KR102180044B1 - Manufacturing method of nano cellulose film - Google Patents

Abstract

Embodiments include (1) preparing a composition containing cellulose nanofibers; (2) extruding and casting the composition into a sheet shape; And (3) drying the sheet-shaped composition to form a film, wherein step (3) is performed under a temperature condition of 150°C or lower and a second drying step performed under a temperature condition of 80°C or higher By including the drying step, it is possible to lower the production cost, and to a method for producing a nanocellulose film capable of improving optical properties and quality.

Description

Manufacturing method of nano cellulose film {MANUFACTURING METHOD OF NANO CELLULOSE FILM}

The embodiment relates to a method of manufacturing a nanocellulose film capable of lowering production cost and improving optical properties and quality.

Barrier films for packaging are widely used in order to suppress deterioration of food, daily necessities, medicines, etc. and to maintain their function and quality. Conventionally, in order to manufacture such a barrier film for packaging, an aluminum vapor deposition method, a coating method, a vapor deposition method, an ethylene vinyl alcohol film processing method, and the like have been used. However, since aluminum deposition and coating are not eco-friendly methods using metal or chlorine gas, they are recently avoided, and the deposition method has a problem that cracks may occur in the deposition layer, and the ethylene vinyl alcohol film processing method is recycled. When mixing with other materials in the (recycle) process, there is a disadvantage that a gel may be generated in the processing process.

Meanwhile, a film used as a cover window of a display device is required not only to have transparency, but also to optical properties such as scratch resistance, surface hardness, and coefficient of thermal expansion. Conventionally, transparent polyimide has been mainly used for a foldable cover window, and polycarbonate or polymethyl methacrylate has been mainly used for a non-foldable cover window. However, while polyimide has excellent transparency and folding properties, it has a high coefficient of thermal expansion and does not satisfy a low phase difference, which may cause polarization mura, and polycarbonate or polymethyl methacrylate has low scratch resistance and hardness. .

Accordingly, there is an attempt to use a cellulose film using cellulose nanofibers, which is an eco-friendly material, has excellent transparency and barrier properties, and has a low coefficient of thermal expansion, a low phase difference, and a high modulus. However, such a process of filming cellulose nanofibers has disadvantages in that the production yield is low or thickness control is difficult and cost is high due to a multistage process.

For example, Korean Patent Application Publication No. 2015-0098715 discloses a pretreatment step in which a pretreatment solvent is sequentially added to a dispersion containing cellulose and water and each is irradiated with ultrasonic waves. Such a pretreatment step can improve transparency. , It is difficult to control the thickness.

Republic of Korea Patent Publication No. 2015-0098715

Accordingly, the embodiment is to provide a method of manufacturing a nano cellulose film having a low phase difference and high modulus, while being an eco-friendly material by a simple process, excellent transparency and barrier properties.

A method of manufacturing a nanocellulose film according to an embodiment includes: (1) preparing a composition including cellulose nanofibers; (2) extruding and casting the composition into a sheet shape; And (3) drying the sheet-shaped composition to form a film, wherein step (3) is performed under a temperature condition of 150°C or lower and a second drying step performed under a temperature condition of 80°C or higher Includes a drying step.

The nanocellulose film manufactured according to the method of manufacturing a nanocellulose film according to an embodiment has a transmittance of 80% or more, a haze of 7% or less, a modulus of 5 GPa or more, and an in-plane retardation (Ro) of 30 nm or less. .

The method of manufacturing a nanocellulose film according to the embodiment may provide a nanocellulose film having excellent transparency and barrier properties, and having a low phase difference and high modulus.

In addition, the manufacturing method of the nanocellulose film according to the embodiment is environmentally friendly, the manufacturing process is simple, and there is an effect of cost reduction.

Hereinafter, the invention will be described in detail through embodiments. The implementation is not limited to the content disclosed below, and may be modified in various forms unless the gist of the invention is changed.

In the present specification, when a certain part "includes" a certain component, it means that other components may be further included rather than excluding other components unless otherwise stated.

All numbers and expressions indicating amounts of components, reaction conditions, and the like described herein are to be understood as being modified by the term "about" in all cases unless otherwise specified.

Manufacturing method of nano cellulose film

A method of manufacturing a nanocellulose film according to an embodiment includes: (1) preparing a composition including cellulose nanofibers; (2) extruding and casting the composition into a sheet shape; And (3) drying the sheet-shaped composition to form a film, wherein step (3) is performed under a temperature condition of 150°C or lower and a second drying step performed under a temperature condition of 80°C or higher Includes a drying step.

