KR102226570B1 - Eco Friendly Weed Control Sheet Composition and Constructing Methods Using Thereof - Google Patents
Eco Friendly Weed Control Sheet Composition and Constructing Methods Using Thereof Download PDFInfo
- Publication number
- KR102226570B1 KR102226570B1 KR1020200127931A KR20200127931A KR102226570B1 KR 102226570 B1 KR102226570 B1 KR 102226570B1 KR 1020200127931 A KR1020200127931 A KR 1020200127931A KR 20200127931 A KR20200127931 A KR 20200127931A KR 102226570 B1 KR102226570 B1 KR 102226570B1
- Authority
- KR
- South Korea
- Prior art keywords
- parts
- weight
- thermoplastic resin
- sheet
- eco
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
- A01G13/0256—Ground coverings
- A01G13/0268—Mats or sheets, e.g. nets or fabrics
- A01G13/0275—Films
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
- A01G13/0256—Ground coverings
- A01G13/0293—Anchoring means for ground coverings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01H—STREET CLEANING; CLEANING OF PERMANENT WAYS; CLEANING BEACHES; DISPERSING OR PREVENTING FOG IN GENERAL CLEANING STREET OR RAILWAY FURNITURE OR TUNNEL WALLS
- E01H11/00—Control of undesirable vegetation on roads or similar surfaces or permanent ways of railways, e.g. devices for scorching weeds or for applying herbicides; Applying liquids, e.g. water, weed-killer bitumen, to permanent ways
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Toxicology (AREA)
- Environmental Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
본 발명은 친환경 방초시트 조성물 및 이를 이용한 방초시트 시공방법에 관한 것으로서, 보다 상세하게는 잡초의 생장을 상부에서 물리적으로 압박함으로써 하부의 뿌리층은 유지하되 대부분의 잡초의 생장을 정지시킴으로서, 제초제를 사용하지 않고 물리적 강도로 잡초생육을 억제할 수 있도록 하는 친환경 방초시트 조성물 및 이용한 방초시트 시공방법에 관한 것이다.The present invention relates to an eco-friendly herbicide sheet composition and a method for constructing a herbicide sheet using the same, and more particularly, by physically pressing the growth of weeds from the upper part, the root layer of the lower part is maintained but the growth of most weeds is stopped. The present invention relates to an eco-friendly herbicide sheet composition and a method for constructing a herbicide sheet used to suppress weed growth with physical strength without use.
현대사회의 발전과 함께 도심 속 친환경을 위한 녹지공간의 조성이 늘어남은 물론, 식재수목의 선별과 식생에도 많은 노력이 경주되고 있다.Along with the development of modern society, the creation of green spaces for eco-friendliness in the city center has increased, as well as a lot of efforts are being made to select planted trees and vegetation.
그러나 식재의 계획과 선별에 의해 선정되어진 식재식물이라 하더라도, 그 주변 토양에 이미 내재되어 있던 다른 식물 또는 바람에 실려 유입되는 식물 특히, 잡초나 잡목과 같은 식물 종자의 급속한 발아와 성장으로 인해 원래의 조성형태와 목적이 훼손되는 경우가 많아 식재식물의 조성 후에도 지속적으로 제초작업 및 식재 복구작업을 병행하여야 하므로 유지관리에 많은 시간과 비용이 소요되고 있는 실정이다.However, even planted plants selected by planting planning and selection, due to the rapid germination and growth of other plants already embedded in the surrounding soil or plants introduced by the wind, especially plant seeds such as weeds and shrubs. Since the form and purpose of the composition are often damaged, the weeding work and planting restoration work must be carried out continuously even after the planting plant is formed, so a lot of time and cost are required for maintenance.
종래 위와 같은 잡초 생장을 억제하기 위한 부직포 또는 방초매트와 같은 제품들이 존재하였으나, 종래의 부직포나 방초매트 등은 단순히 토양을 덮어씌울 수 있게 하는 데에만 주안을 두고 있을 뿐이어서 잡초의 발아나 생장을 충분히 차단하지 못할 뿐더러, 아울러 선정되어 식재된 식재식물의 생장을 방해하게 되는 부작용을 나타내기도 한다.Conventionally, there have been products such as non-woven fabrics or grass mats for suppressing the growth of weeds, but conventional non-woven fabrics and grass mats are only focused on allowing the soil to be covered, thus preventing the germination or growth of weeds. In addition to not being able to block sufficiently, it also exhibits side effects that interfere with the growth of planted plants that have been selected and planted.
또한, 종래에는 위와 같은 종래 부직포나 방초매트 등을 토양에 시공함에 있어서도 단순히 부직포 등을 포설한 이후에 고정앵커와 같은 지지용구를 군데군데 토양에 박는 방식에 불과하기 때문에, 고정앵커가 부직포 등을 관통하면서 형성한 관통홀 등에 의해 부직포 자체가 쉽게 손상되거나 상기 관통홀을 통해 토양 속의 잡초 종자가 발아하여 생장하게 되는 문제를 일으키게 된다.In addition, in the conventional non-woven fabric or grass mat as described above, even in the construction of the soil, since it is only a method of placing support tools such as fixed anchors in the soil in several places after installing the non-woven fabric, etc., the fixed anchor is a non-woven fabric, etc. The nonwoven fabric itself is easily damaged by a through hole formed while penetrating, or a problem in which weed seeds in the soil germinate and grow through the through hole occurs.
또한, 위와 같이 단순히 부직포 상에 고정앵커를 군데군데 박아 고정시키는 종래의 방식에서는 토양에 박힌 고정앵커의 헤드부가 부직포를 직접 가압하는 정도가 크기 때문에 부직포가 손상되거나 또는 고정앵커 주위의 부직포가 상대적으로 위로 들리게 되어 토양의 지면으로부터 떠있는 상태가 되기 때문에 토양과 부직포 사이의 공간으로의 통풍에 의해 토양 표면이 쉽게 건조되거나 토사 유실이 발생하여 식재된 식재식물의 생장에 악영향을 미치게 되는 문제 역시 일으키게 된다.In addition, in the conventional method in which the fixed anchors are simply mounted on the nonwoven fabric as described above, the head of the fixed anchor embedded in the soil directly presses the nonwoven fabric, so that the nonwoven fabric is damaged or the nonwoven fabric around the fixed anchor is relatively Since it is lifted up and floats from the ground, the soil surface is easily dried or soil loss occurs due to ventilation into the space between the soil and the nonwoven fabric, which adversely affects the growth of planted plants. .
이러한 종래 기술로는 대한민국특허공개 제10-2013-0067698호에는 차광에 의한 태양 복사열 감소 및 토양 내의 잡초 종자가 발아하는 것을 차단함은 물론 식재되는 식물의 종자나 뿌리에는 식생에 필요한 수분과 공기를 충분히 공급할 수 있으며, 자외선으로부터 보호될 수 있는 별도의 자외선 처리제를 혼합하여 외부에 지속적으로 노출된 상태에서도 장기간 내구성을 확보할 수 있고, 방초시트를 토양에 고정하기 위해 앵커핀을 관통/삽입하더라도 앵커핀에 의해 형성된 관통홀을 통해 잡초 종자가 발아하는 것까지 점착테이프를 사용하여 차단할 수 있고, 앵커핀의 관통에 의한 시트의 손상이나 들림을 방지하고 앵커핀 헤드부의 돌출높이를 감소시켜 점착테이프의 부착강도를 강화할 수 있는 방초시트가 개시되어 있다.As such prior art, Korean Patent Publication No. 10-2013-0067698 discloses that solar radiation is reduced by shading and prevents weed seeds from germinating in the soil, as well as moisture and air required for vegetation in the seeds or roots of plants to be planted. It can be supplied sufficiently, and by mixing a separate UV treatment agent that can be protected from UV rays, long-term durability can be secured even in the state of constant exposure to the outside, and even if an anchor pin is penetrated/inserted to fix the grass sheet to the soil, the anchor It is possible to block even the germination of weed seeds through the through hole formed by the pin with adhesive tape, prevent damage or lifting of the sheet due to penetration of the anchor pin, and reduce the protruding height of the anchor pin head to prevent the adhesive tape from being sprouted. A herbivorous sheet capable of reinforcing adhesion strength is disclosed.
또한, 대한민국 등록특허 제10-1649464호에는 무기질 시멘트, 마사토, 대나무칩 분쇄분, 어패류가루, 무기질 안료, 생석회, 그래핀 및 무기질 결합재를 포함하여 이루어진 방초토 조성물이 개시되어 있다.In addition, Republic of Korea Patent Registration No. 10-1649464 discloses an inorganic cement, Masato, bamboo chip pulverized powder, fish and shellfish powder, inorganic pigments, quicklime, graphene and a pesticide composition comprising an inorganic binder.
본 발명은 전술한 문제점을 극복하기 위해 창출된 것으로서, 잡초의 생장을 상부에서 물리적으로 압박함으로써 하부의 뿌리층은 유지하되 대부분의 잡초의 생장을 정지시킴으로서, 제초제를 사용하지 않고 물리적 강도로 잡초의 생육을 억제할 수 있도록 하는 친환경 방초시트 조성물을 제공하고자 한다.The present invention was created in order to overcome the above-described problem, by physically pressing the growth of weeds from the top to maintain the root layer of the lower but to stop the growth of most weeds, without the use of herbicides, weeds with physical strength. It is intended to provide an eco-friendly herbicide sheet composition that can inhibit growth.
본 발명은 The present invention
열가소성 수지 100중량부 기준으로,Based on 100 parts by weight of thermoplastic resin,
숯가루 5 내지 20중량부;5 to 20 parts by weight of charcoal powder;
탄산칼슘 1 내지 5중량부;1 to 5 parts by weight of calcium carbonate;
이산화티탄 1 내지 5중량부;1 to 5 parts by weight of titanium dioxide;
나노세라믹 입자 1 내지 5중량부;1 to 5 parts by weight of nanoceramic particles;
스테아린산 1 내지 5중량부;1 to 5 parts by weight of stearic acid;
저수축제 2 내지 10중량부;2 to 10 parts by weight of a low shrinkage agent;
난연제 1 내지 5중량부;1 to 5 parts by weight of a flame retardant;
박리방지제 1 내지 3중량부;1 to 3 parts by weight of an anti-peeling agent;
오존열화방지제 1 내지 3중량부; 및 1 to 3 parts by weight of an ozone deterioration inhibitor; And
산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물을 제공한다.It provides an eco-friendly herbicide sheet composition comprising 1 to 3 parts by weight of an antioxidant.
