KR102220449B1 - Method of manufacture of eco-friendly dry paper scrubbers and multi-use detergent-containing paper washcloths with a layer of cleaning coating liquid containing natural-derived surfactants - Google Patents

Method of manufacture of eco-friendly dry paper scrubbers and multi-use detergent-containing paper washcloths with a layer of cleaning coating liquid containing natural-derived surfactants Download PDF

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KR102220449B1
KR102220449B1 KR1020200131271A KR20200131271A KR102220449B1 KR 102220449 B1 KR102220449 B1 KR 102220449B1 KR 1020200131271 A KR1020200131271 A KR 1020200131271A KR 20200131271 A KR20200131271 A KR 20200131271A KR 102220449 B1 KR102220449 B1 KR 102220449B1
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paper
water
coating liquid
soluble
liquid layer
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KR1020200131271A
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Korean (ko)
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김경민
류가람
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김경민
류가람
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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L17/00Apparatus or implements used in manual washing or cleaning of crockery, table-ware, cooking-ware or the like
    • A47L17/04Pan or pot cleaning utensils
    • A47L17/08Pads; Balls of steel wool, wire, or plastic meshes
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16Cloths; Pads; Sponges
    • A47L13/17Cloths; Pads; Sponges containing cleaning agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B25/00Packaging other articles presenting special problems
    • B65B25/14Packaging paper or like sheets, envelopes, or newspapers, in flat, folded, or rolled form
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/022Emulsions, e.g. oil in water
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22Agents rendering paper porous, absorbent or bulky
    • D21H21/24Surfactants
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper

Abstract

The present invention relates to a method for manufacturing an eco-friendly dry paper scrubber having a cleaning-function coating liquid layer including a naturally-derived surfactant and effective microorganisms, capable of easily washing dishes and the like, being biodegraded and recycled, and implementing reservation of resources and waste reduction in a sustainable manner. The method comprises: a first step of preparing wetting-enhanced dense-tissue paper with a basis weight of 40-100 g per square meter; a second step of placing the prepared paper on a coating machine; a third step of preparing a water-soluble coating solution in which acrylic polymer water-soluble emulsion and hydrophobic inorganic pigment are mixed, to secure durability of the paper placed on the coating machine, injecting the prepared water-soluble coating solution into the coating machine, and applying the water-soluble coating solution with 3-5 g per square meter to the upper surface of the paper by operating the coating machine to form a water-soluble coating liquid layer to prevent the paper from being torn; a fourth step of obtaining the paper in which the water-soluble coating liquid layer is dried by using a drying means at 70-150°C for the paper in which the water-soluble coating liquid layer is formed to secure the durability; and a fifth step of preparing a cleaning-function coating solution by mixing a natural-derived surfactant, an effective microorganism solution, vegetable glycerin, baking soda, citric acid, essential oil, and hub extract to enable the paper in which the water-soluble coating liquid layer is dried to be used in washing dishes.

Description

천연유래 계면활성제와 유효미생물을 포함하는 세정기능코팅액층이 구비되어 있는 친환경 건식 종이수세미의 제조방법{Method of manufacture of eco-friendly dry paper scrubbers and multi-use detergent-containing paper washcloths with a layer of cleaning coating liquid containing natural-derived surfactants}TECHNICAL FIELD The method of manufacture of eco-friendly dry paper scrubbers and multi-use detergent-containing paper washcloths with a layer of cleaning is equipped with a layer of a washing function coating liquid containing a natural surfactant and effective microorganisms. coating liquid containing natural-derived surfactants}

본 발명은 수세미에 관한 것으로, 보다 상세하게는 식기 등을 용이하게 세정할 수 있도록 함과 아울러 생분해와 재활용이 가능하여 지속가능한 자원보존과 쓰레기를 줄일 수 있도록 하는 천연유래 계면활성제와 유효미생물을 포함하는 세정기능코팅액층이 구비되어 있는 친환경 건식 종이수세미의 제조방법에 관한 것이다.The present invention relates to a scrubber, and more particularly, it includes a natural-derived surfactant and effective microorganisms that enable easy cleaning of tableware, etc., as well as biodegradation and recycling, which enables sustainable resource conservation and reduction of waste. It relates to a method of manufacturing an eco-friendly dry paper scrubber provided with a cleaning function coating liquid layer.

일반적으로, 수세미는 주방에서 그릇이나 식기, 가스레인지, 가전제품 등을 세정하는데 주로 사용될 뿐 아니라 욕조나 세면대, 변기, 타일 등으로까지 이용과 응용이 가능하여 그 활용의 범위가 넓다.In general, the scrubber is mainly used to clean dishes, dishes, gas ranges, home appliances, etc. in the kitchen, and can be used and applied to bathtubs, washbasins, toilets, tiles, and the like, so that the range of use thereof is wide.

