KR102269536B1 - Rubber composition having fire retardant and sound absorbing, and mat for reducing the floor noise comprising the same - Google Patents

Rubber composition having fire retardant and sound absorbing, and mat for reducing the floor noise comprising the same Download PDF

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KR102269536B1
KR102269536B1 KR1020180091463A KR20180091463A KR102269536B1 KR 102269536 B1 KR102269536 B1 KR 102269536B1 KR 1020180091463 A KR1020180091463 A KR 1020180091463A KR 20180091463 A KR20180091463 A KR 20180091463A KR 102269536 B1 KR102269536 B1 KR 102269536B1
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parts
rubber
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박영태
임종욱
이지훈
박지영
엄윤수
구민철
이정율
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주식회사 미요
엄윤수
주식회사 코스모소재
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
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    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
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    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
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    • C08L15/00Compositions of rubber derivatives
    • C08L15/02Rubber derivatives containing halogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
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    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00Fireproofing materials
    • C09K21/02Inorganic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/22All layers being foamed

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Abstract

본 발명은 난연성 및 흡음성을 모두 최고 등급 수준으로 만족하는 고무 조성물 및 이를 포함하는 난연성 층간소음 방지 매트에 관한 것으로, 본 발명에 따른 고무 조성물은 고무 베이스로서 저렴한 부틸고무, 난연제로서 수산화알미늄 및 염화파라핀, 및 발포제로서 ADCA(Azodicarbonamide)를 특정 함량비로 배합함에 따라서 난연성 및 흡음성을 모두 최고 수준 등급으로 만족하는 효과가 있다.The present invention relates to a rubber composition that satisfies both flame retardancy and sound absorption at the highest grade level, and a flame retardant interlayer noise prevention mat comprising the same. The rubber composition according to the present invention comprises inexpensive butyl rubber as a rubber base, aluminum hydroxide and chlorinated paraffin as a flame retardant. , and as a foaming agent, ADCA (Azodicarbonamide) is blended in a specific content ratio, thereby satisfying both flame retardancy and sound absorption at the highest level.

Description

난연성 및 흡음성 고무 조성물 및 이를 포함하는 층간소음 방지 매트{Rubber composition having fire retardant and sound absorbing, and mat for reducing the floor noise comprising the same}Flame retardant and sound-absorbing rubber composition and interlayer noise prevention mat comprising the same {Rubber composition having fire retardant and sound absorbing, and mat for reducing the floor noise comprising the same}

본 발명은 난연성 및 흡음성을 모두 최고 등급 수준으로 만족하는 고무 조성물 및 이를 포함하는 난연성 층간소음 방지 매트에 관한 것이다.The present invention relates to a rubber composition that satisfies both flame retardancy and sound absorption at the highest grade level, and a flame retardant interlayer noise prevention mat comprising the same.

현대의 주거형태인 아파트, 빌라 등의 복층건물에서는, 상층 거주자의 생활중 발생하는 충격음과 진동이 하층으로 고스란히 전달되어 상하층 주민 간에 분쟁이 야기될 수 있다. 이러한 이유로 유아나 어린이가 있는 가정에서는, 거실 등에 소정 크기의 매트를 깔아둠으로써, 아이가 뛰거나 장난칠 때 하층으로 전달되는 충격음과 진동을 어느 정도 방지함과 동시에 아이가 넘어질때 다치지 않도록 하고 있다.In multi-story buildings such as apartments and villas, which are modern residential types, shock sounds and vibrations generated during the lives of upper floors are transmitted to the lower floors, which can cause disputes between upper and lower floors. For this reason, in families with infants and children, by laying a mat of a predetermined size in the living room, etc., the impact sound and vibration transmitted to the lower floor when the child runs or plays are prevented to some extent, and the child is not injured when he falls. have.

이러한 종래의 매트는, 단층의 발포합성수지로 구성되거나, 발포합성수지층의 하면에 바닥층(고무 베이스)을 적층시켜 구성된 것이 대부분으로, 바닥층(고무 베이스)으로는 부틸고무(IIR, Isobutene-isoprene Rubber)가 주로 사용되고 있으나, 이는 충격음과 진동을 차단하는 효과가 기대에 미치지 못하여 상하층 주민 간의 분쟁가능성이 상존하게 된다.Most of these conventional mats are composed of a single layer of foamed synthetic resin, or are formed by laminating a bottom layer (rubber base) on the lower surface of the foamed resin layer, and the bottom layer (rubber base) is butyl rubber (IIR, Isobutene-isoprene Rubber). is mainly used, but the effect of blocking shock sounds and vibrations does not meet expectations, so the possibility of disputes between the upper and lower floors exists.

부틸고무(또는 이소부텐-이소프렌 고무(Isobutene-isoprene Rubber), IIR)는 대부분이 이소부텐이고 소량의 이소프렌을 함유한 공중합체이다. NR, SBR, BR, NBR과는 다르게 부틸고무는 단지 소량의 이중결합만 존재하는 아주 포화도가 높은 고무이다. 상기 소량의 불포화부분(이중결합)이 가황에 필요한 자리를 제공한다.Butyl rubber (or Isobutene-isoprene Rubber, IIR) is a copolymer containing mostly isobutene and a small amount of isoprene. Unlike NR, SBR, BR, and NBR, butyl rubber is a highly saturated rubber with only a small amount of double bonds. The small amount of unsaturation (double bond) provides a site necessary for vulcanization.

또한, 현재 시판중인 부틸고무를 고무 베이스로 사용한 층간소음 방지 매트는 대부분이 난연성 기준을 만족하지 못하여, 화재에 취약한 문제가 있다.In addition, most of the interlayer noise prevention mats using butyl rubber on the market as a rubber base do not satisfy flame retardancy standards, so there is a problem of being vulnerable to fire.

이에, 본 발명자는 고무 베이스로서 저렴한 부틸고무, 난연제로서 수산화알미늄 및 염화파라핀, 및 발포제로서 ADCA(Azodicarbonamide)를 특정 함량비로 배합한 고무 조성물이 난연성 및 흡음성을 모두 최고 수준 등급으로 만족함을 알아내고, 본 발명을 완성하였다.Accordingly, the present inventors found that a rubber composition containing inexpensive butyl rubber as a rubber base, aluminum hydroxide and chlorinated paraffin as a flame retardant, and ADCA (Azodicarbonamide) as a foaming agent in a specific content ratio satisfies both flame retardancy and sound absorption at the highest level, The present invention was completed.

등록특허 10-1765870호Registered Patent No. 10-1765870

본 발명의 목적은 난연성 및 흡음성 고무 조성물을 제공하는 것이다.It is an object of the present invention to provide a flame retardant and sound-absorbing rubber composition.

