KR102317518B1 - A sandwich panel and a manufacturing method thereof - Google Patents

Abstract

The present invention provides a core layer of a nonwoven fiber structure; a skin layer laminated on at least one surface of the core layer; and an adhesive layer for adhering the core layer and the skin layer, wherein when the sound absorption coefficient of the entire panel is measured by an impedance tube method, the average value of the sound absorption coefficient at a frequency of 500 to 6500 Hz is 0.25 to 0.50, a sandwich panel is about

Description

Sandwich panel and manufacturing method thereof

The present invention relates to a sandwich panel and a method for manufacturing the same.

A typical sandwich panel has structural rigidity similar to that of a metal panel and is effective in reducing weight, so it is used in various fields such as construction materials.

In such a sandwich panel, a core layer is formed between skin layers formed of aluminum, iron, or the like to control the physical properties of the panel. For example, a foamed resin material is used for the core layer to increase the weight reduction effect of the panel, or a general resin, composite material, or balsa wood material is used to increase the mechanical strength of the panel.

However, such a sandwich panel does not have sufficient weight reduction and mechanical strength, and is not excellent in elongation, so there are limitations in product application. In addition, when the panel is formed by applying an adhesive between the skin layer and the core layer, there is a problem in that the formability during processing is poor because the bonding force between the layers is weak.

As a background art related to the present invention, there is Korean Patent Laid-Open No. 10-2017-0140111, which discloses a sandwich panel and a manufacturing method thereof.

However, in the case of the sandwich panel, although physical properties such as high density and high flexural strength and tensile strength were secured, the sound absorption performance of the panel was not sufficient, so there was a problem in that the blocking effect such as noise was deteriorated.

Korean Patent Laid-Open Publication No. 10-2017-0140111, Sandwich panel and manufacturing method thereof

In order to solve the above problem, the present inventors studied on a sandwich panel manufactured by performing a needle punching process when manufacturing a nonwoven fabric used as a core material of a sandwich panel, and as a result, the present invention was completed.

Accordingly, it is an object of the present invention to provide an improved sandwich panel to improve the sound-absorbing performance of the panel while improving the mechanical strength of the core material in manufacturing the sandwich panel, thereby improving the effect of blocking noise and the like.

In order to achieve the above purpose,

The present invention provides a core layer of a nonwoven fiber structure; a skin layer laminated on at least one surface of the core layer; and an adhesive layer for adhering the core layer and the skin layer, wherein when the sound absorption coefficient of the entire panel is measured by an impedance tube method, the average value of the sound absorption coefficient at a frequency of 500 to 6500 Hz is 0.25 to 0.50, a sandwich panel provides

The sandwich panel according to the present invention improves the sound absorption performance of the panel while improving the mechanical strength of the core material through the sandwich panel manufactured by limiting the conditions of needle punching during the manufacture of the nonwoven fabric used as the core material of the sandwich panel, By providing an improved sandwich panel to improve the effect of blocking noise, etc., structural materials for home appliances (TV back cover, washing machine board, etc.), interior and exterior boards for construction, interior and exterior materials for automobiles, interior and exterior materials for trains/ships/aircraft, and various partitions It is suitable for use in boards, elevator structural materials, etc.

1 is a schematic diagram of a sandwich panel according to the present invention.
2 is a graph showing the sound absorption characteristics of the sandwich panels of Example 1 and Comparative Examples 1 and 2 according to the present invention.

Advantages and features of the present invention and methods of achieving them will become apparent with reference to the embodiments described below in detail in conjunction with the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but will be implemented in a variety of different forms, and only these embodiments allow the disclosure of the present invention to be complete, and common knowledge in the technical field to which the present invention belongs It is provided to fully inform the possessor of the scope of the invention, and the present invention is only defined by the scope of the claims. Like reference numerals refer to like elements throughout.

Hereinafter, a sandwich panel according to a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings.

A sandwich panel according to the present invention comprises a core layer of a non-woven fiber structure; a skin layer laminated on at least one surface of the core layer; And as a panel comprising an adhesive layer for adhering the core layer and the skin layer, when the sound absorption coefficient of the entire panel is measured by an impedance tube method, the average value of the sound absorption coefficient at a frequency of 500 to 6500 Hz may be 0.25 to 0.50, Preferably, the average value of the sound absorption coefficient of a frequency of 500 to 6500 Hz may be 0.28 to 0.40.

In addition, the sandwich panel of the present invention may have a sound absorption coefficient of 0.35 to 0.60 at a frequency of 1600 Hz, a sound absorption coefficient of 0.30 to 0.80 at a frequency of 2000 Hz, and a sound absorption coefficient of 0.30 to 0.60 at a frequency of 2500 Hz.

