KR102344366B1 - Section repair material pumping to long-distance and increaing thickness of spray coating and method for emergency repair using threrof - Google Patents

Section repair material pumping to long-distance and increaing thickness of spray coating and method for emergency repair using threrof Download PDF

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KR102344366B1
KR102344366B1 KR1020200142439A KR20200142439A KR102344366B1 KR 102344366 B1 KR102344366 B1 KR 102344366B1 KR 1020200142439 A KR1020200142439 A KR 1020200142439A KR 20200142439 A KR20200142439 A KR 20200142439A KR 102344366 B1 KR102344366 B1 KR 102344366B1
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mortar
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liquid
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김재환
채영강
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(주)에이엠에스 엔지니어링
(주)신미건설
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • C04B22/062Oxides, Hydroxides of the alkali or alkaline-earth metals
    • C04B22/064Oxides, Hydroxides of the alkali or alkaline-earth metals of the alkaline-earth metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/06Oxides, Hydroxides
    • C04B22/066Magnesia; Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/14Acids or salts thereof containing sulfur in the anion, e.g. sulfides
    • C04B22/142Sulfates
    • C04B22/143Calcium-sulfate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/16Acids or salts thereof containing phosphorus in the anion, e.g. phosphates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2611Polyalkenes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B24/2641Polyacrylates; Polymethacrylates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4505Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
    • C04B41/4535Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied as a solution, emulsion, dispersion or suspension
    • C04B41/4543Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied as a solution, emulsion, dispersion or suspension by spraying, e.g. by atomising
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04GSCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
    • E04G23/00Working measures on existing buildings
    • E04G23/02Repairing, e.g. filling cracks; Restoring; Altering; Enlarging
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30Water reducers, plasticisers, air-entrainers, flow improvers
    • C04B2103/34Flow improvers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/44Thickening, gelling or viscosity increasing agents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Architecture (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to a section repairing material and a repairing method capable of enabling long-distance pumping and spray thickness increase, enabling early practical strength expression, and thus enabling emergency repair of a concrete structure. A section repairing material according to the present invention includes a binder composition including 9.8 to 18.8 wt% of a performance improving agent composed of a fluorinated polyolefin resin, an acrylic resin, magnesium oxide, an expanding agent, a fast curing agent, anhydrite, and slaked lime, and 81.2 to 90.2 wt% of ordinary Portland cement, and filler; and includes 0.1 to 3.0 wt% of an acceleration enhancing agent composed of potassium phosphate and distilled water, and a liquid curing promoting agent including 97.0 to 99.9 wt% of a liquid alkali-free accelerating agent.

Description

장거리 압송 및 뿜칠두께 증대가 가능한 단면보수재 및 이를 활용한 응급보수공법{SECTION REPAIR MATERIAL PUMPING TO LONG-DISTANCE AND INCREAING THICKNESS OF SPRAY COATING AND METHOD FOR EMERGENCY REPAIR USING THREROF}SECTION REPAIR MATERIAL PUMPING TO LONG-DISTANCE AND INCREAING THICKNESS OF SPRAY COATING AND METHOD FOR EMERGENCY REPAIR USING THREROF

본 발명은 장거리 압송을 통해 콘크리트 구조물의 응급 보수가 가능한 단면보수재 및 이를 활용한 응급보수공법에 관한 것으로, 더욱 구체적으로는, 수평 100m 또는 수직 40m 이상의 장거리 압송이 가능하여 고소작업이 가능하고 뿜칠두께 증대가 가능하여 시공 이음부를 최소화 할 수 있고 조기 실용강도 발현이 가능하여 콘크리트 구조물의 응급보수가 가능한 단면보수재 및 이를 활용한 보수공법에 관한 것이다. The present invention relates to a cross-section repair material capable of emergency repair of a concrete structure through long-distance pressurization and an emergency repair method using the same. It relates to a section repair material that can be increased to minimize construction joints, and to enable early expression of practical strength, enabling emergency repair of concrete structures and a repair method using the same.

콘크리트 구조물은 우수한 내구성으로 인해 반영구적 구조물의 건설 재료로 널리 사용되고 있다. 그러나 콘크리트 구조물에는 콘크리트의 건조수축, 부동침하, 블리딩 또는 응력의 과다 등 여러 가지 다양한 원인에 의해서 크고 작은 균열이 발생한다. 또한 콘크리트 구조물이 해양 환경에 오랜 기간 노출될 경우 해수의 작용에 의하여 콘크리트가 침식되고 철근이 부식을 일으키며 체적 팽창에 의해 콘크리트가 균열 및 박리를 일으킴으로써, 결과적으로 콘크리트 구조물의 성능이 저하되게 된다. 겨울철에는 콘크리트가 동결 및 융해 작용으로 인해 콘크리트의 파손이 발생하기도 하고, 자동차의 배기가스에 오랜 기간 노출될 경우 중성화 현상으로 인해 내부 철근이 부식되고 콘크리트가 균열 또는 탈락되는 경우가 발생하기도 한다. 이러한 구조물의 열화가 계속 진행되면 결국 구조물의 붕괴를 초래할 위험성이 있기 때문에 지속적으로 관리하고 보수할 필요가 있다. Concrete structures are widely used as construction materials for semi-permanent structures due to their excellent durability. However, large and small cracks occur in concrete structures due to various causes such as drying shrinkage of concrete, floating settlement, bleeding, or excessive stress. In addition, when a concrete structure is exposed to the marine environment for a long period of time, the concrete erodes by the action of seawater, the reinforcing bars corrode, and the concrete cracks and peels due to volume expansion, resulting in deterioration of the performance of the concrete structure. In winter, concrete breaks down due to freezing and thawing, and when exposed to automobile exhaust gas for a long period of time, the internal rebar corrodes and the concrete cracks or falls off due to the neutralization phenomenon. If the deterioration of these structures continues, there is a risk of eventually leading to the collapse of the structures, so it is necessary to continuously manage and repair them.

또한 구조물 표면의 박리 또는 초기 결함이나 균열의 발생은 열화 요인의 이동을 용이하게 하여 열화의 진행을 촉진시키므로 철근 콘크리트 구조물의 안정성 및 성능 확보를 위해서는 열화 초기에 보수를 실시하여 더 이상의 열화의 진행을 억제하고 내구성능을 향상시킬 필요가 있다. 따라서 콘크리트의 열화, 강재의 부식, 기타의 원인에 의해 구조물 단면의 박리나 탈락 등의 열화 인자를 포함하는 콘크리트 부분을 제거한 후 단면을 원래의 성능 및 형태로 복원하기 위해 보수 보강 재료를 충진하거나 뿜칠 시공을 하여 보수를 실시하는 것이 일반적이다.In addition, peeling of the structure surface or occurrence of initial defects or cracks facilitates the movement of deterioration factors and accelerates deterioration. It is necessary to suppress and improve durability performance. Therefore, after removing the concrete part that contains deterioration factors such as delamination or drop-off of the cross section of the structure due to deterioration of concrete, corrosion of steel, or other causes, fill or spray with repair reinforcement material to restore the cross section to its original performance and shape. It is common to carry out repairs after construction.

그리고 국내 사회간접시설이 증가하면서, 고속도로, 철도시설에 교량이 많이 건설되었으며, 교량이 차지하는 비중이 다른 시설물보다 월등히 높다. 그러나 보수공사 중에 차량이나 철도가 통과하면, 교량부재에 진동이 가해지고, 보수단면이 균열 및 탈락으로 이어질 수 있다. 따라서 교량 보수 후에 진동으로 보수몰탈의 하자가 많이 발생하고 있으므로, 이러한 문제를 해결하기 위해서는 타설 후에 진동에 강하고, 짧은 시간이 지난 후에도 균열 및 탈락 등이 발생하지 않는 보수몰탈의 개발이 필요하다. And as the number of domestic social overhead facilities increased, many bridges were built on highways and railroad facilities, and the proportion of bridges was significantly higher than that of other facilities. However, if a vehicle or railroad passes during repair work, vibration is applied to the bridge member, which may lead to cracks and drop-offs in the repair section. Therefore, since many defects of repair mortar occur due to vibration after bridge repair, in order to solve this problem, it is necessary to develop a repair mortar that is strong in vibration after pouring and does not crack or fall off even after a short period of time.

종래 단면보수공사는 철근콘크리트의 열화현상으로 인해 박리, 박락, 부식, 팽창되는 철근콘크리트의 단면보수시 일반 폴리머 몰탈로 시공하였다. 따라서 열화된 콘크리트 구조물의 열화손상부와 단면보수보강부재의 1회 최소 시공두께가 30mm 이하로 매우 얇고, 단면보수재의 경제적 비용이 높아서 실시설계 반영시 공사비용의 고가로 인한 발주처 및 시공사의 부담이 가중되어 광범위한 콘크리트의 전면 단면보수가 불가능하였다는 문제점이 있었다. 즉 기존기술은 적용단가가 높아서 콘크리트의 단면보수보강공사와 신축공사비용의 차이가 크지 않기 때문에 실제 콘크리트구조물 단면보수보강공사 적용시 많은 애로사항이 있었으며, 특히 대규모의 콘크리트구조물 단면보수공사에 대한 적용이 현실적으로 불가능하였다. In the conventional cross-sectional repair work, general polymer mortar was used to repair the cross-section of reinforced concrete that was exfoliated, exfoliated, corroded, or expanded due to the deterioration of reinforced concrete. Therefore, the minimum construction thickness of the deteriorated part of the deteriorated concrete structure and the sectional repair and reinforcement member at one time is 30 mm or less, and the economic cost of the sectional repair material is high. There was a problem that it was impossible to repair the front section of a wide range of concrete due to the heavy load. In other words, there were many difficulties when applying the actual concrete structure cross-section repair and reinforcement work because the cost difference between the cross-section repair and reinforcement work of concrete and the new construction cost is not large due to the high cost of application of the existing technology. This was practically impossible.

