하는 것이 좋다.It is good to add 2-5 wt% of n-butyl acryl (N-BUTYL ACRYLATE) added to the disinfectant.

살균제에 첨가하는 칼슘옥사이드(Calcium oxide)는 석회·생석회(生石灰)라고도 하고 산소와 칼슘의 화합물로 백색의 결정이다. 공기 중에서 분해되며 물과 반응하면 발열하여 수산화칼슘을 생성한다. 석회비료, 건조제, 시멘트, 표백제등 다양한 용도로 쓰이며 알칼리성이 강해 흡입하면 위험하다. 화학식 CaO. 순수한 것은 등축정계(等軸晶系)의백색 결정으로, 녹는점 2,570℃이다. 공기 중에 방치하면 수분과 이산화탄소를 흡수하여 수산화칼슘(소석회)과 탄산칼슘으로 분해한다. 또, 물을 작용시키면 발열(發熱)하여 수산화칼슘이 된다. 석회석 또는 탄산칼슘 CaCO3을 약 900℃ 이상으로 가열하면 생긴다 Calcium oxide added to the disinfectant is also called lime or quicklime, and is a compound of oxygen and calcium, and is a white crystal. It decomposes in air and reacts with water to exotherm to form calcium hydroxide. It is used for various purposes such as lime fertilizer, desiccant, cement, and bleach. Formula CaO. Pure is equiaxed white crystals with a melting point of 2,570°C. When left in the air, it absorbs moisture and carbon dioxide and decomposes into calcium hydroxide (slaked lime) and calcium carbonate. In addition, when water is reacted, heat is generated to form calcium hydroxide. It is formed when limestone or calcium carbonate CaCO3 is heated to about 900°C or higher.

살균제에 첨가하는 칼슘옥사이드(CALCIUM OXIDE) 1중량% 미만 첨가하는 것이 좋다.It is recommended to add less than 1% by weight of calcium oxide (CALCIUM OXIDE) added to the disinfectant.

상기 살균제에 혼합첨가하는 노닐페놀 에톡실레이트(nonylphenol ethoxylates, NPEs)는 물과 기름에 대한 친화성 정도를 나타내는 값이 좋아 유용성 계면 활성제 및 유화제(특히, 음이온성 계면활성제의 생산에 이용), 윤활제, 정전기 방지제, 고성능 섬유-정련제, 농약용 유화제, 항산화제(특히, 고무 및 플라스틱 제조에 이용), 및 윤활유 첨가제로 많이 이용되고 있다. Nonylphenol ethoxylates (NPEs) mixed and added to the disinfectant have good values indicating the degree of affinity for water and oil, so oil-soluble surfactants and emulsifiers (especially used in the production of anionic surfactants), lubricants , an antistatic agent, a high-performance fiber-refining agent, an emulsifier for agrochemicals, an antioxidant (especially used in the manufacture of rubber and plastics), and a lubricant additive.

살균제에 첨가하는 노닐페놀에톡시레이트 (NONYLPHENOL ETHOXYLATE) 1중량% 미만 첨가하는 것이 좋다.It is recommended to add less than 1% by weight of nonylphenol ethoxylate (NONYLPHENOL ETHOXYLATE) added to the disinfectant.

코팅액에 첨가하는 제올라이트계는 나노다공성 구조체로 무기항균제를 사용함으로서 열에서도 산화 및 변질되지 않아, 코팅액의 물성이 변경되는 것을 막아 중심 고인장경질층과 외부 및 내부 내충격경질층 간의 접착력을 향상시켜 충격강도가 낮아지는 것을 방지할 수 있을 뿐만 아니라, 작업공정상 각 성분들의 배합과정 또한 고온에서 고점도 상태에서 이루어질 수 있어 각 성분들의 균일한 혼합이 가능하고 작업성을 향상시킬 수 있다.The zeolite system added to the coating solution is a nanoporous structure. By using an inorganic antibacterial agent, it is not oxidized or deteriorated even by heat, so it prevents the physical properties of the coating solution from being changed, improves the adhesion between the central high tensile hard layer and the external and internal hard hard layer, so that the impact strength can be prevented from being lowered as well. , the mixing process of each component in the working process can also be made in a high-viscosity state at a high temperature, so that uniform mixing of each component is possible and workability can be improved.