본 발명의 다른 목적은 상기 고무 조성물을 포함하는 난연성 흡음 매트를 제공하는 것이다.Another object of the present invention is to provide a flame-retardant sound-absorbing mat comprising the rubber composition.

본 발명의 또 다른 목적은 상기 고무 조성물을 포함하는 난연성 층간소음 방지 매트를 제공하는 것이다.Another object of the present invention is to provide a flame-retardant interlayer noise prevention mat comprising the rubber composition.

본 발명의 다른 목적은 상기 고무 조성물을 포함하는 난연성 방진재를 제공하는 것이다.Another object of the present invention is to provide a flame-retardant anti-vibration material comprising the rubber composition.

본 발명의 또 다른 목적은 상기 고무 조성물로 제조된 고무 베이스를 포함하는 난연성 흡음 매트를 제공하는 것이다.Another object of the present invention is to provide a flame-retardant sound-absorbing mat comprising a rubber base made of the rubber composition.

본 발명의 다른 목적은 상기 고무 조성물로 제조된 고무 베이스를 포함하는 난연성 층간소음 방지 매트를 제공하는 것이다.Another object of the present invention is to provide a flame-retardant interlayer noise prevention mat comprising a rubber base made of the rubber composition.

상기 목적을 달성하기 위하여,In order to achieve the above object,

본 발명은 고무 베이스로서 부틸고무 또는 할로겐화부틸고무 80 중량부 기준; 난연제로서 수산화알미늄 17-23 중량부; 난연제로서 염화파라핀 8-12 중량부; 및 발포제로서 ADCA(Azodicarbonamide) 0.15-0.35 중량부; 를 포함하는 난연성 및 흡음성 고무 조성물을 제공한다.The present invention is based on 80 parts by weight of butyl rubber or halogenated butyl rubber as a rubber base; 17-23 parts by weight of aluminum hydroxide as a flame retardant; 8-12 parts by weight of chlorinated paraffin as a flame retardant; and 0.15-0.35 parts by weight of ADCA (Azodicarbonamide) as a blowing agent; It provides a flame retardant and sound-absorbing rubber composition comprising a.

또한, 본 발명은 상기 고무 조성물을 포함하는 난연성 흡음 매트를 제공한다.In addition, the present invention provides a flame-retardant sound-absorbing mat comprising the rubber composition.

나아가, 본 발명은 상기 고무 조성물을 포함하는 난연성 층간소음 방지 매트를 제공한다.Furthermore, the present invention provides a flame-retardant interlayer noise prevention mat comprising the rubber composition.

또한, 본 발명은 상기 고무 조성물을 포함하는 난연성 방진재를 제공한다.In addition, the present invention provides a flame-retardant anti-vibration material comprising the rubber composition.

나아가, 본 발명은 연질 EVA(Ethylene Vinyl Acetate) 발포고무층; PU(polyurethane) 발포고무층; 경질 EVA(Ethylene Vinyl Acetate) 발포고무층; PU(polyurethane) 발포고무층; 및 본 발명에 따른 고무 조성물로 제조된 고무 베이스;가 순차적으로 적층된 것을 특징으로 하는 난연성 흡음 매트를 제공한다.Further, the present invention is a soft EVA (Ethylene Vinyl Acetate) foamed rubber layer; PU (polyurethane) foam rubber layer; Hard EVA (Ethylene Vinyl Acetate) foamed rubber layer; PU (polyurethane) foam rubber layer; And a rubber base made of the rubber composition according to the present invention; provides a flame-retardant sound-absorbing mat, characterized in that sequentially laminated.

또한, 본 발명은 연질 EVA(Ethylene Vinyl Acetate) 발포고무층; PU(polyurethane) 발포고무층; 경질 EVA(Ethylene Vinyl Acetate) 발포고무층; PU(polyurethane) 발포고무층; 및 본 발명에 따른 고무 조성물로 제조된 고무 베이스;가 순차적으로 적층된 것을 특징으로 하는 난연성 층간소음 방지 매트를 제공한다.In addition, the present invention is a soft EVA (Ethylene Vinyl Acetate) foamed rubber layer; PU (polyurethane) foam rubber layer; Hard EVA (Ethylene Vinyl Acetate) foamed rubber layer; PU (polyurethane) foam rubber layer; And a rubber base made of the rubber composition according to the present invention; provides a flame-retardant interlayer noise prevention mat, characterized in that sequentially laminated.

본 발명에 따른 고무 조성물은 고무 베이스로서 저렴한 부틸고무(또는 할로겐화부틸고무), 난연제로서 수산화알미늄 및 염화파라핀, 및 발포제로서 ADCA(Azodicarbonamide)를 특정 함량비로 배합함에 따라서 난연성 및 흡음성을 모두 최고 수준 등급으로 만족하는 효과가 있다.The rubber composition according to the present invention contains inexpensive butyl rubber (or halogenated butyl rubber) as a rubber base, aluminum hydroxide and chlorinated paraffin as a flame retardant, and ADCA (Azodicarbonamide) as a foaming agent in a specific content ratio. has a satisfactory effect.

도 1은 실시예 2에서 제조한 난연성 층간소음 방지 매트의 단면도이다.1 is a cross-sectional view of the flame-retardant interlayer noise prevention mat prepared in Example 2.

이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

난연성 및 flame retardant and 흡음성sound absorption 고무 조성물 rubber composition

본 발명은 고무 베이스로서 부틸고무 또는 할로겐화부틸고무 80 중량부 기준;The present invention is based on 80 parts by weight of butyl rubber or halogenated butyl rubber as a rubber base;

난연제로서 수산화알미늄 17-23 중량부;17-23 parts by weight of aluminum hydroxide as a flame retardant;

난연제로서 염화파라핀 8-12 중량부; 및8-12 parts by weight of chlorinated paraffin as a flame retardant; and

발포제로서 ADCA(Azodicarbonamide) 0.15-0.35 중량부;0.15-0.35 parts by weight of ADCA (Azodicarbonamide) as a blowing agent;

를 포함하는 난연성 및 흡음성 고무 조성물을 제공한다.It provides a flame retardant and sound-absorbing rubber composition comprising a.

본 발명에 따른 난연성 및 흡음성 고무 조성물은 EPDM(Ethylene Propylene Diene Monomer), 천연고무, 무기충전재, 프로세스 오일, 산화아연, 스테아린산, 계면활성제, 광차단제, 가공조제, 노화방지제, 산화방지제, 가황제 및 가황촉진제로 이루어진 군으로부터 선택되는 1종 이상의 첨가제를 더 포함할 수 있다.The flame-retardant and sound-absorbing rubber composition according to the present invention is EPDM (Ethylene Propylene Diene Monomer), natural rubber, inorganic filler, process oil, zinc oxide, stearic acid, surfactant, light blocking agent, processing aid, antioxidant, antioxidant, vulcanizing agent and At least one additive selected from the group consisting of vulcanization accelerators may be further included.