좀 더 구체적으로 살펴보면, 기존 공법의 제품들은 장비에 의해 장거리 운송이 가능할지라도 마찰열에 의해 물성이 변질되고 품질에 영향을 미쳐 하자발생으로 연결된다. 그리고 기존의 일반 콘크리트 단면보수재는 초경량으로 기존 콘크리트 구조물의 단면 보수시 1회 시공두께가 30mm 이하로 얇아서 초벌시공과 재벌시공시 경화시간을 요한다. 따라서 100mm의 두께 타설시를 예로 들면 최소 3회 이상의 작업공정을 요하므로 시공비용에 있어 과도한 비용을 필요로 한다. 또한 기존의 단면 보수재는 제품 내에 전체중량의 50% 이상의 잔골재(모래)와 50%에 가까운 시멘트류가 혼합 구성되어 있어 물을 혼합한 습식혼합물 및 경화체의 비중이 약 2.2kg/㎤로 콘크리트의 중량과 비슷할 만큼 높아 단면보수시 제품 자체중량으로 인하여 30mm 이하인 1회 시공두께를 증대시킬 수 없는 한계가 있다. 아울러, 보수공사 중에 차량이 통과하면, 교량부재에 진동이 가해지고, 보수단면이 균열 및 탈락으로 이어질 수 있다. 따라서 교량 보수 후에 진동으로 보수몰탈의 하자가 많이 발생하고 있는 문제점이 있었다.Looking more specifically, even if the products of the existing method can be transported over long distances by equipment, their physical properties are altered by frictional heat and their quality is affected, leading to defects. In addition, the existing general concrete cross-section repair materials are ultra-lightweight, and when repairing the cross-section of an existing concrete structure, the thickness of one application is 30 mm or less, so hardening time is required for initial construction and chaebol construction. Therefore, when pouring 100mm thick, for example, it requires at least three or more work processes, which requires excessive cost in construction cost. In addition, the existing single-sided repair materials are composed of 50% or more of the total weight of fine aggregate (sand) and close to 50% of cement in the product. Due to the product's own weight during section repair, there is a limit that the thickness of one-time installation, which is less than 30mm, cannot be increased. In addition, if a vehicle passes during the repair work, vibration is applied to the bridge member, and the repair section may lead to cracks and dropouts. Therefore, there was a problem that many defects of repair mortar occurred due to vibration after bridge repair.

한편, 콘크리트 급결제는 다양한 건축 기술에 있어서 중요도가 증가하고 있다. 종래에는 알루미네이트 급결제(aluminate accelerator)가 주로 사용되어 왔다. 그러나 알루미네이트 급결제는 강알칼리 특성을 가지고 있어, 장기강도가 상당히 떨어지며 이의 취급시 작업자의 피부화상, 눈과 각막의 식각을 유발하는 등의 인체 유해성에 관한 문제를 야기한다. 상기 알루미네이트 급결제의 문제점을 보완하기 위하여 알칼리프리 급결제(alkali-free accelerator)가 개발되었다. 알칼리프리 급결제는 알칼리 함량이 1%이하이고 ph가 약산성이기 때문에 인체에 자극이 적어 작업 환경을 개선하고 환경오염의 위험성을 줄일 수 있다. 또한, 알칼리프리 급결제는 종래 알루미네이트 급결제와는 달리 수화 초기부터 강알칼리 성분을 배출하여 칼슘 실리케이트상(C3S, C2S)의 용출을 강제로 증진시키지 않는다. 그 결과, 알칼리프리 급결제는 장기재령이 충분한 칼슘 실리케이트 하이드레이트(calcium silicate hydrate; CSH)겔의 생성을 유도하여 장기강도의 저하가 적고, 미세한 에트링자이트(ettringite, C3A·3CaSO4·32H2O)를 다량 생성함으로써 골재-몰탈(페이스트) 계면의 특성이 우수하여 내구성이 상기 알루미네이트 급결제보다 좋다는 장점을 가진다. 그러나 일반적으로 시판되는 알칼리프리 급결제는 조기강도 발현에 다소 문제가 있다. 따라서 알칼리프리 급결제는 터널 공사, 지하 공사 또는 보수 공사 등 콘크리트의 조기강도 발현이 중요한 건축 기술 분야에 사용되기 어렵다는 단점을 가진다. 이에 상기의 문제점을 보완한 조기강도 발현이 우수한 급결제의 개발이 요구되고 있다.On the other hand, the importance of concrete quick-setting is increasing in various construction technologies. Conventionally, an aluminate accelerator has been mainly used. However, aluminate quick-setting admixture has a strong alkali property, so its long-term strength is considerably lowered, and when handling it, it causes problems related to harmfulness to the human body, such as skin burns and etching of eyes and corneas. An alkali-free accelerator has been developed in order to compensate for the problems of the aluminate quick-setter. Alkali-free quick-setting admixtures have less than 1% alkali content and slightly acidic pH, so there is little irritation to the human body, improving the working environment and reducing the risk of environmental pollution. In addition, the alkali-free quick-setting admixture does not forcibly promote the dissolution of calcium silicate phases (C3S, C2S) by discharging strong alkali components from the initial stage of hydration, unlike the conventional aluminate quick-setting admixture. As a result, alkali-free quick-setting adjuvant induces the formation of calcium silicate hydrate (CSH) gel with sufficient long-term age, so there is little decrease in long-term strength, and fine ettringite (C3A·3CaSO 4 ·32H 2 ) O) by generating a large amount of aggregate-mortar (paste) interface characteristics are excellent, and has the advantage of better durability than the aluminate quick-setting admixture. However, commercially available alkali-free quick-setting agents have some problems in developing early strength. Therefore, alkali-free quick-setting has a disadvantage in that it is difficult to use in the field of construction technology where the early strength expression of concrete is important, such as tunnel construction, underground construction, or repair construction. Accordingly, there is a demand for the development of a quick-setting admixture excellent in early strength expression that compensates for the above problems.

대한민국 등록특허 제10-0582840호(2006.05.17.)Republic of Korea Patent Registration No. 10-0582840 (2006.05.17.)

본 발명은 상기와 같은 문제점을 감안하여 안출된 것으로, 본 발명의 목적은 수평 100m 또는 수직 40m 이상의 장거리 압송이 가능하여 고소작업이 가능하고 뿜칠두께 증대가 가능하여 시공 이음부를 최소화 할 수 있고 조기 실용강도 발현이 가능하여 콘크리트 구조물의 응급보수가 가능한 단면보수재 및 보수공법을 제공하는 데 있다. The present invention was devised in consideration of the above problems, and the object of the present invention is to enable long-distance pressure feeding of 100 m horizontally or 40 m or more vertically, so that it is possible to work at a height and increase the spraying thickness, so that the construction joint can be minimized and early practical use. The purpose of this is to provide a section repair material and repair method that enables emergency repair of concrete structures due to the ability to express strength.

상기한 바와 같은 목적을 달성하기 위한 특징에 따르면, 본 발명은 장거리 압송을 통해 콘크리트 구조물의 응급보수가 가능한 단면보수재 및 이를 활용한 보수공법에 관한 것으로서, 불소화폴리올레핀수지, 아크릴계 수지, 산화마그네슘, 팽창제, 속경재, 무수석고 및 소석회로 구성되는 성능개선제 9.8∼18.8중량%와 보통포틀랜드시멘트 81.2∼90.2중량%로 바인더 조성물 34.7 ~ 47.2중량%와 필러 52.8~65.3중량%를 혼합하여 제조된 몰탈 조성물을 포함한다.According to the characteristics for achieving the above object, the present invention relates to a cross-section repair material capable of emergency repair of a concrete structure through long-distance pressure feeding and a repair method using the same, and relates to a fluorinated polyolefin resin, an acrylic resin, magnesium oxide, and an expanding agent. A mortar composition prepared by mixing 34.7 to 47.2 wt% of a binder composition and 52.8 to 65.3 wt% of a filler at 9.8 to 18.8 wt% of a performance improving agent composed of , fast hardwood, anhydrite and slaked lime and 81.2 to 90.2 wt% of ordinary Portland cement include

상기 성능개선제는 불소화폴리올레핀수지 0.2∼5.5중량%, 아크릴계수지 15.7∼20.3중량%, 산화마그네슘 5.0∼12.0중량%, 팽창제 10.8∼20.4중량%, 속경재 17.5∼22.2중량%, 무수석고 18.8∼25.3중량%, 소석회 9.5∼14.8중량%를 혼합하여 이루어진다.The performance improving agent is 0.2 to 5.5% by weight of fluorinated polyolefin resin, 15.7 to 20.3% by weight of acrylic resin, 5.0 to 12.0% by weight of magnesium oxide, 10.8 to 20.4% by weight of expanding agent, 17.5 to 22.2% by weight of fast hardwood, 18.8 to 25.3% by weight of anhydrite %, 9.5 to 14.8% by weight of slaked lime is mixed.

이때 상기 성능개선제는, 유동화제 1.0∼2.5중량%, 증점제 0.05∼0.15중량%, 수축저감제 0.5∼1.8중량%, 섬유보강재 0.5∼2.2중량%, 공기연행제 0.01∼0.13중량%, 지연제 0.1∼5.0중량%를 더 포함할 수 있다.At this time, the performance improving agent is, 1.0 to 2.5% by weight of a fluidizing agent, 0.05 to 0.15% by weight of a thickener, 0.5 to 1.8% by weight of a shrinkage reducing agent, 0.5 to 2.2% by weight of a fiber reinforcement, 0.01 to 0.13% by weight of an air entraining agent, 0.1% by weight of a retarder -5.0 wt% may be further included.

또한 초기 급결력을 향상시키고 뿜칠 후 6시간 이내에 5.0 ㎫ 이상의 실용강도를 발현할 수 있도록 액상경화촉진제를 상기 몰탈 조성물 100 중량부에 대하여 2.4∼7.2 중량부 범위 내에서 첨가하고, 상기 액상경화촉진제는 인산칼륨 1.5∼12.5중량%와 증류수 87.5∼98.5중량%로 구성되는 급결향상제 0.1∼3.0중량% 및 액상알칼리프리급결제 97.0∼99.9중량%로 이루어질 수 있다.In addition, a liquid curing accelerator is added within the range of 2.4 to 7.2 parts by weight based on 100 parts by weight of the mortar composition to improve the initial fastening power and to express a practical strength of 5.0 MPa or more within 6 hours after spraying, and the liquid curing accelerator is It may be composed of 0.1 to 3.0% by weight of a quick-setting enhancer composed of 1.5 to 12.5% by weight of potassium phosphate and 87.5 to 98.5% by weight of distilled water and 97.0 to 99.9% by weight of a liquid alkali-free quick-setting agent.