상기제올라이트는 무기항균제로 사용되는데 비표면적이 발달한 알루미노 규산염인 제올라이트는 세균이나 곰팡이의 세포막의 단백질에 흡착되어 이온물질들과 활성산소에 의해 세포구조를 파괴하고 에너지대사를 불능으로 만들어 균사체를 사멸시키는 방식으로 항균효과를 가져오기 때문에 일시적인 항균력은 유기항균제보다 조금 낮기는 하나 인체안정성이 높고 내성균이 나타나지 않으며, 항균지속기간도 반영구적으로 사용할 수 있다.The zeolite is used as an inorganic antibacterial agent. Zeolite, an aluminosilicate salt with a developed specific surface area, is adsorbed to the protein of the cell membrane of bacteria or fungi, destroys the cell structure by ionic substances and active oxygen, and disables energy metabolism to destroy the mycelium. Because it has an antibacterial effect in a way that kills it, its temporary antibacterial power is slightly lower than that of organic antibacterial agents, but it has high human stability, no resistant bacteria, and can be used semi-permanently.

이와 같은 항균제로 첨가하는 제올라이트는 적은 양으로도 살균, 살충, 소독 등의 효과를 얻을 수 있으므로 그 첨가량을 제올라이트 30 내지 50중량부를 참가하는 것이 바람직하며, 만약 그 첨가량을 30중량부미만으로 하면 항균효과가 미비하게 나타나며, 50중량부를 초과하여 첨가하여도 특별한 항균력의 증가가 나타나지 않고 고가의 무기항균제의 남발로 인한 원가상승의 요인이 되기 때문이다.Since the zeolite added as such an antibacterial agent can obtain effects such as sterilization, insecticide, and disinfection even with a small amount, it is preferable to participate in the amount of zeolite 30 to 50 parts by weight, and if the amount added is less than 30 parts by weight, antibacterial This is because the effect is insignificant, and even when added in excess of 50 parts by weight, there is no increase in special antibacterial activity, and this is because it becomes a factor of cost increase due to overuse of expensive inorganic antibacterial agents.

바인더는 수용성 바인더 수지를 첨가하는데 공지의 아크릴산, 아크릴아미드, 아크릴로니트릴 등의 아크릴 화합물을 사용할 수 있다. 수용성 바인더 수지는 물 1000중량부에 대해 15-20중량%로 사용된다. 이와 같은 비율의 바인더 수지의 양은 코팅 조성물이 섬유에의 알맞은 접착력을 발휘하게 해준다.As the binder, a well-known acrylic compound such as acrylic acid, acrylamide, or acrylonitrile may be used to add a water-soluble binder resin. The water-soluble binder resin is used in an amount of 15-20% by weight based on 1000 parts by weight of water. The amount of the binder resin in this ratio allows the coating composition to exhibit adequate adhesion to the fibers.

상기 물, 살균제, 바인더. 제올라이트를 혼합한 수용성 코팅액에 직물을 함침하여 직물이 수용성 코팅액을 충분히 흡수하여 탈취 및 살균 물질을 침투시킨 직물지를 로울러(R) 사이를 통과시켜 직물지를 가압하여 겉면에 있는 코팅액이 직물지의 내부까지 침투하도록 하면서 과잉흡수된 코팅액을 제거하여 코팅액이 직물지에 고르게 코팅되도록 한다. The water, disinfectant, and binder. By impregnating the fabric with the water-soluble coating solution mixed with zeolite, the fabric absorbs the water-soluble coating solution sufficiently, and the deodorizing and sterilizing material is passed through the rollers (R) to pressurize the fabric, and the coating solution on the outer surface penetrates to the inside of the fabric. Remove the excessively absorbed coating solution while doing so so that the coating solution is evenly coated on the fabric paper.