종래 수세미들은, 합성사를 망상구조로 직조한 네트형, 합성사를 직조한 망체 내에 스펀지 등을 충진시킨 폼 충진형 등의 다양한 합성수지 수세미들이 보급되었고, 이러한 합성수지 수세미들은 세정물의 표면 손상의 유발 정도가 작고 또 소량의 세정제 투입에 의해 다량의 거품을 발생하므로, 부드러운 오염물의 제거에 용이한 이점을 갖는다.In the conventional scrubbers, various synthetic resin scrubbers such as a net type woven synthetic yarn in a network structure and a foam filled type in which a sponge is filled in a mesh structure woven synthetic yarn have been popularized. In addition, since a large amount of foam is generated by the addition of a small amount of detergent, it has the advantage of easy removal of soft contaminants.

그런데, 상기 합성수지 수세미는 철 수세미와 달리 세정력이 떨어져 냄비나 불판 등 오염물의 고착정도가 심한 세정물에는 사용이 어렵고, 또 세정물에서 제거된 오염물이 섬유조직 내에 침투하여 수세미의 2차적인 오염 발생을 야기할 수 있다.However, unlike iron scrubbers, the synthetic resin scrubber is difficult to use for cleaning products with high degree of adhesion of contaminants such as pots and fire plates due to its low cleaning power.Also, contaminants removed from the cleaning material penetrate into the fiber tissue, causing secondary contamination of the scrubber. Can cause.

상기한 문제점을 해결하기 위해, 2015년 07월 28일자 출원번호 제10-2015-0106396호(발명의 명칭 : 합성수지 수세미의 제조방법)로 특허청에 출원된 바 있으며, 청구범위는 " 합성수지를 열간 용융시킨 폴리머를 일자형의 압출구가 형성된 T다이스를 따라 압출시켜 0.1 내지 0.35mm의 설정두께를 갖는 전폭의 필름시트를 성형하는 열간 압출공정과; 상기 압출 성형된 전폭의 필름시트를 냉각조의 냉각수에 함침 및 급냉시켜, 필름시트를 냉간 경화시키는 냉간 경화공정과; 상기 전폭의 필름시트를, 재단날들이 설정폭으로 배치된 재단부에 길이방향으로 통과시켜서, 전폭의 필름시트를 설정폭으로 분할 재단한 평판형 필름세사들을 형성하는 재단공정과; 상기 재단공정에 의해 성형된 평판형 필름세사를, 코일링 가이드를 포함하여 구성된 코일링 성형부에 길이방향으로 통과시켜, 평판형 필름세사를 나선형 꼬임이 연속적으로 형성된 코일형 필름세사로 소성 변형시키는 코일링 성형공정; 및 상기 코일형 필름세사를 환형 권취부에 투입시켜, 필름세사들이 환형으로 권취된 합성수지 수세미를 성형하는 환형 권취공정을 포함하여 구성된 것을 특징으로 하는 합성수지 수세미의 제조방법. " 이다.In order to solve the above problems, it has been filed with the Korean Intellectual Property Office on July 28, 2015 with application number 10-2015-0106396 (name of the invention: manufacturing method of synthetic resin scrubber), and the claims are "Hot melt synthetic resin. A hot extrusion process of extruding the polymer along a T-dice with a straight extrusion hole to form a full-width film sheet having a set thickness of 0.1 to 0.35 mm; and impregnating the extruded full-width film sheet into the cooling water of a cooling tank. And a cold hardening process of cold-hardening the film sheet by rapid cooling; The full-width film sheet is passed in a longitudinal direction to a cutting unit in which the cutting blades are arranged in a set width, and the full-width film sheet is divided into a set width. A cutting process for forming flat film fibers; The flat film fiber formed by the cutting process is passed in a longitudinal direction to a coiling molding unit including a coiling guide, so that the flat film fiber is spirally twisted. A coiling forming process of plastically deforming into a continuously formed coil-type film fiber; And by introducing the coil-type film fiber into an annular winding part, the film fiber is formed including an annular winding process of forming a synthetic resin scrubber wound in an annular shape. A method for manufacturing synthetic resin scrubbers characterized by.

그러나, 상기 합성수지 수세미의 제조방법으로 제조된 합성수지 수세미는 생분해와 재활용을 할 수 없는 관계로 자원보존 및 쓰레기를 줄일 수 없는 문제점이 있었다.However, the synthetic resin scrubber manufactured by the method of manufacturing the synthetic resin scrubber cannot be biodegraded and recycled, so there is a problem in that it cannot conserve resources and reduce waste.

다른 한편, 현재 다양하게 식기 등을 세정하는 수세미는 스펀지, 아크릴, 폴리에틸렌계열, 부직포에 의하여 만들어진 것들이 대부분이며, 사용하는 세정제 또한 석유화학화합물에 의한 합성계면활성제를 주로 사용하고 있기에 환경오염 문제, 물의 과다사용 문제, 쓰레기의 양산문제 등이 상당할 뿐만 아니라 환경파괴와 쓰레기의 과다등 사회적인 문제점들을 누구나 인지하고 있으나, 일률적인 석유계에서 유래한 제품사용으로 환경에 부담을 주며, 소비자 또한 가격이 저렴하고 사용히 편리하며, 위생적인 제품을 선호하게 수 밖에 없는 것이 현실 때문에 쓰레기가 급격히 증가하는 사회적인 문제가 대두되고 있는 실정에 있다.On the other hand, most of the current scrubbers for washing dishes, etc. are mostly made of sponge, acrylic, polyethylene, and non-woven fabrics, and the detergents used are also synthetic surfactants made of petrochemical compounds. Everyone is aware of social problems such as environmental destruction and excessive waste, as well as the problem of overuse and mass production of garbage, but the use of products derived from the petroleum system puts a burden on the environment, and consumers are also inexpensive. Because of the reality that people have no choice but to prefer hygienic products that are convenient to use and are convenient to use, there is a situation in which the social problem of the rapid increase of garbage is on the rise.