상술한 목적을 달성하기 위한 본 발명의 보수공법은, 불소화폴리올레핀수지, 아크릴계 수지, 산화마그네슘, 팽창제, 속경재, 무수석고 및 소석회로 구성되는 성능개선제 9.8∼18.8중량%와 보통포틀랜드시멘트 81.2∼90.2중량%로 이루어지는 바인더 조성물 34.7∼47.2중량%와 필러 52.8∼65.3중량%를 혼합하고, 바인더 조성물 및 필러를 혼합하여 제조된 몰탈 조성물 100중량부에 대하여 12∼16중량부의 배합수를 혼합하는 단계; 상기 몰탈-배합수 혼합물을 몰탈펌프를 이용하여 몰탈호스를 통해 교량 또는 기둥 구조물의 긴급 보수 지점의 분사노즐건으로 운송하는 단계; 인산칼륨 1.5∼12.5중량%와 증류수 87.5∼98.5중량%로 구성되는 급결향상제 0.1∼3.0중량% 및 액상알칼리프리급결제 97.0∼99.9중량%로 이루어지는 액상경화촉진제를 압송펌프를 이용하여 액상호스를 통해 상기 분사노즐건으로 압송하는 단계; 공기압축기에서 생성된 압축공기를 에어호스를 통해 상기 분사노즐건으로 압송하는 단계; 및 상기 분사노즐건에서 상기 몰탈-배합수 혼합물과 액상경화촉진제와 압축공기를 혼합하여 교량 또는 기둥 구조물로 뿜칠하는 단계;를 포함한다.The repair method of the present invention for achieving the above object is 9.8 to 18.8 wt% of a performance improving agent composed of fluorinated polyolefin resin, acrylic resin, magnesium oxide, expanding agent, fast hardwood, anhydrite and slaked lime, and 81.2 to 90.2% by weight of ordinary Portland cement. Mixing 34.7 to 47.2% by weight of the binder composition and 52.8 to 65.3% by weight of the filler, and mixing 12 to 16 parts by weight of a compounding water with respect to 100 parts by weight of the mortar composition prepared by mixing the binder composition and the filler; transporting the mortar-mixed water mixture to a spray nozzle gun at an emergency repair point of a bridge or column structure through a mortar hose using a mortar pump; A liquid curing accelerator consisting of 0.1 to 3.0% by weight of a quick-setting enhancer composed of 1.5 to 12.5% by weight of potassium phosphate and 87.5 to 98.5% by weight of distilled water and 97.0 to 99.9% by weight of a liquid alkali-free quick-setting agent is passed through a liquid hose using a pressure pump. pressure-feeding with the injection nozzle gun; compressing the compressed air generated by the air compressor to the injection nozzle gun through an air hose; and mixing the mortar-mixed water mixture, liquid hardening accelerator, and compressed air in the spray nozzle gun and spraying the mixture onto a bridge or column structure.

이때, 상기 액상경화촉진제는 상기 바인더 조성물과 필러를 혼합한 몰탈 조성물 100 중량부에 대하여 2.4∼7.2 중량부 범위 내에서 혼합되되, 상기 분사노즐건에 장착된 밸브에 의해 상기 중량 범위로 조절되는 것이 바람직하다.At this time, the liquid curing accelerator is mixed within the range of 2.4 to 7.2 parts by weight with respect to 100 parts by weight of the mortar composition in which the binder composition and the filler are mixed, and the weight range is controlled by the valve mounted on the spray nozzle gun. desirable.

본 발명에 따른 장거리 압송을 통해 콘크리트 구조물의 응급보수가 가능한 단면보수재 및 보수공법에 따르면, 콘크리트 구조물의 열화 부분을 보수함에 있어 단면보수재와 호스의 마찰열을 최소화하여 유동성이 확보되어 수평 100m 또는 수직 40m 이상의 장거리 압송이 가능하고 고소작업이 용이할 뿐만 아니라 안정적 품질을 확보할 수 있는 장점이 있다. According to the sectional repair material and repair method that enables emergency repair of a concrete structure through long-distance pressure feeding according to the present invention, fluidity is secured by minimizing the frictional heat between the sectional repair material and the hose in repairing the deteriorated part of the concrete structure, so that 100m horizontally or 40m vertically Long-distance pressurization is possible, and work at height is easy, and it has the advantage of securing stable quality.

그리고 본 발명에 의하면, 뿜칠 후 초기 급결력을 향상시켜 1회 시공두께를 150mm 이상 처짐 없이 뿜칠하여 시공 이음부를 최소화 할 수 있는 효과가 있다.And, according to the present invention, there is an effect that can minimize the construction joint by spraying without sagging more than 150mm in thickness at one time by improving the initial fastening force after spraying.

또한 본 발명에 의하면, 뿜칠 후 빠른 경화반응으로 단시간에 조기강도가 발현되어 6시간 이내에 실용강도(압축강도 5.0㎫ 이상)를 만족하여 응급보수가 가능한 이점이 있다.In addition, according to the present invention, there is an advantage that an emergency repair is possible by satisfying the practical strength (compressive strength of 5.0 MPa or more) within 6 hours because early strength is expressed in a short time due to a rapid curing reaction after spraying.

본 발명의 특징과 장점은 첨부된 도면에 의하여 설명되는 실시예에 의하여 보다 명확하게 이해될 수 있을 것이다.The features and advantages of the present invention will be more clearly understood by the embodiments described by the accompanying drawings.

본 발명의 실시 예에 기재되거나 도면에 도시된 구성요소들의 구성 및 배열에 의해 본 발명의 응용이 제한되는 것은 아니다. 본 발명은 다른 실시 예들로 구현될 수 있고, 다양한 방법으로 수행될 수 있다. 또한 장치 또는 요소의 방향 등과 같은 용어들에 관하여 실시 예에 사용된 표현 및 술어는 단지 본 발명의 설명을 단순화하기 위해 사용되며, 관련된 장치 또는 요소가 단순히 특정 방향을 가져야 함을 나타내거나 의미하지 않는다. 예를 들면, "제1", "제2"와 같은 용어가 본 발명을 설명하는 실시 예와 청구항에 사용되는데, 이러한 용어가 상대적인 중요성 또는 취지를 나타내거나 의미하는 것으로 의도되지 않는다.The application of the present invention is not limited by the configuration and arrangement of components described in the embodiments of the present invention or shown in the drawings. The present invention may be embodied in other embodiments and may be practiced in various ways. Also, the expressions and predicates used in the embodiments with respect to terms such as the orientation of devices or elements are used only to simplify the description of the present invention, and do not indicate or imply that the related devices or elements simply have to have a specific orientation. . For example, although terms such as "first" and "second" are used in the embodiments and claims describing the present invention, such terms are not intended to indicate or imply relative importance or spirit.

또한, 본 명세서 및 청구범위에 사용된 용어나 단어는 통상적이거나 사전적인 의미로 한정하여 해석되어서는 아니되며, 발명자가 발명의 용어와 개념을 가장 최선의 방법으로 설명하기 위하여 본 발명의 기술적 사상에 부합하는 의미와 개념에 입각하여 기재한 것으로 해석하여야 한다.In addition, the terms or words used in the present specification and claims are not to be construed as being limited to conventional or dictionary meanings, and the inventors are in the technical spirit of the present invention in order to explain the terms and concepts of the invention in the best way. It should be interpreted as written based on the corresponding meaning and concept.

따라서 본 발명은 제시되는 실시 예에 한정되지 않으며, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의하여 본 발명의 기술 사상과 아래에 기재될 특허청구 범위에 기재된 기술상의 균등한 범위 내에서 다양한 수정 및 변경이 가능하다.Therefore, the present invention is not limited to the presented embodiment, and within the technical spirit of the present invention and the technical equivalents described in the claims to be described below by those of ordinary skill in the art to which the present invention pertains. Various modifications and changes are possible.

다음에서 본 발명의 바람직한 실시예를 상세하게 설명한다.In the following, preferred embodiments of the present invention will be described in detail.

<단면보수재><Sectional repair material>

본 발명은 보통포틀랜드시멘트와 성능개선제를 포함하는 단면보수재로서, 액상알칼리프리급결제와 급결향상제로 구성되는 액상경화촉진제를 더 포함할 수 있다. The present invention is a cross-section repair material comprising ordinary Portland cement and a performance improving agent, and may further include a liquid hardening accelerator comprising a liquid alkali-free quick-setting agent and a quick-setting agent.

본 발명에 따른 단면보수재는 [표 1]과 같은 요구 성능을 만족시키기 위하여 바인더 조성물 및 필러를 혼합하여 제조된 몰탈 100중량부에 대하여 배합수는 12~16 중량부, 액상경화촉진제는 2.4∼7.2 중량부를 사용한다. 압송 전 유동성(flow)은 210±10mm, 온도는 20±5℃가 적당하다.The cross-section repair material according to the present invention contains 12 to 16 parts by weight of the compounding water and 2.4 to 7.2 parts by weight of the liquid curing accelerator based on 100 parts by weight of the mortar prepared by mixing the binder composition and the filler in order to satisfy the required performance as shown in [Table 1]. Use parts by weight. 210±10mm for flow and 20±5℃ for temperature before pumping.

구분division 요구성능required performance 장거리 압송 가능 여부Long-distance compression possible 수평 100m 또는 수직 40m 이상More than 100m horizontally or 40m vertically 운송 후 유동성(flow)Post-transport flow 운송 전 대비 ±10mm 이내Within ±10mm compared to before transport 운송 후 발열온도Fever temperature after transportation 운송 전 대비 ±5℃ 이내Within ±5℃ compared to before transportation 1회 시공두께(합판거푸집)One-time construction thickness (plywood formwork) 150mm 이상150mm or more 처짐 여부Whether to sag XX 압추강도(㎫)Compression strength (㎫) 6시간6 hours 5.0㎫ 이상5.0 MPa or more

보다 상세히 설명하면, 상기 바인더 조성물는 성능개선제 9.8∼18.8중량%와 보통포틀랜드시멘트 81.2∼90.2중량%로 이루어진다.More specifically, the binder composition consists of 9.8 to 18.8% by weight of the performance improving agent and 81.2 to 90.2% by weight of ordinary Portland cement.