또한, 본 발명은In addition, the present invention
열가소성 수지 100중량부 기준으로, 숯가루 5 내지 20중량부, 탄산칼슘 1 내지 5중량부, 이산화티탄 1 내지 5중량부, 나노세라믹 입자 1 내지 5중량부, 스테아린산 1 내지 5중량부, 저수축제 2 내지 10중량부, 난연제 1 내지 5중량부, 박리방지제 1 내지 3중량부, 오존열화방지제 1 내지 3중량부, 및 산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물을 혼합하는 혼합단계;Based on 100 parts by weight of thermoplastic resin, 5 to 20 parts by weight of charcoal powder, 1 to 5 parts by weight of calcium carbonate, 1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of nanoceramic particles, 1 to 5 parts by weight of stearic acid, low shrinkage agent A mixing step of mixing an eco-friendly herbicide sheet composition comprising 2 to 10 parts by weight, 1 to 5 parts by weight of a flame retardant, 1 to 3 parts by weight of a peeling inhibitor, 1 to 3 parts by weight of an ozone deterioration inhibitor, and 1 to 3 parts by weight of an antioxidant;
상기 혼합단계가 종료된 친환경 방초시트 조성물을 지지체상에 유연하여 시트를 제조하는 시트 제조단계;A sheet manufacturing step of producing a sheet by flexing the eco-friendly herbivorous sheet composition on which the mixing step is completed on a support;
상기 시트 제조단계가 종료된 후 건조하는 건조단계; 및A drying step of drying after the sheet manufacturing step is finished; And
상기 건조단계가 종료된 후 시트를 권취하는 권취단계를 포함하는 친환경 방초시트 제조방법을 제공한다.After the drying step is completed, it provides an eco-friendly method for manufacturing a herbivorous sheet comprising a winding step of winding the sheet.
또한, 본 발명은In addition, the present invention
시공할 대상면을 정리하는 정리단계;Arrangement step of arranging the target surface to be constructed;
상기 정리단계가 종료된 후 대상면에 열가소성 수지 100중량부 기준으로, 숯가루 5 내지 20중량부, 탄산칼슘 1 내지 5중량부, 이산화티탄 1 내지 5중량부, 나노세라믹 입자 1 내지 5중량부, 스테아린산 1 내지 5중량부, 저수축제 2 내지 10중량부, 난연제 1 내지 5중량부, 박리방지제 1 내지 3중량부, 오존열화방지제 1 내지 3중량부, 및 산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물을 이용한 방초시트를 전개하는 방초시트 전개단계; 및After the cleaning step is completed, based on 100 parts by weight of the thermoplastic resin on the target surface, 5 to 20 parts by weight of charcoal powder, 1 to 5 parts by weight of calcium carbonate, 1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of nanoceramic particles , Stearic acid 1 to 5 parts by weight, low shrinkage agent 2 to 10 parts by weight, flame retardant 1 to 5 parts by weight, peeling inhibitor 1 to 3 parts by weight, ozone deterioration inhibitor 1 to 3 parts by weight, and antioxidants containing 1 to 3 parts by weight A grass sheet development step of developing a grass sheet using an eco-friendly grass sheet composition; And
상기 방초시트 전개단계가 종료된 후 방초시트 상단에 보도블록을 설치하거나, 방초시트의 일측에 고정팩을 지면에 삽입하여 고정하는 고정단계를 포함하는 친환경 방초시트 조성물을 이용한 방초시트 시공방법을 제공한다.Provides a method of constructing a grass sheet using an eco-friendly grass sheet composition including a fixing step of installing a sidewalk block on the top of the grass sheet after the step of developing the grass sheet, or inserting and fixing a fixing pack on the ground at one side of the grass sheet. do.
본 발명에 따른 친환경 방초시트 조성물은 잡초의 생장을 상부에서 물리적으로 압박함으로써 하부의 뿌리층은 유지하되 대부분의 잡초의 생장을 정지시킴으로서, 제초제를 사용하지 않고 물리적 강도로 잡초의 생육을 억제할 수 있는 효과가 있다.The eco-friendly herbicide sheet composition according to the present invention physically presses the growth of weeds from the top to maintain the root layer at the bottom, but stops the growth of most weeds, thereby suppressing the growth of weeds with physical strength without the use of herbicides. There is an effect.
이하, 본 발명을 구체적으로 설명한다.Hereinafter, the present invention will be described in detail.
한 가지 관점에서, 본 발명은 열가소성 수지 100중량부 기준으로, 숯가루 5 내지 20중량부; 탄산칼슘 1 내지 5중량부; 이산화티탄 1 내지 5중량부; 나노세라믹 입자 1 내지 5중량부; 스테아린산 1 내지 5중량부; 저수축제 2 내지 10중량부; 난연제 1 내지 5중량부; 박리방지제 1 내지 3중량부; 오존열화방지제 1 내지 3중량부; 및 산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물을 제공한다.In one aspect, the present invention, based on 100 parts by weight of a thermoplastic resin, 5 to 20 parts by weight of charcoal powder; 1 to 5 parts by weight of calcium carbonate; 1 to 5 parts by weight of titanium dioxide; 1 to 5 parts by weight of nanoceramic particles; 1 to 5 parts by weight of stearic acid; 2 to 10 parts by weight of a low shrinkage agent; 1 to 5 parts by weight of a flame retardant; 1 to 3 parts by weight of an anti-peeling agent; 1 to 3 parts by weight of an ozone deterioration inhibitor; And it provides an eco-friendly herbaceous sheet composition comprising 1 to 3 parts by weight of an antioxidant.
다른 관점에서, 본 발명은 열가소성 수지 100중량부 기준으로, 숯가루 5 내지 20중량부, 탄산칼슘 1 내지 5중량부, 이산화티탄 1 내지 5중량부, 나노세라믹 입자 1 내지 5중량부, 스테아린산 1 내지 5중량부, 저수축제 2 내지 10중량부, 난연제 1 내지 5중량부, 박리방지제 1 내지 3중량부, 오존열화방지제 1 내지 3중량부, 및 산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물을 혼합하는 혼합단계; 상기 혼합단계가 종료된 친환경 방초시트 조성물을 지지체상에 유연하여 시트를 제조하는 시트 제조단계; 상기 시트 제조단계가 종료된 후 건조하는 건조단계; 및 상기 건조단계가 종료된 후 시트를 권취하는 권취단계를 포함하는 친환경 방초시트 제조방법을 제공한다.In another aspect, the present invention is based on 100 parts by weight of a thermoplastic resin, 5 to 20 parts by weight of charcoal powder, 1 to 5 parts by weight of calcium carbonate, 1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of nanoceramic particles, stearic acid 1 Eco-friendly herbivorous sheet comprising from to 5 parts by weight, 2 to 10 parts by weight of a low shrinkage agent, 1 to 5 parts by weight of a flame retardant, 1 to 3 parts by weight of a peeling inhibitor, 1 to 3 parts by weight of an ozone deterioration inhibitor, and 1 to 3 parts by weight of an antioxidant A mixing step of mixing the composition; A sheet manufacturing step of producing a sheet by flexing the eco-friendly herbivorous sheet composition on which the mixing step is completed on a support; A drying step of drying after the sheet manufacturing step is finished; And it provides an eco-friendly herbaceous sheet manufacturing method comprising a winding step of winding the sheet after the drying step is completed.
또 다른 관점에서, 본 발명은 상기 친환경 방초시트 조성물을 이용한 방초시트 시공방법에 있어서, 시공할 대상면을 정리하는 정리단계; 상기 정리단계가 종료된 후 대상면에 열가소성 수지 100중량부 기준으로, 숯가루 5 내지 20중량부, 탄산칼슘 1 내지 5중량부, 이산화티탄 1 내지 5중량부, 나노세라믹 입자 1 내지 5중량부, 스테아린산 1 내지 5중량부, 저수축제 2 내지 10중량부, 난연제 1 내지 5중량부, 박리방지제 1 내지 3중량부, 오존열화방지제 1 내지 3중량부, 및 산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물을 이용한 방초시트를 전개하는 방초시트 전개단계; 및 상기 방초시트 전개단계가 종료된 후 방초시트 상단에 보도블록을 설치하거나, 방초시트의 일측에 고정팩을 지면에 삽입하여 고정하는 고정단계를 포함하는 친환경 방초시트 조성물을 이용한 방초시트 시공방법을 제공한다.In yet another aspect, the present invention provides a method for constructing a pesticide sheet using the environmentally friendly pesticide sheet composition, comprising: an arrangement step of arranging a target surface to be constructed; After the cleaning step is completed, based on 100 parts by weight of the thermoplastic resin on the target surface, 5 to 20 parts by weight of charcoal powder, 1 to 5 parts by weight of calcium carbonate, 1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of nanoceramic particles , Stearic acid 1 to 5 parts by weight, low shrinkage agent 2 to 10 parts by weight, flame retardant 1 to 5 parts by weight, peeling inhibitor 1 to 3 parts by weight, ozone deterioration inhibitor 1 to 3 parts by weight, and antioxidants containing 1 to 3 parts by weight A grass sheet development step of developing a grass sheet using an eco-friendly grass sheet composition; And installing a sidewalk block on the top of the grass sheet, or inserting and fixing a fixing pack on the ground at one side of the grass sheet after the step of developing the grass sheet is completed. to provide.