그리고, 석유유래 합성계면활성제 등은 물에서 분해가 쉽게되지 않는점과 액상세정제를 사용할 경우 액상세정제를 과다하게 사용하게 되어 물사용 증가와 하천의 정화능력을 떨어뜨리는 문제점이 있었다.In addition, petroleum-derived synthetic surfactants are not easily decomposed in water, and when a liquid detergent is used, the liquid detergent is excessively used, resulting in an increase in water use and a decrease in the purifying ability of rivers.

따라서, 본 발명은 상기한 종래 기술에 따른 제반 문제점을 해결하기 위하여 개량발명된 것으로서, 본 발명의 목적은 식기 등을 용이하게 세정할 수 있도록 함과 아울러 생분해와 재활용이 가능하여 지속가능한 자원보존과 쓰레기를 줄일 수 있도록 하는 천연유래 계면활성제와 유효미생물을 포함하는 세정기능코팅액층이 구비되어 있는 친환경 건식 종이수세미의 제조방법을 제공하는 데 있다.Accordingly, the present invention is an improved invention in order to solve all the problems according to the prior art, and an object of the present invention is to enable easy cleaning of dishes, etc., as well as biodegradation and recycling, so that sustainable resource conservation and It is to provide a method of manufacturing an eco-friendly dry paper scrubber provided with a layer of a cleaning function coating liquid containing a natural surfactant and effective microorganisms to reduce waste.

그러나 본 발명의 목적은 상기에 언급된 목적으로 제한되지 않으며, 언급되지 않은 다른 목적들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.However, the object of the present invention is not limited to the above-mentioned object, and other objects that are not mentioned will be clearly understood by those skilled in the art from the following description.