As a result of the experiments of the present inventors, in the case of a conventional sandwich panel, physical properties such as flexural strength and tensile strength are deteriorated, and in particular, the sound absorption performance of the panel is not sufficient, and there is a problem in that the blocking effect such as noise is deteriorated. TV back cover, washing machine board, etc.), interior and exterior boards for construction, interior and exterior materials for automobiles, interior and exterior materials for trains/ships/aircraft, boards for various partitions, and elevator structural materials were in need of improvement.

However, the present inventors have produced a sandwich panel suitable for use as a living material or an industrial material, by improving the sound absorption performance of the panel and manufacturing an improved sandwich panel to improve the blocking effect of noise and the like.

core layer

A sandwich panel according to the invention comprises a core layer 10 of a non-woven fibrous structure.

The core layer 10 of the sandwich panel according to the present invention is made of a non-woven fiber structure, including polyester-based fibers and a binder.

In the present invention, the term 'nonwoven fiber structure' refers to bonding a fiber aggregate on a web or a sheet with an adhesive or using a thermoplastic fiber, and the core layer according to the present invention comprises Since the fibers have a nonwoven fiber structure in which the fibers are entangled with each other, all or part of the polyester-based fibers are fused by the binder, and thus natural pores are included in the core layer, so that air permeability is improved, and weight reduction is improved can do it That is, since the fibers have natural pores formed while being entangled with each other, unlike the case where pores are artificially formed by an additive such as a foaming agent, since it is a non-foaming core, manufacturing costs can be reduced, and the foaming process can be omitted. Efficiency can also be increased.

The average length of the polyester-based fibers included in the core layer according to the present invention is preferably 5 to 100 mm. When the average length of the fibers is less than 5 mm, it may be difficult to expect the effect of high elongation due to the short length of the fibers . Conversely, when it exceeds 100 mm, the space occupied by the gap of the core layer may be reduced because the content of fibers entangled with each other increases. In addition, when it exceeds 100 mm, during the manufacture of the core layer, the dispersion of the fibers is not made smoothly, and the physical properties of the core layer may be deteriorated.

The binder included in the core layer may be a non-hygroscopic copolymer resin or a hygroscopic copolymer resin.

In particular, the non-absorbent copolymer resin used in the present invention refers to a resin having a property of not absorbing moisture in the air, and specifically, based on the molded article of the present invention manufactured using the resin, the temperature and relative A weight change rate (that is, an increase rate of moisture content) of the molded article after standing at 85% humidity for 100 hours may be less than 0.1%, preferably less than 0.08%, more preferably less than 0.07%.

In general, since the moisture absorption of the PET fibers contained in the molded article is less than 0.05%, if the weight change rate of the molded article exceeds 0.05%, it means that the amount of moisture absorbed by the binder, which is another component in the molded article, is significant. do. In this regard, the non-absorbent copolymer resin used in the present invention has a weight change rate (that is, an increase in moisture content) of the molded article after being left for 100 hours at 85° C. , preferably less than 0.08%, more preferably less than 0.07%.

As such a non-hygroscopic copolymer resin, a polyester fiber, a diol-based monomer having strong crystallinity and excellent elasticity, and an acid component capable of imparting flexibility are copolymerized together, and one that satisfies the water absorption may be used. .

Specifically, as the polyester fiber, any one or more selected from the group consisting of polyethylene terephthalate (PET), polytrimethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate may be used, and as the diol-based monomer, neo From the group consisting of pentyl glycol, diethylene glycol, ethylene glycol, poly(tetramethylene) glycol, 1,4-butanediol, 1,3-propanediol, 1,6-hexanediol, 1,4-cyclohexanedimethanol, etc. Any one or more selected from may be used, and as the acid component, any one or more selected from the group consisting of isophthalic acid, adipic acid, 2,6-naphthalenedicarboxylic acid, sebacic acid, succinic acid, and the like may be used.

All or part of the polyester-based fibers included in the core layer according to the present invention are fused by a binder that is a non-hygroscopic resin, and the binder may have a melting point of 160° C. or higher.

The core layer according to the present invention has an apparent density of 0.5 to 0.8 g/cm ³ . Since it satisfies the above density range, it may have sufficient mechanical strength to be used as a packaging material for large cargo.

Since the core layer according to the present invention satisfies the mechanical strength as described above, it is included in a sandwich panel, and is used as a structural material for home appliances (TV back cover, washing machine board, etc.), interior and exterior boards for construction, interior and exterior materials for automobiles, and trains/ships. /It can be used as interior and exterior materials for aircraft (boards such as partitions), boards for various partitions, and elevator structural materials.

