KR102162606B1 - Silicone capsules with liquid composition for curing - Google Patents
Silicone capsules with liquid composition for curing Download PDFInfo
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Abstract
본 발명은 실리콘캡슐에 관한 것으로써, 사용과 목적 및 효과에 따라 함유량을 달리하여 경화되는 시간을 조절할 수 있고, 경화력을 상승시킨 액상의 조성물이 내부에 구비된 실리콘캡슐에 관한 것으로써, 실리콘캡슐 내부의 조성물을 이용하여 경화시키는 위치 및 제품에 맞게 상기 조성물 중에서 일부분의 성분량을 조절하여 경화되는 시간을 조절할 수 있고, 경화력을 극대화하기 위해 추가적인 조성물을 혼합하였으며, 사용자가 실리콘캡슐의 파열을 손쉽게 하거나 또는 별도의 제품을 통해 실리콘캡슐의 파열이 손쉽게 되도록 실리콘캡슐에 대한 형상, 구조 및 재질에 대해서도 한정한 경화용 액상 조성물이 구비된 실리콘캡슐에 관한 것이다.The present invention relates to a silicone capsule, wherein the curing time can be adjusted by varying the content according to use, purpose, and effect, and relates to a silicone capsule having a liquid composition having increased curing power therein. Using the composition inside the capsule, the curing time can be adjusted by adjusting the amount of components in the composition according to the curing position and product, and additional compositions are mixed to maximize curing power, and the user can prevent the rupture of the silicone capsule. It relates to a silicone capsule provided with a liquid composition for curing that is limited in shape, structure, and material of the silicone capsule so that the silicone capsule can be easily ruptured through a separate product.
Description
본 발명은 실리콘캡슐에 관한 것으로써, 사용과 목적 및 효과에 따라 함유량을 달리하여 경화되는 시간을 조절할 수 있고, 경화력을 상승시킨 액상의 조성물이 내부에 구비된 실리콘캡슐에 관한 것이다.The present invention relates to a silicone capsule, and the curing time can be adjusted by varying the content according to use, purpose, and effect, and relates to a silicone capsule having a liquid composition having increased curing power therein.
우선, 종래기술을 살펴보면,First of all, looking at the prior art,
일반적으로, 하이드로실릴화 경화성 오가노폴리실록산 조성물은 접착 특성이 불량한 문제점이 있다.In general, the hydrosilylation curable organopolysiloxane composition has a problem of poor adhesive properties.
이러한 문제점을 해결하기 위해, 에폭시 화합물 및 유기 알루미늄 화합물을 조성물에 가하는 방법 또는 조성물을 규소 결합 불포화 그룹 및 알콕시 그룹을 갖는 유기 규소 화합물 및 알루미늄 또는 지르코늄 화합물과 배합하는 방법이 제안되었다.In order to solve this problem, a method of adding an epoxy compound and an organoaluminum compound to a composition or a method of blending the composition with an organosilicon compound having a silicon-bonded unsaturated group and an alkoxy group and an aluminum or zirconium compound has been proposed.
또 다른 방법은 조성물을 지르코늄 화합물 및 비스(트리알콕시실릴)알칸, 규소 결합 알콕시 그룹을 갖는 디실란, 및 에폭시 그룹을 갖는 실록산 또는 알콕시실란으로 이루어진 그룹으로부터 선택된 규소 화합물과 배합하는 것으로 이루어진다.Another method consists in blending the composition with a silicon compound selected from the group consisting of a zirconium compound and a bis(trialkoxysilyl)alkane, a disilane having a silicon bonded alkoxy group, and a siloxane or alkoxysilane having an epoxy group.
상기 경화성 오가노폴리실록산 조성물의 단점은 조성물의 저장 동안 시간 경과시 발생하는, 유기 금속 화합물의 존재하에 규소 결합 수소 원자 및 물 또는 실란올 그룹 사이의 축합 반응 또는 기타 반응하에, 상기 조성물로부터 형성된 경화 생성물이 허용되는 수치 이하로 경도가 손실되는 것으로 이루어진다.The drawback of the curable organopolysiloxane composition is the cured product formed from the composition under condensation reactions or other reactions between the silicon-bonded hydrogen atom and water or silanol groups in the presence of an organometallic compound, which occurs over time during storage of the composition. It consists of loss of hardness below this permissible value.