기존 콘크리트 구조물 단면 보수에 사용되는 보통포틀랜드시멘트를 포함한 폴리머시멘트몰탈은 배합수와 혼합시 유동성이 160mm 미만으로 매우 작다. 배합수를 늘리게 되면 유동성은 증가하지만, 재료분리가 발생하여 몰탈을 운송하는데 있어 페이스트만 먼저 이송되기 때문에 품질에 문제가 발생하게 된다. 한편 배합수를 고정하고 고유동화제로 유동성을 증가시킬 수 있지만, 장거리 운송 과정에서 몰탈과 고압호스의 마찰이 발생하여 열이 발생하기 때문에 수화반응이 앞당겨져 유동성이 감소한다. 따라서 유동성이 동일하게 감소하여 품질에도 영향을 미칠 뿐만 아니라 몰탈 압송펌프 등 장비도 과부하가 걸리게 된다. 상기 문제들로 인하여 교각 및 기둥 구조물의 장거리 운송 및 긴급보수를 진행하는데 많은 어려움이 따른다. Polymer cement mortar including ordinary Portland cement used for cross-section repair of existing concrete structures has very small fluidity of less than 160mm when mixed with mixing water. If the mixing number is increased, the fluidity is increased, but material separation occurs and only the paste is transferred first in transporting the mortar, which causes a quality problem. On the other hand, the mixing water can be fixed and the fluidity can be increased with a high fluidity agent, but the friction between the mortar and the high-pressure hose occurs during long-distance transportation and heat is generated, so the hydration reaction is accelerated and the fluidity is reduced. Therefore, the fluidity is reduced in the same way, which not only affects the quality, but also overloads the equipment such as the mortar pump. Due to the above problems, there are many difficulties in carrying out long-distance transportation and emergency repair of piers and column structures.

따라서 본 발명에서는 이러한 종래기술의 문제점을 해소하기 위하여 보통포틀랜드시멘트에 성능개선제를 첨가하는 것으로서, 이러한 성능개선제는 불소화폴리올레핀수지 0.2∼5.5중량%, 아크릴계수지 15.7∼20.3중량%, 산화마그네슘 5.0∼12.0중량%, 팽창제 10.8∼20.4중량%, 속경재 17.5∼22.2중량%, 무수석고 18.8∼25.3중량%, 소석회 9.5∼14.8중량%를 혼합하여 이루어진다.Therefore, in the present invention, in order to solve the problems of the prior art, a performance improving agent is added to ordinary Portland cement, and the performance improving agent is 0.2 to 5.5 wt% of a fluorinated polyolefin resin, 15.7 to 20.3 wt% of an acrylic resin, and 5.0 to 12.0 wt% of magnesium oxide. % by weight, 10.8 to 20.4% by weight of an expanding agent, 17.5 to 22.2% by weight of fast hardwood, 18.8 to 25.3% by weight of anhydrite, and 9.5 to 14.8% by weight of slaked lime.

본 발명에서 사용하는 불소화폴리올레핀수지(PTFE; Polytetrafluoroethylene)는 일반적으로 상용되고 있는 불소화폴리올레핀수지(폴리테트라플루오르에틸렌, 폴리비닐리덴플루오라이드, 테트라플루오로에틸렌 또는 비닐리덴플루오로라이드의 공중합체 및 테트라플루오로에틸렌과 헥사플루오로프로필렌의 공중합체)를 의미한다. 통상적으로 불소화폴리올레핀수지는 표면 에너지가 극히 적은 특성을 가지고 있어서 윤활용, 저마찰용, 또는 내마모용 등으로 사용되기도 한다. 불소화폴리올레핀수지는 대표적인 불소수지로 폴리에틸렌의 분자구조에서 수소원자를 불소원자로 치환시킨 고분자물질로서 내마모성, 내수성, 내유성, 내화학성, 내약품성, 저마찰계수, 비점착성, 전기절연성, 불연성, 내후성 등을 보유하고 무독성 물질로 알려져 있다. 특히 -250∼300℃ 정도의 광범위한 사용온도에서 안정성을 유지하여 특성이 변화하지 않으며 압출, 사출, 도료, 접착, 잉크, 코팅, 페인트, 파이프, 배관, 전자재료 및 다양한 산업에서 핵심 원료 및 첨가제로 사용되고 있다.Fluorinated polyolefin resin (PTFE; Polytetrafluoroethylene) used in the present invention is a fluorinated polyolefin resin (polytetrafluoroethylene, polyvinylidene fluoride, tetrafluoroethylene or a copolymer of vinylidene fluoride and tetrafluoro a copolymer of roethylene and hexafluoropropylene). In general, fluorinated polyolefin resins have very low surface energy, so they are sometimes used for lubrication, low friction, or wear resistance. Fluorinated polyolefin resin is a representative fluororesin, which is a polymer material in which hydrogen atoms are substituted with fluorine atoms in the molecular structure of polyethylene. and is known to be non-toxic. In particular, it maintains stability in a wide range of operating temperatures of -250 to 300°C, so its properties do not change. is being used

이러한 불소화폴리올레핀수지는 0.2∼5.5중량%의 첨가로 인해 장거리 운송 과정에서 몰탈과 고압호스의 마찰열을 최소화하여 유동성을 확보할 수 있다. 불소화폴리올레핀수지 0.2중량% 미만으로 첨가하면, 마찰열이 발생하여 유동성을 확보하기 어려우며, 5.5중량%를 초과하면 제조단가가 대폭 증대되기 때문에 0.2∼5.5중량% 범위 내에서 사용되는 것이 바람직하다.Due to the addition of 0.2 to 5.5 wt% of the fluorinated polyolefin resin, it is possible to secure fluidity by minimizing the frictional heat between the mortar and the high-pressure hose during long-distance transportation. When the fluorinated polyolefin resin is added in an amount of less than 0.2% by weight, frictional heat is generated and it is difficult to secure fluidity, and when it exceeds 5.5% by weight, the manufacturing cost is greatly increased. Therefore, it is preferably used within the range of 0.2 to 5.5% by weight.

본 발명에서 사용하는 아크릴계수지는 부착성이 우수하여 다양한 소재의 바탕면에도 뛰어난 부착력을 발휘하며, 들뜸이나 균열 발생이 없다. 특히 콘크리트, 몰탈, 석재, 타일, 금속, 목재, 아스팔트, 합성 수지계 마감면 등의 바탕면에 강력한 부착력을 발휘하여, 기존 마감재위에 바로 시공이 가능하여, 폐기물로 인한 환경오염이 없고, 공사기간을 단축 할 수 있는 첨단 기능성 도료 타입의 마감재이다. 또한 내마모성이 우수하여 마찰에 대한 저항성이 뛰어나고, 논스립 기능이 탁월할 뿐만 아니라 내충격성이 우수하여 외부압력을 자체적으로 흡수하기 때문에 진동에 의한 균열과 박리현상을 방지할 수 있다.The acrylic resin used in the present invention exhibits excellent adhesion to the base surface of various materials because of its excellent adhesion, and there is no lifting or cracking. In particular, it exerts strong adhesion to the base surface of concrete, mortar, stone, tile, metal, wood, asphalt, synthetic resin-based finishing surfaces, etc. It is a high-tech functional paint type finishing material that can be shortened. In addition, it has excellent abrasion resistance, excellent friction resistance, excellent non-slip function, and excellent impact resistance.

본 발명의 아크릴계수지는 15.7∼20.3중량%의 첨가로 인해 우수한 부착성능을 확보할 수 있고, 뿜칠 후 들뜸이나 균열 발생을 방지한다. 아크릴계수지 15.7중량% 미만으로 첨가하면, 부착성능이 감소하여 들뜸이나 균열을 발생시키고, 20.0중량%를 초과하면 제조단가가 대폭 증대되기 때문에 15.7∼20.3중량% 범위 내에서 사용되는 것이 바람직하다.The acrylic resin of the present invention can secure excellent adhesion performance due to the addition of 15.7 to 20.3% by weight, and prevents lifting or cracking after spraying. When the acrylic resin is added in an amount of less than 15.7% by weight, the adhesion performance is reduced to cause lifting or cracking, and when it exceeds 20.0% by weight, the manufacturing cost is significantly increased, so it is preferably used within the range of 15.7 to 20.3% by weight.

본 발명에서 사용하는 산화마그네슘은 1300℃에서 소성한 사소마그네슘을 사용한다. 소성온도가 1300℃ 미만이면 물과 혼합시 급격하게 반응하여 비빔량 및 작업시간 확보가 어렵고, 1300℃를 초과하면 경제성이 떨어진다.Magnesium oxide used in the present invention is magnesium tetrahydrogen calcined at 1300 ℃. If the firing temperature is less than 1300℃, it reacts rapidly when mixed with water, making it difficult to secure the amount of bibim and working time.

본 발명의 산화마그네슘은 5.0∼12.0중량%의 첨가로 인해 액상경화촉진제와 뿜칠이 완료된 후에 조기강도 발현에 도움을 준다. 산화마그네슘 5.0중량% 미만으로 첨가하면, 조기강도가 발현되지 않기 때문에 6시간 이내에 실용강도(압축강도 5.0 ㎫ 이상)를 만족하지 못하고, 12.0중량%를 초과하면 비빔성이 감소하고 단위중량의 증가로 뿜칠 후 처짐이 발생하기 때문에 5.0∼12.0중량% 범위 내에서 사용되는 것이 바람직하다.Magnesium oxide of the present invention helps to develop early strength after completion of spraying with the liquid curing accelerator due to the addition of 5.0 to 12.0% by weight. When magnesium oxide is added in an amount of less than 5.0% by weight, the practical strength (compressive strength of 5.0 MPa or more) is not satisfied within 6 hours because early strength is not expressed. Since sagging occurs after spraying, it is preferably used within the range of 5.0 to 12.0 wt%.

본 발명에서 사용하는 팽창제는 바인더의 수축을 보상할 정도의 팽창이 발생되어, 몰탈의 건조 수축균열을 저감시켜 수밀성 증대 목적으로 사용한다.The expanding agent used in the present invention expands enough to compensate for the shrinkage of the binder, and is used for the purpose of increasing watertightness by reducing drying shrinkage cracks of the mortar.