The core layer according to the present invention may further include a sheath-core type bicomponent fiber. The sheath-core type bicomponent fiber may include a core part of a polyester fiber; and a non-hygroscopic copolymer resin sheath part surrounding the core part. The sheath-core type bicomponent fiber may be included in the core layer according to the present invention because the resin of the sheath portion remains unmelted, which was introduced in the manufacturing step of the core layer according to the present invention.

In the core part of the sheath-core type bicomponent fiber, the polyester fiber may use any one or more selected from the group consisting of polyethylene terephthalate (PET), polytrimethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate. have.

The sheath portion of the sheath-core type bicomponent fiber may use the same non-hygroscopic copolymer resin as the binder included in the core layer according to the present invention.

Specifically, the non-absorbent copolymer resin refers to a resin having a property of not absorbing moisture in the air, and specifically, based on the molded article of the present invention manufactured using the resin, 100 at 85° C. and 85% relative humidity. A weight change rate (that is, an increase rate of moisture content) of the molded article after standing for a period of time may be less than 0.1%, preferably less than 0.08%, more preferably less than 0.07%.

In general, since the moisture absorption of the PET fibers contained in the molded article is less than 0.05%, if the weight change rate of the molded article exceeds 0.05%, it means that the amount of moisture absorbed by the binder, which is another component in the molded article, is significant. do. In this regard, the non-absorbent copolymer resin used in the present invention has a weight change rate (that is, an increase in moisture content) of the molded article after being left for 100 hours at 85° C. , preferably less than 0.08%, more preferably less than 0.07%.

As such a non-absorbent copolymer resin, a polyester fiber, a diol-based monomer having strong crystallinity and excellent elasticity, and an acid component capable of imparting flexibility are copolymerized together, and one that satisfies the water absorption may be used. .

Specifically, as the polyester fiber, any one or more selected from the group consisting of polyethylene terephthalate (PET), polytrimethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate may be used, and as the diol-based monomer, neo From the group consisting of pentyl glycol, diethylene glycol, ethylene glycol, poly(tetramethylene) glycol, 1,4-butanediol, 1,3-propanediol, 1,6-hexanediol, 1,4-cyclohexanedimethanol, etc. Any one or more selected from may be used, and as the acid component, any one or more selected from the group consisting of isophthalic acid, adipic acid, 2,6-naphthalenedicarboxylic acid, sebacic acid, succinic acid, and the like may be used.

The sheath-core type bicomponent fiber is prepared by melt spinning and drawing using the components of the core and the components of the sheath.

In addition, when the non-hygroscopic resin is used as the sheath component of the sheath-core type bicomponent fiber, flexural strength and tensile strength are improved, and the core layer can be manufactured by a dry process, thereby making it easy to manufacture a high-density core layer. In addition, when it is used as a packaging material for large cargo, it is possible to prevent the nonwoven fabric from sagging due to its good physical properties and shape retention even under a high temperature and high humidity atmosphere.

In addition, the core layer according to the present invention may further include a filler such as glass fiber, carbon fiber, polymer fiber, and the like. In addition, a flame retardant such as a bromine-based organic flame retardant may be further included. In addition to this, additives such as impact modifiers and heat stabilizers may be further included.

The method for manufacturing the core layer according to the present invention may be manufactured by the following method.

The method for manufacturing the core layer according to the present invention comprises the steps of: a) preparing a nonwoven fiber; b) The number of punching per minute is 300 to 1000 times per minute on the nonwoven fiber, the movement speed of the nonwoven fabric is 1 to 8 m/min, and the punching density is 100 to 500 punches/cm ^{2 The} core layer is manufactured by performing a needle punching process step; may include.

First, in step a), a nonwoven fiber is prepared. In order to prepare the nonwoven fiber, (A) a polyester fiber and (B) a sheath comprising a core part of the polyester fiber and a sheath part that is a non-hygroscopic copolymer resin surrounding the core part - After mixing the sheath-core type bicomponent fibers, heating and pressing are performed to prepare nonwoven fibers.

In this case, (A) polyester fiber and B) sheath-core type bicomponent fiber may be mixed in a weight ratio of 1:99 to 80:20 and used. B) When the content of the sheath-core type bicomponent fiber is less than the above range, the fusion between the fibers may not be sufficient and the physical properties of the nonwoven fiber may be deteriorated.

Then, in step b), after mixing the nonwoven fibers, a needle punching process may be performed to prepare a nonwoven fabric (core layer).

The needle punching process is, the number of punches per minute to the mixed nonwoven fiber is 300 to 1000 times, the movement speed of the nonwoven fabric is 1 to 8 m/min, and the punching density is 100 to 500 punches/cm ² , a needle punching process A needle punching process may be performed, and more preferably, the number of punches per minute for the nonwoven fiber is 400 to 700 times, the movement speed of the nonwoven fabric is 1.5 to 6 m/min, and the punching density is 200 to 400 punches/cm ² can proceed.