한편, 축합 경화성 오가노폴리실록산 조성물에 대한 축합 반응 촉매가 유기 수지에 캡슐화된 유기 금속 화합물로 이루어진 마이크로캡슐의 형태로 제조될 수 있는 것으로 공지되어 있다.On the other hand, it is known that a condensation reaction catalyst for a condensation curable organopolysiloxane composition can be prepared in the form of microcapsules made of an organometallic compound encapsulated in an organic resin.
그러나, 이러한 축합반응 촉매가 하이드로실릴화 경화성 오가노폴리실록산 조성물에 첨가되는 경우, 시간이 지남에 따라 경화체에서 경도 손실을 억제할 수 있다는 것은 공지되어 있지 않다.However, it is not known that when such a condensation catalyst is added to the hydrosilylation curable organopolysiloxane composition, it is possible to suppress the loss of hardness in the cured product over time.
이에 종래에는 등록번호 제10-1187594호의 '경화성 오가노폴리실록산 조성물'와, 등록번호 제10-1623220호의 '접착성 캡슐화 조성물 및 그로 제조된 전자 소자' 및 등록번호 제10-1740185호의 '접착제 조성물'이 개시되어 있지만, 상기한 문제점에 대해서는 여전히 개선되고 있지 않은 실정이다.Thus, conventionally,'curable organopolysiloxane composition' of registration number 10-1187594,'adhesive encapsulation composition and electronic device manufactured therefrom' of registration number 10-1623220, and'adhesive composition' of registration number 10-1740185 Although is disclosed, the situation is still not improved with respect to the above problems.
본 발명은 상기한 종래기술의 문제점을 해결하기 위해 안출해낸 것으로써, 실리콘캡슐 내부의 조성물을 이용하여 경화시키는 위치 및 제품에 맞게 상기 조성물 중에서 일부분의 성분량을 조절하여 경화되는 시간을 조절할 수 있고, 경화력을 극대화하기 위해 추가적인 조성물을 혼합하였으며, 사용자가 실리콘캡슐의 파열을 손쉽게 하거나 또는 별도의 제품을 통해 실리콘캡슐의 파열이 손쉽게 되도록 실리콘캡슐에 대한 형상, 구조 및 재질에 대해서도 한정한 경화용 액상 조성물이 구비된 실리콘캡슐을 제공함에 주안점을 두고 기술적 과제로서 완성해낸 것이다.The present invention has been devised to solve the problems of the prior art, and the curing time can be controlled by adjusting the amount of a part of the composition in accordance with the curing position and product using the composition inside the silicone capsule, An additional composition is mixed to maximize the curing power, and a curing liquid with limited shape, structure and material of the silicone capsule so that the user can easily rupture the silicone capsule or easily rupture the silicone capsule through a separate product. It was completed as a technical task with an emphasis on providing a silicone capsule with a composition.
이에 본 발명은 외부의 힘으로 피막이 파열되어 내부에 있는 액상이 외부로 흘러내려 상기 액상이 시간의 흐름에 따라 경화되는 액상용 실리콘캡슐에 있어서, 상기 실리콘캡슐의 내부에는 다수개의 성분이 혼합된 액상의 조성물이 구비되되 상기 조성물에는, 폴리디메틸실록산 45 ~ 65wt%, 디오가노 폴리실록산(액상) 20 ~ 35wt%, 촉매제 0.01 ~ 0.3wt% 가 혼합된 조성물로 이루어지는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐을 그 기술적 특징으로 한다.Accordingly, the present invention relates to a liquid silicone capsule in which a film is ruptured by an external force and the liquid inside flows to the outside so that the liquid is cured over time, wherein the inside of the silicone capsule is a liquid containing a plurality of components. The composition is provided with a composition of polydimethylsiloxane 45 ~ 65wt%, diorgano polysiloxane (liquid) 20 ~ 35wt%, catalyst is provided with a liquid composition for curing, characterized in that consisting of a mixture of 0.01 ~ 0.3wt% The silicone capsule is characterized by its technical features.