수용성 코팅액을 충분히 흡수한 직물을 직물에 수지의 수용성 코팅액을 침투시켜 수지는 중합하고 동시에 섬유에 고착 또는 반응하여 결합시켜 살균효과를 갖도록 코팅액으로 코팅된 직물을 가열하여 건조하면서 탈취 및 살균 물질이 직물의 내부까지 들어가도록 예비가열을 실시한다. Deodorizing and sterilizing substances are removed by heating and drying the fabric coated with the coating solution to have a sterilization effect by allowing the fabric that has sufficiently absorbed the water-soluble coating solution to permeate the fabric with the water-soluble coating solution of the resin, and the resin is polymerized and at the same time adhered or reacted to the fibers to have a sterilization effect. Preheating is performed so that it enters the inside of the

먼저 코팅액을 코팅된 작물을 큐어링하기 전에 예비가열을 실시한다. First, the coating solution is preheated before curing the coated crops.

상기 예비가열을 실시하는 것은 짧은시간 내에 직물이 가열되어 큐어링 효과를 높여 직물의 품질을 향상하기 위하여 큐어링을 실시하기 이전에 직물지를 가열챔버(20)에서 상대적으로 낮은 온도에서 직물을 가열하면서 건조를 실시한다. Conducting the pre-heating is to heat the fabric at a relatively low temperature in the heating chamber 20 before curing the fabric to improve the quality of the fabric by heating the fabric within a short time to increase the curing effect and improve the quality of the fabric. Drying is carried out.

예비가열은 열풍을 이용하여 80∼100℃에서 15 내지 20초 동안 실시하여 직물지를 본가열하여 큐어링을 실시하기 전에 수성코팅액을 흡수한 직물을 가열하여 직물을 건조하면서 열을 가해지도록 짧은 시간에 큐어링을 되도록한다. Pre-heating is carried out at 80-100° C. for 15-20 seconds using hot air for 15 to 20 seconds to heat the fabric that has absorbed the aqueous coating solution before curing the fabric by heating the fabric in a short time to dry the fabric and apply heat. Curing should be done.

큐어링은 상기 예비가열된 직물지를 연속하여 본가열챔버(30)에서 열풍을 이용하여 가열온도는 150 ∼170℃에서 25∼40초동안 실시한다.Curing is carried out at a heating temperature of 150-170° C. for 25-40 seconds using hot air in the main heating chamber 30 in succession to the preheated fabric paper.

큐어링은 코팅액이 중합하고 동시에 섬유에 견고하게 고착 또는 반응시켜 결합하기 위한 것으로 직물지에 흡수된 코팅액의 수분 증발과 수지화 반응이 섬유의 표면, 내부, 직물의 틈 등에서도 일어나며, 건조하면서 직물에 코팅액이 속까지 들어가 있게 하여 오랜동안 살균제성분과 제올라이트가 직물지의 내부에 위치하게 되므로 살균성분과 제올라이트의 오래동안 효과를 갖을 수 있게 한다.Curing is for the purpose of bonding the coating solution by polymerization and at the same time firmly adhering or reacting to the fiber. Evaporation of moisture and resinization reaction of the coating solution absorbed into the fabric also occurs on the surface, inside, and between the fabric gaps, etc. By allowing the coating solution to enter the inside, the disinfectant component and zeolite are located inside the fabric for a long time, so that the sterilizing component and the zeolite can have a long-lasting effect.

큐어링은 150 ∼170℃에서 실시한다. Curing is carried out at 150 ~ 170 ℃.

150 ℃이하인 경우에는 코팅액이 섬유 내부까지 들어가지 않고 표면에 많이 있어 큐어링 효과가 떨어지고 170℃ 이상일 경우에는 직물이 변형되는 경우가 있어If the temperature is below 150℃, the coating solution does not enter the inside of the fiber and there is a lot of it on the surface, so the curing effect is poor. If it is above 170℃, the fabric may be deformed

150 ∼170℃에서 실시하는 것이 좋다.It is recommended to carry out at 150 ~ 170 ℃.

큐어링 시간은 25∼40초 동안 실시한다.Curing time is 25-40 seconds.