If the number of punches per minute is less than 300, there is a problem in that the degree of binding between the nonwoven fibers is lowered, and when the number of punchings per minute is more than 1000 times, there is a problem in that the nonwoven fibers are broken. In addition, if the moving speed of the nonwoven fabric is slower than 1 m/min, there is a problem in that the production speed is too slow, and if it is faster than 8 m/min, there is a problem in that it is not easy to control the punching density. In addition, when the punching density is ^{less than 100 punches/cm 2} , there is a problem in that the degree of binding between the nonwoven fibers is lowered ^{, and when the punching density is more than 500 punches/cm 2} , there is a problem in that the nonwoven fibers break.

The needle punching process may be performed two or more times. When the needle punching process is performed two or more times, it is possible to increase the binding force of the interlayer fibers, which is effective in preventing delamination.

As the needle punching process in the above range is performed, the physical bonding force by needle punching is improved, thereby improving the sound absorption performance of the panel of the finally manufactured sandwich panel, thereby improving the blocking effect of noise and the like.

Specifically, after mixing the nonwoven fibers and carding using a carding machine, a needle punching process of the above conditions is performed to prepare a nonwoven fabric having a basis weight of 1000 to 2500 gsm.

Thereafter, the manufactured nonwoven fabric is mounted on a plurality of unwinding devices, and then moved to a hot press. At this time, after mounting 2 to 10 of the manufactured nonwoven fabric in a plurality of unwinding devices according to the number, it may be moved to a hot press for manufacturing the core layer. When a plurality of nonwoven fabrics are used by using a plurality of unwinding devices in this way, since the thickness of each nonwoven fabric becomes thin, the length of the nonwoven fabric wound around one unwinding device becomes long. Therefore, since it is possible to reduce the number of times of use of the softener for connecting the nonwoven fabrics continuously input during the continuous process, there is an advantage that the process can be simplified.

Thereafter, the core layer is prepared by heating and pressing the plurality of nonwoven fabrics moved to the hot press under a temperature condition of 170 to 210° C. and a pressure condition of 1 to 10 MPa.

The heating press used in the above is not particularly limited as long as it is commonly used in the industry, and as a specific example, a double belt press or the like may be used.

In addition, the method of manufacturing the core layer according to the present invention,

After performing the needle punching process of step b), preheating for 3 to 10 minutes at a temperature of 160 to 210° C. may be further included.

When the preheating step is further included as described above, since thermal energy is previously applied to the non-absorbent copolymer resin of the sheath portion of the sheath-core type bicomponent fiber in the nonwoven fabric, there is an advantage in that the time for the heating and pressing process can be shortened. .

skin layer

The sandwich panel according to the present invention includes a skin layer 20 laminated on at least one surface of the core layer.

The skin layer 20 of the sandwich panel according to the present invention may be formed of a metal material, and preferably any one selected from the group consisting of aluminum, iron, stainless steel (SUS), magnesium, and electrogalvanized steel sheet (EGI). It may include more than one. For example, in order to have excellent formability and flexural rigidity, the skin layer 20 including an electrogalvanized steel sheet (EGI) may be applied to the sandwich panel. In addition, the skin layer 20 including aluminum may be applied to the sandwich panel in order to reduce the weight.

The thickness of the skin layer 20 may be less than or equal to 6% of the thickness of the entire panel. The skin layer of the conventional sandwich panel had a problem in that the thickness of the skin layer had to be thick due to the low mechanical strength of the core material, thereby increasing the weight of the sandwich panel. As the strength is improved, the thickness of the skin layer can be set to 6% or less of the total thickness of the panel, and thus the weight can be reduced.

adhesive layer

The sandwich panel according to the present invention includes an adhesive layer (not shown) for bonding the core layer and the skin layer.

The adhesive layer of the sandwich panel according to the present invention is applied between the core layer 10 and the skin layer 20 to bond the core layer 10 and the skin layer 20 . The adhesive layer is preferably applied with a uniform thickness in consideration of the viscosity. In the present invention, a sandwich panel may be manufactured by laminating the core layer 10 and the skin layer 20 and then curing it, or by thermally pressing the core layer 10 and the skin layer 20 after laminating the core layer 10 and the skin layer 20. Sandwich panels can be manufactured. At this time, as the adhesive penetrates into the core layer 10 during curing or thermocompression bonding, the skin layer 20 and the core layer 10 are not only chemically bonded to the components constituting the core layer 10 but also mechanically bonded. ) has the effect of improving the adhesion. The chemical bonding means that the adhesive becomes a covalent bond with the upper surface and the lower surface of the core layer, a hydrogen bond, a van der Waals bond, an ionic bond, and the like.