본 발명에 따른 고무 조성물에 있어서, 부틸고무 또는 할로겐화부틸고무 80 중량부 기준으로,In the rubber composition according to the present invention, based on 80 parts by weight of butyl rubber or halogenated butyl rubber,

수산화알미늄 17 중량부 미만 또는 23 중량부 초과일 경우 난연성 및 흡음성이 저하되는 문제가 있고,When the amount of aluminum hydroxide is less than 17 parts by weight or more than 23 parts by weight, there is a problem in that flame retardancy and sound absorption are lowered,

염화파리핀 8 중량부 미만 또는 12 중량부 초과일 경우 난연성 및 흡음성이 저하되는 문제가 있으며,When the amount of paraffin chloride is less than 8 parts by weight or more than 12 parts by weight, there is a problem in that flame retardancy and sound absorption are lowered,

발포제로서 ADCA(Azodicarbonamide) 0.15 중량부 미만일 경우 흠음성이 저하되는 문제가 있고 0.35 중량부 초과일 경우 난연성이 저하되는 문제가 있다.When the amount of ADCA (Azodicarbonamide) as a foaming agent is less than 0.15 parts by weight, there is a problem that the sound quality is lowered, and when it is more than 0.35 parts by weight, there is a problem that the flame retardancy is reduced.

바람직하게,Preferably,

상기 고무 베이스로서 부틸고무 또는 할로겐화부틸고무 80 중량부 기준;Based on 80 parts by weight of butyl rubber or halogenated butyl rubber as the rubber base;

난연제로서 수산화알미늄 18.5-21.5 중량부;18.5-21.5 parts by weight of aluminum hydroxide as a flame retardant;

난연제로서 염화파라핀 9-11 중량부; 및9-11 parts by weight of chlorinated paraffin as a flame retardant; and

발포제로서 ADCA(Azodicarbonamide) 0.2-0.3 중량부;0.2-0.3 parts by weight of ADCA (Azodicarbonamide) as a blowing agent;

를 포함할 수 있다.may include.

더욱 바람직하게,More preferably,

상기 고무 베이스로서 부틸고무 또는 할로겐화부틸고무 80 중량부 기준;Based on 80 parts by weight of butyl rubber or halogenated butyl rubber as the rubber base;

난연제로서 수산화알미늄 18.5-21.5 중량부;18.5-21.5 parts by weight of aluminum hydroxide as a flame retardant;

난연제로서 염화파라핀 9-11 중량부;9-11 parts by weight of chlorinated paraffin as a flame retardant;

발포제로서 ADCA(Azodicarbonamide) 0.2-0.3 중량부;0.2-0.3 parts by weight of ADCA (Azodicarbonamide) as a blowing agent;

EPDM(Ethylene Propylene Diene Monomer) 14.5-15.5 중량부;EPDM (Ethylene Propylene Diene Monomer) 14.5-15.5 parts by weight;

천연고무 4.5-5.5 중량부;4.5-5.5 parts by weight of natural rubber;

무기충전재로서 실리카 43-47 중량부;43-47 parts by weight of silica as an inorganic filler;

무기충전재로서 카본 0.15-0.25 중량부;0.15-0.25 parts by weight of carbon as an inorganic filler;

무기충전재로서 탄산칼슘 28-32 중량부;28-32 parts by weight of calcium carbonate as an inorganic filler;

프로세스 오일 10-14 중량부;10-14 parts by weight of process oil;

산화아연 6-8 중량부;6-8 parts by weight of zinc oxide;

스테아린산 1-2 중량부;1-2 parts by weight of stearic acid;

PEG-4000 1-2 중량부;PEG-4000 1-2 parts by weight;

이산화티타늄 9-11 중량부;9-11 parts by weight of titanium dioxide;

가공조제 1-2 중량부;1-2 parts by weight of processing aid;

노화방지제 1-2 중량부;1-2 parts by weight of an antioxidant;

산화방지제 1.5-2.5 중량부;1.5-2.5 parts by weight of antioxidant;

가황제 1.0-1.4 중량부; 및1.0-1.4 parts by weight of a vulcanizing agent; and

가황촉진제(브루밍 방지제) 5-6 중량부;를 포함할 수 있다.5-6 parts by weight of a vulcanization accelerator (anti-bruising agent); may be included.

본 발명에 따른 고무 조성물에 있어서,In the rubber composition according to the present invention,

상기 '부틸고무'는 고무 베이스 및 흡음재 역할을 하고,The 'butyl rubber' serves as a rubber base and sound absorbing material,

상기 '난연제'는 난연성을 부여하는 역할을 하며,The 'flame retardant' serves to impart flame retardancy,

상기 '발포제'는 고무 베이스 무게 저감 및 흡음 보조 역할을 한다.The 'foaming agent' serves to reduce the weight of the rubber base and assist in sound absorption.

본 발명에서는 '난연제'가 난연성에만 영향을 미치는 것이 아니라 함량에 따라서 흡음성에도 영향을 미치는 점과, '발포제'가 고무 베이스에 기포를 발생시켜 무게를 저감하는 본연의 효과 이외에 함량에 따라서 흡음성뿐만 아니라 난연성에도 영향을 미치는 점을 알아낸 점에 기술적 특징이 있다.In the present invention, the 'flame retardant' not only affects the flame retardancy, but also affects the sound absorption according to the content, and the 'foaming agent' generates bubbles in the rubber base to reduce the weight. There is a technical feature in the point that it also affects the flame retardancy.

매트 및 mat and 방진재anti-vibration material

본 발명은 상기 난연성 및 흡음성 고무 조성물을 포함하는 난연성 흡음 매트, 난연성 층간소음 방지 매트, 난연성 방진재 등을 제공한다.The present invention provides a flame-retardant sound-absorbing mat, a flame-retardant interlayer noise prevention mat, a flame-retardant anti-vibration material, and the like, comprising the flame-retardant and sound-absorbing rubber composition.

또한, 본 발명은 연질 EVA(Ethylene Vinyl Acetate) 발포고무층;In addition, the present invention is a soft EVA (Ethylene Vinyl Acetate) foamed rubber layer;

PU(polyurethane) 발포고무층;PU (polyurethane) foam rubber layer;

경질 EVA(Ethylene Vinyl Acetate) 발포고무층;Hard EVA (Ethylene Vinyl Acetate) foamed rubber layer;

PU(polyurethane) 발포고무층; 및PU (polyurethane) foam rubber layer; and

본 발명에 따른 고무 조성물로 제조된 고무 베이스;가 순차적으로 적층된 것을 특징으로 하는 난연성 흡음 매트, 또는 난연성 층간소음 방지 매트를 제공한다.It provides a flame-retardant sound-absorbing mat, or a flame-retardant interlayer noise prevention mat, characterized in that the rubber base made of the rubber composition according to the present invention is sequentially laminated.