본 발명의 팽창제는 10.8∼20.4중량%의 첨가로 인해 몰탈의 건조 수축균열의 발생을 저감시켜준다. 팽창제 10.8중량% 미만으로 첨가하면, 건조 수축균열이 발생되고, 20.4중량%를 초과하면 팽창균열이 발생되기 때문에 10.8∼20.4중량% 범위 내에서 사용되는 것이 바람직하다.The expansion agent of the present invention reduces the occurrence of drying shrinkage cracks in the mortar due to the addition of 10.8 to 20.4 wt%. When added in an amount of less than 10.8% by weight of the expanding agent, drying shrinkage cracks occur, and when it exceeds 20.4% by weight, expansion cracks occur, so it is preferably used within the range of 10.8 to 20.4% by weight.

본 발명의 속경재는 17.5∼22.2중량%의 첨가로 인해 몰탈의 수화반응을 앞당겨 조기강도를 확보할 수 있다. 속경재 17.5중량% 미만으로 첨가하면, 수화반응을 앞당길 수 없어 6시간 이내에 실용강도(압축강도 5.0 ㎫ 이상)를 확보할 수 없고, 22.2중량%를 초과하면 가사시간이 줄어들어 작업성을 확보하기 어렵고 뿜칠 후 조기수축이 크게 발생되기 때문에 17.5∼22.2중량% 범위 내에서 사용되는 것이 바람직하다.Due to the addition of 17.5 to 22.2% by weight of the fast hardwood of the present invention, it is possible to accelerate the hydration reaction of the mortar to secure early strength. When added at less than 17.5 wt% of fast hardwood, the hydration reaction cannot be accelerated, so practical strength (compressive strength 5.0 MPa or more) cannot be secured within 6 hours. It is preferable to use within the range of 17.5 to 22.2% by weight because premature shrinkage is largely generated after spraying.

본 발명의 무수석고는 18.8∼25.3중량%의 첨가로 인해 속경재 사용으로 인한 조기수축을 보상해준다. 속경재에는 알루미나 함량이 높아 수축량이 크기 때문에 무수석고의 첨가로 조기 수축량을 감소시킬 수 있다. 무수석고 18.8중량% 미만으로 첨가하면, 속경재 사용량에 대한 수축보상이 어렵고, 25.3중량%를 초과하면 압축강도 저하가 발생되기 때문에 18.8∼25.3중량% 범위 내에서 사용되는 것이 바람직하다.The anhydrite of the present invention compensates for premature shrinkage due to the use of fast hardwood due to the addition of 18.8 to 25.3% by weight. Because fast hardwood has a high alumina content and a large amount of shrinkage, early shrinkage can be reduced by adding anhydrite. When anhydrite is added in an amount of less than 18.8% by weight, it is difficult to compensate for shrinkage for the amount of fast hardwood used, and when it exceeds 25.3% by weight, a decrease in compressive strength occurs, so it is preferably used within the range of 18.8 to 25.3% by weight.

본 발명의 소석회는 9.5∼14.8중량%의 첨가로 인해 액상경화촉진제와 뿜칠이 완료된 후에 초기 급결력을 향상시켜 준다. 소석회 9.5중량% 미만으로 첨가하면, 액상경화촉진제와 뿜칠이 완료된 후에 초기 급결력이 약해 처짐이 발생하여 1회 시공두께를 확보할 수 없고, 14.8중량%를 초과하면 비빔성이 줄어들기 때문에 9.5∼14.8중량% 범위 내에서 사용되는 것이 바람직하다.The slaked lime of the present invention improves the initial quick-setting power after completion of spraying with the liquid curing accelerator due to the addition of 9.5 to 14.8% by weight. When slaked lime is added in an amount of less than 9.5% by weight, after completion of spraying with the liquid curing accelerator, the initial quick-setting force is weak and sagging occurs, so that one-time construction thickness cannot be secured. It is preferably used within the range of 14.8% by weight.

본 발명의 배합수는 바인더 조성물 및 필러를 혼합하여 제조된 100중량부에 대하여 25∼35중량부로 한다. 25중량부 미만이면 비빔이 어렵고, 35중량부를 초과하면 재료분리 발생으로 품질이 저하되기 때문에 25∼35중량부 범위 내에서 사용되는 것이 바람직하다.The blending water of the present invention is 25 to 35 parts by weight based on 100 parts by weight prepared by mixing the binder composition and the filler. If it is less than 25 parts by weight, it is difficult to mix, and if it exceeds 35 parts by weight, the quality is deteriorated due to material separation, so it is preferably used within the range of 25 to 35 parts by weight.

성능개선제는 유동화제 1.0∼2.5중량%를 더 첨가하는 것이 바람직하다. 1.0중량% 미만이면 비빔이 어렵고, 2.5중량%를 초과하면 단가 상승의 요인이 되기 때문에 1.0∼2.5중량% 범위 내에서 사용되는 것이 바람직하다.It is preferable that the performance improving agent further adds 1.0 to 2.5% by weight of a glidant. If it is less than 1.0% by weight, it is difficult to cook, and if it exceeds 2.5% by weight, it is a factor of an increase in unit price. Therefore, it is preferably used within the range of 1.0 to 2.5% by weight.

성능개선제는 증점제 0.05∼0.15중량%를 더 첨가하는 것이 바람직하다. 0.05중량% 미만이면 재료분리 현상이 발생되고, 0.15중량%를 초과하면 점도가 과해지기 때문에 0.05∼0.15중량% 범위 내에서 사용되는 것이 바람직하다.It is preferable to further add 0.05-0.15 weight% of a thickener as a performance improving agent. When it is less than 0.05% by weight, material separation occurs, and when it exceeds 0.15% by weight, the viscosity becomes excessive, so it is preferably used within the range of 0.05 to 0.15% by weight.

성능개선제는 수축저감제 0.5∼1.8중량%를 더 포함하는 것이 바람직하다. 0.5중량% 미만이면 길이변화 성능이 떨어지며, 1.8중량%를 초과하면 단가 상승의 요인이 되기 때문에 0.5∼1.8중량% 범위 내에서 사용되는 것이 바람직하다.The performance improving agent preferably further comprises 0.5 to 1.8 wt% of a shrinkage reducing agent. If it is less than 0.5% by weight, the length change performance is deteriorated, and if it exceeds 1.8% by weight, it is a factor of an increase in unit price, so it is preferably used within the range of 0.5 to 1.8% by weight.

성능개선제는 섬유보강재 0.5∼2.2중량%를 더 포함하는 것이 바람직하다. 섬유보강재는 PVA 3mm, 6mm, 12mm 중 1종 이상을 사용한다. 0.5중량% 미만이면 휨강도 성능이 떨어지며, 2.2중량%를 초과하면 비빔이 어렵고 단가 상승의 요인이 되기 때문에 0.5∼2.2중량% 범위 내에서 사용되는 것이 바람직하다.It is preferable that the performance improving agent further comprises 0.5 to 2.2% by weight of the fiber reinforcing material. For fiber reinforcement, use at least one of PVA 3mm, 6mm, and 12mm. If it is less than 0.5% by weight, the flexural strength performance is deteriorated, and if it exceeds 2.2% by weight, it is preferable to use it within the range of 0.5 to 2.2% by weight, because it is difficult to bibim and causes an increase in unit cost.

성능개선제는 공기연행제 0.01∼0.13중량%를 더 포함하는 것이 바람직하다. 0.01중량% 미만이면 단위중량의 증가로 뿜칠 후 처짐이 발생되고, 0.13중량%를 장기 압축강도가 감소되기 때문에 0.01∼0.13중량% 범위 내에서 사용되는 것이 바람직하다.The performance improving agent preferably further comprises 0.01 to 0.13 wt% of an air entraining agent. If it is less than 0.01% by weight, sagging occurs after spraying due to an increase in unit weight, and 0.13% by weight is preferably used within the range of 0.01 to 0.13% by weight because long-term compressive strength is reduced.

성능개선제는 지연제 0.1∼5.0중량%를 더 포함하는 것이 바람직하다. 0.1중량% 미만이면 지연효과가 미미하여 유동성이 급격하게 저하되고, 5.0중량%를 초과하면 조기 압축강도가 감소되기 때문에 0.1∼5.0중량% 범위 내에서 사용되는 것이 바람직하다.It is preferable that the performance improving agent further comprises 0.1 to 5.0% by weight of a retarder. If it is less than 0.1% by weight, the delay effect is insignificant and the fluidity is rapidly reduced, and if it exceeds 5.0% by weight, the early compressive strength is reduced, so it is preferably used within the range of 0.1 to 5.0% by weight.

현재 상용화된 액상알칼리프리급결제의 주성분은 황산알루미늄(aluminium sulphate, Al2(SO4)3·12-18H2O로, 이 성분은 물에 대한 용해도가 매우 높기 때문에 시멘트에 다량의 황산염을 공급하여 수화초기부터 에트링자이트의 생성을 촉진하게 된다. 이를 통해 수화반응을 앞당겨 급결력 및 조기강도를 발현하게 한다.The main component of the currently commercialized liquid alkali-free quick-setting admixture is aluminum sulphate (Al 2 (SO 4 ) 3 ·12-18H 2 O. Because this component has very high solubility in water, a large amount of sulfate is supplied to cement. It promotes the production of etringite from the early stage of hydration, which accelerates the hydration reaction to express quick-setting power and early strength.