본 발명인 경화용 액상 조성물이 구비된 실리콘캡슐에 따르면, 실리콘캡슐의 형상을 한정하여 사용자가 직접 파열하거나 또는 별도의 제품을 통해 파열 시, 손쉽게 파열될 수 있도록 하였고, 실리콘캡슐의 파열을 더욱 손쉽게 하기 위해 돌출부 또는 홈부를 형성하였으며, 사용자의 외력 또는 별도 제품의 외력을 제외하고는 손쉽게 파열되지 않도록 재질을 한정하였고, 실리콘캡슐 내부의 액상 조성물에 대한 성분 중에서 경화되는 시간을 조절할 수 있도록 하였으며, 경화 시 경화력을 상승시킬 수 있는 성분에 대해서도 조절할 수 있도록 하는 등 효과가 큰 발명이다.According to the silicone capsule provided with the liquid composition for curing according to the present invention, the shape of the silicone capsule is limited so that when the user ruptures directly or through a separate product, it can be easily ruptured, making it easier to rupture the silicone capsule. For this purpose, protrusions or grooves are formed, and the material is limited so that it does not rupture easily except for the external force of the user or the external force of a separate product, and the curing time can be controlled among the components of the liquid composition inside the silicone capsule. It is an invention that has a great effect, such as being able to control components that can increase hardening power.
도 1은 본 발명인 실리콘캡슐을 나타내는 평면도
도 2는 본 발명인 실리콘캡슐에 대한 다양한 형상을 나타내는 측면도
도 3은 본 발명인 실리콘캡슐에 이중피막이 형성된 것을 나타내는 평면도
도 4는 본 발명인 실리콘캡슐에 돌출부 또는 홈부가 형성된 것을 나타내는 단면도
도 5는 도 3의 이중피막에 대한 다른 실시 예를 나타내는 단면도1 is a plan view showing the present inventors silicone capsule
Figure 2 is a side view showing various shapes of the present inventors silicone capsule
Figure 3 is a plan view showing that a double film is formed on the silicone capsule of the present invention
Figure 4 is a cross-sectional view showing that the protrusion or groove is formed in the silicone capsule of the present invention
5 is a cross-sectional view showing another embodiment of the double film of FIG. 3
이하, 첨부되는 도면과 관련하여 상기 목적을 달성하기 위한 본 발명의 바람직한 구성 및 작용에 대해 도 1 내지 도 5를 참고로 설명하면 다음과 같다.Hereinafter, a preferred configuration and operation of the present invention for achieving the above object will be described with reference to FIGS. 1 to 5 with reference to the accompanying drawings.
우선, 본 발명인 실리콘캡슐은 외부의 힘으로 피막이 파열되어 내부에 있는 액상이 외부로 흘러내려 상기 액상이 시간의 흐름에 따라 경화되는 액상용 실리콘캡슐에 있어서, 상기 실리콘캡슐의 내부에는 다수개의 성분이 혼합된 액상의 조성물이 구비되되 상기 조성물에는, 폴리디메틸실록산 45 ~ 65wt%, 디오가노 폴리실록산(액상) 20 ~ 35wt%, 촉매제 0.01 ~ 0.3wt% 가 혼합된 조성물을 포함한다.First of all, the silicone capsule of the present invention is a liquid silicone capsule in which the film is ruptured by an external force and the liquid inside flows to the outside so that the liquid is cured over time, wherein a plurality of components are contained in the silicone capsule. A mixed liquid composition is provided, but the composition includes a composition in which 45 to 65 wt% of polydimethylsiloxane, 20 to 35 wt% of diorgano polysiloxane (liquid), and 0.01 to 0.3 wt% of a catalyst are mixed.
상기 혼합물에 폴리 아크릴산 나트륨 1 ~ 1.2wt%, 실리콘오일 8 ~ 20wt%, 메틸옥시미노실란(methyl oximino silane : MOS) 1.5 ~ 8wt%, 비닐옥시미노실란(vinyl oximino silane : VOS) 0.2 ~ 3wt%, 연무질 실리카 2 ~ 15wt%, 아미노실란 0.2 ~ 3wt% 가 혼합된 제 1조성물이 포함된다.In the mixture, sodium polyacrylate 1 to 1.2 wt%, silicone oil 8 to 20 wt%, methyl oximino silane (MOS) 1.5 to 8 wt%, vinyl oximino silane (VOS) 0.2 to 3 wt% , 2 to 15 wt% of aerosol silica, and 0.2 to 3 wt% of aminosilane are mixed with the first composition.
