KR102207016B1 - Modified-Asphalt Concrete Compositions for Roads Using Latex Resin and Constructing Methods Using Thereof - Google Patents

Abstract

The present invention provides a modified asphalt concrete composition for roads comprising a latex resin. The modified asphalt concrete composition for roads comprises, based on 100 parts by weight of asphalt: 1 to 25 parts by weight of a latex resin; 1 to 25 parts by weight of a styrene ethylene butylene styrene copolymer; 1 to 25 parts by weight of a petroleum resin; 1 to 10 parts by weight of a modifier; 500 to 2,000 parts by weight of aggregates; 30 to 150 parts by weight of fine powder aggregates; 0.1 to 2 parts by weight of sodium benzoate; 0.1 to 2 parts by weight of cellulose fiber; 0.1 to 2 parts by weight of wax; 0.1 to 2 parts by weight of an antioxidant; and 0.1 to 2 parts by weight of a stabilizer. The modified asphalt concrete composition for roads according to the present invention, specifically, the modified asphalt concrete composition for roads comprising a latex resin has high cohesion and high bonding force and thus has good durability, has good elastic force and can prevent plastic deformation, aging, and/or peeling from occurring easily and thus can prevent infiltrating water and portholes, and can enable a placing process to be easily carried out at low costs.

Description

Modified-Asphalt Concrete Compositions for Roads Using Latex Resin and Constructing Methods Using Thereof}

The present invention relates to a modified asphalt concrete composition for roads containing a latex resin and a construction method thereof, and more particularly, a modified asphalt concrete composition for roads containing a latex resin for improving the properties of the asphalt concrete composition and a construction method thereof It is about.

Recently, a problem has occurred in the common performance of road paving materials, and various studies are being conducted in the production and construction of road paving materials.

In particular, modified asphalt is gradually being used as a material to reduce plastic deformation and temperature cracks caused by temperature differences in Korea since the mid-1990s.

Currently, many companies are conducting research and material development work to improve the physical performance of the binder.

The civil engineering industry is putting a lot of effort into improvement of construction methods and quality control.

As new construction methods for construction crack control, there are Echelon Paving (a construction method that suppresses the occurrence of longitudinal joints by placing two lanes simultaneously) and Material Transfer Vehicle (MTV), and the above construction methods prevent uneven compaction due to temperature deviation and are uniform. This is a method to improve the packaging quality by securing the laying temperature.

However, there is still no fundamental solution to problems such as deformation and damage of pavements and portholes caused by stormwater penetration.

In addition, there is a method of applying specially processed epoxy resin to the surface of the bridge steel deck to form a waterproof and anti-corrosive layer, spraying silica to make an anti-slip layer, and then attaching ascon on it.

However, the above method can only form an adhesive layer utilizing the adhesive performance and waterproof performance of an epoxy material, and it is impossible to apply the base layer and the surface layer as a packaging structure.

In order to overcome this problem, Korean Patent Laid-Open No. 10-2010-0079385 includes 15 to 75% by weight of a base material including epoxy resin, aerosol, dispersant and ceramic powder, and modified aliphatic polyamine and tertiary amine. A composite composition for bridge pavement or road pavement comprising 5 to 25% by weight of a hardener and 15 to 75% by weight of an aggregate is disclosed.

On the other hand, in general, asphalt is a black or dark brown solid or semi-solid thermoplastic material composed of a very complex composition of thousands or more of high molecular hydrocarbons (CH) containing organic compounds and trace amounts of inorganic compounds, and gradually changes to a liquid state when heated. Have.

The asphalt is divided into natural asphalt, petroleum-based asphalt, and paving tar, and straight asphalt and emulsified asphalt are widely known.

In addition, the asphalt is used as a bonding material or an adhesive material because it has excellent adhesion and excellent adhesion to mineral materials, and is also used as a waterproof material because it is not soluble in water and is impermeable, and the viscosity can be changed according to the purpose of use. Its application range is diverse, and it is used for various purposes such as road pavement, waterproofing, general industrial use, and agricultural use.

Asphalt used for road pavement is petroleum-based asphalt, straight asphalt having excellent adhesion, extensibility, and water absorption is generally used.

However, since straight asphalt has a low softening point, high temperature sensitivity, low weather resistance, and low cohesive strength, it is supplemented and used by adding various modifiers to suit the characteristics of the place where it is used.

In general, the types of asphalt modifiers include rubber, thermoplastic resin, thermosetting resin, hydrocarbon, filler, fiber, antioxidant, reducing agent, and natural rubber, styrene butadiene rubber (SBR), and waste tires. (Crumb Rubber), etc. are used, and Styrene Butadiene Styrene (SBS), Ethylenevinylacetate (EVA), Polyethylene (PE), Polypropylene (PP), Polyvinyl Chloride (PVC), Polyethylene Terephthalate (PET), etc. are used for the thermoplastic resin series. , Epoxy resin, urethane resin, acrylic resin, phenol resin, petroleum resin, etc. are used in the thermosetting resin series, and natural asphalt and gilsonite are used in the hydrocarbon series.

However, the asphalt modifiers developed so far have problems with cracks and plastic deformation of the pavement, which appears as asphalt decreases resistance to low-temperature cracks and fatigue cracks after construction due to the large temperature difference of the four seasons. There are problems such as oxidation of asphalt caused by exposure to sunlight and aggregate desorption due to weakening of adhesion. In addition, the plant-mix type is not easy to secure uniform quality, and the pre-mix type (pre-mix type) Mixtype) Modified asphalt is difficult to preserve because it is difficult to uniformly mix the constituents, and because each constituent such as the modifying material and asphalt depends on the physical combination, it has poor storage properties.

In particular, since 2000, modified concrete, which has improved the performance of concrete with fast-setting cement and polymer, has been developed, and has been widely used as a repair material for concrete road structures due to its short curing time, high water permeability and freezing and thawing resistance.

However, since the modified concrete contains a large amount of latex, the cost is high, and the heat reflectance is high, so the prevention effect of early freezing in winter is inferior to that of conventional asphalt concrete, and the heat absorption rate is low, as in Korea, as in Korea In an environment where) is severe, there is a problem that cracks, surface peeling, and falling out (portholes) occur due to temperature stress.

Moreover, in some bridges and special areas where the ground/congestion is severe and the heavy vehicle ratio is high, it is difficult to withstand general modified asphalt (PMA) pavement.