본 발명에 따른 열가소성 수지는 열을 가하여 경화(硬化) 성형하면, 다시 열을 가해도 형태가 변하지 않는 수지로서 내열성, 내용제성, 내약품성, 기계적 성질, 전기절연성이 좋으며, 충전제를 넣어 강인한 성형물을 만들 수가 있다.The thermoplastic resin according to the present invention is a resin that does not change its shape even when heat is applied again when heat is applied to it, and has good heat resistance, solvent resistance, chemical resistance, mechanical properties, and electrical insulation. I can make it.
바람직한 열가소성 수지로는 당업계의 통상적인 열가소성 수지라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 폴리에틸렌(PE), 폴리프로필렌(PET), 폴리에틸렌테레프탈레이트(PET) 또는 이들의 혼합물을 사용하는 것이 좋다.As a preferred thermoplastic resin, any conventional thermoplastic resin in the art may be used, but preferably polyethylene (PE), polypropylene (PET), polyethylene terephthalate (PET), or a mixture thereof is preferably used. .
본 발명에 따른 방초시트 조성물, 특정적으로 친환경 방초시트 조성물의 열가소성 수지 외 나머지 성분들의 함량은 열가소성 수지100중량부를 기준으로 한다. The content of the other components other than the thermoplastic resin of the herbicide sheet composition according to the present invention, specifically the eco-friendly herbicide sheet composition, is based on 100 parts by weight of the thermoplastic resin.
본 발명에 따른 숯가루는 높은 공극율로 인하여 방초시트 조성물을 구성하는 조성물의 분산성을 향상시키는 동시에 결합력을 향상시켜 강도를 증가시키도록 하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 숯가루라면 어떠한 것을 사용하여도 무방하며, 바람직하게는 볼밀로 분말화한 숯가루를 사용하는 것이 좋다.The charcoal powder according to the present invention is to increase the strength by improving the bonding strength while improving the dispersibility of the composition constituting the herbicide sheet composition due to the high porosity. Anything may be used, and it is preferable to use charcoal powder powdered with a ball mill.
바람직한 숯가루의 사용량은 특별히 한정되는 것은 아니지만, 추천하기로는 열가소성 수지 100중량부 기준으로 5 내지 20중량부인 것이 좋다.A preferred amount of the charcoal powder used is not particularly limited, but is preferably 5 to 20 parts by weight based on 100 parts by weight of the thermoplastic resin.
본 발명에 따른 탄산칼슘은 친환경 방초시트 조성물의 치수 안정성 및 내마모성을 향상시키기 위한 것으로서, 이러한 목적을 갖는 탄산칼슘이라면 어떠한 것을 사용하여도 무방하며, 그 사용량은 열가소성 수지 100중량부 기준으로 1 내지 5중량부인 것이 좋다.Calcium carbonate according to the present invention is to improve the dimensional stability and abrasion resistance of the eco-friendly herbivorous sheet composition, and any calcium carbonate having this purpose may be used, and the amount used is 1 to 5 based on 100 parts by weight of the thermoplastic resin. It is better to be in parts by weight.
본 발명에 따른 이산화티탄은 내구성과 내충격성 등의 물성을 향상시킬 뿐만 아니라, 방초시트에 생물이 부착되어 식생하는 것을 방지하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 이산화티탄이라면 어떠한 것을 사용하여도 무방하고, 그 사용량은 열가소성 수지 100중량부 기준으로 1 내지 5중량부인 것이 좋다.Titanium dioxide according to the present invention not only improves physical properties such as durability and impact resistance, but also prevents vegetation due to attachment of organisms to the herbicide sheet, and any conventional titanium dioxide in the art for this purpose is used. It is okay to do so, and the amount is preferably 1 to 5 parts by weight based on 100 parts by weight of the thermoplastic resin.
여기서, 상기 이산화티탄의 입자 크기는 0.02 내지 5㎛일 수 있다. Here, the particle size of the titanium dioxide may be 0.02 to 5㎛.
상기 이산화티탄의 입자가 0.02㎛ 이상이면 내충격성 및 제조비용을 감소시킬 수 있으며, 5㎛ 이하이면 열가소성 수지를 포함하는 조성물 내에 이산화티탄이 균일하게 분사되어 충분히 수분을 차단할 수 있다.If the titanium dioxide particle is 0.02 μm or more, impact resistance and manufacturing cost may be reduced, and if it is 5 μm or less, titanium dioxide is uniformly sprayed into the composition containing the thermoplastic resin to sufficiently block moisture.
본 발명에 따른 나노세라믹 입자는 치밀하고 경도가 높은 표면을 형성하기 때문에, 수증기와 기타 기체, 액체의 투과를 방지함은 물론, 내습성, 내구성, 내후성, 내충격성, 내약품성이 향상된다.Since the nanoceramic particles according to the present invention form a dense and high hardness surface, the penetration of water vapor and other gases and liquids is prevented, as well as moisture resistance, durability, weather resistance, impact resistance, and chemical resistance.
상기 나노세라믹 입자의 사용량은 열가소성 수지 100중량부 기준으로 1 내지 5중량부인 것이 좋다.The amount of the nanoceramic particles is preferably 1 to 5 parts by weight based on 100 parts by weight of the thermoplastic resin.
바람직한 나노세라믹 입자는 실리콘카바이드, 알루미나, 지르코니아-실리카, ZnO, TiO2 및/또는 CaCO3가 포함된다. Preferred nanoceramic particles include silicon carbide, alumina, zirconia-silica, ZnO, TiO 2 and/or CaCO 3 .
이들 세라믹입자는 평균 입경이 나노미터 범위인 것이 바람직한데, 구체적으로 상기 실리콘카바이드의 평균 입경은 300 내지 500nm, 상기 알루미나의 평균 입경은 500 내지 1000nm, 상기 지르코니아-실리카의 평균 입경은 500 내지 1000nm, 상기 ZnO의 평균 입경은 500 내지 1000nm, 상기 TiO2의 평균 입경은 100 내지 300nm, 그리고 CaCO3의 평균 입경은 500 내지 1000nm인 것이 바람직하다.These ceramic particles are preferably in the range of nanometers, specifically, the average particle diameter of the silicon carbide is 300 to 500 nm, the average particle diameter of the alumina is 500 to 1000 nm, the average particle diameter of the zirconia-silica is 500 to 1000 nm, The average particle diameter of ZnO is 500 to 1000 nm, the average particle diameter of TiO 2 is 100 to 300 nm, and the average particle diameter of CaCO 3 is preferably 500 to 1000 nm.
이 중에서도 실리콘카바이드는 천연광물로 존재하지 않으므로 인공적으로 합성하며, 고온에서의 화학적 안정성 및 내식성이 뛰어나고 높은 경도를 갖는다.Among these, silicon carbide does not exist as a natural mineral, so it is artificially synthesized, has excellent chemical stability and corrosion resistance at high temperatures, and has high hardness.
본 발명에 따른 스테아린산은 점성을 낮추며, 탄력성을 높여줌과 동시에 시공 후 강성을 향상시키기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 스테아린산이라면 어떠한 것을 사용하여도 무방하며, 그 사용량은 특별히 한정되지 않지만, 열가소성 수지 100중량부 기준으로 1 내지 5중량부인 것이 바람직하다.Stearic acid according to the present invention is intended to lower viscosity, increase elasticity, and at the same time improve rigidity after construction, and any conventional stearic acid in the art for this purpose may be used, and the amount of use thereof is not particularly limited. , It is preferably 1 to 5 parts by weight based on 100 parts by weight of the thermoplastic resin.
본 발명에 따른 저수축제는 방초시트 조성물을 이용한 방초시트 제조시 수축되는 것을 방지하기 위한 것으로서, 이러한 목적을 갖는 당업계에서 통상적으로 사용되는 저수축제라면 특별히 한정되지 않지만, 바람직하게는 폴리비닐 아세테이트계 저수축제, 폴리에스터계 저수축제, 특정적으로 불포화 폴리에스터 수지로 이루어진 저수축제를 사용하는 것이 좋다.The low shrinkage agent according to the present invention is to prevent shrinkage during the manufacture of the herbicide sheet using the herbicide sheet composition, and is not particularly limited as long as it is a low shrinkage agent commonly used in the art for this purpose, but is preferably polyvinyl acetate-based It is preferable to use a low-shrinkage agent, a polyester-based low-shrinkage agent, or a low-shrinkage agent specifically composed of an unsaturated polyester resin.
바람직한 저수축제의 사용량은 사용자의 선택에 따라 변경 가능하지만, 추천하기로는 열가소성 수지 100중량부 기준으로 2 내지 10중량부인 것이 좋다.The preferred amount of the low shrinkage agent can be changed according to the user's selection, but it is recommended that the amount is 2 to 10 parts by weight based on 100 parts by weight of the thermoplastic resin.
본 발명에 따른 난연제는 친환경 방초시트 조성물로 제조되는 방초시트에 난연성을 제공하기 위한 것으로서, 이러한 목적을 위해 당업계에서 통상적으로 사용되는 난연제라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 수산화알루미늄, 수산화마그네슘 또는 이들의 혼합물을 사용하는 것이 좋다.The flame retardant according to the present invention is to provide flame retardancy to the herbicide sheet made of an eco-friendly herbicide sheet composition, and any flame retardant commonly used in the art for this purpose may be used, but preferably aluminum hydroxide, It is better to use magnesium hydroxide or a mixture thereof.
여기서, 상기 수산화알루미늄과 수산화마그네슘은 열이 가해지면 화학작용에 의해 수산기(-OH)가 나오면서 공기 중의 수소와 결합하여 물을 생성함으로써 물질의 연소를 방해하게 되는 메커니즘을 갖지만, 상기 수산화알루미늄은 저온, 예를 들면 150 내지 200℃의 온도범위에서 불연성을 갖고, 수산화마그네슘은 고온, 예를 들면 200 내지 250℃의 온도범위에서 불연성을 나타내어 본 발명에 따른 방초시트 조성물이 넓은 범위 온도범위, 예를 들면 고온 및 저온에서 모두 탁월한 불연성을 제공할 수 있다.Here, the aluminum hydroxide and magnesium hydroxide have a mechanism to interfere with the combustion of the material by generating water by combining with hydrogen in the air while the hydroxyl group (-OH) is released by a chemical reaction when heat is applied, but the aluminum hydroxide has a low temperature. , For example, has non-flammability in a temperature range of 150 to 200 °C, and magnesium hydroxide exhibits non-flammability in a high temperature, for example, 200 to 250 °C, so that the herbivorous sheet composition according to the present invention has a wide temperature range, such as For example, it can provide excellent non-flammability at both high and low temperatures.