본 발명에 따른 매트에 있어서, 상기 연질 EVA 발포고무층의 비중은 0.65-0.75일 수 있고, 상기 경질 EVA 발포고무층의 비중은 1.1-1.2일 수 있다. 구체적으로, 상기 연질 EVA 발포고무층은 매트의 최상층에 적층되므로 부드러운 성질이 필요하고, 상기 경질 EVA 발포고무층은 매트의 중간에 삽입되므로 매트 형상을 유지하기 위해 단단한 성질이 필요하다.In the mat according to the present invention, the specific gravity of the soft EVA foamed rubber layer may be 0.65-0.75, and the specific gravity of the rigid EVA foamed rubber layer may be 1.1-1.2. Specifically, since the soft EVA foamed rubber layer is laminated on the top layer of the mat, soft properties are required, and the hard EVA foamed rubber layer is inserted in the middle of the mat, so it needs hard properties to maintain the mat shape.

본 발명에 따른 매트에 있어서, 상기 PU 발포고무층의 비중은 0.2-0.3일 수 있다. 구체적으로, PU 발포고무층은 충격을 흡수해주는 역할을 한다.In the mat according to the present invention, the specific gravity of the PU foamed rubber layer may be 0.2-0.3. Specifically, the PU foamed rubber layer serves to absorb the impact.

이하, 본 발명을 하기의 실시예에 의하여 더욱 상세하게 설명한다. 단, 하기의 실시예는 본 발명을 예시하는 것일 뿐, 본 발명의 내용이 하기의 실시예에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the following examples are merely illustrative of the present invention, and the content of the present invention is not limited by the following examples.

<< 실시예Example 1> 난연성 및 1> Flame retardant and 흡음성sound absorption 테스트용 '고무 베이스'의 제조 Manufacture of 'rubber base' for testing

하기 표 1의 조성으로,With the composition of Table 1 below,

니더(KNEADER) 장치에 부틸고무, EPDM, 천연고무를 넣어 70-90℃의 범위 이내의 온도에서 15-20분 소련 단계를 거친 다음, 무기충전재, 난연제 및 첨가제(하기 표 1에서 6-14번의 성분)를 투입하여 약 130-200초 범위 내에서 혼련작업을 실시하였다.Put butyl rubber, EPDM, and natural rubber in a kneader device and pass through the USSR step for 15-20 minutes at a temperature within the range of 70-90 ° C. Then, inorganic fillers, flame retardants and additives ( ingredients) and kneading was carried out within the range of about 130-200 seconds.

다음으로, 18인치 로라(Roller) 장치에서 가황제, 촉진제(브루밍 방지제), ADCA(Azodicarbonamide) 발포제를 투입하여, 로라 온도 60-70℃에서 약 15분 정도 내림 작업후 두께10mm*폭300mm*길이1000mm의 시트형태로 만들었다. 만든 시트는 18-20℃의 고무숙성실에서 6-10시간 숙성작업을 마치고, 목적에 맞는 크기로 재단하고, 목적에 맞는 모양으로 성형 프레스 작업하여 사용하였다.Next, a vulcanizing agent, accelerator (anti-bruising agent), and ADCA (Azodicarbonamide) foaming agent are added in an 18-inch roller device, and lowered for about 15 minutes at a roller temperature of 60-70°C. After working, thickness 10mm*width 300mm* It was made in the form of a sheet with a length of 1000 mm. The prepared sheet was aged for 6-10 hours in a rubber aging room at 18-20 ° C, cut to a size suitable for the purpose, and molded and pressed into a shape suitable for the purpose.

난연성 테스트용 샘플은 130×13×2 mm 크기로 재단하였고,The sample for the flame retardancy test was cut to 130×13×2 mm size

흡음성 테스트용 샘플은 250×250×10 mm 크기로 재단하였다.The sample for the sound absorption test was cut to a size of 250 × 250 × 10 mm.

성분명Ingredient name 함량
(중량부)
content
(parts by weight)
기능 또는 역할function or role
1One 부틸고무butyl rubber 8080 고무 베이스 및 흡음 역할 Rubber base and sound absorption role 22 EPDM
(Ethylene Propylene Diene Monomer)
EPDM
(Ethylene Propylene Diene Monomer)
1515 부틸고무의 물성 보완 역할The role of complementing the physical properties of butyl rubber
33 천연고무natural rubber 55 고무 베이스의 미끄럼 방지Non-slip rubber base 44 실리카silica 4545 무기충전재(부형제 역할)Inorganic filler (the role of excipient) 55 카본(흑연)Carbon (Graphite) 0.20.2 무기충전재(부형제 역할)Inorganic filler (the role of excipient) 66 프로세스오일
(CAS no. 64742-65-0; 제조사: (주)이득; 제품명: P-4)
process oil
(CAS no. 64742-65-0; Manufacturer: Gain Co., Ltd.; Product name: P-4)
1212 용매 역할solvent role
77 탄산칼슘calcium carbonate 3030 무기충전재(부형제 역할)Inorganic filler (the role of excipient) 88 산화아연zinc oxide 77 가교 보조제crosslinking aid 99 스테아린산stearic acid 1.51.5 가교 보조제crosslinking aid 1010 PEG-4000
(CAS no. 25322-68-3; 제조사: ICI Surfactants, 영국)
PEG-4000
(CAS no. 25322-68-3; Manufacturer: ICI Surfactants, UK)
1.51.5 계면활성제(무기충전재와 고무 성분의 혼합 보조 역할)Surfactant (Auxiliary role of mixing inorganic fillers and rubber components)
1111 이산화티타늄(TiO2)Titanium dioxide (TiO 2 ) 1010 고무 베이스 색 보존Preserve rubber base color 1212 가공조제
(제조사: STRUKTOL, 독일; 제품명: FL)
processing aid
(Manufacturer: STRUKTOL, Germany; Product name: FL)
1.51.5 고무성분 혼합에 도움 역할Helps in mixing rubber components
1313 파라핀왁스
(제조사: (주)대운; 제품명: SUNOC#150)
paraffin wax
(Manufacturer: Daewoon Co., Ltd.; Product name: SUNOC#150)
1.51.5 노화방지제(광차단 역할)Anti-aging agent (light blocking role)
1414 BHT(Butylated Hydroxy Toluene)Butylated Hydroxy Toluene (BHT) 22 산화방지제(곰팡이 예방 역할)Antioxidants (to prevent mold) 1515 ADCA(Azodicarbonamide)ADCA (Azodicarbonamide) 0.250.25 발포제(무게 감소 및 흡음 보완 역할) Foaming agent (reducing weight and complementing sound absorption) 1616 수산화알미늄aluminum hydroxide 2020 난연제flame retardant 1717 염화파라핀Chlorinated paraffin 1010 난연제flame retardant 1818 황(sulfur)sulfur 1.21.2 가황제(고무성분 가교 역할)Vulcanizing agent (crosslinking rubber component) 1919 N-Cyclohexyl-2-benzothiazolylsulfenamide (CAS no.: 95-33-0)N-Cyclohexyl-2-benzothiazolylsulfenamide (CAS no.: 95-33-0) 1One 가황촉진제(완성품에서 약물이 베어 나오는 브루밍 현상 방지 역할)Vulcanization accelerator (acting to prevent bruising from bleeding out of the finished product) 2020 2,2'-Dithiobis(benzothiazole) (CAS no.: 120-78-5)2,2'-Dithiobis(benzothiazole) (CAS no.: 120-78-5) 1.51.5 가황촉진제(완성품에서 약물이 베어 나오는 브루밍 현상 방지 역할)Vulcanization accelerator (acting to prevent bruising from bleeding out of the finished product) 2121 Bis(dimethylthiocarbamoyl) disulfide (CAS no.: 137-26-8)Bis(dimethylthiocarbamoyl) disulfide (CAS no.: 137-26-8) 1.51.5 가황촉진제(완성품에서 약물이 베어 나오는 브루밍 현상 방지 역할)Vulcanization accelerator (acting to prevent bruising from bleeding out of the finished product) 2222 Zinc(II) Dibutyldithiocarbamate (CAS no.: 136-23-2)Zinc(II) Dibutyldithiocarbamate (CAS no.: 136-23-2) 1.51.5 가황촉진제(완성품에서 약물이 베어 나오는 브루밍 현상 방지 역할)Vulcanization accelerator (acting to prevent bruising from bleeding out of the finished product)