상기 실리콘캡슐의 피막은 다수개의 성분이 혼합된 혼합물로 제조되되 나일론 50 ~ 70 중량부와, MWNT(Multi-Walled Nano Tube. 이하 '다층나노튜브'라함.) 2 ~ 4(0.1g/㎖) 중량부와, 산화방지제 0.2 중량부 및 분산제 1 ~ 5 중량부가 혼합된 혼합물을 가공, 압출하여 제조된다.The film of the silicone capsule is made of a mixture of a plurality of components, but 50 to 70 parts by weight of nylon and MWNT (Multi-Walled Nano Tube. hereinafter referred to as'multi-layer nanotube') 2 to 4 (0.1g/ml) It is prepared by processing and extruding a mixture of 0.2 parts by weight of an antioxidant and 1 to 5 parts by weight of a dispersant.
상기 혼합물에는 불포화 카르복실산 화합물의 공중합체로 이루어진 스티렌계수지 8 ~ 20 중량부와, 폴리에테르에스테르 수지 10 ~ 15 중량부와, 폴리에틸렌글리콜-디아크릴레이트를 친수성 단량체로 하는 화합물 3 ~ 7 중량부 및 플루오르 화합물 0.3 ~ 0.5중량부가 혼합된 제 1혼합물이 포함된다.The mixture includes 8 to 20 parts by weight of a styrene resin composed of a copolymer of an unsaturated carboxylic acid compound, 10 to 15 parts by weight of a polyether ester resin, and 3 to 7 parts by weight of a compound containing polyethylene glycol-diacrylate as a hydrophilic monomer. A first mixture in which 0.3 to 0.5 parts by weight of a part and a fluorine compound are mixed is included.
상기 실리콘캡슐은 원형 또는 다각형 또는 하나 이상의 중공부가 형성된 원형 또는 하나 이상의 중공부가 형성된 다각형으로 형성된다.The silicone capsule is formed in a circular shape or a polygonal shape or a circular shape in which one or more hollow portions are formed, or a polygon in which one or more hollow portions are formed.
상기 실리콘캡슐의 상부 또는 하부 또는 측면부 또는 중공부가 형성된 부분에는 하나 이상의 돌출부 또는 홈부가 형성되어 있다.One or more protrusions or grooves are formed in the upper or lower part of the silicone capsule, or at the side or hollow part.
상기한 본 발명에 대해 도 1 내지 도 5를 참고로 보다 상세히 설명하면,Referring to Figures 1 to 5 for the present invention described in more detail,
본 발명인 실리콘캡슐은 외부의 힘으로 피막이 파열되어 내부에 있는 액상이 외부로 흘러내려 상기 액상이 시간의 흐름에 따라 경화되도록 하는 실리콘캡슐로써, 내부에는 다수개의 성분이 혼합된 액상의 조성물이 구비되고, 피막은 다수개의 성분이 혼합된 합성수지재질로 제조된다.The silicone capsule of the present invention is a silicone capsule in which a film is ruptured by an external force so that the liquid inside flows to the outside so that the liquid is cured with the passage of time, and a liquid composition in which a plurality of components are mixed is provided. , The film is made of a synthetic resin material in which a number of components are mixed.
우선, 내부에 구비되는 다수개의 조성물은,First of all, a plurality of compositions provided inside,
상기 실리콘캡슐의 내부에 구비되되 폴리디메틸실록산 45 ~ 65wt%, 디오가노 폴리실록산(액상) 20 ~ 35wt%, 촉매제 0.01 ~ 0.3wt% 가 혼합된 조성물을 포함한다.It is provided inside the silicone capsule, but includes a composition in which 45 to 65 wt% of polydimethylsiloxane, 20 to 35 wt% of diorgano polysiloxane (liquid), and 0.01 to 0.3 wt% of a catalyst are mixed.
상기 조성물에는 실리콘캡슐의 사용용도 및 경화되는 시간에 따라 촉매제의 양을 조절할 수 있으며, 그에 따라 폴리디메틸실록산과 디오가노 폴리실록산에 대한 양도 조절될 수 있다.In the composition, the amount of the catalyst may be adjusted according to the usage of the silicone capsule and the curing time, and accordingly, the amount of polydimethylsiloxane and diorgano polysiloxane may be adjusted.