보다 상세히 설명하면, 일반 콘크리트(시멘트)의 수화과정에서는 시멘트에 혼합된 이수석고(gypsum, CaSO4·2H2O)의 용해로 생산된 황산염으로 에트링자이트가 생성되기 때문에 충분한 황산염의 공급이 이루어지지 않는다. 그러나 액상알칼리프리급결제를 사용하는 경우, 급결제 중의 황산알루미늄이 용해되어 생산된 다량의 황산염이 공급됨으로서, 시멘트는 다량의 에트링자이트를 생성하게 된다. 액상알칼리프리급결제를 사용하는 경우에 생성되는 에트링자이트는 일반 콘크리트에서 생성되어지는 에트링자이트와는 다소 차이를 보인다. 시멘트 중의 이수석고의 용해로 공급되어지는 황산염은 용출속도가 느리며 국부적인 반면, 액상알칼리프리급결제로부터 생성되는 황산염은 콘크리트 중에 균일하게 분포하고 농도가 높다. 따라서 생성되어지는 에트링자이트는 다량일 뿐만 아니라, 결정이 미세하며 전체적으로는 매우 치밀한 구조를 형성하게 된다. 액상알칼리프리급결제의 경우, 수화초기부터 강알칼리 성분을 배출하여 칼슘실리케이트상의 용출을 강제로 증진시키지 않기 때문에 장기재령에서 충분한 C-S-H 상의 생성을 가져와 장기강도의 저하가 적다는 장점을 가지고 있다. 하지만 액상알칼리프리급결제만을 사용해서는 본 발명에서 의도하는 1회 뿜칠두께 150mm와 6시간 이내에 5.0 ㎫ 이상의 압축강도를 달성할 수 있기 때문에, 액상알칼리프리급결제 97.0∼99.9중량%에 급결향상제 0.1∼3.0중량%를 혼합하여 사용한다.More specifically, in the hydration process of general concrete (cement), since ettringite is produced by the dissolution of dihydrate gypsum (gypsum, CaSO 4 ·2H 2 O) mixed with cement, sufficient sulfate is supplied. do not support However, when a liquid alkali-free quick-setting admixture is used, a large amount of sulfate produced by dissolving aluminum sulfate in the quick-setting admixture is supplied, so that the cement produces a large amount of ettringite. Ettringite produced when liquid alkali-free quick-setting admixture is used is somewhat different from ettringite produced from general concrete. Sulphate supplied by dissolution of dihydrate gypsum in cement has a slow dissolution rate and is localized, whereas sulphate generated from liquid alkali free quick-setting admixture is uniformly distributed in concrete and has a high concentration. Accordingly, the produced etringite is not only in a large amount, but also in fine crystals, forming a very dense structure as a whole. In the case of liquid alkali-free quick-setting admixture, since it does not forcibly enhance the dissolution of the calcium silicate phase by discharging strong alkali components from the initial stage of hydration, it has the advantage of producing sufficient CSH phase at long-term age and reducing long-term strength. However, since it is possible to achieve the intended spraying thickness of 150 mm and a compressive strength of 5.0 MPa or more within 6 hours by using only the liquid alkali-free quick-setting admixture, 0.1 to 97.0 to 99.9% by weight of the quick-setting enhancer 3.0% by weight is mixed and used.

이러한 급결향상제는 인산칼륨 1.5∼12.5중량%, 증류수 87.5∼98.5중량%를 혼합하여 이루어진다.This quick setting enhancer is made by mixing 1.5 to 12.5% by weight of potassium phosphate and 87.5 to 98.5% by weight of distilled water.

인산칼륨은 제1인산칼륨을 사용하고 1.5∼12.5중량% 범위 내에서 사용되는 것이 바람직하다. 1.5중량% 미만이면 초기 급결력 및 조기강도의 확보가 어렵고, 12.5중량%를 초과하면 단가 상승의 요인이 되기 때문에 1.5∼12.5중량% 범위 내에서 사용되는 것이 바람직하다.Potassium phosphate is preferably used within the range of 1.5 to 12.5% by weight using monobasic potassium phosphate. If it is less than 1.5% by weight, it is difficult to secure initial quick-setting strength and early strength, and if it exceeds 12.5% by weight, it is a factor of an increase in unit price, so it is preferably used within the range of 1.5 to 12.5% by weight.

아울러 장기 압축강도 및 경제성 확보 등을 위해 사용되는 필러는 천연모래, 인조규사, 플라이애시, 실리카흄, 탄산칼슘으로 이루어진 군으로부터 1종 이상 혼합하여 사용한다.In addition, the filler used to secure long-term compressive strength and economic feasibility, etc., is used by mixing one or more types from the group consisting of natural sand, artificial silica sand, fly ash, silica fume, and calcium carbonate.

플라이애시, 실리카흄, 탄산칼슘은 미세공극을 충전하는 역할과 더불어 포졸란반응에 의해 매트릭스를 형성하는 역할을 하므로 가능한 한 고분말도를 사용하는 것이 좋다.Fly ash, silica fume, and calcium carbonate play a role of filling micropores and forming a matrix by pozzolan reaction, so it is better to use a high powder as much as possible.

천연모래, 인조규사는 강도를 향상시키는 역할을 하므로 천연모래, 인조규사 1호사∼8호사 중 사용하는 것이 좋다.Natural sand and artificial silica sand play a role in improving strength, so it is better to use natural sand or artificial silica sand No. 1 to No. 8.

필러는 바인더 조성물 34.7∼47.2중량%에 대해 52.8∼65.3중량%로 혼합되고, 52.8중량% 미만이면 장기 압축강도 저하 및 단가 상승 요인이 되며, 65.3중량%를 초과하면 압축강도 저하 및 배합수 증대로 인한 성능이 감소되기 때문에 52.8∼65.3중량% 범위 내에서 사용되는 것이 바람직하다.The filler is mixed at 52.8 to 65.3% by weight based on 34.7 to 47.2% by weight of the binder composition, and when it is less than 52.8% by weight, it causes a decrease in long-term compressive strength and an increase in unit price. It is preferable to use within the range of 52.8 to 65.3 wt% because the performance is reduced.

<보수공법><Repair method>

상술한 단면보수재를 이용하여 장거리 압송을 통해 교각 또는 콘크리트 구조물을 응급 보수하는 보수공법에 대해 설명하면 다음과 같다.A repair method for emergency repair of a pier or concrete structure through long-distance pressure feeding using the above-described section repair material will be described as follows.

먼저 본 발명에 따른 바인더 조성물와 필러를 몰탈 배치믹서를 통해 혼합하여 몰탈 조성물을 생성하고, 이를 배합수와 혼합한다. 혼합비율은 상술한 바와 같이, 필러는 바인더 조성물 34.7∼47.2중량%에 대해 52.8∼65.3중량%로 혼합되고, 배합수는 바인더 조성물 및 필러를 혼합하여 제조된 몰탈 조성물 100중량부에 대하여 12∼16중량부로 한다. First, the binder composition and the filler according to the present invention are mixed through a mortar batch mixer to produce a mortar composition, and this is mixed with mixing water. The mixing ratio is as described above, the filler is mixed at 52.8 to 65.3% by weight based on 34.7 to 47.2% by weight of the binder composition, and the blending water is 12 to 16 with respect to 100 parts by weight of the mortar composition prepared by mixing the binder composition and the filler. by weight.

혼합된 몰탈은 몰탈펌프를 이용하여 몰탈호스를 통해 콘크리트 구조물에서 응급 보수가 필요한 지점까지 대략 수평 100m 또는 수직 40m 이상으로 장거리 압송된다. 여기서 사용되는 몰탈펌프는 스퀴즈펌프나 스네이크펌프 중 어느 하나인 것이 바람직하다.The mixed mortar is pumped over a long distance from the concrete structure to the point where emergency repair is needed through a mortar hose using a mortar pump, approximately 100m horizontally or 40m vertically. The mortar pump used here is preferably either a squeeze pump or a snake pump.

본 발명에 따른 단면보수재에는 액상경화촉진제가 포함되는데, 상기 액상경화촉진제는 압송펌프를 이용하여 액상호스를 통해 분사노즐건으로 압송된다. 여기서 압송펌프는 액상경화촉진제 조성물을 일정량을 계속적으로 토출이 가능한 장비를 사용해야 하고, 맥동의 영향을 받지 않는 펌프를 사용해야 한다.The end face repair material according to the present invention includes a liquid hardening accelerator, and the liquid hardening accelerator is pressurized to the spray nozzle gun through a liquid hose using a pressure pump. Here, the pressure pump must use equipment capable of continuously discharging a certain amount of the liquid curing accelerator composition, and use a pump that is not affected by pulsation.

콘크리트 구조물에 분사하기 위한 분사노즐건에는 상술한 몰탈-배합수 혼합물이 압송되고, 별도의 액상호스를 통해 액상경화촉진제가 압송된다 그리고 상기 몰탈-배합수 혼합물과 액상경화촉진제가 혼합되면서 뿜칠되도록 하기 위하여 상기 분사노즐건에는 공기압축기에 연결되어 압축공기를 압송하는 에어호스가 추가적으로 장착된다. 즉, 분사노즐건에는 몰탈-배합수 혼합물, 액상경화촉진제 및 압축공기가 별도로 주입될 수 있는 장비하여 혼합하고 뿜칠 할 수 있는 장비여야 하고, 액상경화촉진제 및 압축공기의 양을 조절할 수 있는 밸브가 장착되는 것이 보다 바람직하다. The above-mentioned mortar-mixed water mixture is pressurized to the spray nozzle gun for spraying the concrete structure, and the liquid hardening accelerator is pressurized through a separate liquid hose, and the mortar-mixed water mixture and the liquid hardening accelerator are mixed and sprayed. In order to do this, an air hose connected to an air compressor to pump compressed air is additionally mounted to the injection nozzle gun. That is, the spray nozzle gun must be equipped with equipment that can separately inject the mortar-mixed water mixture, liquid curing accelerator and compressed air, and must be equipped to mix and spray, and a valve to control the amount of liquid curing accelerator and compressed air It is more preferable to be mounted.

<실시예와 비교예><Examples and Comparative Examples>

다음으로 본 발명에 따른 실시예와 이에 대비되는 비교예 1∼4에 대해 설명한다. 실시예 및 비교예 1∼4에 대한 구체적인 배합사항은 다음의 [표 2]에 기재된 바와 같다.Next, Examples according to the present invention and Comparative Examples 1 to 4 in comparison thereto will be described. Specific formulations for Examples and Comparative Examples 1 to 4 are as described in Table 2 below.