Step (1)

Step (1) is a step of preparing a composition containing cellulose nano fibers.

According to one embodiment, the cellulose nanofibers may be manufactured by a chemical treatment method and a mechanical treatment method.

The chemical treatment method is from the group consisting of 2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl (TEMPO), carboxymethyl (CM, -CH ₂ COO-), phosphate esters, and enzymes. At least one selected may be used, and the mechanical treatment method may use at least one selected from the group consisting of a high pressure homogenizer, a grinder, a microfluidizer, and an aqueous counter collision.

Specifically, by substituting a part of the hydroxy group of the cellulose nanofibers with weak hydrophilic groups through the chemical treatment method and the mechanical treatment method to weaken the van der waals force, fibrillation of the fiber ( fibrillation) can be effectively promoted.

According to one embodiment, the cellulose nanofibers may be additionally subjected to a hydrophobic treatment method. Specifically, the hydrophobic treatment method may use at least one method selected from the group consisting of acetylation, silanization, crosslinking, fluorination, addition of AKD (Alkyl Ketene Dimer) and addition of ASA (alkyl succinic anhydride).

Specifically, by substituting a portion of the hydroxyl group of the nanocellulose through the hydrophobic treatment method with a hydrophobic group having a low affinity for moisture, the moisture barrier property may be improved.

According to one embodiment, the width of the cellulose nanofibers may be 5 to 200 nm. For example, the width of the cellulose nanofibers may be 10 to 200 nm, 30 to 200 nm, or 50 to 200 nm. If the above range is satisfied, transparency may be improved. Specifically, when the width of the cellulose nanofibers exceeds 200 nm, the transparency is lowered by affecting the visible light region.

According to one embodiment, the aspect ratio of the cellulose nanofibers may be 100 or more. For example, the aspect ratio of the cellulose nanofibers may be 130 or more, 150 or more, 180 or more, 100 to 300, 100 to 250, 130 to 250, 150 to 250, 170 to 300, 100 to 200, or 100 to 150. . If the above range is satisfied, mechanical strength and modulus can be improved. Therefore, it is easy to apply to a barrier film for packaging or a cover window of a display device.

According to one embodiment, the composition may include cellulose nanofibers and water.

According to one embodiment, the composition may include the cellulose nanofibers in an amount of 80% by weight or more based on the total weight of the composition. For example, the composition may contain 85% by weight or more, 90% by weight or more, 95% by weight or more, 98% by weight or more, 99% by weight or more, or 99.9% by weight or more, based on the total weight of the composition. .

According to one embodiment, the composition may include one or more matrix resins selected from the group consisting of polyvinyl alcohol resin, epoxy resin, polyvinyl butyral, and ethylene vinyl acetate. Specifically, the composition may improve impact resistance, glass adhesion, or transparency by including the matrix resin.

According to one embodiment, the composition may contain the matrix resin in an amount of 0 to 20% by weight based on the total weight of the composition. For example, the composition is based on the total weight of the composition, the matrix resin is 0 to 18% by weight, 0 to 15% by weight, 0 to 10% by weight, 0 to 8% by weight, 0 to 5% by weight, 0.1 to It may be 5 wt%, 0 to 3 wt%, 0.1 to 2 wt%, 0 to 1 wt%, 0 to 0.5 wt%, 0 to 0.1 wt%, or 0.01 to 0.1 wt%.

According to one embodiment, the composition may further include one or more additives selected from the group consisting of surfactants, antifoaming agents and UV absorbers.

The surfactant is used to improve the dispersibility of the particles and is not particularly limited. For example, a silicone-based surfactant, sodium lauryl acid, alkyl benzenesulfonic acid, and the like may be used.

The UV absorber may be, for example, a benzotriazole-based, benzophenone-based, or cyanoacrylate-based. Examples of the benzotriazole-based ultraviolet absorber include 2-(2'-hydroxy-5'-methylphenyl)benzotriazole, 2-(2'-hydroxy-5'-t-butylphenyl)benzotriazole, 2- (2'-hydroxy-3',5'-di-t-butylphenyl)benzotriazole, 2-(2'-hydroxy-3'-t-butyl-5'-methylphenyl)-5- Chlorobenzotriazole, 2-(2'-hydroxy-3',5'-di-t-butylphenyl)-5-chlorobenzotriazole, 2-(2'-hydroxy3',5'-di -t-amylphenyl)benzotriazole or 2-[2'-hydroxy-3'-(3``,4'',5'',6''-tetrahydrophthalamidemethyl)-5'-methylphenyl ]Benzotriazole, but is not limited thereto. In addition, as the benzophenone-based ultraviolet absorber, 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octoxybenzophenone, 2-hydroxy- 4-dodecyloxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone or 2-hydroxy-4- Methoxy-5-sulperbenzophenone, but is not limited thereto. Examples of the cyanoacrylate-based ultraviolet absorber include 2-ethylhexyl-2-cyano-3,3'-diphenyl acrylate, ethyl-2-cyano-3,3'-diphenyl acrylate, It is not limited.