하기 표 3의 실시예 1-1 내지 실시예 3-5에서 제조한 샘플들은, The samples prepared in Examples 1-1 to 3-5 of Table 3 below are,

고무 베이스로서 '부틸고무','Butyl rubber' as a rubber base,

제1난연제로서 '수산화알미늄','Aluminum hydroxide' as the first flame retardant,

제2난연제로서 '염화파라핀','Chlorinated paraffin' as a second flame retardant,

발포제로서 'ADCA(Azodicarbonamide)'를 제외한 나머지 첨가제의 함량은 상기 표 1에 기재된 것과 동일하게 사용하였다.The content of the remaining additives except for 'ADCA (Azodicarbonamide)' as a foaming agent was used in the same manner as described in Table 1 above.

<< 실시예Example 2> 난연성 층간소음 방지 매트의 제조 2> Manufacture of flame retardant interlayer noise prevention mat

연질 EVA(Ethylene Vinyl Acetate) 발포고무층 <비중 0.7>;Soft EVA (Ethylene Vinyl Acetate) foam layer <specific gravity 0.7>;

PU(polyurethane) 발포고무층 <비중 0.25>;PU (polyurethane) foamed rubber layer <specific gravity 0.25>;

경질 EVA(Ethylene Vinyl Acetate) 발포고무층 <비중 1.15>;Hard EVA (Ethylene Vinyl Acetate) foam layer <specific gravity 1.15>;

PU(polyurethane) 발포고무층 <비중 0.25>; 및PU (polyurethane) foamed rubber layer <specific gravity 0.25>; and

실시예 1의 고무 조성물로 제조된 고무 베이스;를 순차적으로 적층하고, 접착공정을 통해 매트를 제조하였다.A rubber base prepared from the rubber composition of Example 1 was sequentially laminated, and a mat was prepared through an adhesion process.

여기서, 각층의 두께는 고무 베이스 10mm를 제외하고는 모두 5mm이다.Here, the thickness of each layer is 5 mm except for the rubber base 10 mm.

도 1은 실시예 2에서 제조한 난연성 층간소음 방지 매트의 단면도이다.1 is a cross-sectional view of the flame-retardant interlayer noise prevention mat prepared in Example 2.

<< 실험예Experimental example 1> 난연성 및 1> Flame retardant and 흡음성sound absorption 평가 evaluation

난연성 평가 방법Flame retardant evaluation method

난연성 평가는 실시예 1에서 제조한 125×13×10 mm 크기의 고무 베이스를 난연성 테스트용 샘플로 하여 한국건설생활환경시험연구원에서 사용하고 있는 'UL 94 V (Vertical Burning Test)' 평가방법을 사용하였고, 그 결과를 하기 표 3에 나타내었다.For the flame retardancy evaluation, the 'UL 94 V (Vertical Burning Test)' evaluation method used by the Korea Institute of Construction and Living Environment Test using the 125 × 13 × 10 mm size rubber base prepared in Example 1 as a flame retardant test sample was used. and the results are shown in Table 3 below.

구체적으로, UL 94 V 난연성 평가는 플라스틱 제품의 수직 방향으로 불꽃을 가했을 때, 제품의 연소 양상 및 주위로의 화염 전파 정도를 평가하는 것으로, 시편은 130×13×2 mm 크기로 실시하고, 20 mm 길이의 불꽃을 10초간 시편에 접염 후, 시편의 연소 시간 t1 측정 및 연소 양상을 기록한다. 1차 접염 후 연소가 종료되면, 다시 10초간 접염 후 시편의 연소시간 t2 및 불똥이 맺힌 시간(glowing time) t3을 측정하고, 연소 양상을 기록한다. 마지막으로, t1, t2, t3의 연소시간 및 연소 양상(적하에 의한 탈지면 발화 여부, 클램프까지의 연소 여부 등)을 판단하여, 등급을 V-0(최고 등급), V-1, V-2 등급으로 산출한다.Specifically, the UL 94 V flame retardancy evaluation is to evaluate the combustion aspect of the product and the degree of flame propagation to the surroundings when a flame is applied in the vertical direction of the plastic product, and the specimen is carried out with a size of 130 × 13 × 2 mm, 20 After contacting the specimen with a flame of mm length for 10 seconds, measure the combustion time t1 of the specimen and record the combustion pattern. When the combustion is finished after the first contact, the combustion time t2 and the glowing time t3 of the specimen after contacting for 10 seconds are measured, and the combustion pattern is recorded. Finally, by determining the combustion time and combustion pattern of t1, t2, and t3 (whether or not the cotton wool ignites by dripping, whether it burns up to the clamp, etc.), the grade is set to V-0 (highest grade), V-1, V-2. calculated by grade.