구분division 실시예Example 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 비교예4Comparative Example 4




바인더
조성물





bookbinder
composition
시멘트cement 보통포틀랜드시멘트Ordinary Portland Cement 330330 330330 330330 330330 폴리머
시멘트
몰탈
1,000
polymer
cement
mortar
1,000
성능
개선제
Performance
improver
불소화폴리올레핀수지Fluorinated polyolefin resin 1.51.5 -- 1.51.5 1.51.5
아크릴계수지acrylic resin 1313 1313 1313 1313 산화마그네슘magnesium oxide 4.54.5 4.54.5 4.54.5 -- 팽창제swelling agent 99 99 99 99 속경재Sok Kyung-jae 1515 1515 1515 -- 무수석고anhydrite 1515 1515 1515 1515 소석회slaked lime 99 99 -- 99 유동화제glidant 1.21.2 1.21.2 1.21.2 1.21.2 증점제thickener 0.050.05 0.050.05 0.050.05 0.050.05 수축저감제shrinkage agent 0.50.5 0.50.5 0.50.5 0.50.5 섬유보강재fiber reinforcement 1.01.0 1.01.0 1.01.0 1.01.0 공기연행제air entrainment agent 0.050.05 0.050.05 0.050.05 0.050.05 지연제retardant 0.20.2 0.20.2 0.20.2 0.20.2 필러filler 실리카흄Silica fume 120120 121.5121.5 129129 139.5139.5 인조규사artificial silica 480480 480480 480480 480480 합계Sum 1,0001,000 1,0001,000 1,0001,000 1,0001,000 1,0001,000 배합수mixing water 140140 140140 140140 140140 160160 액상
경화
촉진제
liquid
Hardening
accelerant
급결제quick payment 액상알칼리프리Liquid alkali free 24.324.3 24.324.3 2525 24.324.3 --
급결
향상제
rush
enhancer
인산칼륨+증류수Potassium phosphate + distilled water 0.70.7 0.70.7 -- 0.70.7 --

[표 2]와 같은 배합사항을 갖는 실시예와 비교예 1∼3, 비교예 4(폴리머시멘트몰탈)에 대하여 수평 100m(또는 수직 40m) 이상 압송 가능 여부를 확인하고, 압송 후의 유동성과 발열온도를 측정하였고, 합판거푸집을 별도 제작하여 1회 뿜칠 시공두께와 처짐 여부를 확인하고, 몰드에 시험체를 제작하여 압축강도를 측정하였다.For Examples, Comparative Examples 1 to 3, and Comparative Example 4 (polymer cement mortar) having the same formulation as in [Table 2], check whether it is possible to pressurize 100m horizontally (or 40m vertically) or more, and fluidity and heat generation temperature after pressurization was measured, and the plywood formwork was separately manufactured to check the thickness to be sprayed once and whether there was any sagging, and the compressive strength was measured by making a specimen in a mold.

먼저 바인더 조성물와 필러를 혼합하여 제조된 몰탈, 배합수, 액상경화족진제를 준비하였다. 첫 번째로 배치믹서에 몰탈과 배합수를 넣고 믹싱한 후 믹싱된 몰탈을 몰탈펌프에 고압 압송호스를 연결하여 수평100m(수직40m) 운송하였다. 두 번째로 액상경화촉진제는 별도 압송펌프에 액상호스를 연결하여 수평100m(수직40m) 운송하였다. 압송된 몰탈와 액상경화촉진제는 수평100m(수직40m) 운송지점에서 별도 공기압축기에서 공급되는 압축공기와 함께 분사노즐건에 연결하여 뿜칠하였다. 그 결과는 [표 3]에 기재된 바와 같다.First, a mortar prepared by mixing a binder composition and a filler, mixing water, and a liquid hardening pacifier were prepared. First, mortar and mixing water were put in a batch mixer and mixed, and then the mixed mortar was transported horizontally 100m (vertically 40m) by connecting a high-pressure pressure hose to the mortar pump. Second, the liquid curing accelerator was transported horizontally 100m (vertically 40m) by connecting a liquid hose to a separate pressure pump. The pressurized mortar and liquid hardening accelerator were connected to a spray nozzle gun together with compressed air supplied from a separate air compressor at a transportation point of 100 m horizontally (40 m vertically) and sprayed. The results are as shown in [Table 3].

구분division 실시예Example 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3 비교예 4Comparative Example 4 비고note 수평100m(수직40m) 이상
운송 가능 여부
Horizontal 100m (vertical 40m) or more
Carriage availability
OO XX OO OO OO 장비사용use of equipment
압송 전 유동성(flow)Flow before pumping 210mm210mm 207mm207mm 206mm206mm 208mm208mm 132mm132mm Table FlowTable Flow 압송 후 유동성(flow)Flow after pumping 207mm207mm XX 202mm202mm 206mm206mm 120mm120mm Table FlowTable Flow 압송 전 발열온도Heating temperature before conveying 20.2℃20.2℃ 20.5℃20.5℃ 20.3℃20.3℃ 20.5℃20.5℃ 20.5℃20.5℃ 표면온도surface temperature 압송 후 발열온도Exothermic temperature after conveying 20.3℃20.3℃ 32.0℃32.0℃ 20.3℃20.3℃ 20.6℃20.6℃ 32.4℃32.4℃ 표면온도surface temperature 뿜칠 도중 처짐 여부Whether it sags during spraying XX 측정불가not measurable OO XX OO 육안평가Visual evaluation 1회 뿜칠 시공두께Construction thickness to be sprayed once 155mm155mm 측정불가not measurable 31mm31mm 152mm152mm 30mm30mm 거푸집
별도제작
formwork
Separate production
압축강도compressive strength 6시간6 hours 7.8MPa7.8 MPa 측정불가not measurable 3.0MPa3.0 MPa 측정불가not measurable 측정불가not measurable KS F 4042KS F 4042 종합평가Comprehensive evaluation OO XX XX XX XX

상기 [표 3]에서 알 수 있듯이, 먼저 실시예는 배치믹서에 몰탈과 배합수를 넣고 믹싱한 후 믹싱된 몰탈을 몰탈펌프에 고압 압송호스를 연결하여 압송하였을 때 수평100m(수직40m) 이상 압송이 가능하였고, flow는 운송 전 210mm에서 운송 후 207mm로 감소폭이 10mm 이내였고, 발열온도는 운송 전 20.2℃에서 운송 후 20.3℃로 증가폭이 5℃ 이내였다. 별도 제작된 거푸집에 몰탈을 뿜칠 하였을 때 뿜칠 도중 처짐이 발생하지 않았으며, 1회 155mm까지 뿜칠이 가능하였다. 압축강도는 KS F 4042 규격 몰드로 시험체를 제작하여 6시간 압축강도를 측정 결과 7.8 ㎫로서 기준치인 5.0 ㎫ 이상을 만족하였다. 실시예는 모든 기준치를 만족하였다.As can be seen from [Table 3], in the embodiment, first, after mixing mortar and mixing water in a batch mixer, when the mixed mortar is connected to a mortar pump by connecting a high-pressure pressure-feeding hose, horizontal 100m (vertical 40m) or more pressure-feeding This was possible, and the flow decreased within 10 mm from 210 mm before transportation to 207 mm after transportation, and the exothermic temperature increased from 20.2°C before transportation to 20.3°C after transportation within 5°C. When spraying mortar on a separately manufactured formwork, no sagging occurred during spraying, and spraying was possible up to 155mm at a time. The compressive strength was 7.8 MPa as a result of measuring the compressive strength for 6 hours by manufacturing a test specimen using a KS F 4042 standard mold, which satisfies the standard value of 5.0 MPa or more. The examples met all criteria.

비교예 1은 불소화폴리올레핀수지가 첨가되지 않았기 때문에 압송되는 동안 마찰이 발생되고 열이 누적되어 수평100m(수직40m) 이상 운송이 불가했고, flow는 운송 전 207mm에서 운송 후의 flow값은 없었으며, 발열온도는 운송 전 20.5℃에서 운송 후 32.0℃로 증가폭이 11.5℃로 5℃를 초과했다. 따라서 물성이 크게 변질되었다고 판단하여 다음단계의 뿜칠을 진행할 수 없었고, 처짐 여부, 1회 뿜칠 시공두께, 압축강도를 측정할 수 없었다. 비교예 1은 모든 기준치를 만족하지 못하였다.In Comparative Example 1, since the fluorinated polyolefin resin was not added, friction occurred and heat was accumulated during pressure feeding, making it impossible to transport more than 100 m horizontal (40 m vertical), and the flow was 207 mm before transport. There was no flow value after transport, and heat was generated. The temperature increased from 20.5°C before transportation to 32.0°C after transportation, exceeding 5°C with an increase of 11.5°C. Therefore, it was judged that the physical properties were significantly altered, so the spraying in the next step could not be carried out, and it was not possible to measure the sagging, the thickness of one spraying, and the compressive strength. Comparative Example 1 did not satisfy all standard values.

비교예 2는 소석회와 급결향상제를 첨가하지 않고 액상알칼리프리급결제만 사용 하였을 때 수평100m(수직40m) 이상 운송이 가능하였고, flow는 운송 전 206mm에서 운송 후 202mm로 감소폭이 10mm 이내였고, 발열온도는 운송 전 20.3℃에서 운송 후 20.3℃로 증가폭이 5℃ 이내였다. 하지만 뿜칠 과정에서 31mm부터 처짐이 발생하였으며, 압축강도도 완전한 반응이 이루어지지 않아 6시간 3.0MPa로 기준치를 만족하지 못하였다.In Comparative Example 2, when only liquid alkali-free quick setting agent was used without adding slaked lime and quick setting enhancer, it was possible to transport more than 100 m horizontally (40 m vertically), and the flow decreased from 206 mm before transport to 202 mm after transport within 10 mm, and heat generation The temperature increased within 5°C from 20.3°C before transportation to 20.3°C after transportation. However, deflection occurred from 31 mm during the spraying process, and the compressive strength did not fully respond to the standard value of 3.0 MPa for 6 hours.

비교예 3은 산화마그네슘과 속경재를 제외하였을 때 수평100m(수직40m) 이상 운송이 가능하였고, flow는 운송 전 208mm에서 운송 후 206mm로 감소폭이 10mm 이내였고, 발열온도는 운송 전 20.5℃에서 운송 후 20.6℃로 증가폭이 5℃ 이내였다. 별도 제작된 거푸집에 몰탈을 뿜칠하였을 때 뿜칠 도중 처짐이 발생하지 않았으며, 1회 152mm까지 뿜칠이 가능하였다. 단, 압축강도는 빠른 수화반응이 이루어지지 않아 6시간의 압축강도를 측정할 수 없었다.Comparative Example 3 was able to transport more than 100 m horizontally (40 m vertically) when excluding magnesium oxide and fast hardwood, and the flow decreased from 208 mm before transport to 206 mm after transport within 10 mm, and the exothermic temperature was transported at 20.5° C. before transport. After that, the increase was within 5°C to 20.6°C. When spraying mortar on a separately manufactured formwork, no sagging occurred during spraying, and spraying was possible up to 152mm at a time. However, as for the compressive strength, it was not possible to measure the compressive strength for 6 hours because the hydration reaction did not occur quickly.