The content of the additive is not particularly limited, but may be 0.01 to 5% by weight or 0.01 to 3% by weight based on the total weight of the composition.

Step (2)

Step (2) is a step of extruding and casting the composition into a sheet shape.

According to one embodiment, the composition is transferred to a single extruder using a screw feeder, extruded with a T-die in an extruder, and then cast in a casting drum. It can be made into a sheet.

According to one embodiment, the extrusion may be performed at 250°C or less. For example, the extrusion may be performed at 230°C or less, 80°C to 250°C, or 80°C to 230°C. If the above range is satisfied, extrusion can be effectively performed without damaging the cellulose nanofibers. Specifically, at less than 80° C., the viscosity is high, so that it is difficult to flow, so that extrusion is difficult, and at more than 250° C., carbonization of cellulose nanofibers may occur.

Step (3)

Step (3) is a step of drying the sheet-like composition to form a film.

According to one embodiment, the step (3) includes a first drying step performed under a temperature condition of 130°C or lower and a second drying step performed under a temperature condition of 70°C or higher.

According to one embodiment, the first drying step may be performed at a temperature of 60° C. to 130° C., for 40 to 200 seconds, and a line speed of 5 to 15 m/min. For example, the first drying step may be performed for 40 seconds to 180 seconds or 50 seconds to 160 seconds at a temperature of 60 ℃ to 120 ℃ or 70 ℃ to 100 ℃. In addition, the first drying step may be performed under conditions of a line speed of 5 to 13 m/min or 5 to 10 m/min. If the above range is satisfied, the quality of the film can be improved. Specifically, when the temperature of the first drying step exceeds 130° C., bubbles may be formed in the film, so that the quality of the film may be lowered.

According to one embodiment, the first drying step may be performed in a drying chamber immediately after casting.

According to an embodiment, the second drying step may be performed at a temperature of 70° C. to 180° C., for 40 to 200 seconds, and a line speed of 5 to 15 m/min. For example, the second drying step may be performed at a temperature of 70°C to 180°C or 80°C to 170°C for 40 seconds to 180 seconds or 50 seconds to 160 seconds. In addition, the second drying step may be performed under conditions of a line speed of 5 to 13 m/min or 5 to 10 m/min. If the above range is satisfied, the quality of the film can be improved. Specifically, by uniformly removing moisture, not only the quality of the film can be improved, but also the thickness of the film can be precisely controlled.

According to an embodiment, the second drying step may include step A performed by a roll dryer and step B performed by a floating dryer.

Specifically, the second drying step includes the step A and the step B, thereby effectively controlling the moisture of 95% or 97% or more. Therefore, it is possible to effectively prevent the nanocellulose film from being swollen by moisture, and there is an advantageous effect in securing transparency.

According to an embodiment, the second drying step may include stretching in at least one of a first direction and a second direction perpendicular to the first direction. Specifically, the second drying step may include stretching in a first direction and a second direction. For example, it may be stretched 0.1 to 4.0 times in the first direction, and 0.1 to 3.0 times stretched in the second direction.

The first direction may be a longitudinal direction (MD), and the second direction may be a transverse direction (TD). Alternatively, the first direction may be a transverse direction (TD), and the second direction may be a longitudinal direction (MD).

Nano cellulose film

The nanocellulose film manufactured according to the method of manufacturing a nanocellulose film according to an embodiment has a transmittance of 80% or more, a haze of 7% or less, a modulus of 5 GPa or more, and an in-plane retardation (Ro) of 30 nm or less. .

According to one embodiment, the transmittance of the nanocellulose film may be 80% or more. For example, the transmittance of the nanocellulose film may be 85% or more, 88% or more, 89% or more, 80% to 99%, 80% to 99%, or 85% to 99%.