바람직한 난연제의 사용량은 열가소성 수지 100중량부 기준으로 1 내지 5중량부인 것이 좋다.The preferred amount of the flame retardant is preferably 1 to 5 parts by weight based on 100 parts by weight of the thermoplastic resin.
본 발명에 따른 박리방지제는 방초시트의 표면에서 조성물이 쉽게 박리되어 탈리되는 것을 방지하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 박리방지제라면 어떠한 것을 사용하여도 무방하지만, 바람직하게는 폴리인산계, 아민계, 또는 인산 에스테르계 박리방지제를 사용하는 것이 좋고, 추천하기로는 액상형으로 비중이 1.0 이상이고 60℃ 점도가 110 cPs인 폴리인산계 박리방지제; 산가가 10 ㎎KOH/g 이하이고, 총 아민가가 140 내지 400㎎HCl/g인 아민계 박리방지제인 것이 좋다.The peeling inhibitor according to the present invention is to prevent the composition from being easily peeled off and detached from the surface of the herbivorous sheet, and any conventional peeling inhibitor having this purpose in the art may be used, but preferably polyin It is preferable to use an acid-based, amine-based, or phosphoric acid ester-based peeling inhibitor, and is recommended, a polyphosphoric acid-based peeling inhibitor having a specific gravity of 1.0 or more and a viscosity of 110 cPs at 60° C. in liquid form; It is preferable that it is an amine-based peeling inhibitor having an acid value of 10 mgKOH/g or less and a total amine value of 140 to 400 mgHCl/g.
바람직한 박리방지제의 사용량은 특별히 한정되지 않지만, 사용자의 선택에 다라 열가소성 수지 100중량부 기준으로 1 내지 3중량부인 것이 좋다.The preferred amount of the peeling inhibitor used is not particularly limited, but is preferably 1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin, depending on the user's choice.
본 발명에 따른 오존열화방지제는 방초시트 조성물이 햇빛 등에 노출되어 열화되는 것을 방지하기 위한 것으로서, 이러한 목적을 갖는 당업계의 통상적인 오존열화방지제라면 어떠한 것을 사용하여도 무방하다.The ozone deterioration inhibitor according to the present invention is to prevent deterioration of the herbicide sheet composition due to exposure to sunlight, etc., and any conventional ozone deterioration inhibitor having this purpose may be used.
바람직한 오존열화방지제는 6PPD (N-(1,3-dimethylutyl)-N'-phenyl-p-phenylenediamine) 및/또는 TAPDT(2,4,6-tris-(N-1,4-dimethylpentyl-p-phenylenediamino)-1,3,5-triazine)를 포함하여 오존라디칼의 산화작용에 의한 방초시트의 촉진열화작용을 오존열화방지제 분자구조에 아민과 결합된 방향족 고리화합물 거대분자의 이중결합부분이 자유전자 이동현상에 의해 활성화된 오존라디칼과 상쇄되어 방초시트의 열화방지 및 열화를 지연시키는 수지 혼합조성으로 구성될 수 있다.Preferred ozone deterioration inhibitors are 6PPD (N-(1,3-dimethylutyl)-N'-phenyl-p-phenylenediamine) and/or TAPDT(2,4,6-tris-(N-1,4-dimethylpentyl-p- Including phenylenediamino)-1,3,5-triazine), the double bond portion of the macromolecule of the aromatic cyclic compound bonded to the amine in the molecular structure is free electrons for the accelerated deterioration of the herbivorous sheet due to the oxidation of ozone radicals. It can be composed of a resin mixture composition that offsets the activated ozone radicals by the migration phenomenon to prevent and delay the deterioration of the herbicide sheet.
즉, 상기 오존열화방지제는 페닐렌디아민(Phenylenediamine-based)계 왁스를 사용할 수 있고, 6PPD와 TAPDT을 포함하는 혼합수지 조성을 사용하거나 라디칼 생성이 활발한 방향족 폴리아민계 등을 사용할 수 있으며, 특히 페닐렌디아민계를 사용하는 것이 바람직하다.That is, as the ozone deterioration inhibitor, a phenylenediamine-based wax may be used, a mixed resin composition including 6PPD and TAPDT, or an aromatic polyamine type having active radical generation may be used, and in particular, phenylenediamine It is preferable to use a system.
바람직한 오존열화방지제의 사용량은 열가소성 수지 100중량부 기준으로 1 내지 3중량부를 사용하는 것이 좋다.The amount of the ozone deterioration inhibitor is preferably used in an amount of 1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin.
본 발명에 따른 산화방지제는 친환경 방초시트 조성물의 산화를 방지하기 위한 것이다.The antioxidant according to the present invention is for preventing oxidation of the eco-friendly herbicide sheet composition.
바람직한 산화방지제는 아민계, 비스페놀계, 모노페놀계 및 유황계 산화방지제가 사용될 수 있고, 그 사용량은 열가소성 수지 100중량부 기준으로 1 내지 3중량부인 것이 좋다.Preferred antioxidants may be amine-based, bisphenol-based, monophenol-based and sulfur-based antioxidants, and the amount thereof is preferably 1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin.
특정적으로, 본 발명에 따른 산화방지제는 고온에서 가공이 이루어질 경우 저분자형 고분자형 페놀계 산화방지제, 예를 들면 2.2-메틸렌비스(4-메틸-6-t-부틸페놀)[2 . 2 - M e t h y l e n e b i s ( 4 - m e t h y l - 6 - t - b u t y l p h e n o l )], 2.6-디-t-부틸-4-메틸페놀(2.6-di -t-Butyl-4-methylphenol) 또는 이들의 혼합물을 사용하는 것을 추천한다.Specifically, when the antioxidant according to the present invention is processed at high temperature, a low molecular weight polymeric phenolic antioxidant, for example 2.2-methylenebis(4-methyl-6-t-butylphenol)[2. 2-M ethylenebis (4-methyl-6-t-butylphenol )], 2.6-di-t-Butyl-4-methylphenol (2.6-di -t-Butyl-4-methylphenol) or mixtures thereof I recommend you.
이와 같은 구성을 갖는 본 발명에 따른 친환경 방초시트 조성물은 하기의 특정 양태로 실시되는 부가물을 1종 또는 1종 이상 더 포함할 수 있다.The eco-friendly herbivorous sheet composition according to the present invention having such a configuration may further include one or more additives implemented in the following specific embodiments.
특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물을 자외선으로부터 보호하여 안정성을 제공하기 위하여 안정제를 열가소성 수지 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다. As a specific embodiment, the eco-friendly herbivorous sheet composition according to the present invention may further include 1 to 5 parts by weight of a stabilizer based on 100 parts by weight of a thermoplastic resin in order to provide stability by protecting the composition from ultraviolet rays.
바람직한 안정제로는 아크릴 폴리올 수지, 무황변 폴리 우레아수지, 폴리이소시아네이트 또는 이들의 혼합물을 사용하는 것이 좋다.As a preferable stabilizer, it is preferable to use an acrylic polyol resin, a non-yellowing polyurea resin, a polyisocyanate, or a mixture thereof.
다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 표면평활성, 흐름성 향상 및 내후성을 증대시키기 위하여 폴리에틸렌 왁스를 열가소성 수지 100중량부 기준으로 1 내지 5중량부 더 포함할 수 있다.As another specific aspect, the eco-friendly herbicide sheet composition according to the present invention may further include 1 to 5 parts by weight of polyethylene wax based on 100 parts by weight of the thermoplastic resin in order to improve the surface smoothness, flowability, and weather resistance of the composition.
여기서, 상기 폴리에틸렌 왁스의 사용량이 1중량부 미만이면 흐름성 저하로 인해 성형성 및 시공성이 떨어지고 내후성이 약화되는 문제점이 있으며, 5중량부 이상이면 시트의 물성이 저하되는 문제가 있다.Here, when the amount of the polyethylene wax is less than 1 part by weight, moldability and workability are deteriorated due to a decrease in flowability, and weather resistance is weakened, and when the amount is 5 parts by weight or more, there is a problem that the physical properties of the sheet are deteriorated.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 반응성, 응집 방지성, 화학적 안정성, 내구성 등을 개선하기 위하여 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부의 지르코알루미네이트를 더 포함할 수 있다. As another specific aspect, the eco-friendly herbicide sheet composition according to the present invention further comprises 0.1 to 2 parts by weight of zircoaluminate based on 100 parts by weight of the thermoplastic resin in order to improve the reactivity, anti-aggregation, chemical stability, and durability of the composition. Can include.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물들의 저장안정성을 향상시키기 위하여 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부의 2,2,4-트리메틸-1,3-펜탄디올아이소부틸산(2,2,4-Trimethyl-1,3-Pentanediol Isobutyrate)를 더 포함 할 수 있다.As another specific embodiment, the eco-friendly herbicide sheet composition according to the present invention is 0.1 to 3 parts by weight of 2,2,4-trimethyl-1,3-pentanediol iso based on 100 parts by weight of a thermoplastic resin in order to improve the storage stability of the compositions. It may further contain butyric acid (2,2,4-Trimethyl-1,3-Pentanediol Isobutyrate).