기존 보수공법에 사용되어지고 있는 비교예 4는 수평100m(수직40m) 이상 운송이 가능하였고, flow는 운송 전 132mm에서 운송 후 120mm로 감소폭이 10mm를 초과했고, 발열온도는 운송 전 20.5℃에서 운송 후 32.4℃로 증가폭이 5℃를 초과했다. 뿜칠 과정에서 30mm부터 처짐이 발생하였으며, 6시간 압축강도는 측정 불가했다.Comparative Example 4, which is used in the existing repair method, was able to be transported horizontally 100m (vertical 40m) or more, the flow decreased from 132mm before transport to 120mm after transport, exceeding 10mm, and the exothermic temperature was transported at 20.5℃ before transport. After that, the increase at 32.4°C exceeded 5°C. Deflection occurred from 30mm during the spraying process, and the compressive strength for 6 hours could not be measured.

이상에서 살펴본 바와 같이, 본 발명에 따르면, 콘크리트 구조물의 열화 부분을 보수함에 있어 몰탈과 호스의 마찰열을 최소화하여 유동성이 확보되어 수평 100m 또는 수직 40m 이상의 장거리 압송이 가능하고 고소작업이 용이할 뿐만 아니라 안정적 품질을 확보할 수 있고, 뿜칠 후 초기 급결력을 향상시켜 1회 시공두께를 150mm 이상 처짐 없이 뿜칠하여 시공 이음부를 최소화 할 수 있으며, 뿜칠 후 빠른 경화반응으로 단시간에 조기강도가 발현되어 6시간 이내에 실용강도(압축강도 5.0㎫ 이상)를 만족하여 응급보수가 가능하게 된다.As described above, according to the present invention, in repairing the deteriorated part of the concrete structure, fluidity is secured by minimizing the frictional heat between the mortar and the hose, so that long-distance pressure feeding of 100m horizontally or 40m or more is possible, and work at high altitude is easy. Stable quality can be secured, and the initial quick-setting power after spraying can be improved to minimize the construction joint by spraying with a thickness of 150mm or more at one time without sagging. It satisfies the practical strength (compressive strength of 5.0 MPa or more) within the range, so that emergency repair is possible.

본 발명의 권리는 위에서 설명된 실시 예에 한정되지 않고 청구범위에 기재된 바에 의해 정의되며, 본 발명의 분야에서 통상의 지식을 가진 자가 청구범위에 기재된 권리범위 내에서 다양한 변형과 개작을 할 수 있다는 것은 자명하다.The rights of the present invention are not limited to the above-described embodiments, but are defined by the claims, and those of ordinary skill in the art can make various modifications and adaptations within the scope of the claims. it is self-evident

Claims (7)

불소화폴리올레핀수지, 아크릴계 수지, 산화마그네슘, 팽창제, 속경재, 무수석고 및 소석회로 구성되는 성능개선제 9.8∼18.8중량%와 보통포틀랜드시멘트 81.2∼90.2중량%로 이루어지는 바인더 조성물 34.7 ~ 47.2중량%와 필러 52.8~65.3중량%를 혼합하여 제조된 몰탈 조성물을 포함하고,
상기 성능개선제는 불소화폴리올레핀수지 0.2∼5.5중량%, 아크릴계수지 15.7∼20.3중량%, 산화마그네슘 5.0∼12.0중량%, 팽창제 10.8∼20.4중량%, 속경재 17.5∼22.2중량%, 무수석고 18.8∼25.3중량%, 소석회 9.5∼14.8중량%를 혼합하여 이루어지며,
초기 급결력을 향상시키고 뿜칠 후 6시간 이내에 5.0 ㎫ 이상의 실용강도를 발현할 수 있도록 액상경화촉진제를 상기 몰탈 조성물 100 중량부에 대하여 2.4∼7.2 중량부 범위 내에서 첨가하고,
상기 액상경화촉진제는 인산칼륨 1.5∼12.5중량%와 증류수 87.5∼98.5중량%로 구성되는 급결향상제 0.1∼3.0중량% 및 액상알칼리프리급결제 97.0∼99.9중량%로 이루어지는 것을 특징으로 하는 장거리 압송을 통해 콘크리트 구조물의 응급 보수가 가능한 단면보수재.
Fluorinated polyolefin resin, acrylic resin, magnesium oxide, expanding agent, fast hardwood, anhydrite and slaked lime, 9.8 to 18.8 wt% of a performance improving agent, and 81.2 to 90.2 wt% of ordinary Portland cement 34.7 to 47.2 wt% of a binder composition and 52.8 wt% It contains a mortar composition prepared by mixing ~65.3% by weight,
The performance improving agent is 0.2 to 5.5 wt% of a fluorinated polyolefin resin, 15.7 to 20.3 wt% of an acrylic resin, 5.0 to 12.0 wt% of magnesium oxide, 10.8 to 20.4 wt% of an expanding agent, 17.5 to 22.2 wt% of a fast hardwood, 18.8 to 25.3 wt% of anhydrite %, is made by mixing 9.5 to 14.8% by weight of slaked lime,
A liquid curing accelerator is added within the range of 2.4 to 7.2 parts by weight based on 100 parts by weight of the mortar composition to improve the initial fastening power and to express a practical strength of 5.0 MPa or more within 6 hours after spraying,
The liquid curing accelerator comprises 0.1 to 3.0% by weight of a quick-setting enhancer composed of 1.5 to 12.5% by weight of potassium phosphate and 87.5 to 98.5% by weight of distilled water and 97.0 to 99.9% by weight of a liquid alkali-free quicksetting agent. A single-sided repair material that enables emergency repair of concrete structures.
삭제delete 제1항에 있어서,
상기 성능개선제는, 유동화제 1.0∼2.5중량%, 증점제 0.05∼0.15중량%, 수축저감제 0.5∼1.8중량%, 섬유보강재 0.5∼2.2중량%, 공기연행제 0.01∼0.13중량%, 지연제 0.1∼5.0중량%를 더 포함하는 것을 특징으로 하는 장거리 압송을 통해 콘크리트 구조물의 응급 보수가 가능한 단면보수재.
According to claim 1,
The performance improving agent is, 1.0 to 2.5% by weight of a fluidizing agent, 0.05 to 0.15% by weight of a thickener, 0.5 to 1.8% by weight of a shrinkage reducing agent, 0.5 to 2.2% by weight of a fiber reinforcing agent, 0.01 to 0.13% by weight of an air entraining agent, 0.1 to a retardant Sectional repair material capable of emergency repair of concrete structures through long-distance pressure feeding, characterized in that it further comprises 5.0% by weight.
삭제delete 삭제delete 불소화폴리올레핀수지, 아크릴계 수지, 산화마그네슘, 팽창제, 속경재, 무수석고 및 소석회로 구성되는 성능개선제 9.8∼18.8중량%와 보통포틀랜드시멘트 81.2∼90.2중량%로 이루어지는 바인더 조성물 34.7∼47.2중량%와 필러 52.8∼65.3중량%를 혼합하고, 바인더 조성물 및 필러를 혼합하여 제조된 몰탈 조성물 100중량부에 대하여 12∼16중량부의 배합수를 혼합하는 단계;
상기 몰탈-배합수 혼합물을 몰탈펌프를 이용하여 몰탈호스를 통해 교량 또는 기둥 구조물의 긴급 보수 지점의 분사노즐건으로 압송하는 단계;
인산칼륨 1.5∼12.5중량%와 증류수 87.5∼98.5중량%로 구성되는 급결향상제 0.1∼3.0중량% 및 액상알칼리프리급결제 97.0∼99.9중량%로 이루어지는 액상경화촉진제를 압송펌프를 이용하여 액상호스를 통해 상기 분사노즐건으로 압송하는 단계;
공기압축기에서 생성된 압축공기를 에어호스를 통해 상기 분사노즐건으로 압송하는 단계; 및
상기 분사노즐건에서 상기 몰탈-배합수 혼합물과 액상경화촉진제와 압축공기를 혼합하여 교량 또는 기둥 구조물로 뿜칠하는 단계;를 포함하는 것을 특징으로 하는 콘크리트 구조물의 응급 보수용 단면보수재를 이용한 보수공법.
Fluorinated polyolefin resin, acrylic resin, magnesium oxide, expanding agent, fast hardwood, anhydrite and slaked lime, 9.8 to 18.8 wt% of a performance improving agent, and 81.2 to 90.2 wt% of ordinary Portland cement 34.7 to 47.2 wt% of a binder composition and 52.8 wt% Mixing ∼65.3% by weight, mixing 12 to 16 parts by weight of a compounding water with respect to 100 parts by weight of a mortar composition prepared by mixing a binder composition and a filler;
pressure-feeding the mortar-mixed water mixture to a spray nozzle gun at an emergency repair point of a bridge or column structure through a mortar hose using a mortar pump;
A liquid curing accelerator consisting of 0.1 to 3.0% by weight of a quick-setting enhancer consisting of 1.5 to 12.5% by weight of potassium phosphate and 87.5 to 98.5% by weight of distilled water and 97.0 to 99.9% by weight of a liquid alkali-free quick-setting agent is passed through a liquid hose using a pressure pump. pressure-feeding with the injection nozzle gun;
compressing the compressed air generated by the air compressor to the injection nozzle gun through an air hose; and
In the spray nozzle gun, mixing the mortar-mixed water mixture, liquid hardening accelerator, and compressed air, and spraying the mixture onto a bridge or column structure.
제6항에 있어서,
상기 액상경화촉진제는 상기 바인더 조성물과 필러를 혼합한 몰탈 조성물 100 중량부에 대하여 2.4∼7.2 중량부 범위 내에서 혼합되되, 상기 분사노즐건에 장착된 밸브에 의해 상기 중량 범위로 조절되는 것을 특징으로 하는 콘크리트 구조물의 응급 보수용 단면보수재을 이용한 보수공법.
7. The method of claim 6,
The liquid curing accelerator is mixed within the range of 2.4 to 7.2 parts by weight based on 100 parts by weight of the mortar composition in which the binder composition and the filler are mixed, characterized in that it is adjusted to the above weight range by a valve mounted on the spray nozzle gun. A repair method using sectional repair materials for emergency repair of concrete structures.
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