Therefore, a very strong asphalt pavement should be constructed thick, but in the case of general asphalt pavement, not only should it be thick, but also have strong elasticity, toughness, and tensile strength.

In general, a waterproofing process is involved in preventing deterioration of the lower layer in concrete bridges as well as steel box girder bridges.

However, the waterproof layer (such as a coating or coating) has a problem in that it has no structural performance and is expensive.

Therefore, as mentioned above, if a mixture having excellent elasticity and a mixture having high toughness and tensile strength but accompanied by a high adhesion function is applied, an asphalt pavement that exhibits structural performance and durability at the same time can be achieved, and thus it can withstand excessive traffic loads. It is an asphalt pavement with excellent durability and functions, so it is easy to construct and to open traffic quickly.

Meanwhile, as a prior art related to the above-described technology, Korean Patent Publication No. 10-2016-0106070 discloses a polymer-modified asphalt composition and a method for producing a polymer-modified asphalt concrete using the same.

The present invention has been created to overcome the above-described problems, and has good durability, does not easily cause plastic deformation, aging, and/or peeling, while a modification for road pavement comprising a latex resin capable of preventing permeation and portholes. Provides an asphalt concrete composition.

The present invention

Based on 100 parts by weight of asphalt,

1 to 25 parts by weight of a latex resin;

1 to 25 parts by weight of a styrene ethylene butylene styrene copolymer;

1 to 25 parts by weight of petroleum resin;

1 to 10 parts by weight of a modifier;

500 to 2,000 parts by weight of aggregate;

30 to 150 parts by weight of fine powder aggregate;

0.1 to 2 parts by weight of sodium benzoate;

0.1 to 2 parts by weight of cellulose fibers;

0.1 to 2 parts by weight of wax;

0.1 to 2 parts by weight of an antioxidant; And

It provides a modified asphalt concrete composition for roads comprising a latex resin containing 0.1 to 2 parts by weight of a stabilizer.

In addition, the present invention

An arrangement step of arranging the target surface to be constructed;

1 to 25 parts by weight of latex resin, 1 to 25 parts by weight of styrene ethylene butylene styrene copolymer, 1 to 25 parts by weight of petroleum resin, 1 to 10 parts by weight of modifier Parts, 500 to 2,000 parts by weight of aggregate, 30 to 150 parts by weight of fine powder aggregate, 0.1 to 2 parts by weight of sodium benzoate, 0.1 to 2 parts by weight of cellulose fiber, 0.1 to 2 parts by weight of wax, 0.1 to 2 parts by weight of antioxidant, and A pouring step of pouring a modified asphalt concrete composition for roads containing a latex resin containing 0.1 to 2 parts by weight of a stabilizer;

A compaction step of compacting the modified asphalt concrete composition for roads containing the latex resin poured after the pouring step is finished; And

It provides a method of constructing a modified asphalt concrete composition for roads comprising a latex resin comprising a curing step of curing the modified asphalt concrete composition for roads comprising a latex resin after the compaction step is completed.

The modified asphalt concrete composition for roads according to the present invention, specifically the modified asphalt concrete composition for roads containing a latex resin, has high cohesion and high bonding strength, so that it has good durability, good elasticity, and plastic deformation, aging and/or peeling Is not easily generated, there is an effect of preventing permeation water and portholes, and making it easy to perform the pouring process at low cost.

Hereinafter, the present invention will be described in detail.

In one aspect, the present invention, based on 100 parts by weight of asphalt, 1 to 25 parts by weight of latex resin; 1 to 25 parts by weight of a styrene ethylene butylene styrene copolymer; 1 to 25 parts by weight of petroleum resin; 1 to 10 parts by weight of a modifier; 500 to 2,000 parts by weight of aggregate; 30 to 150 parts by weight of fine powder aggregate; 0.1 to 2 parts by weight of sodium benzoate; 0.1 to 2 parts by weight of cellulose fibers; 0.1 to 2 parts by weight of wax; 0.1 to 2 parts by weight of an antioxidant; And it provides a modified asphalt concrete composition for roads comprising a latex resin containing 0.1 to 2 parts by weight of a stabilizer.

In another aspect, the present invention is a cleanup step of arranging the target surface to be constructed; 1 to 25 parts by weight of latex resin, 1 to 25 parts by weight of styrene ethylene butylene styrene copolymer, 1 to 25 parts by weight of petroleum resin, 1 to 10 parts by weight of modifier Parts, 500 to 2,000 parts by weight of aggregate, 30 to 150 parts by weight of fine powder aggregate, 0.1 to 2 parts by weight of sodium benzoate, 0.1 to 2 parts by weight of cellulose fiber, 0.1 to 2 parts by weight of wax, 0.1 to 2 parts by weight of antioxidant, and A pouring step of pouring a modified asphalt concrete composition for roads containing a latex resin containing 0.1 to 2 parts by weight of a stabilizer; A compaction step of compacting the modified asphalt concrete composition for roads containing the latex resin poured after the pouring step is finished; And it provides a method for constructing a modified asphalt concrete composition for roads comprising a latex resin comprising a curing step of curing the modified asphalt concrete composition for roads comprising a latex resin after the compaction step is completed.

The asphalt according to the present invention is not particularly limited as long as it is an asphalt commonly used in the art, but petroleum-based asphalt such as straight asphalt or an asphalt mixture may be used.

Here, it is recommended to use a natural asphalt mixture as the asphalt mixture.

The asphalt mixture, in particular, the natural asphalt mixture is not particularly limited as long as it is a natural asphalt mixture commonly used in the art, but preferably straight asphalt, Trinidad lake asphalt, Trinidad epure (Trinidad epure) ) It is preferable to use asphalt or a mixture of at least one or more selected from these, more preferably a mixture of straight asphalt and natural asphalt with a penetration degree of 20 to 40, for example Trinidadrake asphalt and/or Trinidad ePure asphalt. It is recommended to use a mixture of 70 to 80% by weight of straight asphalt having a penetration degree of 20 to 40 and 20 to 30% by weight of natural asphalt consisting of Trinidad Epure asphalt or Trinidad ePure asphalt.

Here, the straight asphalt is a conventional asphalt obtained by distilling or distilling the raw material with petroleum asphalt and purifying the residue, especially those having an intrusion degree of 20 to 40 are better because they are easy to install on roads, alone or It is better to mix it with the asphalt mixture.