이와 같이 큐어링은 큐어링을 실시하기 전에 직물을 예비가열하여 단시간내에 온도를 올려 직물을 제직한 실이 확장되어 큐어링이 일어나면서 탈취 및 살균 물질 등이 직물의 다수개의 섬유사로 만들어진 실 안쪽까지 위치하게 되는 것이다 In this way, in curing, the fabric is preheated before curing and the temperature is raised within a short period of time to expand the weaving yarn, and as curing occurs, deodorizing and sterilizing substances are transferred to the inside of the yarn made of multiple fiber yarns of the fabric. will be located

큐어링하는 온도와 시간은 서로 반비례로 실시한다.The curing temperature and time are inversely proportional to each other.

즉 큐어링온도가 높으면 큐어링시간은 짧게 하고 큐어링 온도가 낮으면 큐어링 시간은 길게 실시한다. That is, if the curing temperature is high, the curing time is short, and if the curing temperature is low, the curing time is long.

상기 코팅하여 큐어링된 직물을 급냉한다 The coated and cured fabric is quenched.

큐어링을 실시한 직물에 흡수된 코팅액의 수분 증발과 수지화 반응이 섬유의 표면, 내부, 직물의 틈 등에서도 일어나며, 건조하면서 직물에 코팅액이 속까지 들어가 있는 성분이 외부로 빠져 않도록 냉각챔버(40)에서 냉풍 또는 냉수로 급냉을 실시한다.Moisture evaporation and resinization reaction of the coating solution absorbed in the cured fabric also occurs on the surface, inside, and gaps of the fabric, and a cooling chamber (40 ) to perform rapid cooling with cold air or cold water.

상기 급냉은 큐어링된 직물을 연속하여 3 ∼ 20℃ 냉풍을 사용하여 실시한다 The quenching is carried out using 3 to 20 ° C cold air continuously for the cured fabric.

각각의 물질에는 각각 온도에 따른 안정상태를 유지하여는 성질이 있어서 오랜시간동안을 두면서 냉각하면 물질의 본래의 상태로 되돌아 오게 되는데 고온에서 큐어링된 직물을 냉풍으로 급격하게 냉각하면 직물이 안정상태를 유지하기 위하여 원래의 상태로 변화하려는과정에서 충분한 시간이 없어 겉면만 원래의 상태로 변화하고 내부는 변화하지 못하여 큐어링된 그대로 있으면서 직물의 원래의 상태로 되돌아 못하고 급격하게 변화하게 된다.Each material has a property of maintaining a stable state according to temperature, so if it is cooled for a long time, the material returns to its original state. In the process of changing to the original state in order to maintain the fabric, there is not enough time, so only the outer surface changes to the original state, and the inside does not change, so it remains cured and changes rapidly without returning to the original state of the fabric.

따라서 고온으로 가열하여 큐어링된 직물을 급냉하면 직물의 겉은 원래의 상태로 변화가 일어나면서 큐어링으로 코팅액이 수분 증발과 수지화반응으로 코팅액이 직물속까지 들어가 있는 코팅액 성분이 외부로 빠져 나오는 것을 방지하게 되므로 살균성분이 직물내부에 그대로 잔존하게 하여 살균효과를 오래동안 지속하기 위한 것이다. Therefore, when the cured fabric is rapidly cooled by heating to a high temperature, the outer surface of the fabric is changed to its original state. This is to keep the sterilizing effect for a long time by allowing the sterilizing component to remain inside the fabric as it is.

급냉하는 온도는 일반적으로 큐어링쳄버의 온도보다 상당히 낮은 냉풍으로 실시한다. The temperature for rapid cooling is generally performed with cold air considerably lower than the temperature of the curing chamber.

바람직한 실시 형태에서, 챔버에서 3∼20℃ 냉풍으로 급냉을 실시하는 것이 바람직하다. In a preferred embodiment, it is preferable to perform rapid cooling in the chamber by 3 to 20° C. cold air.

상기 급냉을 실시하여 냉각된 직물을 공지의 방식으로 텐타 등 후가공을 실시한다 After performing the above-mentioned rapid cooling, the cooled fabric is subjected to post-processing such as tenter in a known manner.