According to one embodiment, the haze of the nanocellulose film may be 7% or less. For example, the haze of the nanocellulose film may be 6% or less, 5% or less, 4.5% or less, 4% or less, or 3% or less.

According to one embodiment, the modulus of the nanocellulose film may be 5 GPa or more. For example, the modulus of the nanocellulose film may be 5.2 GPa or more, 5.5 GPa or more, 6.0 GPa or more, 10 GPa or less, 5 GPa to 10 GPa, or 5 GPa to 8 GPa.

According to one embodiment, the air permeability of the nanocellulose film may be less than 50 g/m ² .day.atm. For example, the air permeability of the nanocellulose film is 0.01 to 40 g/m ² .day.atm, 0.01 to 30 g/m ² .day.atm, 0.1 to 20 g/m ² .day.atm, 0.1 to 0.1 It may be 10 g/m ² .day.atm or 0.1 to 5 g/m ² .day.atm.

According to one embodiment, the plane direction retardation Ro of the nanocellulose film may be 30 nm or less. For example, the plane direction retardation (Ro) of the nanocellulose film may be 25 nm or less, 20 nm or less, 1 to 25 nm, 3 to 20 nm, 5 to 15 nm, or 5 to 10 nm. When the above range is satisfied, fairness is excellent, and polarization mura is not observed.

The in-plane retardation is a parameter defined as the product of the anisotropy (△Nxy=|Nx-Ny|) of the refractive index of the orthogonal biaxial on the film and the film thickness d(nm) (△Nxy X d), which represents optical isotropy and anisotropy. It is a measure. The plane direction retardation R _o is a plane direction retardation value at a wavelength of 550 nm, and is expressed by Equation 1 below.

[Equation 1]

R _o = (n _x －n _y ) × d

In this case, n _x is the refractive index in the uniaxial (x-axis) direction in the film plane, n _y is the refractive index in the uniaxial direction orthogonal to the x-axis in the film plane, and d is the thickness (nm) of the film.

According to one embodiment, the thickness of the nanocellulose film may be 5 to 200 μm. For example, the thickness of the nanocellulose film is 5 to 180 ㎛, 5 to 150 ㎛, 5 to 130 ㎛, 5 to 100 ㎛, 5 to 90 ㎛, 10 to 80 ㎛, 20 to 60 nm, 10 to 50 ㎛ Alternatively, it may be 15 to 40 μm.

According to one embodiment, the nanocellulose film may include a siloxane-based hard coating layer on one surface. Specifically, the nanocellulose film includes a hard coating layer coated with a siloxane-based compound, thereby improving hardness, durability and reliability of the nanocellulose film.

The nanocellulose film according to one embodiment is eco-friendly, has excellent transparency and barrier properties, has a low phase difference and high modulus, and thus can be used as a barrier film for packaging and a cover window film.

The above will be described in more detail by the following examples. However, the following examples are for illustrative purposes only, and the scope of the examples is not limited thereto.

[Example 1]

Cellulose nanofibers with a width of 10 nm and an aspect ratio of 150 using a chemical treatment method using 2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl (TEMPO) and a mechanical treatment method using a high pressure homogenizer Was prepared. A composition was prepared by mixing 99.9% by weight of the cellulose nanofibers with 0.1% by weight of an additive (UV absorbent benzotriazole, Tinuvin, Basf).

The composition was transferred to a single extruder using a screw feeder, extruded at 100° C. with a T-die, and then cast in a casting drum to form a sheet. .

Immediately after casting, the first drying step was performed in a drying chamber at 70° C., and then step A in a roll dryer at 80° C. and step B in a floating dryer at 100° C. 2 To prepare a 25 μm-thick nanocellulose film by performing the drying step.

[Example 2]

Cellulose nanofibers having a width of 10 nm and an aspect ratio of 100 were prepared using a chemical treatment method using an enzyme, a mechanical treatment method using a high pressure homogenizer, and a hydrophobic treatment method of silanization.

A composition was prepared by mixing 90% by weight of the cellulose nanofibers, 9.9% by weight of polyvinyl alcohol (POVAL, 95% or more Hydrolysis, Kuraray), and 0.1% by weight of additives (antifoaming agent HS-Defoamer VF200, Shinheung New Materials).

The composition was transferred to a single extruder using a screw feeder, extruded at 100° C. with a T-die, and then cast in a casting drum to form a sheet. .