The straight asphalt is preferably contained in the asphalt mixture in an amount of 70 to 80% by weight. If the content is less than 70% by weight, it may take a long time to harden after paving the asphalt, the softening point may be lowered, and if it exceeds 80% by weight, the fluidity may be lowered.

In addition, the natural asphalt serves to improve the fluidity of the modified asphalt concrete composition for roads including the latex resin according to the present invention, and to increase deformation resistance, sliding resistance, and friction resistance.

As the natural asphalt, Trinidad lake asphalt and/or Trinidad epure asphalt may be used.

The natural asphalt is preferably included in the asphalt mixture in an amount of 20 to 30% by weight, and when the content is less than 20% by weight, the effect of improving fluidity, deformation resistance, sliding resistance and friction resistance is insignificant, and exceeds 30% by weight. If so, the asphalt of the present invention may be softened and the softening point may be lowered.

The content of the remaining components other than the asphalt constituting the modified asphalt concrete composition for roads according to the present invention, specifically the modified asphalt concrete composition for roads containing latex resin, is based on 100 parts by weight of asphalt.

The latex resin according to the present invention is mixed with an asphalt concrete composition, specifically a modified asphalt concrete composition for roads containing latex resin to maintain the flexibility of asphalt concrete in winter, prevent low-temperature cracking, and physical properties of asphalt concrete. In order to improve overall, any conventional latex resin in the art for this purpose may be used, but preferably, an inorganic reactive group (CxHyOz, CaHb), which is a terminal group of the silane, is incorporated by mixing a silane coupling agent into the latex resin. ) To a latex resin solution having a solid content of 40 to 50% by weight, a silicone resin solution in which 1 to 10% by weight of a silane coupling agent and ethanol are mixed in a ratio of 1:1.5 to 3 by weight compared to the latex resin solution It is better to use those prepared by stirring.

On the other hand, the amount of the preferred latex resin is not particularly limited according to the user's selection, but is preferably 1 to 25 parts by weight based on 100 parts by weight of asphalt.

Styrene Ethylene Butylene Styrene (SEBS) copolymer according to the present invention is a polymer having excellent stability in which all double bonds in butadiene of a styrene butadiene styrene block copolymer (SBS) resin are saturated with hydrogenation It can add elasticity to the asphalt concrete composition.

In addition, the styrene ethylene-butylene styrene is a block copolymer based on styrene and butadiene and has rubber-like elasticity, and while most rubbers are not easily molded due to crosslinking, they can be reshaped into thermoplastic rubber. Therefore, when heated above the Tg temperature of polystyrene, the domains soften and flow with shearing force, and when cooled, the domains can be reproduced again, so it can be easily molded using a thermoplastic molding method.

On the other hand, since the styrene ethylene butylene styrene copolymer is not thermally decomposed, there is no fear of harmful odors to the human body, elastic resilience and permanent deformation resistance are improved, and durability, cold resistance, abrasion resistance, and resilience are excellent.

A preferred amount of the styrene ethylene butylene styrene copolymer is not particularly limited, but is preferably 1 to 25 parts by weight based on 100 parts by weight of asphalt.

The petroleum resin according to the present invention is to provide high adhesion to a modified asphalt concrete composition for roads, specifically a modified asphalt concrete composition for roads containing a latex resin, and petroleum commonly used in the art for this purpose Resins, preferably aromatic petroleum resins, aliphatic petroleum resins, or mixtures thereof may be used, and particularly preferably, the melting temperature is 100°C or higher, the penetration degree is 3dmm or less, and the viscosity (hereinafter, 140°C viscosity) is 50 A petroleum resin having a melting temperature of 110°C to 140°C, penetration of 0.5 to 2dmm, and a viscosity of 140°C to 50 to 300 cps is preferable, but more recommended is a viscosity of 100 to 150 cps. Phosphorus aliphatic C-5 petroleum resin is recommended.

A preferred amount of petroleum resin used is not particularly limited, but it is recommended that it is 1 to 25 parts by weight based on 100 parts by weight of asphalt.

The modifier according to the present invention improves the durability and fluidity of the modified asphalt concrete composition for roads, specifically the modified asphalt concrete composition for roads containing latex resin, and increases fluidity at high temperatures and inhibits cracking at low temperatures. As for this purpose, any modifier having this purpose may be used, but preferably rubber, plastic or a mixture thereof may be used.

As a preferred rubber, it is recommended to use natural rubber, styrene-butadiene (SB), polypropene latex, ground rubber, or at least one or more mixtures selected from these.

As a preferred plastic, it is recommended to use polypropylene (PP), ethylene acrylic copolymer, polyvinyl chloride, ethylene propylene, polyolefin, or a mixture of at least one selected from these.

The preferred amount of modifier can be changed according to the user's choice, but it is recommended that it is 1 to 10 parts by weight based on 100 parts by weight of asphalt.

The aggregate according to the present invention is a mineral material for construction that can form a lump by being aggregated by a binder such as asphalt, latex resin, styrene isoprene styrene and/or petroleum resin, and is chemically stable.

The aggregate refers to sand, gravel, basalt, pitted stone, basalt, and other similar materials.

Specifically, it may further include a basic malt having an absorption rate of about 0.7% as the aggregate.

Here, it is preferable to use the aggregate having an average particle size of 0.08 to 13 mm, specifically, those having an average particle size of 0.08 mm or more and less than 4.76 mm are referred to as fine aggregates, and those of 4.76 mm or more are referred to as coarse aggregates.

The preferred amount of aggregate is preferably 500 to 2,000 parts by weight based on 100 parts by weight of asphalt, and the amount of fine aggregate and coarse aggregate contained in the aggregate is not particularly limited, and thus can be appropriately adjusted as needed.

The fine powder aggregate according to the present invention is to be filled in the pores between the aggregate, specifically fine aggregate and coarse aggregate, to improve waterproofness, etc., and any fine powder aggregate commonly used in the art for this purpose is used. It is also okay.

It is recommended that the size of the fine powder aggregate has an average particle size of at least 0.08 mm, more preferably 0.001 to 0.079 mm, and the amount used is preferably 30 to 150 parts by weight based on 100 parts by weight of asphalt.

In addition, the fine powder aggregate refers to a fine stone powder, a limestone fine powder, a sand fine powder, a gravel fine powder, a basalt fine powder, a crushed stone fine powder, a basalt fine powder, and other similar materials.