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 내마모성, 내약품성, 내용제성, 내열성 및/또는 내수성을 개선하기 위하여 열가소성 수지 100중량부 기준으로 0.01 내지 0.1중량부의 푸르푸릴알코올(furfuryl alcohol)을 더 포함할 수 있다.In another specific embodiment, the eco-friendly herbicide sheet composition according to the present invention is 0.01 to 0.1 parts by weight based on 100 parts by weight of a thermoplastic resin in order to improve abrasion resistance, chemical resistance, solvent resistance, heat resistance and/or water resistance. ) May be further included.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 결빙방지성을 향상시키기 위하여 열가소성 수지 100중량부 기준으로 0.01 내지 4중량부의 규산나트륨을 더 포함할 수 있다.As another specific aspect, the eco-friendly herbivorous sheet composition according to the present invention may further include 0.01 to 4 parts by weight of sodium silicate based on 100 parts by weight of the thermoplastic resin in order to improve the anti-icing properties of the composition.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 강도, 내화성 및 내식성을 개선하기 위하여 열가소성 수지 100중량부 기준으로 0.01 내지 0.1중량부의 세륨을 더 포함할 수 있다.As another specific aspect, the eco-friendly herbivorous sheet composition according to the present invention may further include 0.01 to 0.1 parts by weight of cerium based on 100 parts by weight of the thermoplastic resin in order to improve strength, fire resistance, and corrosion resistance.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 내구성 및 열안정성을 향상시키기 위하여 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부의 트리아세틴을 더 포함할 수 있다.As another specific aspect, the eco-friendly herbivorous sheet composition according to the present invention may further include 0.1 to 3 parts by weight of triacetin based on 100 parts by weight of the thermoplastic resin in order to improve durability and thermal stability.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 재료분리 저항성, 작업성 및 동결융해 내구성 등을 향상시키기 위하여 이미다졸린베타인을 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부로 더 포함할 수 있다.As another specific aspect, the eco-friendly herbivorous sheet composition according to the present invention further contains imidazoline betaine in an amount of 0.1 to 2 parts by weight based on 100 parts by weight of a thermoplastic resin in order to improve material separation resistance, workability, and freeze-thaw durability of the composition. Can include.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 경화속도를 조절하고 내식성을 개선하기 위하여 규불화마그네슘을 열가소성 수지 100중량부 기준으로 0.05 내지 3중량부로 더 포함할 수 있다. As another specific embodiment, the eco-friendly herbivorous sheet composition according to the present invention may further include magnesium silicide in an amount of 0.05 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin in order to control the curing speed of the composition and improve corrosion resistance.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 내구성, 내마모성 및 분산성을 향상시키기 위하여 스테아린산칼슘을 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부로 더 포함할 수 있다.As another specific aspect, the eco-friendly herbivorous sheet composition according to the present invention may further include 0.1 to 2 parts by weight of calcium stearate based on 100 parts by weight of the thermoplastic resin in order to improve the durability, abrasion resistance, and dispersibility of the composition.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 경화성을 향상시키기 위하여 트리페닐포스파인(triphenyphosphine)을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.As another specific embodiment, the eco-friendly herbicide sheet composition according to the present invention may further include triphenylphosphine in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin in order to improve the curability of the composition.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 혼합시 반응속도를 빠르게 하고, 접착 성능을 향상시키기 위하여 2-브로모피리딘(2-bromopyridine)을 열가소성 수지 100중량부 기준으로 0.1 내지 5중량부로 더 포함할 수 있다.As another specific embodiment, the eco-friendly herbicide sheet composition according to the present invention is 0.1 based on 100 parts by weight of a thermoplastic resin in order to speed up the reaction rate and improve the adhesion performance when the composition is mixed. It may further contain to 5 parts by weight.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 내열성, 탄성회복력, 및 내주름성 등을 향상시키기 위하여 디이소노닐프탈레이트(Di-Isononyl Phthalate, (DINP))를 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.In another specific embodiment, the eco-friendly herbivorous sheet composition according to the present invention contains diisononyl phthalate (DINP) by 100 weight of a thermoplastic resin in order to improve the heat resistance, elastic recovery power, and wrinkle resistance of the composition. It may further include 0.1 to 3 parts by weight based on parts.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물조성물의 항균성 및 방오성을 향상시키기 위하여 일라이트를 열가소성 수지 100중량부 기준으로 0.1 내지 1중량부로 더 포함할 수 있다.As another specific embodiment, the eco-friendly herbicide sheet composition according to the present invention may further include ilite in an amount of 0.1 to 1 part by weight based on 100 parts by weight of the thermoplastic resin in order to improve the antimicrobial and antifouling properties of the composition composition.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 경도를 향상시키고 표면오염을 감소시키기 위하여 열가소성 수지 100중량부 기준으로 1 내지 3중량부의 트리메틸올프로판 트리아크릴레이트를 더 포함할 수 있다.In another specific aspect, the eco-friendly herbicide sheet composition according to the present invention may further include 1 to 3 parts by weight of trimethylolpropane triacrylate based on 100 parts by weight of a thermoplastic resin in order to improve the hardness of the composition and reduce surface contamination. have.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 속경성, 강도 및 내구성을 개선하기 위해 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부의 탄산아파타이트를 더 포함할 수 있다.As another specific aspect, the eco-friendly herbicide sheet composition according to the present invention may further include 0.1 to 2 parts by weight of carbonate apatite based on 100 parts by weight of the thermoplastic resin in order to improve the fast setting, strength and durability of the composition.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 내마모성, 내오염성, 내화학성, 내후성, 내염해성, 중성화 저항성을 개선하기 위해 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부의 디시클로헥실암모늄 2-시아노아크릴레이트를 더 포함할 수 있다.In another specific aspect, the eco-friendly herbicide sheet composition according to the present invention is 0.1 to 2 parts by weight of dicyclo based on 100 parts by weight of a thermoplastic resin in order to improve the abrasion resistance, stain resistance, chemical resistance, weather resistance, salt decomposition resistance, and neutralization resistance of the composition. Hexyl ammonium 2-cyanoacrylate may be further included.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 접착강도 특성과 내마모성, 내오염성, 내화학성, 내후성, 내염해성 등을 개선하기 위해 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부의 하이드록시탄산마그네슘을 더 포함할 수 있다.In another specific embodiment, the eco-friendly herbivorous sheet composition according to the present invention is 0.1 to 2 parts by weight based on 100 parts by weight of a thermoplastic resin in order to improve the adhesive strength properties, abrasion resistance, stain resistance, chemical resistance, weather resistance, and salt resistance of the composition. It may further include magnesium hydroxycarbonate.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 강도, 내화성, 내마모성, 및 내부식성 등을 개선하기 위하여 열가소성 수지 100중량부 기준으로 0.1 내지 4중량부의 할로이사이트(halloysite)를 더 포함할 수 있는데, 상기 할로이사이트는 알루미늄과 실리콘이 약 1:1의 비율로 포함되어 있는 점토질 광물질로서 이를 조성물에 포함시키면 상기와 같은 효과를 발현하게 된다.In another specific aspect, the eco-friendly herbicide sheet composition according to the present invention further contains 0.1 to 4 parts by weight of halloysite based on 100 parts by weight of a thermoplastic resin in order to improve the strength, fire resistance, abrasion resistance, and corrosion resistance of the composition. The haloysite is a clay mineral containing aluminum and silicon in a ratio of about 1:1, and when it is included in the composition, the above effect is expressed.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 장기강도, 내식성 및 내화성을 향상시키기 위하여 페라이트(ferrite)를 열가소성 수지 100중량부 기준으로 1 내지 3중량부 더 포함할 수 있는데, 그 함량이 열가소성 수지 100중량부 기준으로 3중량부를 초과하면 빠른 경화특성을 보이기는 하나 경제성이 떨어지며, 1중량부 미만이면 상기와 같은 개선효과가 미미하여 좋지 않다.In another specific aspect, the eco-friendly herbicide sheet composition according to the present invention may further include 1 to 3 parts by weight of ferrite based on 100 parts by weight of the thermoplastic resin in order to improve the long-term strength, corrosion resistance and fire resistance of the composition, If the content exceeds 3 parts by weight based on 100 parts by weight of the thermoplastic resin, it exhibits rapid curing characteristics, but the economical efficiency is deteriorated. If it is less than 1 part by weight, the above-described improvement effect is insignificant and is not good.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 반응성을 높여 조기강도를 발현하기 위하여 알루민산스트론튬(strontium aluminate)를 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.As another specific embodiment, the eco-friendly herbicide sheet composition according to the present invention may further include strontium aluminate in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin in order to increase the reactivity of the composition and to express early strength. have.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 강도, 내마모성, 및 내구성을 향상시키기 위하여 질화마그네슘을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.As another specific aspect, the eco-friendly herbivorous sheet composition according to the present invention may further include magnesium nitride in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin in order to improve the strength, abrasion resistance, and durability of the composition.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 반응성을 개선하여 강도를 발현하고, 내오염성 및 재료분리 저항성을 향상시키기 위하여 메타인산 나트륨(sodium metaphosphate)를 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.As another specific aspect, the eco-friendly herbicide sheet composition according to the present invention is 0.1 sodium metaphosphate based on 100 parts by weight of a thermoplastic resin in order to improve reactivity to express strength, and to improve fouling resistance and material separation resistance. It may further contain to 3 parts by weight.
또 다른 특정 양태로서, 본 발명에 따른 친환경 방초시트 조성물은 조성물의 열적·화학적 안정성을 향상시켜 내화성을 개선하고 충진성을 향상시키기 위하여 규산알루미늄을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함할 수 있다.In another specific aspect, the eco-friendly herbicide sheet composition according to the present invention further comprises 0.1 to 3 parts by weight of aluminum silicate based on 100 parts by weight of the thermoplastic resin in order to improve the fire resistance and improve the filling property by improving the thermal and chemical stability of the composition. Can include.
이와 같은 구성을 갖는 본 발명에 따른 친환경 방초시트 조성물을 이용한 방초시트 제조방법을 설명하면 다음과 같다.A method of manufacturing a herbicide sheet using an eco-friendly herbicide sheet composition according to the present invention having such a configuration is as follows.