살균기능을 갖는 직물 제조방법은 직물을 준비하는 단계(100)와; 직물를 코팅액으로 탈취 및 살균 물질을 코팅하는 코팅단계(200)와; 코팅액의 일부를 제거하는 직물지 가압 단계(300)와; 코팅액의 일부를 제거한 직물을 가열하는 예비가열단계(400)와; 가열하여 건조하면서 탈취 및 살균 물질이 직물의 내부까지 들어가도록 하는 큐어링하는 단계(500)와; 큐어링으로 직물의 내부까지 들어가 있는 탈취 및 살균 물질이 직물지외부로 빠져나오는 못하게 냉풍으로 냉각하는 급냉단계(600)와; 냉각된 직물을 텐타 등 후가공단계(700);로 구성된다.A method of manufacturing a fabric having a sterilization function includes the steps of preparing a fabric (100); A coating step 200 of coating the fabric with a deodorizing and sterilizing material with a coating solution; A fabric pressing step 300 for removing a portion of the coating solution and; A preheating step 400 of heating the fabric from which a part of the coating solution is removed; Curing (500) to allow the deodorizing and sterilizing material to enter the interior of the fabric while drying by heating; A rapid cooling step 600 of cooling with cold air so that the deodorizing and sterilizing material that has entered the inside of the fabric by curing does not escape to the outside of the fabric; It consists of a post-processing step 700 such as tenter of the cooled fabric.

직물 준비하는 단계(100)Fabric preparation step (100)

직물은 소파용 직물이나 케텐 침구류 벽지 등으로 사용시 기능을 발현할수 있는 것으로 면, 마 등으로 제직한 천연섬유, 재생섬유 및 합성섬유 등의 다양한 재질로 1종만을 사용할 수도 있고, 2종 이상을 사용할 수도 있으며, 바람직하게는 3종을 이용하여 제직할 수 있으면 제직하지 않는 부직포를 사용하여 통상의 방식으로 만들어진 원사라면 제한되지 않고 직물지는 공지의 다양한 제직기를 이용하여 제직될 수 있다.Fabrics can express their functions when used as sofa fabrics, ketene bedding, wallpaper, etc., and various materials such as natural fibers, regenerated fibers and synthetic fibers woven from cotton, hemp, etc. It may also be used, and preferably, if it can be woven using three types, it is not limited as long as it is a yarn made in a conventional manner using a non-woven nonwoven fabric, and the woven paper can be woven using a variety of known weaving machines.

직물를 코팅액으로 탈취 및 살균 물질을 코팅하는 코팅단계(200)Coating step (200) of coating the fabric with a deodorizing and sterilizing material with a coating solution

공지의 직물을 살균제 제올라이트 바인더를 물에 혼합한 수용코팅액을 용기(10)에 충진하여 직물을 수용코팅액에 침적하여 코팅하는 것으로 직물을 코팅하는 코팅액은 물 1000중량부를 기준으로 피피(PP, POLYPROPYLENE) 97중량%, 알루미노실리케이트(ALUMINO SILICATES) 3∼8중량%, 알루미노규산나트륨(ALUMINIUM SODIUM SILICATE) 3중량%, 에틸아크릴(ETHYL ACRYLATE) 2∼5중량%, n부틸아크릴(N-BUTYL ACRYLATE) 2∼5중량%, 칼슘옥사이드(CALCIUM OXIDE) 1중량% 미만, 아크릴산(ACRYLIC ACID) 1중량% 미만, 노닐페놀에톡시레이트 (NONYLPHENOL ETHOXYLATE) 1중량% 미만으로 구성된 살균제 5 내지 10중량부, 바인더 50 내지 150중량부, 제올라이트 30 내지 50중량부를 혼합한 수용성코팅액에 함침하여 직물이 충분히 흡수하여 탈취 및 살균 물질을 침투되게하여 코팅한다. A known fabric is filled with an aqueous coating solution in which a disinfectant zeolite binder is mixed with water in the container 10, and the fabric is immersed in the aqueous coating solution to coat the fabric. The coating solution for coating the fabric is PP, POLYPROPYLENE) 97% by weight, 3 to 8% by weight of aluminosilicate (ALUMINO SILICATES), 3% by weight of sodium aluminosilicate (ALUMINIUM SODIUM SILICATE) 3% by weight, 2 to 5% by weight of ethyl acrylic (ETHYL ACRYLATE), n-butyl acrylic (N-BUTYL ACRYLATE) ) 2 to 5% by weight, less than 1% by weight of calcium oxide (CALCIUM OXIDE), less than 1% by weight of acrylic acid (ACRYLIC ACID), 5 to 10 parts by weight of a disinfectant consisting of less than 1% by weight of nonylphenol ethoxylate (NONYLPHENOL ETHOXYLATE), 50 to 150 parts by weight of the binder and 30 to 50 parts by weight of the zeolite are impregnated in the water-soluble coating solution to allow the fabric to absorb it sufficiently and to penetrate the deodorizing and sterilizing material.