Sodium benzoate according to the present invention provides viscoelasticity and elasticity of a modified asphalt concrete composition for roads containing latex resin.

The preferred amount of sodium benzoate can be changed according to the user's choice, but it is recommended that it is 0.1 to 2 parts by weight based on 100 parts by weight of asphalt, and the effect is less than 0.1 parts by weight based on 100 parts by weight of asphalt. It is insignificant, and if it exceeds 2 parts by weight, it becomes excessive and may reduce physical properties, which is not good.

The cellulose fiber according to the present invention is to provide tensile strength and/or light weight due to stress applied in the longitudinal-transverse direction of the poured surface formed of a modified asphalt concrete composition for roads containing a latex resin, and has this purpose. Any cellulose fiber may be used, but it is preferable to use natural cellulose fiber, and the amount thereof is preferably 0.1 to 2 parts by weight based on 100 parts by weight of asphalt.

Wax according to the present invention is an asphalt concrete composition, specifically a modified asphalt concrete composition for roads, more specifically to lower the temperature required for the production and / or construction of a modified asphalt concrete composition for roads containing latex resin compared to the conventional method , Preferably, it is to minimize the emission of carbon dioxide and harmful substances by allowing it to be lowered by about 20 to 40°C, and any conventional wax used for this purpose may be used, but preferably polyethylene wax is used. It is good to use, and the amount is preferably 0.1 to 2 parts by weight based on 100 parts by weight of asphalt.

As a specific embodiment, the wax according to the present invention may be a mixture mixed with a modified fatty acid. In this case, the wax, specifically polyethylene wax, is preferably mixed with a modified fatty acid in a weight ratio of 1:0.1 to 0.6. .

Here, it is preferable that the polyethylene wax has a melting point of 95 to 125°C and a melt viscosity of 80 to 400 cPs at about 140°C.

At this time, if the melting point of the polyethylene wax is less than 95°C, the stiffness of the asphalt may be weakened when mixed with the asphalt, and if the melting point exceeds 125°C, it is sufficiently dispersed in the modified asphalt concrete composition for roads containing latex resin. And there is a risk of deterioration of properties.

In addition, when the melt viscosity of polyethylene wax at 140°C is less than 80 cPs, the high-temperature properties are weakened, making it unsuitable as asphalt for road pavement.When the melt viscosity at 140°C exceeds 400 cPs, the viscosity of the asphalt becomes too high to produce asphalt concrete composition and There may be a problem that the process is not performed properly during pouring.

On the other hand, the modified fatty acid used by mixing with the wax serves to improve the moisture sensitivity of the asphalt concrete composition while supplementing the neutralization function of the polyethylene wax.

Specifically, the modified fatty acid is obtained by melt-reacting a fatty acid having 12 to 24 carbon atoms with at least one selected from the group consisting of calcium hydroxide, magnesium hydroxide, zinc hydroxide and zinc oxide in terms of the effect of improving the moisture sensitivity of the asphalt concrete composition. desirable.

In addition, it is preferable that the modified fatty acid has a melting point in the range of 110 to 140°C. When the melting point of the modified fatty acid is out of the above range and is higher than the manufacturing temperature of the asphalt concrete composition, the effect of supplementing the medium temperature function and improving the moisture sensitivity cannot be obtained.

The antioxidant according to the present invention is for preventing oxidation of an asphalt concrete composition, specifically a modified asphalt concrete composition for roads containing a latex resin.

Preferred antioxidants may be amine-based, bisphenol-based, monophenol-based and sulfur-based antioxidants, and the amount thereof is preferably 0.1 to 2 parts by weight based on 100 parts by weight of asphalt.

Specifically, the antioxidant according to the present invention is a low-molecular/high-molecular phenolic antioxidant, for example 2.2-methylenebis(4-methyl-6-t-butylphenol)[2. 2-M ethylenebis (4-methyl-6-t-butylphenol )], 2.6-di-t-butyl-4-methylphenol (2.6-di -t-Butyl-4-methylphenol) or mixtures thereof I recommend you.

The stabilizer according to the present invention is to provide stability by protecting the modified asphalt concrete composition for roads containing latex resin from ultraviolet rays, and any conventional stabilizer in the art having such a purpose may be used, but preferably It is recommended to use an acrylic polyol resin, a non-yellowing polyurea resin, a polyisocyanate, or a mixture thereof, and the amount is recommended to be 0.1 to 2 parts by weight based on 100 parts by weight of asphalt.

The asphalt concrete composition according to the present invention, specifically the modified asphalt concrete composition for roads, and more specifically the modified asphalt concrete composition for roads containing a latex resin, comprises one or more additives implemented in the following specific embodiments. It may contain more.

As a specific embodiment, the asphalt concrete composition according to the present invention, specifically the modified asphalt concrete composition for roads, and more specifically the modified asphalt concrete composition for roads comprising a latex resin, cracks and cracks even after rapid curing after the composition is placed. The polyvinylidene fluoride resin may be further included in an amount of 0.1 to 4 parts by weight based on 100 parts by weight of asphalt in order to improve the dropping phenomenon and provide processability, adhesion and stability of the composition.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 0.1 to 3 parts by weight based on 100 parts by weight of asphalt in order to improve the adsorption and adhesion of the composition, and to improve the reaction speed when the composition is mixed. It may further include a weight part of 2-bromopyridine (2-Bromopyridine).

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 0.1 to 3 parts by weight based on 100 parts by weight of asphalt in order to prevent separation of materials due to the difference in specific gravity between the components of the composition. It may further include welan gum.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 0.1 to 4 parts by weight of neopentyl glycol (Neopentylglycol, NPG) based on 100 parts by weight of asphalt to prevent shrinkage during curing of the composition. It may further include.

In another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention comprises 0.1 to 5 parts by weight of a plaster based on 100 parts by weight of asphalt so that the components included in the composition are easily mixed with water. It may contain more.

Here, when the amount of the plaster used is less than 0.5 parts by weight based on 100 parts by weight of asphalt, it is difficult for various components included in the composition to be easily mixed with water, and when it exceeds 5 parts by weight, strength and chemical resistance are deteriorated. There is.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is used to improve plasticity and water retention of the composition, and to prevent cracking and increase strength, in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of asphalt. It may further contain betaine.