평가기준은 하기 표 2와 같이, 시편의 연소시간 t1, t2, t3 및 연소 양상에 따라 등급을 부여한다.As shown in Table 2 below, the evaluation criteria are graded according to the combustion time t1, t2, t3 and the combustion pattern of the specimen.

평가 방법Assessment Methods V-0V-0 V-1V-1 V-2V-2 개별 연소 시간 (t1 또는 t2)Individual burn time (t1 or t2) ≤10초≤10 seconds ≤30초≤30 seconds ≤30초≤30 seconds 전처리 조건 별 전체 연소시간 (t1+t2)Total combustion time by pretreatment condition (t1+t2) ≤50초≤50 seconds ≤250초≤250 seconds ≤250초≤250 seconds 2차 접염 후의 연소 및 불똥이 맺힌 시간 (t2+t3)Combustion and spark formation time after secondary contact (t2+t3) ≤30초≤30 seconds ≤60초≤60 seconds ≤60초≤60 seconds 클램프(125mm 표시)까지의 연소 여부Burning up to the clamp (125mm mark) NoNo NoNo NoNo 불똥 적하에 의한 탈지면의 발화Ignition of cotton wool by spark drop NoNo NoNo YesYes

흡음성sound absorption (충격음 감소) 평가 방법(Shock Sound Reduction) Evaluation Method

흡음성 평가는 실시예 2에서 제조한 난연성 층간소음방지 매트를 흡음성 테스트용 샘플로 하여 한국건설생활환경시험연구원에서 사용하고 있는 'KS F2865:2015(바닥 표면 마감재의 경량 및 중량충격음 저감량 실험실 측정방법)'의 시험방법으로 바닥충격음레벨 저감량을 측정하였고, 그 결과를 하기 표 3에 나타내었다.Sound absorption evaluation is 'KS F2865:2015 (laboratory measurement method for light weight and weight impact sound reduction of floor surface finishing materials), which is used by the Korea Construction Living Environment Testing Institute using the flame-retardant interlayer noise prevention mat prepared in Example 2 as a sound absorption test sample. The amount of floor impact sound level reduction was measured by the test method of ', and the results are shown in Table 3 below.

구체적으로, 수음실 용적은 57.02m2이고, 철근콘크리트구조물 샘플[슬래브두께 210mm; 벽두께 250mm; 형상: 직방형6면체(ISO 10140-5 Type)]에 실시예 2에서 제조한 난연성 층간소음방지 매트를 시공한 전후에, 다양한 충격(100, 125, 160, 200, 250, 315, 400, 500, 630, 800, 1000, 1250, 1600, 2000, 2500, 3150 Hz)을 가하여 전달되는 충격음 평균 감소량(dB) 및 평균 감소율(%)을 측정한 결과를 하기 표 3에 나타내었다.Specifically, the volume of the collection room is 57.02m 2 , and the reinforced concrete structure sample [slab thickness 210mm; wall thickness 250mm; Shape: Rectangular hexahedron (ISO 10140-5 Type)] before and after installing the flame-retardant interlayer noise prevention mat prepared in Example 2, various impacts (100, 125, 160, 200, 250, 315, 400, 500 , 630, 800, 1000, 1250, 1600, 2000, 2500, 3150 Hz) and the average reduction (dB) and average reduction rate (%) of the transmitted impact sound were measured and the results are shown in Table 3 below.

참조로, 충격음 평균 감소율이 60%를 초과하는 제품은 흡음성(차음성) 최고 등급 "S급", 55-60%에 해당하는 제품은 "A급", 55% 미만에 해당하는 제품은 "B급"으로 분류하였다.For reference, products with an average impact sound reduction rate exceeding 60% are “Class S” for sound absorption (sound insulation), “Class A” for products with 55-60%, and “B” for products with less than 55%. class".

구성 성분 함Žc (중량부)Ingredients Included (parts by weight) 난연성 등급Flame-retardant grade 충격음shock sound 부틸고무butyl rubber 난연제flame retardant 발포제blowing agent 수산화알미늄aluminum hydroxide 염화파라핀Chlorinated paraffin ADCA(Azodicarbonamide)ADCA (Azodicarbonamide) 평균 감소량average decrease 평균 감소율average rate of decline 실시예
1-1
Example
1-1
8080 1717 1010 0.250.25 V-1V-1 35.8dB35.8dB A급
57.1%
Class A
57.1%
실시예
1-2
Example
1-2
8080 18.518.5 1010 0.250.25 V-0V-0 37.8dB37.8dB S급
60.2%
S class
60.2%
실시예
1-3
Example
1-3
8080 2020 1010 0.250.25 V-0V-0 38.4dB38.4dB S급
61.2%
S class
61.2%
실시예
1-4
Example
1-4
8080 21.521.5 1010 0.250.25 V-0V-0 38.2dB38.2dB S급
60.9%
S class
60.9%
실시예
1-5
Example
1-5
8080 2323 1010 0.250.25 V-1V-1 34.9dB34.9dB A급
55.6%
Class A
55.6%
실시예
2-1
Example
2-1
8080 2020 88 0.250.25 V-1V-1 35.9dB35.9 dB A급
57.2%
Class A
57.2%
실시예
2-2
Example
2-2
8080 2020 99 0.250.25 V-0V-0 38.0dB38.0dB S급
60.6%
S class
60.6%
실시예
2-3
Example
2-3
8080 2020 1010 0.250.25 V-0V-0 38.4dB38.4dB S급
61.2%
S class
61.2%
실시예
2-4
Example
2-4
8080 2020 1111 0.250.25 V-0V-0 37.9dB37.9dB S급
60.4%
S class
60.4%
실시예
2-5
Example
2-5
8080 2020 1212 0.250.25 V-1V-1 35.0dB35.0dB A급
55.8%
Class A
55.8%
실시예
3-1
Example
3-1
8080 2020 1010 0.150.15 V-0V-0 34.1dB34.1dB B급
54.3%
Class B
54.3%
실시예
3-2
Example
3-2
8080 2020 1010 0.200.20 V-0V-0 37.9dB37.9dB S급
60.4%
S class
60.4%
실시예
3-3
Example
3-3
8080 2020 1010 0.250.25 V-0V-0 38.4dB38.4dB S급
61.2%
S class
61.2%
실시예
3-4
Example
3-4
8080 2020 1010 0.300.30 V-0V-0 38.5dB38.5dB S급
61.4%
S class
61.4%
실시예
3-5
Example
3-5
8080 2020 1010 0.350.35 V-2V-2 38.9dB38.9 dB S급
62.0%
S class
62.0%

표 3에 나타난 바와 같이, 1)부틸고무, 2)난연제(수산화알루미늄 및 염화파라핀), 및 3)발포제의 함량은 고무 베이스 샘플의 난연성 및 흡음성에 중요한 인자인 것으로 확인되었고, 실시예 1-1 내지 실시예 3-5 중에서 난연성 'V-0 등급'과 충격음 평균 감소율 'S급'을 동시에 만족하는 샘플은 특정 함량비에서만 나타나 임계적 의의가 있음을 알 수 있었다.As shown in Table 3, the contents of 1) butyl rubber, 2) flame retardants (aluminum hydroxide and chlorinated paraffin), and 3) blowing agent were confirmed to be important factors for flame retardancy and sound absorption of the rubber base sample, Example 1-1 In Examples 3-5, the samples satisfying both the flame retardancy 'V-0 grade' and the average impact sound reduction rate 'S grade' appeared only at a specific content ratio, indicating that there is a critical significance.