Immediately after casting, the first drying step was performed in a drying chamber at 70° C., step A was performed on a roll dryer at 80° C., and then in the width direction (TD) using a peripheral speed difference. After 0.5-fold stretching orientation, a second drying step was performed through step B in a floating dryer at 100°C to prepare a 25 μm-thick nanocellulose film.

[Example 3]

Cellulose nanofibers having a width of 20 nm and an aspect ratio of 100 were prepared using a mechanical treatment method using aqueous counter collision and a hydrophobic treatment method of acetylation.

After transferring the composition of 100 weight of the cellulose nanofibers to a single extruder using a screw feeder, extruded at 150°C with a T-die, and then a casting drum ( casting drum) to form a sheet.

Immediately after casting, the first drying step was performed in a drying chamber at 70° C., followed by step A in a roll dryer at 80° C. and step B in a floating dryer at 95° C. Two drying steps were performed. A siloxane-based high-hardness hard coating was applied off-line on one side to prepare a 25 μm-thick nanocellulose film.

[Comparative Example 1]

By mixing 90% by weight of cellulose nanofibers with a width of 300 nm and an aspect ratio of 50, polyvinyl alcohol (POVAL, Hydrolysis 95% or more, Kuraray Corporation) 9.9% by weight and additives (foaming agent HS-Defoamer VF200, Shinheung New Materials) 0.1% by weight. The composition was prepared.

The composition was transferred to a single extruder using a screw feeder, extruded at 100° C. with a T-die, and then cast in a casting drum to form a sheet. .

Immediately after casting, the first drying step was performed in a drying chamber at 70° C., followed by step A in a roll dryer at 80° C. and step B in a floating dryer at 95° C. 2 To prepare a 25 μm-thick nanocellulose film by performing the drying step.

[Comparative Example 2]

By mixing 90% by weight of cellulose nanofibers with a width of 10 nm and an aspect ratio of 150, polyvinyl alcohol (POVAL, Hydrolysis 95% or more, Kuraray Corporation) 9.9% by weight and additives (foaming agent HS-Defoamer VF200, Shinheung New Materials) 0.1% by weight. The composition was prepared.

The composition was transferred to a single extruder using a screw feeder, extruded with a T-die at 260° C., and then cast in a casting drum to form a sheet. .

Immediately after casting, the first drying step was performed in a drying chamber at 100°C, followed by step A in a roll dryer at 130°C and step B in a floating dryer at 140°C. 2 To prepare a 25 μm-thick nanocellulose film by performing the drying step.

[Comparative Example 3]

A composition was prepared by mixing 99.9% by weight of cellulose nanofibers having a width of 20 nm and an aspect ratio of 150 and 0.1% by weight of an additive (UV absorbent benzotriazole, Tinuvin, Basf).

The composition was transferred to a single extruder using a screw feeder, extruded at 100° C. with a T-die, and then cast in a casting drum to form a sheet. .

Immediately after casting, the first drying step was performed in a drying chamber at 150°C, followed by step A in a 160°C roll dryer and step B in a 170°C floating dryer. 2 To prepare a 25 μm-thick nanocellulose film by performing the drying step.

[Comparative Example 4]

By mixing 90% by weight of cellulose nanofibers with a width of 300 nm and an aspect ratio of 50, polyvinyl alcohol (POVAL, Hydrolysis 95% or more, Kuraray Corporation) 9.9% by weight and additives (foaming agent HS-Defoamer VF200, Shinheung New Materials) 0.1% by weight. The composition was prepared.

The composition was transferred to a single extruder using a screw feeder, extruded at 100° C. with a T-die, and then cast in a casting drum to form a sheet. .

Immediately after casting, the first drying step was performed in a drying chamber at 70° C., followed by Step A in a roll dryer at 75° C. and Step B in a floating dryer at 95° C. 2 To prepare a 25 μm-thick nanocellulose film by performing the drying step.

[Evaluation Example 1: Whether or not there is a defect]

It was visually observed whether bubbles, pinholes, and carbides were present inside the film, and when observed was indicated by O, and when not observed was indicated by X.

[Evaluation Example 2: Thickness Control]

By measuring the thickness, O is indicated for a case that satisfies the thickness range within ±5% based on the thickness of 25 µm intended to be manufactured, and X is indicated for the case not.

[Evaluation Example 3: Transmittance]

The transmittance was measured according to ASTM D1003.

[Evaluation Example 4: Haze]

Haze was measured using a C-light source using a haze meter (model name: SEP-H) of Nihon Semitsu Kogaku (Japan).