The mechanical bonding refers to a form in which the rings are physically hung as if they are hung with each other as the adhesive permeates into the core layer. This form is also called mechanical interlocking. Due to the natural pores included in the core layer 10 , the adhesive permeates the upper and lower surfaces of the core layer 10 .

The adhesive constituting the adhesive layer may include at least one of an olefin-based adhesive, a urethane-based adhesive, an acrylic adhesive, and an epoxy-based adhesive. The olefin-based adhesive may be at least one selected from the group consisting of polyethylene, polypropylene, and amorphous polyalphaolefin adhesives. The urethane-based adhesive may be used without limitation as long as it is an adhesive including a urethane structure (-NH-CO-O-). The acrylic adhesive may include at least one of a polymethyl methacrylate adhesive, a hydroxyl group-containing polyacrylate adhesive, and a carboxy group-containing polyacrylate adhesive. The epoxy adhesive is bisphenol-A type epoxy adhesive, bisphenol-F type epoxy adhesive, novolac epoxy adhesive, linear aliphatic epoxy resins, and cycloaliphatic epoxy resins. may include

In addition, the adhesive may include a photocurable adhesive, a hot melt adhesive, or a thermosetting adhesive, and any one of a photocuring method and a thermosetting method may be used. For example, a sandwich panel can be manufactured by thermosetting a laminate including a skin layer, a core layer, and an adhesive. The thermosetting may be performed for about 5 minutes to 2 hours at 50 to 110° C., which is the curing temperature of the epoxy resin, and curing may be performed for about 1 to 10 hours even at room temperature.

The adhesive layer may be applied to a thickness of about 20 to 300 μm, but is not limited thereto.

As a method of applying the adhesive layer to one surface of the skin layer 20, any one method selected from among a die coating method, a gravure coating method, a knife coating method, and a spray coating method may be used.

Another adhesive used for the adhesive layer may include a first adhesive layer including high-density polyethylene (HDPE) and a second adhesive layer including low-density polyethylene (LDPE).

The high density polyethylene (HDPE) may have a density of 0.940 to 0.965 g/cm ³ , and the low density polyethylene (LDPE) may have a density of 0.910 to 0.925 g/cm ³ .

The adhesive constituting the adhesive layer is not particularly limited as long as it can form a first adhesive layer including high-density polyethylene (HDPE) and a second adhesive layer including low-density polyethylene (LDPE), but is preferably co-extruded using a film extruder to manufacture

The adhesive layer may be applied to a thickness of about 20 to 300 μm, and the first adhesive layer and the second adhesive layer may each have a thickness of 10 to 150 μm, but is not limited thereto, and the first adhesive layer and the second adhesive layer are not limited thereto. The thickness of the adhesive layer may be the same or different.

In order to form the skin layer on the adhesive layer, the sandwich panel may be manufactured by positioning the skin layer on the adhesive layer and then thermocompression bonding the laminate including the skin layer, the core layer, and the adhesive. The thermocompression bonding may be performed at a pressure of 2 to 10 MPa at 150 to 200° C. for about 3 to 10 minutes.

At this time, the core layer and the high-density polyethylene (HDPE) adhesive are attached, and the skin layer and the low-density polyethylene (LDPE) adhesive are placed so that they are attached. In this way, LDPE adhesive is used for the skin layer so that it can be easily attached even with relatively low heat, and HDPE adhesive is used for the core layer to prevent the adhesive melted by heat from penetrating into the core and failing to exert adhesive force. By doing so, it is possible to improve the adhesion between the respective components.

sandwich panel

The sandwich panel according to the present invention is formed by sequentially stacking the skin layer 20 , the core layer 10 , and the skin layer 20 , and applying an adhesive layer between the core layer 10 and the skin layer 20 . is manufactured by After the above components are laminated, the curing and pressing steps may be performed, but the present invention is not limited thereto.

Specifically, the method for manufacturing a sandwich panel according to the present invention comprises:

a) preparing a non-woven fiber; b) manufacturing the core layer by performing a needle punching process on the nonwoven fiber at a number of punches per minute of 300 to 1000 times, a moving speed of 1 to 8 m/min of the nonwoven fabric, and a punching density of 100 to 500 punches/cm ^{2 ;} c) forming an adhesive layer on at least one surface of the core layer; and d) forming a skin layer on the adhesive layer.

Steps a) and b) are the same as the above-described method for manufacturing the core layer.

After that, in step c), an adhesive layer is formed on at least one surface of the core layer.