또한, 상기 혼합된 조성물에는 조성물의 목적 및 효과에 따라 혼합된 제 1조성물이 포함된다.In addition, the mixed composition includes the first composition mixed according to the purpose and effect of the composition.
상기 제 1조성물에는 폴리 아크릴산 나트륨 1 ~ 1.2wt%, 실리콘오일 8 ~ 20wt%, 메틸옥시미노실란(methyl oximino silane : MOS) 1.5 ~ 8wt%, 비닐옥시미노실란(vinyl oximino silane : VOS) 0.2 ~ 3wt%, 연무질 실리카 2 ~ 15wt%, 아미노실란 0.2 ~ 3wt% 가 혼합된다.The first composition includes 1 to 1.2 wt% of sodium polyacrylate, 8 to 20 wt% of silicone oil, 1.5 to 8 wt% of methyl oximino silane (MOS), and 0.2 to vinyl oximino silane (VOS). 3wt%, aerosol silica 2~15wt%, aminosilane 0.2~3wt% are mixed.
상기 기본조성물(폴리디메틸실록산, 디오가노 폴리실록산, 촉매제가 혼합된 조성물)은 제 1조성물과 동시에 혼합한 후, 일정 온도로 가열단계를 거쳐 완성된다.The basic composition (a composition in which polydimethylsiloxane, diorgano polysiloxane, and a catalyst is mixed) is mixed with the first composition at the same time, and then heated to a certain temperature to be completed.
또한, 상기 제 1조성물의 경우, 상기와 같이 기본조성물에 동시에 혼합하거나 또는 상기 제 1조성물의 성분을 별도로 혼합한 후, 일정온도로 가열하고 건조기를 이용하여 1차 건조하고, 완전 건조된 제 1조성물에 대해 일정온도로 가열하고 자연건조를 이용하여 2차 건조한 후, 완전 건조된 제 1조성물에 대해 상기 기본조성물과 혼합하여 일정 온도로 가열단계를 거쳐 최종적으로 완성하게 되도록 하였다.In addition, in the case of the first composition, after simultaneously mixing with the basic composition or separately mixing the components of the first composition as described above, the first composition is heated to a certain temperature and first dried using a dryer, and then completely dried. The composition was heated to a certain temperature and then dried for a second time using natural drying, and then the completely dried first composition was mixed with the basic composition to be finally completed through a heating step at a certain temperature.
상기 1차 건조 후 또는 1차 건조와 2차 건조 후에는 각각 촉매제가 일정량 추가될 수도 있다.After the first drying or after the first drying and the second drying, a certain amount of a catalyst may be added, respectively.
상기 실리콘캡슐의 피막은 다수개의 성분이 혼합된 혼합물로 제조되되 나일론 50 ~ 70 중량부와, MWNT(Multi-Walled Nano Tube. 이하 '다층나노튜브'라함.) 2 ~ 4(0.1g/㎖) 중량부와, 산화방지제 0.2 중량부 및 분산제 1 ~ 5 중량부가 혼합된 혼합물을 가열, 가공 및 압출하여 제조된다.The film of the silicone capsule is made of a mixture of a plurality of components, but 50 to 70 parts by weight of nylon and MWNT (Multi-Walled Nano Tube. hereinafter referred to as'multi-layer nanotube') 2 to 4 (0.1g/ml) It is prepared by heating, processing and extruding a mixture in which parts by weight, 0.2 parts by weight of an antioxidant and 1 to 5 parts by weight of a dispersant are mixed.
상기 혼합물은 가열, 가공 및 압출을 순차적으로 진행할 수도 있지만,The mixture may be heated, processed and extruded sequentially, but
혼합물의 내구성을 위해 1차 가공 후, 건조기를 통한 1차 건조와, 1차 건조 완료된 혼합물을 2차 가공하여 자연건조를 통한 2차 건조 및 2차 건조 완료된 혼합물을 3차 가공하여 건조기를 통한 3차 건조까지 완료된 혼합물을 압출하여 피막을 제조할 수 있다.For the durability of the mixture, after the first processing, the first drying through a dryer, the second drying through natural drying by secondary processing the mixture, and the second drying through natural drying, and the third processing of the finished mixture through a dryer. The mixture can be extruded until the secondary drying is completed to prepare a film.
또한, 상기 혼합물에는 불포화 카르복실산 화합물의 공중합체로 이루어진 스티렌계수지 8 ~ 20 중량부와, 폴리에테르에스테르 수지 10 ~ 15 중량부와, 폴리에틸렌글리콜-디아크릴레이트를 친수성 단량체로 하는 화합물 3 ~ 7 중량부 및 플루오르 화합물 0.3 ~ 0.5중량부가 혼합된 제 1혼합물이 포함된다.In addition, the mixture includes 8 to 20 parts by weight of a styrene resin composed of a copolymer of an unsaturated carboxylic acid compound, 10 to 15 parts by weight of a polyether ester resin, and a compound 3 to 3 having polyethylene glycol-diacrylate as a hydrophilic monomer. A first mixture in which 7 parts by weight and 0.3 to 0.5 parts by weight of a fluorine compound are mixed is included.
상기 혼합물과 제 1혼합물의 혼합은,Mixing the mixture and the first mixture,
단순 혼합으로 통해 피막을 제조할 수도 있지만,The film can also be prepared by simple mixing,
상기 제 1혼합물을 혼합물과 혼합하기 전, 전처리과정을 거친 후, 혼합하여 사용할 수도 있다.Before mixing the first mixture with the mixture, after undergoing a pretreatment process, the first mixture may be mixed and used.
상기 제 1혼합물에 대한 전처리과정은,The pretreatment process for the first mixture,
상기 제 1혼합물을 혼합하여 1차 가공 후, 건조기를 통한 1차 건조와, 1차 건조 완료된 혼합물을 2차 가공하여 자연건조를 통한 2차 건조까지 완료된 제 1혼합물을 상기한 혼합물과 혼합하여 최종적으로 건조기를 통해 건조한 후, 압출하여 피막을 제조할 수 있다.After the first mixture is mixed and processed, the first mixture is mixed with the mixture and the mixture is first dried through a dryer, and the mixture is secondarily dried through natural drying. After drying through a dryer, it can be extruded to prepare a film.
상기 실리콘캡슐은 원형 또는 다각형 또는 하나 이상의 중공부가 형성된 원형 또는 하나 이상의 중공부가 형성된 다각형으로 형성된다.The silicone capsule is formed in a circular shape or a polygonal shape or a circular shape in which one or more hollow portions are formed, or a polygon in which one or more hollow portions are formed.
상기 실리콘캡슐의 상부 또는 하부 또는 측면부 또는 중공부가 형성된 부분에는 하나 이상의 돌출부 또는 홈부가 형성되어 있다.One or more protrusions or grooves are formed in the upper or lower part of the silicone capsule, or at the side or hollow part.
상기 실리콘캡슐이 사용자로 하여금 외력이 닿는 부분 또는 실리콘캡슐이 파열되도록 외력을 가진 별도의 제품이 닿는 부분인 실리콘캡슐의 상부 또는 하부 또는 측면도 또는 중공부가 형성된 내측부분에는 2중피막이 하나 이상 형성된다.At least one double film is formed on the upper or lower part of the silicone capsule, the side view, or the inner part where the hollow part is formed of the silicone capsule, which is a part to which the user touches an external force or a part to which a separate product with external force touches so that the silicone capsule ruptures.
상기 2중피막은 내부에 공기층이 형성되며, 상기한 2중피막을 제외한 부분의 피막보다 2중피막의 두께가 얇게 형성된다.The double film has an air layer therein, and a thickness of the double film is thinner than that of the portion other than the double film.
상기 얇게 형성되는 2중피막은 한겹으로 형성된 피막과 대비하여 단일의 피막 두께를 나타낸다.The thinly formed double film exhibits a single film thickness compared to the single film formed in a single layer.
상기 2중피막의 경우, 외피와 내피로 각각 구분되지만, 외피의 내측에는 상기한 돌출부 또는 홈부가 하나 이상 형성될 수도 있다.In the case of the double film, it is divided into an outer skin and an inner skin, but one or more of the aforementioned protrusions or grooves may be formed inside the outer skin.
또한, 상기 2중피막의 내부에는 공기층이 형성되거나 또는 촉매제가 일정량 위치될 수도 있다.In addition, an air layer may be formed or a certain amount of a catalyst may be positioned inside the double film.
상기 2중피막에 위치되는 촉매제는 실리콘캡슐의 파열 시, 액상 조성물에 대한 경화 시간을 조절하기 위함이다.The catalyst positioned on the double film is to control the curing time for the liquid composition when the silicone capsule is ruptured.
상기와 같은 본 발명에 따르면, 실리콘캡슐의 형상을 한정하여 사용자가 직접 파열하거나 또는 별도의 제품을 통해 파열 시, 손쉽게 파열될 수 있도록 하였고, 실리콘캡슐의 파열을 더욱 손쉽게 하기 위해 돌출부 또는 홈부를 형성하였으며, 사용자의 외력 또는 별도 제품의 외력을 제외하고는 손쉽게 파열되지 않도록 재질을 한정하였고, 실리콘캡슐 내부의 액상 조성물에 대한 성분 중에서 경화되는 시간을 조절할 수 있도록 하였으며, 경화 시 경화력을 상승시킬 수 있는 성분에 대해서도 조절할 수 있도록 한다.According to the present invention as described above, the shape of the silicone capsule is limited so that when the user ruptures directly or through a separate product, it can be easily ruptured, and protrusions or grooves are formed to make the rupture of the silicone capsule easier. The material was limited so that it would not easily rupture except for the external force of the user or the external force of a separate product, and the curing time was controlled among the components of the liquid composition inside the silicone capsule, and the curing power can be increased during curing. You can also adjust the ingredients that are present.
Claims (7)
상기 조성물은,
폴리디메틸실록산 45 ~ 65wt%, 디오가노 폴리실록산(액상) 20 ~ 35wt%, 촉매제 0.01 ~ 0.3wt% 가 혼합된 기본조성물을 포함하고,
상기 기본조성물에 폴리 아크릴산 나트륨 1 ~ 1.2wt%, 실리콘오일 8 ~ 20wt%, 메틸옥시미노실란(methyl oximino silane : MOS) 1.5 ~ 8wt%, 비닐옥시미노실란(vinyl oximino silane : VOS) 0.2 ~ 3wt%, 연무질 실리카 2 ~ 15wt%, 아미노실란 0.2 ~ 3wt% 가 혼합된 제 1조성물이 포함되며,
상기 피막은 다수개의 성분이 혼합된 기본혼합물을 가공, 압출하여 제조되되,
상기 기본혼합물에는,
나일론 50 ~ 70 중량부와, MWNT(Multi-Walled Nano Tube. 이하 '다층나노튜브'라함.) 2 ~ 4(0.1g/㎖) 중량부와, 산화방지제 0.2 중량부 및 분산제 1 ~ 5 중량부가 혼합된 기본혼합물이 포함되고,
불포화 카르복실산 화합물의 공중합체로 이루어진 스티렌계수지 8 ~ 20 중량부와, 폴리에테르에스테르 수지 10 ~ 15 중량부와, 폴리에틸렌글리콜-디아크릴레이트를 친수성 단량체로 하는 화합물 3 ~ 7 중량부 및 플루오르 화합물 0.3 ~ 0.5중량부가 혼합된 제 1혼합물이 포함된 액상용 실리콘캡슐에 있어서,
상기 조성물은 기본조성물과 제 1조성물이 상호 혼합되되,
제 1조성물의 성분들은 혼합 후, 일정온도로 가열하여 건조기를 통한 1차건조와, 상기 1차건조 완료된 제 1조성물을 일정온도로 가열하여 자연건조를 통한 2차건조와, 상기 2차건조 완료된 제 1조성물을 기본조성물과 상호 혼합하여 일정온도로 가열하여 조성물을 완성하고,
상기 기본혼합물은 가열, 가공 및 압출을 순차적으로 진행하되,
기본혼합물의 성분들을 혼합하여 1차 가공 후, 건조기를 통한 1차건조와, 상기 1차건조 완료된 기본혼합물을 자연건조를 통한 2차건조와, 상기 2차건조 완료된 기본혼합물과 제 1혼합물을 혼합 후, 건조기를 통한 3차건조를 거쳐 피막을 제조하며,
상기 제 1혼합물은 기본혼합물과 혼합 전, 전처리과정을 거치되,
제 1혼합물의 성분들을 혼합하여 1차가공 후, 건조기를 통한 1차건조와, 상기 1차건조 완료된 제 1혼합물을 자연건조를 통한 2차건조를 거친 후, 상기 기본혼합물과 혼합되는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
The film is ruptured by an external force, and the liquid inside flows to the outside, and the liquid phase hardens over time, and a liquid composition in which a plurality of components are mixed is provided,
The composition,
Including a basic composition in which 45 to 65 wt% of polydimethylsiloxane, 20 to 35 wt% of diorgano polysiloxane (liquid), and 0.01 to 0.3 wt% of a catalyst are mixed,
In the basic composition, 1 to 1.2 wt% of sodium polyacrylate, 8 to 20 wt% of silicone oil, 1.5 to 8 wt% of methyl oximino silane (MOS), 0.2 to 3 wt of vinyl oximino silane (VOS) %, aerosol silica 2 ~ 15wt%, aminosilane 0.2 ~ 3wt% is mixed with the first composition,
The film is manufactured by processing and extruding a basic mixture in which a plurality of components are mixed,
In the basic mixture,
50 to 70 parts by weight of nylon, 2 to 4 (0.1g/ml) parts by weight of MWNT (Multi-Walled Nano Tube. hereinafter referred to as'multi-layer nanotubes'), 0.2 parts by weight of antioxidant and 1 to 5 parts by weight of dispersant A mixed basic mixture is included,
8 to 20 parts by weight of a styrene resin composed of a copolymer of an unsaturated carboxylic acid compound, 10 to 15 parts by weight of a polyether ester resin, 3 to 7 parts by weight of a compound containing polyethylene glycol-diacrylate as a hydrophilic monomer, and fluorine In the liquid silicone capsule containing the first mixture in which 0.3 to 0.5 parts by weight of the compound is mixed,
The composition is mixed with the base composition and the first composition,
The components of the first composition are mixed and then heated to a certain temperature to be first dried through a dryer, and the first composition is heated to a certain temperature to be dried through natural drying, and the second dried is completed. The first composition is mixed with the basic composition and heated to a certain temperature to complete the composition,
The basic mixture is heated, processed and extruded sequentially,
After primary processing by mixing the components of the basic mixture, primary drying through a dryer, secondary drying through natural drying of the primary mixture, and mixing the primary mixture and the first mixture completed with the secondary drying After that, the film is prepared through the third drying through a dryer,
The first mixture is subjected to a pretreatment process before mixing with the basic mixture,
The components of the first mixture are mixed and subjected to primary processing, followed by primary drying through a dryer, and secondary drying through natural drying of the first mixture, and then mixing with the basic mixture. A silicone capsule with a liquid composition for curing.
상기 실리콘캡슐(10)은 원형 또는 다각형 또는 하나 이상의 중공부가 형성된 원형 또는 하나 이상의 중공부가 형성된 다각형으로 형성되는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
The method of claim 1,
The silicone capsule 10 is a silicone capsule provided with a liquid composition for curing, characterized in that it is formed in a circular shape or a polygonal shape or a circular shape in which one or more hollow portions are formed, or a polygonal shape in which one or more hollow portions are formed.
상기 실리콘캡슐(10)의 상부 또는 하부 또는 측면부 또는 중공부가 형성된 부분에는 하나 이상의 돌출부 또는 홈부(110)가 형성되어 있는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
The method of claim 5,
A silicone capsule provided with a liquid composition for curing, characterized in that at least one protrusion or groove 110 is formed in an upper or lower portion of the silicone capsule 10, a side portion, or a hollow portion.
상기 실리콘캡슐(10)의 상부 또는 하부 또는 측면부 또는 중공부가 형성된 내측부분에는 2중 피막(120)으로 형성되는 것을 특징으로 하는 경화용 액상 조성물이 구비된 실리콘캡슐.
The method of claim 5,
A silicone capsule provided with a liquid composition for curing, characterized in that the upper or lower part of the silicone capsule 10, a side part, or an inner part formed with a hollow part is formed as a double film 120.
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