As another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention may further include 0.1 to 5 parts by weight of gibbsite based on 100 parts by weight of asphalt in order to improve strength, abrasion resistance, and fire resistance. .

Here, when the amount of gibsite is less than 0.1 parts by weight, the performance improvement effect may be weak, and when the amount of gibsite is more than 5 parts by weight, workability decreases and manufacturing cost increases, which is not economical.

As another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention may further contain 0.1 to 5 parts by weight of cerium based on 100 parts by weight of asphalt in order to improve strength, fire resistance and corrosion resistance.

In another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 1 to 3 parts by weight of ferrite based on 100 parts by weight of asphalt in order to improve the long-term strength, corrosion resistance and fire resistance of the composition. It may further include, and if the content exceeds 3 parts by weight based on 100 parts by weight of asphalt, it exhibits rapid hardening properties, but the economy is poor, and if it is less than 1 part by weight, the above-described improvement effect is insignificant and is not good.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 0.1 to 4 parts by weight of halo based on 100 parts by weight of asphalt in order to improve the strength, fire resistance, abrasion resistance, and corrosion resistance of the composition. It may further include a halloysite, and the halloysite is a clay mineral containing aluminum and silicon in a ratio of about 1:1, and when it is included in the composition, the above effect is expressed.

As another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention may further include 0.1 to 4 parts by weight of zinc ammonium chloride based on 100 parts by weight of asphalt in order to enhance wet strength and abrasion resistance. have.

As another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention may further include 0.1 to 5 parts by weight of phylum powder based on 100 parts by weight of asphalt in order to improve the breathability and oil absorption of the composition. , The phyllite is a type of metamorphic rock that is formed through processes such as hydrolysis and metamorphism, weathering and corrosion in the clay sediment layer, and its main components include silica, alumina, and metal oxides. It contains voids and has a porosity that is almost similar to that of zeolite, but has a large fraction of foam, and when it is included in a modified asphalt concrete composition for roads containing latex resin, it has the same effect as described above. The average particle size of the powder is 3 to 30 μm.

In another specific aspect, the modified asphalt concrete composition for roads containing the latex resin according to the present invention penetrates into the voids of the construction surface on which the modified asphalt concrete composition for roads containing the latex resin is constructed to closely maintain the structure of latex. Bauxite powder may be further included in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of asphalt in order to prevent lift and improve durability and adhesion strength of the modified asphalt concrete composition for roads containing resin, and the average particle size of the preferred bauxite powder Is 1 to 10 μm.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention may further include dibutylphthalate in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt to prevent cracking and peeling of the composition. have.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is based on 100 parts by weight of asphalt in order to improve the strength, penetration, and water repellency of the composition. It may further include 1 to 3 parts by weight.

In another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention further comprises 1 to 3 parts by weight of gelite fine powder based on 100 parts by weight of asphalt in order to develop long-term strength and improve durability of the composition. The gelite is a mineral that has an effect of 187 times or more of loess, and has a high-quality far-infrared emission effect in addition to the above effect, and the preferred average particle size is 1 to 5 μm.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is based on 100 parts by weight of asphalt citric acid in order to prevent condensation of the material constituting the composition and secure a certain working time. It may further include 5 parts by weight.

In another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 1 to 5 parts by weight of sodium stea based on 100 parts by weight of asphalt in order to ensure breathability while preventing moisture penetration into the surface of the composition. The rate may be further included, and if the content is less than 1 part by weight based on 100 parts by weight of asphalt, the desired moisture penetration prevention function cannot be obtained, and if it exceeds 5 parts by weight, the strength of the composition decreases, which is not good.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention further comprises 0.1 to 5 parts by weight of a boric acid compound based on 100 parts by weight of asphalt in order to improve the water resistance and scratch resistance of the composition. Examples of the boric acid compound may include orthoboric acid, metaboric acid, tetraboric acid, methyl borate, ethyl borate, and the like, and orthoboric acid is preferably used.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention may further include 0.1 to 5 parts by weight of calcium aluminate based on 100 parts by weight of asphalt in order to prevent drying shrinkage of the composition. , When calcium aluminate is included in the modified asphalt concrete composition for roads containing latex resin, it becomes expandable to prevent drying and shrinkage of the composition.If the amount is less than 0.1 parts by weight based on 100 parts by weight of asphalt, the effect is It is insignificant, and if it exceeds 5 parts by weight, it is not good because it is excessive and can reduce workability.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention further comprises 1 to 5 parts by weight of sodium metasilicate based on 100 parts by weight of asphalt in order to improve the compressive strength and flexural strength of the composition. If the content is less than 1 part by weight, fluidity is lowered and irregular air bubbles are formed, and if it exceeds 5 parts by weight, it is difficult to secure a curing time, which is not good.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention further includes magnesium nitride in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt in order to improve the strength, abrasion resistance, and durability of the composition. can do.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is sodium metaphosphate to improve the reactivity of the composition to express strength, and to improve contamination resistance and material separation resistance. It may further include 0.1 to 3 parts by weight based on 100 parts by weight of asphalt.

As another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is based on 100 parts by weight of asphalt in order to block the delay of setting in winter, increase strength and increase viscosity to improve the flowability of asphalt. As 1 to 5 parts by weight of aluminum sulfate may be further included.

As another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 0.1 to 3 parts by weight based on 100 parts by weight of asphalt in order to increase the composition reactivity and express early strength. It may contain more as wealth.

As another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention may further include ilite in an amount of 0.1 to 1 parts by weight based on 100 parts by weight of asphalt in order to improve the antibacterial and antifouling properties of the composition.

In another specific aspect, the modified asphalt concrete composition for roads containing the latex resin according to the present invention is 0.1 to 5 parts by weight based on 100 parts by weight of asphalt in order to improve the water repellency of the modified asphalt concrete composition for roads containing the latex resin. Potassium methylsiliconate may be further included, and if the amount of potassium methylsiliconate is less than 0.1 parts by weight, the effect of water repellency is insignificant, and if it exceeds 5 parts by weight, compatibility is lowered.

As another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is to prevent corrosion and coating dropout due to deterioration factors such as salt damage or neutralization of the object to which the composition is applied. It may further include methyltrimethoxysilane (MTMS), the amount of which is preferably 1 to 5 parts by weight based on 100 parts by weight of asphalt.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is imidazoline betaine based on 100 parts by weight of asphalt in order to improve the material separation resistance, workability and freeze-thaw durability of the composition. It may further contain 0.1 to 2 parts by weight.