상기한 목적을 달성하기 위한 본 발명에 따른 천연유래 계면활성제와 유효미생물을 포함하는 세정기능코팅액층이 구비되어 있는 친환경 건식 종이수세미의 제조방법은,
습강처리가 되어 있는 조직이 치밀한 1제곱미터당 40g ∼ 100g 평량 종이를 준비하는 제1단계와;
상기 제1단계 후, 준비된 종이를 코팅기에 거치하는 제2단계와;
상기 제2단계 후, 코팅기에 거치되어 있는 종이에 내구성 기능을 보다 더 확보 하기 위하여 아크릴계 고분자 수용성에멀전과 소수성 무기안료가 혼합된 수용성코팅액을 준비하고 준비된 수용성코팅액을 코팅기에 주입한 후, 코팅기를 동작시켜 수용성코팅액을 종이 상면에 1제곱미터당 3g ∼ 5g을 도포하여 종이가 찢어지지 않도록 수용성코팅액층을 형성하는 제3단계와;
상기 제3단계 후, 내구성 기능을 보다 더 확보 하기 위하여 수용성코팅액층이 형성된 종이를 섭씨 70℃ ∼ 150℃로 운전되고 있는 건조수단으로 보내어 수용성코팅액층이 건조된 종이를 얻는 제4단계와;
상기 제4단계 후, 수용성코팅액층이 건조된 종이에 식기가 세정될 수 있도록 천연유래 계면활성제와 유효미생물원액과 식물성 글리세린과 베이킹소다와 구연산과 에센셜오일과 허브추출물로 혼합된 세정기능코팅액을 준비하고 준비된 세정기능코팅액을 정제수에 희석하는 제5단계와;
상기 제5단계 후, 희석된 세정기능코팅액을 수용성코팅액층이 형성된 종이 저면에 1제곱미터당 10g ∼ 40g을 도포하여 세정기능코팅액층을 형성하는 제6단계와;
상기 제6단계 후, 수용성코팅액층과 세정기능코팅액층이 형성된 종이를 섭씨 70℃ ∼ 150℃로 운전되고 있는 건조수단으로 보내어 수용성코팅액층과 세정기능코팅액이 건조된 종이를 얻고, 건조된 종이를 와인딩장치(winding device)에 투입하여 롤(Roll)형태로 구불구불한 종이를 얻는 제7단계와;
상기 제7단계 후, 얻어진 롤형태 구불구불한 종이를 엠보싱장치에 투입하여 엠보싱된 롤형태 구불구불한 종이인 건식 종이수세미를 얻는 제8단계와;
상기 제8단계 후, 엠보싱된 건식 종이수세미를 용도에 맞게 슬리팅(slitting)하여 롤 타입이나 티슈 형태의 제품으로 포장하는 제9단계를 포함하되,
상기 제2단계에서 코팅기는 그라비아코팅기 또는 로드바타입코팅기 또는 에어나이프타입코팅기 또는 콤마타입코팅기이고,
상기 제5단계에서 천연유래 계면활성제는 코코넛 또는 대두 또는 콩 또는 사포닌 또는 사과에서 추출한 것으로, 소듐코코일애플아미노산(애플워시) 또는 데실글루코사이드 또는 라우릴글루코사이드 또는 코코글루코사이드이며,
상기 제5단계에서 희석비율은 정제수 60 ∼ 90중량부 기준으로 세정기능코팅액 10 ∼ 40중량부인 것을 특징으로 한다.
A method of manufacturing an eco-friendly dry paper scrubber provided with a cleaning function coating liquid layer containing a natural surfactant and effective microorganisms according to the present invention for achieving the above object,
A first step of preparing a basis weight paper of 40g to 100g per square meter with a dense tissue subjected to wet strength treatment;
A second step of placing the prepared paper in a coater after the first step;
After the second step, in order to further secure the durability function of the paper mounted on the coating machine, a water-soluble coating solution in which an acrylic polymer water-soluble emulsion and a hydrophobic inorganic pigment are mixed is prepared, and the prepared water-soluble coating solution is injected into the coating machine, and then the coating machine is operated. A third step of forming a water-soluble coating liquid layer to prevent tearing of the paper by applying 3g to 5g per square meter of the water-soluble coating liquid to the upper surface of the paper;
After the third step, the paper on which the water-soluble coating liquid layer is formed is sent to a drying means operated at 70°C to 150°C in order to further secure the durability function, thereby obtaining paper on which the water-soluble coating liquid layer is dried;
After the fourth step, prepare a cleaning functional coating solution mixed with a natural-derived surfactant, an effective microorganism stock solution, vegetable glycerin, baking soda, citric acid, essential oil, and herbal extracts so that dishes can be washed on paper on which the water-soluble coating layer is dried. And a fifth step of diluting the prepared washing function coating solution in purified water;
After the fifth step, a sixth step of forming a cleaning functional coating layer by applying 10g to 40g per square meter of the diluted washing functional coating solution to the bottom of the paper on which the aqueous coating layer is formed;
After the sixth step, the paper on which the water-soluble coating liquid layer and the washing functional coating liquid layer are formed is sent to a drying means operated at 70°C to 150°C to obtain a paper on which the water-soluble coating liquid layer and the cleaning functional coating liquid are dried, and the dried paper A seventh step of inputting the paper into a winding device to obtain a paper winding in the form of a roll;
After the seventh step, an eighth step of injecting the obtained roll-shaped serpentine paper into an embossing device to obtain a dry paper scrubber which is an embossed roll-shaped serpentine paper;
After the eighth step, including a ninth step of slitting the embossed dry paper scrubber to suit the purpose and packaging it as a roll-type or tissue-type product,
In the second step, the coating machine is a gravure coating machine, a rod bar type coating machine, an air knife type coating machine, or a comma type coating machine,
In the fifth step, the natural surfactant is extracted from coconut or soybean or soybean or saponin or apple, and is sodium cocoylapple amino acid (apple wash) or decyl glucoside or lauryl glucoside or coco glucoside,
The dilution ratio in the fifth step is characterized in that 10 to 40 parts by weight of the cleaning functional coating solution based on 60 to 90 parts by weight of purified water.

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이상에서 상술한 바와 같이 본 발명에 따른 천연유래 계면활성제와 유효미생물을 포함하는 세정기능코팅액층이 구비되어 있는 친환경 건식 종이수세미의 제조방법은 종이제에 일정량의 수용성 코팅액 및 세정기능코팅액을 함유하게 하여 건식으로 한장씩 뽑아서 쓰거나, 두루마리 형태로 일정 크기로 잘라서 사용할 수 있으며, 두루마리 종이호일처럼 일정크기를 사용자의 선호도에 따라 다양하게 잘라서 사용할 수 있는 편의성을 제공하는 효과가 있다.As described above, the method of manufacturing an eco-friendly dry paper scrubber provided with a cleaning function coating liquid layer containing a natural surfactant and effective microorganisms according to the present invention contains a certain amount of a water-soluble coating liquid and a cleaning function coating liquid in the paper. Therefore, it can be used by picking out one by one in a dry method, or cutting it into a certain size in the form of a scroll, and it has the effect of providing convenience to cut and use a certain size according to the user's preference, like a roll of paper foil.

그리고, 현재 사용되고 있는 부직포나 폴리프로필렌, 폴리에틸렌등의 수세미는 생분해가 어렵고, 음식물의 내부침투로 인하여 현실적으로 재활용도 할 수 없기에 쓰레기의 과대발생등으로 환경에 큰 위협이 되고 있는 관계로, 본 발명은 음식물이 종이 내부에 침투하지 않는 구조이기에 위생적이며, 재활용이 용이한 이점이 있다.In addition, since currently used scrubbers such as non-woven fabric, polypropylene, polyethylene, etc. are difficult to biodegrade, and cannot be recycled realistically due to internal penetration of food, the present invention poses a great threat to the environment due to excessive generation of garbage. It is hygienic because it is a structure that does not allow food to penetrate the inside of paper, and has the advantage of easy recycling.