코팅액의 일부를 제거하는 직물지 가압 단계(300)Pressing the fabric paper to remove a part of the coating solution (300)

상기 직물을 용기(10)에서 코팅액으로 탈취 및 살균 물질을 코팅하는 코팅단계(200)에서 코팅액을 흡수한 직물의 겉면에 있는 코팅액이 직물지의 내부까지 침투하도록 하면서 과잉흡수된 코팅액을 제거하여 코팅액이 직물지에 고르게 코팅되도록 탈취 및 살균 물질을 흡수한 직물을 로울러(R) 사이를 통과시켜 직물지를 가압한다. In the coating step 200 of coating the deodorizing and sterilizing material in the container 10 with the coating solution, the coating solution on the outer surface of the fabric, which has absorbed the coating solution, penetrates to the inside of the fabric, and the excess absorption of the coating solution is removed. The fabric absorbing the deodorizing and sterilizing material is passed between the rollers (R) to pressurize the fabric so that it is evenly coated on the fabric.

코팅액의 일부를 제거한 직물을 가열하는 예비가열단계(400)A pre-heating step (400) of heating the fabric from which a part of the coating solution has been removed

상기 코팅액의 일부를 제거하는 직물지 가압 단계(300)을 거친 직물을 수성코팅액을 코팅된 직물을 건조하여 짧은 시간에 큐어링이 되도록하기 위한 것으로 가열쳄버(30)에서 열풍을 이용하여 80∼100℃에서 15 내지 20초 동안 실시한다. This is to cure the fabric that has undergone the pressing step 300 of the fabric paper to remove a part of the coating solution in a short time by drying the fabric coated with the aqueous coating solution. for 15 to 20 seconds.

가열하여 건조하면서 탈취 및 살균 물질이 직물의 내부까지 들어가도록 하는 큐어링하는 단계(500)Curing (500) to allow the deodorizing and sterilizing material to enter the inside of the fabric while drying by heating

상기 코팅액의 일부를 제거한 직물을 가열하는 예비가열단계(400)를 거쳐 가열된 직물을 건조하면서 흡수된 코팅액의 수분 증발과 수지화 반응이 섬유의 표면, 내부, 직물의 틈 등에서도 일어나 코팅액이 속까지 들어가 있게 하여 오랜동안 살균제성분과 제올라이트가 직물지의 내부에 위치하게 되므로 코팅성분이 견고하게 고착 또는 반응시켜 결합하여 살균성분과 제올라이트의 오래동안 효과를 갖을 수 있도록 상기 예비가열된 직물지를 연속하여 본가열챔버(30)에서 열풍을 이용하여 가열온도는 150 ∼170℃에서 25∼40초동안 실시한다.The moisture evaporation and resinization reaction of the absorbed coating solution while drying the heated fabric through the pre-heating step 400 of heating the fabric from which a part of the coating solution is removed occurs also on the surface, inside, and gaps of the fabric, etc. Since the disinfectant component and the zeolite are located inside the textile paper for a long time by allowing the Using hot air in the heating chamber 30, the heating temperature is carried out at 150 to 170° C. for 25 to 40 seconds.