As another specific aspect, the modified asphalt concrete composition for roads containing the latex resin according to the present invention is a normal butyl acrylate (n-butyl acrylate) in order to improve the adhesion performance of the modified asphalt concrete composition for roads containing the latex resin. It may further include 0.1 to 4 parts by weight based on 100 parts by weight of asphalt. If it is less than 1 part by weight based on 100 parts by weight of asphalt, the adhesion is lowered, and if it exceeds 4 parts by weight, it is not good because it is not economical.

In another specific aspect, the modified asphalt concrete composition for roads containing the latex resin according to the present invention is Mullite to improve the strength, creep resistance, abrasion resistance, fire resistance, etc. of the modified asphalt concrete composition for roads containing the latex resin. (mullite) may be further included in an amount of 1 to 5 parts by weight based on 100 parts by weight of asphalt.The mullite is a mineral belonging to an orthorhombic system and has a colorless or pink color, and contains a lot of aluminum oxide and silicon dioxide. Asphalt 100 If it is less than 1 part by weight, the improvement effect such as strength, abrasion resistance, and fire resistance is insignificant, and if it exceeds 5 parts by weight, workability is deteriorated, which is not good.

In another specific aspect, the modified asphalt concrete composition for roads containing the latex resin according to the present invention is magnesium silicate in order to control the curing speed of the modified asphalt concrete composition for roads containing the latex resin, and to improve water resistance and corrosion resistance. It may further include 0.5 to 3 parts by weight based on 100 parts by weight of asphalt.

In another specific aspect, the modified asphalt concrete composition for roads containing the latex resin according to the present invention is 100 weight of calcium stearate as asphalt in order to improve the durability, abrasion resistance, and dispersibility of the modified asphalt concrete composition for roads containing the latex resin. It may further include 0.1 to 2 parts by weight on a part basis.

In another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is prepared by using tetramethylene diisocyanate based on 100 parts by weight of asphalt in order to improve water resistance, chemical resistance and/or adhesion of the composition. It may further contain 0.1 to 5 parts by weight.

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is made of 0.1 to 3 parts by weight of ulsonite based on 100 parts by weight of asphalt in order to improve the waterproofness and chemical resistance of the composition. It may contain more.

Here, the ulsonite is a powder having excellent acicular water absorption, replacing the organic thickener and adsorbing particles, for example, particles such as resin, specifically particles such as latex resin, on the surface of the powder particles, so that the slump of asphalt concrete is high or It is added to suppress migration of particles to the surface layer of asphalt concrete by the vibration source intersecting during construction. For maximum effect, hardness 4.5 to 5.0, specific gravity about 2.9, particle size 30㎛±5, earth It is preferable to use one that satisfies the condition of 15:1 aspect ratio.

In another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention contains 1 to 4 parts by weight of dibutylhydroxytoluene based on 100 parts by weight of asphalt in order to prevent rancidity and aging of the composition and improve stability. It may contain more as wealth.

In another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is prepared by using sulfoxy polyethylene glycol allyl ether as asphalt 100 to facilitate mixing between components constituting the composition and to improve the stability of the composition. It may further contain 0.1 to 5 parts by weight based on parts by weight, but if the content is less than 0.1 parts by weight based on 100 parts by weight of asphalt, the composition is not easily blended, and if it exceeds 5 parts by weight, stability is degraded excessively, which is not good. .

In another specific aspect, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 0.1 to 4 parts by weight of butyl-2-propeno based on 100 parts by weight of asphalt in order to improve the waterproofness and chemical resistance of the composition. It may further include eight.

In another specific embodiment, the modified asphalt concrete composition for roads comprising the latex resin according to the present invention is 0.01 to 1 part by weight of mono-tert-butyl based on 100 parts by weight of asphalt in order to improve the bonding strength between the components constituting the composition. -It may further contain hydroquinone.

The asphalt concrete composition according to the present invention having such a configuration, specifically, a method of constructing a modified asphalt concrete composition for roads containing latex resin will be described as follows.

Here, the construction method of the modified asphalt concrete composition for roads containing the latex resin is not particularly limited, but preferably, a rearranging step of arranging the target surface to be constructed;

1 to 25 parts by weight of latex resin, 1 to 25 parts by weight of styrene ethylene butylene styrene copolymer, 1 to 25 parts by weight of petroleum resin, 500 to 2,000 parts by weight of aggregate Part, 30 to 150 parts by weight of fine powder aggregate, 0.1 to 2 parts by weight of sodium benzoate, 0.1 to 2 parts by weight of cellulose fiber, 0.1 to 2 parts by weight of wax, 0.1 to 2 parts by weight of antioxidant, and 0.1 to 2 parts by weight of stabilizer A pouring step of pouring a modified asphalt concrete composition for roads containing a latex resin;

A compaction step of compacting the modified asphalt concrete composition for roads containing the latex resin poured after the pouring step is finished; And

And a curing step of curing the modified asphalt concrete composition for roads containing latex resin after the compaction step is completed.

Hereinafter, the present invention will be described in detail through examples. However, the following examples are for illustrative purposes only and are not intended to limit the scope of the present invention by these examples.

[Example 1]

After preparing a silicone resin solution by mixing 100 g of straight asphalt with a penetration of 30 and 5 g of a silane coupling agent (N-2 (aminoethyl) 3-Aminopropyltriethoxysilane) with 10 g of ethanol (99.5%), 100 g of a latex resin solution (47% solid content) was mixed with silicone. Silicone latex resin 12g, styrene ethylenebutylene styrene copolymer 12g, aliphatic C-5 petroleum resin 13g with a viscosity of 130 cps at 140℃, and natural rubber and polypropylene in a weight ratio of 1:1 5g of mixed modifier, 1,200g of aggregate mixed with gravel with an average particle size of about 3mm and gravel with an average particle size of about 5mm at a weight ratio of 5:5, 80g of fine powder aggregate consisting of limestone with an average particle size of about 0.03mm, sodium benzo Modified asphalt concrete for roads containing latex resin by mixing 1 g of Eight, 1 g of natural cellulose fiber, 1 g of polyethylene wax, 1 g of 2.2-methylenebis (4-methyl-6-t-butylphenol), and 1 g of non-yellowing polyurea resin The composition was prepared.