그리고, 본 발명은 세정물 량에 따라 그에 맞게 사용하면 되기에 적정량의 세정제를 사용하는 효과와 수세미가 종이재질로 생분해와 재활용이 가능하여 지속가능한 자원보존 효과와 쓰레기를 줄일 수 있는 효과가 있다.In addition, the present invention has the effect of using an appropriate amount of cleaning agent to be used according to the amount of cleaning material, and the effect of biodegrading and recycling the scrubber with paper material, thereby conserving sustainable resources and reducing waste.

그리고, 본 발명은 전세계적인 코로나와 같은 전염병의 유행으로 실내보다는 야외에서 활동하기를 선호하여 등산이나 캠핑을 하는 사람들의 증가로 인하여 휴대가 간편하면서 쓰레기를 줄일 수 있는 제품의 필요성에 부합하는 효과가 있다.In addition, the present invention has an effect that meets the need for a product that can reduce garbage while being portable due to the increase of people who are hiking or camping because of the worldwide epidemic of infectious diseases such as corona. have.

그리고, 본 발명은 휴대가 상당히 간편하며, 따로 세정제를 휴대하지 않아도 되고, 자연에서 생분해가 되기 때문에 자연에 버려진다고 하여도 생분해 되기에 토양을 오염시키지 않는 효과가 있다.In addition, the present invention is very easy to carry, does not require a separate cleaning agent, and is biodegradable in nature, so even if it is discarded in nature, it is biodegradable and thus does not pollute the soil.

그리고, 본 발명은 물에 찢어지지 않도록 강화 코팅을 함으로써, 내구성이 뛰어난 효과가 있다.In addition, the present invention has an effect of excellent durability by applying a reinforcing coating so as not to be torn by water.

그리고, 본 발명은 부직포나 아크릴수세미처럼 도톰하고 거친 단면을 가지지 않도록 함과 동시에 조직이 치밀하게 하도록 내구성을 높이는 단계를 포함하여 종이제의 장점인 부드러움으로 인하여 일반 폴리계열의 수세미로 닦기 힘든 구석이나 좁은 부분은 종이의 부드러움으로 더 잘 닦을 수 있는 효과가 있다.In addition, the present invention does not have a thick and coarse cross-section like nonwoven fabric or acrylic scrubber, and at the same time includes the step of increasing the durability so that the structure is dense, and because of the softness that is an advantage of paper, a corner that is difficult to wipe with a general poly-based scrubber The narrow area has the effect of being able to wipe better with the softness of the paper.

특히, 본 발명은 세정물들과 닿은 면적이 치밀하게 밀착되어 표면에 있는 기름기를 좀 더 빠르게 닦아낼 수 있는 효과가 있다.In particular, the present invention has the effect that the area in contact with the cleaning products is closely contacted, so that the oil on the surface can be wiped off more quickly.

이하, 본 발명에 따른 천연유래 계면활성제와 유효미생물을 포함하는 세정기능코팅액층이 구비되어 있는 친환경 건식 종이수세미의 바람직한 실시 예를 설명한다.Hereinafter, a preferred embodiment of an eco-friendly dry paper scrubber provided with a cleaning function coating liquid layer containing a natural surfactant and effective microorganisms according to the present invention will be described.

하기에서 본 발명을 설명함에 있어서, 관련된 공지 기능 또는 구성에 대한 구체적인 설명이 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명을 생략할 것이다.In the following description of the present invention, if it is determined that a detailed description of a related known function or configuration may unnecessarily obscure the subject matter of the present invention, a detailed description thereof will be omitted.

본 발명에 따른 천연유래 계면활성제와 유효미생물을 포함하는 세정기능코팅액층이 구비되어 있는 친환경 건식 종이수세미의 제조방법을 살펴보면 다음과 같다.A method of manufacturing an eco-friendly dry paper scrubber provided with a cleaning function coating liquid layer containing a natural surfactant and effective microorganisms according to the present invention is as follows.

먼저, 습강처리가 되어 있는 조직이 치밀한 1제곱미터당 40g ∼ 100g 평량 종이를 준비한다.First, prepare a basis weight paper of 40g ~ 100g per square meter with a dense wet strength treatment.

여기서, 상기 습강은 종이가 물에 젖어도 잘 찢어지지 않도록 하는 처리공정이다.Here, the wet steel is a treatment process in which paper is not easily torn even when wet with water.

그리고, 상기 준비된 종이를 코팅기(그라비아코팅기 또는 로드바타입코팅기 또는 에어나이프타입코팅기 또는 콤마타입코팅기)에 거치한다.Then, the prepared paper is mounted on a coating machine (gravure coating machine, rod bar type coating machine, air knife type coating machine, or comma type coating machine).