큐어링한 직물을 급냉하는 급냉단계(600)Quenching step (600) of quenching the cured fabric

상기 가열하여 건조하면서 탈취 및 살균 물질이 직물의 내부까지 들어가도록 하는 큐어링하는 단계(500)를 거쳐 큐어링을 실시한 직물에 흡수된 코팅액의 수분 증발과 수지화 반응이 섬유의 표면, 내부, 직물의 틈 등에서도 일어나며, 건조하면서 큐어링으로 직물의 내부까지 들어가있는 탈취 및 살균 물질이 직물지 외부로 빠져나오는 못하도록 큐어링된 직물을 냉각챔버(40)에서 연속하여 3 ∼ 20℃ 냉풍으로 급냉을 실시한다.The moisture evaporation and resinization reaction of the coating solution absorbed in the cured fabric through the curing step 500 to allow the deodorizing and sterilizing material to enter the inside of the fabric while drying by heating is performed on the surface, inside, and fabric of the fiber. In order to prevent the deodorizing and sterilizing substances that have entered the fabric from escaping out of the fabric by curing while drying, the cured fabric is continuously cooled in the cooling chamber 40 with cold air at 3 to 20 ° C. do.

냉각된 직물을 텐타 등 후가공단계(700)Post-processing step (700) such as tenter of the cooled fabric

상기 큐어링한 직물을 급냉하는 급냉단계(600)을 끝난 직물을 공지의 방법으로 후가공을 실시한다. After the quenching step 600 of quenching the cured fabric, post-processing is performed on the fabric in a known manner.

이상에서 설명된 본 발명에 따른 실시예는 예시적인 것에 불과하며, 본 발명이 속하는 기술분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 잘 알 수 있을 것이다. 그러므로 본 발명은 상기의 상세한 설명에서 언급되는 형태로만 한정되는 것은 아님을 잘 이해할 수 있을 것이다.The embodiments according to the present invention described above are merely exemplary, and those of ordinary skill in the art to which the present invention pertains will appreciate that various modifications and equivalent other embodiments are possible therefrom. . Therefore, it will be well understood that the present invention is not limited to the forms recited in the above detailed description.

따라서 본 발명의 진정한 기술적 보호범위는 첨부된 특허청구범위의 기술적 사상에 의해 정해져야 할 것이다. 또한, 본 발명은 첨부된 청구범위에 의해 정의되는 본 발명의 정신과 그 범위내에 있는 모든 변형물과 균등물 및 대체물을 포함하는 것으로 이해되어야 한다.Therefore, the true technical protection scope of the present invention should be determined by the technical spirit of the appended claims. It is also to be understood that the present invention includes all modifications, equivalents and substitutions falling within the spirit and scope of the invention as defined by the appended claims.

10 : 용기 20 : 가열챔버
30 : 본가열챔버 40 : 냉각챔버
100 : 직물을 준비하는 단계
200 : 직물를 코팅액으로 탈취 및 살균 물질을 코팅하는 코팅단계
300 : 코팅액의 일부를 제거하는 직물지 가압 단계
400 : 코팅액의 일부를 제거한 직물을 가열하는 예비가열단계
500 : 가열하여 건조하면서 탈취 및 살균 물질이 직물의 내부까지 들어가도록 하는 큐어링하는 단계
600 : 내부까지 들어가 있는 탈취 및 살균 물질이 직물지외부로 빠져나오는 못하게 냉풍으로 냉각하는 급냉단계
700 : 냉각된 직물을 텐타 등 후가공단계10: vessel 20: heating chamber
30: main heating chamber 40: cooling chamber
100: Steps to prepare the fabric
200: coating step of coating the fabric with a deodorizing and sterilizing material with a coating solution
300: pressurizing the fabric to remove a part of the coating solution
400: a pre-heating step of heating the fabric from which a part of the coating solution has been removed
500: Curing step to allow the deodorizing and sterilizing material to enter the inside of the fabric while drying by heating
600: a rapid cooling step of cooling with cold air so that deodorizing and sterilizing substances that have entered the inside do not escape to the outside of the fabric
700: post-processing step such as tenter of the cooled fabric

Claims (5)