여기서, 상기 친환경 방초시트 조성물의 제조방법은 그 일 양태로서, 열가소성 수지 100중량부 기준으로, 숯가루 5 내지 20중량부, 탄산칼슘 1 내지 5중량부, 이산화티탄 1 내지 5중량부, 나노세라믹 입자 1 내지 5중량부, 스테아린산 1 내지 5중량부, 저수축제 2 내지 10중량부, 난연제 1 내지 5중량부, 박리방지제 1 내지 3중량부, 오존열화방지제 1 내지 3중량부, 및 산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물을 혼합하는 혼합단계;상기 혼합단계가 종료된 친환경 방초시트 조성물을 지지체상에 유연하여 시트를 제조하는 시트 제조단계;Here, the manufacturing method of the eco-friendly herbicide sheet composition is an aspect thereof, based on 100 parts by weight of the thermoplastic resin, 5 to 20 parts by weight of charcoal powder, 1 to 5 parts by weight of calcium carbonate, 1 to 5 parts by weight of titanium dioxide, nanoceramic Particles 1 to 5 parts by weight, stearic acid 1 to 5 parts by weight, low shrinkage agent 2 to 10 parts by weight, flame retardant 1 to 5 parts by weight, peeling inhibitor 1 to 3 parts by weight, ozone deterioration inhibitor 1 to 3 parts by weight, and antioxidant 1 Mixing step of mixing an eco-friendly herbivorous sheet composition comprising to 3 parts by weight; Sheet manufacturing step of manufacturing a sheet by flexing the environmentally friendly herbivorous sheet composition on a support body in which the mixing step is completed;
상기 시트 제조단계가 종료된 후 건조하는 건조단계; 및A drying step of drying after the sheet manufacturing step is finished; And
상기 건조단계가 종료된 후 시트를 권취하는 권취단계를 포함한다.And a winding step of winding up the sheet after the drying step is completed.
이때, 상기 방초시트 제조방법은 상기 방법으로 한정되는 것이 아니라, 다양한 방법, 예를 들면 통상적인 직조, 편조, 사출 등의 방법으로 제조될 수도 있다.At this time, the method of manufacturing the herbicide sheet is not limited to the above method, and may be manufactured by various methods, for example, conventional weaving, braiding, injection, or the like.
한편, 본 발명에 따른 친환경 방초시트 조성물로 제조된 방초시트는 다양한 시공방법으로 현장에 적용될 수 있는바, 이러한 시공방법의 일례로서, 본 발명에 따른 친환경 방초시트 조성물을 이용한 방초시트 시공방법은 친환경 방초시트 조성물을 이용한 방초시트 시공방법에 있어서,On the other hand, the grass sheet made of the eco-friendly grass sheet composition according to the present invention can be applied to the site by various construction methods. As an example of such a construction method, the grass sheet construction method using the eco-friendly grass sheet composition according to the present invention is eco-friendly. In the herbicide sheet construction method using the herbicide sheet composition,
시공할 대상면을 정리하는 정리단계;Arrangement step of arranging the target surface to be constructed;
상기 정리단계가 종료된 후 대상면에 열가소성 수지 100중량부 기준으로, 숯가루 5 내지 20중량부, 탄산칼슘 1 내지 5중량부, 이산화티탄 1 내지 5중량부, 나노세라믹 입자 1 내지 5중량부, 스테아린산 1 내지 5중량부, 저수축제 2 내지 10중량부, 난연제 1 내지 5중량부, 박리방지제 1 내지 3중량부, 오존열화방지제 1 내지 3중량부, 및 산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물을 이용한 방초시트를 전개하는 방초시트 전개단계; 및 상기 방초시트 전개단계가 종료된 후 방초시트 상단에 보도블록을 설치하거나, 방초시트의 일측에 고정팩을 지면에 삽입하여 고정하는 고정단계를 포함한다.After the tidying step is completed, based on 100 parts by weight of the thermoplastic resin on the target surface, 5 to 20 parts by weight of charcoal powder, 1 to 5 parts by weight of calcium carbonate, 1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of nanoceramic particles , Stearic acid 1 to 5 parts by weight, low shrinkage agent 2 to 10 parts by weight, flame retardant 1 to 5 parts by weight, peeling inhibitor 1 to 3 parts by weight, ozone deterioration inhibitor 1 to 3 parts by weight, and antioxidants containing 1 to 3 parts by weight A grass sheet development step of developing a grass sheet using an eco-friendly grass sheet composition; And a fixing step of installing a sidewalk block on the top of the grass sheet or by inserting a fixing pack into the ground at one side of the grass sheet after the step of spreading the grass sheet is completed.
여기서, 상기 정리단계는 방초시트를 시공할 대상면에 존재하는 잡초 등을 제거하고, 지반을 정리하는 것을 포함한다.Here, the arranging step includes removing weeds, etc. existing on the target surface on which the grass sheet is to be constructed, and arranging the ground.
또한, 상기 방초시트 전개단계에 있어서, 사용되는 방초시트가 복수개로 이루어져 있는 경우, 복수개의 방초시트가 서로 겹치도록, 바람직하게는 적어도 10cm 가량 겹치도록 전개하는 것이 좋다.In addition, in the step of developing the grass sheet, when the grass sheet to be used is composed of a plurality of sheets, it is preferable to expand the sheet so that the grass sheets overlap each other, preferably at least about 10 cm.
또한, 본 발명에 따른 친환경 방초시트 조성물을 이용한 방초시트 시공방법의 다른 일례로서, 상기 시공방법은 친환경 방초시트 조성물을 이용한 방초시트 시공방법에 있어서,In addition, as another example of a method for constructing a pesticide sheet using an eco-friendly pesticide sheet composition according to the present invention, the construction method is a method for constructing a pesticide sheet using an environmentally friendly pesticide sheet composition,
시공대상 면적에 대하여 잡초를 제거하고 자갈을 깔아 기초 층을 형성한 후, 상기 기초 층을 다짐장치를 통해 다지는 기초 시공단계;A foundation construction step of forming a foundation layer by removing weeds with respect to the construction target area and laying gravel, and then compacting the foundation layer through a compaction device;
상기 기초 시공단계를 거쳐 다져진 기초의 시공대상 면적에 대하여 부직포를 깔아주는 부직포 시공단계;A non-woven fabric construction step of laying a non-woven fabric on the construction target area of the foundation compacted through the foundation construction step;
상기 부직포 시공단계를 거쳐 시공된 부직포 상면에 상기 제1항에 따른 친환경 방초시트 조성물로 이루어진 방초시트를 일정두께로 고르게 펴면서 미장하는 미장 시공단계;Plasterer construction step of spreading and plastering a herbicide sheet made of the eco-friendly herbicide sheet composition according to claim 1 on the upper surface of the nonwoven fabric constructed through the nonwoven fabric construction step to a predetermined thickness;
상기 미장 시공단계가 종료된 후 양생포 또는 비닐을 덮어 양생하는 양생 시공단계; 및A curing construction step of covering and curing a curing cloth or vinyl after the plastering construction step is completed; And
상기 양생 시공단계를 거쳐 양생이 완료된 후, 추가적으로 강도보강을 위해 방초시트 상면에 물을 뿌려주는 강도보강 마감 시공단계를 포함한다.After the curing is completed through the curing construction step, a strength reinforcement finishing construction step of spraying water on the upper surface of the herbicide sheet for additional strength reinforcement is included.
여기서, 상기 미장 시공단계의 후단에는 필요에 따라, 상기 미장 시공단계를 거쳐 시공된 방초시트 상면에 강도보강을 위해 1차적으로 그래핀 액상을 뿌려주는 1차 보강 시공단계;Here, at the rear end of the plastering construction step, if necessary, a first reinforcement construction step in which graphene liquid is primarily sprayed on the upper surface of the grass sheet constructed through the plastering construction step to reinforce strength;
상기 1차 보강 시공단계를 거쳐 1차적으로 강도보강된 방초시트 상면에 대하여 거친 면을 추가적으로 미장을 통해 평탄화한 후, 평탄화된 방초시트 상면에 2차적으로 강도보강을 위해 그래핀 액상을 뿌려주는 2차 보강 시공단계; 및After the rough surface is additionally flattened by plastering the top surface of the grass sheet that has been primarily reinforced through the first reinforcement construction step, graphene liquid is sprayed on the top surface of the flattened grass sheet for secondary strength reinforcement. Vehicle reinforcement construction step; And
상기 2차 보강 시공단계를 거쳐 2차적으로 강도보강된 방초시트 상면에 대하여 살수처리하는 살수 시공단계를 더 부가하는 것을 포함할 수 있다.It may include further adding a sprinkling construction step of sprinkling treatment on the upper surface of the herbicide sheet that has been secondarily reinforced through the second reinforcement construction step.
이하에서 실시예를 통하여 본 발명을 구체적으로 설명하기로 한다. 그러나 하기의 실시예는 오로지 본 발명을 구체적으로 설명하기 위한 것으로 이들 실시예에 의해 본 발명의 범위를 한정하는 것은 아니다.Hereinafter, the present invention will be described in detail through examples. However, the following examples are for illustrative purposes only and are not intended to limit the scope of the present invention by these examples.
[실시예 1][Example 1]
폴리에틸렌 100g, 숯가루 13g, 탄산칼슘 3g, 평균입자 크기가 약 1㎛인 이산화티탄 3g, 평균 입경이 약 400nm인 실리콘카바이드 3g, 스테아린산 3g, 불포화 폴리에스터 수지로 이루어진 저수축제 6g, 수산화알루미늄 3g, 액상형으로 비중이 1.0 이상이고 60℃ 점도가 110 cPs인 폴리인산계 박리방지제 2g, 6PPD 2g, 및 2.2-메틸렌비스(4-메틸-6-t-부틸페놀) 2g을 혼합하여 친환경 방초시트 조성물을 제조하였다. 100 g of polyethylene, 13 g of charcoal powder, 3 g of calcium carbonate, 3 g of titanium dioxide with an average particle size of about 1 μm, 3 g of silicon carbide with an average particle diameter of about 400 nm, 3 g of stearic acid, 6 g of a low shrinkage agent composed of unsaturated polyester resin, 3 g of aluminum hydroxide, In liquid form, 2g of polyphosphoric acid peeling inhibitor with a specific gravity of 1.0 or more and a viscosity of 110 cPs at 60°C, 2g of 6PPD, and 2g of 2.2-methylenebis(4-methyl-6-t-butylphenol) are mixed to prepare an eco-friendly herbicide sheet composition. Was prepared.