그리고, 상기 코팅기에 거치되어 있는 종이가 찢어지지 않도록 내구성 기능을 보다 더 확보 하기 위하여 수용성코팅액을 준비하고 준비된 수용성코팅액을 코팅기에 주입한 후, 코팅기를 동작시켜 수용성코팅액을 종이 상면에 1제곱미터당 3g ∼ 5g을 도포하여 수용성코팅액층을 형성한다.And, in order to further secure the durability function so that the paper mounted on the coater does not break, a water-soluble coating solution is prepared, and the prepared water-soluble coating solution is injected into the coating machine, and then the water-soluble coating solution is applied to the top surface of the paper by operating the coating machine. Apply ~ 5g to form a water-soluble coating liquid layer.

여기서, 상기 수용성코팅액은 아크릴계 고분자 수용성에멀전과 소수성 무기안료가 혼합된 것이다.Here, the water-soluble coating liquid is a mixture of an acrylic polymer water-soluble emulsion and a hydrophobic inorganic pigment.

그리고, 내구성 기능을 보다 더 확보 하기 위하여 수용성코팅액층이 형성된 종이를 섭씨 70℃ ∼ 150℃로 운전되고 있는 건조수단으로 보내어 수용성코팅액층이 건조된 종이를 얻는다.And, in order to further secure the durability function, the paper on which the water-soluble coating liquid layer is formed is sent to a drying means operated at 70°C to 150°C to obtain the paper on which the water-soluble coating liquid layer is dried.

여기서, 상기 건조수단은 열풍건조기 또는 히팅 롤(Heating Roll)이다.Here, the drying means is a hot air dryer or a heating roll.

그리고, 상기 수용성코팅액층이 건조된 종이에 식기 등이 용이하게 세정될 수 있도록 세정기능코팅액을 준비한다.In addition, a cleaning function coating solution is prepared so that dishes and the like can be easily cleaned on the paper on which the water-soluble coating solution layer is dried.

여기서, 상기 세정기능코팅액은 천연유래 계면활성제와 유효미생물원액이 포함된 것이다.Here, the washing function coating solution contains a natural surfactant and an effective microbial stock solution.

상기 천연유래 계면활성제는 물과 기름처럼 서로 섞이지 않는 경계면에서 활동할 수 있는 분자를 말하며, 세정기능을 담당하고 있으며, 코코넛, 대두, 콩, 사포닌, 사과에서 추출한 것으로, 소듐코코일애플아미노산(애플워시) 또는 데실글루코사이드 또는 라우릴글루코사이드 또는 코코글루코사이드이다.The natural-derived surfactant refers to a molecule that can act on an interface that is not mixed with each other, such as water and oil, and is responsible for cleaning functions, and is extracted from coconut, soybean, soybean, saponin, and apple, and sodium cocoylapple amino acid (apple wash ) Or decylglucoside or laurylglucoside or cocoglucoside.

상기 유효미생물은 EM(Effective Micro-organisms)원액이며, 각종 유효미생물들이 공생하는 발효 용액으로 자연계에 존재하는 많은 미생물들 중에서 특히, 사람에게 유익한 효모, 유산균, 광합성세균의 유용한 미생물 군을 조합, 배양한 것이다.The effective microorganism is EM (Effective Micro-organisms) stock solution, and it is a fermentation solution in which various effective microorganisms coexist. Among many microorganisms present in nature, a combination and culture of useful microorganism groups such as yeast, lactic acid bacteria, and photosynthetic bacteria that are beneficial to humans in particular I did it.

유효미생물은 항산화 물질을 만들어 내고, 유효미생물 균에 의해 부패균 성장이 억제되어 악취와 유해한 물질의 생성을 막는 기능을 한다. 또한, 유효미생물 정착을 통해 자정능력(물이 오염물질을 스스로 분해하는 능력, 자연계에서의 정화작용 능력)을 회복시키고, 깨끗한 물로 되살려주는 역할을 하는 것으로 여러분야에서 다양하게 사용되고 있다.Effective microorganisms produce antioxidant substances, and the growth of spoilage bacteria is inhibited by effective microorganisms, preventing the generation of odors and harmful substances. In addition, it is used in various fields to restore self-cleaning ability (the ability of water to self-decompose pollutants, the ability to purify in nature) through the settlement of effective microorganisms, and to restore clean water.

상기 세정기능코팅액은 천연유래 계면활성제와 유효미생물원액과 식물성 글리세린과 베이킹소다와 구연산과 에센셜오일과 허브추출물의 천연유래 세정물질로 혼합된 것이다.The cleaning function coating solution is a mixture of a natural-derived surfactant, an effective microbial stock solution, vegetable glycerin, baking soda, citric acid, essential oil, and a natural-derived cleaning material of herbal extracts.

그리고, 상기 준비된 세정기능코팅액을 정제수에 희석을 한다.Then, the prepared washing function coating solution is diluted in purified water.

여기서, 희석비율은 정제수 60 ∼ 90중량부 기준으로 세정기능코팅액 10 ∼ 40중량부로 할 수 있다.Here, the dilution ratio may be 10 to 40 parts by weight of the washing function coating solution based on 60 to 90 parts by weight of purified water.