The adhesive constituting the adhesive layer may include at least one of an olefin-based adhesive, a urethane-based adhesive, an acrylic adhesive, and an epoxy-based adhesive. The olefin-based adhesive may be at least one selected from the group consisting of polyethylene, polypropylene, and amorphous polyalphaolefin adhesives. The urethane-based adhesive may be used without limitation as long as it is an adhesive including a urethane structure (-NH-CO-O-). The acrylic adhesive may include at least one of a polymethyl methacrylate adhesive, a hydroxyl group-containing polyacrylate adhesive, and a carboxy group-containing polyacrylate adhesive. The epoxy adhesive is bisphenol-A type epoxy adhesive, bisphenol-F type epoxy adhesive, novolac epoxy adhesive, linear aliphatic epoxy resins, and cycloaliphatic epoxy resins. may include

In addition, the adhesive may include a photocurable adhesive, a hot melt adhesive, or a thermosetting adhesive, and any one of a photocuring method and a thermosetting method may be used. For example, a sandwich panel can be manufactured by thermosetting a laminate including a skin layer, a core layer, and an adhesive. The thermosetting may be performed for about 5 minutes to 2 hours at 50 to 110° C., which is the curing temperature of the epoxy resin, and curing may be performed for about 1 to 10 hours even at room temperature.

The adhesive layer may be applied to a thickness of about 20 to 300 μm, but is not limited thereto.

As a method of applying the adhesive layer to one surface of the skin layer 20, any one method selected from among a die coating method, a gravure coating method, a knife coating method, and a spray coating method may be used.

Another adhesive used for the adhesive layer may include a first adhesive layer including high-density polyethylene (HDPE) and a second adhesive layer including low-density polyethylene (LDPE).

The high density polyethylene (HDPE) may have a density of 0.940 to 0.965 g/cm ³ , and the low density polyethylene (LDPE) may have a density of 0.910 to 0.925 g/cm ³ .

The adhesive constituting the adhesive layer is not particularly limited as long as it can form a first adhesive layer including high-density polyethylene (HDPE) and a second adhesive layer including low-density polyethylene (LDPE), but is preferably co-extruded using a film extruder to manufacture

The adhesive layer may be formed to a thickness of approximately 20 to 300 μm, and the first adhesive layer and the second adhesive layer may each have a thickness of 10 to 150 μm, but is not limited thereto, and the first adhesive layer and the second adhesive layer are not limited thereto. The thickness of the adhesive layer may be the same or different.

After that, in step d), a skin layer is formed on the adhesive layer.

The skin layer 20 of the sandwich panel according to the present invention may be formed of a metal material, and preferably any one selected from the group consisting of aluminum, iron, stainless steel (SUS), magnesium, and electrogalvanized steel sheet (EGI). It may include more than one. For example, in order to have excellent formability and flexural rigidity, the skin layer 20 including an electrogalvanized steel sheet (EGI) may be applied to the sandwich panel. In addition, the skin layer 20 including aluminum may be applied to the sandwich panel in order to reduce the weight.

In order to form the skin layer on the adhesive layer, any one of a photocuring method, a thermosetting method, and a thermocompression bonding method may be used. For example, a sandwich panel may be manufactured by thermosetting or thermocompression bonding a laminate including a skin layer, a core layer, and an adhesive.

The thermosetting may be performed for about 5 minutes to 2 hours at 50 to 110° C., which is the curing temperature of the epoxy resin, and curing may be performed for about 1 to 10 hours even at room temperature.

When the thermocompression bonding is performed using an adhesive including a first adhesive layer containing high-density polyethylene (HDPE) and a second adhesive layer containing low-density polyethylene (LDPE), a skin layer is placed on the adhesive layer, and then a skin layer, A sandwich panel can be manufactured by thermocompression bonding a laminate including a core layer and an adhesive. The thermocompression bonding may be performed at a pressure of 2 to 10 MPa at 150 to 200° C. for about 3 to 10 minutes.

At this time, the core layer and the high-density polyethylene (HDPE) adhesive are attached, and the skin layer and the low-density polyethylene (LDPE) adhesive are placed so that they are attached. In this way, LDPE adhesive is used for the skin layer so that it can be easily attached even with relatively low heat, and HDPE adhesive is used for the core layer to prevent the adhesive melted by heat from penetrating into the core and failing to exert adhesive force. By doing so, it is possible to improve the adhesion between the respective components.

The thickness of the skin layer 20 may be less than or equal to 6% of the thickness of the entire panel. The skin layer of the conventional sandwich panel had a problem in that the thickness of the skin layer had to be thick due to the low mechanical strength of the core material, thereby increasing the weight of the sandwich panel. As the strength is improved, the thickness of the skin layer can be set to 6% or less of the total thickness of the panel, and thus the weight can be reduced.