[실시예 2][Example 2]
실시예 1과 동일한 방법으로 실시하되, 무황변 폴리 우레아수지 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of a non-yellowing polyurea resin.
[실시예 3][Example 3]
실시예 1과 동일한 방법으로 실시하되, 폴리에틸렌 왁스 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of polyethylene wax.
[실시예 4][Example 4]
실시예 1과 동일한 방법으로 실시하되, 지르코알루미네이트 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of zircoaluminate.
[실시예 5][Example 5]
실시예 1과 동일한 방법으로 실시하되, 2,2,4-트리메틸-1,3-펜탄디올아이소부틸산 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but further added 1 g of 2,2,4-trimethyl-1,3-pentanediol isobutyl acid.
[실시예 6][Example 6]
실시예 1과 동일한 방법으로 실시하되, 푸르푸릴알코올 0.05g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but further added 0.05 g of furfuryl alcohol.
[실시예 7][Example 7]
실시예 1과 동일한 방법으로 실시하되, 규산나트륨 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of sodium silicate.
[실시예 8][Example 8]
실시예 1과 동일한 방법으로 실시하되, 세륨 0.05g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 0.05 g of cerium.
[실시예 9][Example 9]
실시예 1과 동일한 방법으로 실시하되, 트리아세틴 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of triacetin.
[실시예 10][Example 10]
실시예 1과 동일한 방법으로 실시하되, 이미다졸린베타인 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of imidazoline betaine.
[실시예 11][Example 11]
실시예 1과 동일한 방법으로 실시하되, 규불화마그네슘 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of magnesium silicide.
[실시예 12][Example 12]
실시예 1과 동일한 방법으로 실시하되, 스테아린산칼슘 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of calcium stearate.
[실시예 13][Example 13]
실시예 1과 동일한 방법으로 실시하되, 트리페닐포스파인 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of triphenylphosphine.
[실시예 14][Example 14]
실시예 1과 동일한 방법으로 실시하되, 2-브로모피리딘 3g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of 2-bromopyridine.
[실시예 15][Example 15]
실시예 1과 동일한 방법으로 실시하되, 디이소노닐프탈레이트 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of diisononylphthalate.
[실시예 16][Example 16]
실시예 1과 동일한 방법으로 실시하되, 일라이트 0.5g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 0.5 g of illite.
[실시예 17][Example 17]
실시예 1과 동일한 방법으로 실시하되, 트리메틸올프로판 트리아크릴레이트 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of trimethylolpropane triacrylate.
[실시예 18][Example 18]
실시예 1과 동일한 방법으로 실시하되, 탄산아파타이트 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of carbonated apatite.
[실시예 19][Example 19]
실시예 1과 동일한 방법으로 실시하되, 디시클로헥실암모늄 2-시아노아크릴레이트 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of dicyclohexylammonium 2-cyanoacrylate.
[실시예 20][Example 20]
실시예 1과 동일한 방법으로 실시하되, 하이드록시탄산마그네슘 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of magnesium hydroxycarbonate.
[실시예 21][Example 21]
실시예 1과 동일한 방법으로 실시하되, 할로이사이트 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of haloysite.
[실시예 22][Example 22]
실시예 1과 동일한 방법으로 실시하되, 페라이트 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of ferrite.
[실시예 23][Example 23]
실시예 1과 동일한 방법으로 실시하되, 알루민산스트론튬 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of strontium aluminate.
[실시예 24][Example 24]
실시예 1과 동일한 방법으로 실시하되, 질화마그네슘 2g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of magnesium nitride.
[실시예 25][Example 25]
실시예 1과 동일한 방법으로 실시하되, 메타인산 나트륨 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of sodium metaphosphate.
[실시예 26][Example 26]
실시예 1과 동일한 방법으로 실시하되, 규산알루미늄 1g을 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of aluminum silicate.
[실시예 27][Example 27]
실시예 1과 동일한 방법으로 실시하되, 실시예 2 내지 실시예 26에 따라 부가된 부가물을 모두 더 부가하여 실시하였다.It was carried out in the same manner as in Example 1, but all of the additives added according to Examples 2 to 26 were further added.
[실 험][Experiment]
실시예에 따라 제조된 친환경 방초시트 조성물을 판상의 지지체상에 유연하여 시트를 제조한 뒤 7일 동안 상온에서 대기 방치 후, 난연성, KSF 2561 부착강도시험, KS F 2429 마모저항시험, KS F 2221 내충격성시험방법 등에 따라 시험하고, 그 측정결과를 표 1로 나타냈다.The eco-friendly anti-grass sheet composition prepared according to the examples was flexible on a plate-like support to prepare a sheet and then left at room temperature for 7 days, and then left to stand at room temperature for 7 days, flame retardancy, KSF 2561 adhesion strength test, KS F 2429 abrasion resistance test, KS F 2221 It was tested according to the impact resistance test method, etc., and the measurement results are shown in Table 1.
표 1에 나타낸 바와 같이, 본 발명에 따른 친환경 방초시트 조성물을 사용한 실시예들은 난연성이 좋고, 부착강도, 내충격성 및 내마모성이 좋은 것으로 나타났다.As shown in Table 1, the examples using the eco-friendly herbicide sheet composition according to the present invention were found to have good flame retardancy, adhesion strength, impact resistance, and abrasion resistance.
이상에서 설명한 바와 같이, 본 발명이 속하는 기술 분야의 당업자는 본 발명이 그 기술적 사상이나 필수적 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예는 모두 예시적인 것이며 한정적인 것이 아닌 것으로서 이해해야만 한다. 본 발명의 범위는 상기 상세한 설명보다는 후술하는 특허청구범위의 의미 및 범위 그리고 그 등가개념으로부터 도출되는 모두 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.As described above, those skilled in the art to which the present invention pertains will understand that the present invention can be implemented in other specific forms without changing the technical spirit or essential features thereof. Therefore, all of the embodiments described above are illustrative and should be understood as non-limiting. The scope of the present invention should be construed as including all changed or modified forms derived from the meaning and scope of the claims to be described later rather than the above detailed description, and equivalent concepts thereof.
Claims (5)
숯가루 5 내지 20중량부;
탄산칼슘 1 내지 5중량부;
이산화티탄 1 내지 5중량부;
나노세라믹 입자 1 내지 5중량부;
스테아린산 1 내지 5중량부;
저수축제 2 내지 10중량부;
난연제 1 내지 5중량부;
박리방지제 1 내지 3중량부;
오존열화방지제 1 내지 3중량부; 및
산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물에,
폴리에틸렌 왁스를 열가소성 수지 100중량부 기준으로 1 내지 5중량부로 더 포함하고,
지르코알루미네이트를 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부로 더 포함하며,
규산나트륨을 열가소성 수지 100중량부 기준으로 0.01 내지 4중량부로 더 포함하고,
세륨을 열가소성 수지 100중량부 기준으로 0.01 내지 0.1중량부로 더 포함하며,
트리아세틴을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고,
이미다졸린베타인을 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부로 더 포함하며,
규불화마그네슘을 열가소성 수지 100중량부 기준으로 0.05 내지 3중량부로 더 포함하고,
트리페닐포스파인을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며,
2-브로모피리딘을 열가소성 수지 100중량부 기준으로 0.1 내지 5중량부로 더 포함하고,
디이소노닐프탈레이트를 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며,
일라이트를 열가소성 수지 100중량부 기준으로 0.1 내지 1중량부로 더 포함하고,
트리메틸올프로판 트리아크릴레이트를 열가소성 수지 100중량부 기준으로 1 내지 3중량부로 더 포함하며,
할로이사이트를 열가소성 수지 100중량부 기준으로 0.1 내지 4중량부로 더 포함하고,
메타인산 나트륨을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며,
규산알루미늄을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하는 친환경 방초시트 조성물.
Based on 100 parts by weight of thermoplastic resin,
5 to 20 parts by weight of charcoal powder;
1 to 5 parts by weight of calcium carbonate;
1 to 5 parts by weight of titanium dioxide;
1 to 5 parts by weight of nanoceramic particles;
1 to 5 parts by weight of stearic acid;
2 to 10 parts by weight of a low shrinkage agent;
1 to 5 parts by weight of a flame retardant;
1 to 3 parts by weight of an anti-peeling agent;
1 to 3 parts by weight of an ozone deterioration inhibitor; And
In an eco-friendly herbicide sheet composition comprising 1 to 3 parts by weight of an antioxidant,
Further comprising 1 to 5 parts by weight of polyethylene wax based on 100 parts by weight of the thermoplastic resin,
Further comprising 0.1 to 2 parts by weight of zircoaluminate based on 100 parts by weight of the thermoplastic resin,
Further comprising 0.01 to 4 parts by weight of sodium silicate based on 100 parts by weight of the thermoplastic resin,
Cerium is further included in an amount of 0.01 to 0.1 parts by weight based on 100 parts by weight of the thermoplastic resin,
Further containing triacetin in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin,
Imidazoline betaine further comprises 0.1 to 2 parts by weight based on 100 parts by weight of the thermoplastic resin,
Further comprising magnesium silicate in an amount of 0.05 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin,
Further comprising 0.1 to 3 parts by weight of triphenylphosphine based on 100 parts by weight of the thermoplastic resin,
2-bromopyridine is further included in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the thermoplastic resin,
Diisononylphthalate further comprises 0.1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin,
Further comprising 0.1 to 1 parts by weight of illite based on 100 parts by weight of the thermoplastic resin,
Further comprising 1 to 3 parts by weight of trimethylolpropane triacrylate based on 100 parts by weight of the thermoplastic resin,
A halosite is further included in an amount of 0.1 to 4 parts by weight based on 100 parts by weight of a thermoplastic resin,
Sodium metaphosphate is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of the thermoplastic resin,
An eco-friendly herbicide sheet composition further comprising 0.1 to 3 parts by weight of aluminum silicate based on 100 parts by weight of a thermoplastic resin.