그리고, 상기 희석된 세정기능코팅액을 수용성코팅액층이 형성된 종이 저면에 1제곱미터당 10g ∼ 40g을 도포하여 세정기능코팅액층을 형성한다.In addition, 10g to 40g per square meter of the diluted cleaning functional coating liquid is applied to the bottom of the paper on which the aqueous coating liquid layer is formed to form a cleaning functional coating liquid layer.

그리고, 상기 수용성코팅액층과 세정기능코팅액층이 형성된 종이를 섭씨 70℃ ∼ 150℃로 운전되고 있는 건조수단으로 보내어 수용성코팅액층과 세정기능코팅액이 건조된 종이를 얻고, 건조된 종이를 와인딩장치(winding device)에 투입하여 롤(Roll)형태로 구불구불한 종이를 얻는다.Then, the paper on which the water-soluble coating liquid layer and the washing function coating liquid layer are formed is sent to a drying means operated at 70°C to 150°C to obtain a paper on which the water-soluble coating liquid layer and the washing function coating liquid are dried, and the dried paper is wound by a winding device ( winding device) to obtain a winding paper in the form of a roll.

그리고, 상기 얻어진 롤형태 구불구불한 종이를 엠보싱장치에 투입하여 엠보싱된 롤형태 구불구불한 종이인 건식 종이수세미를 얻는다.Then, the obtained roll-shaped serpentine paper is put into an embossing device to obtain a dry paper scrubber which is an embossed roll-shaped serpentine paper.

여기서, 상기 엠보싱의 목적은 건식 종이수세미의 닦임성의 기능을 높이기 위한 것이다.Here, the purpose of the embossing is to increase the wipeability function of the dry paper scrubber.

그리고, 상기 엠보싱된 건식 종이수세미를 용도에 맞게 슬리팅(slitting)하여 롤 타입이나 티슈 형태의 제품으로 포장한다.In addition, the embossed dry paper scrubber is slitting to suit the purpose and packaged as a roll-type or tissue-type product.

상기 발명의 상세한 설명은 단지 본 발명의 예시적인 것으로서, 이는 단지 본 발명을 설명하기 위한 목적에서 사용된 것이지 의미 한정이나 특허청구범위에 기재된 본 발명의 범위를 제한하기 위하여 사용된 것은 아니다.The detailed description of the present invention is merely illustrative of the present invention, and is used only for the purpose of describing the present invention, but not for limiting the meaning or limiting the scope of the present invention described in the claims.

그러므로 본 기술 분야의 통상의 지식을 가진 자라면 이로부터 다양한 변형 및 균등한 타 실시예가 가능하다는 점을 이해할 것이다. 따라서 본 발명의 진정한 기술적 보호 범위는 첨부된 특허청구범위의 기술적 사상에 의해 정해져야 할 것이다.Therefore, those of ordinary skill in the art will understand that various modifications and equivalent other embodiments are possible therefrom. Therefore, the true technical protection scope of the present invention should be determined by the technical spirit of the appended claims.

Claims (3)

습강처리가 되어 있는 조직이 치밀한 1제곱미터당 40g ∼ 100g 평량 종이를 준비하는 제1단계와;
상기 제1단계 후, 준비된 종이를 코팅기에 거치하는 제2단계와;
상기 제2단계 후, 코팅기에 거치되어 있는 종이에 내구성 기능을 보다 더 확보 하기 위하여 아크릴계 고분자 수용성에멀전과 소수성 무기안료가 혼합된 수용성코팅액을 준비하고 준비된 수용성코팅액을 코팅기에 주입한 후, 코팅기를 동작시켜 수용성코팅액을 종이 상면에 1제곱미터당 3g ∼ 5g을 도포하여 종이가 찢어지지 않도록 수용성코팅액층을 형성하는 제3단계와;
상기 제3단계 후, 내구성 기능을 보다 더 확보 하기 위하여 수용성코팅액층이 형성된 종이를 섭씨 70℃ ∼ 150℃로 운전되고 있는 건조수단으로 보내어 수용성코팅액층이 건조된 종이를 얻는 제4단계와;
상기 제4단계 후, 수용성코팅액층이 건조된 종이에 식기가 세정될 수 있도록 천연유래 계면활성제와 유효미생물원액과 식물성 글리세린과 베이킹소다와 구연산과 에센셜오일과 허브추출물로 혼합된 세정기능코팅액을 준비하고 준비된 세정기능코팅액을 정제수에 희석하는 제5단계와;
상기 제5단계 후, 희석된 세정기능코팅액을 수용성코팅액층이 형성된 종이 저면에 1제곱미터당 10g ∼ 40g을 도포하여 세정기능코팅액층을 형성하는 제6단계와;
상기 제6단계 후, 수용성코팅액층과 세정기능코팅액층이 형성된 종이를 섭씨 70℃ ∼ 150℃로 운전되고 있는 건조수단으로 보내어 수용성코팅액층과 세정기능코팅액이 건조된 종이를 얻고, 건조된 종이를 와인딩장치(winding device)에 투입하여 롤(Roll)형태로 구불구불한 종이를 얻는 제7단계와;
상기 제7단계 후, 얻어진 롤형태 구불구불한 종이를 엠보싱장치에 투입하여 엠보싱된 롤형태 구불구불한 종이인 건식 종이수세미를 얻는 제8단계와;
상기 제8단계 후, 엠보싱된 건식 종이수세미를 용도에 맞게 슬리팅(slitting)하여 롤 타입이나 티슈 형태의 제품으로 포장하는 제9단계를 포함하되,
상기 제2단계에서 코팅기는 그라비아코팅기 또는 로드바타입코팅기 또는 에어나이프타입코팅기 또는 콤마타입코팅기이고,
상기 제5단계에서 천연유래 계면활성제는 코코넛 또는 대두 또는 콩 또는 사포닌 또는 사과에서 추출한 것으로, 소듐코코일애플아미노산(애플워시) 또는 데실글루코사이드 또는 라우릴글루코사이드 또는 코코글루코사이드이며,
상기 제5단계에서 희석비율은 정제수 60 ∼ 90중량부 기준으로 세정기능코팅액 10 ∼ 40중량부인 것을 특징으로 하는 천연유래 계면활성제와 유효미생물을 포함하는 세정기능코팅액층이 구비되어 있는 친환경 건식 종이수세미의 제조방법.