Here, in preparing the silicone-based latex resin, the time required for input was ((silicon resin + ethanol) weight * 0.4) seconds, and after the silicone resin solution was added to the latex resin solution, stirring was maintained for about 12 hours, Then, it was prepared by removing ethanol through vacuum while heating and stirring in a water bath at 30 to 35°C.

[Example 2]

It was carried out in the same manner as in Example 1, but instead of 1 g of polyethylene wax, 1 g of a mixture in which a modified fatty acid obtained by melt-reacting a polyethylene wax and a fatty acid having 12 to 24 carbon atoms with calcium hydroxide was mixed in a weight ratio of 1: 0.5 was used.

[Example 3]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of a polyvinylidene fluoride resin.

[Example 4]

It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of 2-bromopyridine.

[Example 5]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of Wellan gum.

[Example 6]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of neopentyl glycol.

[Example 7]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of plaster.

[Example 8]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of coco betaine.

[Example 9]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of gibbsite.

[Example 10]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of cerium.

[Example 11]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of ferrite.

[Example 12]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of haloysite.

[Example 13]

It was carried out in the same manner as in Example 1, but further added 2 g of zinc ammonium chloride.

[Example 14]

It was carried out in the same manner as in Example 1, but with an average particle size of 5 μm, 3 g of cheonmaeam powder was further added.

[Example 15]

It was carried out in the same manner as in Example 1, but further added 3 g of bauxite powder having an average particle size of 3 μm.

[Example 16]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of dibutylphthalate.

[Example 17]

It was carried out in the same manner as in Example 1, but further added 2 g of 3-mercaptopropyltrimethoxysilane.

[Example 18]

It was carried out in the same manner as in Example 1, but further added 2 g of a fine gelite powder having an average particle size of 3 μm.

[Example 19]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of citric acid.

[Example 20]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of sodium stearate.

[Example 21]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of orthoboric acid.

[Example 22]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of calcium aluminate.

[Example 23]

It was carried out in the same manner as in Example 1, but was carried out by adding 4 g of sodium metasilicate.

[Example 24]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of magnesium nitride.

[Example 25]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of sodium metaphosphate.

[Example 26]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of aluminum sulfate.

[Example 27]

It was carried out in the same manner as in Example 1, except that 2 g of strontium aluminate was further added.

[Example 28]

It was carried out in the same manner as in Example 1, but was carried out by adding 0.5 g of illite.

[Example 29]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of potassium methylsiliconate.

[Example 30]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of methyltrimethoxysilane.

[Example 31]

It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of imidazoline betaine.

[Example 32]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of normal butyl acrylate.

[Example 33]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of mullite.

[Example 34]

It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of magnesium silicide.

[Example 35]

It was carried out in the same manner as in Example 1, but was carried out by adding 1 g of calcium stearate.

[Example 36]

It was carried out in the same manner as in Example 1, but further added 3 g of tetramethylene diisocyanate.

[Example 37]

It was carried out in the same manner as in Example 1, but was carried out by adding 0.5 g of ulsonite.

[Example 38]

It was carried out in the same manner as in Example 1, but further added 3 g of dibutylhydroxytoluene.

[Example 39]

It was carried out in the same manner as in Example 1, but was carried out by adding 3 g of sulfoxy polyethylene glycol allyl ether.

[Example 40]

It was carried out in the same manner as in Example 1, but was carried out by adding 2 g of butyl-2-propenoate.

[Example 41]

It was carried out in the same manner as in Example 1, but 0.5 g of mono-tert-butyl-hydroquinone was further added.

[Example 42]

It was carried out in the same manner as in Example 1, but all of the additives added according to Examples 3 to 41 were added.

[Experiment]

After preparing an asphalt concrete layer with a thickness of about 60 mm using the composition prepared according to the examples, low temperature (at -10°C) hardenability, cracking property, indirect tensile strength, deformation strength, compressive strength, etc. were measured, and about 50 mm A thick asphalt concrete layer was prepared and the dynamic stability was measured and shown in Table 1.

Here, the dynamic stability was measured through the deformation strength test and test by the Kim Test as plastic deformation resistance evaluation, the indirect tensile strength was conducted to evaluate the crack resistance, and the compressive strength was measured using an asphalt compressive strength tester.

Gelation/1hr
(at -10℃) Degree of cracking Dynamic stability
(pass/mm) Indirect tensile strength
(ITS) Deformation strength
(Mpa) Compressive strength (MPa) 7 days 28 days Example 1 65 none 1868 0.87 5.58 32.1 84 Example 2 65 none 1869 0.86 5.57 30.6 85 Example 3 67 none 1859 0.88 5.84 31.2 86 Example 4 68 none 1864 0.87 5.85 31.8 85 Example 5 68 none 1971 0.86 5.84 31.4 86 Example 6 67 none 1967 0.87 5.87 32.5 88 Example 7 66 none 1958 0.85 5.84 32.9 87 Example 8 65 none 1859 0.89 5.91 31.4 87 Example 9 66 none 1845 0.91 5.79 30.5 87 Example 10 68 none 1923 0.90 5.74 30.6 85 Example 11 65 none 1946 0.89 5.75 29.5 84 Example 12 67 none 1951 0.92 5.74 30.5 87 Example 13 65 none 1957 0.89 5.64 32.1 86 Example 14 66 none 1832 0.88 5.73 29.9 86 Example 15 64 none 1956 0.84 5.72 32.3 87 Example 16 66 none 1978 0.87 5.65 32.1 86 Example 17 67 none 1989 0.90 5.67 30.3 88 Example 18 63 none 1887 0.91 5.78 30.5 87 Example 19 65 none 1867 0.89 5.86 31.7 86 Example 20 64 none 1901 0.85 6.01 31.8 87 Example 21 67 none 1876 0.88 6.05 31.9 87 Example 22 65 none 1983 0.86 5.78 32.1 86 Example 23 67 none 1956 0.87 5.93 32.5 88 Example 24 64 none 1939 0.92 5.63 32.1 87 Example 25 66 none 1984 0.91 5.76 31.3 87 Example 26 67 none 1882 0.98 5.45 30.7 86 Example 27 65 none 1895 0.86 5.74 32.1 88 Example 28 67 none 1878 0.84 5.67 30.6 87 Example 29 67 none 1894 0.87 5.34 32.1 85 Example 30 67 none 1853 0.85 5.65 29.8 86 Example 31 65 none 1889 0.86 5.73 32.6 89 Example 32 68 none 1931 0.87 5.58 29.8 88 Example 33 67 none 1879 0.88 5.75 31.3 87 Example 34 67 none 1978 0.84 5.98 31.3 86 Example 35 65 none 1974 0.87 6.02 31.6 87 Example 36 66 none 1833 0.87 6.14 30.6 88 Example 37 67 none 1927 0.85 5.94 31.3 88 Example 38 66 none 1954 0.86 5.74 32.5 85 Example 39 68 none 1921 0.87 5.75 31.8 83 Example 40 68 none 1947 0.87 5.69 32.1 84 Example 41 65 none 1838 0.88 5.56 30.6 85 Example 42 68 none 1993 0.86 5.82 31.5 88