<< 실험예Experimental example 2> 인체 유해성 평가 2> Human Hazard Assessment

실시예 1에서 제조한 고무 베이스의 인체 유해성을 알아보기 위하여 다음과 같이 실험하였다. 구체적으로, 한국건설생활환경시험연구원에 인체 유해성 평가를 의뢰하였고, 그 결과를 하기 표 4에 나타내었다.In order to find out the harmfulness of the rubber base prepared in Example 1 to the human body, an experiment was conducted as follows. Specifically, a human hazard evaluation was requested from the Korea Institute of Construction and Living Environment, and the results are shown in Table 4 below.

시험항목Test Items 단위unit 시험방법Test Methods 시험결과Test result Polybrominated Biphenyls(PBBs)Polybrominated Biphenyls (PBBs) -- -- -- 1One BromobiphenylBromobiphenyl mg/kgmg/kg (1)(One) 불검출non-detection 22 DibromobiphenylDibromobiphenyl 불검출non-detection 33 TribromobiphenylTribromobiphenyl 불검출non-detection 44 TetrabromobiphenylTetrabromobiphenyl 불검출non-detection 55 PentabromobiphenylPentabromobiphenyl 불검출non-detection 66 HexabromobiphenylHexabromobiphenyl 불검출non-detection 77 HeptabromobiphenylHeptabromobiphenyl 불검출non-detection 88 OctabromobiphenylOctabromobiphenyl 불검출non-detection 99 NonabromobiphenylNonabromobiphenyl 불검출non-detection 1010 DecabromobiphenylDecabromobiphenyl 불검출non-detection Polybrominated Diphenyl Ethers(PBDEs)Polybrominated Diphenyl Ethers (PBDEs) -- -- -- 1111 Bromodiphenyl etherBromodiphenyl ether mg/kgmg/kg (1)(One) 불검출non-detection 1212 Dibromodiphenyl etherDibromodiphenyl ether 불검출non-detection 1313 Tribromodiphenyl etherTribromodiphenyl ether 불검출non-detection 1414 Trtrabromodiphenyl etherTrtrabromodiphenyl ether 불검출non-detection 1515 Pentabromodiphenyl etherPentabromodiphenyl ether 불검출non-detection 1616 Hexabromodiphenyl etherHexabromodiphenyl ether 불검출non-detection 1717 Heptabromodiphenyl etherHeptabromodiphenyl ether 불검출non-detection 1818 Octabromodiphenyl etherOctabromodiphenyl ether 불검출non-detection 1919 Nonabromodiphenyl etherNonabromodiphenyl ether 불검출non-detection 2020 Decabromodiphenyl etherDecabromodiphenyl ether 불검출non-detection 2121 납 (Pb)Lead (Pb) (2)(2) 불검출non-detection 2222 카드뮴 (Cd)Cadmium (Cd) (2)(2) 불검출non-detection 2323 수은 (Hg)Mercury (Hg) (3)(3) 불검출non-detection 2424 6가 크로뮴 (Cr6 +)Hexavalent Chromium (Cr 6 + ) (4)(4) 불검출non-detection (1) IEC 62321-6:2015
(2) IEC 62321-5:2013
(3) IEC 62321-4:2013
(4) IEC 62321-7-2:2017
(1) IEC 62321-6:2015
(2) IEC 62321-5:2013
(3) IEC 62321-4:2013
(4) IEC 62321-7-2:2017

상기 표 4에 나타난 바와 같이, 실시예 1에서 제조한 고무 베이스는 어떠한 인체 유해성 물질도 검출되지 않아 안전한 것을 알 수 있었다.As shown in Table 4, it was found that the rubber base prepared in Example 1 was safe because no substances harmful to the human body were detected.

이제까지 본 발명에 대하여 그 바람직한 실시예들을 중심으로 살펴보았다. 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자는 본 발명이 본 발명의 본질적인 특성에서 벗어나지 않는 범위에서 변형된 형태로 구현될 수 있음을 이해할 수 있을 것이다. 그러므로 개시된 실시예들은 한정적인 관점이 아니라 설명적인 관점에서 고려되어야 한다. 본 발명의 범위는 전술한 설명이 아니라 특히 청구범위에 나타나 있으며, 그와 동등한 범위 내에 있는 모든 차이점은 본 발명에 포함된 것으로 해석되어야 할 것이다.So far, with respect to the present invention, the preferred embodiments have been looked at. Those of ordinary skill in the art to which the present invention pertains will understand that the present invention can be implemented in a modified form without departing from the essential characteristics of the present invention. Therefore, the disclosed embodiments are to be considered in an illustrative rather than a restrictive sense. The scope of the present invention is indicated not in the foregoing description, but in particular in the claims, and all differences within the scope equivalent thereto should be construed as included in the present invention.

Claims (13)