[Evaluation Example 5: Modulus]

Using Instron's universal testing machine UTM 5566A, cut at least 5 cm in the direction orthogonal to the main contraction direction of the sample and 10 mm in the main contraction direction, attach it to a clip at 5 cm intervals, and at room temperature at a speed of 5 mm/min The stress-strain curve was obtained until fracture occurred while stretching to. In the stress-strain curve, the slope of the load against the initial deformation was taken as the modulus (GPa).

[Evaluation Example 6: Speculative Prayer]

According to the standard measurement method of ASTM D3985, the oxygen permeability was measured using an air permeability meter (MOCON, model name OX-TRAM 2/21). (Unit: cc/㎡.day.atm)

[Evaluation Example 7: Phase difference]

The refractive index (nx, ny) of the orthogonal biaxial and the refractive index (nz) in the thickness direction were measured using an Abbe refractometer (NAR-4T, measurement wavelength 589 nm, Atago Inc.), and the thickness d (nm) of the film After measurement using a meter (Millitron 1245D, FineLuf), the unit was converted to nm. The difference between the measured biaxial refractive indices was obtained as an absolute value (|nx-ny|), and the thickness d (nm) of the film was multiplied (nxy×d) to obtain an in-plane retardation (Ro).

The results of Evaluation Examples 1 to 7 are shown in Table 1 below.

Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Defect X X X X O X O thickness
Control O O O O X O O Transmittance (%) 93 91 91 50 80 90 60 Haze (%) 3 4 4 30 15 10 28 Modulus
(Gpa) 6 6.5 6.3 4.5 2.0 4.0 3.0 Speculation
(cc/㎡.day.atm) 0.5 One One 50 300 350 280 In-plane phase difference
(nm) 10 5 10 50 Measure
Impossible Measure
Impossible 45

As shown in Table 1, in the case of the nanocellulose film prepared in the Example, it can be seen that the thickness control, transmittance, haze, modulus, air permeability, and in-plane retardation are excellent without finding any defects.

Claims (12)

As a method for producing a nano cellulose film,
(1) preparing a composition containing cellulose nano fibers;
(2) extruding and casting the composition into a sheet shape; And
(3) drying the sheet-shaped composition to form a film,
The step (3) includes a first drying step performed under a temperature condition of 150°C or less and a second drying step performed under a temperature condition of 80°C or higher,
The nanocellulose film has a transmittance of 80% or more, a haze of 7% or less, a modulus of 5 GPa or more, and an in-plane retardation (Ro) of 30 nm or less. The method of claim 1,
The cellulose nanofibers are prepared by a chemical treatment method and a mechanical treatment method, a method of producing a nanocellulose film. The method of claim 2,
The cellulose nanofibers are prepared by additionally performing a hydrophobic treatment method,
The hydrophobic treatment method uses at least one method selected from the group consisting of acetylation, silanization, crosslinking, fluorination, addition of AKD (Alkyl Ketene Dimer) and addition of ASA (alkyl succinic anhydride) . The method of claim 1,
The width of the cellulose nanofibers is 5 to 200 nm, the aspect ratio is 100 or more, a method of producing a nanocellulose film. The method of claim 1,
The method of manufacturing a nanocellulose film, wherein the composition comprises the cellulose nanofibers in an amount of 80% by weight or more based on the total weight of the composition. The method of claim 1,
The method for producing a nanocellulose film, wherein the composition comprises at least one matrix resin selected from the group consisting of polyvinyl alcohol resin, epoxy resin, polyvinyl butyral and ethylene vinyl acetate. The method of claim 1,
The composition further comprises one or more additives selected from the group consisting of a surfactant, an antifoaming agent and a UV absorber, a method for producing a nanocellulose film. The method of claim 1,
The first drying step is performed at a temperature of 70° C. to 150° C., for 40 to 200 seconds, under conditions of a line speed of 5 to 15 m/min,
The second drying step is performed at a temperature of 80° C. to 170° C., for 40 to 200 seconds, and a line speed of 5 to 15 m/min. The method of claim 1,
The first drying step is performed in a drying chamber immediately after casting,
A method of manufacturing a nanocellulose film, wherein the second drying step comprises step A performed in a roll dryer and step B performed in a floating dryer. A nano cellulose film manufactured according to the method of manufacturing a nano cellulose film of claim 1. The method of claim 10,
The thickness of the film is 5 to 200 ㎛, nano cellulose film. The method of claim 10,
Nano cellulose film comprising a siloxane-based hard coating layer on one side.