As shown in Table 1, the low-temperature curing properties, cracking properties, dynamic stability, indirect tensile strength and deformation strength of the examples using the modified asphalt concrete composition for roads containing latex resin are good, and the compressive strength is 28 days. At 75 megapascals or more, it was confirmed that all the compositions of the examples always had high strength.

As described above, those skilled in the art to which the present invention pertains will understand that the present invention can be implemented in other specific forms without changing the technical spirit or essential features. Therefore, all the embodiments described above are illustrative and should be understood as non-limiting. The scope of the present invention should be construed as including all altered or modified forms derived from the meaning and scope of the claims to be described later rather than the above detailed description, and equivalent concepts thereof.

Claims (5)

Based on 100 parts by weight of asphalt,
1 to 25 parts by weight of a latex resin;
1 to 25 parts by weight of a styrene ethylene butylene styrene copolymer;
140° C. 1 to 25 parts by weight of an aliphatic C-5 petroleum resin having a viscosity of 130 cps;
1 to 10 parts by weight of a modifier;
500 to 2,000 parts by weight of aggregate;
30 to 150 parts by weight of fine powder aggregate;
0.1 to 2 parts by weight of sodium benzoate;
0.1 to 2 parts by weight of cellulose fibers;
0.1 to 2 parts by weight of wax;
0.1 to 2 parts by weight of an antioxidant; And
In the modified asphalt concrete composition for roads containing a latex resin containing 0.1 to 2 parts by weight of a stabilizer,
2-bromopyridine is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt,
It further contains cerium in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of asphalt,
Further comprising 0.1 to 4 parts by weight of zinc ammonium chloride based on 100 parts by weight of asphalt,
3-mercaptopropyltrimethoxysilane further comprises 1 to 3 parts by weight based on 100 parts by weight of asphalt,
Citric acid is further included in 1 to 5 parts by weight based on 100 parts by weight of asphalt,
The boric acid compound is further included in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of asphalt,
Further comprising 1 to 5 parts by weight of sodium metasilicate based on 100 parts by weight of asphalt,
Magnesium nitride further comprises 0.1 to 3 parts by weight based on 100 parts by weight of asphalt,
Further comprising 0.1 to 3 parts by weight of strontium aluminate based on 100 parts by weight of asphalt,
Further comprising 0.1 to 1 parts by weight of illite based on 100 parts by weight of asphalt,
Potassium methyl silicate further comprises 0.1 to 5 parts by weight based on 100 parts by weight of asphalt,
It further comprises 0.1 to 2 parts by weight of imidazoline betaine based on 100 parts by weight of asphalt,
Further comprising 0.5 to 3 parts by weight of magnesium silicate based on 100 parts by weight of asphalt,
Modified asphalt concrete composition for roads comprising a latex resin further comprising 0.01 to 1 part by weight of mono-tert-butyl-hydroquinone based on 100 parts by weight of asphalt.
delete delete delete An arrangement step of arranging the target surface to be constructed;
Aliphatic C-5 petroleum resin 1 to 25 parts by weight of a latex resin, 1 to 25 parts by weight of a styrene ethylene butylene styrene copolymer, and a viscosity of 130 cps at 140° C. based on 100 parts by weight of asphalt on the surface where the cleaning step is completed To 25 parts by weight, modifier 1 to 10 parts by weight, aggregate 500 to 2,000 parts by weight, fine powder aggregate 30 to 150 parts by weight, sodium benzoate 0.1 to 2 parts by weight, cellulose fiber 0.1 to 2 parts by weight, wax 0.1 to 2 parts by weight , In the modified asphalt concrete composition for roads comprising a latex resin containing 0.1 to 2 parts by weight of an antioxidant, and 0.1 to 2 parts by weight of a stabilizer, 2-bromopyridine is further included in an amount of 0.1 to 3 parts by weight based on 100 parts by weight of asphalt And, it further comprises 0.1 to 5 parts by weight of cerium based on 100 parts by weight of asphalt, and further comprises 0.1 to 4 parts by weight of zinc ammonium chloride based on 100 parts by weight of asphalt, and 3-mercaptopropyltrimethoxysilane as asphalt 100 It further comprises 1 to 3 parts by weight based on parts by weight, further comprises 1 to 5 parts by weight based on 100 parts by weight of asphalt, and further comprises 0.1 to 5 parts by weight of a boric acid compound based on 100 parts by weight of asphalt, metasilicic acid Sodium is further included in 1 to 5 parts by weight based on 100 parts by weight of asphalt, magnesium nitride is further included in 0.1 to 3 parts by weight based on 100 parts by weight of asphalt, and strontium aluminate is included in 0.1 to 3 parts by weight based on 100 parts by weight of asphalt. It further includes, further comprising 0.1 to 1 parts by weight of illite based on 100 parts by weight of asphalt, further comprising 0.1 to 5 parts by weight of potassium methylsiliconate based on 100 parts by weight of asphalt, and 100 parts by weight of imidazoline betaine as asphalt It further comprises 0.1 to 2 parts by weight based on parts, and further comprises 0.5 to 3 parts by weight based on 100 parts by weight of asphalt, and 0.01 to 1 parts by weight of mono-tert-butyl-hydroquinone based on 100 parts by weight of asphalt. For roads containing latex resins that are further included A pouring step of pouring the modified asphalt concrete composition;
A compaction step of compacting the modified asphalt concrete composition for roads containing the latex resin poured after the pouring step is finished; And
A method of constructing a modified asphalt concrete composition for roads comprising a latex resin comprising a curing step of curing a modified asphalt concrete composition for roads comprising a latex resin after the compaction step is completed.