공지의 직물을 물 1000중량부를 기준으로 살균제 5 내지 10중량부, 바인더 50 내지 150중량부. 제올라이트 30 내지 50중량부를 혼합한 코팅액에 함침하여 탈취 및 살균 물질을 흡수한 직물을 가압로울러 사이로 통과시켜 여분의 코팅액 일부가 제거된 직물을 열풍으로 가열에서 80∼100℃에서 15 내지 20초 동안 예비가열하고 상기 예비가열후 연속하여 150 내지 180℃의 본가열챔버에서 25 내지 40초동안 가열하여 건조하면서 탈취 및 살균 물질이 직물을 제직하는 실의 내부까지 들어가는 큐어링을 실시하여 실내부에 위치한 탈취 및 살균 물질이 직물지 외부로 빠져나오는 못하게 큐어링된 직물을 연속하여 3 ∼ 20℃ 냉풍으로 급냉하고 후가공 처리하고,
살균제는 피피 (PP, POLYPROPYLENE) 97중량%, 알루미노실리케이(ALUMINO SILICATES)3∼8중량%, 알루미노규산나트륨(ALUMINIUM SODIUM SILICATE)3중량%, 에틸아크릴(ETHYL ACRYLATE)2∼5중량%, n부틸아크릴(N-BUTYL ACRYLATE)2∼5중량%, 칼슘옥사이드(CALCIUM OXIDE) 1중량% 미만, 아크릴산(ACRYLIC ACID)1중량% 미만, 노닐페놀에톡시레이트 (NONYLPHENOL ETHOXYLATE) 1중량% 미만으로 구성되고,
직물은 코팅액에 광촉매액을 50내지 100중량부를 혼합하여 광촉매가 코팅된 것을 특징으로 하는 살균기능을 갖는 직물.

5 to 10 parts by weight of a disinfectant, 50 to 150 parts by weight of a binder, based on 1000 parts by weight of water for a known fabric. By impregnating the coating solution mixed with 30 to 50 parts by weight of zeolite and passing the fabric absorbing the deodorizing and sterilizing material between the pressure rollers, the fabric from which some of the excess coating solution has been removed is heated with hot air at 80 to 100° C. for 15 to 20 seconds. After heating and the pre-heating, it is continuously heated in the main heating chamber at 150 to 180° C. for 25 to 40 seconds and dried while deodorizing and sterilizing substances are cured to enter the inside of the yarn weaving the fabric, so that the deodorization located in the interior part and continuously quenching the cured fabric with cold air at 3 to 20° C. and post-processing to prevent the sterilizing material from escaping to the outside of the fabric,
The disinfectant is PP (PP, POLYPROPYLENE) 97% by weight, ALUMINO SILICATES 3 to 8% by weight, ALUMINIUM SODIUM SILICATE 3% by weight, ethyl acrylic (ETHYL ACRYLATE) 2 to 5% by weight , n-butyl acrylic (N-BUTYL ACRYLATE) 2 to 5% by weight, calcium oxide (CALCIUM OXIDE) less than 1% by weight, acrylic acid (ACRYLIC ACID) less than 1% by weight, nonylphenol ethoxylate (NONYLPHENOL ETHOXYLATE) less than 1% by weight is composed of
The fabric is a fabric having a sterilization function, characterized in that the photocatalyst is coated by mixing 50 to 100 parts by weight of a photocatalyst solution in a coating solution.

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4959268A (en) * 1986-07-16 1990-09-25 Zenji Hagiwara Polymer containing amorphous aluminosilicate particles and process for producing the same
WO2002004569A1 (en) * 2000-07-10 2002-01-17 Mutsuo Himeno Coating composition
KR20020018333A (en) * 2000-09-01 2002-03-08 이윤화 Producing method of surface coating fluid for textile and its coating method
KR100961663B1 (en) * 2009-02-02 2010-06-09 주식회사 태평양산업 Fabric coating composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4959268A (en) * 1986-07-16 1990-09-25 Zenji Hagiwara Polymer containing amorphous aluminosilicate particles and process for producing the same
WO2002004569A1 (en) * 2000-07-10 2002-01-17 Mutsuo Himeno Coating composition
KR20020018333A (en) * 2000-09-01 2002-03-08 이윤화 Producing method of surface coating fluid for textile and its coating method
KR100961663B1 (en) * 2009-02-02 2010-06-09 주식회사 태평양산업 Fabric coating composition

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