A first step of preparing a basis weight paper of 40g to 100g per square meter with a dense tissue subjected to wet strength treatment;
A second step of placing the prepared paper in a coater after the first step;
After the second step, in order to further secure the durability function of the paper mounted on the coating machine, a water-soluble coating solution in which an acrylic polymer water-soluble emulsion and a hydrophobic inorganic pigment are mixed is prepared, and the prepared water-soluble coating solution is injected into the coating machine, and then the coating machine is operated. A third step of forming a water-soluble coating liquid layer to prevent tearing of the paper by applying 3g to 5g per square meter of the water-soluble coating liquid to the upper surface of the paper;
After the third step, the paper on which the water-soluble coating liquid layer is formed is sent to a drying means operated at 70°C to 150°C in order to further secure the durability function, thereby obtaining paper on which the water-soluble coating liquid layer is dried;
After the fourth step, prepare a cleaning functional coating solution mixed with a natural-derived surfactant, an effective microorganism stock solution, vegetable glycerin, baking soda, citric acid, essential oil, and herbal extracts so that dishes can be washed on paper on which the water-soluble coating layer is dried. And a fifth step of diluting the prepared washing function coating solution in purified water;
After the fifth step, a sixth step of forming a cleaning functional coating layer by applying 10g to 40g per square meter of the diluted washing functional coating solution to the bottom of the paper on which the aqueous coating layer is formed;
After the sixth step, the paper on which the water-soluble coating liquid layer and the washing functional coating liquid layer are formed is sent to a drying means operated at 70°C to 150°C to obtain a paper on which the water-soluble coating liquid layer and the cleaning functional coating liquid are dried, and the dried paper A seventh step of inputting the paper into a winding device to obtain a paper winding in the form of a roll;
After the seventh step, an eighth step of injecting the obtained roll-shaped serpentine paper into an embossing device to obtain a dry paper scrubber which is an embossed roll-shaped serpentine paper;
After the eighth step, including a ninth step of slitting the embossed dry paper scrubber to suit the purpose and packaging it as a roll-type or tissue-type product,
In the second step, the coating machine is a gravure coating machine, a rod bar type coating machine, an air knife type coating machine, or a comma type coating machine,
In the fifth step, the natural surfactant is extracted from coconut or soybean or soybean or saponin or apple, and is sodium cocoylapple amino acid (apple wash) or decyl glucoside or lauryl glucoside or coco glucoside,
In the fifth step, the dilution ratio is 10 to 40 parts by weight of a washing function coating solution based on 60 to 90 parts by weight of purified water. An eco-friendly dry paper scrubber provided with a layer of a washing function coating solution containing a natural surfactant and effective microorganisms. Method of manufacturing.


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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102389932B1 (en) * 2022-03-16 2022-04-22 박현주 Disposable scrubber having detergent and Method for manufacturing the scrubber
KR102392213B1 (en) * 2021-07-23 2022-04-29 (주)유진 A process for the preparation of eco-friendly loofah and eco-friendly loofah prepared therefrom

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Publication number Priority date Publication date Assignee Title
JP2000248298A (en) * 1999-02-26 2000-09-12 Lion Corp Cleaning sheet
KR20140134277A (en) * 2012-02-24 2014-11-21 다닐로 론코 Cellulose-based paper containing cleansing agents capable of disaggregating in aqueous liquids and of being wound into continuous rolls

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000248298A (en) * 1999-02-26 2000-09-12 Lion Corp Cleaning sheet
KR20140134277A (en) * 2012-02-24 2014-11-21 다닐로 론코 Cellulose-based paper containing cleansing agents capable of disaggregating in aqueous liquids and of being wound into continuous rolls

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102392213B1 (en) * 2021-07-23 2022-04-29 (주)유진 A process for the preparation of eco-friendly loofah and eco-friendly loofah prepared therefrom
KR102389932B1 (en) * 2022-03-16 2022-04-22 박현주 Disposable scrubber having detergent and Method for manufacturing the scrubber

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