고무 베이스로서 부틸고무 80 중량부 기준;
난연제로서 수산화알미늄 18.5-21.5 중량부;
난연제로서 염화파라핀 9-11 중량부; 및
발포제로서 ADCA(Azodicarbonamide) 0.2-0.3 중량부;
를 포함하는 난연성 및 흡음성 고무 조성물.
Based on 80 parts by weight of butyl rubber as a rubber base;
18.5-21.5 parts by weight of aluminum hydroxide as a flame retardant;
9-11 parts by weight of chlorinated paraffin as a flame retardant; and
0.2-0.3 parts by weight of ADCA (Azodicarbonamide) as a blowing agent;
A flame retardant and sound-absorbing rubber composition comprising a.
삭제delete 제1항에 있어서,
상기 조성물은 EPDM(Ethylene Propylene Diene Monomer), 천연고무, 무기충전재, 프로세스 오일, 산화아연, 스테아린산, 계면활성제, 광차단제, 가공조제, 노화방지제, 산화방지제, 가황제 및 가황촉진제로 이루어진 군으로부터 선택되는 1종 이상의 첨가제를 더 포함하는 것을 특징으로 하는 고무 조성물.
According to claim 1,
The composition is selected from the group consisting of EPDM (Ethylene Propylene Diene Monomer), natural rubber, inorganic filler, process oil, zinc oxide, stearic acid, surfactant, light blocking agent, processing aid, antioxidant, antioxidant, vulcanizing agent and vulcanization accelerator A rubber composition, characterized in that it further comprises one or more additives.
제1항에 있어서,
상기 고무 베이스로서 부틸고무 80 중량부 기준;
난연제로서 수산화알미늄 18.5-21.5 중량부;
난연제로서 염화파라핀 9-11 중량부;
발포제로서 ADCA(Azodicarbonamide) 0.2-0.3 중량부;
EPDM(Ethylene Propylene Diene Monomer) 14.5-15.5 중량부;
천연고무 4.5-5.5 중량부;
무기충전재로서 실리카 43-47 중량부;
무기충전재로서 카본 0.15-0.25 중량부;
무기충전재로서 탄산칼슘 28-32 중량부;
프로세스 오일 10-14 중량부;
산화아연 6-8 중량부;
스테아린산 1-2 중량부;
PEG-4000 1-2 중량부;
이산화티타늄 9-11 중량부;
가공조제 1-2 중량부;
노화방지제 1-2 중량부;
산화방지제 1.5-2.5 중량부;
가황제 1.0-1.4 중량부; 및
가황촉진제 5-6 중량부;를 포함하는 것을 특징으로 하는 고무 조성물.
According to claim 1,
Based on 80 parts by weight of butyl rubber as the rubber base;
18.5-21.5 parts by weight of aluminum hydroxide as a flame retardant;
9-11 parts by weight of chlorinated paraffin as a flame retardant;
0.2-0.3 parts by weight of ADCA (Azodicarbonamide) as a blowing agent;
EPDM (Ethylene Propylene Diene Monomer) 14.5-15.5 parts by weight;
4.5-5.5 parts by weight of natural rubber;
43-47 parts by weight of silica as an inorganic filler;
0.15-0.25 parts by weight of carbon as an inorganic filler;
28-32 parts by weight of calcium carbonate as an inorganic filler;
10-14 parts by weight of process oil;
6-8 parts by weight of zinc oxide;
1-2 parts by weight of stearic acid;
PEG-4000 1-2 parts by weight;
9-11 parts by weight of titanium dioxide;
1-2 parts by weight of processing aid;
1-2 parts by weight of an antioxidant;
1.5-2.5 parts by weight of antioxidant;
1.0-1.4 parts by weight of a vulcanizing agent; and
5-6 parts by weight of a vulcanization accelerator; a rubber composition comprising a.
제1항의 고무 조성물을 포함하는 난연성 흡음 매트.
A flame-retardant sound-absorbing mat comprising the rubber composition of claim 1.
제1항의 고무 조성물을 포함하는 난연성 층간소음 방지 매트.
A flame-retardant interlayer noise prevention mat comprising the rubber composition of claim 1.
제1항의 고무 조성물을 포함하는 난연성 방진재.
A flame retardant anti-vibration material comprising the rubber composition of claim 1 .
연질 EVA(Ethylene Vinyl Acetate) 발포고무층;
PU(polyurethane) 발포고무층;
경질 EVA(Ethylene Vinyl Acetate) 발포고무층;
PU(polyurethane) 발포고무층; 및
제1항의 고무 조성물로 제조된 고무 베이스;가 순차적으로 적층된 것을 특징으로 하는 난연성 흡음 매트.
Soft EVA (Ethylene Vinyl Acetate) foamed rubber layer;
PU (polyurethane) foam rubber layer;
Hard EVA (Ethylene Vinyl Acetate) foamed rubber layer;
PU (polyurethane) foam rubber layer; and
The rubber base made of the rubber composition of claim 1; flame-retardant sound-absorbing mat, characterized in that sequentially laminated.
제8항에 있어서,
상기 연질 EVA 발포고무층의 비중은 0.65-0.75이고,
상기 경질 EVA 발포고무층의 비중은 1.1-1.2인 것을 특징으로 하는 난연성 흡음 매트.
9. The method of claim 8,
The specific gravity of the soft EVA foamed rubber layer is 0.65-0.75,
The specific gravity of the hard EVA foamed rubber layer is a flame-retardant sound-absorbing mat, characterized in that 1.1-1.2.
제8항에 있어서,
상기 PU 발포고무층의 비중은 0.2-0.3인 것을 특징으로 하는 난연성 흡음 매트.
9. The method of claim 8,
The specific gravity of the PU foamed rubber layer is a flame-retardant sound-absorbing mat, characterized in that 0.2-0.3.
연질 EVA(Ethylene Vinyl Acetate) 발포고무층;
PU(polyurethane) 발포고무층;
경질 EVA(Ethylene Vinyl Acetate) 발포고무층;
PU(polyurethane) 발포고무층; 및
제1항의 고무 조성물로 제조된 고무 베이스;가 순차적으로 적층된 것을 특징으로 하는 난연성 층간소음 방지 매트.
Soft EVA (Ethylene Vinyl Acetate) foamed rubber layer;
PU (polyurethane) foam rubber layer;
Hard EVA (Ethylene Vinyl Acetate) foamed rubber layer;
PU (polyurethane) foam rubber layer; and
A flame-retardant interlayer noise prevention mat characterized in that the rubber base made of the rubber composition of claim 1 is sequentially laminated.
제11항에 있어서,
상기 연질 EVA 발포 고무층의 비중은 0.65-0.75이고,
상기 경질 EVA 발포 고무층의 비중은 1.1-1.2인 것을 특징으로 하는 난연성 층간소음 방지 매트.
12. The method of claim 11,
The specific gravity of the soft EVA foamed rubber layer is 0.65-0.75,
The flame retardant interlayer noise prevention mat, characterized in that the specific gravity of the hard EVA foamed rubber layer is 1.1-1.2.
제11항에 있어서,
상기 PU 발포고무층의 비중은 0.2-0.3인 것을 특징으로 하는 난연성 층간소음 방지 매트.
12. The method of claim 11,
The fire retardant interlayer noise prevention mat, characterized in that the specific gravity of the PU foamed rubber layer is 0.2-0.3.
KR1020180091463A 2018-08-06 2018-08-06 Rubber composition having fire retardant and sound absorbing, and mat for reducing the floor noise comprising the same KR102269536B1 (en)

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JP5026232B2 (en) * 2007-11-15 2012-09-12 積水化学工業株式会社 Method for producing crosslinked butyl rubber foam

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JP5026232B2 (en) * 2007-11-15 2012-09-12 積水化学工業株式会社 Method for producing crosslinked butyl rubber foam

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