In addition, as the sandwich panel according to the present invention is manufactured by the above manufacturing method, the physical bonding force by needle punching is improved, and the physical properties of the core layer are improved. Specifically, the sandwich panel of the present invention improves the sound absorption performance of the panel, and the blocking effect of noise is improved. This may be 0.25 to 0.50, and preferably, the average value of the sound absorption coefficient at a frequency of 500 to 6500 Hz may be 0.28 to 0.40.

In addition, the sandwich panel of the present invention may have a sound absorption coefficient of 0.35 to 0.60 at a frequency of 1600 Hz, a sound absorption coefficient of 0.30 to 0.80 at a frequency of 2000 Hz, and a sound absorption coefficient of 0.30 to 0.60 at a frequency of 2500 Hz.

Therefore, the sandwich panel of the present invention can particularly improve the sound absorption performance at a low frequency of 2500 Hz or less.

The sound absorption coefficient can be measured in accordance with ASTM E1050, and the higher the sound absorption coefficient, the higher the blocking effect such as noise.

The characteristic of the sandwich panel of the present invention having the sound absorption coefficient as described above is that the physical bonding force is improved through the needle punching process during the manufacturing of the panel, so that the sound absorption performance of the panel is improved, and the effect of blocking noise is improved. can be

As described above, the sandwich panel according to the present invention has excellent formability as well as mechanical strength by using a core layer having good mechanical properties. In addition, the sound absorption performance of the panel has been improved, so structural materials for home appliances (TV back cover, washing machine board, etc.), interior and exterior boards for construction, interior and exterior materials for automobiles, interior and exterior materials for trains/ships/aircraft (boards such as partitions), and various partitions It is suitable for use as a board, elevator structural material, etc.

Hereinafter, preferred examples are presented to help the understanding of the present invention, but the following examples are merely illustrative of the present invention, and it will be apparent to those skilled in the art that various changes and modifications are possible within the scope and spirit of the present invention, It goes without saying that changes and modifications fall within the scope of the appended claims.

Example : Example 1 and comparative example 1 to 2

(1) Manufacture of sandwich panel

[Example 1]

Polyethylene terephthalate (PET) fiber (Toray Chemical, RPF, fineness of 4 denier, fiber length 51 mm) and sheath-core type PET fiber (Toray Chemical, EZBON-L, fineness of 4 denier, sheath) After preparing a secondary melting point of 164° C., a fiber length of 64 mm), they were mixed in a weight ratio of 30:70.

After mixing using the fibers and carding using a carding machine, the number of punches per minute is 500 times, the movement speed of the nonwoven fabric is 2 m/min, and the punching density is 200 punches/cm ² Through a needle punching process A nonwoven fabric having a basis weight of 1950 gsm was prepared.

After the non-woven fabric is mounted on two unwinding devices, the number of punches per minute is 500 times, the movement speed of the non-woven fabric is 2 m/min, and the needle punching process is repeated ^{at 200 punches/cm 2} a bond was formed.

The nonwoven fabric bonded by needle punching was preheated for 3 minutes after entering a preheating chamber having a chamber temperature of 180°C.

Then, the nonwoven fabric was transferred to a double belt press at a speed of 5 m/min. At this time, the heating temperature of the double belt press was 180° C. and the pressure was 5 MPa, and a 5.7 mm thick core layer was prepared by heating/pressing treatment for 2 minutes.

After applying an epoxy adhesive (Kukdo Chemical) to both sides of the prepared core layer, an aluminum skin layer (AL 3003) formed of an electrogalvanized steel sheet was formed to a thickness of 0.4 mm, and then the laminated result was heated at 100 ° C. It was cured to produce a sandwich panel.

[Comparative Example 1]

A 5.5 mm thick core layer was prepared using HDPE foam resin (LUTENE-H, LG Chem) with an extruder (Bautech, BA-11). (Manufacturing conditions: screw speed 40rpm, temperature 160℃)

After applying an epoxy adhesive (Kukdo Chemical) to both sides of the prepared core layer, a skin layer formed of an electro-galvanized steel sheet was formed to a thickness of 0.5 mm, and then the laminated result was thermally cured at 100° C. to form a sandwich panel. prepared.

[Comparative Example 2]

After mixing using the same fibers as in Example 1, carding was performed using a carding machine, and then thermal bonding was performed at a temperature of 190° C. for 10 seconds without a needle punching process to prepare a nonwoven fabric having a basis weight of 1300 gsm.

After the non-woven fabric was mounted on three unwinding devices, the three non-woven fabrics were put into a preheating chamber having a chamber temperature of 180° C., and then preheated for 3 minutes.

Then, the nonwoven fabric was transferred to a double belt press at a speed of 5 m/min. At this time, the heating temperature of the double belt press was 180° C. and the pressure was 5 MPa, and a 5.7 mm thick core layer was prepared by heating/pressing treatment for 2 minutes.