상기 정리단계가 종료된 후 대상면에 열가소성 수지 100중량부 기준으로, 숯가루 5 내지 20중량부, 탄산칼슘 1 내지 5중량부, 이산화티탄 1 내지 5중량부, 나노세라믹 입자 1 내지 5중량부, 스테아린산 1 내지 5중량부, 저수축제 2 내지 10중량부, 난연제 1 내지 5중량부, 박리방지제 1 내지 3중량부, 오존열화방지제 1 내지 3중량부, 및 산화방지제 1 내지 3중량부를 포함하는 친환경 방초시트 조성물에, 폴리에틸렌 왁스를 열가소성 수지 100중량부 기준으로 1 내지 5중량부로 더 포함하고, 지르코알루미네이트를 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부로 더 포함하며, 규산나트륨을 열가소성 수지 100중량부 기준으로 0.01 내지 4중량부로 더 포함하고, 세륨을 열가소성 수지 100중량부 기준으로 0.01 내지 0.1중량부로 더 포함하며, 트리아세틴을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하고, 이미다졸린베타인을 열가소성 수지 100중량부 기준으로 0.1 내지 2중량부로 더 포함하며, 규불화마그네슘을 열가소성 수지 100중량부 기준으로 0.05 내지 3중량부로 더 포함하고, 트리페닐포스파인을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며, 2-브로모피리딘을 열가소성 수지 100중량부 기준으로 0.1 내지 5중량부로 더 포함하고, 디이소노닐프탈레이트를 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며, 일라이트를 열가소성 수지 100중량부 기준으로 0.1 내지 1중량부로 더 포함하고, 트리메틸올프로판 트리아크릴레이트를 열가소성 수지 100중량부 기준으로 1 내지 3중량부로 더 포함하며, 할로이사이트를 열가소성 수지 100중량부 기준으로 0.1 내지 4중량부로 더 포함하고, 메타인산 나트륨을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하며, 규산알루미늄을 열가소성 수지 100중량부 기준으로 0.1 내지 3중량부로 더 포함하는 친환경 방초시트 조성물을 이용한 방초시트를 전개하는 방초시트 전개단계; 및
상기 방초시트 전개단계가 종료된 후 방초시트 상단에 보도블록을 설치하거나, 방초시트의 일측에 고정팩을 지면에 삽입하여 고정하는 고정단계를 포함하는 친환경 방초시트 조성물을 이용한 방초시트 시공방법.Arrangement step of arranging the target surface to be constructed;
After the cleaning step is completed, based on 100 parts by weight of the thermoplastic resin on the target surface, 5 to 20 parts by weight of charcoal powder, 1 to 5 parts by weight of calcium carbonate, 1 to 5 parts by weight of titanium dioxide, 1 to 5 parts by weight of nanoceramic particles , Stearic acid 1 to 5 parts by weight, low shrinkage agent 2 to 10 parts by weight, flame retardant 1 to 5 parts by weight, peeling inhibitor 1 to 3 parts by weight, ozone deterioration inhibitor 1 to 3 parts by weight, and antioxidants containing 1 to 3 parts by weight In the eco-friendly herbivorous sheet composition, polyethylene wax is further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of a thermoplastic resin, zircoaluminate is further included in an amount of 0.1 to 2 parts by weight based on 100 parts by weight of a thermoplastic resin, and sodium silicate is thermoplastic It further comprises 0.01 to 4 parts by weight based on 100 parts by weight of the resin, and further comprises 0.01 to 0.1 parts by weight based on 100 parts by weight of the thermoplastic resin, and further comprises 0.1 to 3 parts by weight of triacetin based on 100 parts by weight of the thermoplastic resin. And, further comprising an imidazoline betaine in an amount of 0.1 to 2 parts by weight based on 100 parts by weight of a thermoplastic resin, magnesium silicide is further included in an amount of 0.05 to 3 parts by weight based on 100 parts by weight of a thermoplastic resin, and triphenylphosphine is a thermoplastic resin It further comprises 0.1 to 3 parts by weight based on 100 parts by weight, and further comprises 0.1 to 5 parts by weight based on 100 parts by weight of the thermoplastic resin, and 0.1 to 5 parts by weight of diisononylphthalate based on 100 parts by weight of the thermoplastic resin. It further comprises 3 parts by weight, further comprising 0.1 to 1 parts by weight of illite based on 100 parts by weight of the thermoplastic resin, further comprising 1 to 3 parts by weight of trimethylolpropane triacrylate based on 100 parts by weight of the thermoplastic resin, halo The site is further included in an amount of 0.1 to 4 parts by weight based on 100 parts by weight of a thermoplastic resin, sodium metaphosphate is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of a thermoplastic resin, and an aluminum silicate is used in an amount of 0.1 to 4 parts by weight based on 100 parts by weight of the thermoplastic resin. Eco-friendly herbicide sheet containing more by 3 parts by weight A grass sheet development step of deploying a grass sheet using the relics; And
A method of constructing a grass sheet using an eco-friendly grass sheet composition comprising a fixing step of installing a sidewalk block on the top of the grass sheet or by inserting and fixing a fixing pack on one side of the grass sheet after the step of developing the grass sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020200127931A KR102226570B1 (en) | 2020-10-05 | 2020-10-05 | Eco Friendly Weed Control Sheet Composition and Constructing Methods Using Thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020200127931A KR102226570B1 (en) | 2020-10-05 | 2020-10-05 | Eco Friendly Weed Control Sheet Composition and Constructing Methods Using Thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR102226570B1 true KR102226570B1 (en) | 2021-03-12 |
Family
ID=75177141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020200127931A KR102226570B1 (en) | 2020-10-05 | 2020-10-05 | Eco Friendly Weed Control Sheet Composition and Constructing Methods Using Thereof |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR102226570B1 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10131193A (en) * | 1996-10-29 | 1998-05-19 | Toray Ind Inc | Preventive structure for weed on slope |
| JP2001247866A (en) * | 2000-03-06 | 2001-09-14 | Suzuki Sogyo Co Ltd | Material for imparting plant growth environment, its preparation process, soil composition containing the material and soil conditioning process using the material |
| JP2004113101A (en) * | 2002-09-26 | 2004-04-15 | Diatex Co Ltd | Weedproofing sheet |
| JP2010071038A (en) * | 2008-09-22 | 2010-04-02 | Ube Ind Ltd | Weed-proof structure for weed prevention, and execution method therefor |
| JP2017074017A (en) * | 2015-10-15 | 2017-04-20 | 七王工業株式会社 | Weed control board and its usage |
-
2020
- 2020-10-05 KR KR1020200127931A patent/KR102226570B1/en active IP Right Grant
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10131193A (en) * | 1996-10-29 | 1998-05-19 | Toray Ind Inc | Preventive structure for weed on slope |
| JP2001247866A (en) * | 2000-03-06 | 2001-09-14 | Suzuki Sogyo Co Ltd | Material for imparting plant growth environment, its preparation process, soil composition containing the material and soil conditioning process using the material |
| JP2004113101A (en) * | 2002-09-26 | 2004-04-15 | Diatex Co Ltd | Weedproofing sheet |
| JP2010071038A (en) * | 2008-09-22 | 2010-04-02 | Ube Ind Ltd | Weed-proof structure for weed prevention, and execution method therefor |
| JP2017074017A (en) * | 2015-10-15 | 2017-04-20 | 七王工業株式会社 | Weed control board and its usage |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5251398A (en) | Fibrous coatings for protecting fruit bearing or blossoming trees, shrubs or other vegetation from freeze and frost | |
| WO2017132683A1 (en) | Engineered surfaces | |
| KR101677934B1 (en) | Artificial turf structure | |
| KR100995659B1 (en) | Sheet for vegetation, Vegetation mat and Vegetation bag using the same | |
| KR101147837B1 (en) | Natural Paint having high elasticity and the method thereof | |
| KR102226570B1 (en) | Eco Friendly Weed Control Sheet Composition and Constructing Methods Using Thereof | |
| KR101947139B1 (en) | Vegetation board treated with flame-retardant and method for manufacturing the same | |
| KR102392315B1 (en) | Waterproof and root isolation method using urethane roof waterproof agent | |
| KR101283612B1 (en) | Planting composition for greening a slope and greeningmethod using same | |
| KR102567564B1 (en) | Artificial turf system using natural cork filler | |
| KR101282279B1 (en) | Organic Compound Soil for Concrete structure and Afforestation Method Thereof | |
| KR100426321B1 (en) | Putting Green on the Rooftop and Method Constructing the same | |
| KR101721660B1 (en) | Chip coated with thermal barrier property for artifical lawn and manufacturing method thereof | |
| KR102110948B1 (en) | Vegetable retaining wall structure with eco pocket and the construction method | |
| CN106045441A (en) | Desertified land spray-covering material | |
| KR101580032B1 (en) | Biodegradable stake for fixing lawn | |
| KR101523998B1 (en) | Planting material having erosion preventive function and greening method of natural ground using the same | |
| KR101609514B1 (en) | Mat for preventing growing weeds | |
| KR20190091585A (en) | A composition which exhibits a composite or selective effect of electromagnetic wave absorption, electromagnetic interference, antistatic, more than flame resistance, antimicrobial, antifungal, freeze protection, Corrosion prevention performance depending on the mixing ratio of additive materials, type of additive material and an application | |
| KR101435767B1 (en) | Re-vegetation and vegetation based chip technology to provide a surface recording | |
| KR20170032993A (en) | Composition for slope afforestation and method of slope afforestation using the same | |
| JP2008303641A (en) | Weed-preventing method | |
| KR101724663B1 (en) | Eco-friendly elastic pavement using waste particle board and polyurethane resin and constructing method thereof | |
| KR101690274B1 (en) | Manufacturing method for soil board for soil bed | |
| JP6952364B2 (en) | Agricultural film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant |