KR102116332B1 - Process for preparing bread with added cacao beans and rice extrudate - Google Patents

Process for preparing bread with added cacao beans and rice extrudate Download PDF

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KR102116332B1
KR102116332B1 KR1020180041035A KR20180041035A KR102116332B1 KR 102116332 B1 KR102116332 B1 KR 102116332B1 KR 1020180041035 A KR1020180041035 A KR 1020180041035A KR 20180041035 A KR20180041035 A KR 20180041035A KR 102116332 B1 KR102116332 B1 KR 102116332B1
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bread
cacao
rice
added
extruded
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KR20190117988A (en
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류기형
박주연
김영호
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공주대학교 산학협력단
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D8/00Methods for preparing or baking dough
    • A21D8/06Baking processes
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/04Products made from materials other than rye or wheat flour
    • A21D13/047Products made from materials other than rye or wheat flour from cereals other than rye or wheat, e.g. rice
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/36Vegetable material
    • A21D2/364Nuts, e.g. cocoa
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/36Vegetable material
    • A21D2/368Fermentation by-products, e.g. grapes, hops
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D8/00Methods for preparing or baking dough
    • A21D8/02Methods for preparing dough; Treating dough prior to baking
    • A21D8/04Methods for preparing dough; Treating dough prior to baking treating dough with microorganisms or enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/197Treatment of whole grains not provided for in groups A23L7/117 - A23L7/196
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P10/00Shaping or working of foodstuffs characterised by the products
    • A23P10/20Agglomerating; Granulating; Tabletting
    • A23P10/25Agglomeration or granulation by extrusion or by pressing, e.g. through small holes, through sieves or between surfaces
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/20Extruding

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Microbiology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)

Abstract

본 발명은 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법 및 이에 의해 제조된 빵을 제공한다. 본 발명의 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법 및 이에 의해 제조된 빵은 압출성형물의 함량 변화에 따라 제조된 빵의 이화학적 특성, 물리적 특성, 호화특성 등이 변화되고, 제조된 빵의 외관 및 기호도가 특정 비율에서 증가되는 것이 확인되었다. 따라서, 본 발명의 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법 및 이에 의해 제조된 빵은 식품 및 제빵 분야에서 카카오 빈을 활용할 수 있는 기술로 유용하게 사용될 수 있다.The present invention provides a method for producing bread to which cacao beans and rice extrudates are added, and the bread produced thereby. The method of manufacturing bread to which the cacao bean and rice extruded product of the present invention is added and the bread produced by the change in physicochemical properties, physical properties, luxury properties, etc. of the bread produced according to the change in the content of the extruded product, are prepared It was confirmed that the appearance and palatability of the bread increased at a specific rate. Therefore, the method for producing bread to which the cacao bean and the rice extruded product of the present invention are added and the bread produced thereby can be usefully used as a technique for utilizing cacao bean in the food and bakery fields.

Description

카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법{Process for preparing bread with added cacao beans and rice extrudate}Process for preparing bread with added cacao beans and rice extrudate}

본 발명은 빵의 제조방법에 관한 것으로, 더욱 상세하게는 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법에 관한 것이다.The present invention relates to a method of manufacturing bread, and more particularly, to a method of manufacturing bread to which cacao beans and rice extrusion are added.

경제 성장에 따른 생활수준의 향상으로 인간의 수명이 증가하고 건강에 대한 관심이 높아지면서 건강유지를 위한 기능성 생리활성물질에 대한 연구가 활발히 진행되고 있다(1). 그 중 항산화기능을 가진 피토케미칼(phytochemical)로는 녹차, 홍차, 적포도주 및 초콜릿류와 코코아 함유 식품 등이 있으며, 초콜릿 가공품 등의 원료가 되는 카카로 빈(cacao bean)은 카카오(Theobroma cacao) 나무 열매의 씨앗으로 적도의 남북 위도 20° 이내의 수림지역에서 광범위하게 재배되며, 카페인 성분과 유사한 테오브로민(theobromine)과 폴리페놀(polyphenol)이 주요한 성분으로 폴리페놀 함량(2), 항산화활성(3), 충치예방(4) 등 기능성 성분에 대한 연구가 진행되어 왔다. 카카오 빈은 수확하여 발효, 건조, 세척, 로스팅, 분쇄를 거쳐 껍질을 제거한 카카오 닙(cacao nibs)을 카카오 매스(cacao mass)로 가공하여 그대로 사용하거나, 이 카카오 매스(cacao mass)를 압착 또는 용매 추출하여 코코아 버터(cocoa butter)와 지방이 제거된 코코아 분말(cocoa powder)로 가공된다(5).With the improvement of living standards due to economic growth, human lifespan increases and interest in health increases, and research on functional physiologically active substances for maintaining health has been actively conducted (1). Among them, phytochemicals that have antioxidant functions include green tea, black tea, red wine, and foods containing chocolates and cocoa, and cacao beans, which are raw materials for processed chocolate products, are cacao (Theobroma cacao) fruit As a seed, it is cultivated extensively in the forest region within 20 ° of the north and south latitudes of the equator, and theobromine and polyphenol, similar to caffeine, are the main components, with polyphenol content (2), antioxidant activity (3), Research into functional ingredients such as tooth decay prevention (4) has been conducted. The cacao beans are harvested, fermented, dried, washed, roasted, and crushed to remove the peeled cacao nibs into cacao mass, or used as it is, or the cacao mass is compressed or solvent It is extracted and processed into cocoa butter and cocoa powder from which fat is removed (5).

음료나 제과제빵의 소재로 사용되는 코코아 분말(cocoa powder)은 알칼리처리 된 것이 대부분으로 약한 알칼리처리는 색상을 조절하고 수용성을 증대시키는 역할을 하지만 폴리페놀함량은 감소하고(3), pH는 증가하게 된다(6). 빵에서 pH의 증감에 대한 연구를 보면 신안섬초 첨가시 pH의 증가로 인해 식빵의 비용적이 감소하였고(7), 한라봉 분말 첨가시는 pH의 감소로 인해 비용적이 감소하였다고 보고된 바 있다(8). 한편 코코아 분말을 이용한 연구로는 코코아 분말과 콘밀(cornmeal)을 이용한 압출성형(9), 유통되는 코코아 함유 가공품의 항산화활성과 폴리페놀 함량 연구(10), 코코아 분말을 첨가한 식빵의 단백질 및 관능특성(11), 알칼리 처리한 코코아 분말의 폴리페놀 및 안토시아닌 함량연구(12)등이 진행되어 오고 있지만 카카오 빈(cacao whole bean)을 빵에 사용한 연구는 아직 없는 실정이다. 카카오 빈 껍질(cacao bean shell)에는 변비에 효과가 있는 식이섬유가 풍부하며(13) 특히 로스팅(roasting)과 알칼리처리 하지 않은 카카오 빈(cacao whole bean)을 압출성형 하였을 때 항산화활성이 우수하다고 본 발명의 발명자에 의해 보고된 바 있다(14). 압출성형은 고온, 고압, 고전단력이 식품원료의 분자적 구조특성을 효율적으로 변화시켜서 최종적인 조직의 특성을 유도하는데(15) 카카오 빈에는 일반적으로 50% 정도의 많은 지방을 포함하기 때문에 단독으로 압출성형하기 어려워 쌀의 소비를 촉진함과 동시에 밀가루에 비해 알레르기 유발비율이 낮고 소화가 잘되며 필수아미노산 등 영양적인 측면에서 우수한 쌀(16)과 함께 카카오 빈(cacao whole bean)을 압출성형 하였다.Cocoa powder, which is used as a material for beverages or confectionery, is alkali-treated. Mostly, weak alkali treatment serves to control color and increase water solubility, but decreases polyphenol content (3) and increases pH. (6). Studies on the increase and decrease of pH in bread have been reported to decrease the cost of white bread due to an increase in pH when adding Sinanseomcho (7), and a decrease in cost due to a decrease in pH when adding Hallabong powder (8). . Meanwhile, studies using cocoa powder include extrusion molding using cocoa powder and cornmeal (9), antioxidant activity and polyphenol content study of processed cocoa-containing processed products (10), protein and sensory properties of bread added with cocoa powder Characteristics (11), polyphenol and anthocyanin content studies of alkali-treated cocoa powder (12) have been conducted, but there have been no studies using cacao whole beans for bread. The cacao bean shell is rich in dietary fiber that is effective for constipation (13), and is considered to have excellent antioxidant activity, especially when extruding cacao whole beans that have not been roasted and alkali-treated. It has been reported by the inventors of the invention (14). Extrusion is a high-temperature, high-pressure, high-shear force that effectively changes the molecular structural properties of food ingredients to induce final tissue properties (15). Because cacao beans generally contain as much as 50% of fat, they are used alone. It is difficult to extrude, and at the same time, it promotes consumption of rice, and at the same time, it has a lower allergen-producing rate than wheat flour, has good digestion, and extruded cacao whole beans along with rice 16, which is excellent in nutritional aspects such as essential amino acids.

이에 본 발명에서는 생리활성물질로서 카카오 폴리페놀의 기능성과 항산화활성에 대한 자료는 있으나 이를 식품소재로 활용한 자료는 미비하여 그 접근을 하고자 하였다.Accordingly, in the present invention, there are data on the functionality and antioxidant activity of cacao polyphenols as physiologically active substances, but the data using them as food materials were insufficient and attempted to approach them.

한국 공개특허 제10-2010-0064339호 (2010.06.14.)Korean Patent Publication No. 10-2010-0064339 (2010.06.14.) 한국 공개특허 제10-2017-0108594호 (2017.09.27.)Korean Patent Publication No. 10-2017-0108594 (2017.09.27.) 한국 공개특허 제10-2017-0037353호 (2017.04.04)Korean Patent Publication No. 10-2017-0037353 (2017.04.04)

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Part 1-chemical composition, solid fat content and consistency. GRASAS Y ACEITES 63: 79-88. 23. Lee JY, Lee KA, Kwak EJ. 2009. Fermentation characteristics of bread added with Pleurotus eryngii powder. J Korean Soc Food Sci Nutr 38: 757-765.23.Lee JY, Lee KA, Kwak EJ. 2009. Fermentation characteristics of bread added with Pleurotus eryngii powder. J Korean Soc Food Sci Nutr 38: 757-765. 24. Oh WG, Kim JH, Lee SC. 2011. Preparation and characterization of white bread with sweet persimmon. J Korean Soc Food Sci Nutr40: 253-258.24.Oh WG, Kim JH, Lee SC. 2011. Preparation and characterization of white bread with sweet persimmon. J Korean Soc Food Sci Nutr 40: 253-258. 25. Kim YS, Kim MY, Chun SS. 2008. Qualitycharacteristics of domestic wheat white bread with substitutedNelumbo nucifefa G. tea powder. J Korean Soc Food Sci Nutr21: 448-456.25. Kim YS, Kim MY, Chun SS. 2008. Qualitycharacteristics of domestic wheat white bread with substitutedNelumbo nucifefa G. tea powder. J Korean Soc Food Sci Nutr 21: 448-456. 26. Yoon HS, Kim JW, Kim SH, Kim YG, Eom HJ. 2014. Quality characteristics of bread added with aronia powder(Aronia melanocarpa). J Korean Soc Food Sci Nutr43: 273-280.26. Yoon HS, Kim JW, Kim SH, Kim YG, Eom HJ. 2014. Quality characteristics of bread added with aronia powder (Aronia melanocarpa). J Korean Soc Food Sci Nutr 43: 273-280. 27. Shin JW, Shin GM. 2008. Qualityof white pan bread as affected by various concentrations of Corni fructus powder. J East Asian Soc Dietary Life 18: 1007-1013.27.Shin JW, Shin GM. 2008. Qualityof white pan bread as affected by various concentrations of Corni fructus powder. J East Asian Soc Dietary Life 18: 1007-1013. 28. Kang MY, Nam YJ. 1999. Studies on bread-making qualityof colored rice (Suwon 415) flours. Korean J Soc Food Sci 15: 37-41.28. Kang MY, Nam YJ. 1999. Studies on bread-making quality of colored rice (Suwon 415) flours. Korean J Soc Food Sci 15: 37-41. 29. SulaimanKB, Yang TA. 2015. 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본 발명의 발명자들은 카카오 폴리페놀의 기능성과 항산화활성을 식품소재로 활용하는 방법에 대하여 연구하던 중, 쌀과 로스팅하지 않은 카카오 빈의 비율이 4 : 6 으로 압출성형한 압출성형물을 첨가(10, 20, 30%)하여 빵을 제조하고 그 반죽의 물성 및 식빵의 품질에 미치는 영향을 관찰함으로써, 카카오 빈의 폴리페놀과 항산화활성을 충분히 활용함과 동시에 소비자의 기호에 맞는 빵을 제조할 수 있다는 것을 발견하였다.The inventors of the present invention, while studying the method of utilizing the functionality and antioxidant activity of cacao polyphenols as a food material, added a ratio of rice and unroasted cacao beans with an extrusion molding extruded at a ratio of 4: 6 (10, 20, 30%) by making the bread and observing the effect on the properties of the dough and the quality of the bread, making full use of the polyphenols and antioxidant activity of cacao beans and at the same time producing bread that suits the consumer's preferences. Found something.

따라서, 본 발명은 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법 및 이에 의해 제조된 빵을 제공하는 것을 목적으로 한다.Accordingly, an object of the present invention is to provide a method for producing bread to which cacao beans and rice extrudates have been added, and bread prepared thereby.

본 발명의 일 측면에 따라, (a) 카카오 빈-쌀 압출성형물과 밀가루를 혼합하여 반죽을 얻는 단계; 및 (b) 단계(a)에서 얻어진 반죽을 발효시킨 후 굽는 단계를 포함하는, 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법이 제공된다.According to an aspect of the present invention, (a) cacao beans-mixing the extrudate and flour to obtain a dough; And (b) fermenting the dough obtained in step (a), followed by baking, to provide a method for producing bread to which cacao beans and rice extrusion are added.

일 구현예에서, 단계(a)의 상기 카카오 빈-쌀 압출성형물은 쌀 : 카카오 빈의 중량비 4 : 6으로 혼합되어 압출성형된 것일 수 있다. In one embodiment, the cacao bean-rice extrudate of step (a) may be extruded by mixing in a weight ratio of rice: cacao bean 4: 6.

일 구현예에서, 단계(a)에서 카카오 빈-쌀 압출성형물 : 밀가루의 혼합 중량비가 1 : 9 ~ 2 : 8일 수 있다.In one embodiment, the mixing weight ratio of the cacao bean-rice extrudate: wheat flour in step (a) may be 1: 9-2: 8.

일 구현예에서, 단계(b)의 상기 발효는 1차 발효, 중간 발효, 2차 발효의 순서로 이루어질 수 있다.In one embodiment, the fermentation in step (b) may be made in the order of primary fermentation, intermediate fermentation, and secondary fermentation.

일 구현예에서, 단계(a)의 상기 압출성형물은 쌍축 압출성형기를 사용하여 스크루 직경 20.0 ~ 40.0 mm, 길이/직경의 비(L/D ratio) 20 ~ 25:1인 스크루를 사용하고, 수분 함량 15 ~ 35%, 스크루 회전속도 100 ~ 300 rpm, 사출구 온도 120 ~ 140℃의 조건으로 압출성형된 것일 수 있다.In one embodiment, the extrudate of step (a) is a screw diameter 20.0 ~ 40.0 mm using a twin-screw extruder, length / diameter ratio (L / D ratio) using a screw of 20 ~ 25: 1, moisture Content 15 ~ 35%, screw rotation speed 100 ~ 300 rpm, the injection port temperature may be extruded under the conditions of 120 ~ 140 ℃.

본 발명의 다른 측면에 따라, 상기 제조방법에 의해 제조된 카카오 빈과 쌀 압출성형물을 첨가한 빵이 제공된다.According to another aspect of the present invention, a bread to which cacao beans and rice extrudates prepared by the above manufacturing method are added is provided.

본 발명의 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법 및 이에 의해 제조된 빵에 의해, 쌀과 로스팅하지 않은 카카오 빈의 압출성형물(쌀과 로스팅하지 않은 카카오 빈이 4 : 6으로 압출성형됨)을 첨가(10, 20, 30%)하여 빵을 제조하면 압출성형물의 함량 변화에 따라 제조된 빵의 이화학적 특성, 물리적 특성, 호화특성 등이 변화되고, 제조된 빵의 외관 및 기호도가 특정 비율에서 증가되는 것으로 확인되었다.The method for producing bread to which the cacao bean and rice extruded product of the present invention is added and the bread produced thereby, the extruded product of cacao bean that has not been roasted with rice (rice cacao bean that has not been roasted with rice is extruded to 4: 6) ) (10, 20, 30%) to produce bread, the physicochemical properties, physical properties, luxury properties, etc. of the bread are changed according to the content of the extruded product, and the appearance and preference of the bread are specified. It was confirmed to increase in proportion.

따라서, 본 발명의 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법 및 이에 의해 제조된 빵은 식품 및 제빵 분야에서 카카오 빈을 활용할 수 있는 기술로 유용하게 사용될 수 있다.Therefore, the method for producing bread to which the cacao bean and the rice extruded product of the present invention are added and the bread produced thereby can be usefully used as a technique for utilizing cacao bean in the food and bakery fields.

도 1은 압출성형물의 제조에 사용된 압출성형기의 스크루 배열이다.
도 2는 압출성형물과 비-압출성형물을 첨가하여 제조한 식빵의 발효 팽창력이다.
도 3은 압출성형물과 비-압출성형물을 첨가하여 제조한 식빵의 외관이다.
1 is a screw arrangement of an extrusion molding machine used for the production of an extrusion molding.
Figure 2 is the fermentation expansion force of the bread prepared by adding the extruded and non-extruded.
Figure 3 is the appearance of the bread prepared by adding the extruded and non-extruded.

본 발명은 (a) 카카오 빈-쌀 압출성형물과 밀가루를 혼합하여 반죽을 얻는 단계; 및 (b) 단계(a)에서 얻어진 반죽을 발효시킨 후 굽는 단계를 포함하는, 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법을 제공한다.The present invention comprises the steps of (a) mixing the cacao bean-rice extrudate and flour to obtain a dough; And (b) fermenting the dough obtained in step (a), followed by baking, to provide a method for producing bread to which cacao beans and rice extrusion are added.

본 발명의 제조방법은 카카오 빈-쌀 압출성형물과 밀가루를 혼합하여 반죽을 얻는 단계[즉, 단계(a)]를 포함한다. 단계(a)에서 상기 카카오 빈-쌀 압출성형물은 쌀 : 카카오 빈의 중량비 4 : 6으로 혼합되어 압출성형된 것일 수 있다. 또한, 카카오 빈-쌀 압출성형물 : 밀가루의 혼합 중량비는 1 : 9 ~ 2 : 8일 수 있다. 반죽 형성 시에는 반죽 형성에 사용되는 통상적 첨가제, 예를 들어, 강력분, 쇼트닝, 설탕, 정제염, 이스트 등이 추가될 수 있다. 상기 압출성형물은 쌍축 압출성형기를 사용하여 스크루 직경 20.0 ~ 40.0 mm, 길이/직경의 비(L/D ratio) 20 ~ 25:1인 스크루를 사용하고, 수분 함량 15 ~ 35%, 스크루 회전속도 100 ~ 300 rpm, 사출구 온도 120 ~ 140℃의 조건으로 압출성형된 것일 수 있다.The manufacturing method of the present invention includes the step of obtaining dough by mixing the cocoa bean-rice extrudate and flour (ie, step (a)). In step (a), the cacao bean-rice extrudate may be extruded by mixing rice: cacao bean in a weight ratio of 4: 6. In addition, the mixed weight ratio of the cacao bean-rice extruded product: flour may be 1: 9 ~ 2: 8. When forming the dough, conventional additives used for forming the dough may be added, for example, strong powder, shortening, sugar, refined salt, yeast, and the like. The extrudate is a screw having a screw diameter of 20.0 to 40.0 mm and a length / diameter ratio (L / D ratio) of 20 to 25: 1 using a twin-screw extruder, water content of 15 to 35%, screw rotation speed of 100 ~ 300 rpm, the injection port temperature may be extruded under the conditions of 120 ~ 140 ℃.

본 발명의 제조방법은 단계(a)에서 얻어진 반죽을 발효시킨 후 굽는 단계[즉, 단계(b)]를 포함한다. 단계(b)에서 상기 발효는 1차 발효, 중간 발효, 2차 발효의 순서로 이루어질 수 있으며, 각 발효는 통상적으로 사용되는 발효 조건으로 수행될 수 있다.The manufacturing method of the present invention includes a step of fermenting the dough obtained in step (a) and then baking (ie, step (b)). In step (b), the fermentation may be performed in the order of primary fermentation, intermediate fermentation, and secondary fermentation, and each fermentation may be performed under commonly used fermentation conditions.

본 발명은 또한, 상기 제조방법에 의해 제조된 카카오 빈과 쌀 압출성형물을 첨가한 빵을 제공한다.The present invention also provides a bread to which cacao beans and rice extrusion formed by the above manufacturing method are added.

본 발명의 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법에 의해 제조된 빵은 쌀과 로스팅하지 않은 카카오 빈의 압출성형물(쌀과 로스팅하지 않은 카카오 빈이 4 : 6으로 압출성형됨)을 첨가하여 빵을 제조하는 경우에 압출성형물의 함량 변화에 따라 제조된 빵의 이화학적 특성, 물리적 특성, 호화특성 등이 변화되고, 압출성형물의 특정 함량 비율에서 제조된 빵의 외관 및 기호도가 증가되는 것으로 확인되었다.The bread produced by the method for producing bread to which the cacao bean and the rice extruded product of the present invention is added is an extruded product of cacao bean that is not roasted with rice (the cacao bean that has not been roasted with rice is extruded to 4: 6). In the case of making bread, the physicochemical properties, physical properties, and luxury properties of the bread produced are changed according to the change in the content of the extruded product, and the appearance and preference of the bread produced at a specific content ratio of the extruded product are increased. Was confirmed.

이하, 본 발명을 실시예를 통하여 더욱 상세히 설명한다. 그러나, 하기 실시예는 본 발명을 예시하기 위한 것으로, 본 발명의 범위가 이에 제한되는 것은 아니다.Hereinafter, the present invention will be described in more detail through examples. However, the following examples are intended to illustrate the present invention, and the scope of the present invention is not limited thereto.

<실시예><Example>

1. 재료 및 방법1. Materials and Methods

(1) 재료(1) Materials

본 연구에 사용된 쌀은 신통정미소(Asan, Korea)에서 구입하였고, 카카오 빈은 초코동이(Suwon, Korea)에서 구입하여 사용하였다.Rice used in this study was purchased from Shintongjeong Smile (Asan, Korea), and cacao beans were purchased from Chowondong (Suwon, Korea).

쌀과 카카오 빈의 비율은 4 : 6으로 하여 압출성형 하였으며, 식빵 제조에는 강력분(Daehan Flour Mills Co., Seoul, Korea), 쇼트닝(Lottesamkang Co., Cheonan, Korea), 설탕(Samyang Co., Ulsan, Korea), 정제염(Daesang, Seoul, Korea), 이스트(Ottogi Co., Anyang, Korea)를 구입하여 사용하였다.The ratio of rice and cacao beans was extruded with a ratio of 4 to 6, and for bread production, strong flour (Daehan Flour Mills Co., Seoul, Korea), shortening (Lottesamkang Co., Cheonan, Korea), sugar (Samyang Co., Ulsan) , Korea), purified salt (Daesang, Seoul, Korea), and East (Ottogi Co., Anyang, Korea) were used.

(2) 압출성형(2) Extrusion molding

압출성형물의 제조에 사용된 압출성형기는 자체 제작한 실험용 쌍축 압출성형기(THK31T, Incheon Machinery Co., Incheon, Korea)를 사용하였으며 스크루 배열은 도 1과 같다. 스크루 직경은 30.0 mm이며 길이와 직경의 비(L/D ratio)는 23:1이었고, 사출구는 원형으로 직경이 3.0 mm인 것을 사용하였으며 원료 사입량은 100 g/min으로 고정하였다. 수분함량은 25%, 스크루 회전속도는 200 rpm으로 고정하고 사출구 온도는 130℃로 각각 조절하였다. 제조된 압출성형물은 열풍건조기(DS-FCPO 250, Dongseo Sci. Co., Seoul, Korea)에서 50℃로 건조하여 가정용 분쇄기(SMKA-4000, PN Poongnyun Co., Ltd., Ansan, Korea)로 분쇄하여 50-70 mesh의 분말을 시료로 사용하였다.The extrusion molding machine used for the production of the extrusion molding was a self-made experimental twin-screw extrusion molding machine (THK31T, Incheon Machinery Co., Incheon, Korea), and the screw arrangement is shown in FIG. 1. The screw diameter was 30.0 mm, the ratio of the length and diameter (L / D ratio) was 23: 1, and the injection port was circular and the diameter was 3.0 mm, and the raw material injection amount was fixed at 100 g / min. The water content was 25%, the screw rotation speed was fixed at 200 rpm, and the injection port temperature was adjusted to 130 ° C, respectively. The prepared extruded product is dried in a hot air dryer (DS-FCPO 250, Dongseo Sci. Co., Seoul, Korea) at 50 ℃ and crushed with a household grinder (SMKA-4000, PN Poongnyun Co., Ltd., Ansan, Korea) Thus, a powder of 50-70 mesh was used as a sample.

(3) 반죽의 배합비(3) Mixing ratio of dough

제빵에 사용한 원료의 배합비는 하기 표 1(단위: 중량부)과 같다. The mixing ratio of raw materials used in baking is shown in Table 1 (unit: parts by weight).

Figure 112018035123580-pat00001
Figure 112018035123580-pat00001

반죽의 물성 및 제빵 적성 실험을 위한 카카오 빈과 쌀 압출성형물의 함량은 밀가루 100%를 대조구로 압출성형물(extruded, extrusion) 10(E10), 20(E20), 30%(E30)로 첨가하였으며 압출성형하지 않은 시료와의 차이점을 보고자 비-압출성형물(Non-extruded, Non-Extrusion)도 같은 방식(R10, R20, R30%)으로 첨가하였다. 본 발명자의 다른 실험(14)에서 로스팅(roasting)하지 않은 카카오 빈의 항산화 활성이 우수하여 이를 기본으로 하였다.The content of cacao beans and rice extrudates for the experiment of physical properties and baking aptitude of the dough was added as extruded, extrusion 10 (E10), 20 (E20), 30% (E30) with 100% flour as a control. Non-extruded (non-extrusion) was added in the same way (R10, R20, R30%) to see the difference from the unformed sample. In the other experiment (14) of the present inventor, it was based on the superior antioxidant activity of cacao beans that were not roasted.

(4) 제빵 방법(4) Baking method

제빵은 직접반죽법(straight dough method)을 사용하였고, 식빵의 반죽은 혼합기(Model 200, Hobart Co., USA)를 이용하여 유지와 물을 제외한 나머지 원료를 혼합기 안에 넣고 1단의 속도에서 1분, 물 투입 후 2분간 혼합하고 2단의 속도로 2분간 다시 혼합한 뒤 쇼트닝을 투입하였다. 반죽이 형성 될 때까지 혼합하였으며, 최종 반죽의 온도는 27-29℃가 되도록 하였다. 1차 발효는 온도 27℃, 상대습도 80%인 발효기(Daehung, Korea)에서 90분간 실시하였고, 1차 발효 후 반죽을 170 g으로 분할하여 둥글리기 한 후 10분간 중간 발효를 하였다. 밀대를 이용하여 반죽을 성형하여 3개씩(170 g×3) 식빵 틀(21.5×9.5×9 cm)에 넣고, 온도 38℃, 상대습도 85%의 발효기에서 식빵 틀까지 반죽이 팽창하도록 2차 발효하였으며, 발효가 끝난 반죽을 윗 불 190℃, 아랫 불 190℃의 오븐(FDO-7102, Dae Young, Seoul, Korea)에서 30분간 굽기 하였다. 구운 후 제품을 틀에서 분리하여 실온 25℃에서 2시간 냉각하여 폴리에틸렌 백에 포장 후 25℃에서 저장하여 실험에 사용하였다.For the baking, the straight dough method was used, and the dough for bread was mixed with a mixer (Model 200, Hobart Co., USA), and the rest of the ingredients except oil and water were put into the mixer for 1 minute at the speed of 1 step. After mixing with water for 2 minutes and mixing again for 2 minutes at a speed of 2 steps, shortening was added. The mixture was mixed until a dough was formed, and the temperature of the final dough was set to 27-29 ° C. The first fermentation was performed for 90 minutes in a fermenter (Daehung, Korea) with a temperature of 27 ° C and a relative humidity of 80%, and after the first fermentation, the dough was divided into 170 g and rounded, followed by intermediate fermentation for 10 minutes. The dough is molded using a wheat straw and placed into three (170 g × 3) bread molds (21.5 × 9.5 × 9 cm), and the second fermentation is performed to expand the dough from the fermenter at a temperature of 38 ° C and a relative humidity of 85% to the bread mold. The baked dough was baked for 30 minutes in an oven (FDO-7102, Dae Young, Seoul, Korea) at 190 ℃ on the upper and 190 ℃ on the lower. After baking, the product was separated from the mold, cooled at room temperature of 25 ° C for 2 hours, packaged in a polyethylene bag, and stored at 25 ° C for use in the experiment.

(5) (5) 패리노그래프Parino graph (( FarinographFarinograph ))

패리노그래프(Farinograph, Brabender Co., Ltd., Duisburg,Germany)는 AACC 54-21(17) 방법에 따라 분석하였다. 패리노그래프 믹싱볼(mixing bowl)을 30±2℃로 유지하면서 시료의 수분 함량은 14%를 기준으로 300 g 사용하였고, 시료를 혼합하면서 20초 동안 증류수를 첨가하여 패리노그래프 곡선의 중앙이 500 B.U.에 도달할 때까지 흡수량을 조절하면서 흡수율(absorption), MTI(mechanical tolerance index), 반죽도달시간(arrival time), 반죽형성시간(peak time), 출발시간(departure time), 안정도(stability)를 측정하였다.Parinograph (Farinograph, Brabender Co., Ltd., Duisburg, Germany) was analyzed according to AACC 54-21 (17) method. While maintaining the parinograph mixing bowl at 30 ± 2 ° C, the water content of the sample was used at 300 g based on 14%, while distilled water was added for 20 seconds while mixing the sample, and the center of the parinograph curve was 500. Absorption, MTI (mechanical tolerance index), dough arrival time, dough formation time (peak time), departure time (departure time), stability (stability) while controlling the amount of absorption until reaching BU It was measured.

(6) 호화특성(6) Luxury characteristics

압출성형물과 비-압출성형물을 각각 10, 20, 30% 밀가루에 첨가한 페이스트 점도를 측정하기 위해 신속점도 측정기(RVA, Rapid viscosity analyser, RVA3D, Newport Scientific Inc., Narrabeen, Australia)를 사용하였다. 시료 3.5 g(14%, w.b.)을 알루미늄 캔에 넣은 후 증류수 25 mL를 가하고 유리막대를 이용하여 1차 교반한 후 페이스트 점도를 측정하였다. 신속점도측정기의 가열과 냉각조건은 초기온도 25℃에서 2분간 유지한 후 5분간 95℃로 가열 후 3분간 95℃로 유지하였으며, 5분간 25℃로 냉각하였다. 총 소요 시간은 20분이었으며 페달의 회전은 초기 시료의 분산을 증대시키기 위해 960 rpm으로 회전시킨 후 160 rpm에서 점도를 측정하였다(18). 도 2의 페이스트 점도곡선으로부터 최고점도(peak viscosity, PV), 저온최고점도(cold peak viscosity, CPV), 최저점도(trough viscosity, TV), 최종점도(final viscosity, FV), 구조파괴점도(breakdown viscosity, BV) 등의 페이스트 점도 지표를 각각 구하였다.A rapid viscosity analyzer (RVA, Rapid viscosity analyser, RVA3D, Newport Scientific Inc., Narrabeen, Australia) was used to measure the paste viscosity of the extruded and non-extruded, respectively, added to 10, 20 and 30% flour. After adding 3.5 g (14%, w.b.) of the sample into an aluminum can, 25 mL of distilled water was added, the mixture was first stirred using a glass rod, and the paste viscosity was measured. The heating and cooling conditions of the rapid viscosity meter were maintained at an initial temperature of 25 ° C for 2 minutes, then heated to 95 ° C for 5 minutes, then maintained at 95 ° C for 3 minutes, and cooled to 25 ° C for 5 minutes. The total travel time was 20 minutes, and the rotation of the pedal was measured at 160 rpm after rotating at 960 rpm to increase the dispersion of the initial sample (18). From the paste viscosity curve of FIG. 2, peak viscosity (PV), cold peak viscosity (CPV), trough viscosity (TV), final viscosity (FV), structural breakdown viscosity (breakdown) Viscosity, BV) and other paste viscosity indicators were respectively obtained.

(7) 조직감(Texture)(7) Texture

빵은 구운 후 폴리에틸렌 백에 넣어 실온에서 24시간 방치 후 2×2×2 cm의 동일한 크기로 잘라 물성 분석기(Texture analyzer, TA-XT express, stable micro systems, Surrey,England)를 이용하여 직경이 35 mm인 실린더 프로브(cylinder probe)로 측정하였다. 측정조건은 최대하중 5 kg으로 하고 시험 속도(test speed)는 1 mm/sec, 측정 시료 높이 10 mm, 압착률은 75%로 하여 시료의 경도(hardness), 탄력성(springiness), 응집성(cohesiveness) 및 씹힘성(chewiness)을 측정하였으며 3회 반복 측정하여 그 평균값을 사용하였다.After baking, put it in a polyethylene bag, leave it at room temperature for 24 hours, cut it into the same size of 2 × 2 × 2 cm, and use a material analyzer (Texture analyzer, TA-XT express, stable micro systems, Surrey, England) to have a diameter of 35. It was measured with a cylinder probe (mm). The measurement conditions are the maximum load of 5 kg, the test speed is 1 mm / sec, the measured sample height is 10 mm, and the compression rate is 75%, so that the hardness, springiness, and cohesiveness of the sample are measured. And chewiness (chewiness) was measured and the average value was used by measuring 3 times.

(8) 비용적 및 굽기 손실(8) Costly and burning loss

식빵을 구운 후 실온에서 2시간 동안 냉각한 후 종자치환법(19)으로 용적을 3회 반복 측정하고 하기 계산식 1로 계산하여 비용적(specific volume)을 나타내었다[빵 용적(Bread volume), 빵 중량(Bread weight)].After baking the bread, after cooling for 2 hours at room temperature, the volume was repeatedly measured 3 times by the seed replacement method (19) and calculated by the following calculation formula 1 to show the specific volume [Bread volume, bread Bread weight].

[계산식 1][Calculation formula 1]

Figure 112018035123580-pat00002
Figure 112018035123580-pat00002

굽기 과정의 굽기 손실(baking loss)은 식빵을 구운 후 틀에서 분리하여 저울에 올려 굽기 전 무게 510 g(170 g×3)과 비교하였다. 각기 다른 세 개의 시료를 측정하여 평균값을 내어 사용하였으며, 굽기 손실율(baking loss rate)은 하기 계산식 2로 계산하여 반죽의 굽기 후 무게를 표시하였다[반죽 중량(Dough weight), 빵 중량(Bread weight)].Baking loss in the baking process was compared with the weight of 510 g (170 g × 3) before baking by removing the bread from the mold and placing it on a scale. Three different samples were measured and averaged and used, and the baking loss rate was calculated using Equation 2 below to display the weight after baking the dough (Dough weight, Bread weight) ].

[계산식 2][Calculation formula 2]

Figure 112018035123580-pat00003
Figure 112018035123580-pat00003

(9) 발효 팽창력(9) Fermentation expansion force

압출성형물과 비-압출성형물을 첨가한 반죽의 발효 팽창력은 혼합 직후의 반죽 100 g씩을 채취하여 내부 직경이 6.3 cm인 1000 mL 매스실린더(mass cylinder)에 넣어 측정하였다. 25℃ 발효실에서 발효 시키면서 15분 간격으로 150분 까지 반죽의 발효 팽창력(fermentation power)을 구하였다.The fermentation expansion force of the dough to which the extruded and non-extruded products were added was measured by taking 100 g of the dough immediately after mixing and putting it in a 1000 mL mass cylinder having an inner diameter of 6.3 cm. The fermentation power of the dough was determined up to 150 minutes at 15-minute intervals while fermenting in a 25 ° C fermentation chamber.

(10) 색도 측정(10) Chromaticity measurement

색도는 식빵을 제조 후 색차계(CR-300, Minolta, Osaka, Japan)를 이용하여 각 5회 반복 측정하여 평균값을 내었으며, 식빵의 외부 색도(crust color)와 내부 색도(crumb color)를 명도(lightness, L), 적색도(redness, a), 황색도(yellowness, b)로 측정하였다. 이 때 사용한 표준 백색판(standard plate)의 L값은 97.75, a값은 +1.63, b값은 -2.41이었다.After the bread was manufactured, the average value was obtained by repeatedly measuring each of the bread 5 times using a color difference meter (CR-300, Minolta, Osaka, Japan), and the bread's outer color (crust color) and inner color (crumb color) were measured. It was measured by (lightness, L), redness (a), and yellowness (b). The L value of the standard white plate used was 97.75, the a value was +1.63, and the b value was -2.41.

(11) 관능검사(11) Sensory test

관능평가는 훈련된 관능검사요원 제과제빵과 2학년 학생 12명으로 구성하였다. 시료는 구운 후 1일 경과된 것을 일정한 크기(3×3×3 cm)로 자른 후에 시료의 번호를 무작위로 조합하여 부착된 1회용 접시에 담아 물과 함께 실온에서 동시에 제공하였다. 각 시료를 평가한 후에는 반드시 물로 입안을 헹구어 낸 다음에 다른 시료를 평가하도록 하였다. 관능검사의 평가 항목은 맛(taste), 조직감(texture) 및 전체적 기호도(overall preference)의 3가지 항목으로 하고 9점 척도법을 사용하여 매우 나쁨(extreme bad) 1점부터 매우 좋음(extreme good) 9점까지 기록하도록 하였다.The sensory evaluation consisted of trained sensory bakers baking and 12 second graders. The sample was cut into a certain size (3 × 3 × 3 cm) after 1 day of baking, and then randomly combined with a number of samples, placed in an attached disposable dish, and served simultaneously with water at room temperature. After evaluating each sample, the mouth must be rinsed with water to evaluate the other sample. The evaluation items of sensory evaluation are three items of taste, texture, and overall preference, and 9 points scale method is used to measure very bad from 1 point to extremely bad 9 Points were recorded.

(12) 식빵의 외관 평가(12) Evaluation of the appearance of bread

식빵의 단면구조를 나타내기 위하여 상온에서 냉각시킨 식빵의 가운데 부분을 자르고 디지털카메라(Lumix DMC-FX38, Panasonic, Japan)를 이용하여 촬영하였다.To show the cross-sectional structure of the bread, the middle portion of the bread cooled at room temperature was cut and photographed using a digital camera (Lumix DMC-FX38, Panasonic, Japan).

(13) 통계처리(13) Statistics processing

결과의 통계처리는 SPSS(Statistical Package for the Social Science, version 23.0) 프로그램(IBM-SPSS, Thornwood, NY, USA)을 이용하여 일원배치분산분석(one-way ANOVA)을 실시한 후 유의적 차이가 있는 항목에 대해서 p<0.05 수준에서 그 결과를 Duncan’s multiplerange test로 검정하였다.Statistical processing of the results has a significant difference after one-way ANOVA using SPSS (Statistical Package for the Social Science, version 23.0) program (IBM-SPSS, Thornwood, NY, USA). The items were tested at Dunn's multiplerange test at p <0.05 level.

2. 결과 및 고찰2. Results and Discussion

(1) (One) 패리노그래프Parino graph

패리노그램(farinogram)은 기본적으로 반죽의 굳기에 도달하는데 필요한 흡수율 및 개략적인 반죽 특성의 두 가지 물리적 성질을 나타낸다. 압출성형물과 비-압출성형물의 패리노그램 특성은 하기 표 2와 같다. Farinograms basically represent two physical properties: the absorption rate required to reach the dough's stiffness and the rough dough properties. The parinogram properties of the extruded and non-extruded moldings are shown in Table 2 below.

Figure 112018035123580-pat00004
Figure 112018035123580-pat00004

반죽의 흡수율은 대조군이 64.50%을 나타내었으며, R10, R20, R30에서 62.05, 60.07, 58.00%로 감소하였고, E10, E20, E30도 63.01, 62.02, 61.04%로 감소하였다. 압출성형한 율피분말을 첨가한 식빵실험(20)에서는 첨가군의 흡수율이 대조군보다 높게 나타났는데 이는 율피분말에 함유된 전분입자의 손상으로 인한 손상전분과 식이섬유 때문으로 판단된다. MTI는 대조군이 20.00 B.U를 나타냈으며 R10, R20, R30과 E10, E20, E30 모두 첨가량이 증가할수록 증가하였다. MTI는 반죽 저항도를 나타내는 것으로 일반적으로 반죽에 대하여 저항성이 큰 밀가루는 낮은 값을 보이고, 값이 클수록 약한 밀가루를 나타낸다. 반죽도달시간은 대조군이 1.53 min 이었으며 R10, R20, R30은 첨가량이 증가할수록 감소하였고 E10, E20 E30은 3.02, 4.48, 6.03으로 증가하였다. 압출성형과정 중 곡류전분이 호화가 일어나 낮은 온도(25℃)에서 생전분과 다르게 물을 흡수하여 점도가 형성되어(14) 반죽도달시간이 지연된 것으로 판단된다. 반죽형성시간은 대조군이 8.00 min을 나타내었으며 R10, R20, R30은 첨가량이 증가할수록 감소하였고 E10, E20, E30은 6.80, 7.01, 7.53 min으로 증가하였다. 출발시간, 안정도 역시 대조군이 가장 높게 나타났으며 R10, R20, R30 및 E10, E20, E30 모두 첨가량이 증가할수록 감소하였다. 본 실험결과 압출성형물과 비-압출성형물 첨가 시 믹싱내구력은 부재료의 첨가로 인해 대조군에 비해 약해지는 것으로 나타났다.The absorption rate of the dough was 64.50% in the control group, and decreased from R10, R20, and R30 to 62.05, 60.07, and 58.00%, and the E10, E20, and E30 also decreased to 63.01, 62.02, and 61.04%. In the bread experiment (20) in which extruded yulpi powder was added, the absorption rate of the added group was higher than that of the control group, which is judged to be due to the damaged starch and dietary fiber due to the damage of the starch particles contained in the yulpi powder. MTI showed 20.00 B.U in the control group, and R10, R20, R30 and E10, E20, E30 increased as the amount of addition increased. MTI stands for dough resistance. In general, wheat flour having high resistance to dough exhibits a low value, and a larger value indicates weak flour. The dough delivery time was 1.53 min in the control group, and R10, R20, and R30 decreased as the addition amount increased, and E10, E20 and E30 increased to 3.02, 4.48, and 6.03. During the extrusion molding process, grain starch is gelatinized and absorbs water differently from raw starch at a low temperature (25 ° C) to form a viscosity (14), so it is judged that the dough delivery time is delayed. The dough formation time was 8.00 min in the control group, and R10, R20, and R30 decreased as the addition amount increased, and E10, E20, and E30 increased to 6.80, 7.01, and 7.53 min. The starting time and stability were also the highest in the control group, and all of R10, R20, R30 and E10, E20, and E30 decreased as the addition amount increased. As a result of this experiment, it was found that the mixing durability of the extruded and non-extruded compounds was weaker than that of the control group due to the addition of the additive.

(2) 호화 특성(2) Luxury characteristics

압출성형물과 비-압출성형물의 점도는 하기 표 3과 같다. The viscosity of the extruded and non-extruded moldings is shown in Table 3 below.

Figure 112018035123580-pat00005
Figure 112018035123580-pat00005

최고점도(PV)는 농도에 영향을 받게 되는데 R10, R20, R30 및 E10, E20, E30 모두 대조군보다 첨가량이 증가할수록 낮게 나타났으며, 최저점도(TV)와 구조파괴점도(BV) 역시 대조군보다 첨가량이 증가할수록 낮게 나타났다. 최종점도(FV)와 회복점도(SV)는 대조군이 4857 cP, 3488 cP로 나타났으며 R10, R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 낮게 나타났다. 최종점도는 노화도가 낮을수록 낮게 나타나며(21), 회복점도도 다양한 제품들의 조직감을 비교할 때 사용되는 지표로 전분의 노화정도를 반영하는데 R10, R20, R30보다 E10, E20, E30의 최종점도, 회복점도가 낮게 나타나 노화가 더 지연될 것으로 판단된다. Peak time은 대조군이 8.67 cP, R10에서 8.58 cP를 나타냈으며 R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 감소하였다. 호화개시온도는 대조군이 69℃를 나타냈으며 R10, R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 증가하였다. 카카오 빈의 지방 성분이 아밀로오스와 결합하여 호화시간을 지연시킨 것으로 판단되며 카카오 빈에 함유된 코코아 버터의 평균융점이 34℃(22)로 낮아 대조군과의 차이는 크게 나타나지 않았다.The highest viscosity (PV) is affected by the concentration, and R10, R20, R30 and E10, E20, E30 were lower as the amount of addition increased than the control, and the lowest viscosity (TV) and structural breakdown viscosity (BV) were also higher than the control. It appeared lower as the amount of addition increased. The final viscosity (FV) and recovery viscosity (SV) were found to be 4857 cP and 3488 cP in the control group, and decreased as the amount of addition of R10, R20, R30 and E10, E20, and E30 increased. The final viscosity is lower as the aging degree is lowered (21), and the recovery viscosity is an index used to compare the texture of various products.It reflects the degree of aging of starch, and the final viscosity and recovery of E10, E20, E30 than R10, R20, R30. It is judged that the aging will be delayed due to the low viscosity. The peak time was 8.67 cP in the control group, 8.58 cP in R10, and decreased as the amount of R20, R30 and E10, E20, and E30 increased. The luxury initiation temperature was 69 ° C in the control group, and increased with increasing amounts of R10, R20, R30 and E10, E20, and E30. It was determined that the fat component of cacao bean was combined with amylose to delay the gelatinization time, and the average melting point of cocoa butter contained in cacao bean was 34 ° C (22), so there was no significant difference from the control group.

(3) 조직감(Texture)(3) Texture

압출성형물과 비-압출성형물을 첨가하여 제조한 식빵의 조직감은 하기 표 4와 같다. The texture of the bread prepared by adding the extrudate and the non-extrusion is shown in Table 4 below.

Figure 112018035123580-pat00006
Figure 112018035123580-pat00006

식품의 단단함 정도를 나타내는 경도(hardness)는 대조군이 5.39 g을 나타냈으며 R20 4.59 g, E20 4.83 g으로 대조군보다 부드러운 것으로 나타났다. R10, R30은 6.33, 6.69 g으로 나타났으며 E10, E30은 8.25, 6.49 g으로 대조군보다 단단한 것으로 나타났다. 새송이 버섯분말(23)과 신안 섬초 분말을 첨가한 식빵(7)에서는 첨가량이 증가할수록 경도가 증가하였고, 단감(24)과 백련차(25)를 첨가한 식빵에서는 첨가량이 증가할수록 경도는 감소하여 식빵은 첨가되는 부재료의 성질과 양에 따라 달라지는 경향을 나타내는 것으로 판단된다. 탄력성(springiness)은 대조군이 0.96 이었으며 R10, R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 감소하였으나 유의적인 차이는 나타나지 않았다(p<0.05). 응집성(cohesiveness)은 대조군에서 0.57을 나타내었으며 R10, R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 유의적으로 감소하였다(p<0.05). 씹힘성(chewiness)은 E10에서 4.28로 가장 높았으며 R20이 2.00으로 가장 낮게 나타났다. 빵의 경도는 부피, 기공의 발달정도, 수분 함량, 이스트의 양, 발효 시간, 소금의 양과 성형기술에 의해 영향을 받는데 기공이 잘 발달된 빵은 부피가 크고 부드럽기 때문에 경도가 낮아진다.The hardness indicating the degree of food stiffness was 5.39 g in the control group, and R20 4.59 g and E20 4.83 g were found to be softer than the control group. R10 and R30 were 6.33 and 6.69 g, and E10 and E30 were 8.25 and 6.49 g, which was stronger than the control group. In the bread (7) with the oyster mushroom powder (23) and the Sinan island paste added, the hardness increased as the amount increased, and in the bread with the added sweet persimmon (24) and white lotus tea (25), the hardness decreased and the bread decreased. It is judged that it shows a tendency to vary depending on the nature and amount of the added material. The springiness was 0.96 in the control group and decreased as the addition amount of R10, R20, R30 and E10, E20, E30 increased, but no significant difference was found ( p <0.05). Cohesiveness was 0.57 in the control group and was significantly decreased as the amount of R10, R20, R30 and E10, E20, E30 increased ( p <0.05). The chewiness was highest from E10 to 4.28 and the lowest from R20 to 2.00. The hardness of bread is influenced by volume, degree of pore development, moisture content, amount of yeast, fermentation time, salt amount and molding technology. Bread with well-developed pores is bulky and soft, so its hardness is low.

(4) 비용적 및 굽기 손실(4) Cost and burning loss

압출성형물과 비-압출성형물을 첨가하여 제조한 식빵의 비용적과 굽기 손실은 하기 표 5와 같다. The cost and baking loss of the bread prepared by adding the extruded and non-extruded products are shown in Table 5 below.

Figure 112018035123580-pat00007
Figure 112018035123580-pat00007

비용적은 대조군이 4.42로 나타났으며 E10이 4.29를 나타내었다. R10, R20, R30은 4.12, 3.55, 3.28로 감소하였고 E20, E30은 4.11, 3.58로 감소하였으나 R10, R20, R30보다 높게 나타났다. 가스 보유력이 약하게 되면 빵의 부피는 감소하는데 부재료 첨가로 인한 글루텐(gluten)의 희석 효과와 60-70℃ 사이에 호화되어 구조를 형성하는 전분에 비해 34℃ 정도의 융점을 가지는 코코아 버터의 용해로 반죽의 구조가 약화되었을 것으로 판단된다. 아로니아 첨가식빵(26)과 신안 섬초 분말을 첨가한 식빵(7)도 첨가군의 양이 증가할수록 비용적이 감소하였다. 그러나 산수유 분말을 첨가한 식빵(27)에서는 첨가량이 증가할수록 비용적이 증가하였는데 이는 산수유의 신맛을 나타내는 유기산의 영향으로 반죽의 가스 팽창력을 증가시킨 것으로 판단된다.The specific control group was 4.42 and E10 was 4.29. R10, R20, R30 decreased to 4.12, 3.55, 3.28, and E20, E30 decreased to 4.11, 3.58, but higher than R10, R20, R30. When the gas holding power is weak, the volume of the bread decreases, but the dilution effect of gluten due to the addition of subsidiary materials and the melting furnace of cocoa butter having a melting point of about 34 ° C compared to starch that is gelatinized between 60-70 ° C to form a structure are kneaded. It seems that the structure of has been weakened. The bread added with Aaronia added bread (26) and the bread added with Shinan island grass powder (7) also decreased in cost as the amount of the added group increased. However, in the bread 27 to which the cornus powder was added, the cost increased as the addition amount increased, which is judged to increase the gas expansion power of the dough due to the influence of the organic acid representing the acidity of the cornice.

굽기 손실은 R10에서 10.33% 로 가장 높게 나타났으며 대조군과 R20, R30 및 E10, E20, E30에서 첨가량이 증가할수록 감소하였으나 유의적인 차이는 나타나지 않았다(p<0.05). 실험 결과 첨가되는 부재료의 성질과 양, 글루텐을 형성하는 단백질의 감소로 인해 비용적과 굽기 손실이 감소한 것으로 판단된다.The burning loss was highest at 10.33% in R10, and decreased as the addition amount increased in the control group and R20, R30 and E10, E20, and E30, but no significant difference was found ( p <0.05). As a result of the experiment, it is considered that the cost and burning loss were reduced due to the decrease in the nature and amount of the additives added and the protein forming gluten.

(5) 발효 팽창력(5) Fermentation expansion force

압출성형물과 비-압출성형물을 첨가하여 제조한 식빵의 발효 팽창력은 도 2와 같다. 이스트는 반죽내에서 발효 환경에 적응하는데 약 45분이 소요되며 반죽에 존재하는 당은 원래 밀가루에 존재하는 유리당, 이스트 또는 밀가루의 효소에 의해 분해되는 당 및 첨가되는 당으로 발효시간 60분에서는 대조군이 250 mL로 나타났으며 R10, R20, R30에서 220, 240, 230 mL로 E10, E20, E30의 220, 220, 210 mL보다 높았으나 발효시간 90분에서는 R10, R20, R30의 320, 330, 280 mL보다 E10, E20, E30에서 330, 340, 310 mL로 높게 나타났다. 90분까지는 대조군이 가장 높은 팽창력을 보였으나 120분 발효시간에서는 대조군이 380 mL를 나타내었으며 R10, R20, R30에서 340, 350, 300을 나타내었고 E10, E20, E30에서는 400, 400, 360 mL로 E10, E20첨가량에서 대조군보다 높은 발효력을 나타내었다. 발효시간 150분에서는 E10, E20, E30첨가량에서 400, 390, 360 mL로 모두 대조군의 350 mL보다 높은 발효력을 나타내었으며 R10, R20, R30에서는 330, 300, 290 mL로 발효력이 감소하였다. Lee 등(20)은 압출성형공정을 통해 율피분말의 전분이 발효성 당으로의 전환이 가속화되어 발효팽창력의 증가에 영향을 주었다고 하였고, Kang 등(28)은 식빵에 다른 첨가물을 넣어 제조할 경우 글루텐 함량과 첨가물의 성질에 따라 활성 글루텐 등의 구조를 유지할 수 있는 보조물질을 첨가하지 않으면 구조력을 유지하기 어려워 부피가 감소한다고 하였다.The fermentation expansion force of the bread prepared by adding the extrudates and the non-extrusion molds is shown in FIG. 2. Yeast takes about 45 minutes to adapt to the fermentation environment in the dough. The sugar present in the dough is free sugar present in the original flour, sugar decomposed by enzymes of yeast or wheat, and added sugar. It appeared as 250 mL and was higher than 220, 220, 210 mL of E10, E20, E30 from R10, R20, R30 to 220, 240, 230 mL, but at 90 minutes of fermentation time, 320, 330, 280 of R10, R20, R30 It was higher in E10, E20, E30 than mL, 330, 340, 310 mL. Until 90 minutes, the control group showed the highest expansion, but at 120 minutes fermentation time, the control group showed 380 mL, and R10, R20, and R30 showed 340, 350, 300, and E10, E20, and E30 showed 400, 400, and 360 mL. E10 and E20 showed higher fermentation power than the control group. At the fermentation time of 150 minutes, E10, E20, and E30 added at 400, 390, and 360 mL, all of which showed a higher fermentation power than 350 mL of the control group, and at 10, R20, and R30, the fermentation power decreased to 330, 300, and 290 mL. Lee et al. (20) said that starch of yulpi powder through the extrusion molding process accelerated the conversion to fermentable sugars, which influenced the increase in fermentation expansion power, and Kang et al. (28) produced other additives in bread According to the content of gluten and the nature of the additive, it is said that the volume is reduced because it is difficult to maintain the structural strength without adding an auxiliary substance capable of maintaining the structure such as active gluten.

(6) 색도 측정(6) chromaticity measurement

압출성형물과 비-압출성형물을 첨가하여 제조한 식빵의 색도는 하기 표 6과 같다. The color of the bread prepared by adding the extruded product and the non-extruded product is shown in Table 6 below.

Figure 112018035123580-pat00008
Figure 112018035123580-pat00008

외부(crust)의 색상은 아미노산 화합물과 환원당과의 반응에 의해 형성되는 메일라이드 반응에 기인하는 것으로 대조군이 가장 높은 명도, 적색도, 황색도를 나타내었으며 R10, R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 명도, 적색도, 황색도는 감소하는 경향을 나타내었다. 내부(crumb)의 명도는 대조군이 80.23을 나타내었고 R10, R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 감소하였지만 적색도는 R10, R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 높게 나타났다. 황색도는 대조군이 6.54를 나타내었으며 R10, R20, R30첨가량에서는 13.75, 16.01, 15.25, E10, E20, E30의 첨가량에서는 14.10, 15.29, 14.73으로 대조군보다 높게 나타났다. 발효에 따라 다양한 색을 나타내는 카카오 빈(29)의 폴리페놀류의 영향을 받은 것으로 판단된다.The color of the crust is due to the mailide reaction formed by the reaction of the amino acid compound with the reducing sugar, and the control group showed the highest brightness, redness, and yellowness, and R10, R20, R30 and E10, E20, E30 Brightness, redness, and yellowness tended to decrease as the amount of added was increased. The brightness of the interior (crumb) was 80.23 in the control group, and decreased as the addition amount of R10, R20, R30 and E10, E20, E30 increased, but the redness increased as the addition amount of R10, R20, R30 and E10, E20, E30 increased. appear. The yellowness level of the control group was 6.54, and 13.10, 15.25, E10, E20, and E30 in the addition amount of R10, R20, and R30 were 14.10, 15.29, and 14.73, which were higher than the control group. It is judged that the polyphenols of the cacao bean 29 exhibiting various colors are affected by fermentation.

(7) 관능검사(7) Sensory test

압출성형물과 비-압출성형물을 첨가하여 제조한 식빵의 관능검사는 하기 표 7과 같다. Sensory evaluation of bread prepared by adding extruded and non-extruded products is as follows. Table 7.

Figure 112018035123580-pat00009
Figure 112018035123580-pat00009

맛(taste)은 대조군이 8.25로 나타났으며 E10 8.00, E20 8.08로 대조군과 유의적인 차이가 나타나지 않았다(p<0.05). 조직감(texture)은 대조군이 8.50으로 나타났으며 R10 8.00, E10 8.17, E20 8.08로 대조군과 유의적인 차이가 나타나지 않았다(p<0.05). Kim(30)의 녹차 빵 관능 특성 연구에서도 대조구에 비하여 녹차분말의 첨가량이 증가할수록 조직감이 저하되어 대조구와 첨가군간의 유의적인 차이가 있다고 하였다. 전체적 기호도(overall preference)는 대조군이 8.25로 나타났으며 R10, R20, R30은 8.00, 7.92, 7.00로 감소하였고 E10, E20, E30은 8.08, 8.17, 7.42로 감소하였지만 대조군과 R10, R20, E10, E20은 유의적인 차이가 나타나지 않았다(p<0.05). 본 실험 결과 물리적 특성 및 소비자 기호도 등을 고려하여 카카오 빈과 쌀 압출성형물을 제빵에 사용 시 20%까지 첨가하는 것이 바람직한 것으로 판단된다.Taste was found to be 8.25 in the control group, and E10 8.00 and E20 8.08 did not show a significant difference from the control group ( p <0.05). The texture was 8.50 in the control group, and R10 8.00, E10 8.17, and E20 8.08 did not show a significant difference from the control group ( p <0.05). In the study of sensory characteristics of green tea bread by Kim (30), the texture increased as the amount of green tea powder added increased compared to the control, and there was a significant difference between the control and the added groups. The overall preference was 8.25 for the control group, R10, R20, and R30 decreased to 8.00, 7.92, and 7.00, and E10, E20, and E30 decreased to 8.08, 8.17, and 7.42, but the control group and R10, R20, E10, E20 did not show a significant difference ( p <0.05). As a result of this experiment, it is judged that it is desirable to add up to 20% of cacao beans and rice extrudates when used in baking considering physical properties and consumer preference.

(8) 식빵의 외관(8) The appearance of white bread

압출성형물과 비-압출성형물을 첨가하여 제조한 식빵의 외관은 도 3에 나타내었다. 비용적의 결과와 같이 대조군이 가장 큰 부피를 형성하였으며, R10, R20, R30보다 E10, E20, E30의 첨가량에서 부피가 더 큰 것으로 나타났다. 실험결과 압출성형물과 비-압출성형물의 첨가량 모두 글루텐의 부족에 의해 빵의 기본 구조 형성이 이루어지지 않은 것으로 판단된다.The appearance of the bread prepared by adding the extruded product and the non-extruded product is shown in FIG. 3. As a result of the cost, the control group formed the largest volume, and it was found that the volume of E10, E20, and E30 was larger than that of R10, R20, and R30. As a result of the experiment, it was determined that the basic structure of the bread was not formed due to the lack of gluten in both the amount of the extruded and the non-extruded.

3. 요약3. Summary

본 연구에서는 카카오 빈(cacao whole bean)을 사용하여 압출성형하고 이를 식품소재로 개발하고자 하였으며 비교를 위해 압출성형물과 비-압출성형물을 밀가루에(10, 20, 30%) 첨가하여 식빵 반죽의 물성과 품질특성에 미치는 효과를 관찰하였다. 패리노그램은 대조군이 높은 흡수율과 안정도를 나타냈으며 압출성형물과 비-압출성형물은 첨가량이 증가할수록 흡수율은 감소하였고 MTI는 증가하였다. 호화특성은 대조군이 최고점도, 구조파괴점도, 최종점도, 회복점도가 모두 높게 나타났으며 압출성형물과 비-압출성형물은 첨가량이 증가할수록 감소하였으나 R10, R20, R30보다 E10, E20, E30의 최종점도, 회복점도가 낮게 나타났다. 경도는 대조군이 5.39 g을 나타냈으며 R20 4.59와 E20 4.83 g으로 대조군보다 부드러운 것으로 나타났다. 탄력성은 유의적인 차이가 나타나지 않았으며(p<0.05), 응집성은 대조군에서 0.57을 나타내었고 R10, R20, R30 및 E10, E20, E30의 첨가량이 증가할수록 유의적으로 감소하였다(p<0.05). 씹힘성은 E10에서 4.28을 나타냈으며 R20이 2.00으로 가장 낮게 나타났다. 비용적은 대조군이 4.42였고 E10이 4.29를 나타내었다. R10, R20, R30은 4.12, 3.55, 3.28로 감소하였고 E20, E30은 4.11, 3.58로 나타났다. 굽기 손실은 R10에서 10.33%로 나타났으며 대조군과 R20, R30 및 E10, E20, E30에서 첨가량이 증가할수록 감소하였으나 유의적인 차이는 나타나지 않았다(p<0.05). 외부(crust)의 L, a, b값은 대조군이 가장 높게 나타났으며 압출성형물과 비-압출성형물의 첨가량이 증가할수록 감소하였다. 내부(crumb)의 L값은 대조군이 80.23을 나타냈으며 압출성형물과 비-압출성형물의 첨가량이 증가할수록 감소하였지만 a, b값은 증가하였다. 관능검사 결과 맛은 대조구와 E10, E20에서 유의적인 차이가 나타나지 않았고(p<0.05), 전체적 기호도는 대조군과 R10, R20, E10, E20에서 유의적인 차이가 나타나지 않았다(p<0.05). 본 실험 결과 물리적 특성 및 소비자 기호도 등을 고려하여 카카오 빈과 쌀 압출성형물을 제빵에 사용 시 10-20%까지 첨가하는 것이 바람직한 것으로 판단된다.In this study, we tried to extrude using cacao whole bean and develop it as a food material. For comparison, the properties of bread dough by adding extruded and non-extruded products to flour (10, 20, 30%) The effect on the quality characteristics was observed. In the parinogram, the control group showed a high absorption rate and stability, and the extrudates and non-extrusion moldings decreased in absorption rate and increased MTI as the amount of addition increased. The luxury characteristics showed that the control group had the highest viscosity, structural breakdown viscosity, final viscosity, and recovery viscosity. Extrusions and non-extrusion moldings decreased as the amount of addition increased, but the finality of E10, E20, and E30 was higher than that of R10, R20, and R30. The viscosity and recovery viscosity were low. The hardness of the control group was 5.39 g, and R20 4.59 and E20 4.83 g were found to be softer than the control group. There was no significant difference in elasticity ( p <0.05), cohesiveness was 0.57 in the control group, and it was significantly decreased as the amount of R10, R20, R30 and E10, E20, E30 increased ( p <0.05). The chewiness was 4.28 in E10 and R20 was the lowest in 2.00. The specific volume was 4.42 for the control and 4.29 for the E10. R10, R20 and R30 decreased to 4.12, 3.55 and 3.28, and E20 and E30 were 4.11 and 3.58. The burning loss was 10.33% in R10, and it decreased as the addition amount increased in the control group and R20, R30 and E10, E20, E30, but there was no significant difference ( p <0.05). The L, a, and b values of the crust were the highest in the control group and decreased as the amount of the extruded and non-extruded components increased. The L value of the crumb was 80.23 for the control group, and decreased as the addition amount of the extruded and non-extruded compounds increased, but the a and b values increased. As a result of the sensory test, the taste did not show a significant difference in the control and E10, E20 ( p <0.05), and the overall preference did not show a significant difference in the control and R10, R20, E10, E20 ( p <0.05). As a result of this experiment, it is judged that it is desirable to add up to 10-20% of cacao beans and rice extrudates when used in baking considering physical properties and consumer preference.

Claims (6)

(a) 쌀과 로스팅하지 않은 카카오 빈이 중량비 4 : 6으로 압출성형된 카카오 빈-쌀 압출성형물과 밀가루를 1 : 9 ~ 2 : 8 중량비로 혼합하여 반죽을 얻는 단계; 및
(b) 단계(a)에서 얻어진 반죽을 발효시킨 후 굽는 단계
를 포함하는, 카카오 빈과 쌀 압출성형물을 첨가한 빵의 제조방법.
(a) mixing the cacao bean-rice extruded product with wheat and unbaked cacao beans at a weight ratio of 4: 6 and wheat flour in a weight ratio of 1: 9 to 2: 8 to obtain a dough; And
(b) a step of fermenting and baking the dough obtained in step (a)
Including, cacao beans and bread manufacturing method of adding the extrudate.
삭제delete 삭제delete 제1항에 있어서, 단계(b)의 상기 발효가 1차 발효, 중간 발효, 2차 발효의 순서로 이루어지는 것을 특징으로 하는 제조방법.The method according to claim 1, wherein the fermentation in step (b) is performed in the order of primary fermentation, intermediate fermentation, and secondary fermentation. 제1항에 있어서, 단계(a)의 상기 카카오 빈-쌀 압출성형물이 쌍축 압출성형기를 사용하여 스크루 직경 20.0 ~ 40.0 mm, 길이/직경의 비(L/D ratio) 20 ~ 25:1인 스크루를 사용하고, 수분 함량 15 ~ 35%, 스크루 회전속도 100 ~ 300 rpm, 사출구 온도 120 ~ 140℃의 조건으로 압출성형된 것을 특징으로 하는 제조방법.The screw of claim 1, wherein the cacao bean-rice extrudate of step (a) has a screw diameter of 20.0 to 40.0 mm and a length / diameter ratio (L / D ratio) of 20 to 25: 1 using a twin-screw extruder. Using, 15 to 35% water content, the rotation speed of the screw 100 ~ 300 rpm, the manufacturing method characterized in that the extrusion molding under the conditions of the injection port temperature 120 ~ 140 ℃. 제1항, 제4항 및 제5항 중 어느 한 항에 의해 제조된 카카오 빈과 쌀 압출성형물을 첨가한 빵.Bread to which cacao beans and rice extrudates prepared by any one of claims 1, 4 and 5 are added.
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