After applying an epoxy adhesive (Kukdo Chemical) to both sides of the prepared core layer, an aluminum skin layer (AL 3003) formed of an electrogalvanized steel sheet was formed to a thickness of 0.4 mm, and then the laminated result was heated at 100 ° C. It was cured to produce a sandwich panel.

Experimental example : Measurement of sound absorption properties of panels

1. How to measure the sound absorption properties of panels

After cutting the specimens of the sandwich panels of Examples 1 and Comparative Examples 1 and 2 prepared above into a circle having a diameter of 30 mm, using the in-pipe method (impedance tube measurement method) according to ASTM E1050, frequencies from 500 Hz to 6300 Hz The sound absorption coefficient was measured and shown in Table 1 and FIG. 2 below.

Frequency (Hz) sound absorption coefficient Example 1 Comparative Example 1 Comparative Example 2 500 0.34 0.13 0.21 630 0.22 0.19 0.20 800 0.28 0.16 0.18 1000 0.21 0.21 0.24 1250 0.32 0.36 0.35 1600 0.49 0.31 0.34 2000 0.59 0.19 0.28 2500 0.47 0.24 0.29 3150 0.37 0.23 0.27 4000 0.31 0.17 0.21 5000 0.22 0.15 0.20 6300 0.13 0.13 0.13 medium 0.329167 0.205833 0.241667

Referring to Table 1 and FIG. 2, in the case of the sandwich panel of Example 1, compared to the sandwich panel of Comparative Example 1, it was found that the average value of the sound absorption coefficient was improved by about 60%, and compared to the sandwich panel of Comparative Example 2 , it was found that the average value of the sound absorption coefficient improved by about 36%. In particular, it was found that the sound absorption performance at low frequencies below 2500 Hz is significantly superior.

These results are different from Comparative Example 1 using a foamable core layer or Comparative Example 2 without physical bonding by needle punching, Example 1 has a three-dimensional nonwoven fiber structure due to needle punching, so that the mechanical strength inside the core layer is As it becomes excellent, it can be seen that the sound absorption characteristics are improved.

10: core layer
20: skin layer

Claims (16)

a core layer of non-woven fibrous structure;
a skin layer laminated on at least one surface of the core layer; and
A panel comprising an adhesive layer for adhering the core layer and the skin layer,
The core layer is manufactured through a needle punching process of 300 to 1000 punches per minute, a moving speed of 1 to 8 m/min of nonwoven fabric, and a punching density of 100 to 500 punches/cm ^{2 ,}
When the sound absorption coefficient of the entire panel is measured by the impedance tube measurement method, the average value of the sound absorption coefficient at a frequency of 500 to 6500 Hz is 0.25 to 0.50,
The sound absorption coefficient of the frequency 1600 Hz is 0.35 to 0.60,
The sound absorption coefficient of the frequency 2000 Hz is 0.30 to 0.80,
A sandwich panel, having a sound absorption coefficient of 0.30 to 0.60 at a frequency of 2500 Hz. According to claim 1,
The nonwoven fiber structure is a sandwich panel that is adhered to a fiber aggregate on a web or a sheet with an adhesive, or by using a thermoplastic fiber. According to claim 1,
wherein the core layer is a non-foamed core. According to claim 1,
The average value of the absorption coefficient at a frequency of 500 to 6500 Hz is 0.28 to 0.40, a sandwich panel. delete delete delete According to claim 1,
The sound absorption coefficient measurement is a measurement method according to ASTM E1050, a sandwich panel. delete According to claim 1,
The core layer is manufactured by repeating the needle punching process two or more times, a sandwich panel. According to claim 1,
The core layer has a basis weight of 1000 to 2500 gsm, sandwich panel. According to claim 1,
The core layer, the polyester-based fiber core portion (core part); and a sheath part which is a non-hygroscopic copolymer resin surrounding the core part; and a sheath-core type including a bicomponent fiber. 13. The method of claim 12,
The polyester fiber is at least one selected from the group consisting of polyethylene terephthalate (PET), polytrimethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate, a sandwich panel. According to claim 1,
The skin layer is at least one selected from the group consisting of aluminum, iron, stainless steel (SUS), magnesium and electro-galvanized steel (EGI), a sandwich panel. According to claim 1,
The adhesive layer is a sandwich panel comprising at least one of an olefin-based adhesive, a urethane-based adhesive, an acrylic adhesive, and an epoxy-based adhesive. According to claim 1,
The adhesive layer comprises a first adhesive layer comprising high density polyethylene (HDPE) and a second adhesive layer comprising low density polyethylene (LDPE).

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